25

3.3 Hasil Perhitungan Neraca Massa

Tabel 3.1 Tabel neraca massa Reaktor-01

Input Output
Katalis
Komponen F1 F3
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 4166,72 83,33
H2O 25,95 10,07 36,02
H2SO4 2686,44 2686,44
C6H5OH 2525,25
CH3COCH3 1558,13
Subtotal 4192,68 2696,50
Total 6889,18 6889,18

Tabel 3.2 Tabel neraca massa Netralizer-01

Input Input Output

Komponen F2 F3 F4
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 36,02 529,45
H2SO4 2686,44
NH4OH 904,62
NH4HSO4 3097,63
C6H5OH 2525,25 2525,25
CH3COCH3 1558,13 1558,13
Subtotal 6889,18 904,62
Total 7793,80 7793,80
 26

Tabel 3.3 Tabel neraca massa Decanter-01

Input Output Output

Komponen F4 F5 F6
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 529,45 529,45
NH4HSO4 3097,63 3097,63
C6H5OH 2525,25 2525,25
CH3COCH3 1558,13 1558,13
Subtotal 3097,628 4696,17
Total 7793,798 7793,797725

3.4 Tabel neraca massa MD-01

Input Input Output

Komponen F6 F7 F8
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 529,45 529,45
C6H5OH 2525,25 2525,25
CH3COCH3 1558,13 1558,13
Subtotal 1558,13 3138,03
Total 4696,17 4696,17

Tabel 3.5 Tabel neraca massa MD-02

Input Input Output

Komponen F8 F9 F10
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 529,45 529,45
C6H5OH 2525,25 2525,25
Subtotal 612,78 2525,25
Total 3138,03 3138,03
 27

Tabel 3.6 Neraca Massa OverAll

Input Input Output Output Output Output

Katalis
Komponen F1 F3 F5 F7 F9 F10
Kg/Jam Kg/Jam Kg/Jam Kg/Jam Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 4166,72 83,33
H2O 25,95 10,07 529,45
H2SO4 2686,44
NH4OH 904,62
NH4HSO4 3097,63
C6H5OH 2525,25
CH3COCH3 1558,13
Total 7793,8 7793,8
 28

3.4 Hasil Perhitungan Neraca Panas

Tabel 3.7 Neraca Panas Heater-01

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk 56375,88554 -

Panas Keluar - 4410029,802

Q Air Pemanas 4,35E+06

Total 4410029,802 4410029,802

Tabel 3.8 Neraca Panas pada Heater-02

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -3200506364 -

Panas Keluar - -3,88336E+11

Q Air Pemanas -3,85E+11 -

Total -3,88336E+11 -3,88336E+11

Tabel 3.9 Neraca Panas pada Reaktor

Input Output
Item
kJ/Jam kJ/Jam
Panas Reaktan -2228,942736 -
Panas Reaksi - -235530
Panas Produk - -7,79E+09
Q Air Pemanas 3,81E+11 -
Total -7,79E+09 -7,79E+09
 29

Tabel 3.10 Neraca Panas pada Cooler

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -7,79E+09 -

Panas Keluar - -4,10E+07

Q Air Peendingin 7,75E+09 -

Total -4,10E+07 -4,10E+07

Tabel 3.11 Neraca Panas pada Netralizer

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -4,10E+07 -

Panas Keluar - -4,10E+07

Total -4,10E+07 -4,10E+07

Tabel 3.12 Neraca Panas pada Decanter

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -4,10E+07 -

Panas Keluar - -4,10E+07

Total -4,10E+07 -4,10E+07

 30

Tabel 3.13 Neraca Panas pada Heater-03

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -4,10E+07 -

Panas Keluar - -8,42E+09

Q Air Pemanas -8,38E+09 -

Total -8,42E+09 -8,42E+09

Tabel 3.14 Neraca Panas pada Menara Destilasi-01

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -8,42E+09 -

Panas Keluar - -8,42E+09

Total -8,42E+09 -8,42E+09

Tabel 3.15 Neraca Panas pada Heater-04

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -8,42E+09 -

Panas Keluar - -5,69E+10

Q Air Pemanas -4,85E+10 -

Total -5,69E+10 -5,69E+10

 31

Tabel 3.16 Neraca Panas pada Menara Destilasi-02

Input Output
Item
kJ/Jam kJ/Jam

Panas Masuk -5,69E+10 -

Panas Keluar - -5,69E+10

Total -5,69E+10 -5,69E+10

Tabel 3.17 Neraca Panas Over All

KOMPONEN INPUT OUTPUT

HEATER-01 4410029,802 4410029,802
HEATER-02 -3,88E+11 -3,88E+11
REAKTOR -7,79E+09 -7,79E+09
COOLER -4,10E+07 -4,10E+07
NETRALIZER -4,10E+07 -4,10E+07
DECANTER -4,10E+07 -4,10E+07
HEATER-03 -8,42E+09 -8,42E+09
DESTILASI-01 -8,42E+09 -8,42E+09
HEATER-04 -5,69E+10 -5,69E+10
DESTILASI-02 -5,69E+10 -5,69E+10
TOTAL -5,26885E+11 -5,26885E+11
 32

DAFTAR PUSTAKA

[1] Badan Pusat Statistik (BPS), “Data Ekspor Impor Propilen Glikol tahun 2019-2023,”
2024.

[2] Himmeblau, David. M, Basic Principles and Calculation in Chemical

Engineering, 4th Edition, Prentice Halll Inc-englewood elittts, USA
[3] Himmeblau, David. M, Basic Principles and Calculation in Chemical
Engineering, 6th Edition, Prentice Halll Inc-Englewood Elittts, USA
[4] Kirk, R.E. and Othmer, P, Encyclopedia of Chemical Tecnology, Vol 8,
4th Edition, John Willey & Sons Inc., Mew York, 1982.
[5] J. M. Coulson, Chemical Engineering Volume 6, New York: Pergamon Press,
1983.
[6] Mc. Ketta, John, 1983, “Encyclopedia Chemical Process and Design”,
Marchell Dekker Inc., New York.
[7] Kirk, R.E. and Othmer, V.R., 1995, Encyclopedia of Chemical Technology,
vol.16 Mass Transfer to Neuroregulators, 4th ed., John Wiley & Sons Inc.,
New York.
[8] Kirk, R.E. and Othmer, V.R., 1994, Encyclopedia of Chemical Technology,
vol.11 Flavor Characterization to Fuel Cells, 4th ed., John Wiley & Sons
Inc., New York.
[9] Kirk R.E. and Othmer, D.F., 1978, “ Encyclopedia of Chemical Technology “,
vol.1, 2nd edition, A Willey Interscience Publication, John Wiley and Sons
Co., New York
[10] Ullmann. (2003). Ullmann's Encyclopeda of Industrial Chemistry. New
York: John Willey & Sons, Inc.

[11] Kirk, R.E. dan Othmer, D.F. 1967. Encyclopedia of Chemical Engineering
Technology, volume1. New York:John Wiley and Sons Inc

[12] W. McCabe, J. Smith and P. Harriott, Unit Operations of Chemical

Engineering, New York: McGraw-Hill Education, 2004.

[13] Wallas, S.M., Chemical Process Equipment Selection and Design,

Buttwerworth, Heinneman Co., 198.

[14] M. S. Peters, K. D. Timmerhaus and R. E. West, Plant design and economics

for chemical engineers, Colorado: McGraw-Hill, 2003.
 33

[15] S. V. Ness and M. M. Abbott, Introduction to Chemical Engineering

Thermodynamics, Boston: McGraw-Hill, 2018.

[16] Faith, K. A. 1975. Industrial Chemicals. Canada: A Willey- International

Publication.

[17] G. Towler and R. Sinnott, Chemical Engineering Design, Amsterdam:

Elsevier, 2008.

[18] Mc. Ketta, J.J and Cunningham, W.A. 1984. Encyclopedia of Chemical
Engineering and Design. Marcel Dekker Inc. : New York.

[19] Treyball, R.E.1955.Mass Transfer Operator,Internal Student Edition.Tokyo:

Kogakusha Co

[20] Kern, D Q.1965.Process Heat Transfer, 1st Edition.New York: Mc Graw-Hill

Book Co.

[21] Levenspiel, O.1977.Chemical Reaction Engineering, 2nd Edition.New York:

John Wiley & Sons Inc
 34

LAMPIRAN A

NERACA MASSA

A. Perhitungan Neraca Massa

Pabrik yang dirancang berkapasitas 20.000 Ton/tahun
1 ton = 1000 kg
1 tahun produksi = 330 hari
1 hari produksi = 24 jam
20.000 𝑇𝑜𝑛 1.000 𝐾𝑔 1 𝑇𝑎ℎ𝑢𝑛 1 𝐻𝑎𝑟𝑖
Kapasitas produksi × × 330 𝐻𝑎𝑟𝑖 × 24 𝐽𝑎𝑚
𝑇𝑎ℎ𝑢𝑛 𝑇𝑜𝑛

Kapasitas produksi = 2525,25 Kg/jam

B. Berat molekul masing-masing komponen ( kg/kmol )
C6H5(CH3)2COOH = 152
H2O = 18
H2SO4 = 98
C6H5OH = 94
CH3COCH3 = 58
NH4OH = 33
NH4HSO4 = 113
C. Komposisi bahan baku Cumene Hidroperoxide

C6H5(CH3)2COOH= 95 % berat

H2O = 5 % berat

Merubah % mol enjadi % berat Dimisalkan berat campuran 100 kg maka :

Tabel A.1 Komposisi Bahan Baku Cumene Hidroperoxide

Komponen Berat (kg) Mol Persen mol

C6H5(CH3)2COOH 95 0,625 69,21

H2O 5 0,278 30,79
Total 100 0,903 100
 35

D. Komposisi Produk

C6H5OH = 99,9 % berat

H2O = 0,1 % berat

Merubah % mol enjadi % berat Dimisalkan berat campuran 100 kg maka :

Tabel A.2 Komposisi Bahan Baku Etilen Okside

Komponen Berat (kg) Mol Persen mol

C6H5OH 99,9 1,063 99,48

H2O 0,1 0,006 0,52

Total 100 1,069 100

E. Reaksi yang terjadi di reaktor ( R-01 )

Reaksi utama:

C6H5(CH3)2COOH(l) C6H5OH(l) + CH3COCH3(l)

F. Ketentuan dalam reaktor

konversi 98%

G. Perhitungan neraca massa

NERACA MASSA BASIS

Konversi 98 % terhadap Cumene Hidroperoxide

Input awal Cumene Hidroperoxide = 100 Kmol/Jam
C6H5(CH3)2COOH = 100 kmol/jam x 152 = 15200 kg/jam
H2O = 5%/95% x 100 kmol/jam = 5,26 kmol/jam
= 5,26 kmol/jam x 18 = 94,68 kg/jam
 36

1. Reaktor

F2
katalis
C6H5(CH3)2COOH
H2SO4
F1
H2O
C6H5(CH3)2COOH
H2O Reaktor-01 H2SO4

P = 1atm C6H5OH

T = 78 °C CH3COCH3

Konversi reaksi = 98%

Reaksi utama:

C6H5(CH3)2COOH(l) C6H5OH(l) + CH3COCH3(l)

Konversi reaksi = 98 %

C6H5(CH3)2COOH(l) C6H5OH(l) + CH3COCH3(l)

Awal : 100

Reaksi : 98 98 98

Sisa : 2 98 98

F1+ Katalis = F2
Input
F1
C6H5(CH3)2COOH = 100 kmol/jam x 152
= 15200 kg/jam
H2O = 5,26 kmol/jam x 18
= 94,68 kg/jam
Katalis
H2SO4 = 100 kmol/jam x 98
= 9800 kg/jam
 37

H2O = 2%/98% x 100 kmol/jam = 2,04 kmol/jam

= 2,04 kmol/jam x 18
= 36,72 kg/jam
Output
F2

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 94,68 kg/jam + 36,72 kg/jam
= 131,4 kg/jam
H2SO4 = 100 kmol/jam x 98
= 9800 kg/jam

C6H5OH = 98 kmol/jam x 94
= 9212 kg/jam
CH3COCH3 = 98 kmol/jam x 58
= 5684 kg/jam
Tabel A.3 Tabel neraca massa Reaktor-01

Input Output
Komponen Katalis
F1 F3
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 15200 304
H2O 94,68 36,72 131,4
H2SO4 9800 9800
C6H5OH 9212
CH3COCH3 5684
Subtotal 15294,7 9836,72
Total 25131,4 25131,4
 38

2. Netralizer

F3

NH4OH
F2 F4
C6H5(CH3)2COOH
Netralizer-01 C6H5(CH3)2COOH
H2O
H2O
P = 1atm
H2SO4 NH4 HSO4
T = 32 °C
C6H5OH
C6H5OH
CH3COCH3
CH3COCH3
Reaksi :

C6H5(CH3)2COOH(l) C6H5OH(l) + CH3COCH3(l)

Konversi reaksi = 100 %

NH4OH (aq) + H2SO4(aq) NH4HSO4 (aq) + H2O(l)

Awal : 100 100

Reaksi : 100 100 100 100

Sisa : 0 0 100 100

Input
F2

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 131,4 kg/jam
H2SO4 = 5,26 kmol/jam x 18

= 94,68 kg/jam
C6H5OH = 98 kmol/jam x 94
= 9212 kg/jam
CH3COCH3 = 98 kmol/jam x 58
= 5684 kg/jam
 39

F3

NH4OH = 100 kmol/jam x 33

= 3300 kg/jam

Output
F4

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 131,4 kg/jam
C6H5OH = 98 kmol/jam x 94
= 9212 kg/jam

CH3COCH3 = 98 kmol/jam x 58
= 5684 kg/jam
NH4HSO4 = 100 kmol/jam x 113
= 11300 kg/jam

H2O hasil reaksi = 100 kmol/jam x 18

= 1800 kg/jam
Tabel A.4 Tabel neraca massa Netralizer-01

Input Input Output

Komponen F2 F3 F4
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 304 304
H2O 131,4 1931,4
H2SO4 9800
NH4OH 3300
NH4HSO4 11300
C6H5OH 9212 9212
CH3COCH3 5684 5684
Subtotal 25131,4 3300
Total 28431,4 28431,4
 40

3. Decanter

F4 F6
C6H5(CH3)2COOH Decanter-01 C6H5(CH3)2COOH
H2O P = 1atm H2O
NH4 HSO4 T = 32 °C C6H5OH
C6H5OH F5 CH3COCH3
CH3COCH3 NH4 HSO4

Input
F4

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 1931,4 kg/jam

C6H5OH = 98 kmol/jam x 94
= 9212 kg/jam
CH3COCH3 = 98 kmol/jam x 58
= 5684 kg/jam
NH4HSO4 = 100 kmol/jam x 113
= 11300 kg/jam

Output
F5

NH4HSO4 = 100 kmol/jam x 113

= 11300 kg/jam

F6

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 1931,4 kg/jam
 41

C6H5OH = 98 kmol/jam x 94

= 9212 kg/jam
CH3COCH3 = 98 kmol/jam x 58
= 5684 kg/jam

Tabel A.5 Tabel neraca massa Decanter-01

Input Input Output

Komponen F4 F5 F6
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 304 304
H2O 1931,4 1931,4
NH4HSO4 11300 11300
C6H5OH 9212 9212
CH3COCH3 5684 5684
Subtotal 11300 17131,4
Total 28431,4 28431,4
 42

4. Menara Destilasi-01

F7

CH3COCH3
F6 F8

C6H5(CH3)2COOH MD-01 C6H5(CH3)2COOH

H2O P = 1atm H2O

C6H5OH T = 80 °C C6H5OH

CH3COCH3

Input
F6

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 1931,4 kg/jam
C6H5OH = 98 kmol/jam x 94

= 9212 kg/jam
CH3COCH3 = 98 kmol/jam x 58
= 5684 kg/jam
Output
F7

CH3COCH3 = 98 kmol/jam x 58
= 5684 kg/jam
F8

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam

H2O = 1931,4 kg/jam

C6H5OH = 98 kmol/jam x 94
= 9212 kg/jam
 43

Tabel A.6 Tabel neraca massa MD-01

Input Input Output

Komponen F6 F7 F8
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 304 304
H2O 1931,4 1931,4
C6H5OH 9212 9212
CH3COCH3 5684 5684
Subtotal 5684 11447,4
Total 17131,4 17131,4
 44

1. Menara Destilasi-02
F9

C6H5(CH3)2COOH

H2O
F8

C6H5(CH3)2COOH MD-02 F10

H2O P = 1atm C6H5OH

C6H5OH T = 160 °C

Input
F8

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 1931,4 kg/jam
C6H5OH = 98 kmol/jam x 94

= 9212 kg/jam

Output
F9

C6H5(CH3)2COOH = 2 kmol/jam x152

= 304 kg/jam
H2O = 1931,4 kg/jam

F10

C6H5OH = 98 kmol/jam x 94

= 9212 kg/jam
 45

Tabel A.7 Tabel neraca massa MD-02

Input Input Output

Komponen F8 F9 F10
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 304 304
H2O 1931,4 1931,4
C6H5OH 9212 9212
Subtotal 2235,4 9212
Total 11447,4 11447,4
 46

Kapasitas Yang Sesungguhnya

20.000 𝑇𝑜𝑛 1.000 𝐾𝑔 1 𝑇𝑎ℎ𝑢𝑛 1 𝐻𝑎𝑟𝑖

Kapasitas produksi × × 330 𝐻𝑎𝑟𝑖 × 24 𝐽𝑎𝑚
𝑇𝑎ℎ𝑢𝑛 𝑇𝑜𝑛

Kapasitas produksi = 2525,25 Kg/jam

Dari basis perhitungan 100 Kmol/Jam maka dihasilkan C6H5OH 9212 Kg/jam

Jadi untuk mendapatkan C6H5OH dengan kapasitas 20.000 ton/tahun maka :

Kapasitas yang digunakan

Faktor Pengali =
𝐾𝑎𝑝𝑎𝑠𝑖𝑡𝑎𝑠 ℎ𝑎𝑠𝑖𝑙 𝑝𝑟𝑜𝑑𝑢𝑘𝑠𝑖 𝑏𝑎𝑠𝑖𝑠

2525,25
=
9212

= 0,274126

Tabel A.8 Tabel neraca massa Reaktor-01

Input Output
Katalis
Komponen F1 F3
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 4166,72 83,33
H2O 25,95 10,07 36,02
H2SO4 2686,44 2686,44
C6H5OH 2525,25
CH3COCH3 1558,13
Subtotal 4192,68 2696,50
Total 6889,18 6889,18
 47

Tabel A.9 Tabel neraca massa Netralizer-01

Input Input Output

Komponen F2 F3 F4
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 36,02 529,45
H2SO4 2686,44
NH4OH 904,62
NH4HSO4 3097,63
C6H5OH 2525,25 2525,25
CH3COCH3 1558,13 1558,13
Subtotal 6889,18 904,62
Total 7793,80 7793,80

Tabel A.9 Tabel neraca massa Decanter-01

Input Output Output

Komponen F4 F5 F6
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 529,45 529,45
NH4HSO4 3097,63 3097,63
C6H5OH 2525,25 2525,25
CH3COCH3 1558,13 1558,13
Subtotal 3097,628 4696,17
Total 7793,798 7793,797725
 48

Tabel A.10 Tabel neraca massa MD-01

Input Input Output

Komponen F6 F7 F8
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 529,45 529,45
C6H5OH 2525,25 2525,25
CH3COCH3 1558,13 1558,13
Subtotal 1558,13 3138,03
Total 4696,17 4696,17

Tabel A.11 Tabel neraca massa MD-02

Input Input Output

Komponen F8 F9 F10
Kg/Jam Kg/Jam Kg/Jam
C6H5(CH3)2COOH 83,33 83,33
H2O 529,45 529,45
C6H5OH 2525,25 2525,25
Subtotal 612,78 2525,25
Total 3138,03 3138,03
 49

LAMPIRAN B

NERACA PANAS

Kapasitas produksi : 20.000 ton/tahun

Jumlah hari kerja : 330 hari/tahun = 7920 Jam/tahun

Satuan : Kal/jam

Suhu referensi : 25oC = 298K

Penentuan harga-harga Cp

No Komponen A B C D
1. C6H5(CH3)2COOH 1,06988E+01 1,00554E+03 -0,7773E+04 0,0212E+06
2. H2O 1,82964E+01 4,72118E-01 -1,33878E-03 1,31424E-06
3. H2SO4 5,9830E+04 3,9520E+02 -5,2067E-01 -1,60497E-07
4. C6H5OH -3,61614E-01 1,15354E+00 -2,12291E-03 1,74183E-06
5. CH3COCH3 1,68022E+01 8,48409E-01 -2,64114E-03 3,39139E-06
(Yaws,1999)

Harga-harga Cp untuk gas dicari dengan rumus:

Cp = A + BT + CT2 + DT3 KJ/Kgmol K

Harga Cp untuk cairan dicari dengan rumus:

Cp = A + BT + CT2 KJ/Kgmol
 50

1. Heater-01

H-01
Panas Reaktan Panas Produk

Fungsi : Menaikan suhu H2SO4 sebelum masuk kereaktor

T In = 303 K

T Out = 351 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

H2SO4 27,41 2056,93325 56380,54038
H2O 0,56 -8,3122195 -4,65484292

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

H2SO4 27,41 160914,0425 4410653,906
H2O 0,56 -1114,471368 -6,24E+02
 51

2. Heater-02

H-02
Panas Reaktan Panas Produk

Fungsi : Menaikan suhu C6H5(CH3)2COOH sebelum masuk kereaktor

T In = 303 K

T Out = 351 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 27,41 -116764186,5 -3200506352
H2O 1,44 -8,3122195 -11,96959608

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 27,41 -14167673131 -3,88336E+11
H2O 1,44 -1114,471368 -1,60E+03
 52

3. Reaktor

Reaktor
Panas Reaktan Panas Produk

Fungsi : Mereaksikan C6H5(CH3)2COOH

T In = 351 K

T Out = 351 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 27,41 -14167673131 -3,88336E+11
H2O 2 -1114,471368 -2228,942736
H2SO4 27,41 160914,0425 4410653,906

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,42E+10 -7,79E+09
H2O 2 -1,11E+03 -2,23E+03
H2SO4 27,41 1,61E+05 4,41E+06
C6H5OH 26,86 -6,30E+02 -1,69E+04
CH3COCH3 26,86 -2,43E+03 -6,53E+04
 53

Menghitung ⧍r 298 K
Reaksi yang terjadi
Reaksi utama:

C6H5(CH3)2COOH(l) C6H5OH(l) + CH3COCH3(l)

Komponen ⧍f

C6H5(CH3)2COOH -78400

C6H5OH -96360

CH3COCH3 -217570

⧍HP = ⧍HR + ⧍Hr 298

⧍Hr 298 = ⧍HP - ⧍HR

⧍Hr Rx = {-96360+ (-217570) } - (-78400) = -235530 KJ

⧍Hr298 = -235530 KJ
 54

4. Cooler

C-01
Panas Reaktan Panas Produk

Fungsi : Mendinginkan produk keluaran reaktor

T In = 351 K

T Out = 302 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,42E+10 -7,79E+09
H2O 2 -1,11E+03 -2,23E+03
H2SO4 27,41 1,61E+05 4,41E+06
C6H5OH 26,86 -6,30E+02 -1,69E+04
CH3COCH3 26,86 -2,43E+03 -6,53E+04

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -7,46E+07 -4,10E+07
H2O 2 -5,30E+00 -1,06E+01
H2SO4 27,41 1,32E+03 3,63E+04
C6H5OH 26,86 -1,92E+00 -5,17E+01
CH3COCH3 26,86 -1,18E+01 -3,16E+02
 55

5. Netralizer

N-01
Panas Reaktan Panas Produk

Fungsi : Menetralkan produk agar tidak dalam keadaan asam

T In = 302 K

T Out = 302 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -7,46E+07 -4,10E+07
H2O 2 -5,30E+00 -1,06E+01
H2SO4 27,41 1,32E+03 3,63E+04
C6H5OH 26,86 -1,92E+00 -5,17E+01
CH3COCH3 26,86 -1,18E+01 -3,16E+02

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -7,46E+07 -4,10E+07
H2O 29,41 -5,30E+00 -1,56E+02
C6H5OH 26,86 -1,92E+00 -5,17E+01
CH3COCH3 26,86 -1,18E+01 -3,16E+02
 56

6. Decanter

DC-01
Panas Reaktan Panas Produk

Fungsi : Memisahkan Na2SO4 dari produk

T In = 302 K

T Out = 302 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -7,46E+07 -4,10E+07
H2O 29,41 -5,30E+00 -1,56E+02
C6H5OH 26,86 -1,92E+00 -5,17E+01
CH3COCH3 26,86 -1,18E+01 -3,16E+02

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -7,46E+07 -4,10E+07
H2O 29,41 -5,30E+00 -1,56E+02
C6H5OH 26,86 -1,92E+00 -5,17E+01
CH3COCH3 26,86 -1,18E+01 -3,16E+02
 57

7. Heater-03

HE-03
Panas Reaktan Panas Produk

Fungsi : Menaikan suhu produk sebelum masuk ke Menara Destiasi-01

T In = 302 K

T Out = 353 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -7,46E+07 -4,10E+07
H2O 29,41 -5,30E+00 -1,56E+02
C6H5OH 26,86 -1,92E+00 -5,17E+01
CH3COCH3 26,86 -1,18E+01 -3,16E+02

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,53E+10 -8,42E+09
H2O 29,41 -1,21E+03 -3,55E+04
C6H5OH 26,86 -6,91E+02 -1,86E+04
CH3COCH3 26,86 -2,63E+03 -7,08E+04
 58

8. Menara Destilasi-01

MD-01
Panas Reaktan Panas Produk

Fungsi : Memisahka CH3COCH3 dari produk

T In = 353 K

T Out = 353 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,53E+10 -8,42E+09
H2O 29,41 -1,21E+03 -3,55E+04
C6H5OH 26,86 -6,91E+02 -1,86E+04
CH3COCH3 26,86 -2,63E+03 -7,08E+04

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,53E+10 -8,42E+09
H2O 29,41 -1,21E+03 -3,55E+04
C6H5OH 26,86 -6,91E+02 -1,86E+04
CH3COCH3 26,86 -2,63E+03 -7,08E+04
 59

9. Heater-04

HE-04
Panas Reaktan Panas Produk

Fungsi : Menaikan suhu produk sebelum masuk ke Menara Destiasi-02

T In = 353 K

T Out = 433 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,53E+10 -8,42E+09
H2O 29,41 -1,21E+03 -3,55E+04
C6H5OH 26,86 -6,91E+02 -1,86E+04

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,04E+11 -5,69E+10
H2O 29,41 -9,23E+03 -2,71E+05
C6H5OH 26,86 -7,26E+03 -1,95E+05
 60

10. Menara Desilasi-02

MD-02
Panas Reaktan Panas Produk

Fungsi : Memurnikan produk

T In = 433K

T Out = 433 K

T ref = 298 K

Neraca Panas Komponen

H = M × ∫Cp × ΔT

= M × [(A + BT1 + CT12) – (A + BT2 + CT22 ) × (T1 – T2)

INPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,04E+11 -5,69E+10
H2O 29,41 -9,23E+03 -2,71E+05
C6H5OH 26,86 -7,26E+03 -1,95E+05

OUTPUT

Komponen n (kmol/jam) ∫Cp.ΔT H = n.∫Cp.ΔT

C6H5(CH3)2COOH 0,55 -1,04E+11 -5,69E+10
H2O 29,41 -9,23E+03 -2,71E+05
C6H5OH 26,86 -7,26E+03 -1,95E+05
 61

BIODATA PENULIS

Nama : Rayhan Ramadhan Hidayanto

NPM : 2021710450067

Tempat, Tanggal Lahir : Jakarta, 4 Desember 2000

Jenis Kelamin : Laki-laki

Status : Belum Menikah

Pekerjaan : Karyawan Swasta / Mahasiswa

Alamat : Pal Sigunung RT 001/002 Mekarsari,

Cimanggis, Depok 16952

Telp/Hp : 081905874471

Motto : Life’s too mysterious to take it too seriously.

Riwayat Pendidikan

1. SMK Analisis Kimia Tunas Harapan Jakarta, 2019

2. SMP Negeri 91 Jakarta, 2016
3. SD Negeri Pekayon 06 Jakarta, 2013

Jakarta, 03 November 2024

(Rayhan Ramadhan Hidayanto)

 62

BIODATA PENULIS

Nama : Layla Qadarisa

NPM : 2021710450068

Tempat, Tanggal Lahir : Jakarta. 25 Desember 2000

Jenis Kelamin : Perempuan

Status : Belum Menikah

Pekerjaan : Karyawan Swasta / Mahasiswi

Alamat : Jl. Cibubur VII No. 43A, Cibubur, Ciracas, Jakarta

Timur 13720

Telp/Hp : 085780351033
Motto : Keep going, we're still too young to stop.
Riwayat Pendidikan

1. SMK Analisis Kimia Tunas Harapan Jakarta, 2019

2. SMP Negeri 258 Jakarta, 2016
3. SD Negeri 02 Cibubur, 2013

Jakarta, 03 November 2024

(Layla Qadarisa)