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Chemical Kinetics Marks Booster

The document discusses chemical kinetics, focusing on various order reactions and their rate constants (k). It includes equations for zero, first, and second order reactions, as well as the Arrhenius equation for temperature dependence of reaction rates. Additionally, it presents calculations related to reaction times and rate constants using logarithmic transformations.

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agnibanerjee202
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60 views63 pages

Chemical Kinetics Marks Booster

The document discusses chemical kinetics, focusing on various order reactions and their rate constants (k). It includes equations for zero, first, and second order reactions, as well as the Arrhenius equation for temperature dependence of reaction rates. Additionally, it presents calculations related to reaction times and rate constants using logarithmic transformations.

Uploaded by

agnibanerjee202
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

CHEMICAL KINETICS

MARKS BOOSTER
·Ya + MCC + SQP
In
sect
↑

k =
(mol(-1) :
osect
zero order Ent
-
K =
(molc-1)
Mol + sect

second order #
k =
(mocc-1) sect

=
(molc-112 sect

= mol" sect
+50 % =
t =
20 min
t1 =
09]
K 346 5
5x154
.

65 346

09
.

0,
4 =
-
=

=)
t 23 2 X
leg
= 1000
To
K 30465X12

2303
=

leg
o

. 46x102100-90
3

=
2 303
.

55
46x10-
.
2
203 lg
t =

2 30 y
-

lig Im

first

slope =
1
2303

t 0 693
12 = .

K
+ 50 % =
ty = 69 3.
min
+
2 0
-93 0 693
=
- k = .

-
K
+

-
y2
2003 lg =
863 X10 = 102
3X 1000 min
P
troy.
- -

23 lg
100-so

pos
Do
=
X0.6990 =

10-2
17 _
2303 (eglovl6
2303(1 7782)
=
-
0 .

so
t 40 %
2303 lg
=

k = 0 00639
. = 6 . 39X10]

20 l 40
=
tgoy
2003 lg
=

= legte lig
os
-
>
-
InR =
Kt-en Ro
MR = -kt + luRe

y = mx + C

↑
enRo

slope = -
Ruc

t
k = 4X10-3 Mst

Ro
tR
= 0 I M
.

R = 0 . 064M

-
= 036

Tx100e
t-9
-

sec
Arrhenics Eg"

K= A . e-EalRT 2 303 XQ

Ea 2303X80314 = 19 15
Ink In A
.
-
=
-

RT

Ea
ligk lig A -
=
-

2303RT

lg C Zt
TTs
(
log 0
-
.
20
= E
C 500-200)
-
0 02
19
.
.
15 2004500

To 02 sect log 10 = Ea X
200K K 0
= = .
-

10000
19915
-

Tz = 500K K2 = 0 20 sect
.

6383 3 .

Ea
! 950
+
= Ea
-

log 6383 33/md


· =
Ei
M log

19043
th = 30 min T, =
300 K
693 0
.

-
E
k
06930 . .
=

10g3
=
-

30

min T2 =
320k
the =
10
04771X 19 15 X9600
.
= Ea
kz 0 693 2
06
= .

#
Ink vs
1/T
Ink = InA-t
RT
-

Ink Slope = -Ea


-

3/T
logk =

ligH-317
logk =
14 2-1 0 X10M
.
.

Ea = 1 . 0x107
2 303RS
.
-

Fur

Ea = 19 15 X1.
.
0 NOT
k = A e-EalR]
.

(2 1014) 250
:
-

= . 5 x

Sta = -20
O R R
-

Ea = RX25000
ty = 0 . 693
F =
8 314 X2520
.

69
K
06
= 0 .

= -

300

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