Consumer and Industrial Chemistry Overview
Consumer and Industrial Chemistry Overview
CONCEPT MAP
CONSUMER AND INDUSTRIAL CHEMISTRY
Green Technology
Saturated Fat
Explains
Temperature 180°C
Optimum condition
Oils and Can be converted to Hydrogenation Catalyst: Nickel
Fats
Soap
Meanings Explain
Cleaning Cleansing action
Agent
Detergent
Describe &
Explain Effectiveness in soft
Biological enzyme water and hard water
– Biological enzyme
– Whitening
– Fragrance
Preservative
Colouring agent
Analgesic
Stabiliser Examples of food
Medicine additives and food
Types Antimicrobials
Thickening agents
Applications
Psychotic drug
Antioxidant
Nanotechnology Corticosteroids
Emulsifiers
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5
Module Chemistry Form 5
H H H
H C C C H
OH OH OH
General equation for esterification reaction between glycerol and fatty acid.
Esterification reaction between glycerol and fatty acid:
H O H O
H C O H + H O C R H C O C R
O O
O O
H H
1 mol of glycerol 3 mol of fatty acid 1 mol of oil or fat 3 mol of water
R, R’ and R” represent hydrocarbon chains( alkyl groups) that are the same or different.
⇒ Glycerol + Fatty acid Oil or fat + Water
⇒ Oil and fat molecules are made up of two parts i.e derived from glycerol and fatty acid .
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• Saturated fats are esters of saturated fatty • Unsaturated fats are esters of unsaturated fatty
acids. acids.
single • Unsaturated fatty acids contain at least one
• Saturated fatty acids contain
covalent bonds between the carbon atoms in double bond between the carbon
hydrocarbon chains. atoms in hydrocarbon chain.
O H H H H H H H H H H O H H H H H H H H H
HO C C C C C C C C C C C H HO C C C C C C C C C C H
H H H H H H H H H H H H H H H H H
Saturated fatty acids Unsaturated fatty acids
• Example: Palmitic acid, lauric acid and stearic • Example: Oleic acid and linoleic acid
acid.
Physical state at
Solid Liquid
room temperature
• Hydrogen gas is passed through hot oil in the presence of nickel as catalyst at temperature of 180°C and
pressure of 4 atm.
Explain why the physical state of oil turns to solid after hydrogenation.
• The relative molecular mass of the oil molecule increases, as more and more double bonds are added with
hydrogen.
• The strength of forces between molecules becomes stronger and more energy needed to overcome the
force. The boiling point of the oil increases and the physical state changes from liquid to solid.
Source of • Biodiesel is produced from vegetable oils, used cooking oils or animal fats.
energy • Biodiesel is renewable and can be used in existing diesel engines without modification.
Industrial • Vegetable oils are used to make soaps, skin care products, candles, perfumes and other
used personal care and cosmetic products.
What are the effects of eating food with high content in fats on health? Explain.
Animal fats (saturated fats) contain higher LDL cholesterol whereas vegetable oils (unsaturated
fats) contain higher HDL cholesterol.
(i) LDL cholesterol causes plaque deposits on the walls of veins or arteries which will lead to heart attack
and stroke.
(ii) HDL cholesterol reduces deposits on the artery walls.
Soap LS 5.2.1
Define soaps.
Soaps are sodium or potassium salt of fatty acids.
• Soap are prepared by hydrolysing oils or fats in potassium hydroxide or sodium hydroxide solution.
What is saponification?
• Saponification is a process involves hydrolysis of oils or fats with concentrated sodium hydroxide
solution or potassium hydroxide solution .
• The products are glycerol and the salts of fatty acids which are soaps .
Saponification equation:
Oils or fats Sodium hydroxide Saponification Glycerol Sodium salt of fatty acid
+ +
(ESTER) (ALKALI) (ALCOHOL) (SOAP)
O O
H C O C R’ H C OH R’ C O–Na+
+ 3NaOH +
O O
H C O C R” H C OH R” C O–Na+
H H
Given different formulae of fatty acids, derive the respective chemical formulae of the soaps formed.
C11H23COOH
Sodium laurate C11H23COONa Coconut oil
Lauric acid
C15H31COOH
Sodium palmitate C15H31COONa Palm oil
Palmitic acid
C17H35COOH
Sodium stearate C17H35COONa Animal fats
Stearic acid
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Preparing a Sample of Soap in the Laboratory LS 5.2.2
H
H O O
H C OH C15H31 C O–Na+
H C O C C15H31
O O
H C OH
H C O C C15H31 C15H31 C O–Na+
+ 3NaOH +
O
O
H C OH
H C O C C15H31
C15H31 C O–Na+
H
H
Conclusions
• When oils or fats react with concentrated sodium hydroxide or potassium hydroxide
solution, glycerol and fatty acid salts, which is soaps are formed.
• The reaction is called saponification .
Detergent LS 5.2.1
Define detergent.
• Detergent is cleaning agent that is not soap.
• Detergents are sodium salts of alkylbenzene sulphonic acid or alkyl sulphonic acid.
– –
R S O Na+ R O S O Na+
O O
(i) Sulphonation of alkylbenzene: The concentrated sulphuric acid is reacted with alkylbenzene to
form alkylbenzene sulphonic acid.
(ii) Neutralisation: Sodium hydroxide solution is then neutralised the alkylbenzene sulphonic acid to
produce alkylbenzene sulphonate salt, which is detergent .
(i) Sulphation of alcohol: Concentrated sulphuric acid is reacted with long chain alcohol to form alkyl
hydrogen sulphate.
O O
CH3(CH2)nCH2 O H + HO S OH CH3(CH2)nCH2 O S OH + H 2O
O O
Long chain Sulphuric acid Alkyl hydrogen sulphate Water
alcohol
(ii) Neutralisation: Sodium hydroxide solution is then neutralised the alkyl hydrogen sulphate to produce
sodium alkyl sulphate salt, which is detergent .
O O
O O
R C O–
(i) R is a long hydrocarbon chain which are: (ii) –COO– is a carboxylate ion which are:
• hydrophobic (repelled by water) • hydrophilic (soluble in water)
• non-polar end (no charge) • polar end (negatively charge)
• soluble in oil or grease • insoluble in oil or grease
Example:
• Sodium laurate: CH3 – (CH2)14 – COONa in water ionises to: CH3 – (CH2)14 – COO– (soap anion) and Na+.
The structural formula of soap anion:
CH2 CH2 CH2 CH2 CH2 CH2 CH2
–
CH3 CH2 CH2 CH2 CH2 CH2 CH2 C-O
Hydrophobic Hydrophilic
Soap and
Surface
Explain how the cleaning action of soap on oily stains on cloth. Tension of
Water
Hydrophobic Hydrophilic
Hydrophilic Hydrophobic
part part
part part
Grease
Grease
Cloth Water
Cloth
• The soap ionises in water to produce
free moving soap anions and cations. • The hydrophilic part of the soap
• Soap anion reduces the surface tension anions dissolves in water
of water which will increase wetting ability of
while the hydrophobic part dissolves
water. Therefore, water wets the and penetrates into the grease.
dirty cloth.
Cloth Water
Cloth
• The small droplets do not redeposit on the • The hydrophilic part of soap anions
surround the grease, the grease is
surface of the cloth due to repulsion
suspended in the water.
between negative charges on their surface.
• By the movement of water during scrubbing
• The droplets are suspended in water, forming
and rubbing, grease is lifted off the
an emulsion .
surface.
• Rinsing away the dirty water removes the
grease droplets and the surface of the cloth is • The grease is dispersed into
then cleaned. smaller droplet .
O O
What is the effect of hard water to the cleansing action of soaps? Explain.
• The effectiveness of soap is reduced when used in hard water.
• Calcium ions and magnesium ions react with soap anions to form insoluble scum.
2C17H35COO (aq)
− (C17H35COO)2Mg (s)↓
Stearic anion / + Mg (aq) →
2+ Insoluble magnesium
soap anion stearate (scum)
What is the effect of hard water to the cleansing action of detergent? Explain.
• Detergent anions do not form insoluble scum with calcium ions and magnesium ions.
• Detergent can act as cleaning agent in hard water.
• Detergent is more effective than soap in hard water.
Sources Animal fats or vegetable oil Long chain hydrocarbon from petroleum
O O O O O O
The structure of
Sor O O or S
– – –
C O
–
C O O S O
–
O S
O –
O
polar end
atau
(Hydrophilic) O O
O O
Carboxylate ion Benzene sulphonate ion Sulphate ion
Effectiveness Effective in soft water only Effective in soft water and hard water
Formation of
Forms scum in hard water Do not form scum in hard water
scum
Effect on
Biodegradable, do not cause pollution Mostly non-biodegradable, cause pollution
environment
Why are additives added to detergents? State the function of the additives.
Additives Functions
Biological enzyme such as lipase and peptidase Remove protein stains such as blood
Suspension agent such as sodium carboxymethyl To prevent the removed dirt particles redeposited onto
cellulose cleaned fabrics
EXERCISE
_
CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 C–O
Hydrophobic Hydrophilic
(a) State the property of hydrophobic and hydrophilic parts of soap anion. PL1
(b) Soap is used to wash oily stains on cloth. Explain the cleansing action of soap on the oily stain. PL2
• Soap reduces the surface tension of water and increases the wetting ability of water on the surface of
the oily cloth.
• The hydrophobic part of the soap anion dissolves in the oily stains. The hydrophilic part of the soap
anion remains in the water.
• Scrubbing helps to lift the oily stains from the cloth and breaks the oily stains into small droplets.
• The droplets do not redeposit on the surface of the cloth due to repulsion between the negative
charges on their surface.
• The droplets are suspended in water forming an emulsion. Rinsing removes these droplets and leaves
the surface clean.
2 The diagrams below show the structural formula for the anion part of cleansing agent X and cleansing agent Y
particles.
O O
R C O–Na+ R O S O–Na+
O
Cleansing agent X Cleansing agent Y
O
O
O S O–
C O –
O
Cleansing agent X Cleansing agent Y
(c) State the name of part of the cleansing agents X and Y that is soluble in grease. PL2
Hydrophobic
• The soap anions react with the magnesium ions and calcium ions in hard water to form white
precipitate of magnesium and calcium salt or scum.
• Formation of scum reduces the amount of soap for cleaning.
(e) State one advantage of detergent over soap. PL2
Detergent anions react with the magnesium ions and calcium ions in hard water to form soluble salt or
no scum. The cleansing action of detergent is more effective than soap in hard water.
(f) One of the properties of soap and detergent is that they can form lather with water. What is the function of
lather? PL1
It helps to suspend the grease particles.
3 A student carried out two experiments to investigate the cleansing effect of soap and detergent on oily stained
cloth in hard water.
(a) Compare the cleansing effect between Experiment I and Experiment II. PL3
Soap in Experiment I is not effective as cleansing agent in hard water whereas detergent in Experiment
• Hard water contains calcium ions, Ca2+ and magnesium ions, Mg2+.
• Soap anions in hard water react with magnesium ions or calcium ions to form scum, insoluble
• Detergent anions react with Ca2+ ions and Mg2+ ions to form soluble salt, no precipitate, no scum, and
foam is formed.
(c) State the substance which is more suitable as a cleansing agent to remove stains in hard water. PL2
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What are the types of food additives, their functions and examples? LS 5.3.1 LS 5.3.2
Food additives
Type of food additives
(a) Prevent oxidation that causes (a) Add or restore the (b) Make the food
(a) Enhance the (b) Produce (c) Sweeten rancid fats and brown fruits
natural flavour artificial the food colour in food appearance look more
of the food flavour attractive
Examples
Examples Examples
• Monosodium glutamate (MSG) • Ester • Aspartame • Ascorbic acid • Citric acid • Azo compound such as • Triphenyl compounds
(vitamin C) tartrazine and ‘sunset yellow’ such as brilliant blue
Foods
Foods Foods
– Soup – Cake – Drink
– Frozen food – Jam – Juice – Cake – Margarine – Orange juice
171
5
Module Chemistry Form 5
EXERCISE
Solid milk,
tartazine, sugar, ......
microorganisms.
(c) The table below shows the functions for two examples of food additives.
PL1
Type of food
Food additives Functions
additives
Sodium benzoate Controls and inhibits the growth of microorganisms P
Lecithine Improve texture of the food Q
P: Preservatives
Q: Stabiliser
2 The table below shows the types and examples of food additives.
Sodium chloride
Antioxidants X
Y
Flavouring agents MSG
Octyl ethanoate
W Acacia gum
Food colouring Z
(b) (i) Give one example of food that uses sodium nitrate as food additive.
Sausage / burger / meat
PL2
PL3
(c) (i) Give one example of food that uses sodium chloride as food additive.
Salted fish
PL2
(e) Name the example of food additives that cause the children to become hyperactive.
Azo compound / triphenyl compound
PL1
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5.4 MEDICINES AND COSMETICS CS 5.4
Traditional
Medicines
and Their
Uses
Medicines LS 5.4.1
Types
use:
it does not irritate the stomach. bacteria. • Dizziness, dry mouth and throat,
• Should be taken with
• Codeine relieves pain as well as • Disinfectants destroy microorganism on blurred vision and constipation.
a prescription by a
to treat cough and diarrhoea. non-living object such as publics area
doctor.
and building.
The correct way to use: Corticosteroids
Side effects:
• Should be taken with a The correct way to use:
• Drowsiness
prescription by a doctor. • Antibiotic should be taken with a
• Leading to weight
prescription by a doctor. Example:
Side effects: gain after prolonged
• Patient must take full course of the • Betamethasone valerate
• Aspirin is acidic and can cause usage.
antibiotic to make sure all the bacteria
internal bleeding and ulceration. • Uncontrolled muscle Functions:
are killed, otherwise the bacteria may
It is not suitable for gastric movements of the • Reduce inflammation and to treat
become resistant to the antibiotic.
patients. jaw, lips and tongue. asthma, allergic and arthritis.
© Nilam Publication Sdn. Bhd.
Cosmetics LS 5.4.3
Cosmetics are materials or products used externally for the purpose of cleansing , protecting
or beautfying .
What are the basic ingredients of cosmetics? State the examples and their functions.
Basic
Remarks
ingredients
• Lecithin, stearic acid and polysorbates are examples of emulsifiers used in creams
Emulsifier
and lotions to form a homogeneous mixture between water and oil.
• Xanthan gum, gelatin and glycerin are examples of thickeners used in bath gels,
Thickeners
shampoos as well as creams and lotions.
• Titanium dioxide, zinc oxide and iron(III) oxide are example of dyes added to make
Dyes
cosmetic products look attractive .
• Glycerin, lanolin, shea butter and sodium lactate are examples of moisturising agents
Moisturiser
used to retain moisture in cosmetic products.
• Fragrances can provide a pleasant odour and help to remove the smell of some
Fragrances
ingredients.
Types of
Function and examples
cosmetics
• Gives each perfume or product its distinct scent. Fragrance may be derived from
Fragrances petroleum or natural raw materials.
• Examples: Deodorants and perfumes.
Using natural ingredients are safe to use as May contain harmful chemicals and cause
they do not contain harmful chemicals. harmful side effects.
The cost to produce the products is cheap. Prices may be higher and users are often deceived
by the misleading advertisement.
State the examples of the chemicals that may be added to the cosmetics and their NPRA
side effects.
• Hydroquinone: Hypersensitive skin and exposure to UV rays due to reduced pigmentation.
• Tretinoin: Skin redness and peeling.
• Betamethasone valerate: Skin irritation and changes in pigmentation.
• Mercury: Skin irritation and damage to the kidneys and nervous system if absorbed into the bloodstream.
Introduction of nanoparticles
What is nano?
• Nano is something that is too small that it can only be seen with a powerful microscope.
• Nano is one billionth part of (a specified unit); the factor of 10–9.
What is nanoscale?
Nanoscale is a scale to show the size of an object with a length 1-100 nanometres.
Macroscale Microscale Nanoscale Atomic scale
Can be seen Too small to see Smaller than a Size of an
with the naked eye with the naked eye cell and bigger atom
than an atom
What is nanoparticle?
100 10-1 10-2 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-10 10-11
• Nano particle is a particle with the size between 1 to 100 nanometres .
State the relationship between the size of particle with the ratio of surface area to its volume.
The smaller the size of the particle, the bigger the ratio of the surface area to its volume.
Is it possible to see nanoparticle and what are the instrument to observe the structure?
• Nanoparticles are too small to be seen with the naked eye and even with conventional lab microscopes.
• Nanoparticles can be observed using the powerful microscopes as below:
What is nanoscience?
Nanoscience is the study on processing of substances at nano scale.
What is nanotechnology?
Nanotechnology is the development of substances or gadgets using the properties of nanoparticles.
• Dye-sensitived solar cell consist of titanium dioxide. This solar cell is durable ,
Energy and
light-weight and more efficient.
electric
• Graphene battery has long life and save time to recharge battery.
• Iron nanoparticles are used in firefighter fabrics to make fabric resist burning
Textile
and can withstand heat .
• Titanium dioxide is used in fabric to reduce wrinkle of cotton and silk.
• Silicon dioxide nanoparticles is used in fabric to make fabric water repellant .
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Graphene LS 5.4.3
What is graphene? State the speciality of graphene compared to the other carbon allotrope.
• Graphene is a single layer of carbon atoms, tightly bound in a hexagonal lattice.
• Graphene abundantly available in nature and ecologically friendly.
Carbon
Hard and strong • Strength of graphene comes from the strong covalent bonds between
the carbon atoms.
Impermeable • Graphene blocks all liquids and gases to pass through.
Transparent • Graphene absorbs 2.3% of visible light and this makes graphene very
transparent.
Low electrical resistance • Graphene has low electrical resistance .
• This allows a lot of electrons to flow very quickly through it.
Give example of activities that cause the negative effects towards environment.
• Transportation
• Burning of fuel
• Waste and wastewater disposal
• Greenhouse effect
• Pollution
What is the effect of the above phenomena toward the climate change?
• Long draught
• Flood
Google
• Biodiversity lost Form
Green Technology has been implemented in Malaysia according to several sectors. State the application
of Green Technology in each sector.
Sectors Aplications
Power supply • Renewable energy such as solar, hidro, geothermal and wind.
• It is also known as ‘Clean Energy’ or ‘Green Energy’ because does not pollute water
and air.
Building • Green buildings is built with the use of green building materials, efficient use of
energy and water and the production of minimal solid waste.
Domestic waste • Recycling (3R concept – Reduce, Reuse and Recycle) and Landfill Leachate
and wastewater Treatment Method are used to minimise the waste production.
management • The disposed waste are treated to produce new materials such as compost.
Agriculture and • Use of compost fertiliser to improve soil nutrients and management of crop irrigation
forestry using rainwater to water the plants.
What is waste?
Waste is the excess, unwanted product or materials that needs to be disposed of because it is damaged
and broken.
What is wastewater?
Water that contains materials such as sewage, food waste, oil and chemicals.
Solid waste
Are processed to
• Domestic wastewater
• Stormwater (Rain or melted snow that do not absorb into the groundwater)
• Industrial wastewater
What is the effect if polluted land and water are not treated properly?
• Water and land pollution occur
• Unpleasant odours
What is electrocoagulation?
Process to remove the suspended solid from wastewater by using electrolysis principle.
Floc
Carbon Carbon
Wastewater
Sludge
What is floc?
• Floc is the pollutant that coagulates at the top of the treated wastewater.
• The pollutant that accumulates at the bottom is known as sludge.
Wastewater Treatment
Importances of
Increase quality life of human
Green Technology
Spearheading innovation
SPM PRACTICE
PAPER 1
1 The diagram below shows the process where 6 Which of the following food additives is added to
PL2
unsaturated fats can be converted to saturated replace sugar?
PL3
2 A chef spilled curry sauce on his shirt while You need to Alright
cooking. Which additives should be added to the
PL3
finish this medicine. doctor.
detergent to ensure the dirt can be removed?
A Protease
B Sodium hydroxide
C Sodium carbonate
D Fluorescent dyes
A O C O
Which statement best explains the use of graphene
R O S OH R C OH in making biosensor?
A Electrons move faster
O B Has large surface area
B O D O C Electron in graphene is small in size
D Has high mechanical strength
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R O S ONa R C ONa
9 The diagram below shows the wastewater
O PL2 treatment process.
• Relieves pain
• Reduces fever Effluent Sludge
• Not suitable for children Sedimentation
Disposal Treatment
Which of the following could be medicine J?
A Aspirin What is the name of process X?
B Penicillin A Precipitation
C Paracetamol B Electrocoagulation
C Incineration
PAPER 2
SECTION A
1 The diagram shows the molecular structure of aspirin. H
O H
(b) (i) Antibiotic is one of the medicines that is always given by a doctor to a patient. What is the function of
PL1 antibiotic?
To kill or inhibit growth of infectious bacteria.
(ii) Explain why the patient must take full course of the antibiotic prescribed by the doctor.
PL2
To make sure that all the bacteria are killed. If not, the bacteria will become immune to the medicine
or it will cause further infection.
(c) (i) State the name of one type of medicine that changes the emotions and behaviour of the patient.
PL1
Psychotherapeutic
(ii) A patient is suffering from hallucination, delusion or other symptoms of mental illness. Suggest other
PL1 example of medicine that is suitable to treat the patient.
Antipsychotic
(d) Medicines that are obtained from plants and animals are known as traditional medicines. State one name
PL1 of a traditional medicine that can be used to cure diabetes.
Bitter gourd
Antimicrobials
PL1
(iii) In your opinion, is the method in 1(f)(i) effective to sanitise the building in order to reduce risk of
HOTS
COVID-19? Justify your answer.
PL5 • The method is effective because microorganisms are killed and viruses are not spread away. OR
• The method is not effective because it just kills the microorganisms at present.
• If other person is infected after the building has been sanitised, the process of sanitasing need to
be done again.
(a) (i) State the name of the homologous series that sunflower oil belongs to.
Ester PL1
(ii) On the diagram, circle the functional group that determines the homologous series of sunflower oil.
PL2
3 The table below shows three situations of using different types of cosmetics.
5
HOTS
Situation I Situation II Situation III
STEM
beautifying.
(b) Based on situations I, II and III, state type of cosmetics and examples for X, Y and Z.
PL4
Types of cosmetic Examples
X Makeup cosmetic Powder
Y Fragrance Perfumes
(c) Cosmetic X applied by Puan Siti contains mercury and is not registered under Ministry of Health Malaysia
KBAT
(MOH). In your opinion, should Puan Siti continue using cosmetic X? Give reason for your answer.
PL2 Puan Siti should not continue using cosmetic X. Mercury cause damage to the kidneys and nervous
system. It can interfere the development of the brain of unborn babies.
It can also cause rashes, irritation and other damages to the skin.
(d) The manufacture of cosmetic such as cosmetic Z nowadays are incorporating with nanotechnology.
(i) What is nanotechnology?
PL1
Nanotechnology is the development of substances or gadgets using the properties of nano
particles.
4 The table below shows informations about two different type socks.
HOTS
Type of socks A B
PL2
• Common sock with no incorporating • Sock incorporating with
nanotechnology nanotechnology
Characteristics • Get damp when exposed with liquid • Waterproof
• Produce nasty odour after being used • Does not produce nasty ordour after
being used
Based on the information in the table above, which sock is more suitable to be used by an athlete? Explain
your answer.
• Sock B is more suitable to be used by athlete.
• When an athlete is sweating, the liquid produced causes the sock to damp. This reduces fungal infection
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on skin.
• Sock B gives comfortability to the athlete because does not produce nasty odor after being used.
5 The diagram shows the disposal of wastewater from industry into the drainage system.
SECTION B
1 (a) The table below shows the result of experiment on the stain cloth after being cleaned using different
PL3 cleaning agent.
Cleaning agent P Q
Grease Grease
Cleansing action stain stain
in hard water
Suggest cleaning agent P and Q. explain the difference in the observation in table above.
[7 marks]
(ii) Describe methods that can be taken by patient C to produce substance that can be used to treat
rashes on her face. [5 marks]
(c) The diagram below shows one of the application of electrolysis process in wastewater treatment.
PL3
Electrode X
Part Y Wastewater
Suggest the material that can be used at electrode X. State the name of substance that collected at part
Y and it use. [3 marks]
BAHAGIAN C
1 (a) The table below shows information about cosmetics.
PL2
Types of cosmetics X Y Z
Used to beautify the
Information Body treatment Gives fragrance
face
Example Skin moisturiser Blusher Deodorant
(i) What is meant by cosmetics? [1 mark]
(ii) State the type of cosmetics X, Y and Z. State other uses for each cosmetic X, Y and Z other than
those stated in the table above. [6 marks]
(b) The chemical equation below shows the equation for the soap production process.
PL3
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