Product Name : ETHYLENE Revision date: 21 September 2021
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SAFETY DATA SHEET
1. IDENTIFICATION
PRODUCT IDENTIFIER
Product Name: ETHYLENE
Reference Number: 91001
SUPPLIER’S DETAILS
Name ENEOS Corporation
Address 1-2, Otemachi 1-chome, Chiyoda-ku, Tokyo 100-8162 Japan
Phone +81-(0)3-6257-7294
Fax +81-(0)3-6213-3496
Contact Olefin Group, Basic Chemicals Sales Department
Emergency Phone Number +81-(0)3-6257-7294
(Available time; 9:00am - 5:00pm JST on Monday - Friday)
RECOMMENEDED USE OF THE CHEMICAL Chemical basestock
AND REATRICTIONS OF USE Industrial use only. Do not use for medical or food without advice of
experts.
2. HAZARDS IDENTIFICATION
This material is hazardous according to regulatory guidelines (see SDS Section 15).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
Flammable gases Cat 1
Gases under pressure Cat Compressed gas
Gases under pressure Cat Refrigerated liquified gas
Specific target organ toxicity-single exposure Cat 3 (Narcotic effect)
Hazardous to the aquatic environment, short-term (Acute) Cat 3
Hazardous to the aquatic environment, long-term (Chronic) Cat 3
GHS LABEL ELEMENTS:
Pictogram:
Signal Word: Danger
Hazard Statements:
Physical:
H220 : Extremely flammable gas
H280 : Contains gas under pressure; may explode if heated
H281 : Contains refrigerated gas; may cause cryogenic burns or injury
Health:
H336 : May cause drowsiness or dizziness
Environmental:
H402 : Harmful to aquatic life
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H412 : Harmful to aquatic life with long lasting effects
Precautionary Statements:
Prevention:
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P233 : Keep container tightly closed.
P261 : Avoid breathing gas.
P271 : Use only outdoors or in a well-ventilated area.
P273 : Avoid release to the environment.
P282 : Wear cold insulating gloves and either face shield or eye protection.
Response:
P304+P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 : Call a POISON CENTER/doctor/physician if you feel unwell.
P315 : Get immediate medical advice/attention.
P336 : Thaw frosted parts with lukewarm water. Do not rub affected area.
P336+P315 : Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical
advice/attention.
P377 : Leaking gas fire : Do not extinguish, unless leak can be stopped safely.
P381 : In the case of leakage, eliminate all ignition sources.
Storage:
P403 : Store in a well-ventilated place.
P403+P233 : Store in a well-ventilated place. Keep container tightly closed.
P405 : Store locked up.
P410+P403 : Protect from sunlight. Store in a well-ventilated place.
Disposal:
P501 : Dispose of contents/container in accordance with local regulations.
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
Physical/Chemical Hazards
Contact with liquefied gas can cause damage (frostbite) due to rapid evaporative cooling.
Health Hazards
Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygen below safe
breathing levels. Symptoms include shortness of breath, palpitation, unconsciousness, ataxia, lethargy,
headache, nausea, vomiting and disorientation. Further oxygen reduction causes convulsions and
unconsciousness, and can result in death. Since working increases oxygen demand, working in asphyxiant
atmosphere can show suffocation symptoms early. Concentration of oxygen must keep 21vol%.
May cause central nervous system effects.
Environmental Hazards
No additional hazards.
Note: Contact with liquefied gas can cause damage (frostbite) due to rapid evaporative cooling.
If allowed to accumulate to concentrations that reduce oxygen below safe breathing levels, the reduction of
oxygen may cause shortness of breath, palpitation, unconsciousness, ataxia, lethargy, headache, nausea,
vomiting and disorientation. Further oxygen reduction causes convulsions and unconsciousness, and can
result in death.
Excessive exposure may result in headache and dizziness, and may show narcotic effect.
This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which
may vary from person to person.
3. COMPOSITION / INFORMATION ON INGREDIENTS
This material is defined as a substance.
Hazardous Substance(s) or Complex Substance(s)
Name CAS RN® Concentration* GHS Hazard Codes
Ethylene 74-85-1 ≧99.9 % H220, H280, H281,
H336, H402, H412
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Product Name : ETHYLENE Revision date: 21 September 2021
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* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
Concentration values may vary.
4. FIRST-AID MEASURES
DESCRIPTION OF NECESSARY FIRST-AID MEASURE
Inhalation
Remove from further exposure. If respiratory irritation, dizziness, nausea, or unconsciousness occurs,
seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device
or use mouth-to-mouth resuscitation. When mouth-to-mouth resuscitation, responder should be careful to
not expose material. For those providing assistance, avoid exposure to yourself or others. Use adequate
respiratory protection.
Skin contact
If frostbite occurs, immerse involved area in water at body temperature. Keep immersed for 20 to 40
minutes. Do not touch or tighten the frostbite area. Seek medical assistance.
Eye contact
Flush thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists, get medical attention.
Ingestion
Not applicable
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DALAY
Contact with liquefied gas can cause frostbite.
Reduction of oxygen content can cause breathing difficulty.
May result in headache and dizziness, and may show narcotic effect.
INDICATION OF MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF NECESSARY
This light hydrocarbon material, or a component, may be associated with cardiac sensitization following very
high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels
or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Suitable Extinguishing Media: Water fog, sprinkling of water, dry chemical, carbon dioxide (CO2)
Inappropriate Media: Straight streams of water
SPECIFIC HAZARDS ARISING FROM THE CHEMICALS
Specific Hazards Arising from the Chemicals: Flammable gas Gas is flammable and heavier than air.
Gas may travel across the ground and reach remote ignition sources causing a flashback fire danger. As
material is hazardous, firefighters should consider protective equipment indicated in Section 8.
Hazardous Combustion Products: Incomplete combustion products, carbon monoxide, smoke, fume
SPECIFIC PROTECTIVE ACTIONS FOR FIRE-FIGHTERS
Specific protective actions for fire-fighter:
Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Fire Fighting Instructions:
Evacuate non-emergency personal to safe area. Allow the fire to burn under controlled conditions. Do not
extinguish flames at leak because possibility of uncontrolled explosive reignition exists. Stop leak if you can
do it without risk. Move container if you can do it without risk.
Use water spray or fog for cooling tanks or containers surround fire. If a leak or spill has not ignited, use
water spray to disperse the vapors and to protect personnel attempting to stop a leak or to move container.
Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply.
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6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the
Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8
for advice on the minimum requirements for personal protective equipment. Additional protective measures
may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency
responders.
For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for spilled
material and, when applicable, Self Contained Breathing Apparatus (SCBA) can be used depending on the
size of spill and potential level of exposure. If the exposure cannot be completely characterized or an
oxygen deficient atmosphere is possible or anticipated, SCBA is recommended.
Notification Procedures
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. Evacuate non-emergency personal to safe area. Material is toxic or combustible. Advise
occupants surrounding or in downwind areas to warn them to evacuate, if needed.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).
Stop leak if you can do it without risk. Allow liquid to evaporate from the surface. Change direction of
cylinder to give off gases rather than liquid if you can do it without risk. CAUTION: When in contact with
refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning.
Use water spray to reduce vapors or divert vapor cloud drift. All equipment used when handling the product
must be grounded. Do not direct water at spill or source of leak. Do not touch or walk through spilled
material. Prevent spreading of vapors through sewers, ventilation systems and confined areas.
Isolate area until gas has dispersed.
Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).
Allow liquid to evaporate from the surface. See Land Spill section of the SDS for advice for gases.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current
direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts
should be consulted. Note: Local regulations may prescribe or limit action to be taken.
7. HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING
Prevent exposure to ignition sources. Material can accumulate static charges which may cause an
electrical spark (ignition source). Use proper bonding and/or ground procedures. Use non-sparking tools
and explosion-proof equipment. However, bonding and grounds may not eliminate the hazard from static
accumulation.
Auto-refrigeration: Drains can be plugged and valves may become inoperable because of the formation of
ice when expanding vapors or vaporizing liquids cause temperatures to drop below the freezing point of
water.
Material can accumulate static charges. Material can mix with air or oxygen and form flammable mixtures.
Gases are flammable and heavier than air. Gases may travel across the ground and reach remote ignition
sources causing a flashback fire danger. Pay attention to leakage very much.
Avoid contact with liquefied gas, as contact with liquefied gas can cause damage (frostbite) due to rapid
evaporative cooling.
CONDITION FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended.
Keep container closed. Handle containers with care. Open slowly in order to control possible pressure
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release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Keep away from
incompatible materials. The container choice, for example storage vessel, may effect static accumulation
and dissipation. Storage containers should be grounded and bonded. Fixed storage containers, transfer
containers and associated equipment should be grounded and bonded to prevent accumulation of static
charge.
Suitable Materials and Coatings (Chemical Compatibility): Stainless Steel, Steel (do not use at low
temperature)
Unsuitable Materials and Coatings: Steel (at low temperature)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
CONTROL PARAMETERS
Occupational exposure limits/standards (Note: Exposure limits are not additive)
Substance Name Form Limit / Standard NOTE Source
Ethylene Vapour STEL - - ACGIH(2020)
TWA 200 ppm
Biological limit values
No biological limits allocated
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
APPROPRIATE ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Control measures to consider: Use explosion-proof ventilation equipment to stay below
exposure limits.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT (PPE)
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for
use with this material, as provided below, is based upon intended, normal usage. Any specific protective
equipment information provided is based on published literature and protective equipment manufacturer
data.
Eye/Face Protection:
If contact is likely, chemical goggles or safety glasses with side shields are recommended.
Skin and Body Protection:
The types of clothing to be considered for this material include: Chemical resistant clothing
(non-permeable) is recommended.
Respiratory Protection:
If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to
protect worker health, an approved respirator may be appropriate. Respirator selection, use, and
maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be
considered for this material include: following manufactures instructions
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure
mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are
inadequate, if concentration is high, gas/vapor warning properties are poor, or if air purifying filter
capacity/rating may be exceeded.
Hand Protection:
Use suitable protective glove. Glove suitability and breakthrough time will differ depending on the specific
use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough
times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be
considered for this material include:
Thermally protective gloves are recommended. If contact with forearms is likely, wear gauntlet style
gloves.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and
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protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be
cleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the
environment by applying appropriate control measures to prevent or limit emissions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Note: Physical and chemical properties are provided for safety, health and environmental considerations
only and may not fully represent product specifications. Contact the Supplier for additional information.
Physical State: Gas
Colour: Colorless/Clear
Odour: Characteristic odor
Melting Point/Freezing Point: -169.2 °C
Boiling Point or Initial Boiling Point -104 °C
and Boiling Range:
Flammability : Flammable
Lower and Upper Explosion Limit LEL: 2.7 (vol％) UEL: 36.0 (vol％)
/Flammable Limits (Approximate volume % in air):
Flash Point: -136 °C
Auto-ignition Temperature: 490 °C
Decomposition Temperature: No data
pH: N/A
Kinematic Viscosity: 0.0093 mPa・sec @0 °C
Solubility: Negligible
Partition Coefficient n-Octanol/Water (log value): 1.13
Vapor Pressure: 8100 kPa @15 °C
Density and/or Relative Density (at 20 ºC): 0.00126g/cm³ @0 °C
Relative Vapour Density (Air = 1): 0.98 at 101 kPa
Particle Characteristics: N/A
10. STABILITY AND REACTIVITY
REACTIVITY: No reactivity under normal conditions.
CHEMICAL STABILITY: Material is stable under normal conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will occur hardly under normal
conditions.
CONDITIONS TO AVOID: Heat, sparks, flame, and other ignition source
INCOMPATIBLE MATERIALS: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
In fire, carbon monoxide can be generated.
11. TOXICOLOGICAL INFORMATION
Information described here are based on the data for this material, structurally similar materials and/or components.
(Information of structurally similar materials and/or components)
Information Conclusion/Remarks
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Acute toxicity
Oral Not classified
This material is gas. No data available
Dermal Not classified
This material is gas. No data available
Inhalation （Gas） Not classified
LC50(rat)：>50000ppm
Skin corrosion/irritation Classification not possible
Not enough information
Serious eye damage/irritation Classification not possible
Not enough information
Sensitization
Respiratory Classification not possible
No data available
Skin Classification not possible
No data available
CMR hazard
Germ cell mutagenicity Classification not possible
in vivo test; negative, in vitro test; negative
Carcinogenicity Classification not possible
IARC; group 3, ACGIH; A4
Reproductive toxicity Classification not possible
Not enough information
Additional category for effects on or via lactation Classification not possible
No data available
Specific target organ toxicity
Single exposure Category 3 (narcotic effect)
Narcotic effect was observed
Repeated exposure Not classified
No adverse effect was ovserved
Aspiration hazard
This material is gas Not classified
OTHER INFORMATION
IARC Classification:
Chemical Name Classification
Ethylene Group 3
12. ECOLOGICAL INFORMATION
Information described here are based on the data for this material, structurally similar materials and/or components.
TOXICITY
Expected to be harmful to aquatic organisms.
Expected to be harmful to aquatic organisms with long lasting effects.
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PERSISTENCE AND DEGRADABILITY
Biodegradation:
No information available for biodegradation.
Hydrolysis:
Transformation due to hydrolysis not expected to be significant.
Photolysis:
Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
No additional information
BIOACCUMULATION POTENTIAL
Not expected to bioaccumulate.
MOBILITY IN SOIL
Gases will partition rapidly to air.
OTHER ADVERSE EFFECTS
Hazard to the Ozone Layer
Not expected to be harmful to ozone layer.
ECOLOGICAL DATA
Toxicity
Test Duration Organism Type Test Results
Aquatic - Acute Toxicity 72 hour(s) Pseudokirchneriella ErC50 72 mg/l
subcapitata
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
Disposal Recommendations
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
Empty Container Warning
Empty Container Warning (where applicable): Empty containers may contain residue and can be
dangerous. Do not attempt to refill or clean containers without proper instructions.
Empty cylinders should be completely drained and safely stored until appropriately reconditioned or
disposed in accordance with applicable laws and regulations. Empty cylinders should be taken for
recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR
EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER
SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
14. TRANSPORT INFORMATION
LAND - Precautionary Transportation Measures & Conditions:
Comply with applicable laws and regulations.
SEA (IMDG) / AIR (IATA)
UN Number: 1038
UN Proper Shipping Name: ETHYLENE, REFRIGERATED LIQUID, ETHYLENE
Transport Hazard Class(es): 2.1
Packing Group: -
Environmental hazards: No
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EMS Number: F-D, S-U
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code：
Not applicable This product is not liquid substances.
15. REGULATORY INFORMATION
This material is considered hazardous according to the Classification of Chemicals based on Globally Harmonized
System of Classification and Labelling of Chemicals (GHS).
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT IN QUESTION
National Laws and Regulations:
Comply with applicable laws and regulations.
16. OTHER INFORMATION
KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H220 : Extremely flammable gas : Flammable gases,Cat 1
H280 : Contains gas under pressure; may explode if heated : Gases under pressure,Cat Compressed gas, Liquefied
gas, Dissolved gas
H281 : Contains refrigerated gas; may cause cryogenic burns or injury : Gases under pressure,Cat Refrigerated
liquefied gas
H336 : May cause drowsiness or dizziness : Specific target organ toxicity, single exporsure (Narcotic effect),Cat 3
H402 : Harmful to aquatic life : Hazardous to the aquatic environment, short-term (Acute),Cat 3
H412 : Harmful to aquatic life with long lasting effects : Hazardous to the aquatic environment, long-term
(Chronic),Cat 3
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The information and recommendations contained herein are, to the best knowledge and belief of ENEOS
Corporation, accurate and reliable as of the date issued. You can contact ENEOS Corporation to insure that this
document is the most current available from ENEOS Corporation. The information and recommendations are
offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is
suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health,
safety and other necessary information is included with and/or on the container. Appropriate warnings and
safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly
prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in
part, is not permitted.
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