RED OX REACTIONS
µ
onidation
FILE Lon
.
→ Oxidation state
Redon Reactions
→ Balancing
Redon Reactions
→
Types of
1 QI s
Concept of Oxidation Reduction
PMT 2015-
onidation Reduction
Addition of oxygen removal of
oxygen
•
•
Removal
•
of hydrogen • Addition
of hydrogen
• loss of electrons • Gain
of electrons
• Increase in onidation No .
• Decrease in onidation No .
• Addition
of non metal • Addition
of metal
Oxidising Agent he substance that
gains )
electron (reduced
Important onidising Agents :
• kmn Oy
HN Oz Hgclz
K2 cuz Oy NaN Oz Kilby
• oxides
of
elements
MgO bro bells Py Dio
:
, , ,
• fluorine is the strongest Onidismg Agent
electron (onidised)
Reducing Agent : The substance that loses
Important reducing Agents :
All metals : Na 2n Fe ne etc
pm T 2014 eg
.
, , ,
.
•
Hydroids : Hel
,
H Bee ,
HI ,
HS etc .
• Lithium is
strongest Reducing agent in solution .
Equivalent wt .
of OA
IRA = molecular
weight
electrons
No .
of gained co Ay -
electrons lost CRA)
No .
of
Equivalent wt = Molecular
weight
in ouidation
change mole
No .
five
Oxidation State
GG•yap
wnfifigationn.tt
eoommmmonmooniedationnstatete
+2 NSL
IA + 2 NSZ
'
TIA +3 ,
+2
ns2np
ME
TIA +4 , -13 ,
-12 , +2 , -2 ,
-2
,
-3 ,
-4
n.ph
Mp3
-
IA +5 ,
-13 ,
+2 ,
-2 , -3 n'S2
VI A +6 ,
-14 ,
+2 ,
-2 NSZ np "
VI A +7 MS
'
's
, +5 , -13 ,
+2 ,
-2
hp
Neet 2018
'
common Onidatiorr states
PMT 2012 i
compound onidation state
N +
(-2×4)=-1 n +7
-
-_
Mnoy 2)
Lonygen
-
-_
-
Hz 505 -
trots.iq#gPTnhkddgeo.N.ofs--t2t2t2 +6
linkage
,qwxide
- 2 p
1121208 ¥, sina.aoo-oo-s.io?oitntion.ofSEfIf2t2
I
I
-
be ftp.ofje-peronideo.N.ofae
-
to .
-
3 i linkage -
a
z
-
-
Caollz Cad ! ou
- -
z 72
Fez
•
Fez Oy Feo +
Cequimolaumintwee)
Life in -12
2. Fe in -13
be , 0,2 2K (7×2)=-2
-
-
a > + f
-
B. 06 ON -_
6 Neet 2019 Odb
Balancing Redon Reaction
Onidation No . method Ion -
electron method
Example
-
Example -
Cu Cu (NO 3)
- -
Og Mz O
-
t HN → t NO z t
Iz t on → I 03 t I t
te O
'
z
step I -
write
given equation step I
-
split into a half
write onidation of all atoms equations
step I No
-
Tinto; ciifiiiojjztni of + Ii E Hao ( d)
oui
' -
ai Ig
-
→
+
,
Iz t on → t
Iz ( reducer)
-
→ I
www.otefhafgniong!
#
step -
step TI Adding on ions
-
+5 + y
HN Oz → NO z
-
② ( for 2 molecule of H2O -
OH ions)
-
Increase in onidation 2
No
of Cu 2
per molecule
-
-
.
oxidation
-
Decrease in No .
of N = 2
per molecule Iz t 12011 → 2IOj +
6h20
Step II -
make increase and decrease
electrons
equal multiply ② by CD Step TI Adding
-
. .
cut 2MW Oz → Cu ( NO 3)
z
+ 2N
Oz + H2O to the sides
deficient
in electrons
Balance Nitrate ions 2105+61120+10 e-
-
step I -
. Iz -112011 →
Cll
-
4 HN Og Cu (NO Iz 2e → 23
-
→ t
3)
+ t 2N
Oz -1 2h20
z
step II
Balancing electrons
-
both
in
-
half reactions .
12 OH
2IOj GHz Ot Ge
-
Iz →
Follow
t t
I
any LIZ IT
5 2e
-
t → 2
Io
step I -
Add both half
reactions
nature
's : :: is:: : :: :
Types of Redon Reactions
Indirect redox Direct Redon Intermolecular Intramolecular
Reaction reaction Redox Reaction Redox Reaction
where onidation Where onidation Where one where one
and redox and reduction reactant is element is
reactions occur reactions occur onidised and onidised
in different in some other is while other
vessels vessel reduced .
is reduced
in same
o +3
compound .
LAL + Fez 03 2KI0z
-13 O
Is
"
-2
Alzoztfe 2k£, -1302
Disproportionation Reaction
Same
and
substance
reduction .
undergoes simultaneous onidation
O -
t +5
362 t 6 NaOH 5 Nacl +
Nacloz -131120
decrease
Neet 2019
increase
