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The document outlines various topics related to organometallic compounds and metallurgy, including catalytic processes, chemical reactions, and synthetic methods. It discusses specific compounds like Ferrocene and XeF6, detailing their preparation, structure, and reactions. Additionally, it includes exercises such as matching columns and true/false statements to reinforce understanding of the material.

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MJ K
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31 views2 pages

Assignment

The document outlines various topics related to organometallic compounds and metallurgy, including catalytic processes, chemical reactions, and synthetic methods. It discusses specific compounds like Ferrocene and XeF6, detailing their preparation, structure, and reactions. Additionally, it includes exercises such as matching columns and true/false statements to reinforce understanding of the material.

Uploaded by

MJ K
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

UNIT-III

1 Describe basic steps involved in homogeneous catalysis.


2 Discuss the following chemical reactions of organometallic compounds
1) Reactions with protic reagents 2) Redistribution reactions
3 Explain the following synthetic methods of organometallic compounds.
1) Transmetallation 2) Carbanion-halide exchange
4 With reference to Ferrocene discuss the following reactions 1) Acylation 2) Oxidation
5 Describe the chemical reactions of OMCs.
6 With reference to Ferrocene discuss the following reactions 1) Sulphonation 2) Alkylation
7 Explain the following synthetic methods of organometallic compounds.
1) Oxidative addition 2) Methylene insertion
8 Explain the mechanism of Wilkinson’s catalyst in hydrogenation of alkenes.
9 Describe structure and bonding of Ferrocene on the basis of VBT.

UNIT-IV 15
1 Describe the froth flotation and magnetic separation methods involved in metallurgy.
2 With reference to XeF6, explain 1) preparation 2) structure
3 Explain the essential and non-essential elements?
4 Explain bessemerisation and electrorefining processes involved in metallurgy of copper.
5 With reference to XeO4, explain 1) preparation 2) structure
6 What are the different types of metallurgy? Write a note on Zone refining method.
7 With reference to XeF4, explain 1) preparation 2) structure
8 Explain electro-refining process involved in metallurgy of copper.
9 Discuss the role of Na+ and K+ w.r.t. ion pump.
10 With reference to XeO2, explain 1) preparation 2) structure

Match the columns


I a) Multi-centre electron deficient OMC i) Oxidation
b) Cyclopentadienyl anion ii) Al2(CH3)6
c) Ferrocene to ferricinium ion iii) Diazomethane
d) Methylene insertion iv) Heterogeneous catalysis
e) Haber’s process v) Six electrons donor

II a) Gaseous phase of Ferrocene i) C6H5- Na+


b)  bonded OMCs ii) eclipsed configuration
c) η5 iii) 2 centred 2 electron bond
d) Diamagnetic v) pentahapto
e) Ionic OMCs v) paired electrons

1
State whether the following statements are true or false
1 Calcination is a process in which the ore is hydrolysed with water.
2 Cuprite is the main ore of copper.
3 XeF4 has a tetrahedral structure.
4 Metalloenzymes catalyze various biological processes.
5 Some OMCs form complexes with amines.
6 XeOF2 has a bond angle slightly less than 900.
7 A transition element present in haemoglobin is magnesium.
8 XeF6 has a square planar structure.
9 Ferrocene has non-zero dipole moment.
10 Ferrocene is an orange solid.
11 Ferrocene obeys the eighteen electron rule and hence is stable.
12 Ferrocene is diamagnetic
13 Ferrocene is soluble in water.
14 Zn(CH3)2 is sigma () bonded OMC.

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