NEET/JEE Hints and Solutions Guide
NEET/JEE Hints and Solutions Guide
NEET/JEE
HINTS, SOLUTIONS, EXPLANATIONS
Given ℎ 𝑡ℎ = 2×ℎ 𝑡ℎ. By solving we get 𝑢 = 65 𝑚/𝑠
5 6
1 (3) 7 (2)
If acceleration is variable (depends on time) then
2
𝑎𝑡
𝑣 = 𝑢 + ∫(𝑓)𝑑𝑡 = 𝑢 + ∫(𝑎 𝑡)𝑑𝑡 = 𝑢 + 2
8 (3)
𝑅𝑒𝑞 Between any two vertex will be 𝑚𝑣
2
Tension, 𝑇 = 𝑟
+ 𝑚𝑔 cos 𝑐𝑜𝑠 θ
1 1 1
𝑅𝑒𝑞
= 12 + 6 ⇒ 𝑅𝑒𝑞 =4Ω 𝑚𝑣
2
𝐹𝑜𝑟, θ = 30°, 𝑇1 = + 𝑚𝑔 cos 𝑐𝑜𝑠 30°
2 (2) 𝑟
3 (4) 9 (1)
1 2 2𝑢sin𝑠𝑖𝑛 θ
Kinetic energy, 𝐸 = 𝑚𝑣 Time of flight, 𝑇 = 𝑔
2
'2 2 2𝑑𝑢sin𝑠𝑖𝑛 θ
∆𝐸 𝑣 −𝑣 ∴ 𝑑𝑇 =
∴ 𝐸
×100 = 2 ×100 𝑔
𝑣
2
= [(1. 5) − 1]×100 Now, ∴
𝑑𝑇
=
𝑑𝑢
=
1
𝑇 𝑢 20
𝑑𝑇
= 125% ∴% increase in 𝑇 = ×100
𝑇
(1)
1
4 = 20
×100 = 5%
2 −2
2 −2
= ⎡⎢ 2 ⎤⎥ = [𝑀𝑇 ]
1 [𝑊] 𝑀𝐿 𝑇
𝑊= 𝑘𝑥 ⇒ [𝑘] =
2 2
[𝑥 ] ⎣ 𝐿 ⎦ 10 (4)
2
𝑢 𝑜
5 (2) ℎ𝑚𝑎𝑥 = 2𝑔
= 10 [∵θ = 90 ]
Time taken by first drop to reach the ground
2
2ℎ 2×5 𝑢 = 200
𝑡= 𝑔
⇒𝑡 = 10
= 1 𝑠𝑒𝑐
2
As the water drops fall at regular intervals from a 𝑢
𝑅𝑚𝑎𝑥 = 𝑔
= 20𝑚
tap therefore time difference between any two
drops =
1
2
𝑠𝑒𝑐 11 (2)
In this given time, distance of second drop from At height r from center of earth. Orbital velocity
2 𝐺𝑀
the tap =
1
2
𝑔 ( )
1
2
=
10
8
= 1. 25 𝑚 = 𝑟
∴ By energy conservation
Its distance from the ground
= 5 − 1. 25 = 3. 75𝑚
𝐺𝑀𝑚
KE of ‘m’ + − 𝑟 =0+0 ( )
6 (3) (At infinity, PE=KE=0)
2
ℎ
𝑛
𝑡ℎ = 𝑢 −
𝑔
2
(2𝑛 − 1) ⇒KE of ‘m’=
𝐺𝑀𝑚
𝑟
= ( ) 𝐺𝑀
𝑟
m=𝑚𝑣
2
10
12 (3)
ℎ 𝑡ℎ =𝑢− 2
(2×5 − 1) = 𝑢 − 45 Potential difference between two faces
5
perpendicular to x-axis will be
10 → →
ℎ 𝑡ℎ =𝑢− 2
(2×6 − 1) = 𝑢 − 55 𝑙.(𝑉×𝐵)=12mV
6
13 (1)
The coin falls behind him it means the velocity of According to the principle of conservation of
train was increasing otherwise the coin fall angular momentum, in the absence of external
directly into the hands of thrower torque, the total angular momentum of the system
14 (3) is constant.
2
From geometry 𝑙 = 𝑥 + 𝑦 but 𝑦 is constant,
2 2 23 (4)
2
𝑑𝑙 𝑑𝑥 P=𝑖 R.
hence differentiating, we have, 2𝑙 𝑑𝑡
= 2𝑥 𝑑𝑡
∴ for 𝑖𝑚𝑎𝑥, R must be minimum
𝑑𝑙
But 𝑑𝑡
= 𝑣. Hence horizontal velocity of block, 2
From color coding R=50× 10 Ω
𝑑𝑥
𝑣𝑥 = 𝑑𝑡 ∴ 𝑖𝑚𝑎𝑥=20 mA
24 (3)
If the body is projected with velocity 𝑣(𝑣 < 𝑣𝑒)
then height up to where it rises,
𝑅
ℎ= 2
𝑣𝑒
2 −1
𝑣
𝑙.𝑣 𝑣
⇒ 𝑙𝑣 = 𝑥. 𝑣𝑥 or 𝑣𝑥 = = 𝑅
𝑥 sin𝑠𝑖𝑛 θ ⇒ℎ = 11.2 2
= 4𝑅 (𝑎𝑝𝑝𝑟𝑜𝑥.)
15 (3) ( ) 10
−1
2
∆𝑙2 𝐷1 1
= =
(1)
∆𝑙1 2 16
𝐷2
16
Let dielectric constant of material used be K. 1
10ϵ0 3
𝐴
12∈0 3
𝐴
14∈0 3
𝐴
𝐾∈0𝐴 ∴ ∆𝑙2 = 16
𝑚𝑚
∴ 𝑑
+ 𝑑
+ 𝑑
= 𝑑
⇒K=12 26 (1)
17 (2) Steel has the highest elasticity.
Work = Force × Displacement 27 (1)
If force and displacement both are doubled then According to principle of continuity,
work would be four times 𝐴𝑣 = 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
18 (1)
→ ∂𝑈 ^ ∂𝑈 ^ ^ ^
𝐹= 𝑖 − ∂𝑦 𝑗 = 7𝑖 − 24𝑗 𝑜𝑟 𝐴1𝑣1 = 𝐴2𝑣2
∂𝑥
2 2
→ 2 2 𝑜𝑟 π𝑟1𝑣1 = π𝑟2𝑣2
|𝐹| = (7) + (− 24) = 25 𝑢𝑛𝑖𝑡
19 (2) 𝐺𝑖𝑣𝑒𝑛, 𝑟1 =
4
2
𝑐𝑚 = 0. 02 𝑚,
𝑑𝐿 2 2
τ= 𝑑𝑡
= 𝑚(𝑢 θ) = (1)(10) 45° = 50 Nm
2
𝑟2 = 𝑐𝑚 = 0. 01𝑚,
20 (4) 2
2 2 160 160
𝐼 = 𝑀𝐾 = 160⇒𝐾 = 𝑀
= 10
= 16⇒𝐾 = 4𝑚 −1
𝑣1 = 3𝑚𝑠
21 (4) 2 2
Torque acting on a body in circular motion is zero. ∴ π(0. 02) ×3 = π(0. 01) 𝑣2
22 (3)
0.02 2
𝑜𝑟 𝑣2 = ( ) ×3 = 12 𝑚𝑠
0.01
−1
28 (3)
Velocity of ball when it strikes the water surface
𝑣 = 2𝑔ℎ …(i)
Terminal velocity of ball inside the water 33 (2)
→ →
𝑣=
2
9
𝑟𝑔
2
( ) ρ−1
η
…(ii) Work done, W= (∆µ).𝐵
−2
Equating (i) and (ii) we get =2×10 × 1 cos(0.125)
2 𝑟𝑔
2
=0.02 J
2𝑔ℎ = 9 η
(ρ − 1) ∴ correct answer is (2)
4 ρ−1 2 34 (3)
⇒ℎ =
2
81
𝑟 ( )
η
𝑔
Here 𝑑𝑄 = 50 𝐽, 𝑑𝑊 =− 15 𝐽
𝑑𝑈 = 𝑑𝑄 − 𝑑𝑊 = 50 − (− 15) = 65 𝐽
29 (2)
Path difference=dsin 𝑠𝑖𝑛 θ ≈𝑑θ
1 35 (3)
=0.1× 40 mm=2500nm This is the case of free expansion of gas. In free
Or bright fringe, path difference must be integral expansion ∆𝑈 = 0⇒ Temp. remains same
multiple of λ.
∴ 2500=nλ1=𝑚λ2
36 (3)
γ γ−1 γ
𝑃𝑉 = 𝐾 or 𝑃γ𝑉 𝑑𝑉 + 𝑑𝑃. 𝑉 = 0
∴ λ1=625, λ2=500 (from m=5)
(for n=4)
⇒
𝑑𝑃
𝑃
=− γ
𝑑𝑉
𝑉
or
𝑑𝑃
𝑃
×100 =− γ ( 𝑑𝑉
𝑉
×100)
=− 1. 4×5 = 7%
30 (3)
' 37 (4)
𝐴 𝑣 = 2 𝐴 𝑣' or 𝑣 = 𝑣/2 𝑝𝑉
The value of for one mole of an ideal gas
For a horizontal pipe, according to Bernoull’s 𝑇
'
Or 𝑝 = 𝑝 +
1
2
ρ𝑣 1 − (
2 1
4 ) 𝑣2
𝑣1
=
𝑇2
𝑇1
⇒
𝑣𝑆
400
=
(273+227)
(273+27)
=
5
3
3 2
=𝑝+ 8
ρ𝑣
⇒ 𝑣𝑠 = 400 5/3 = 516𝑚/𝑠
31 (3)
As is clear from figure. 39 (4)
𝑑𝑄 𝑑𝑄1 𝑑𝑄2
= + The difference of 𝐶𝑃 and 𝐶𝑉 is equal to 𝑅, not 2𝑅
𝑑𝑡 𝑑𝑡 𝑑𝑡
40 (2)
(
𝐾 𝐴1+𝐴2 𝑑𝑇 ) 𝑑𝑇 𝑑𝑇 Time period of simple pendulum
𝑑𝑥
= 𝐾1𝐴1 𝑑𝑥
+ 𝐾2𝐴2 𝑑𝑥
𝑙
𝑇 = 2π 𝑔
𝐾1𝐴1+𝐾2𝐴2
𝐾= 𝐴1+𝐴2 From this formula it can be predicted that time
period does not depend on the mass of bob.
32 (3)
In convection hot particles move upward (due to
41 (2)
Acceleration in SHM is directly proportional to
low density) and light particle move downward
displacement and is always directed to its mean
(due to high density)
position
42 (1)
The given equation is
π
𝑦 = 5 sin 𝑠𝑖𝑛 2
(100𝑡 − 𝑥)
…(i)
Comparing Eq. (i) with standard wave equation, 49 (2)
given by +
Charge on electron and 𝐻 is same; the ratio 𝑒/𝑚
𝑦 = 𝐴 sin 𝑠𝑖𝑛 (ω𝑡 − 𝑘𝑥) is ratio of mass of proton to electron.
…(ii) 50 (3)
we have 𝑋-rays are light waves or a form of light energy.
100π
ω= 2
= 50π 51 (1)
2π 16 18
⇒ 𝑇
= 50 π The no. of nucleons in 𝑂 and 𝑂 are 16 and 18
2π respectively.
⇒ 𝑇= =0.04 s
50π 52 (3)
43 (1) Higher photo-current implies , higher no. of
It is required to calculate the time from extreme electrons emitted/sec.
position 53 (1)
Hence, in this case equation for displacement of 1
H atom has 1𝑠 configuration. Shielding effect is
particle can be written as
property of penultimate shell electrons.
𝑥 = 𝑎 sin 𝑠𝑖𝑛 ω𝑡 + ( π
2 ) = 𝑎 cos 𝑐𝑜𝑠 ω𝑡 54 (4)
𝑎 π 2π π
⇒ = 𝑎 cos 𝑐𝑜𝑠 ω𝑡⇒ω𝑡 = ⇒ .𝑡 = ⇒𝑡 = Electron affinity is defined as “the energy released
2 3 𝑇 3
when an extra electron is added to neutral
44 (1) gaseous atom. The increasing order of electron
Since, affinity is
720 6 3 2 4 2 4 2 5 2 5
1200
= 10
= 5
, 𝑖. 𝑒., 3: 5 2𝑠 2𝑝 < 3𝑠 3𝑝 < 2𝑠 2𝑝 < 3𝑠 3𝑝
𝑂 < 𝑆 < 𝐹 < 𝐶𝑙
Odd harmonics are produced only if the pipe is General electron affinity decreases with the
closed at one end. increase in the size of atom, since nuclear
45 (3) attraction decrease down a group. The value of
Frequency of 𝑝 𝑡ℎ harmonic electron affinity increase as we move along a
𝑝𝑣 2𝑙𝑛 2×0.33×1000 period since the size of atoms decrease in a
𝑛= 2𝑙
⇒𝑝 = 𝑣
= 330
=2
period. Electron affinity of O and F are less than S
46 (1) and Cl respectively due to very small size.
In the given metal nitride, nitrogen present is 28% 55 (1)
that means, the nitride contains 28 g nitrogen and Given electronic configuration of anion X is
72 g metal. 2 * 2 2 * 2 2 2 2 * 1
σ1𝑠 , σ1𝑠 , σ2𝑠 , σ2𝑠 , π2𝑝𝑥 = π2𝑝𝑦 , σ2𝑝𝑧 , π2𝑝𝑥
72
Moles of metal = 𝑥
28 ∴ Total number of electrons of anion X = 15
Moles of nitrogen = 14 = 2 −
72 Hence, the anion X is 𝑁2 .
⟹ Molar ratio, 𝑀: 𝑁 = 𝑥 : 2 = 3: 2
56 (4)
72
𝑥
= 3 𝐻𝐶≡𝐶 − 𝐻𝐶 = 𝐶𝐻 − 𝐶𝐻3 10σ, 3π
∴𝑥 = 24 57 (1)
⊕
(4)
1
47 𝑁2 ⇒BO=2.5⇒⎡π − 𝐵𝑜𝑛𝑑 = 2&σ − 𝐵𝑜𝑛𝑑 = 2 ⎤
⎣ ⎦
23
∵ 63.8 g of Cu has atoms = 6.023 × 10 𝑁2⇒B.O.=3.0⇒[π − 𝐵𝑜𝑛𝑑 = 2&σ − 𝐵𝑜𝑛𝑑 = 1]
23 ⊕
6.023×10
∴1𝑔 of Cu has = 𝑂2 =B.O.=2.5⇒
63.5𝑔
23
6.023×10 [π − 𝐵𝑜𝑛𝑑 = 1. 5& σ − 𝐵𝑜𝑛𝑑 = 1]
∴0. 635 𝑔 of Cu has = 63.5
×0. 635 𝑂2⇒B.O.=2⇒[π − 𝐵𝑜𝑛𝑑 = 1 & σ − 𝐵𝑜𝑛𝑑 = 1]
= 6. 023×10
21
atoms 58 (4)
48 (2) 𝑆 = 𝐶 = 𝑆.
𝑀=
5
34×100/1000
= 1. 47 59 (2)
𝐻2𝑂2 act as oxidizing agent and reducing agent in ∴ The metal sulphide with lowest 𝐾𝑠𝑝(𝑃𝑏𝑆) will
acidic medium as well as basic medium. precipitate out first because its inonic product will
𝐻2𝑂2 Act as oxidant :- exceed its 𝐾𝑠𝑝first and the metal sulphide with
⊕ ⊝
𝐻2𝑂2+2𝐻 +2𝑒 → 2𝐻2O (In acidic medium) highest 𝐾𝑠𝑝(𝑁𝑖𝑆) will precipitate out at last.
𝐻2O+2𝑒
⊝ ⊝
→ 2𝑂𝐻 (In basic medium) 67 (2)
𝐻2𝑂2 Act as reductant :- Let the solubility of 𝐴𝑔𝐶𝑙 𝑖𝑠 𝑆
+ −
+ ⊝
𝐻2𝑂2 → 2𝐻 +𝑂2 + 2𝑒 (In basic medium) 𝐴𝑔𝐶𝑙 = 𝐴𝑔 + 𝐶𝑙
⊝ ⊝
𝑠 𝑠
𝐻2𝑂2+2𝑂𝐻 → 2𝐻2𝑂 + 𝑂2 + 2𝑒 (In basic −
[𝐶𝑙 ] from 𝑁𝑎𝐶𝑙=0.2
medium) −
60 (3) Concentration of 𝐶𝑙 = 𝑆 + 0. 2
𝐾𝑠𝑝 = 𝑆(𝑆 + 0. 2)
𝑉𝐴 𝑡𝐵 𝑀𝐵
𝑡𝐴
× 𝑉𝐵
= 𝑀𝐴
−10 2
1. 8×10 = 𝑆 + 0. 2𝑆
(𝑆 is very small as 𝐴𝑔𝐶𝑙 is sparingly soluble in
10 𝑀𝐵 2
= water, thus 𝑆 <<< 1)
20 49
−10
1. 8×10 = 0. 2𝑆
49 −10
𝑀𝐵 = = 12. 254 1.8×10
4 𝑆= 0.2
−10
61 (3) = 9. 0×10 M
The volume of one mole of a gas is called molar 68 (4)
volume. It is 22.4 L at STP or NTP for 𝐶𝑂2 gas it is 3𝑂2(𝑔)⇌2𝑂3(𝑔)
maximum at 127℃ and 1 atm 𝑂2 𝑎𝑛𝑑 𝑂3 are the allotropes of oxygen, i.e., have
62 (2) different composition, so the equilibrium exist
An experimental fact. between them is considered as chemical
63 (1) equilibrium.
The process involves conversion of 1 mole of 𝐻2𝑂 69 (2)
7+ 2+
from liquid to vapour state and thus, heat changes 𝑀𝑛 5𝑒 ⟶𝑀𝑛
are called heat of vaporisation.
64 (3) 70 (1)
It provides information about physical states of 𝑁𝑎3𝐴𝑠𝑂4 is sodium arsenate
reactants and products as well as about thermal −3
Or 𝐴𝑠𝑂4 is arsenate.
changes. (d) is wrong because combustion is
exothermic. Thus, 𝑎 + 4 × (− 2) = −3
65 (4) ∴𝑎 = + 5
𝐶 + 2𝐻2 → 𝐶𝐻4; ∆𝐻 = − 17. 9 𝑘𝑐𝑎𝑙…….. (𝑖)
71 (4)
Adipic acid
𝐶 + 𝑂2 → 𝐶𝑂2; ∆𝐻 =− 94. 1 𝑘𝑐𝑎𝑙…….. (𝑖𝑖) 𝐶𝑂2𝐻− (𝐶𝐻2) − 𝐶𝑂2𝐻𝑑𝑒ℎ𝑦𝑑𝑟𝑎𝑡𝑖𝑛𝑔→𝑎𝑔𝑒𝑛𝑡
4
𝐻2 +
1
𝑂2 → 𝐻2𝑂; ∆𝐻 =− 68. 3 𝑘𝑐𝑎𝑙……(𝑖𝑖𝑖) 7 membered cyclic anhydride (very unstable)
2 72 (2)
𝑀𝑒𝑞. 𝑜𝑓 𝐾2𝐶𝑟2𝑂7 = 𝑀𝑒𝑞. 𝑜𝑓 𝐻2𝑆
Eqs. [(ii) + 2 × (iii)] – (i),
𝐶𝐻4 + 2𝑂2 → 2𝐻2𝑂 0.81
2𝑥𝑉 = 34/2
𝑥 1000
66 (4)
For precipitation, ionic product > solubility ∴𝑉 = 23. 8 𝑚𝐿
product 73 (3)
It is a fact.
74 (3)
𝐻2 does not react with 𝐴𝑢, 𝐶𝑢 𝑜𝑟 𝑁𝑖. with Ca, it
gives 𝐶𝑎𝐻2
83 (3)
75 (3) Canonical structures proposed in resonance are
Calcium is obtained by electrolysis of a fused mass not the real structure of compound. The
of 𝐶𝑎𝐶𝑙2 and KCl at about 700℃ in an electrolytic compound showing resonance has a definite
cell made of graphite anode and iron cathode. structure which can however be not drawn on
2+ − paper.
𝐶𝑎𝐶𝑙2 ⇌𝐶𝑎 + 2𝐶𝑙
84 (4)
All show geometrical isomerism :
At anode
− −
2𝐶𝑙 →𝐶𝑙2 + 2𝑒
At cathode
2+ −
𝐶𝑎 + 2𝑒 →𝐶𝑎
76 (3)
𝑀𝑔 is found in sea water.
77 (1)
𝐶𝑎𝐶𝑂3 ∆ → 𝐶𝑎𝑂 + 𝐶𝑂2
(𝑋)