Wta - 11 Coc3 Thermochemistry
Wta - 11 Coc3 Thermochemistry
PHYSICS
SECTION - I
1. A boat of mass 40 kg is floating on water. A body of mass 10kg on the boat moves by 8
m
towards the shore. The distance by which the boat moves away the shore is
A) 4 m B) 3 m C) 2 m D) 1.6 m
2. A mud ball at rest explodes into three fragments of
masses in the
Ratio [Link]. The two equal masses move with velocities
2 i垐 5 j 6 k垐a n d 4 i垐 3 j 2 k . Find the velocity of the third
mass.
A) 21 m / s B) 10 m/s
C) 10 m / s D) 5 m /s
5. The angular velocity of the earth with which it has to rotate so that acceleration due to
gravity on
6 0 latitude becomes zero.
0
gp gp gp gp
A) 3 B) 4 C) D) 2
R R R R
6. In a double star system, two stars of masses m a n d m separated by a distance d rotate
1 2
their center
of mass. Then their common angular velocity would be
G m1 G m2 G m1 m2 d
3
A) B) C) D)
d
3
d
3
d
3
G m1 m2
7. At the height h above the surface of earth, the value of g : (R is radius of the
earth)
A) Falls to 1% of the value at the surface if h= 9R
B) Falls by 1% of the value at the surface if h= 64 km
C) Falls by 1% of the value at the surface if h= 7R
D) Falls by 1% of the value at the surface if h= 32 km
8. The acceleration due to gravity on moon is only one sixth that on earth.
Ratio of
moon radius R m to earth’s radius R e should be:
A) 6/1 if both are assumed to have same density B) 1/6 if both are assumed to have
5 9
same density C) i f e i s g i ven a s 5 / 3 D) i f m i s g i ven a s 3 / 5
18 m 5 e
9. Two blocks of masses m and M are interconnected by an ideal spring of stiffness k. If m
is
pushed with a velocity v 0
2 gR
A) The velocity of the point mass m is v
m
1
M
m
B) The velocity of the block M is V 2 gR
M
mR
C) The position of the point mass is x 2
M m
D) The x component of displacement of the center of mass of the block M is
mR
M m
12. An ideal spring is permanently connected between two blocks of masses M and m.
The blocks-
spring system can move over a smooth horizontal table along a straight line along the
length of
the spring as shown in figure. The blocks are brought nearer to compress the spring
SEC: CO C3 IPL WT - 11 (06.02.2025) Page 5
JEE-ADV_2019 PI Sri Chaitanya IIT Academy, India
and then
released. In the subsequent motion,
13. A train of mass M is moving on a circular track of radius ‘R’ with constant speed V. The
length
of train is half of the perimeter of the track. The linear momentum of the train will be
M V / value of is (only magnitude)
14. The density of a newly discovered planet is twice that of the earth. The acceleration
due to
gravity at the surface of the planet is equal to that at the surface of the earth. If the
radius of the
earth is R and the radius of the planet is R’. Then what is the value of R/R’?
15. If the radius of the earth were to shrink by 2% its mass remaining the same, by how
much
percentage would the acceleration due to gravity on the earth’s surface would increase?
16. Four similar particles of mass ‘m’ are orbiting in a circle of radius ‘r’ in
the
same angular direction symmetrically because of their mutual
gravitational
Gm 1 1
attractive force. Velocity of a particle is given by .
r 2 n
G 3
distance 2 2 . where is the angular velocity of each star about centre of mass of
CHEMISTRY
SECTION - I
19. The bond dissociation energies for C l2 , I 2 , and I C l are 242.3, 151 and 2 1 1 .3 kJ / mol e . The
enthalpy
of sublimation of iodine is 6 2 .8 kJ / mol e . What is the standard enthalpy of formation of I C l g
The heat
evolved was found to be 5138.8 kJ. Calculate the heat of reaction at constant pressure.
A) 4770.9 kJ B) -5143.8 kJ C) 6796.6 kJ D) 5143.8 kJ
21. The specific heat of I in vapour and solid state are 0.031 and 0.055 cal/g respectively.
2
The heat
of sublimation of iodine at 2 0 0 C i s 6 .0 9 6 kca l mol . The heat of sublimation of iodine at
0 1
0
250 C
will be
A) 3 .8 kca l mol B) 4 .8 kca l mol
1
C) 2 .2 8 kca l 1
mol
1
D) 5 .8 kca l mol
1
22. Calculate the enthalpy of formation ( i n kca l / mol ) of HI g from the following data.
H 2 g C l2 g 2 H C l g : H 4 4 .2 0 kca l
H C l g aq H C l a q : H 1 7 .3 1 kca l
H I g aq HI aq : H 1 9 .2 1 kca l
K O H aq H C l aq K C l a q : H 1 3 .7 4 kca l
K O H aq H I aq KI aq : H 1 3 .6 7 kca l
C I 2 g 2 K I aq 2 K C l a q I 2 s : H 5 2 .4 2 kca l
A) 1 9 .2 1 B) 3 2 .8 7 C) 5 .9 4 D) 7 .8 2
n
23. The process A g A n a q or B
n
g B n a q is exothermic. Which of these
3
have r H more negative than Ce g C e 3 a q ?
3
A) Lu g L u 3 a q B) Yb
3
g Y b 3 a q
C) E u g E u a q
3
D) 3
Sm
3
g Sm 3 a q
24. What is the bond enthalpy of Xe-F bond?
X eF 4 g X e g F
g
F 2 g F g ; r H 2 9 2 kca l / mol
I . E of X e 2 7 9 k .ca l / mol e
B . E of F 2 3 0 k .ca l / mol e
E . A of F 8 5 k .ca l / mol e
A) 3 4 k .ca l / mol e B) 3 2 k .ca l / mol e
C) 1 4 2 .1 2 kJ / mol e D) 1 3 3 .8 8 kJ / mol e
25. From the following data, mark the option(s) where H is correctly written for the given
reaction.
Given: H a q O H a q H O l ; H 5 7 .3 kJ 2
H sol u ti on of BO H g 2 0 kJ / mol
H i on i za ti on of HA 1 5 kJ / mol a n d B O H i s a str on g b a se
R e a cti on r H kJ / mol
A) H A aq B O H aq B A a q H 2O 4 2 .3
B) HA g BO H g B A a q H 2O 93
C ) B aq O H aq BO H aq 20
D ) HAg H aq A aq 5 5 .7
T he N N b on d en er g y i n N 2 H 4
is
30. Use the following data to calculate the lattice energy of strontium chloride.
The enthalpy of sublimation of strontium = 1 6 4 kj / mol e
First ionization energy for strontium = 5 4 9 kj / mol e
Second ionization energy for strontium = 1 0 6 4 kj / mol e
The enthalpy of dissociation of chlorine, C I 2 4 3 kj / mol e 2
SECTION - III
31. What amount of ice (gm) will remain when 52gm ice is added to 100gm of water at
33. A solution of 500ml of 2M KOH is added to 500ml of 2M H C l and the mixture is will
shaken.
The rise in temp T is noted. The experiment is again performed using 250mL of KOH
1
solution
and 500mL of H C l solution & the rise in temp is T noted. Then T is _____ times of T 2 1 2
with
the common temp 2 8 .7 c . The water equivalent of the calorimeter is _________ gm
0
35. I ce W a ter 2 7 7 K has r H nearly 6 0 0 0 .0 J mol . The maximum heat liberated during
1
the
freezing of 1 .8 0 cm water is _______________ (in kJ)
3
36. The integral enthalpy of solution of one mole H SO in n mole of water is given by the 2 4
equation
7 5 n
H kj / mol e . If 1mole of H 2 SO 4 dissolved in 5 moles of water, calculated H
n 1 .8
_______kj
MATHEMATICS
SECTION - I
4
37. The slope of a straight line passing through A(-2, 3) is . The points on the line that are
3
10 units
away from A are
A) 6, 1 0 , 3, 5 B) 7 , 5 , 1, 1 C) 7 , 9 , 1 7 , 1 D) 8, 1 1 , 4, 5
38. Normal form of the line x y 2 0 is
5 5 7 7
A) x cos y si n 1 B) x cos y si n 1
4 4 4 4
3 3
C) x cos y si n 1 D) x cos y si n 1
4 4 4 4
39. The equation of perpendicular bisectors of AB and AC of a A B C are x y 5 0 and
SECTION - II
41. The equations of straight line passing through 2, 7 and having an intercept of length 3
between
the straight lines 4x 3 y 1 2 a n d 4 x 3 y 3 is / are
A) x 2 0 B) x 2 0 C) 7 x 2 4 y 1 8 2 0 D) 7x 24 y 182 0
4
42. The line x y meets the lines x y 1 0 and 2x y 5 at A and B respectively.
3
Coordinates of S
4
on x y such that [Link]=25
3
A) 0, 4 2 B) 4 2, 3 2 C) 4 2, 3 2 D) 0, 0
l 3 l 2 3 m3 m 3
2
n3 n 3
2
A) 1 3,1 3 B) 1 3, 1 3
C) 3 3, 3 3 D) 3 1, 3 1
47. The coordinates of a point on x y 3 0 whose distance from x 2y 2 0 is 5 is/are
A) 1, 4 B) 9, 6 C) 1, 4 D) 9, 6
48. The equation of straight line passing through the point 2, 3 and inclined at an angle of
1
1
tan
2
with the line y 2 x 5 is
A) x 2 B) y 3 C) 4x 3 y 17 0 D) 3x 4 y 18 0
SECTION - III
>>>> 0 <<<<
PHYSICS :
1 D 2 A 3 C 4 D 5 D
6 C 7 AD 8 BC 9 ABCD 10 ABCD
11 AD 12 ABCD 13 2 14 2 15 4
16 4 17 7 18 0
CHEMISTRY :
19 B 20 B 21 D 22 C 23 ABD
24 BD 25 ABD 26 CD 27 ACD 28 AD
29 C 30 BD 31 2 32 14 33 1.5
34 13.4 35 0.6 36 -55.15
MATHEMATICS :
37 D 38 A 39 B 40 C 41 AD
42 BCD 43 ABCD 44 ABCD 45 BC 46 AB
47 CD 48 AD 49 9 50 4.32 51 1.5
52 8 53 4 54 11
Sri Chaitanya IIT Academy JEE-ADV_(2019_P1)
SOLUTIONS
PHYSICS:
1.
CHEMISTRY:
19.
MATHEMATICS:
37.
>>>> 0 <<<<
2
CO C3 IPL WT – 11 (06.02.2025)