FIITJEE CPT-2 Exam Instructions and Format
FIITJEE CPT-2 Exam Instructions and Format
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
BATCH – XII TH
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-2
SECTION – I : PHYSICS
PART – A: (Single Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
0I
( )
Z
(C) 2 − 3 (D) zero A
2
I0 I1
2. A circular loop wire with current I1 = and a V shaped wire with current
r
I2 are arranged in a plane as shown in diagram. If magnetic field at O is 37 o
O 37o
zero, value of I2 is I2
a
13aI0 12aI0 a
(A) (B)
35r 17r
aI0 12aI0
(C) (D)
r 35r
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-3
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-4
1
6. A ring of radius m and of negligible mass is rigidly fixed at C by non B
B
conducting rigid spokes on non conducting rod of length 5 m and mass 2
kg. Rod being axis of ring and current of 10 A is flowing in the ring as 1A
C
shown in the figure. Rod resting against smooth vertical wall while its
other end is on rough horizontal surface. Whole arrangement is placed in
uniform vertical magnetic field of 2T. Given AC = 4m, g = 10 m/s 2. 37
2x A
Minimum value of so that whole system remain in equilibrium is .
15
Find x.
10 13
(A) (B)
15 15
14 16
(C) (D)
15 15
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-5
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
10. Two infinitely long straight wires lie in the xy-plane along the lines x = ±R. The wire located
at x = +R carries a constant current I1 and the wire located at x = –R carries a constant current I2. A
circular loop of radius R is suspended with its centre at (0, 0, 3R ) and in a plane parallel to the xy-
plane. This loop carries a constant current I in the clockwise direction as seen from above the loop.
The current in the wire is taken to be positive if it is in the + ĵ direction. Which of the following
statements regarding the magnetic field B is (are) true?
(A) If I1 = I2 , then B cannot be equal to zero at the origin (0, 0, 0)
(B) If I1 0, and I2 0, then B can be equal to zero at the origin (0, 0, 0)
(C) If I1 0, and I2 0, then B can be equal to zero at the origin (0, 0, 0)
I
(D) If I1 = I2 , then the z-component of the magnetic field at the centre of the loop is − 0
2R
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-6
12. When a current–carrying coil is placed in a uniform magnetic field with its magnetic moment anti–
parallel to the field.
(A) Torque on it is maximum (B) Torque on it is zero
(C) Potential energy is maximum (D) Dipole is in unstable equilibrium.
13. Thin insulated wire forms a plane spiral consisting of a large number N of
closely packed in turns through which a DC current I is flowing. The radii of
internal and external loops are a and b respectively. Choose the correct
+
option(s).
0IN b
(A) The magnetic field at the centre of the spiral is n
2(b − a) a
0IN b I
(B) The magnetic field at the centre of the spiral is n
(b − a) a
IN 2
(C) Magnetic moment of the spiral is (b + a2 + ab)
2
IN 2
(D) Magnetic moment of the spiral is (b + a2 + ab)
3
14. A particle of mass M and positive charge Q, moving with a constant velocity u1 = 4ims ˆ −1 , enters a
region of uniform static magnetic field normal to the x-y plane. The region of the magnetic field
extends from x = 0 to x = L for all values of y. After passing through this region, the particle emerges
( )
on the other side after 10 milliseconds with a velocity u2 = 2 3iˆ + ˆj m/s−1. The correct statement(s)
is (are)
(A) The direction of the magnetic field is −z direction.
(B) The direction of the magnetic field is +z direction.
50M
(C) The magnitude of the magnetic field units.
3Q
100M
(D) The magnitude of the magnetic field is units.
3Q
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-7
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
An infinite cylindrical wire of radius R and having current density J(r) = J 0[1 −(r/R)]. y
Then find the answer of following questions.
R r R r
(C) B (D) B
R r R r
A 100 turn closely wound circular coil of radius 10 cm carries a current of 3.2 A. A uniform horizontal magnetic
field of strength 2T is turned on. The axis of the coil is initially in the direction of the field. The coil rotates
through an angle of 90º under the influence of the magnetic field. The moment of inertia of the coil is 0.1 kg
m2.
18. What is the angular speed acquired by the coil when it has rotated by 90º?
(A) 20 s−1 (B) 30 s−1
−1
(C) 40 s (D) 60 s−1
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-8
SECTION – II : CHEMISTRY
PART – A: (Single Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. Ph
() 2
⎯⎯⎯⎯⎯ →P
1 NH OH
( 2) PCl ,H+
5
O
H
P will be:
(A) Ph (B) Ph
O
HN
HN
O
(C) (D) O
NH
O
O
2. Which of the following is the correct option of reagent for the given conversion?
COOH
CH4
(A) Br2 / h, MgCl , Br2 / h, HCOOH
(B) Cl2 / h, MgCl , Br2 / h, KCN / H3O+
(C) Br2 / h, MgCl , Br2 / h, NaNH2 ,HCN,H3O+
(D) Cl2 / h, CH3MgBr, Br2 / h, CH3 COOH
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-9
Ph CH3 D CH3
(C) D CH2 (D) H H
Ph
H H Ph CH3
4. O
H2C C NH2 (IV ) O
HC C6H4 NH C CH3
(III)
H2C NH CH CH2 NH2 (I)
(II) CH3
Arrange the above mentioned nitrogen atoms of the compound in decreasing order of basic nature?
(A) I > II > IV > III (B) II > I > IV > III
(C) II > I > III > IV (D) I > IV > III > II
pK a = 9.67
(A) 3.22 (B) 6.96
(C) 5.93 (D) 8.05
7. Which of the following combinations of terms best describes the polymerization of a diisocyanate
(OCN-R-NCO) and a diol to form a polyurethane?
(A) chain growth condensation (B) step growth condensation
(C) chain growth addition (D) step growth addition
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-10
8. Which of the following produce 1o amine after undergoing a rearrangement reaction followed by
hydrolysis:
(A) O (B) O H
R C NH2 R C N
OH
(C) O (D) R - CN
R C N3
9. () i LDA
NC CN ⎯⎯⎯⎯⎯⎯ →?
(ii) NaOH,H O 2
(iii)
LDA is lithium diisopropylamide. Select the incorrect statements regarding the final product:
(A) It gives iodoform test (B) It undergoes Cannizzaro’s reaction
(C) It is a lactone (D) It is a ketone
10. Which of the following will not yield the expected product as major product?
O O CH3
O O CH3
(A) 2 (i)NaOC
⎯⎯⎯⎯⎯
H
2 5⎯→
(ii)HCl CH3 O
CH3
O
H3C H3C O O
(i)NaOC2H5
CH3 ⎯⎯⎯⎯⎯
(B) O
(ii)HCl
⎯
→ O
CH3 H3C CH3
H3C CH3
O
O
O O
|| ||
(C) (i)NaOC2H5
C2H5O C(CH2 )4 C OC2H5 ⎯⎯⎯⎯⎯⎯ → O
(ii)HCl
CH3
O O O
|| || O
(i)NaOC2H5
(D) C2H5O C(CH2 )2 C OC2H5 ⎯⎯⎯⎯⎯⎯ → CH3
(ii)HCl
O
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-11
11. C2H5Br
(Y)
N O ⎯⎯⎯
Base
→ ( X)
H
(Z)
AgNO3 / C2H5Br
Select the correct statement(s) regarding X, Y and Z:
(A) (X) is aromatic in nature (B)
(Y) is
N O
CH2CH3
(C) (D) (X) is non-aromatic
(Z) is
N OC 2H5
14. Which of the following compounds react with benzene sulphonyl chloride in aqueous potassium
hydroxide to give a clear solution which on acidification gives a precipitate?
(A) Me (B) NH
Me
N
Me
(C) NH2 (D) NH2
Me
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-12
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Chemist A
Chemist A suggested that the best method for preparing an ester involves the reaction of a carboxylic acid
with an alcohol, as shown in Reaction A.
O O
H2 SO4
CH3 COH + HOCH2CH3 CH3 COCH2CH3 + H2O
Reaction A
O OH OH OH
CH3 COH H+
CH3 COH
CH3 CH2 OH
CH3 COH CH3 COH + H
HOCH2CH3 O CH2CH3
O OH OH
O CH2CH3
Chemist B
Chemist B pointed out the Reaction A often gives low yields because the equilibrium constant is relatively low.
As an alternative, Chemist B suggested that a higher yielding method to synthesize esters involves the
reaction of an acid chloride (such as acetyl chloride) with an alcohol, as shown in Reaction B.
O O O
Et3N
CH3 COH ⎯⎯⎯→
SOCl2
CH3 CCl ⎯⎯⎯⎯⎯
→ CH3 COCH2CH3 + HCl
HOCH2 CH3
Reaction B
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-13
16. Chemist A separated the three organic compounds in Reaction A on a thin-layer chromatography
plate that separated the compounds according to polarity. If the least polar compound travelled the
farthest up the plate, what was the order of the distance travelled by the three compounds?
(A) Carboxylic acid < alcohol < ester (B) Ester < alcohol < carboxylic acid
(C) Alcohol < carboxylic acid < ester (D) Ester < carboxylic acid < alcohol
An -amino acids ‘A’ has molecular formula C3H7NO3. ‘A’ on treatment with methanol in presence of HCl
yields ‘B’ [C4H10NO3Cl]. ‘B’ on further treatment with PCl5 yields ‘C’ [C4H9NO2Cl2] which on acidic hydrolysis
yields ‘D’ [C3H6NO2Cl]. ‘D’ on reduction with Na(Hg) in dilute acidic medium yields alanine.
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-14
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
/2
( 2cosec x )
17
1. The following integral dx is equal to
/4
(
log 1+ 2 ) (
log 1+ 2 )
( ) (e )
16 17
−u
(A) 2 e +e
u
du (B) u
+ e −u du
0 0
(
log 1+ 2 ) (
log 1+ 2 )
(e ) ( )
17 16
−u
(C) u
−e du (D) 2 eu − e−u du
0 0
sin( 2n − 1)x
2.
0
sin x
dx, (n N), is equal to
(A) 1 (B)
(C) 2 (D) /2
x −1 dx 2
3. Let f ( x ) =
x +1 x +x +x
3 2
such that f (1) =
3
. Then which of the following is true
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-15
cos x + 3
4. 1 + 4 sin x + + 4 sin
dx , is
x +
2
3 3
cos x sec x
(A) +c (B) +c
1 + 2sin x + 1 + 2sin x +
3 3
sin x 1
(C) +c (D) tan−1 1 + 2 sin x + + c
2 3
1 + 2sin x +
3
f f f ...... f ( x )
( )
dx
1/ n
5. Let f ( x ) = a − xn and g ( x ) = . Then equals
2m times
( g( x ))
n
(1+ (g( x )) ) n 1/ n
n−1
n −1
(A)
n
n − 1
1
1+ n
x
n
+C (B)
1
1− n
(
1 + x −n ) n +C
n +1 n
−1
(C)
1
1+ n
(
1 + xn ) n +C (D)
n
(
1 − xn ) n +1 +C
2n + 1 1 1 2n + 1
g' g − g' g
6. Let g(x) = ef(x) ; g(x + 1) = xg(x), then 2 2 2 2 , where n N, is
2n + 1 1
g g
2 2
1 1 1 1 1 1
(A) 2 1 + + + ..... + (B) 2 1 + + + ..... +
2 3 n 3 5 2n − 1
(C) 0 (D) none of these
2
7. f ( x ) + f ( x + 1/ 2) = 1 such that f ( x ) is non negative continuous function then find f ( x ) dx
0
1
(A) (B) 1
2
(C) 2 (D) data insufficient
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-16
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
3
8. Let f : − , → R be a continuous function such that f ( 0 ) = 1 and
2 2 f ( t ) dt = 0 . Then which of the
0
following statements is(are) TRUE?
(A) The equation f(x) – 3 cos 3x = 0 has at least one solution in 0,
3
6
(B) The equation f(x) – 3 sin 3x = − has at least one solution in 0,
3
x
x f ( t ) dt
(C) lim 0
2
= −1
x →0
1 − ex
x
sin x f ( t ) dt
(D) lim 0
= −1
x →0 x2
(C)
(x 3
)(
− 1 x3 + 1 )+x 6
( 6coslog x + sinlog x ) + c
12 37
(D)
(x 3
)(
− 1 x3 + 1 )+x 6
( 6coslog x + sinlog x ) + c
12 74
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-17
(1 + x 2 )( 2 + x 2 )
10. ( x cos x + sin x ) 4
dx equals
x
11. Suppose that f(x) is a differentiable invertible function with f(x) 0 and h(x) =
f ( t ) dt . Given that
1
f(1) = f(1) = 1 and g(x) is inverse of f(x). Let G(x) = x 2g(x) – xh(g(x)) x R. Which of the following
are correct
(A) G(1) = 2 (B) G(1) = 3
(C) G(1) = 2 (D) G(1) = 3
x 1
12. If
x − x − 2 dx = f(x).g(x) where x and{x} are integral and fractional parts of x, respectively
0
{x}
(A) f(x) = (B) g(x) = ( {x} − 1)
2
x
(C) f(x) = (D) g(x) = ([x] − 1)
2
13. Let f(x) = 5x tan x + 8 sin(tan x) + 5 ln(cos x), then in the interval − , 0
4
(A) f(x) is increasing (B) f(x) has a point of local maxima
(C) f(x) has a root (D) f(x) is always negative
14. Let f(x) = [Link], x − , then
2 2
(A) f(x) has a point of local minima at x =
4
(B) f(x) has a point of local maxima in the interval − , 0
4
(C) f(x) has exactly two points of local maxima/minima in − ,
2 2
(D) f(x) has no root in − ,
2 2
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-18
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Let n be a positive integer such that In = xn a2 − x 2 dx , then answer the following questions:
x a2 − x 2 dx
4
0
15. The value of the expression a
is equal to
x a − x dx
2 2 2
a 2
3a2
(A) (B)
6 2
3a2 a2
(C) (D)
4 2
−xn−1 ( a2 − x 2 )
3/2
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-19
x2 − ax + 1
Consider the function f : (−, ) → (−, ) defined by f(x) = , 0 < a < 2.
x2 + ax + 1
ex
f (t)
18. Let g(x) = 1+ t
0
2
dt
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-20
ANSWERS
PHYSICS (SECTION –I)
1. C 2. D 3. C 4. B
5. A 6. C 7. B 8. B, C
9. B, C 10. A, B, D 11. A, B, C 12. B, C, D
13. A, D 14. A, C 15. B 16. D
17. B 18. A
1. A 2. B 3. A 4. B
5. A 6. B 7. D 8. A, B, C
9. A, B, C 10. B, D 11. A, B, C 12. C, D
13. A, B, C, D 14. C, D 15. D 16. A
17. C 18. A
1. A 2. B 3. C 4. C
5. B 6. B 7. B 8. A, B, C
17. A 18. B
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-21
SOLUTIONS
PHYSICS (SECTION –I)
1. C
If the loop is completed by wire of length 2R along y-axis i.e. the diametre of the semicircle
→ →
then B.d = 0I [Ampere’s law]. And due to the diameter wire only,
→ 0I 0I 30I
B at all point on the circle 3x2 + 3z2 = R2, is sin 1 + sin 2 = sin60o + sin60o =
4r R 4R
4
3
→ → 30I R 3
B.d (due to diameter wire only) =
4R
2
3
=
2
0I
→ → 30I (
2 − 3 0I )
Hence, B.d due to semicircle = 0I − 2
=
2
2. D
0I1 I1
B1 =
2r r
2 0I2 4 3 350I2 o
37 53 o
o o
B2 = + = 37
4a 3 5 5 24a 37
4 I2
5 5
0I0 350I2 53o
=
2r 24ra
12aI0
I2 =
35r
3. C
0 i2
mg = i1 . . . (1)
2d
By displacing a small distance x in vertical plane
0 i1i2
− mg = ma
2 ( d + x )
−1
0 i1i2 x
1 + − mg = ma
2 d d
ii
− 0 12 2 x = a
2 md
2md2
T = 2
0i1i2
4. B
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-22
x2
tan =
g
sin R sin 2
=
cos g
1
cos = = 60
2
qx 2
M= = 3 10−4
2
5. A
mv 02
ev 0B =
R
mv 0
B=
eR
a2 + R2 = b − R
b2 − a2
R=
2b
2bmv 0
B= 2
(b − a2 )e
6. C
Area of ring = r2 = 1m2 N2
B
Torque of ring = iABsin = 1 1 2 sin (90 + 37) B
4
20 = 16 N-m (clockwise)
5 1A
C
N2 = f = N1 N1
N1 = 20 N …(i) 20N
N2 = 20 …(ii) 37
Taking torque about A A f
5
N25 sin 37 − 20 cos37 − 16 = 0
2
20 3 − 40 − 16 = 0
14
=
15
7. B
0I
. (IRd )
I
dF =
2R sin I
dF
Total force F = dF sin
d
2
I2 R
= 0 d = 0I2 O
0 2
8. B, C
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-23
9. B, C
Consider the forces and hence the radii of curvature of the
particles trajectory at various stages. The path executed by
the particle will look as shown.
10. A, B, D
(A) If I1 = I2, magnetic field due to infinite wires is z
equal to zero . So there must be a non–zero
magnetic field at O due to the current C
carrying loop.
I
(B) If I1 0 & I2 0 , magnetic field due to
straight lines are along positive z–axis and
due to loop it is along negative z–axis. I2
I1
(C) If I1 0 & I2 0 magnetic field due to x
O
straight wires are along negative z–axis and
due to the loop it is also along negative z–
axis.
(D) BC = 0 −kˆ
( along z axis )
( )
I
2R
11. A, B, C
FR = 2 2iBa . 2iBa
2iBa
12. B, C, D
= M B and U = −M.B
here M and B are anti–parallel
= O and U = +MB (maximum)
13. A, D
N
dN = dr
b−a
b
I N 0IN b
So, B0 = 0 dr = n
a
2r b − a 2(b − a) a
N IN(b3 − a3 ) IN 2
M = Ir 2 dr = = (b + a2 + ab)
b−a 3(b − a) 3
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-24
14. A, C
So magnetic field is along −ve, z-direction.
Time taken in the magnetic field = 10 10 −3 M
y
2 ( 3iˆ + ˆj )
=
6QB 30
30
M 1000M
B= −3
=
60 10 Q 60Q
50M
=
3Q
4iˆ x
15. B
16. D
15-16. Current inside as a function of r
x
I = (2[Link]) J0 1 −
R
r
x2
dI = 2J0 x − dx
0
R
r 2 r 3
I = 2J0 − 0
2 3R
B.d = 0i
r2 r3
B.2r = 2J0 − 0
2 3R
r r2
B = J0 −
2 3R
For max B
dB 1 2r
= J0 − =0
dr 2 3R
r = (3R/4)
3 R 9 R2 3
Bmax = 0J0 − = J R 0
4 2 16 3R 16 0
17. B
18. A
0NI
17-18. From B =
2R
Here, N = 100; I = 3.2 A, and R = 0.1 m. Hence
4 10−7 102 3.2 4 10−5 10
B= = (using 3.2 = 10) = 2 10−3 T
2 10−1 2 101
The direction is given by the right-hand thumb rule.
The magnetic moment is given by Equation (4.30),
m = NIA = NIr2 = 100 3.2 3.14 10−2 = 10Am2
The direction is once again given by the right hand thumb rule.
= m B = mBsin
Initially, = 0. Thus initial torque t = 0. Finally, = /2 (or 90).
Thus, final torque f = mB = 10 2 = 20 N m
From Newton’s second law,
d
I = mBsin
dt
Where I is the moment of inertia of the coil. From chain rule,
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website: [Link].
C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-25
d d d d
= =
dt d dt d
Using this,
Id = mB sin d
Integrating from = 0 to = /2
f /2
I d = mB
0
sin d
0
2f
I = −mBcos |0 /2 = mB
2
1/2 1/2
2mB 2 20
f = = = 20 s−1
I 10−1
1. Beckmann rearrangement
2. Br C N COOH
MgCl +
Cl2 /h
CH4 ⎯⎯⎯→ CH3 Cl ⎯⎯⎯⎯
→ ⎯⎯⎯→
Br2 /h
⎯⎯⎯
KCN
→ ⎯⎯⎯
H3 O
→
N O O
N
9. NC CN ⎯⎯⎯→
LDA
⎯⎯→ ⎯⎯⎯⎯⎯
→Hydrolysis
⎯⎯→
NC NC COOH
10. For Claisen condensation, ester should have 2 hydrogen, in ‘D’ option ring is strained
11.
⎯⎯⎯
Base
→ ⎯⎯⎯⎯
C2H5Br
→
Ag+
N O N O N OCH 2CH3
N O
H ( X)
C2H5Br
N O
CH2CH3
12. Teflon is polytetrafluoroethene, terylene is a polyester while nylon-6,6 and nylon-6 are polyamides.
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website: [Link].
C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-26
13.
C O O H C O O CH3
C C
R CH3
C C
14. Primary amines react with benzene sulphonyl chloride to form N-substituted benzene sulphonamide
which react with aqueous KOH to form a soluble salt. The solution on acidification give a precipitate.
O O
R − NH2 + Cl S ⎯⎯→ R NH S
O O
O O
K
⎯⎯⎯
→ R N
KOH
S ⎯⎯⎯
→ R
HCl
NH S
O O (ppt.)
NH3Cl O NH2
C H C C O CH3 D H C COOH
H2 C Cl H2C Cl
1. A
2
( 2 cosec x )
17
dx
4
Let eu + e–u = 2 cosec x, x =
4
u = ln 1 + 2 , x =
2
(
u=0 )
eu − e−u
cosec x + cot x = eu and cosec x – cot x = e–u cot x =
2
(eu – e–u) du = –2 cosec x cot x dx
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-27
0
(e u
− e−u )
(e )
17
−u
− u
+e du
ln(1+ 2 )
2 cosec x cot x
0 (
ln 1+ 2 )
( ) ( )
16 16
= −2 eu + e−u du = 2 eu + e−u du
(
ln 1+ 2 ) 0
2. B
sin( 2n − 1)x
Let I =
0
sin x
dx, n N
sin 2nx cos x − cos 2nx sin x
=
0
sin x
dx
sin 2nx cos x
=
0
sin x
− − cos 2nx dx
sin 2nx
Since = 2[ cosx + cos3x + ....cos(2n -1)x ]
sin x
I= 2 ( cos x + cos3x + cos5x + .... + cos ( 2n − 1) x ) cos x − cos2nx dx
0
= (1 + cos2x + (cos2x + cos 4x ) + .... + cos ( 2n − 2 ) x ) + cos2nx − cos2nx dx
0
sin2x sin 4x sin ( 2n − 2 ) x
= x + 2 + + .... +
2 ( 2n − 2 ) 0
4
= + 2(0 + 0 + ...) = .
3. C
1
Put x + =t
x
4. C
cos x + 3 cos x + 3
I=
2
dx =
(1+ sin x + 3 cos x )
2
dx . Dividing by sin2 x we get
1 + 2sin x +
3
cosec x cot x + 3 cosec 2 x 1 sin x
I= ( cosec x + 1 + 3 cot x )
2
dx =
cosec x + 1 + 3 cot x
+c =
1 + 2sin x +
+c
3
5. B
( )
1/ n
We have f ( x ) = a − xn so that
1/ n
( ( ))
n
(
) ( )
1/ n 1/ n 1/ n
f f ( x ) = f a − xn = a − a − x
n
= a − a − xn
g ( x ) = f f .....f ( x ) = x
2m times
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-28
dx dx dx dt
= x = x =− nt (using t = 1 + x−n)
(1+ (g( x )) ) (1+ x ) (1 + x )
1/ n 1/ n
n 1/ n 1/ n
( g( x ))
n n n n+1 −n
1 t −1/ n+1
1
( )
1 1−
=− +c = 1 + x −n n +c
n 1 1 − n
− + 1
n
6. B
ln g(x + 1) = ln x + ln g(x)
g'(x + 1) g' ( x ) 1
− =
g(x + 1) g ( x ) x
2n + 1 1 1 2n + 1
g' g − g' g
2 2 2 2 = 2 1 + 1 + 1 + ..... + 1
2n + 1 1 3 5 2n − 1
g
g
2 2
7. B
f ( x ) + f ( x + 1/ 2) = 1
f ( x + 1) + f ( x + 1/ 2) = 1
f ( x ) = f ( x + 1) f(x) is periodic with period 1
1/ 2 1
0
2 f ( x ) dx + f ( x ) dx
1/ 2
1
x = t + in second integral
2
1/ 2 1/ 2
0
0
2 f ( x ) dx + f ( t + 1/ 2 ) dt =1.
8. A, B, C
(A) Let g(x) = f(x) – 3 cos3x
/3 /3 /3 /3
0
g ( x )dx = ( f ( x ) − 3cos3x )dx = f ( x ) dx − 3cos3x dx = 0
0 0 0
f ( t ) dt f (x)
(C) lim 0 = lim = f (0) = 1
x →0 x x →0 1
x x
x f ( t ) dt − f ( t )
x2
lim 0
= lim 0
= −1
x →0 1 − ex
x
2
x2
2
x →0 x (e x2
−1 )
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-29
x
f (t)
sin x 0
(D) lim =1
x →0 x x
9. A, D
x cos log xdx
5 2
log x 1 + coslog x
x dx = x5
5
cos2 dx
2 2
1 1
= x5 dx + x5 coslogxdx
2 2
x 6 1 6t
12 2
= + e cos tdt, where t = log x
10. B, C
x cos x + sin x = 1 + x2 cos ( x − cot −1 x )
2 + x2
I= 1+ x 2
sec 4 ( x − cot −1 x ) dx
dt 2 + x 2
Put t = x – cot–1 x = =
dx 1 + x 2
tan3 ( x − cot −1 x )
I = tan ( x − cot −1 x ) + +c
3
ALITER
Put x = tan t dx = sec2 t dt
x cos x + sin x = sec sin (x + )
(1 + x2 )( 2 + x2 ) sec 2 t (1 + sec 2 t )
( x cos x + sin x ) 4
dx = sec 4
t sin x + t )
4(
sec 2 tdt
1 + sec 2 t
sin cosec u du (u = tant + t )
4
= 4(
dt =
tant + t )
( cot u)3 3
1 1 − x tan x 1 − x tan x
= − − cot u + c = − − +c
3 3 x + tan x x + tan x
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-30
11. A, D
h(x) = f(x)
h(x) = f(x)
h(1) = 0, f(1) = f(1) = h(1) = h(1) = 1 = g(1)
f(g(x)) = x
f(g(x)) . g(x) = 1
f(g(1)) . g(1) = 1 f(1) . g(1) = 1 g(1) = 1
G(x) = x2g(x) – xh(g(x))
G(x) = 2x g(x) + x2g(x) – h(g(x)) – xh(g(x)) . g(x)
= 2xg(x) + x2g(x) – h(g(x)) – x2g(x) = 2xg(x) – h(g(x))
G(x) = 2g(x) + 2xg(x) – h(g(x)) . g(x) = 2g(x) + xg(x)
G(1) = 2g(1) – h(g(1)) = 2
G(1) = 2g(1) + g(1) = 3.
12. A, B
x+x x x+x
1 1 1
I=
x −
2
dx =
x −
2
dx + x − 2 dx
0 0 x
1 x 1 x
1 1 1 1
0
= x x − dx +
2
0
0
x − 2 dx = x x − 2 dx +
x − 2 dx
0
x
x (x − 1) x
1
x2 x x2 x
= x − + −
2 2 2 2
=0+
2
=
2
(x − 1)
0 0
13. A, D
f(x) = 5x tan x + 8 sin(tan x) + 5 ln (cos x), x − , 0 f(x) = sec2 x·(5x + 8 cos (tan x))
4
Now let g(x) = 5x + 8 cos(tan x). So, g(x) = 5 – 8 sin(tan x) sec2 x > 0 in − , 0
4
5 5 1 16 − 5
So, g(x) is increasing. So, for x > − , g(x) > g − = − + 8cos1 − + 8 = 0
4 4 4 4 2 4
So, f(x) > 0. So, f(x) is increasing in − , 0 . Also at x = 0, LHL = 0. So, f(x) < 0 x − , 0 .
4 4
14. A, B, C
f(x) = cos2 x etan x f '(x) = etan x (1− sin2x) f "(x) = etan x (−2cos2x) + etan x sec2 x (1− sin2x)
tan2 x − 1
f "(x) = etan x 2 2
+ ( sec 2 x − 2 tan x ) = f(x)(tanx − 1) ( tan3 x − tan2 x + 3tanx + 1)
1 + tan x
Now, let g(x) = tan3 x − tan2 x + 3tanx + 1 g'(x) = (3tan2 x − 2tanx + 3 ) sec 2 x 0
So, g(x) is increasing. Also, g − g(0) 0 . So, g(x) has exactly one root in − ,
4 2 2
So, f(x) has exactly two roots in − , . At x = , f(x) has a local minima.
2 2 4
15. D
a
3( 2 3/2
−x a − x2 )
a a a
3 2 2 a2
x4 a − x dx = + a2
x a − x2 dx = x a2 − x 2 dx .
2 2 2
3 0 6 2
0 0 0
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C M T E S T - 2 ( X I I t h ) P h a s e - 4 ( P a p e r - 2 ) -PCM(000000.0)-31
16. C
x x (x )
n−1
In = n
a2 − x 2 dx = a2 − x 2 dx
1 3/2 n −1
= xn−1 − ( a2 − x2 ) + xn−2 ( a2 − x2 ) a2 − x2 dx
3 3
n −1 2 n −1
= − xn−1 ( a2 − x2 )
1 3/2
+ a In−2 − In
3 3 3
n − 1 a2 ( n − 1)
In = − x ( a − x )
1 n−1 2 2 3/2
1 + + In−2 .
3 3 3
17. A
4ax(x2 + ax + 1)2 − 4ax(x 2 − 1)(2x + a)(x 2 + ax + 1)
f (x) =
(x2 + ax + 1)4
4a −4a
f (1) = f ( −1) =
(2 + a)2 (2 − a)2
(2 + a)2 f(1) + (2 − a)2 f(−1) = 0.
18. B
f (e x )e x
g(x) =
1 + e2x
Hence positive for (0, ) and negative for (−, 0).
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