SRI AADARSH JUNIOR COLLEGE

KUKATPALLY
SECOND YEAR
EAPCET-2
MPC d. Three sigma bonds
CHEMISTRY-II 8. Phosphorous acid on heating gives the
1. The oxidation states usually shown by following products
nitrogen and phosphorus are, The above reaction is an example of
a. +3 only a. Oxidation
b. +5 only b. Thermal decomposition
c. Both +3 and +5 c. Disproportionation
d. -3 d. Reduction
2. When white phosphorus is heated at 473K 9. Complete the following reaction, 𝑃𝐶𝑙5
under high pressure , what will happen 𝐻𝑒𝑎𝑡
𝑝𝑟𝑜𝑑𝑢𝑐𝑡(𝑠)The product is /are
a. Alpha- Black phosphorus is formed a. PCl3
b. Beta- Black phosphorus is formed b. Cl2
c. Red phosphorus is formed c. POCl3
d. No change would be observed d. Both a and b
3. Which of the following oxides is anhydride 10. Which of the following elements has the
of nitrous acid? greatest tendency to form A3- ions?
a. N2O3 a. Phosphorous
b. NO2 b. Nitrogen
c. NO c. Bismuth
d. N2O4 d. Antimony
4. Correct order of decreasing lewis acid 11. Which among the following oxoacids of
strength of trichlorides of group 15 elements phosphorous will have P-O-P bonds?
is i. H4P2O5
a. AsCl3>PCl3>BiCl3>SbCl3 ii. H4P2O6
b. PCl3>AsCl3>SbCl3>BiCl3 iii. H4P2O7
c. NCl3>PCl3>AsCl3>SbCl3 iv. (HPO3)3
d. SbCl3>BiCl3>PCl3>AsCl3 a. III & IV
5. The decreasing order of boiling points of the b. I & II
following hydrides c. I & III
a. SbH3>AsH3>PH3>NH3 d. II & IV
b. NH3>SbH3>Ash3>PH3 12. Consider the reaction
c. SbH3>NH3>AsH3>PH3 P4+3NaOH+3H2OQ+3NaH2PO2 identity the
d. PH3>AsH3>SbH3>NH3 reaction in which Q is not the product
6. Fill in the blanks (Equation are not balanced)
i) Ca3P2+6HCL->3CaCl2+.....p.... a. Ca3P2+H2O-
ii) P4+3NaOH+3H2O- b. H3PO3-delta
>.....q....+3NaH2PO2 c. PH4I+KOH-
iii) PH4I+KOH->KI+H2O+....r........p,q,r d. PCl3+H2O
respectively 13. Brown ring test is to detect the presence of
a. PH3,H3PO3,PI3 a. NO3-
b. PH3,PH3,PH3 b. Cl-
c. PCl3,H3PO4,PH3 c. I-
d. PCl5,PH3,P4O6 d. Br-
7. In nitrogen molecule, the two atoms of 14. When copper metal is treated with cold and
nitrogen are joined by dilute nitric acid , it forms
a. One sigma bond and one Pi bond a. NO
b. Two sigma bonds and one Pi bond b. N2O
c. One sigma bond and two Pi bond c. N2O5
 d. NO3 c. Only S is correct, but R is wrong
15. Which one of the following is not a colour d. Both S and R are wrong
less compound 23. The refractive index of the material of a
a. NO double convex lens is 1.5 and its focal length
b. N2O4 is 5 cm. If the radii of curvature are equal,
c. N2O the value of the radius of curvature (in cm) is
d. NO2 a. 5.0
16. How many bridging oxygen atoms are b. 6.5
present in P4O10? c. 8.0
a. 4 d. 9.5
b. 5 24. An achromatic combination of lenses
c. 6 produces
d. 2 a. Images in black and white
17. Oxidation state of S in H2S2O8 b. Coloured images
a. 8 c. images unaffected by variation of
b. 6 refractive index with wavelength
c. 4 d. Highly enlarged images are formed
d. 7 25. Consider the following statements A and B.
18. Which of the following does not exist Identify the correct choice in the given
a. XeOF4 answers.
b. NeF2
c. XeF2 A. The refractive index of the extra-
d. XeF6 ordinary ray depends on the angle of
19. Commercial name of peroxydisulphric acid is incidence in double refraction.
a. Marshall acid B. The vibrations of light waves acquire
b. Caro’s acid one sidedness for both ordinary and
c. Oleum extraordinary rays in double
d. Fuming sulphuric acid refraction.
20. The geometry of XeO4 is a. A and B are wrong
a. Octaherdal b. A and B are correct
b. Tetrahedral c. A is correct and B is wrong
c. Linear d. A is wrong and B is correct
d. Square pyramidal 26. A convex lens of focal length 0.15 m is made
of material of refractive index 3/2. When it is
PHYSICS-II placed in a liquid, its focal length is increased
21. The refractive index of a material of a plano- by 0.225 m. The refractive index of the liquid
concave lens is 5/3, the radius of curvature is
is 0.3 m. The focal length of the lens in air is a. 7/4
a. -0.45m b. 5/4
b. -0.6m c. 9/4
c. -0.75m d. 3/2
d. -1.0m 27. A prism is made up of material of refractive
22. Statement (S): Using Huygen's eyepiece index √3. The angle of the prism is Å. If the
mea- surement can be taken but are not angle of minimum deviation is equal to angle
correct. of the prism, then the value of A is
Reason (R): The cross wires, scale and final a. 30°
image are not magnified proportionately b. 45°
because the image of the object is magnified c. 60°
by two lenses, whereas the cross wire scale d. 75°
is magnified by one lens only. 28. The difference in the number of
a. Both S and R are true, R explains S wavelengths, when yellow light propagates
b. Both S and R are true, but R cannot through air and vacuum columns of the
explains S same thickness is one. The thickness of the
 air column is [Refractive index of air µ 34. The focal length of an equi-convex lens is
1.0003, wave- length of yellow light in greater than the radius of curvature of any
vacuum = 6000 Å] of the surfaces. Then, the refractive index of
a. 1.8 mm the material of the lens is
b. 2 mm a. Greater than zero but less than 1.5
c. 2 cm b. Greater than 1.5 but less than 2.0
d. 2.2 cm c. Greater than 2.0 but less than 2.5
29. When a glass prism of refracting angle 60° is d. Greater than 2.5 but less than 2.0
immersed in a liquid its angle of minimum 35. Assertion (A): Optical fibres are widely used
deviation is 30°. The critical angle of glass in communication network.
with respect to the liquid medium is Reason (R): Optical fibres are small in size,
a. 42° lite weight, flexible and there is no scope for
b. 45° interference in them.
c. 50° a. Both (A) and (R) are true and (R) is the
d. 52° correct explanation of (A)
30. In the visible region the dispersive powers b. Both (A) and (R) are true but (R) is not
and the mean angular deviations for crown the correct explanation of (A)
and flint glass prisms are ω, ω' and d, d' c. (A) is true but (R) is false
respectively. The condition of getting d. (A) is false but (R) is true
dispersion with zero deviation, when th two 36. 21. In Ramsden eyepiece, the two
prisms are combined is planoconvex lenses each of focal length fare
a. √ ω d + √ ω 'd = 0 separated by a distance 12 cm. The
b. ω 'd + ω d' = 0 equivalent focal length (in cm) of the
c. ω d + ω 'd' = 0 eyepiece is
d. (ω d)² + (ω 'd') ²=0 a. 10.5
31. One face of the glass prism is silver polished. b. 13.5
A light ray falls at an angle of 45° on the c. 12.0
other face. After reflection it is subsequently d. 15.5
reflected from the silvered face and then 37. 1. Three thin lenses are combined by placing
retraces its path. The refracting angle of them in contact with each other to get more
prism is 30°. The refractive index of the magnification in an optical instrument. Each
prism is lens has a focal length of 3 cm. If the least
a. 3/2 distance of distinct vision is taken as 25 cm,
b. √2 the total magnification of the lens
c. √3/2 combination in normal adjustment is
d. √3 a. 9
32. Assertion (A): Propagation of light through b. 26
an optical fibre is due to total internal reflec- c. 300
tion taking place at the core-clad interface. d. 3
Reason (R): Refractive index of the material 38. An image is formed at a distance of 100 cm
of the core of the optical fibre is greater from the glass surface when light from point
than that of air. source in air falls on a spherical glass surface
a. Both (A) and (R) are true and (R) is the with refractive index 1.5. The distance of the
correct explanation of (A) light source from the glass surface is 100 cm.
b. Both (A) and (R) are true but (R) is not The radius of curvature is
the correct explanation of (A) a. 20 cm
c. (A) is true but (R) is false b. 40 cm
d. (A) is false but (R) is true c. 30 cm
33. Dispersive power depends on the following d. 50 cm
a. Material of the prism 39. A convex lens of glass (1.45) has a focal
b. Shape of the prism length f, in air. The lens is immersed in a
c. Size of the prism liquid of refractive index (4) 1.3. The ratio of
d. Size, shape and material of the prism the liquid is
 a. 3.9
b. 0.23
c. 0.43
d. 0.39
40. A thin converging lens of focal length f= 25
cm forms the image of an object on a screen
placed at a distance of 75 cm from the lens.
The screen is moved closer to the lens by a
distance of 25 cm. The distance through
which the object has to be shifted, so that its
image on the screen in sharp again is
a. 37.5 cm
b. 16.25 cm
c. 12.5 cm
d. 13.5 cm