Nuclear Physics Foundations and Concepts
Nuclear Physics Foundations and Concepts
Nuclear Physics
Rodrigo Alonso
IPPP OC307
[Link]-de-pablo@[Link]
What are the most elemental components of matter? Our answer to this question has
been evolving with time as our knowledge progressed finding appropriate descriptions at each
increasingly small scale. Here we zoom in to femto-metre (fm) distances to explore nuclear
structure; the forces, the components and the conservation laws that rule over this sub-atomic
world. We will develop the formalism in quantum mechanics and special relativity that allows us
to look deep into matter, learn about nuclear binding energies and transitions, and the models
that help us understand them.
These notes are self-contained but here’s a list of useful references
fm
100 pm
1
PHYS3621 - Nuclear CONTENTS
Contents
1 Introduction and units 3
1.1 Scattering experiments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.2 Natural units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
2 Relativistic Kinematics 6
5 Rutherford Experiment 14
5.1 Rutherford cross section . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
5.2 Comparison with experiment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
5.3 Mott cross section . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
6 Nuclear shapes 17
6.1 Form factor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
6.2 Energetic enough to see . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
8 Nuclear stability 24
10 A-changing decays 28
11 Nuclear power 31
12 Shell model 34
12.1 Spin and parity of nuclei . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
12.2 Excited states . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
2
PHYS3621 - Nuclear 1 INTRODUCTION AND UNITS
3
PHYS3621 - Nuclear 1 INTRODUCTION AND UNITS
Nin
Flux= σ (1.2)
A·t
So in these units a car travels at 0.0000001 c or an Olympian reaches 1035 ℏ in hammer throw
but an alpha particle from radioactive decay might have 0.01 c and an electron has spin ℏ/2.
What makes natural units less straightforward than other units is that one also omits c and ℏ.
Making them implicit has the advantage of simplifying our computations, since in practice it
means
4
PHYS3621 - Nuclear 1 INTRODUCTION AND UNITS
The choice for energy in natural units is electronvolt (eV) and time, space, momentum and
mass are given as powers of this basic unit.
In summary, if somebody gives you speed or angular momentum in natural units, multiply
by c or ℏ respectively to convert to other system and for time, space, mass or a composite of
these use powers of ℏ, c as in table 1.
A useful reference for fundamental constants and conversion factors is the p.d.g.
N In a nutshell
• Scattering experiments, our means to look deep within matter, are characterized
by luminosity L and cross section σ.
• In natural units mass, space and momentum are given in terms of powers of the
energy unit: eV. We convert to other units with powers of ℏ, c as in table 1.
5
PHYS3621 - Nuclear 2 RELATIVISTIC KINEMATICS
2 Relativistic Kinematics
The relation between energy and mass for a particle at rest is one of the most publicized
equations in science and here we will find use for it. First however, the actual relation for a
particle with speed v is:
mc2 m
E=p =√ (2.1)
1 − (v/c)2 1 − v2
where the second line is in natural units. A small velocity expansion returns the familiar kinetic
energy (it is a good exercise to do this explicitly). This equation also tells us that the energy is
different for different observers, in particular higher the larger relative speed and always larger
than the energy in the rest frame. Similarly, although not evidently so, an event with a given
duration on its rest frame will appear to last longer for another observer. This time dilation is
the same factor as the ratio of the energy and mass, let’s see why.
This observation follows from special relativity, which in its rather minimal formulation,
groups together different magnitudes together in 4-vectors. These four-vectors are represented
by a letter with an index which in our convention will be a Greek letter
t E
µ
x t µ
px E
x = =
, p = = . (2.2)
y x py p
z pz
The reason this is not a purely aesthetical arrangement is that magnitudes within a four-vector
get mixed up for different observers.
Consider this situation, you are sitting down in your frame with coordinates xµ and an
observer O′ moving at a relative speed v (β = v/c) along the x axis and towards x = ∞ passes
you by at t = 0. Her/his coordinates are x′µ , to translate them into yours we do
′
t γ βγ t
x βγ γ x′ 1
= γ=p (2.3)
y′
y 1 1 − β2
z 1 z′
This means that an event at rest in the original frame which takes t′e seconds, i.e. x′µ e =
(t′e , 0, 0, 0), seems to take te = γt′e for you, that is it takes a factor γ longer. Equivalently a
particle at rest for O′ has energy m and no momentum, p′µ = (m, 0, 0, 0), whereas you measure
a 4-momentum
pµ = (γm, vγm, 0, 0)T
and we recover the expression for the energy 2.1. The non-relativistic limit gives us the usual
expression for momentum and energy but we see here that it breaks down when velocities are
close to c and (γ − 1) ∼ 1.
In our scattering experiments we express kinematics in terms of 3-momentum p rather than
speed; according to our derivation the connection is p = γmv, but then how do we write the
energy in terms of momentum? Direct substitution would do it but here let us instead use the
invariant scalar product of a four vector, defined as
1
−1
p2 ≡pµ ηµν pν = pµ pµ = pµ pµ = E 2 − p2
ηµν = (2.4)
−1
−1
6
PHYS3621 - Nuclear 2 RELATIVISTIC KINEMATICS
where we used Einstein’s convention i.e. repeated indexes are summed over. The use of this
scalar product is that every observer will measure the same magnitude and the simplest frame
to compute it is the particle’s rest frame where (p′ )2 = (p′0 )2 = m2 , but we can explicitly check
that we get the same in our frame
(2.4) p p
p2 =γ 2 (1 − v 2 )m2 = m2 = E 2 − p2 E= m2 + p2 , v= . (2.5)
E
This is the relation between momentum and energy that we will employ in the following.
The grouping of energy and momentum into a 4-vector also makes the conservation laws for
energy and momentum more compact. Take for example a particle with momentum p decaying
to two particles A and B with momentum kA , kB . We have
µ µ
pµ = kA + kB
If we take the square on both sides we will obtain an invariant magnitude as:
m2 − m2A − m2B
m2 = m2A + m2B + 2kA · kB kA · kB =
2
which is the same quantity in all frames; that is, take the energy of particle A times the energy
of particle 2, subtract the product of their 3-momenta and the magnitude you get is, regardless
of your relative velocity, (m2 − m2A − m2B )/2.
N In a nutshell
• The scalar product in Minkowski is built with the metric of eq. (2.4) and is the
same for all observers
7
PHYS3621 - Nuclear 3 PARITY AND ANGULAR MOMENTUM
Symmetry The set of transformations that leave the laws of physics the same
The presence of symmetry is useful since it simplifies the study of any given physical system.
This can be made explicit, in a connection which is one of the most fundamental in physics:
Symmetry Consequence
continuous (e.g. rotations) conserved quantity (e.g. angular momentum)
discrete (e.g. parity) selection rule
We will not attempt at a proof of this, which is beyond our scope but refer the interest
reader to the Emily Noether theorem.
We have made a distinction in the type of symmetry between discrete and continuous, this
is best understood with an example, as in fig. 2. A continuous symmetry is constituted of a
continuous set of transformations while a discreet one has a finite, countable set.
Figure 2: LHS: Continuous symmetry - a circle which looks the same when rotating any angle
θ RHS: Discrete symmetry - A square only looks the same if we rotate it 90, 180 or 270 degrees.
3.1 Parity
The action of parity is simply to take x to −x, that is a inversion around the origin. It might
sound cumbersome but lets call P̂ the parity operator which does such a transformation. You
can entertain yourself to do some parity transformations, here is sample:
P̂ × =
8
PHYS3621 - Nuclear 3 PARITY AND ANGULAR MOMENTUM
P̂ × =
What we learn from the second example is that some magnitudes, on top of the relocation
imposed by parity, pick up a minus sing
dx dx
v= → − = −v
dt dt
In fact this exhausts the list of possibilities, a magnitude might pick up a minus sign or none. We
can see this by considering the quantum operator acting twice, P̂ P̂ (x) = P̂ (−x) = −(−x) = x.
That is acting twice we end up where we started, in terms of eigenstates of the parity operator,
such that
P̂ (Eigenstate) = Pi (Eigenstate) (3.1)
one has
+1
P̂ P̂ = 1, P̂ P̂ (Eigenstate) = Pi2 (Eigenstate) = (Eigenstate) ⇒ Pi = (3.2)
−1
The action on a particle’s wave function of parity is
P̂ ψ(x) = Pintrinsic ψ(−x) (3.3)
The prefactor is the intrinsic parity of a particle; there is some arbitrariness in defining this,
one can in particular set it to +1 and forget about it (but if one does so the antiparticle will
have opposite intrinsic parity, see NPP2 lectures).
The wave-function can then be split into two pieces which are eigenstates as
1 1
ψ(x) = (ψ(x) + ψ(−x)) + (ψ(x) − ψ(−x)) ≡ ψ+ (x) + ψ− (x) (3.4)
2 2
P̂ ψ± (x) = (±)ψ(x) (3.5)
The selection rule that follows if parity is a symmetry, i.e. it leaves the fundamental physics
unchanged can be stated as
if one starts with
a parity eigenstate
if [P̂ , H] = 0 parity is conserved so (3.6)
it will stay a parity
eigenstate
The composition law for parity can be derived from the consideration of the action of P̂
on a composite system of (distinguishable particles for simplicity) in parity eigenstates ψPi (xi ),
P̂ ψPi (xi ) = Pi ψPi (xi ) as
P̂ ψP1 (x1 )ψP2 (x2 ) . . . ψPn (xn ) =P1 ψP1 (x1 )P2 ψP2 (x2 ) . . . Pn ψPn (xn ) (3.7)
= P1 P2 ...P3 ψP1 (x1 )ψP2 (x2 ) . . . ψPn (xn ) (3.8)
| {z }
total parity
9
PHYS3621 - Nuclear 3 PARITY AND ANGULAR MOMENTUM
J= 0 1/2 1 3/2...
Jz 0 1/2 1
J J, Jz (3.9)
|{z} −1/2 0
quantum numbers −1
That is a total of 2J + 1 state for angular momentum J and we also recall J2 = J(J + 1).
There is a composition law for momentum in quantum mechanics, a prominent example
being the Hydrogen atom
J = |{z}
L + |{z}
S |L − S| ≤J ≤ L + S (3.10)
orbital spin
and for example if L = 1, S = 1/2 for an electron in the p orbital, J = 1/2 or 3/2.
It is worth asking about parity, the Hamiltonian is e2 /(4πε0 |x) and invariant under a par-
ity transformation, so it is a good quantum number. The Hamiltonian eigenstates that one
find solving the Hydrogen atom have well-defined parity, which is captured by the spherical
harmonics
So that only one of the two options for the angular momentum of the radiation is allowed.
N In a nutshell
• When parity leaves the dynamics of a system invariant, parity [which take just two
values, ±1] is preserved.
10
PHYS3621 - Nuclear 4 SCATTERING FROM FERMI’S GOLDEN RULE
On the other hand we can write the wave function for our states as
eip·x
Z
Ψp (x) =⟨x|Ψp ⟩ = √ dx3 |Ψp (x)|2 = 1 (4.3)
V V
Our momentum states however should not depend on volume which will be set to infinity so we
define them as
|p⟩
|Ψp ⟩ ≡ √ ⟨x|p⟩ = eip·x (4.4)
V
11
PHYS3621 - Nuclear 4 SCATTERING FROM FERMI’S GOLDEN RULE
where in the second line we take Born’s approximation to retain one power of the interaction
Hamiltonian which will suffice here.
The question we ask in our scattering experiments is what is the probability that an initial
momentum state p scatters into a final momentum state p′ . Here we make the assumption that
the target very massive and not does not recoil.
(Ep′ , p′ )
θ
This is the transition probability for a momentum state, if we instead sum over a number of
momentum states we take the continuum limit as prescribe above
X 2 V d 3 p′
Pp→p′ → dPp→p′ =2πδ(Ep′ − Ep )t ⟨Ψp′ |Hint |Ψp ⟩ (4.13)
n
(2π)3
which is Fermi’s Golden rule for a time independent perturbation. You have seen this rule for an
oscillating perturbation where the integrand was approximated to ei∆Et cos(ωt) ∼ ei(∆E−ω)t /2.
The result here can be obtained as a limit by sending ω → 0 and multiplying the matrix element
by 2 and hence Fermi’s rule by 4.
1
How did theRsecond line get an integral? By virtue of a connection of matrix algebra and calculus that says
1
e−A eA+B − 1 = 0 dze−zA BezA + O(B 2 ) R∞
2
To convince yourself of this you can evaluate the 2 sin(ωt)/ω at ω = 0 and the result that −∞ sin(x)/x = π
which if motivated, you can derive with complex analysis.
12
PHYS3621 - Nuclear 4 SCATTERING FROM FERMI’S GOLDEN RULE
which is independent of the area and where we used the relation v = p/Ep that you can derive
in the first problem sheet.
Number of events needs re-interpretation as well; we have one particle so N cannot be larger
than 1, can we make sense of N ≤ 1? We can if we take it to be a probability; the particle
does indeed scatter or it doesn’t but we can only find in what ratio if we repeat the experiment
many times. This will give us the probability that any one particle scatters, a number smaller
than one. The differential probability for scattering into a momentum p′ is therefore after our
re-cast of chapter 1:
t |p|
dPp→p′ = t × F × dσp→p′ = dσp→p′ (4.14)
V Ep
The probability on the left-hand side we have computed with Fermi’s Golden rule; if we substi-
tute it in:
2
t |p| ⟨p′ |Hint |p⟩ V d 3 p′
dσp→p′ = 2π t δ(Ep′ − Ep ) (4.15)
V Ep V (2π)3
the factors of volume and time are the same on both sides and drop out for a result independent
of V as it should. The Dirac delta can be used to do the integral over the modulus of p′ and
obtain:
2
Ep ′
dσ = ⟨p |Hint |p⟩ dΩ |p|′ = |p| (4.16)
(2π)
with dΩ = sin θdθdϕ the solid angle measure for the direction of the scattered particle. This
concludes our derivation, we have expressed cross section in terms of the interaction Hamilto-
nian. Were someone to give us an experiment and an explicit Hint as predicted by some theory
we could test said theory.
N In a nutshell
• Fermi’s Golden rule gives us the cross section as the square of a matrix element.
• Approximating a non-recoiling target in and out momenta have the same modulus
and the differential cross section depends only on scattering angle.
13
PHYS3621 - Nuclear 5 RUTHERFORD EXPERIMENT
5 Rutherford Experiment
With the tools to compute scattering probabil-
ity one can now look back at the seminal ex-
periment which started nuclear physics as we
now know it. The leading theory of the atom at
the turn of the 20th century was Thomson’s or
the plum pudding model where the electrons are
held in place by a substance with positive charge
that extends over the atom. In order to test
this theory in 1905 Rutherford and his students
Geiger and Marsden spread a few-atoms-thick
Gold film and shot alpha particles (i.e. Helium,
4 He, stripped of its electrons) at it, measuring
2
the direction along which the particles had scat-
tered.
The expectation from Thomson’s model is
that most of the alpha particles would pass
unperturbed; if they encountered an electron,
which is ten thousand times lighter, they would knock it off without changing course, whereas
going through the positively charge substance might have slowed them but not deflected them
much. It was then to Rutherford’s reported surprise that they detected a significant number of
alpha particles scattered at large angles and even backwards. They concluded that the mass of
atoms must be concentrated in a small region and those backscattered particles happened to
bounce of this ’nucleus’.
with q = p − p′ . That is the Fourier transform of the potential. One can perform this transform
by changing to spherical coordinates:3
The dependence on the radius r is then limited to complex exponential; we know how to do this
integral but how do we evaluate it given that the upper limit of integration is r = ∞? Here the
way will be to introduce an exponential factor as H → He−r/a , then take a → ∞ which gives
3
To do the polar angle integration stepwise do cos θx = η so dη = −sθx dθx and remember to re-order the
limits of integration η = ±1.
14
PHYS3621 - Nuclear 5 RUTHERFORD EXPERIMENT
e−r/a (a → ∞) ∼ 1. This is more justified than what you would think, after all, at a distance
of about the Bohr radius of Gold we have the electron screening an even further there’s no
potential. What we obtain is
Taking our limit a → ∞ leaves us with q2 only in the denominator. The modulus of the
transferred momentum q is, given that |p′ | = |p|:
where EK is the kinetic energy, EK = p2 /2m and αem = e2 /4πε0 is the electromagnetic fine
structure constant.
600 60
400 40
200 20
0 θ 0 θ
40 60 80 100 120 140 160 180 100 120 140 160 180
Figure 5: Histogram built out of a Rutherford-like experiment with a total of 1000 scattering
events.
15
PHYS3621 - Nuclear 5 RUTHERFORD EXPERIMENT
probability to get an even or odd number, if we roll and even number twice it doesn’t mean
our probabilities were
√ wrong. This limitation can be pushed to be smaller by measuring more
and improves as 1/ N , the systematic limitation however can only be overcome with better
technology.
2π 2π(197 fm MeV)
|p| = = ∼ 13 MeV
0.1pm 100fm
where we introduced a factor ℏc to convert from SI to NU. While an alpha particle can achieve
this momentum for v ∼ 0.003c for an electron this momentum is well above its mass which
means it is a relativistic particle (can you find its speed? v = |p|/Ep ).
This means that the electron would be relativistic and our formula has to be corrected to
Mott’s scattering cross section for no recoil
dσ dσ
= (1 − v 2 sin2 (θ/2)) (5.6)
dΩ Mott dΩ Ruth
The behaviour of this formula can be justified in the relativistic limit. It does indeed cancel
for backscattering (θ = 0) when v ∼ 1. This follows from conservation of angular momentum;
at high energies helicity, i.e. spin along direction of motion, is a conserved quantum number.
Angular momentum itself is conserved and with Coulomb’s potential there is no transfer of
angular momentum. All these factors mean we can’t have a relativistic particle helicity bouncing
straight back.
N In a nutshell
• Coulomb’s potential with a point charge at the center of the atom describes Ruther-
ford’s experiment.
• Differential cross section are reconstructed as histograms with real data to test our
theories.
16
PHYS3621 - Nuclear 6 NUCLEAR SHAPES
6 Nuclear shapes
Rutherford’s experiment taught us that the atom is mostly an electron cloud in volume and a
small nucleus in its mass. One can do better than this qualitative description and put numbers
in place of ‘mostly’. This chapter outlines how we do this while giving an explicit connection
of wavelength and the distances we can resolve.
Z1 Z2 e 2 f (y)
Z Z
3
Hint = d y d3 xf (x) = 1 (6.1)
4πε0 |x − y|
where f (y) is the probability density of a proton. Here we have used some of our implicit
knowledge, that is that the charge Z1 e is made up of Z1 identical particles and we even gave
them a name, the proton.
Propagating this change to the cross section we have the square of a more complicated
Fourier transform. One can nonetheless factorize this change with a little massaging as
iq·x f (y) iq(z+y) f (y) iqz
Z Z
3 e 3 e 3 e
Z Z Z
3 3 3 iqy
d xd y = d z d y = d z d y e f (y) (6.2)
|x − y| |z| |z|
which returns
R
eiqr − e−iqr
3 3 sin |q|R
Z
2 2
F (q ) = r dr(2π) = − cos(|q|R) (6.5)
4πR3 0 iqr (|q|R)2 |q|R
This form factor presents a number of the features of finite size targets.
• In low energy limit qR ≪ 1 one does not have enough energy to resolve the size of the
nucleus and it is effectively point-like. This can be seen taking the limit
F (q2 ≪ R−2 ) → 1
17
PHYS3621 - Nuclear 6 NUCLEAR SHAPES
which you can do yourself using the expansion of sine and cosine for small argument
x3 x2
sin(x) =x − + O(x5 ) cos(x) =1 − + O(x4 )
6 2
and means we will recover Rutherford’s cross section where the nucleus is described as
point-like. This is evidence for our statement that to resolve distances of a size d we
should use particles with momentum of at least 1/d (in natural units).
• In the high momentum regime there will be angles θ where interference causes the cross
section to approximately cancel, we can find the first of this values numerically
sin(|q0 |R)
− cos(|q0 |R) = 0 |q0 |R = 2|p| sin(θ0 /2)R ≃ 4.493 (6.6)
|q0 |R
the second instead located at |q|0 R ≃ 7.725, etc. Given the momentum of the incoming
particles and the angle of the first cancellation θ0 one can determine R.
when we increase enough our projectile’s momentum a diffraction-like pattern will appear in
our distribution in scattering angle. Let us look at actual data and see; fig. 6a contains the
experimental data points in black, our naive ansatz in dashed red and a grown-up ansatz for
the form factor in blue which reads
C
fph = (6.7)
1+ e(r−R)/a
with C a normalization factor.
(a) Ratio of cross section to Rutherford’s cross sec- (b) Charge distribution as inferred from scattering
tion as a function of the scattering angle data
Whereas our sphere modelling does not fall squarely on top of the data it does give the
ballpark value within a few degrees. In fact for enough data, we can turn it around and obtain
the inverse Fourier transform of the form factor to get the charge density f , which is what is
done in fig. 6b.
N In a nutshell
• The effect of a finite size target is encoded in the form factor F (q2 ) in our cross
section.
18
PHYS3621 - Nuclear 7 NUCLEAR MASSES AND BINDING ENERGIES
• It is attractive (except for a repulsive core for distances smaller than ≃ 1 fm).
If we were to follow the successful steps of the Hydrogen atom one could think of reconstructing
the force from nucleon nucleon scattering then computing the bound states from Schrodinger’s
equation. This program is however faced with a number of hurdles
• The nuclear force is so strong that perturbative methods have poor convergence
• Its a many body problem with all particles of the same mass.
• Nucleons move at large speeds and the non relativistic approximation is not always valid.
Let’s have a look at the first step of this program, reconstructing the nucleon-nucleon po-
tential as possible in principle from nucleon-nucleon scattering, we would find:
(S1 x)(S2 x)
VNcl =V0 (r) + Vss (r)(S1 · S2 ) + VT (r) 3 − S1 S2 + VLS (r)(S1 + S2 ) · L
r2
(S1 · p)(S2 · p)
+ VLs (r)(S1 · L)(S2 · L) + Vps (r) (7.1)
m2
with S1,2 the spin of each nucleon and L angular momentum. Compare this to the Coulomb
potential and you may realize why a phenomenological approach will be adopted here.
Rather than solving for the bounds states of a multi-particle system with a complicated
potential we can just ask Nature directly what the binding energies are. This turns out to be
a very straightforward experimental determination, the reason behind given by Einstein’s mass
formula.
where u is the atomic mass unit defined by the nuclear mass of Carbon M (12
6 C) = 12u. The
most common form of Helium is made up of two protons and two neutrons which we denote
19
PHYS3621 - Nuclear 7 NUCLEAR MASSES AND BINDING ENERGIES
4 Hewith superindex total number of nucleons (mass number) and subindex number of protons
2
(atomic number). So one would expect the mass of Helium to be
Comparing these two values of mass reveals one of the most striking results in nuclear physics.
The mass of the nucleus is less than the mass of its constituent parts; what is this deficit?
Binding energy B, the connection energy-mass given by Einstein’s mass relation m = E/c2 .
For Helium we have
EB
B(4, 2) = = 2Mp + 2Mn − M (42 He) = 0.031u . (7.5)
c2
To dismantle a nucleus we have to put in this amount of energy as shown in fig. 7. This energy
corresponds to the mass difference between free and bound nucleons and is therefore also called
the mass defect. The mass defect is clearly manifest in nuclear physics, but it does not mean
+
+
Figure 7: In order to break the bond of a nucleus into separate nucleons energy is required (e.g.
by an energetic photon).
that it only happens here. In atomic physics electrons are also in bound states and this will
give a mass defect only here binding energies of 13eV are 8 orders of magnitude smaller than
atomic masses and it is safe to neglect it.
The exercise can be repeated for all elements of the periodic table giving us a wealth of data
about the nuclear force. To classify our nuclei we use two numbers, as
Atomic number: the number of protons in the nucleus. Because the number of proton is
the same as the number of electrons in a neutral atom the atomic number specifies the
chemical properties of the atom. It is normally denoted with Z
Mass number: the number of proton and neutrons. As its name suggests it is roughly related
to the mass of the nucleus in atomic mass units. It is usually denoted with A.
A nucleus with atomic number Z and mass number A has therefore N = A − Z neutrons.
Nuclides are represented as A X, A A
Z X or Z XN with X the chemical symbol for the atom.
The binding energy B(A, Z) of a nucleus with atomic number Z and mass number A is the
difference between its atomic mass and the sum of the mass of its constituents.
20
PHYS3621 - Nuclear 7 NUCLEAR MASSES AND BINDING ENERGIES
Here, M (1 H) = Mp + me includes the masses of the proton and of the electron. This formula
assumes that the energy difference coming from the electron binding energies is negligible (it is
≈ 13.6 eV). The binding energies for all nuclei are shown in Fig. 8b.
21
PHYS3621 - Nuclear 7 NUCLEAR MASSES AND BINDING ENERGIES
Pairing term [EPairing = δ/A1/2 ] Nuclei with even numbers of protons and
neutrons are more stable. The reason is again a quantum effect and can not
be explained by analogy with the liquid drop. In terms of shells, it can be
explained by the fact that two different nucleons with opposite spin can be on
the same shell, whereas a third nucleon would need to be on the next shell, i.e.
lead to a bigger, more weakly bound nucleus. So we expect different values of
δ for both protons and neutrons appearing in even numbers, one even and one
odd and for both in odd numbers. The scaling as a function of A is found to be as A−1/2 .
+δp even-even nucleus
δ= 0 odd-even nucleus (7.8)
−δp odd-odd nucleus
Although this model of the binding energies of nucleons is descriptive and we can only
motivate the terms with qualitative explanations it does a good job of describing nature with a
relatively small number of inputs as you can see in fig 8b.
22
PHYS3621 - Nuclear 7 NUCLEAR MASSES AND BINDING ENERGIES
N In a nutshell
• Binding energies change nuclear masses at the ∼ 1% level and are described by the
semi-empirical liquid drop formula.
23
PHYS3621 - Nuclear 8 NUCLEAR STABILITY
8 Nuclear stability
Not all bound states of protons and neutrons result in a stable nucleus. There are a relatively
small number of nuclides that can be observed, with a smaller that are stable. The stable
nuclides are shown in Fig. 9. The mass formula can tell us if a given transition is energetically
viable, that is explicitly decays can occur if the difference of masses of initial state and final
state, here called Q, is positive
This does not tell us however how it happens or if it happens at all. There are a first a few
rules that decays should satisfy as we have found through experiments
Figure 9: Stability of the nuclides as a function of the number of protons Zand the number of
neutrons N . The color coding indicates the lifetime in seconds. Figure taken from [3].
Neutrons and protons are assigned a baryon number of one and this conservation means that
their total number will not change. Equivalently electron e− and electron neutrino νe have
electron number 1 but their anti-particles the positron e+ and anti-neutrino ν̄e electron number
−1.
Nuclei have a baffling range of lifetimes from ms to millions of years. This reflects both the
fact that there are different mechanisms for decay and that these mechanisms are very sensitive
to differences in bound states.
24
PHYS3621 - Nuclear 8 NUCLEAR STABILITY
The mean lifetime is related to the halflife by t1/2 = τ ln(2). Figure 10 shows the exponential
decay of the number of nuclei and the lifetime and half time.
The frequency of decays in a material is called the activity
dN
A=− = λN
dt
Commonly used units for the activity are Becquerel (1Bq = 1 decay/s) or Curie (1Ci = 3.7 ·
1010 Bq). The activity of a sample decreases with time as the number of candidate nuclei for a
decay diminishes,
The range of lifetimes for nuclei spans many orders of magnitude: some nuclides live for a mere
fs after being produced in the lab while others have a lifetime longer than thousands of years
and are present on earth contributing to the environmental radiation. The SI unit for measuring
the radiation dose is the sievert, Sv, and is determined by energy absorbed by kilogram of tissue
times a quality factor γ̄ which depends on the type of radiation (β, γ, γ̄ = 1; α, γ̄ = 20). Typical
doses we are exposed to are in the mSv per year.
N In a nutshell
• The characteristic decay time is the mean lifetime, the inverse of the decay rate
which is the time it takes for a sample to decrease by 0.368.
25
PHYS3621 - Nuclear 9 BETA-DECAYS (DECAYS WITH CONSTANT A)
n → p + e− + ν̄e (9.1)
this process is called β decay and it explains why there are no free neutrons even though there
are free protons. Neutrons can be long lived when they are part of a nucleus, energetically
neutron decay as above releases Q = 0.8MeV but average binding energy per nucleon are 10
times that, see 8b. In fact the opposite effect can also happen if the nucleus resulting from
a proton changing into a neutron is less massive. This can be triggered by a reduction in
the Coulomb energy and depending on the neutron-proton imbalance may result in the newly
created neutron taking a lower energy state than the proton. Nuclei with large number of
protons will tend to exchange protons for neutrons and nuclei with large numbers of neutrons
compared to protons will tend to exchange protons for neutrons. This processes called β-decay
do not change the mass number A but change Z.
Three processes are possible, all using variations of the β-decay formula (9.1) by moving
particles between final and initial state. All of them include neutrinos whose mass can be
neglected.
β − decay: A neutron in the nucleus decays into a proton, an electron and an electron anti-
neutrino.
n → p + e− + ν̄e (9.2)
Such a decay is possible if the mass difference between the parent and daughter nuclei is
large enough to “afford” the creation of the electron an neutrino. In terms of atom masses
the condition is :
where the fact that we use atom masses takes the additional electron produced in the
decay into account since the daughter nucleus has one more electron than the parent.
β + decay: A proton in the nucleus is changed into a neutron by emitting a positron and a
neutrino:
p → n + e+ + νe (9.5)
For this process to happen the mass difference between the nuclei should be large enough
to ”buy” the mass of the positron. In terms of atomic masses the condition is
we need to add twice the mass of the electron on the right-hand side to account for the
mass of Z electrons and 1 positron.
26
PHYS3621 - Nuclear 9 BETA-DECAYS (DECAYS WITH CONSTANT A)
electron capture: in this case we consider the case in which an electron from the atom com-
bines with a proton to give a neutron and a neutrino:
p + e− → n + νe , (9.8)
and for this process to occur the condition is less stringent because no energy is needed
to produce a positron or electron, only the (negligible) energy for the neutrino is needed.
The condition is
Since these decays do not change A we can quantify this by looking at the semi-empirical
formula eq. 7.7 and eq. (7.6) for a fixed value of A, and substituting N = A − Z
Z2 (A − 2Z)2 δ
M (A, Z) = (A − Z)Mn + Z(Mp + me ) − aV A + as A2/3 + ac 1/3
+ aa − 1/2 ,
A 4A A
(9.11)
we find that the mass formula is quadratic in Z so we expect the masses of the isobars to fit on
a parabola.
In the case of odd A we have one parabola, as shown in Figure 11. In such a case only one
isobar is the lowest and is β-stable. All other isobars can decay to that stable isobar.
In the case of even A nuclei there are two parabolas because of the pairing term. An example
is shown in Figure 11. In some cases we are in a situation where there are two nuclides of the
even-even type lower than a nuclide of odd-odd type.
N In a nutshell
• β decays exchange neutrons and protons and change Z by one unit while leaving
A the same.
• They involve electrons, positrons, neutrinos and anti-neutrinos and occur in 3 forms
β − (n → p), β + (p → n) and electron capture (p → n).
27
PHYS3621 - Nuclear 10 A-CHANGING DECAYS
Figure 11: Mass differences between isobars and the lightest isobar for A = 77 (left) and A = 80
(right). The arrows represent β-decays.
10 A-changing decays
Weak or β decays change the charge of a nucleon but leave the nucleus with the same number of
nucleons A. Electromagnetism and the strong force cannot do this since they preserve both the
number of protons and neutrons but they can mediate the rearranging of these into separate
daughter nuclei. This occurs mostly in 3 processes
i) Proton and neutron emission Very proton or neutron rich nuclei are so unstable that they
emit a single proton or neutron before it can undergo a beta decay. This is a very rare process
that only occurs in a small number of nuclei. The decay formula for these processes are
A A−1
Neutron emission: Z XN −→ Z YN −1 +10 n1 , (10.1)
A A−1
Proton emission: Z XN −→Z−1 YN +10 p0 . (10.2)
ii) α-decay Another possibility for decay is the α-decay where an 4 He nucleus, also called
α-particle is emitted. This decay reduces Z by two units and A by four,
A
Z XN −→A−4 4
Z−2 YN −2 + 2 He2 . (10.5)
It occurs often for heavy nuclei for which binding energy per nucleon is smaller the larger the
mass number, as show in fig. 8b. For this decay to happen the mass of the atom must satisfy:
We can estimate the probability for this decay by considering the effective potential that the
α-particle is subject to, sketched on the left-hand side of fig 12. Outside of the nucleus (that is
further than the range of the nuclear force) the alpha particle only feels the Coulomb potential
of the remaining Z − 2 protons in the nucleus whereas inside the nucleus the attractive strong
force is simplified to produce a square-well potential. For positive total energy then there is a
chance that the α particle tunnels out of the well.
28
PHYS3621 - Nuclear 10 A-CHANGING DECAYS
Energy Energy
induced fission
spontaneous fission
V (r)
↵ particle Coulomb barrier
r
R r
V (r)
Nuclear potential
Figure 12: Left panel: Potential of an α-particle as a function of the distance to the nucleus.
Right panel: Potential for the two daughters in a fission process as a function of the separation.
To estimate the likelihood of the α particle escaping we can first consider the simplified
case of a particle directed towards a thin wall as in fig. 13. The time-independent Schrodinger
equation reads
1 ∂ 2
VI x<0
− + V (x) Ψ = EΨ V (x) = V 0 < x < ∆x (10.7)
2m ∂ 2 x II
0 x > ∆x
iii) Nuclear fission α-decay is only one case in which the nu-
cleus splits into several smaller nuclei. If we look at the energy as we pull the two parts of a
nucleus apart we can reconstruct the potential as a function of the distance between the two
29
PHYS3621 - Nuclear 10 A-CHANGING DECAYS
parts which is sketched in fig. 12. Starting from the ground state of the parent nucleus (which
we assume to be spherically symmetric) at first the surface energy dominates and we have to in-
put energy to stretch it out, but at some finite distance this is overcome by the electromagnetic
interaction whose force tries to push the two same-charge daughter nuclei apart.
The height of the barrier is called the activation energy. Very few nuclides decay through
spontaneous fission, in most cases α-decay is more likely (see fig. 14). The probability of fission
increases with Z and is more likely for heavy nuclides. Fission processes can be induced by
exposing the nuclides to a flux of neutrons. If an atom absorbs a neutron it will acquire its
kinetic energy (although part of it will be needed to produce the daughter nucleus recoil) and it
also gains the bounding energy associated with the additional neutron. This additional energy
can bring the nucleus energy above the fission barrier, triggering the fission of the nucleus.
N In a nutshell
• For A ≳ 100 nuclei are less bound for increasing A and can decay into lighter nuclei
• This can occur through i) proton or neutron emission ii) α particle emission iii)
fission
30
PHYS3621 - Nuclear 11 NUCLEAR POWER
11 Nuclear power
Energy is produced in each nuclear decay and can be a priori extracted for our use. Radioactive
substances will however follow the exponential decay law and disappear within a period of a
few lifetimes which is a problem for storage. Instead if one can find a stable substance which
combined or sparked by another undergoes a reaction and produces energy we have a viable
energy source. The qualitative process is like combustion with the quantitative difference being
that where chemical bounds rearrange to produce an energy of around eV per reaction; nuclear
energy is a million times more efficient. Here we will outline how this energy is harnessed in
fission reactors and a brief sketch of how this might be possible in fusion in the future.
Fission As we pointed out a neutron can be absorbed by a nuclei and trigger fission, in the
case of 235 U ,
1
fission 0n + 235 236 141 92 1
92 U → 92 U −→ 56 Ba + 36 Kr + 3 0 n (11.1)
where we observe that there are three neutrons produced in the reaction; if they were to go on
to excite other 235 U nuclei past their activation energy we would have ourselves 9 neutrons and
the making of a chain reaction. This feature helps sustain fission but it also requires monitoring
and counterbalance.
Figure 15: Cross sections for induced fission and radiative capture for the two main isotopes or
uranium. The shaded regions represent the typical energies for thermal neutrons (around 0.025
eV) and neutrons from the fission process (around 1 MeV). Data from [4]
The balance is provided in part by Uranium itself, in practice the produced neutrons do not
always produce fission when absorbed, one can also have photon emission as the outcome
1
rad. caputure 0n + 235 236 236
92 U → 92 U −→ 92 U + γ (11.2)
In addition 235 U is not found in Nature in isolation but it occurs with a split of 99% 238 U
and 0.7% 235 U. Figure 15 shows the cross section for the absorption of a neutron by these two
isotopes of uranium; here we can see that for 238 U radiative capture dominates for most of the
31
PHYS3621 - Nuclear 11 NUCLEAR POWER
range.
1
rad. caputure 0n + 238 239 239
92 U → 92 U −→ 92 U + γ (11.3)
In particular it does so for MeV neutrons which are produced in fission (with a peak slightly
lower than 1 MeV) which is the reason why uranium in the earth crust does not undergo a
fission chain reaction. In fission power plants reaction is kept going under control with the
combination of three ingredients
• Fuel Uranium with an isotope composition close to its natural abundance. One can read
from fig. 15 what is more likely to occur to a neutron from fission given its energy by
identifying the largest cross section.
• Moderator For these neutrons to be mainly recycled into another fission process they
are cooled down by the moderator. This substance, rich in neutrons but light enough to
sizably bounce off an scattering with a neutron, is commonly heavy water or graphite.
• Control rods In order to decrease the rate of the reaction, control rods of a material that
absorbs neutrons can be inserted in the fissible material, with common materials being
Boron.
Control rod
Fission Absorption
Moderation
Capture
Figure 16: Left: Schematic representation of the moderator and fuel arrangement in a nuclear
reactor. Right: Breazeale Nuclear Reactor at the University of Pennsylvania.
Fusion A drawback of fission is the production of radioactive materials with a thousand year
lifetime whose radiation is armful. While safe disposal of this products should solve the problem,
there is the (so far unrealized) possibility of using nuclear reactions which do not produce toxic
materials.
Fusion makes use of the tightly bounded 42 He nucleus to output energy. The reaction con-
sidered is
3 2 4
1 H + 1 H −→ 2 He + n
32
PHYS3621 - Nuclear 11 NUCLEAR POWER
is therefore a charged very hot substance, a plasma which is handled by magnetic fields in smart
configurations. For these and other reasons fusion presents a challenge which we haven’t met
yet even if there’s progress in experiments like ITER in France.
N In a nutshell
• Fusion makes use of the tightly bound 42 He and offers a waste-free alternative but
is in R&D at present.
33
PHYS3621 - Nuclear 12 SHELL MODEL
Figure 17: First excited state energy. The highest energies (and hence the most stable states)
are concentrated around proton and neutron numbers equal to 2,8,20,28,50,82,126
12 Shell model
The wealth of data on nuclear masses allowed us to learn about the strong interaction and
model the binding energies it produces with some success in terms of the phenomenological
drop formula. This description however cannot explain some outstanding features in the data
nor it does tell us about excited states. Indeed one of the signals of a state being composite
(other than the obvious “it can be broken apart”) is that it has excited states that correspond
to less tightly bounded combinations of its constituents.
Looking at the data we find that certain nuclei with so-called magic numbers both require a
large amount of energy to transition to their first excited state and have larger binding energies
per nucleon than its neighbours see figs 17, 8b. The nuclear shell model provides an explanation.
We have seen that the nucleon potential is more complex than the Coulomb potential that
describes the atom; this nonetheless does not prevents us from employing some of the techniques
of atomic physics, it just means they will have a smaller range of applicability and less precision
on its prediction. For a simple case where we can expect some success consider a nucleon in
the effective potential induced by the rest of the nucleons. We assume that this potential is
spherically symmetric and that the remaining A − 1 nucleons combine to have 0 total angular
momentum (this is usually the case if A−1 is even). The solution to Schrodinger’s equation will
then be labelled by a principal quantum number n for the radial solutions and an angular mo-
mentum index L for the spherical harmonic function YL,m (θ, ϕ) and a total angular momentum
index J, which in our case given neutron and protons have S = 1/2 is L ± 1/2. Spin-statistics
tells us that no two fermions can be on the same state so we expect the protons to settle on the
lowest energy unfilled states and the same for neutrons but since they are distinct fermions they
fill their own set of states. We will use spectroscopic nomenclature as n LJ with L = s, p, d, f....
If we ignore the nuclear spin in a first stage, the situation is that of the Hydrogen atom,
only now our potential is short range (∼ fm) which means we can approximate it to roughly
follow the nucleon density that we derived from experiment in chapter 6
V0
V (r) = − (12.1)
1 + e(r−r0 )/a
with parameters r0 and a fitted from data and this being called the Saxon-Woods potential
34
PHYS3621 - Nuclear 12 SHELL MODEL
Figure 18: Illustration of the shell model, the potential and magic numbers.
Figure 19: Energy levels in a harmonic oscillator (H.O.), and infinite potential well (ISQ), in
the Saxon-Woods potential before (WS) and after including the spin-orbit coupling (WS+SO).
Figure taken form [2]
35
PHYS3621 - Nuclear 12 SHELL MODEL
(WS). With this potential we obtain the levels shown in the central part of Figure 19, (WS) for
comparison shown together with the energy states of a harmonic oscillator (H.O.) and infinite
square well (ISQ). This does account for why 42 He is so tightly bound: two neutrons and two
protons fill the first shell and there is a considerable gap till the next energy state. For higher
A neglecting the spin is not a good approximation, but given our simplified scenario with the
rest of nucleons having no net angular momentum, there is only one other term to consider in
our potential, spin orbit coupling:
Whose correction to the energy can be estimated, first computing the average of the spin
coupling as we do in atomic physics:
PΨ = ±Ψ
In particular for orbital angular momentum we can deduce the parity by the spherical harmonic
property
P YL,m (θ, ϕ) = YL,m (π − θ, ϕ + π) → (−1)L YL,m (θ, ϕ)
Composite states have parity equal to the product of their individual parities. Electromagnetism
and the strong interactions conserve parity which means it is a useful quantum number to label
our states and derive selection rules.
In addition to explaining the location of magic quantum numbers, the shell model can predict
parity and total angular momentum for ground states in certain cases.
Even-even If we have an even number of protons and neutrons we can expect the parity to
be +1 since for every nucleon we can find another with the same parity. As for angular
momentum we expect nucleons to pair up and give no net total as in the Hydrogen
atom. These approximations are specially good for magic numbers with full shells. The
prediction is then J P = 0+ as we can verify in fig. 21 for the doubly magic 168 O
36
PHYS3621 - Nuclear 12 SHELL MODEL
Figure 20: Energy levels for protons and neutrons. The ordering within a band are different for
higher levels, but the structure in bands with magic number of nucleons is the same.
37
PHYS3621 - Nuclear 12 SHELL MODEL
Figure 21: Energy levels for nuclei with proton and neutron numbers close to the magical
number 8.
Even Odd In this case the parity and momentum will be given by the unpaired nucleon, that
is, J P = (L ± 1/2)L . This is again a very good approximation for the unpaired nucleon
being one more than or one short of (also called hole) a magic number. For example 179 F
has one extra proton on top of a closed shell and by fig. 20 one has J P = 5/2+ which is
what is observed fig. 21.
Odd-odd Here the total parity and angular momentum is the combination of the unpaired
proton and neutron, but among the different possibilities the shell model does not tell us
which to choose.
38
PHYS3621 - Nuclear 12 SHELL MODEL
we have
Jp = Jd + ⃗ℓ (12.4)
The rule for angular momentum composition dictates |Jd − ℓ| ≤ Jp ≤ Jd + ℓ but given that we
often know the nuclear total angular momenta it is more useful to rewrite it as
|Jp − Jd | ≤ ℓ ≤ Jp + Jd . (12.5)
It is important to note that this equation leads to results that can appear counter-intuitive. For
example for Jp = Jd = 1 we can have ℓ = 2. It would appear that the angular momentum did
not change and yet the photon carries some angular momentum away. The important point is
that this is a vector equation and in this case J⃗p = −J⃗d and while they have the same norm
their angular momentum did change as a vector. In other words one can have ∆J = 0 with
∆J ̸= 0.
There are two ways for the initial state to change its angular momentum, it can change its
spin or change its orbital angular momentum. If a spin change has occurred, the transition
is classed as “magnetic” if not it is called “electric”. A transition with change on angular
momentum ℓ = |⃗ℓ| is labelled Eℓ or M ℓ if it is electric or magnetic. Evaluation of matrix elements
shows that the amplitude for a change of spin is typically smaller than that of changing the
orbital momentum, so magnetic transitions are normally less likely than the electric transitions
for the same ℓ. On the other hand higher ℓ transitions are less likely so a given process will
normally occur with the lowest ℓ allowed by the conservation constraints. The parity of the EM
radiation is different for electric and magnetic radiation: it is (−1)ℓ for an electric transition
and (−1)ℓ+1 for a magnetic transition. Conservation of parity gives (Pp,d are parities of parent
and daughter nuclei):
(
Pd (−1)ℓ for Eℓ transitions
Pp = (12.6)
Pd (−1)ℓ+1 for M ℓ transitions
where we used Pp−1 = Pp . For each ℓ only one of the E and M transitions will be allowed
by parity. If a Eℓ transition is allowed, parity will allow transitions E(ℓ ± 2), E(ℓ ± 4)... and
M (ℓ ± 1), M (ℓ ± 3)..., but angular momentum conservation will not allow all of them. We will
often find situations where Eℓ and M (ℓ ± 1) are allowed and wonder which one is most likely.
The case Eℓ/M (ℓ + 1) is easy as E transitions are more likely than M transitions and the
likelihood is decreasing strongly with increasing ℓ. The other case with M ℓ and E(ℓ + 1) is
more complicated and the two can be of similar size, leading to interference effects.
Take fig. 21 again for an example, and consider the first excited to ground level transition
of F. Angular momenta for the photon (multipolarity) allowed are 2, 3, 4 whereas parity for Eℓ
transition dictates (−1)ℓ = 1 and (−1)ℓ = −1 for M ℓ. The most likely transition is therefore
E2.
39
PHYS3621 - Nuclear 12 SHELL MODEL
N In a nutshell
• The spin-orbit interaction in the nucleus is much stronger than in the hydrogen
atom and has opposite sign.
• The shell model can explain the magic numbers and predict spin and parity of
ground state of nuclei, as well as some excited states.
• Nuclei in excited states can relax to lower lying states through the emission of
photons. This process is called γ-radiation and obeys the selection rules imposed
by parity and angular momentum conservation.
40
PHYS3621 - Nuclear REFERENCES
References
[1] C. Scholz F. Zetsche B. Povh, K. Rith and M. Lavelle. Particles and Nuclei. Springer
Berlin, Heidelberg, 2008.
[2] Takigawa N. and Washiyama K. Fundamentals of Nuclear Physics. Springer, Tokyo, 2017.
41