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Wta - 11 Coc3 Thermochemistry

The document is a model test paper for JEE Advanced 2019 from Sri Chaitanya IIT Academy, covering subjects like Physics, Chemistry, and Mathematics. It includes various problems related to center of mass, gravitation, thermochemistry, and straight lines, along with specific questions for students to solve. The test is scheduled for February 6, 2025, and is designed for students preparing for competitive exams in India.

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0% found this document useful (0 votes)
27 views15 pages

Wta - 11 Coc3 Thermochemistry

The document is a model test paper for JEE Advanced 2019 from Sri Chaitanya IIT Academy, covering subjects like Physics, Chemistry, and Mathematics. It includes various problems related to center of mass, gravitation, thermochemistry, and straight lines, along with specific questions for students to solve. The test is scheduled for February 6, 2025, and is designed for students preparing for competitive exams in India.

Uploaded by

abcxyz6530
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SRI CHAITANYA IIT ACADEMY - INDIA.

A.P, TELANGNA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI


A right Choice for the Real Aspirant
JEE ADVANCED 2019_P1 MODEL
WEEKEND TEST - 11
Sec: CO C3 IPL WTA-11 Date:
06.02.2025
SYLLABUS :
Physics : CENTER OF MASS (60%): Linear momentum and its conservation, Applications,
Misllaneous problems on above concepts frame, reduced mass of two particle
system,
Problems based on C frame, GRAVITATION (40%): Introduction, Newton’s law of
gravitation, Super position principle between point masses, Inertial and
gravitational
mass, relation between g and G, factors effecting the Value of g
Chemistry : Thermochemistry: Types of reactions, Enthalpy of reaction, Factors effecting
Enthalpy of reaction, Enthalpy of formation, Hess law, Enthalpy of formation,
problems, heat of combustion, Enthalpy of bond dissociation, Problems, Enthalpy
of neutralization, Problems, Enthalpy of Phase transition, Lattice enthalpy,
hydration enthalpy, enthalpy of solutions, Integral enthalpy of solution, Integral
enthalpy of dilution, enthalpy of hydrogenation, resonance energy
Mathematics : Straight lines: Definition, slope, Different forms, position of two points w.r.t line,
perpendicular distance, distance between parallel lines, foot of the
JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
perpendicular, image, foot of the perpendicular, image, angle between the
lines.

Name of the Student: ___________________ H.T. NO:

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India

PHYSICS
SECTION - I

1. A boat of mass 40 kg is floating on water. A body of mass 10kg on the boat moves by 8
m
towards the shore. The distance by which the boat moves away the shore is
A) 4 m B) 3 m C) 2 m D) 1.6 m
2. A mud ball at rest explodes into three fragments of
masses in the
Ratio [Link]. The two equal masses move with velocities
2 i垐 5 j  6 k垐a n d  4 i垐 3 j  2 k . Find the velocity of the third
mass.

A) 21 m / s B) 10 m/s

C) 10 m / s D) 5 m /s

3. Consider a system of two particles P and Q of mass m and 4m respectively. If speed of


particles
Q is 1 m/s with respect to center of mass of P and Q, then what will be speed (in m/s) of
particles
P with respect to center of mass of P and Q?
A) 6 m/s B) 3 m/s C) 4 m/s D) 1 m/s
4. You are given total mass M. How do you divide it into two parts so that the gravitational
force
between them at a given separation is maximum
M 3M M 2M M 4M M M
A) , B) , C) , D) ,
4 4 3 3 5 5 2 2
SECTION - II

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India

5. The angular velocity of the earth with which it has to rotate so that acceleration due to
gravity on
6 0 latitude becomes zero.
0

gp gp gp gp
A) 3 B) 4 C) D) 2
R R R R
6. In a double star system, two stars of masses m a n d m separated by a distance d rotate
1 2

their center
of mass. Then their common angular velocity would be
G m1 G m2 G  m1  m2  d
3

A) B) C) D)
d
3
d
3
d
3
G  m1  m2 
7. At the height h above the surface of earth, the value of g : (R is radius of the
earth)
A) Falls to 1% of the value at the surface if h= 9R
B) Falls by 1% of the value at the surface if h= 64 km
C) Falls by 1% of the value at the surface if h= 7R
D) Falls by 1% of the value at the surface if h= 32 km
8. The acceleration due to gravity on moon is only one sixth that on earth.
Ratio of
moon radius  R m  to earth’s radius  R e  should be:
A) 6/1 if both are assumed to have same density B) 1/6 if both are assumed to have
5  9 
same density C) i f e i s g i ven a s 5 / 3 D) i f m i s g i ven a s 3 / 5
18 m 5 e
9. Two blocks of masses m and M are interconnected by an ideal spring of stiffness k. If m
is
pushed with a velocity v 0

A) Velocity of centre of the system


mv 0
M  m;
M m

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
2
M mv 0
B) Kinetic energy of the system M  m  with respect CM is equal to
2M  m
2
M mv 0
C) The maximum work done by the spring is equal 
2M  m
Mm
D) Maximum compression of spring x m ax  v0
M  m k
10. A block of mass 2kg and 1kg are connected by spring of spring constant 100 N/m. 2 kg
is given
a velocity of 15 m/s initially and 1kg is at rest, then

A) maximum velocity of 2kg 15 m/s B) maximum velocity of 1kg 20 m/s


C) minimum velocity of 2kg 5 m/s D) minimum velocity of 1kg 0 m/s
11. A block of mass M has a circular cut with a frictionless surface as shown. The block
rests on the
horizontal frictionless surface of a fixed table. Initially the right edge of the block is at x
= 0, in
a coordinate system fixed to the table. A point mass m is released from rest at the
topmost point
of the path as shown and it slides down. When the mass loses contact with the block,
its position
is x and the velocity is v. At that instant, which of the following options is/are correct?

2 gR
A) The velocity of the point mass m is v 
m
1
M
m
B) The velocity of the block M is V  2 gR
M
mR
C) The position of the point mass is x  2
M m
D) The x component of displacement of the center of mass of the block M is
mR

M m
12. An ideal spring is permanently connected between two blocks of masses M and m.
The blocks-
spring system can move over a smooth horizontal table along a straight line along the
length of
the spring as shown in figure. The blocks are brought nearer to compress the spring
SEC: CO C3 IPL WT - 11 (06.02.2025) Page 5
JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
and then
released. In the subsequent motion,

A) Initially they move in opposite directions with velocities inversely proportional to


their
masses
B) The ratio of their velocities remains constant
C) Linear momentum and energy of the system remain conserved
D) The two block will oscillate about their centre of mass, which remains stationary
SECTION - III

13. A train of mass M is moving on a circular track of radius ‘R’ with constant speed V. The
length
of train is half of the perimeter of the track. The linear momentum of the train will be
 M V /  value of  is (only magnitude)
14. The density of a newly discovered planet is twice that of the earth. The acceleration
due to
gravity at the surface of the planet is equal to that at the surface of the earth. If the
radius of the
earth is R and the radius of the planet is R’. Then what is the value of R/R’?

15. If the radius of the earth were to shrink by 2% its mass remaining the same, by how
much
percentage would the acceleration due to gravity on the earth’s surface would increase?

16. Four similar particles of mass ‘m’ are orbiting in a circle of radius ‘r’ in
the
same angular direction symmetrically because of their mutual
gravitational
Gm  1 1
attractive force. Velocity of a particle is given by    .
r  2 n

Then ‘n’ is equal to


17. Binary starts of comparable masses rotate under the influence of each other’s gravity
at a
1

 G 3
distance 2  2  . where  is the angular velocity of each star about centre of mass of
 

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
the
system. If difference between the masses of two stars is 6 units, find the ratio of the
masses of
bigger to smaller star.
18. A man of mass 80kg is riding on a small cart of mass 40kg which is rolling along a
level floor at
speed of 2 m/s. He is running on the car so that his velocity relative to the cart is 3m/s
in the
direction opposite to the motion of the cart. What is the speed of the center of mass of
the
system?

CHEMISTRY
SECTION - I

19. The bond dissociation energies for C l2 , I 2 , and I C l are 242.3, 151 and 2 1 1 .3 kJ / mol e . The
enthalpy
of sublimation of iodine is 6 2 .8 kJ / mol e . What is the standard enthalpy of formation of I C l g 

A) 4 0 1 9 ca l / mol B) 4 0 1 9 ca l / mol C) 1 6 .8 kJ / mol D) 1 6 .8 kJ / mol


20. 1 mole of naphthalene  C H  was burnt in oxygen gas at 2 5 C at constant volume.
10 8
0

The heat
evolved was found to be 5138.8 kJ. Calculate the heat of reaction at constant pressure.
A) 4770.9 kJ B) -5143.8 kJ C) 6796.6 kJ D) 5143.8 kJ
21. The specific heat of I in vapour and solid state are 0.031 and 0.055 cal/g respectively.
2

The heat
of sublimation of iodine at 2 0 0 C i s 6 .0 9 6 kca l mol  . The heat of sublimation of iodine at
0 1

0
250 C
will be
A) 3 .8 kca l mol  B) 4 .8 kca l mol 
1
C) 2 .2 8 kca l 1
mol
1
D) 5 .8 kca l mol 
1

22. Calculate the enthalpy of formation ( i n kca l / mol ) of HI g from the following data.
H 2  g   C l2  g   2 H C l  g  : H  4 4 .2 0 kca l

H C l  g   aq  H C l  a q  : H  1 7 .3 1 kca l

H I  g   aq  HI  aq  : H  1 9 .2 1 kca l

K O H  aq   H C l  aq   K C l  a q  : H  1 3 .7 4 kca l

K O H  aq   H I  aq  KI  aq  : H  1 3 .6 7 kca l

C I 2  g   2 K I  aq   2 K C l  a q   I 2  s  : H  5 2 .4 2 kca l
A) 1 9 .2 1 B) 3 2 .8 7 C) 5 .9 4 D) 7 .8 2

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
SECTION - II

n
23. The process A g  A n  a q  or B
n
g  B  n  a q  is exothermic. Which of these
3
have  r H more negative than Ce g  C e 3  a q  ?
3
A) Lu g  L u 3  a q  B) Yb
3
g  Y b 3  a q 
C) E u   g   E u   a q 
3
D) 3
Sm
3
g  Sm 3  a q 
24. What is the bond enthalpy of Xe-F bond?
X eF 4  g   X e  g   F 
g
 F 2  g   F  g  ;  r H  2 9 2 kca l / mol

I . E of X e  2 7 9 k .ca l / mol e

B . E of F 2  3 0 k .ca l / mol e

E . A of F  8 5 k .ca l / mol e
A) 3 4 k .ca l / mol e B) 3 2 k .ca l / mol e
C) 1 4 2 .1 2 kJ / mol e D) 1 3 3 .8 8 kJ / mol e
25. From the following data, mark the option(s) where H is correctly written for the given
reaction.
Given: H   a q   O H   a q   H O  l  ; H  5 7 .3 kJ 2

H sol u ti on of HAg  7 0 .7 kJ / mol

H sol u ti on of BO H  g   2 0 kJ / mol

H i on i za ti on of HA  1 5 kJ / mol a n d B O H i s a str on g b a se

R e a cti on r H  kJ / mol 

A) H A  aq   B O H  aq   B A  a q   H 2O  4 2 .3
B) HA  g   BO H  g   B A  a q   H 2O  93
 
C ) B  aq   O H  aq   BO H  aq   20
 
D ) HAg H  aq   A  aq   5 5 .7

26. Consider the following data:


r H o
 N 2H 4, l   5 0 kJ / mol , ; r H o
 NH 3, g   4 6 kJ / mol

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
B .E  N  H   3 9 3 kJ / mol a n d B . E .  H  H   4 3 6 kJ / mol , a l so  va p H  N 2 H 4
l  1 8 kJ / mol

T he N N b on d en er g y i n N 2 H 4
is

A) 2 2 6 kJ / mol B) 1 5 4 kJ / mol C) 1 9 0 kJ / mol D) 4 5 .4 5 k C a l / mol


27. A quantity that can be directly measured is
A) Heat of formation of H O  l  B) Heat of formation C H  g 
2 4

C) Latent heat of fusion of ice D) Heat of combustion of ethyl alcohol


28. At 300 K, the standard enthalpies of formation of,
C 6 H 5 C O O H  S  , C O 2  g  a n d H 2 O 1 a r e  4 0 8,  3 9 3 a n d  2 8 6 kJ / mol

respectively. The enthalpy of combustion of benzoic acid(s) at 300 K is


A) -3201 kJ/mol, at constant pressure
B) -3199.75 kJ/mol, at constant volume
C) -3201 kJ/mol, at constant volume
D) -3199.75 kJ/mol, at constant pressure
29. The diagram illustrates the energy change of a set
of
reactions
Which of the following, statement are correct?
A) The enthalpy change for the reaction
1
P R is  33 kJ mol
B) The enthalpy change for the transformation
R  Q will be endothermic
C) The enthalpy change for the transformation
R  Q will be exothermic
D) The enthalpy change for the transformation S  P will be 4 2 kJ mol  1

30. Use the following data to calculate the lattice energy of strontium chloride.
The enthalpy of sublimation of strontium =  1 6 4 kj / mol e
First ionization energy for strontium =  5 4 9 kj / mol e
Second ionization energy for strontium =  1 0 6 4 kj / mol e
The enthalpy of dissociation of chlorine, C I  2 4 3 kj / mol e 2

The electron affinity of chlorine, C I   3 4 9 kj / mol e


Enthalpy of formation Sr C l   8 2 8 kj / mol e2

A) 3 1 5 0 kJ / mol B) 2 1 5 0 kJ / mol C) 7 5 2 .8 5 k .ca l / mol D) 5 1 3 .8 5 k .ca l / mol

SECTION - III

31. What amount of ice (gm) will remain when 52gm ice is added to 100gm of water at

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
40 cgiven
0

[Link] of water = 1 cal/gm


latent heat of fusion of ice = 80 cal/gm
32. The heat capacity of liquid water is 7 5 .6 J / k .mol e while the enthalpy of fusion of ice is
6 kJ / mol e what is the smallest number of ice cubes each containing 9gm of water
needed to
cool 500gm of liquid water from 2 0 c to 0 c 0 0

33. A solution of 500ml of 2M KOH is added to 500ml of 2M H C l and the mixture is will
shaken.
The rise in temp T is noted. The experiment is again performed using 250mL of KOH
1

solution
and 500mL of H C l solution & the rise in temp is T noted. Then T is _____ times of T 2 1 2

34. A calorimeter contains 70.2g of water at 1 5 .3 c . If 143.7gm of water at 3 6 .5 c is mixed it


0 0

with
the common temp 2 8 .7 c . The water equivalent of the calorimeter is _________ gm
0

35. I ce W a ter  2 7 7 K  has  r H nearly 6 0 0 0 .0 J mol  . The maximum heat liberated during
1

the
freezing of 1 .8 0 cm water is _______________ (in kJ)
3

36. The integral enthalpy of solution of one mole H SO in n mole of water is given by the 2 4

equation
7 5 n
H  kj / mol e . If 1mole of H 2 SO 4 dissolved in 5 moles of water, calculated H
n  1 .8
_______kj

MATHEMATICS
SECTION - I

4
37. The slope of a straight line passing through A(-2, 3) is . The points on the line that are
3
10 units
away from A are
A)  6, 1 0  ,  3, 5  B)  7 , 5  ,  1, 1  C)  7 , 9  ,  1 7 , 1  D)  8, 1 1  ,  4, 5 
38. Normal form of the line x  y  2  0 is
5 5 7 7
A) x cos  y si n 1 B) x cos  y si n 1
4 4 4 4
3 3  
C) x cos  y si n 1 D) x cos  y si n 1
4 4 4 4
39. The equation of perpendicular bisectors of AB and AC of a  A B C are x  y  5  0 and

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
x  2 y  0 respectively. If A  (1, 2 ) then slope of BC is
2 1 1 11 2
A) B) C) D)
11 2 2 11
40. For what values of '  ' for which point  3  ,   lies inside of triangle formed by the lines y x,
x  a xi s and line x  y  4 is
A) 1    1 B) 1    0 C) 0   1 D) 1    2

SECTION - II

41. The equations of straight line passing through  2, 7  and having an intercept of length 3
between
the straight lines 4x  3 y  1 2 a n d 4 x  3 y  3 is / are
A) x  2  0 B) x  2  0 C) 7 x  2 4 y  1 8 2  0 D) 7x  24 y 182  0
4
42. The line x  y meets the lines x  y 1  0 and 2x  y  5 at A and B respectively.
3
Coordinates of S
4
on x  y such that [Link]=25
3
A)  0, 4 2  B)  4 2, 3 2 C) 4 2, 3 2  D)  0, 0 

 l 3 l 2  3   m3 m 3 
2
 n3 n 3 
2

43. If the points  , ,  ,  and  ,  , where l , m, n are different from 1,


 l 1 l 1   m 1 m 1   n 1 n 1 
lie
on the line a x  b y  c  0 then
b c
A) l  m  n  B) lm  mn  n l 
a a
3b c
C) l mn  D) l mn  ( l m  mn  l n )  3( l  m  n )  0
a
44. A line through A  5,  4  with slope tan  meets the lines
x  3 y  2  0, 2x  y  4  0, x  y 5  0
2
 15   10   6 
2 2

at P, Q, R respectively such that       then


 AP   AQ   AR 
2 6
A) tan   B)  cos   si n 
3 AR

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JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
10 15
C)  2 cos   si n  D)  cos   3 si n 
AQ AP
45. A line 4x  y  1 through the point P  2,  7  meets the line QR whose equation is 3x  4 y 1  0
at the
point Q, then equation of line PR so that PQ = PR
A) 4 x  y  1 5  0 B) 4 x  y  1 5  0
C) 5 2 x  8 9 y  5 1 9  0 D) 5 2 x  8 9 y  5 1 9  0
46. Two sides of a rhombus OABC (lying entirely in the first or third quadrant) of area equal
to 2
x
sq. units are y  , y  3x . Then the possible coordinates of B is/are (O being the origin)
3

A) 1  3,1  3 B)  1  3, 1  3

C) 3  3, 3  3 D)  3  1, 3 1
47. The coordinates of a point on x  y  3  0 whose distance from x 2y 2 0 is 5 is/are
A)  1, 4  B)  9, 6  C)  1,  4 D)  9, 6

48. The equation of straight line passing through the point  2, 3  and inclined at an angle of
1 
1
tan  
2
with the line y  2 x  5 is
A) x  2 B) y 3 C) 4x  3 y 17  0 D) 3x  4 y 18  0
SECTION - III

49. A, B are points on the line 3x  4 y  1 5  0 , OA = OB = 9, the area of O A B is p q then value


of
p
 ______
q
50. Sum of intercepts of a line parallel to 4 x  7 y  2 8  0 and passing through (1, 1) is _________
51. If the base of an equilateral triangle is x  y  2 and its opposite vertex is (2, 1) and the
length of its
p q
each side is then  _________
q p

52. The sum of algebraic distances from the points 2


 m , m  w h er e m  1, 2, 3 ......2 0 2 5 , to a
variable
straight line is zero and if such a line always passes through the point   ,   and

SEC: CO C3 IPL WT - 11 (06.02.2025) Page 12


JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
1 1013 
   p qr s th en q  r  ______ (pqrs is four-digit number)
 3 
53. Two opposite vertices of a rectangle are (1, 3) and (5, 1) and the equation of the other
diagonal
of this rectangle is y  2 x  k then the value of k =___________
54. The equation of the line which is equidistant from parallel lines
9x 6y 7  0 and 3x  2 y  6  0 is 1 8 x  1 2 y  p  0 then p = ___________

>>>> 0 <<<<

SEC: CO C3 IPL WT - 11 (06.02.2025) Page 13


Sri Chaitanya IIT Academy - India
WEEKEND TEST - 11
JEE-ADVANCED_ (2019 PAPER_1)
CLASS : CO C3 IPL DATE : 06.02.2025
KEY SHEET

PHYSICS :

1 D 2 A 3 C 4 D 5 D
6 C 7 AD 8 BC 9 ABCD 10 ABCD
11 AD 12 ABCD 13 2 14 2 15 4
16 4 17 7 18 0

CHEMISTRY :

19 B 20 B 21 D 22 C 23 ABD
24 BD 25 ABD 26 CD 27 ACD 28 AD
29 C 30 BD 31 2 32 14 33 1.5
34 13.4 35 0.6 36 -55.15

MATHEMATICS :

37 D 38 A 39 B 40 C 41 AD
42 BCD 43 ABCD 44 ABCD 45 BC 46 AB
47 CD 48 AD 49 9 50 4.32 51 1.5
52 8 53 4 54 11
Sri Chaitanya IIT Academy JEE-ADV_(2019_P1)

SOLUTIONS
PHYSICS:
1.

CHEMISTRY:
19.

MATHEMATICS:
37.

>>>> 0 <<<<

2
CO C3 IPL WT – 11 (06.02.2025)

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