PHYSICAL CONSTANTS OF

HYDROCARBONS C, TO C10

Prepared by
ASTM Committee D-2
on Petroleum Products and Lubricants
and
API Research Project 44 on
Hydrocarbons and Related Compounds

ASTM DATA SERIES PUBLICATION DS 4A

List price $4.00

05-004010-12

AMERICAN SOCIETY FOR TESTING AND MATERIALS

1916 Race Street, Philadelphia, Pa. 19103
©BY AMERICAN SOCIETY FOR TESTING AND MATERIALS 1971
Library of Congress Catalog Card Number :79—170766

NOTE

The Society is not responsible, as a body,

for the statements and opinions
advanced in this publication.

Printed in Baltimore, Md.

August 1971
Foreword

The tabulation of the physical constants of d to Cio hydrocarbons,

shown as Tables 1C1.1 through 1C1.17, is based upon a revision of Data
Series 4 prepared for publication by Committee D-2 on Petroleum Products
and Lubricants of the American Society for Testing and Materials. Constants
in both the U.S. and metric systems are tabulated.
The major source of data for thetabulation is the findings of API Research
Project 44, Data on Hydrocarbons and Related Compounds. These data are
either selected critically, calculated precisely, or of good experimental
quality. Data included from other sources are shown in italics. Estimated
values of properties are shown in parentheses. The atomic weights used are
based on oxygen = 15.9994, carbon = 12.011, and hydrogen = 1.0080.
 Related
ASTM Publications

Manual on Hydrocarbon Analysis, STP 332A (1968),

$16.00

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Petroleum Industry, STP 428 (1968),, $3.50
Contents

Table U. S. Units Page

1C1.1 Paraffins 2
1C1.2 Cycloparaffins 8
1C1.3 Monoolefins and Diolefins 14
1C1.4 Cycloolefins 22
1C1.5 Acetylenes 24
1C1.6 Alkylbenzenes, Naphthalene, Indans, and Tetrahydronaphthalene 26
1C1.7 Styrenes and Indenes 28
1C1.8 Gaseous Hydrocarbons, C{ to C5 30
Metric Units
1C1.9 Paraffins 32
1C1.10 Cycloparaffins 38
1C1.11 Monoolefins and Diolefins 44
1C1.12 Cycloolefins 52
1C1.13 Acetylenes 54
1C1.14 Alkylbenzenes, Naphthalene, Indans, and Tetrahydronaphthalene 56
1C1.15 Styrenes and Indenes 58
1C1.16 Gaseous Hydrocarbons, Ci to C5 60
1C1.17 Appendixes
I Key to Footnotes (Superscripts) 61
II Units and Conversion Factors 61
III Definitions of Properties 61
IV Key to References 65
V References 71
 DS4A-EB/Aug. 1971
1C1.1
TABLE 1C1.1—Paraffins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' °»* the. Liquid," no
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
at 1 Pres- Air at 1 Grav- ity*. » sion** °
No. Compound atmos, sure at atmos, ity. ' at 60
deg
Fahr
100 F, deg Tem- 60 F/60 F F, deg v\aTfp
psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at68F at77F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Paraffins, Ci to Ci:
1 Methane, CH(, M.W. 16.043 -258.69 -296.46" 667.8 -116.63 0.0991 O.S> S40' 18.70' S.l>
2 Ethane, C2Hs, M.W. 30.070 -127.48 -297.89" 707.8 +90.09 0.0788 0.8S84d [Link] Sl.l6d %.md
d
3 Propane, CjHs, M.W. 44.097 -43.67 190 -305.84e 616.3 206.01 0.0737 0.5077d 147.2 31.59"* 4.223* 0.00152''

Paraffins, [Link], M.W. 58.124:

4 n-Butane +31.10 61.6 -217.05 550.7 305.65 0.0702 0.58441' 110.6'* [Link]"' 4.8651* 0.00117'' 1.3326'' 1.3292''
5 2-Methylpropane (isobutane) 10.90 72.2 -255.29 529.1 274.98 0.0724 o^si* 119.8"' 35.05* 4.686<i 0.00119''

Paraffins, CBHIS, M.W. 72.151:

6 rc-Pentane 96.92 15.570 -201.51 488.6 385.7 0.0675 0.6310 92.8 39.28 5.251 0.00087 1.35748 1.35472
7 2-Methylbutane (isopentane) 82.12 20.44 -255.83 490.4 369.10 0.0679 0.6247 95.0 38.89 5.199 0.00090 ' 1.35373 1.35088
8 2,2-Dimethylpropane (neopentane) 49.10 SS.9 2.17 464.0 321.13 0.0674 0.5967 105.6 37. H* 4.965'* 0.00104'' 1.342* 1.339d

Paraffins, C«Hn, M.W. 86.178:

9 n-Hexane 155.72 4.956 -139.58 436.9 453.7 0.0688 0.6640 81.6 41.34 5.526 0.00075 1.37486 1.37226
10 2-Methylpentane 140.47 6.767 -244.63 436.6 435.83 0.0681 0.6579 83.6 40.96 5.475 0.00078 1.37145 1.36873
11 3-MethyIpentane 145.89 6.098 453.1 448.3 0.0681 0.6689 80.0 41.65 5.568 0.00075 1.37652 1.37386
12 2,2-Dimethylbutane 121.52 9.856 -147.72 446.8 420.13 0.0667 0.6540 84.9 40.72 5.443 0.00078 1.36876 1.36595
13 2,3-Dimethylbutane 136.36 7.404 -199.38 453.5 440.29 0.0665 0.6664 80.8 41.49 5.546 0.00075 1.37495 1.37231

Paraffins, C7H18, M.W. 100.205:

14 n-Heptane 209.17 1.620 -131.05 396.8 512.8 0.0691 0.6882 74.1 42.85 5.728 0.00069 1.38764 1.38511
15 2-MethyIhexane 194.09 2.271 -180.89 396.5 495.00 0.0673 0.6830 75.7 42.53 5.685 0.00068 1.38485 1.38227
16 3-MethyIhexane 197.32 2.130 408.1 503.78 0.0646 0.6917 73.1 43.07 5.757 0.00069 1.38864 1.38609
17 3-Ethylpentane 200.25 2.012 -181.48 419.3 513.48 0.0665 0.7028 69.9 43.76 5.850 0.00070 1.39339 1.39084
18 2,2-Dimethylpentane 174.54 3.492 -190.86 402.2 477.23 0.0665 0.6782 77.1 42.23 5.645 0.00072 1.38215 1.37955
19 2,3-Dimethylpentane 193.61 2.351 421.8 507.56 0.0628 0.6996 70.8 43.56 5.823 0.00070 1.39196 1.38945
20 2,4-Di methylpentane 176.89 3.292 -182.63 396.9 475.95 0.0668 0.6773 77.4 42.17 5.637 0.00072 1.38145 1.37882
21 3,3-Di methyl pentane 186.91 2.773 -210.01 427.2 505.85 0.0662 0.6976 71.3 43.44 5.807 0.00065 1.39092 1.38842
22 2,2,3-Trimethylbutane 177.58 3.374 -12.82 428.4 496.44 0.0636 0.6946 72.2 43.25 5.782 0.00069 1.38944 1.38692

Paraffins, CsHis, M.W. 114.232:

23 n- Octane 258.22 0.537 -70.18 360.6 564.22 0.0690 0.7068 68.7 44.01 5.883 0.00062 1.39743 1.39505
24 2-Methylheptane 243.78 0.768 -164.19 360.3 547.68 0.0685 0.7021 70.0 43.72 5.844 0.00061 1.39494 1.39257
25 3-Methylheptane 246.08 0.731 -184.98 369.3 554.94 0.0651 0.7101 67.8 44.22 5.911 0.00062 1.39848 1.39610
26 4-Methylheptane 243.89 0.765 -185.72 368.7 551.46 0.0667 0.7090 68.1 44.15 5.902 0.00066 1.39792 1.39553
27 3-Ethylhexane 245.37 0.748 378.3 558.21 0.0638 0.7178 65.6 44.70 5.976 0.00063 1.40162 1.39919
28 2,2-Dimethylhexane 224.32 1.221 -186.12 366.8 530.10 0.0670 0.6997 70.7 43.57 5.824 0.00065 1.39349 1.39104
29 2,3-Dimethylhexane 240.10 0.861 381.2 554.61 0.0656 0.7165 66.0 44.62 5.965 0.00063 1.40113 1.39880
30 2,4-Dimethylhexane 228.98 1.097 370.8 536.67 0.0662 0.7047 69.3 43.88 5.866 0.00066 1.39534 1.39291
31 2,5-Dimethylhexane 228.39 1.101 -132.07 360.6 530.44 0.0676 0.6979 71.2 43.46 5.810 0.00065 1.39246 1.39004
32 3,3-Di methylhexane 233.55 1.030 -194.98 384.9 551.97 0.0621 0.7143 66.6 44.48 5.946 0.00062 1.40009 1.39782
33 3,4-Di methylhexane 243.92 0.797 390.5 564.26 0.0654 0.7236 64.1 45.06 6.023 0.00063 1.40406 1.40180
34 2-Methyl-3-ethyIpentane 240.18 0.874 -174.91 391.6 561.09 0.0621 0.7236 64.0 45.06 6.024 0.00063 1.40401 1.40167
35 3-Methyl-3-etTiylpentane 244.88 0.834 -131.52 407.2 578.17 0.0638 0.7315 61.9 45.55 6.089 0.00059 1.40775 1.40549
36 2,2,3-Tri methylpentane 229.72 1.142 -170.07 395.9 554.63 0.0611 0.7202 65.0 44.85 5.996 0.00063 1.40295 1.40066
37 2,2,4-Tri methylpentane 210.63 1.708 -161.27 372.4 519.46 0.0656 0.6962 71.7 43.35 5.795 0.00065 1.39145 1.38898
38 2,3,3-Trimethylpentane 238.58 0.967 -149.68 409.0 572.74 0.0638 0.7303 62.2 45.48 6.080 0.00059 1.40750 1.40522
39 2,3,4-Trimethylpentane 236.25 0.976 -164.56 395.9 559.87 0.0646 0.7233 64.1 45.04 6.021 0.00063 1.40422 1.40198
40 2,2,3,3-Tetramethylbutane 223.65 0.83^ +213.24 416 562.6 0.0646 ... ...

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

Copyright © 1971 by ASTM International [Link]

 1C1.1

TABLE 1C1.1—Paraffins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability
sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,a Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10< (np-nc)/<2 centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form H20 Motor Method Research Method No.
Fahr Boiling (liquid)+CO2 (gas) (gas)+C02 (gas) D357 D 908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

[Link] 219.22 .... 5.0 15 1

O
0.4097 0.9256 210.41 2.9 13 +0.05* +1.6*.' 2
0.3881 0.5920 183.05 21 498" 19 767 2.1 9.5 97.1 1.8*'' 3

181.6 0.S867 0.5636 165.65 21 136" 102 980 19 493 94 970 1.8 8.4 89.6' +0.4*= 93.8' +0.4* 4
225,7 0.3872 0.5695 157.53 21 086° 98 990 19 443 91 280 1.8 8.4 97.6 +0.10*' 5

98.1 98.0 0.330<i 159.3 0.3883 0.5U1 153.59 20 926° 110 120 19 339 101 770 1.4 8.3 62.6' 84.2' 61.7' 86.0' 6
98.7 98.6 170.6 0.3827 0.5353 147.13 20 887" 108 800 19 300 100 540 1.4 (8.3) 90.3 92.3 +1.0* 7
9811 98d 216* (0.3866) 0.554 136.68 20 819" 103 560 19 282 95 660 1.4 (8.3) 80.2 99.9 85.5 0.1* 8

98.1 98.0 0.4137 155.5 0.3864 0.6832 143.95 20 784 115 060 19 232 106 470 1.2 7.7 26.0 65.2 24.8 65.3 9
98.7 98.6 164.8 0.8872 0.5264 138.67 20 756 113 850 19 205 105 340 1.2 (7-7) 73.5 91.1 73.4 93.1 10
97.2 97.1 156.7'' 0.S815 0.507 140.09 20 768 115 840 19 217 107 180 (1.2) (7.7) 74.3 91.3 74.5 93.4 11
99.9 99.8 , ,_, 178.2* 0.S809 0.5165 131.24 20 711 112 930 19 160 104 470 1.2 (7.7) 93.4 +2.1* 91.8 +0.6* 12
98.4 98.3 161.4* 0.378 0.5127 136.08 20 743 115 250 19 191 106 620 (1.2) (7.7) 94.3 +1.8* +0.3* 13

97.8 97.7 0.5214 0.3425<! 157.5 0.3875 0.5283 136.01 20 681 118 660 19 156 109 910 1.0 7.0 0.0 46.9 0.0 43.5 14
98.4 98.5 165.2 (0.390) 0.5223 131.59 20 658 117 630 19 133 108 950 (1.0) (7.0) 46.4 74.5 42.4 73.2 15
97.5 97.4 158.9 ([Link]) 0.511 132. H 20 668 119 160 19 144 110 370 (1.0) (7-0) 55.8 81.0 52.0 74.7 16
95.7 95.7 150.3 (0.390) 0.511,5 132.83 20 679 121 130 19 154 112 200 (1.0) (7.0) 69.3 88.0 65.0 85.0 17
99.4 99.3 171.7 (0.396) 0.5171 125.13 20 620 116 610 19 095 107 980 (1.0) (7.0) 95.6 +2.4* 92.8 +0.4* 18
96.4 96.2 153.7 (0.391) 0.50 130.39 20 642 120 370 19 117 111 470 (1.0) (7.0) 88.5 +0.3* 91.1 +0.3* 19
98.7 98.6 173.8 0.3906 0.6247 126.58 20 636 116 510 19 111 107 900 (1.0) (7.0) 83.8 99.1 83.1 96.6 20
97.4 97.1 158.9 (0.895) 0.502 127.21 20 638 120 050 19 113 111 180 (1.0) (7.0) 86.6 +0.6* 80.8 97.7 21
98.7 98.3 162.0 0.3812 0.4995 124.21 20 627 119 430 19 103 110 610 (1.0) (7.0) +0.1* +3.1* +1.8* 22

98.1 98.0 0.6476 0.4039 159.1 (0.3876) 0.5239 129.53 20 604 121 420 19 099 112 550 0.96 28.1 24.8 23
98.6 98.5 165* (0.3871) 0.5173 127.2 20 585 120 500 19 079 111 680 0.98 23.0' 60.8' 20.6' 57.8' 24
97.6 97.5 162.0' (0.383) 0.5134 127.6 20 595 121 930 19 090 113 020 (0.98) 35.0 68.0 26.8 59.6 25
97.6 97.5 160.9* (0.S8S) 0.5152 127.53 20 597 121 750 19 092 112 850 (0.98) 39.0 70.1 26.7 61.1 26
96.5 96.4 155.7* (0.8838) 0.50 126.50 20 601 123 300 19 097 114 300 (0.98) 52.4 80.0 33.5 61.1 22
99.8 99.7 172* (0.892) 0.506 121.4 20 559 119 910 19 054 111 140 (0.98) 77.4 95.2 72.5 93.3 23
97.1 97.0 159.1* (0.8824) 0.50 124.98 20 594 123 020 19 089 114 030 (0.98) 78.9 93.7 71.3 91.7 24
97.9 97.8 164.1* (0.368) 0.51 122.7 20 577 120 890 19 072 112 050 (0.98) 69.9 89.0 65.2 87.3 37
99.1 99.0 172.4'' (0.373) 0.5114 122.8 20 564 119 670 19 059 110 910 (0.98) 55.7 82.9 55.2 81.6 38
97.4 97.3 162* (0.384) 0.5053 122.2 20 575 122 530 19 070 113 570 (0.98) 83.4 100 75.5 94.6 39
96.7 96.6 154.4* 0.50 125.24 20 596 124 250 19 091 115 170 (0.98) 81.7 97.1 76.3 94.7 30
96.2 96.1 153.0* 0.S79S 0.50 124.08 20 605 124 320 19 100 115 240 (0.98) 88.1 +0.1* 87.3 100 31
95.9 95.8 150.6* (0.3782) 0.49 123.43 20 593 125 590 19 088 116 410 (0.98) 88.7 +0.2* 80.8 95.9 35
97.3 97.2 159.4* (0.388) 0.50 120.5 20 577 123 570 19 072 114 530 (1.0) 99.9 +2.0* +1.2* 36
100.6 100.5 175.1 0.3768 0.4892 116.71 20 569 119 390 19 064 110 660 1.0 100.0 +3.0* 100.0 +3.0* 37
96.2 96.1 152.6* (0.380) 0.5046 121.7 20 590 125 320 19 085 116 220 (1.0) 99.4 +2.0* +0.6* 38
97.0 96.9 154.9* 0.3876 0.5094 123.20 20 585 124 130 19 079 115 050 (1.0) 95.9 +0.7* +0.2* 39
0.3908 118.3 (1.0) 40

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p.>.64»
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.
 1C1.1
TABLE 1C1.1—Paraffins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' •• * the Liquid," no
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.at 1 Pres- Air at 1 Grav- ity*. « sion*- °
No. Compound atmos, sure at atmos, ity o. c at 60
deg 100 F, deg Tem- 60 F/60 F F, deg V\9T/p
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at68F at 77 F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Paraffins, CnHa, M.W. 128.259:

41 n-Nonane 303.47 0.179 -64.28 332 610.68 0.0684 0.7217 64.6 44.94 6.008 0.00063 1.40542 1.40311
42 2-Methyloctane 289.90 0.25 -112.67 332 596.5 0.0676 0.7175 65.7 44.68 5.973 0.00058 1.4031 1.4008
43 3-Methyloctane 291.61 0.25 -161.7 339 602.6 0.0661 0.7245 63.8 45.11 6.030 0.00059 1.4063 1.4040
44 4-Methyloctane 288.39 0.27 -171.8 339 598.1 0.0653 0.7244 63.8 45.11 6.030 0.00063 1.4062 1.4039
45 3-Ethylheptane 289.4 0.27 348 603.3 0.0638 0.7308 62.1 45.51 6.084 0.00064 1.4093 1.4070
46 4-Ethylheptane 286.2 0.30 347 598.6 0.0631 0.7324 61.7 45.61 6.097 0.00064 1.4096 1.4073
47 2,2-Dimethylheptane 270.86 0.42 -171.38 337 580.3 0.0657 0.7146 66.5 44.50 5.949 0.00062 1.4016 1.3993
48 2,3-Dimethylheptane 284.9 0.31 348 601.7 0.0643 0.7302 62.3 45.47 6.078 0.00059 1.4085 1.4062
49 2,4-DimethyIheptane 271.22 0.40 339 578.7 0.0646 0.7194 65.2 44.80 5.989 0.00058 1.4034 1.4011
60 2,5-Dimethylheptane 276.8 0.36 341 586.4 0.0652 0.7210 64.7 44.90 6.002 0.00063 1.4038 1.4015
51 2,6-Dimethylheptane 276.40 0.36 -153.2 334 580.6 0.0668 0.7131 66.9 44.41 5.937 0.00062 1.4007 1.3983
52 3,3-Dimethylheptane 278.64 0.37 353 599.7 0.0632 0.7299 62.4 45.45 6.076 0.00064 1.4088 1.4063
53 3,4-Dimethylheptane 285.1 0.31 357 605.8 0.0628 0.7356 60.9 45.81 6.124 0.00055 1.4111 1.4089
54 3,5-Dimethylheptane 276.8 0.36 348 590.2 0.0637 0.7265 63.3 45.24 6.048 0.00054 1.4067 1.4044
55 4,4-Di methylheptane 275.4 0.40 353 594.1 0.0626 0.7299 62.4 45.45 6.076 0.00064 1.4076 • 1.4053
56 2-Methyl-3-ethylhexane 280.4 0.35 356 599.2 0.0621 0.7378 60.3 45.94 6.141 0.00064 1.4120 1.4097
67 2-Methyl-4-ethylhexane 272.8 0.40 348 584.6 0.0629 0.7278 62.9 45.32 6.058 0.00064 1.4068 1.4046
68 3-Methyl-3-ethylhexane 296.1 0.33 370 615.9 0.0608 0.7454 58.3 46.42 6.205 0.00056 1.4140 1.4120
59 3-Methyl-4-ethyIhexane 284.7 0.32 364 609.3 0.0612 0.7440 58.7 46.33 6.193 0.00056 1.4149 1.4128
60 2,2,3-Trimethylhexane 272.50 0.43 362 598.8 0.0622 0.7336 61.4 45.68 6.107 0.00055 1.4105 1.4082
61 2,2,4-Trimethylhexane 259.79 0.57 -184.0 345 572.9 0.0633 0.7196 65.1 44.81 5.990 0.00058 1.4033 1.4010
62 2,2,5-Trimethylhexane 255.37 0.62 -158.37 338 562.8 0.0648 0.7182 65.5 44.72 5.978 0.00058 1.39972 1.39728
63 2,3,3-Trimethylhexane 279.84 0.38 -178.23 370 613.4 0.0613 0.7418 59.3 46.19 6.175 0.00056 1.4141 1.4119
64 2,3,4-Trimethylhexane 282.31 0.35 366 610.5 0.0617 0.7433 58.9 46.29 6.188 0-00056 1.4144 1.4120
65 2,3,5-Trimethylhexane 268.43 0.45 -198.0 348 583.0 0.0636 0.7262 63.3 45.22 6.045 0.00063 1.4061 1.4037
66 2,4,4- Tri methy 1 hexane 267.19 0.504 -172.07 353 587.3 0.0624 0.7278 62.9 45.32 6.058 0.00054 1.40745 1.4055
67 3,3,4-Trimethylhexane 284.86 0.34 -150.12 381 624.6 0.0605 0.7497 57.2 46.69 6.242 0.00065 1.4178 1.4154
68 3,3-Diethylpentane 295.14 0.282 -27.56 388 638.4 0.0591 0.7575 55.3 47.17 6.306 0.00052 1.42051 1.41837
69 2,2-Dimethyl-3-ethylpentane 272.91 0.43 -147.04 370 603.3 0.0607 0.7389 60.0 46.01 6.151 0.00055 1.4123 1.4102
70 2,3-Dimethyl-3-ethy lpentane 292.5 0.30 389 632.7 0.0596 0.7591 54.9 47.27 6.319 0.00057 1.4221 1.4197
71 2,4-Dimethyl-3-ethylpentane 278.06 0.39 -188.25 366 604.6 0.0611 0.7421 59.2 46.21 6.177 0.00056 1.4137 1.4115
72 2,2,3,3-Tetramethylpentane 284.53 0.362 + 14.20 397 639.9 0.0597 0.7606 54.5 47.37 6.332 0.00052 1.42360 1.42140
73 2,2,3,4-Tetramethylpentane 271.45 0.476 -185.96 372 606.2 0.0612 0.7430 58.9 46.27 6.185 0.00056 1.41472 1.41246
74 2,2,4,4-Tetramethylpentane 252.13 0.730 -87.16 342 568.8 0.0629 0.7236 64.1 45.06 6.023 0.00054 1.40694 1.40459
75 2,3,3,4-Tetramethylpentane 286.82 0.340 -151.78 391 636.6 0.0601- 0.7587 55.0 47.26 6.317 0.00057 1.42222 1.42003

Paraffins, CioH!2, M.W. 142.286:

76 n-Deoane 345.48 0.0597 -21.36 304 652.1 0.0679 0.7342 61.2 45.72 6.112 0.00055 1.41189 1.40967
77 2-Methylnonane 332.65 0.085 -102.32 304 639.0 0.0671 0.7306 62.2 45.50 6.082 0.00064 1.4100 1.4075.
78 3-Methylnonane 334.0 0.085 -120.59 310 . 644.7 0.0655 0.7375 60.4 45.93 6.140 0.00064 1.4125 1.4103
79 4-Methylnonane 330.3 0.095 -145.7 310 639.3 0.0647 0.7364 60.7 45.86 6.131 0.00060 1.4118 1.4095
80 5-Methylnonane 329.2 0.098 -125.81 310 637.9 6.0645 0.7367 60.6 45.88 6.133 0.00060 1.4122 1.4100
81 3-Ethyloctane 331.7 0.095 317 645.1 0.0632 0.7442 58.6 46.34 6.195 0.00056 1.4156 1.4136
82 4-Ethyloctane 326.61 0.11 316 637.9 0.0621 0.7422 59.1 46.22 6.179 0.00056 1.4151 1.4131
83 2,2-Dimethyloctane 314.4 0.14 309 624.0 0.0653 0.7285 62.7 45.36 6.064 0.00055 1.4082 1.4060
84 2,3-Dimethyloctane 327.81 0.11 317 644.2 0.0638 0.7420 59.2 46.21 6.177 0.00056 1.4149 1.4127
85 2,4-Dimethyloctane 312.6 0.15 310 619.3 0.0637 0.7305 62.2 45.49 6.081 0.00055 1.4091 1.4069
86 2,5-Dimethyloctane 317.3 0.13 312 626.0 0.0641 0.7343 61.2 45.73 6.113 0.00055 1.4112 1.4089
87 2,6-DimethyIoctane 320.74 0.12 312 626.0 0.0648 0.7319 61.8 45.58 6.093 0.00055 1.4106 1.4084
88 2,7-Dimethyloctane 319.80 0.12 -65 304 625.8 0.0664 0.7285 62.7 45.36 6.064 0.00059 1.4086 1.4062
89 3,3-Dimethyloctane 322.2 0.13 322 642.4 0.0627 0.7432 58.9 46.28 6.187 0.00056 1.4165 1.4142
90 3,4-Dimethyloctane 326.1 0.11 325 645.6 0.0620 0.7489 57.4 46.64 6.235 0.00056 1.4182 1.4159
91 3,5-Dimethyloctane 318.9 0.13 317 631.8 0.0625 0.7408 59.5 46.13 6.167 0.00055 1.4139 1.4115
92 3,6-Dimethyloctane 321.4 0.12 317 635.4 0.0633 0.7405 59.6 46.11 6.164 0.00060 1.4139 1.4115
93 4,4-Dimethyloctane 316.5 0.15 320 632.8 0.0617 0.7385 60.1 45.99 6.148 0.00055 1.4144 1.4122
94 4,5-Dimethyloctane 323.87 0.12 325 642.4 0.0615 0.7511 56.9 46.77 6.252 0.00056 1.4190 1.4167

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p.| 04.;
2. M.W. = molecular weight.
3. See Appendix I, p{ 61 -i for definitions of superscripts.
 1C1.1

TABLE 1C1.1—Paraffins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,a Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10' (nr-nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form H20 Motor Method Research Method No.
Fahr Boiling (liquid)+CO2 (gas) (gas)+C02 (gas) D357 D 908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

97.4 97.2 0.8087 0.4766 164.7 0.3840 0.6228 123.76 to 544 123 610 19 056 114 670 0.87• 2.9 41
98.5 98.4 171.5'' (0.398) 0.516 122.9 20 525 122 780 19 036 113 870 (0.85) 42
97.6 97.5 167.0* (0.388) 0.511 123.3 20 532 123 990 19 044 115 010 (0.85) 43
97.6 97.5 166.1'' ([Link]) 0.51 122.7 20 533 124 000 19 045 115 010 (0.85) 44
96.7 96.6 163'' (0.379) 0.50 123.1 20 540 125 150 19 052 116 080 (0.85) 45
96.7 96.6 154' 0.50 122.9 20 542 125 430 19 053 116 340 (0.85) 46
99.6 99.5 174'' (0.398) 0.503 116.6 20 499 124 140 19 011 113 270 (0.85) 30.5 33.5 50.3 77.2 47
97.3 97.2 163.8' 0.51 121.0 20 526 124 940 19 038 115 890 (0.88) 48
97.9 97.8 172* 0.51 118.5 20 515 123 050 19 027 114 120 (0.85) 49
97.9 97.8 172* 0.51 119.3 20 514 123 310 19 026 114 370 (0.85) 50
99.0 98.9 176.0' (0.383) 0.52 119.1 20 507 121 940 19 019 113 090 (o.85) 51
97.5 97.4 165' 0.503 118.4 20 514 124 830 19 026 115 770 (0.85) 52
96.9 96.8 158' 0.50 121.9 20 534 125 940 19 045 116 800 (0.85) 53
97.0 96.9 0.51 119.5 20 521 124 300 19 033 115 280 (0.85) 54
97.5 97.4 0.51 118.5 20 516 124 840 19 027 115 780 (0.85) 55
96.7 96.6 0.50 120.6 20 534 126 280 19 046 117 130 (0.85) 56
97.0 96.9 0.51 119.5 20 523 124 510 19 034 115 480 (0.85) 57
96.0 95.9 0.49 119.8 20 534 127 600 19 046 118 350 (0.85) 58
95.6 95.5 0.49 122.0 20 541 127 400 19 052 118 160 (0.85) 59
97.4 97.3 162' 0.50 116.6 20 518 125 490 19 030 116 390 (0.85) 60
98.9 98.8 172' (0.383) 0.51 114.0 20 517 123 080 19 029 114 160 (0.85) 61
98.8 99.0 180.9 (0.376) 0.52 113.2 20 482 121 480 18 993 112 650 (0.85) 62
96.4 96.3 (0.384) 0.50 117.3 20 523 126 910 19 035 117 710 (0.85) 63
96.5 96.4 0.50 119.6 20 527 127 210 19 039 117 990 (0.85) 64
97.9 97.8 169 (0.S68) 0.51 116.7 20 513 124 190 19 025 115 180 (0.85) 65
98.2 98.2 (0.384) 0.51 115.0 20 526 124 530 19 038 115 500 (0.85) 66
95.4 95.3 ([Link]) 0.49 117.8 20 535 128 370 19 047 119 060 (0.85) 67
94.6 94.3 149' (0.S780) 0.48 120.6 20 542 129 730 19 054 120 330 (0.85) 91.6 +0.1* 84.0 97.1 68
96.4 96.3 (0.383) 0.51 116.7 20 551 126 600 19 063 117 430 (0.85) 99.5 +0.8* +1.8* >+6* 69
94.7 94.6 151* 0.48 118.4 20 544 130 010 19 056 120 590 (0.85) 70
96.5 96.4 (0.369) 0.50 118.7 20 561 127 190 19 073 117 990 (0.85) 96.6 +0.4* +0.5* +3.6* 71
96.1 95.9 154* (0.387) 0.48 118.2 20 533 130 200 19 044 120 760 0.84*" 95.0 99.4 +3.6* >+4.0* 72
96.8 96.8 (0.380) 0.50 114.9 20 534 127 190 19 046 117 970 (0.85) 73
100.8 101.0 167* (0.386) 0.51 110.1 20 527 123 840 19 038 114 860 (0.85) 74
95.5 95.5 (0.380) 0.48 117.1 20 534 129 880 19 045 120 460 (0.85) 75

98.1 98.0 1.004 0.5591 170.6 0.3835 0.5208 118.68 20 493 125 440 19 017 116 410 0.78m 2.6 76
99 99 176.5' (0.398) 0.517 118.5 20 477 124 730 19.001 115 740 (0.75) 77
98 98 172.9' (0.405) 0.511 118.2 20 483 125 950 19 007 116 880 (0.75) 78
98 98 172.9' (O.4OS) 0.514 117.2 20 485 125 780 19 009 116 720 (0.75) 79
98 98 172.2' (O.4OS) 0.510 116.9 20 485 125 820 19 009 116 760 (0.75) 80
96 96 167* 0.50 116.9 20 481 127 060 19 005 117 910 (0.75) 81
96 96 0.51 115.7 20 494 126 820 19 018 117 680 (0.75) 82
100 100 178* 0.505 113.9 20 451 124 200 18 974 115 240 (0.75) 83
97 97 167' 0.51 115.4 20 479 126 680 19 004 117 560 (0.75) 84
98 98 176* 0.52 114.3 20 469 124 660 18 993 115 670 (0.75) 85
99 99 171* 0.51 114.3 20 468 125 310 18 994 116 280 (0.75) 86
99 99 172' 0.51 115.4 20 467 124 890 18 992 115 890 (0.75) 87
98.7 98.6 174.2 (0.888) 0.510 115.6 20 460 124 260 18 986 115 300 (0.75) 88
97 97 167* 0.502 113.7 20 469 126 830 18 993 117 680 (0.75) 89
97 97 163* 0.50 114.9 20 486 127 910 19 010 118 700 (0.75) 90
97 97 0.51 114.0 20 476 126 460 19 000 117 340 (0.75) 91
97 97 169' 0.51 115.0 20 475 126 390 18 998 117 280 (0.75) 92
97 97 0.51 112.5 20 469 126 030 18 994 116 950 (0.75) 93
95.9 95.8 165* 0.50 114.4 20 487 128 270 19 011 119 030 (0.75) 94

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 . for definitions of superscripts.
1C1.1
TABLE 1C1.1—Paraffins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*- a< b the Liquid,0 ni>
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.atl Pres- Air at 1 Grav- ity*- c sion*' °
No. Compound atmos, sure at atmos, ity 0. 0 at 60
deg 100 F, deg Tem- 60 F/60 F F, deg V\dT) „
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at68F at 77 F
psi • deg cu ft cu ft gal Fahr
Fahr per lb

Paraffins C10H22 (continued):

95 4-w-Propylheptane 315.5 0.13 316 622.4 0.0614 0.7400 59.7 46.08 6.160 0.00055 1.4135 1.4113
96 4-Isopropylheptane 318.0 0.14 323 634.3 0.0605 0.7433 58.9 46.29 6.188 0.00056 1.4155 1.4132
97 2-Methyl-3-ethylheptane 322.2 0.13 323 640.0 0.0612 0.7477 57.7 46.56 6.224 0.00056 1.4174 1.4151
tte 2-Methyl-4-ethylheptane 313.2 0.15 317 623.7 0.0614 0.7401 59.7 46.09 6.161 0.00055 1.4137 1.4114
99 2-MethyI-5-ethylheptane 319.5 0.13 317 632.7 0.0625 0.7397 59.8 46.06 6.157 0.00055 1.4134 1.4111
100 3-Methyl-3-ethylheptane 326.8 0.12 335 656.4 0.0599 0.7542 56.1 46.97 6.279 0.00056 1.4208 1.4185
101 3-Methyl-4-ethylheptane 324.0 0.13 331 646.3 0.0597 0.7545 56.0 46.99 6.282 0.00056 1.4206 1.4183
102 3-Methyl-5-ethylheptane 316.8 0.14 323 632.5 0.0609 0.7447 58.5 46.38 6.200 0.00056 1.4164 1.4141
103 4-Methyl-3-ethylheptane 325.4 0.12 331 648.3 0.0600 0.7547 56.0 47.00 6.283 0.00056 1.4207 1.4184
104 4-Methyl-4-ethylheptane 321.4 0.14 335 648.9 0.0591 0.7551 55.9 47.02 6.286 0.00057 1.4210 1.4187
105 2,2,3-Trimethylheptane 315.7 0.15 329 641.7 0.0615 0.7464 58.1 46.48 6.213 0.00056 1.4168 1.4145
106 2,2,4-Trimethylheptane 298.9 0.22 314 610.5 0.0621 0.7316 61.9 45.56 6.090 0.00055 1.4092 1.4069
107 2,2,5-Trimethylheptane 303.4 0.20 314 616.8 0.0629 0.7322 61.7 45.60 6.096 0.00055 1.4101 1.4078
108 2,2,6-Trimethylheptane 300.11 0.20 -157 309 608.5 0.0645 0.7279 62.9 45.33 6.060 0.00054 1.4078 1.4055
109 2,3,3-Trimethylheptane 320.4 0.14 337 652.1 0.0606 0.7529 56.4 46.89 6.268 0.00056 1.4202 1.4179
110 2,3,4-Trimethylheptane 319.8 0.14 332 645.3 0.0606 0.7526 56.5 46.87 6.266 0.00056 1.4195 1.4172
111 2,3,5-Trimethylheptane 321.3 0.14 325 643.5 0.0616 0.7492 57.4 46.66 6.238 0.00056 1.4169 1.4146
112 2,3,6-Tri methy lheptane 312.8 0.16 317 628.0 0.0630 0.7388 60.0 46.01 6.151 0.00055 1.4131 1.4108
113 2,4,4-Trimethylheptane 303.8 0.21 322 621.0 0.0609 0.7387 60.1 46.00 6.149 0.00055 1.4143 1.4120
114 2,4,5-TrimethyIheptane 313.7 0.16 325 632.8 0.0612 0.7452 58.2 46.41 6.204 0.00056 1.4160 1.4137
115 2,4,6-Trimethylheptane 297.7 0.21 312 603.0 0.0630 0.7269 63.1 45.26 6.050 0.00054 1.4071 1.4048
116 2,5,5-Trimethy lheptane 307.08 0.18 322 625.6 0.0619 0.7441 58.7 46.34 6.195 0.00056 1.4149 1.4126
117, 3,3,4-Trimethylheptane 323.4 0.14 344 660.2 0.0592 0.7606 54.5 47.37 6.332 0.00057 1.4236 1.4213
118 3,3,5-Trimethylheptane 312.26 0.17 328 636.8 0.0605 0.7469 57.9 46.51 6.217 0.00056 1.4170 1.4147
119 3,4,4-Tri methylheptane 322.0 0.14 344 658.2 0.0590 0.7614 54.3 47.42 6.339 0.00057 1.4235 1.4212
120 3,4,5-Trimethylheptane 324.5 0.13 339 655.7 0.0596 0.7598 54.7 47.32 6.326 0.00057 1.4229 1.4206
121 2-Methyl-3-isopropylhexane 332.1 0.13 332 662.5 0.0596 0.7515 56.8 46.80 6.256 0.00056 1.4195 1.4172
122 3,3-Diethyl hexane 331.3 0.11 350 670.6 0.0574 0.7654 53.4 47.67 6.372 0.00057 1.4258 1.4235
123 3,4-Diethylhexane 327.0 0.12 338 654.4 0.0584 0.7551 55.9 47.02 6.286 0.00057 1.4190 1.4167
124 2,2-Dimethyl-3-ethylhexane 313.0 0.17 335 641.5 0.0592 0.7526 56.5 46.87 6.266 0.00056 1.4197 1.4174
125 2,2-Dimethyl-4-ethylhexane 297 0.24 322 610.9 0.0607 0.7381 60.2 45.96 6.144 0.00055 1.4131 1.4107
126 2,3-Di methyl-3-ethyl hexane 326.7 0.13 351 668.8 0.0581 0.7678 52.8 47.82 6.393 0.00057 1.4270 1.4247
127 2,3-Dimethyl-4-ethylhexane 321.6 0.14 339 651.6 0.0590 0.7595 54.8 47.30 6.323 0.00057 1.4226 1.4203
128 2,4-Di methyl-3-et hy lhexane 320.2 0.14 339 649.6 0.0588 0.7593 54.9 47.29 6.322 0.00057 1.4225 1.4202
129 2,4-DimethyI-4-ethyIhexane 322.0 0.14 344 658.2 0.0590 0.7604 54.6 47.36 6.331 0.00057 1.4235 1.4212
130 2,5-Dimethyl-3-ethylhexane 309.4 0.18 325 626.7 0.0605 0.7447 58.5 46.38 6.200 0.00056 1.4157 1.4134
131 3,3-Dimethyl-4-ethylhexane 325.2 0.14 351 666.7 0.0578 0.7677 52.8 47.81 6.391 0.00057 1.4269 1.4246
132 3,4-Di methyI-3-ethylhexane 323.8 0.14 351 664.7 0.0575 0.7675 52.9 47.80 6.390 0.00057 1.4267 1.4244
133 2,2,3,3-Tetramethylhexane 320.61 0.16 -65 15 357 671.2 0.0583 0.7684 52.7 47.85 6.397 0.00053 1.42818 1.42600
134 2,2,3,4-Tetramethyl hexane 317.8 0.17 344 657.1 0.0591 0.7592 54.9 47.28 6.320 0.00057 1.4216 1.4193
135 2,2,3,5-Tetramethylhexane 299.1 0.23 329 622.8 0.0608 0.7422 59.1 46.22 6.179 0.00060 1.4142 1.4119
136 2,2,4,4-Tetramethylhexane 308.8 0.23 326 639.0 0.0602 0.7503 57.1 46.72 6.246 0.00056 1.4208 1.4185
137 2,2,4,5-Tetramethylhexane 298.22 0.24 322 617.7 0.0612 0.7396 59.8 46.06 6.157 0.00055 1.41318 1.41095
138 2,2,5,5-Tetramethylhexane 279.45 0.35 +9 34 312 589.6 0.0627 0.7230 64.2 45.02 6.018 0.00063 1.40550 1.40316
139 2,3,3,4-Tetramethylhexane 328.32 0.14 360 680.0 0.0579 0.7735 51.4 48.17 6.439 0.00053 1.4298 1.4275
140 2,3,3,5-Tetramethylhexane 307.6 0.20 337 638.6 0.0598 0.7528 56.5 46.88 6.267 0.00056 1.4196 1.4173
141 2,3,4,4-Tetramethylhexane 322.9 0.15 351 668.3' 0.0583 0.7665 53.1 47.74 6.382 0.00053 1.4267 1.4244
142 2,3,4,5-Tetramethylhexane 313.2 0.17 339 644.4 0.0597 0.7535 56.3 46.92 6.272 0.00056 1.4204 1.4181
143 3,3,4,4-Tetramethylhexane 338.0 0.20 373 704.7 0.0570 0.7863 48.5 48.97 6.546 0.00049 1.4368 1.4346
144 2,4-Di methyl-3-isopropylpentane 314.71 0.17 -115 01 339 646.5 0.0587 0.7624 54.1 47.48 6.347 0.00052 1.42463 1.42248
145 2-Methyl-3,3-diethylpentane 337.5 0.11 367 692.2 0.0564 0.7835 49.1 48.79 6.522 0.00054 1.4343 1.4320
146 2,2,3-Trimethyl-3-ethylpentane 337.1 0.12 373 703.4 0.0566 0.7860 48.5 48.95 6.544 0.00054 1.4420 1.4397
147 2,2,4-Trimethyl-3-ethylpentane 311.5 0.19 344 648.1 0.0583 0.7614 54.3 47.42 6.339 0.00057 1.4223 1.4199
148 2,3,4-Trimethyl-3-ethylpentane 337.05 0.12 369 696.7 0.0570 0.7814 49.6 48.67 6.506 0.00058 1.4333 1.4310
149 2,2,3,3,4-Pentamethylpentane 330.94 0.14 -33 57 375 699.4 0.0572 0.7838 49.0 48.81 6.525 0.00049 1.43606 1.43412
150 2,2,3,4,4-Pentamethylpentane 318.76 0.19 -37 71 348 669.6 0.0587 0.7708 52.1 48.00 6.417 0.00048 1.43069 1.42868

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64-'
2. M.W. = molecular weight.
3. See Appendix I, p.. 61 , for definitions of superscripts.
 1C1.1

TABLE 1C1.1—Paraffins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,*1 Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10< (nF-nc)/d ccntistokcs lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form H20 Motor Method Research Method No.
Fahr Boiling (liquid)+CO2 (gas) (gas)+C02 (gas) D 357 D 908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

95.9 95.8 169'' 0.51 115.2 20 494 126 430 19 019 117 330 (0.75) 95
97 97 0.51 113.2 20 489 126 970 19 013 117 820 (0.75) 96
96 96 0.50 114.0 20 487 127 700 19 012 118 500 (0.75) 97
96 96 0.51 112.9 20 477 126 350 19 002 117 240 (0.75) 98
96 96 0.51 114.0 20 475 126 250 19 000 117 150 (0.75) 99
97 97 163'' 0.50 113.4 20 487 128 820 19 011 119 540 (0.75) 100
96 96 0.50 113.8 20 494 128 930 19 018 119 640 (0.75) 101
96 96 0.50 113.9 20 482 127 170 19 007 118 010 (0.75) 102
96 96 0.50 114.0 20 494 128 950 19 018 119 660 (0.75) 103
97 97 0.50 112.8 20 488 128 970 19 012 119 680 (0.75) 104
97 97 165* 0.50 112.1 20 468 127 350 18 992 118 170 (0.75) 105
100 100 0.51 110.0 20 469 124 850 18 995 115 850 (0.75) 106
100 100 0.51 110.8 20 440 124 790 18 965 115 780 (0.75) 107
98 98 178'' ([Link]) 0.52 111.0 20 434 124 020 18 958 115 060 (0.75) 108
96 96 0.50 112.4 20 479 128 550 19 004 119 290 (0.75) 109
97 97 0.49 112.8 20 481 128 520 19 005 119 260 (0.75) 110
97 97 0.50 112.3 20 470 127 880 18 994 118 660 (0.75) 111
97 97 0.51 112.8 20 462 126 050 18 978 116 900 (0.75) 112
97 97 0.51 109.9 20 481 126 130 19 005 117 040 (0.75) 113
97 97 0.50 112.1 20 470 127 180 18 994 118 010 (0.75) 114
97 97 180'' 0.52 111.5 20 453 123 930 18 977 114 990 (0.75) 115
97 97 0.50 111.1 20 452 126 880 18 977 117 730 (0.75) 116
97 97 0.49 112.4 20 486 129 900 19 010 120 540 (0.75) 117
97 97 158* 0.50 110.8 20 487 127 550 19 011 118 360 (0.75) 88.7 +0.2* 86.4 100 118
97 97 0.49 112.0 20 490 130 070 19 014 120 700 (0.75) 119
97 97 0.49 113.2 20 487 129 790 19 011 120 440 (0.75) 120
98 98 0.50 110.6 20 483 128 330 19 007 119 080 (0.75) 121
95 95 156* 0.49 113.7 20 503 130 830 19 028 121 418 (0.75) 122
94.7 94.6 163* 0.50 113.8 20 500 129 060 19 024 119 760 (0.75) 123
97 97 0.50 110.9 20 476 128 490 19 000 119 225 (0.75) 124
97 97 0.51 109.5 20 476 125 990 19 001 116 910 (0.75) 125
97 97 0.49 112.4 20 497 131 220 19 021 121 770 (0.75) 126
97 97 0.49 112.5 20 486 129 720 19 012 120 390 (0.75) 127
97 97 0.49 112.3 20 488 129 710 19 012 120 370 (0.75) 128
97 97 0.49 112.0 20 497 129 950 19 021 120 600 (0.75) 129
97 97 0.50 111.3 20 470 127 110 18 996 117 950 (0.75) 130
97 97 0.49 112.1 20 492 131 150 19 016 121 700 (0.75) 131
97 97 0.49 111.8 20 504 131 210 19 028 121 760 (0.75) 132
97 97 0.49 109.9 20 489 131 250 19 013 121 800 (0.75) 92.4 96.7 +2.0* +2.5* 133
98 98 158* 0.49 110.0 20 496 129 720 19 020 120 380 (0.75) 134
98 98 0.51 109.5 20 452 126 560 18 976 117 430 (0.75) 135
99 99 0.50 105.9 20 492 128 180 19 016 118 940 (0.75) 136
99 99 0.51 108.2 20 464 126 180 18 987 117 080 (0.75) 137
102 102 181* 0.52 106.6 20 408 123 000 18 932 114 100 (0.75) 138
97 97 0.48 111.8 20 494 132 150 19 018 122 630 (0.75) 139
97 97 0.50 109.6 20 490 128 600 19 015 119 340 (0.75) 140
97 97 0.49 110.8 20 507 131 060 19 031 121 630 (0.75) 141
98 98 0.50 111.4 20 475 128 600 18.999 119 330 (0.75) 142
97 97 1.47* 0.47 105.8 20 505 134 410 19 029 124 740 (0.75) 143
97 97 0.49 109.9 20 476 130 150 19 000 120 770 (0.75) 144
97 97 0.48 113.4 20 514 133 980 19 038 124 340 (0.75) 145
97 97 0.47 110.2 20 505 134 370 19 030 124 710 (0.75) 146
98 98 0.49 109.2 20 498 130 120 19 022 120 750 (0.75) 147
97 97 0.48 111.9 20 506 133 600 19 031 123 990 (0.75) 148
97 97 0.47 109.9 20 526 134 120 19 050 124 480 (0.75) 149
98 98 0.48 106.7 20 517 131 840 19 041 122 360 (0.75) 150

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p., 64.
2. M.W. = molecular weight.
3. See Appendix I, p. i 61 *, for definitions of superscripts.
 1C1.2

TABLE 1C1.2—Cycloparaffins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*. ••' the Liquid,*1 TID
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-a
.at 1 Pres- Air at 1 Grav- ity*. « sion*.
No. Compound atmos, sure at atmos, ity". ' at 60
deg 100 F, deg Tem- 60 F/60 F F, deg V\dT)
Fahr psi Fahr ]'res- t
pera- Vol- API at 60 F,
. ure, ture, ume, lb per lb per per deg at68F at 77 F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Alkylcyclopropanes, C3 and C4:

l Cyclopropane, CsHe, M.W. 42.081 -27.0 -197.36 797.0 256.39 0.065 35.08 4.690
2 Methylcyclopropane, C«H8, M.W. 56.108 +33.31 -287.1

Alkylcyclopropanes, CsHio, M.W. 70.135:

3 Ethylcyclopropane -96.66 -236.61 0.6891 73.8 42.90 5.735 0.00082 1.3786 1.3756
4 1,1-Di methylcyclopropane 69.12 -164.0 0.6654 81.2 41.43 5.538 0.00083 1.3669 1.3639''
5 1, cis-2-Dimethylcyclopropane 98.64 -221.59 0.6990 70.9 43.52 5.818 0.00078 1.3829 1.3800
6 1, (rans-2-Dimethylcyclopropane 82.76 -237.24 0.6748 78.2 42.02 5.617 0.00084 1.3713 1.3683

Alkylcyclopropanes, CcHi=, M.W. 84.162:

7 n-Propylcyclopropane 156.45 0.7163 66.0 44.60 5.962 0.00076 1.3930 1.3905
8 Isopropylcyclopropane 136.96 -171.26 0.7037 69.6 43.82 5.858 0.00079 1.3865 1.3835
9 1-Methyl-l-ethylcyclopropane 134.17 -202.4 0.7069 68.7 44.02 5.885 0.00079 1.3887 1.3857
10 l-Methyl-cis-2-ethylcyclopropane 152.60 0.7197 65.1 44.81 5.990 0.00072 1.3953 1.3923
11 l-Methyl-(rans-2-ethylcyclopropane 137.57 0.6986 71.0 43.50 5.815 0.00078 1.3846 1.3816
12 1,1,2-Tri methylcyclopropane 126.37 -216.75 0.6998 70.7 43.57 5.824 0.00079 1.3864 1.3834
13 l,cis-2,cis-3-Trimethylcyclopropane 151 0.7231 64.2 45.03 6.020 0.00081 1.3970 1.3940
14 1, cis-2, tran$-3-Tri methylcyclopropane 139.5 0.7030 69.8 43.77 5.851 0.00079 1.3873 1.3843

Alkylcyclobutanes, C4 and Cs:

IS Cyclobutane, CRs, M.W. 56.108 54.52 -131.26e 723 368.2 0.060 0.6997* 70.7'' 43.57<* 5.824<* 0.00087,i 1.365<i 1.362"*
16 Methylcyclobutane, C5H10, M.W. 70.135 97.3 0.6978 71.3 43.45 5.808 0.00074 1.3836 1.3810

Alkylcyclobutanes, C«H,2, M.W. 84.162:

17 Ethylcyclobutane 159.06 -224.97 0.7327 61.6 45.63 6.100 0.00073 1.4020 1.3994
18 1,1-Dimethylcyclobutane 133 0.718 65.6 44.7 5.98 0.00081 1.396 1.393
19 1, cis-2- Dimethylcyclobutane 154 0.741 59.5 46.1 6.16 0.00079 1.404 1.401
20 1, frans-2-Dimethylcyclobutane 140 0.718 65.6 44.7 5.98 0.00081 1.395 1.392
21 l,cis-3-Dimethylcyclobutane 140.9 0.7154 66.3 44.55 5.955 0.00071 1.3933 1.3908
22 l,(rans-3-Dimethylcyclobutane 135.5 0.7064 68.8 43.98 5.879 0.00070 1.3896 1.3871

Alkylcyclopentanes, Cs and Cs:

23 Cyclopentane, C5H10, M.W. 70.135 120.65 9.914 -136.91 e 53.8 461.5 0.059 0.7504 57.1 46.73 6.247 0.00070 1.40645 1.40363
24 Methylcyclopentane, CeHi2, M.W. 84.162 161.25 4.503 -224.44 I 48.9 499.35 0.0607 0.7536 56.3 46.93 6.274 0.00071 1.40970 1.40700

Alkylcyclopentanes, C;HU, M.W. 98.189:

25 Ethylcyclopentane 218.24 1.409 -217.22 4 92.8 565.47 0.0611 0.7710 52.0 48.02 6.420 0.00067 1.41981 1.41730
26 1,1-Dimethylcyclopentane 189.47 2.561 -93.57 5 00 525 0.059 0.7592 54.9 47.28 6.320 0.00066 1.41356 1.41091
27 l,cis-2-DimethylcycIopentane 211.16 1.648 -65.01 500 557 0.060 0.7773 50.5 48.41 6.472 0.00063 1.42217 1.41963
28 1, irans-2-DimethyIcycIopentane 197.36 2.192 -179.63 500 536 0.059 0.7562 55.6 47.09 6.295 0.00066 1.41200 1.40941
29 1, cis-3-Dimethylcyclopentane 195.39 2.291 -208.68 5 14 532 0.059 0.7496 57.3 46.68 6.240 0.00065 1.40894 1.40633
30 1, (rons-3-Dimethylcyclopentane 197.10 2.209 -209.17 5 00 536 0.059 0.7534 56.3 46.92 6.272 0.00066 1.41074 1.40813

Alkylcyclopentanes, CsHie, M.W. 112.216:

31 »-Propylcyclopentane 267.73 0.471 -179.20 4 S5.0 628 0.0807 0.7807 49.7 48.62 6.500 0.00058 1.42626 1.42389
32 Isopropylcyclopentane 259.57 0.601 -168.46 4 35.0 622 0.0802 0.7807 49.7 48.62 6.500 0.00054 1.42582 1.42350
33 1-Methyl-l-ethylcyclopentane 250.75 0.726 -226.86 4 33.5 606 0.0602 0.7855 48.6 48.92 6.540 0.00059 1.42718 1.42476
34 l-Methyl-cis-2-ethylcyclopentane 262.51 0.550 -158.67 4 SS.5 eis 0.0601 0.7897 47.7 49.18 6.574 0.00059 1.42933 1.42695
35 l-Methyl-£rans-2-ethylcyclopentane 250.2 0.72 -2S8.0 4 28.2 699 0.0601 0.7733 51.5 48.16 6.438 0.00058 1.4219 1.4195
36 l-Methyl-cis-3-ethylcyclopentane 250.0 0.71 4 28.2 597 0.0601 0.771 52.0 48.0 6.42 0.00058 1.419 1.417
37 l-Methyl-fmns-3-ethylcyclopentane 250.0 0.74 4 20. S 598 0.0601 0.771 52.0 48.0 6.42 0.00058 1.419 1.417
38 1,1,2-Trimethylcyclopentane 236.72 0.999 -6.93 4 28.2 583.5 0.0595 0.7772 50.6 48.40 6.470 0.00063 1.42298 1.42051
39 1,1,3-Tri methylcyclopentane 220.81 1.393 -224.41 4 10.0 565.5 0.0596 0.7528 56.5 46.88 6.267 0.00066 1.41119 1.40870
40 1,cis-2, cis-3-Trimethylcyclopentane 253.4 0.69 -177.56 4 ®6.2 598 0.0694 0.7836 49.1 48.80 6.524 0.00059 1.4262 1.4238
41 1,cis-2,fra««-3-Trimethylcyclopentane 243.5 0.85 -170 4 20.3 584 0.0594 0.7749 51.1 48.26 6.451 0.00058 1.4218 1.4194
42 l,trans-2,cis-3-Trimethylcyclopentane 230.74 1.14 -170.85 4 10.0 570 0.0594 0.7580 55.2 47.21 6.311 0.00066 1.4138 1.4114
43 1, cis-2, cis-4-TrimethyIcyclopentane 242.17 0.84 -206.19 4 18.8 584 0.0594 0.776 50.8 48.3 6.46 0.00063 1.4188 1.4162
44 1, cis-2, *rans-4-Trimethylcyclopentane 242.13 0.881 -206.61 4 17.4 583 0.0594 0.7680 52.7 47.83 6.394 0.00057 1.41855 1.41612
45 1, trans-2, cis-4-Trimethylcyclopentane 228.73 1.162 -203.42 4 07.8 568 0.0594 0.7518 56.7 46.82 6.259 0.00066 1.41060 1.40812

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p.. 61 , for definitions of superscripts.
 1C1.2
TABLE 1C1.2—Cycloparaffins (U.S . Units)
Specific Disper- Kinematic Vis- Heat Capacity at
sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,0 Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Nnmhers
10< (nF-nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form HgO Net, to form H2O Motor Method Nn
Fahr Boiling (liquid)+COj (gas) (gas)+C02 (gas) D357 D 908
Gas, Liquid Point, 1
at 77 at 100 at 210 Ideal at 1 atmos, Btu
F F F F State atmos per lb " With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

0
204.8 2.4 10.4 1
(1-8) 81.2 87.2 +0.2* +0.4* 2

(1.4) 83.8' 87.8 +0.2* +0.7* 3

4
98 98 84.3 !
86.6 +0.4* +0.7* 5
101 101 86.9 +0.4* +0.7* 6

(1.2) 7
(1.2) 88.1 93.0 +0.02* +0.2* 8
(1.2) 9
(1.2) 10
(1-2) 11
110 110 (1.2) 87.8 93.0 +1.5* >+3.0* 12
(1.2) 13
(1.2) 14

0.413 185.3 20 858*° 121 670<* 19 497d 113 730d (1.8) 15

0.465 (1.4) 16

99 99 101.7'' 1.2 7.7 63.9 41.1 17

(1.2) 18
(1.2) 19
(1.2) 20
(1.2) 21
(1.2) 22

94.3 94.2 0.499 62.2 0.2712 0.4216 167.34 20 188 126 300 18 827 117 790 (1.4) 84.9' 95.2 +0.1* +0.9* 23
96.2 96.1 0.565 91.4 0.3010 0.4407 147.83 20 ISO 128 480 18 769 117 930 (1.2) 8.35 80.0 93.0 91.3 +0.5* 24

95.5 95.4 0.619 0.39 98.1 0.3062 0.4437 141.35 20 120 129 330 18 759 120 580 1.1 6.7 61.2 80.7 67.2 79.5 25
97.3 97.2 HS.0h 0.3140 0.4465 132.63 20 082 127 100 18 721 118 480 (1.1) 89.3 +0.1* 92.3 +0.9* 26
97.4 97.3 103.8* 0.3159 04608 138.80 20 113 130 330 18 752 121 510 (1.1) 27
96.5 96.4 116.1* 0.3170 0.451 135.12 20 086 126 620 18 724 118 040 (1.1) 28
97.4 97.3 0.3170 0.M96 134.33 20 091 125 550 18 730 117 040 (1.1) 73.1 86.8 79.2 91.2 29
96.2 96.1 121.8* 0.3170 (0.45) 134.86 20 100 126 250 18 739 117 700 (1.1) 72.6 87.1 80.6 93.2 30

95.7 95.6 0.724 0.46 112.1 0.3153 0.4518 130.7 20 108 130 880 18 747 122 030 (0.95) 28.1 60.5 31.2 59.8 31
95.6 95.5 {0.307) (0.41) 130.7 (20 089) (ISO 760) (18 728) (121 900) (0.95) 76.2 89.4 81.1 94.3 32
95.9 95.8 (0.338) (0.46) 128.9 (20 074) (131 470) (18 710) (122 530) (0.95) 33
94.7 94.6 117.5h (0.805) (0.41) 132.3 (20 062) (132 030) (18 699) (123 060) (0.95) 34
95 95 126.0* (ft. 306) (0.41) 129.4 (20 072) (129 400) (18 709) (120 620) (0.95) 35
95 95 (0.305) (0.41) 129.5 (20 072) (129 040) (18 709) (120 280) (0.95) 59.8 79.6 57.6 79.2 36
95 95 (0.305) (0.41) 129.0 (20 073) (129 050) (18 711) (120 290) (0.95) 59.8 79.6 57.6 79.2 37
97.0 96.9 (0.3X4) (0.44) 124.9 (20 030) (129 780) (18 668) (120 950) (0.95) 38
98.7 98.6 (0.324) (0-44) 121.4 (20 038) (125 760) (18 676) (117 210) (0.95) 83.5 95.6 87.7 +0.1* 39
96 96 105.8 {0.312) (0.42) 128.9 (20 016) (ISO 770) (18 657) (121 890) (0.95) 40
96 96 105.8 (0.31%) (0.42) 127.0 (20 020) (129 330) (18 661) (120 650) (0.95) 41
96 96 105.8 (0.312) (0.42) 123.8 (20 026) (126 670) (18 667) (117 980) (0.95) 42
96 96 (0.312) (0.42) 126.6 (20 020) (129 510) 18 661) 120 720) (0.95) 43
95.8 95.7 (0.312) (0.42) 126.6 (20 021) (128 190) (18 617) [119 210) (0.95) 79.5 89.2 98.3 44
96.9 96.8 ... (0.312) (0.42) 124.1 (20 023) {125 500) (18 664) '116 990) (0.95) ... ... 45

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p., 61 , for definitions of superscripts.
1C1.2
TABLE 1C1.2—Cycloparaffins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' °- * the Liquid,0 no
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.at 1 Pres- Air at 1 Grav- ity*. ' sion*' a
No. Compound atmos, sure at atmos, ity». c at 60
deg 100 F, deg Tem- 60 F/60 F F, deg V\BT) p
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at 68 F at77F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Alkylcyclopentanes, CnHis, M.W. 126.243:

46 ra-Butyleyclopentane 313.92 (0.17) -162.35 895.3 677 0.0612 0.7888 47.9 49.12 6.566 0.00054 1.4316 1.4293
47 Isobutylcyclopentane 298.35 (0.26) -175.39 896.8 666.5 0.0607 0.7853 48.7 48.90 6.537 0.00059 1.4298 1.4273
48 sec-Butylcyclopentane 309.87 (0.20) 896.8 681 0.0607 0.7989 45.6 49.75 6.651 0.00055 1.4357 1.4332
49 (ert-Butylcyclopentane 292.77 ([Link]) -140.4 402.7 660 0.0602 0.7954 46.4 49.53 6.621 0.00055 1.4338 1.4313
50 1-Methyl-l-n-propylcyclopentane 295 0.803 44.7 50.0 6.68 0.00060 1.437 1.435
51 l-Methyl-m-2-re-propylcyclopentane 306.68 (0.19) -155 S97.5 662.5 0.0606 0.7965 46.1 49.60 6.631 0.00055 1.4343 1.4318
52 l-Methyl-(r<ms-2-n-propylcyclopentane 295.50 (0.26) -189 390.9 650 0.0606 0.7818 49.5 48.69 6.509 0.00059 1.4274 1.4249
53 l-Methyl-c*s-3-?i-propylcyclopentane 298 (0.40) 0.784 49.0 48.8 6.52 0.00059 1.426 1.424
54 l-Methyl-tams-3-w-propylcyclopentane 298 (0.40) 0.784 49.0 48.8 6.52 0.00059 1.426 1.424
55 1-Methyl-l-isopropylcyclopentane 298 0.803 44.7 50.0 6.68 0.00060 1.436 1.434
56 l-Methyl-«'s-2-isopropylcyclopentane 298 0.796 46.3 49.6 6.63 0.00060 1.434 1.432
57 l-MethyWrcms-2-isopropylcyclopentane 288 0.785 48.7 48.8 6.52 0.00059 1.429 1.427
58 l-Methyl-cis-3-isopropylcydopentane 288 <-m 886.5 637 0.0601 0.784 49.0 48.8 6.52 0.00059 1.426 1.424
59 l-Methyl-irans-3-isopropylcyclopentane 288 <-112 386.5 637 0.0601 0.784 49.0 48.8 6.52 0.00059 1.426 1.424
60 1,1-Diethylcyclopentane 304 0.8072 43.8 50.27 6.720 0.00055 1.4388 1.4363
61 1, cts-2-Diethylcyclopentane 308.44 (0.18) -180 402.7 664.5 0.0606 0.8004 45.3 49.85 6.664 0.00060 1.4355 1.4330
62 1, /raras-2-Diethylcyelopentane 297.59 (0.25) -139 392.4 652.6 0.0606 0.7876 48.4 49.05 6.557 0.00059 1.4295 1.4270
63 l,«'s-3-Diethylcyclopentane 302 0.791 47.4 49.3 6.59 0.00059 1.430 1.428
64 1, *rans-3-Diethylcyclopentane 302 0.791 47.4 49.3 6.59 0.00059 1.430 1.428
65 1, l-Dimethyl-2-ethylcyoIopentane 280 0.792 47.2 49.4 6.60 0.00069 1.432 1.430
66 1, l-Dimethyl-3-ethylcyclopentane 273 0.774 51.3 48.2 6.44 0.00063 1.421 1.419
67 l,cis-2-Dimethyl-l-ethyIcyclopentane 291 0.803 44.7 50.0 6.68 0.00060 1.437 1.435
68 1, ir<ms-2-DimethyI-l-ethylcyclopentane 291 0.800 45.4 49.8 6.66 0.00060 1.435 1.433
69 l,m's-2-Dimethyl-c!s-3-ethylcyclopentane 306 0.800 45.4 49.8 6.66 0.00060 1.434 1.432
70 1,cis-2-Dimethyl-*r<ms-3-ethylcyclopentane 293 0.792 47.2 49.3 6.59 0.00059 1.431 1.429
71 l,(nms-2-DimethyI-cis-3-ethylcyclopentane 280 0.772 51.8 48.1 6.43 0.00058 1.422 1.420
72 l,irans-2-Dimethyl-*rans-3-ethylcyclopentane 293 0.788 48.1 49.1 6.56 0.00059 1.428 1.426
73 1, cis-2-DimethyI-cis-4-ethylcyclopentane 297 0.800 45.4 49.8 6.66 0.00060 1.432 1.430
74 1, cis-2-Dimethyl-ir<ms-4-ethylcyclopentane 297 0.785 48.7 48.9 6.54 0.00059 1.426 1.424
75 l,(r<ms-2-Dimethyl-cis-4-ethylcyclopentane 284 0.773 51.5 48.1 6.43 0.00048 1.420 1.418
76 1, cis-3-Dimethyl-l-ethylcyclopentane 277 0.778 50.4 48.4 6.47 0.00049 1.423 1.421
77 1, <rans-3-Dimethyl-l-ethylcyclopentane 277 0.782 49.4 48.7 6.51 0.00059 1.425 1.423
78 1, cis-3-Dimethyl-cis-2-ethylcyclopentane 306 0.793 46.9 49.4 6.60 0.00059 1.432 1.430
79 1, as-3-Dimethyl-(rans-2-ethylcyclopentane 279 0.770 52.3 47.9 6.40 0.00048 1.421 1.419
80 l,trans-3-Dimethyl-cts-2-ethylcyclopentane 291 0.788 48.1 49.1 6.56 0.00059 1.429 1.427
81 l,cis-3-Dimethyl-cis-4-ethylcyclopentane 293 0.793 46.9 49.4 6.60 0.00059 1.430 1.428
82 1, cis-3-DimethyI-irems-4-ethylcyclopentane 279 0.770 52.3 47.9 6.40 0.00048 1.420 1.418
83 l,(rarcs-3-Dimethyl-cis-4-ethylcyclopentane 279 0.773 51.5 48.1 6.43 0.00048 1.421 1.419
84 l,<ra»s-3-Dimethyl-(rans-4-ethylcycIopentane 293 0.782 49.4 48.7 6.51 0.00059 1.425 1.423
85 1,1,2,2-Tetra methylcyclopentane 271 0.798 45.8 49.7 6.64 0.00050 1.434 1.432
86 1,1, cis-2,cis-3-Tetramethylcyclopentane 280 0.783 49.2 48.8 6.52 0.00059 1.426 1.424
87 1,1, cis-2, ircms-3-Tetramethylcyclopentane 266 0.771 52.0 48.0 6.42 0.00058 1.421 1.419
88 1,1, cis-2, cis-4-Tetramethylcyclopentane 266 0.778 50.3 48.4 6.47 0.00049 1.424 1.422
89 1,1, cis-2, frarcs-4-Tetramethylcyclopentane 266 0.767 53.0 47.8 6.39 0.00062 1.419 1.417
90 1,1,3,3-Tetramethylcyclopentane 244.49 -127.08 0.7551 55.9 47.02 6.286 0.00057 1.4125 1.4101
91 1,1, cis-3, cis-4-Tetramethylcyclopentane 266.27 -157.89 0.7712 52.0 48.03 6.421 0.00058 1.4209 1.4189
92 1,1, cis-3, (raws-4-Tetramethylcyclopentane 250.92 -185.65 0.7531 56.4 46.90 6.270 0.00056 1.4118 1.4095
93 1,2,2, cis-3-TetramethylcycIopentane 280 0.785 48.7 48.9 6.54 0.00059 1.427 1.425
94 1,2,2, (ra?iS-3-Tetramethylcyclopentane 280 0.793 46.9 49.4 6.60 0.00059 1.431 1.429
95 1, cis-2, cis-3, cis-4-Tetramethylcyclopentane 297.18 -148.36 0.7968 46.1 49.62 6.684 0.00049 1.4332 1.4308
96 1, cis-2, cis-3, (raras-4-Tetramethylcy clopentane 286.81 0.7807 49.8 48.62 6.499 0.00058 1.4248 1.4224
97 1, cis-2, trans-3, cis-4-Tetramethylcyclopentane 272.97 -166.92 0.7718 62.0 48.0S 6.421 0.00058 1.4208 1.4184
98 1,cis-2, fra7js-3,*ra7js-4-Tetramethylcyclopentane 289.S3 -168.39 0.7777 50.5 48.43 6.474 0.00058 1.4297 1.4278
99 1, (rans-2, ct's-3, fr<ms-4-Tetramethylcyclopentane 261.03 0.7605 54.8 47.36 6.332 0.00061 1.4155 1.4131
100 1, (nms-2, trans-3, cis-4-Tetramethylcyclopentane 274.17 -171.60 0.7731 51.6 48.14 6.486 0.00048 1.4219 1.4195

Alkylcyclopentanes, CIOHM, M.W. 140.270:

101 re-Pentylcyclopentane 356.9 -11 7 0.7954 46.3 49.54 6.622 0.00055 1.4358 1.4336

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

10
 1C1.2
TABLE 1C1.2--Cycloparaff ns (U.S . Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid," Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10' (nF-nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form H2O Motor Method Research Method No.
Fahr Boiling (liquid)+CO2 (gas) (gas)+C02 (gas) D 357 D 908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atraos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

96 96 0.908 0.53 119.7 0.3224 04558 123.8 20 105 132 190 18 743 123 240 (0.85) -2l 36.7 -3s 29.6 46
100 100 ([Link]) (040) (««) (20 0S8) (131 000) (18 667) (122 000) (0.85) 28.2 58.1 33.4 59.2 47
([Link]) (040) (IM) (w mi) (1SS 000) (18 66$) (124 000) (0.85) 48
96 96 (0.320) (041) (116) (19 995) (132 600) (18 6S4) (124 000) (0.85) 49
(0.85) 50
95 95 130.1 A
(O.S19) (041) (12S) (20 028) (iss 000) (18 640) (124 000) (0.85) 51
97 97 130.1* (0.819) (041) (119) (20 008) (ISO 400) (18 645) (122 OOO) (0.85) 52
(0.85) 53
(0.85) 54
(0.85) 55
(0.85) 56
(0.85) 57
([Link]) (040) U'u) (20 015) (ISO 700) (18 652) (122 000) (0.85) 58
([Link]) (040) (115) (20 015) (ISO 700) (18 652) (122 000) (0.85) 59
(0.85) 60
95 95 127.21 ([Link]) (040) (m) (21 999) (U7 000) (18 6S9) (124 000) (0.85) 61
96 96 127.2* ([Link]) (040) (119) (20 007) (131 000) (18 644) (122 000) (0.85) 62
(0.85) 63
(0.85) 64
(0.85) 65
(0.85) 66
(0.85) 67
(0.85) 68
(0.85) 69
(0.85) 70
(0.85) 71
,, (0.85) 72
(0.85) 73
(0.85) 74
#, (0.85) 75
(0.85) 76
(0.85) 77
(0.85) 78
(0.85) 79
(0.85) 80
., (0.85) 81
(0.85) 82
.. (0.85) 83
(0.85) 84
(0.85) 85
(0.85) 86
(0.85) 87
(o.85) 88.0 98.1 96.2 +0.3* 88
(0.85) 88.0 98.1 96.2 +0.3* 89
(0.85) 90
t. (0.85) 91
(0.85) 92
(0.85) 93
.. (0.85) 94
(0.85) 95
(0.85) 96
(0.85) 97
(0.85) 98
(0.85) 99
(0.85) 100

96 96 1.128 0.62 0.3281 (0.462) 119.4 20 099 133 270 18 738 124 250 (0.75) 101

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 -, for definitions of superscripts.

11
1C1.2

TABLE 1C1.2—Cycloparaffins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*. B> * the Liquid,0 UD
at BO F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
at 1 Pres- Air at 1 Grav- ity*. ' sion*. °
No. Compound atmos, sure at atmos, ity". « at 60
deg 100 F, deg Tem- 60F/60F F, deg V\dT) p
Fahr psi Fahr Pres- pera- Vol- API at60F,
sure, ture, ume, lb per lb per per deg at 68 F at77F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Alkylcyclohexanes, Ce and C7:

102 Cyclohexane, CeHu, M.W. 84.162 177.29 3.264 43.77 591 536.7 0.0586 0.7834 49.1 48.79 6.522 0.00068 1.42623 1.42354
103 Methylcyclohexane, CjHu, M.W. 98.189 213.68 1.609 -195.87 503.5 570.27 0.0600 0.7740 51.3 48.20 6.444 0.00063 1.42312 1.42058

Alkylcyclohexanes, CsHu, M.W. 112.216:

104 Ethylcyclohexane 269.23 0.483 -168.360 440 637 0.064 0.7922 47.1 49.34 6.596 0.00054 1.43304 1.43073
105 1,1-Dimethylcyclohexane 247.19 0.820 -28.28 430 604 0.064 0.7854 48.7 48.91 6.539 0.00059 1.42900 1.42662
106 1, czs-2-DimethyIcyclohexane 265.53 0.540 -57.99 430 631 0.066 0.8006 45.2 49.86 6.666 0.00055 1.43596 1.43358
107 1, *rans-2-Dimethylcyclohexane 254.17 0.707 -126.70 430 613 0.066 0.7802 49.9 48.59 6.496 0.00058 1.42695 1.42470
108 1 ,cis-3-Dimethylcyclohexane 248.17 0.783 -103.97 430 604 0.064 0.7704 52.2 47.98 6.414 0.00058 1.42294 1.42063
109 1 ,*r<ms-3-DimethyIcyclohexane 256.03 0.651 -130.14 430 617 0.066 0.7892 47.8 49.15 6.571 0.00059 1.43085 1.42843
110 1, cis-4-Dimethylcyclohexane 255.79 0.661 -125.33 430 617 0.066 0.7873 48.2 49.03 6.555 0.00059 1.42966 1.42731
111 1, (rtms-4-Dimethylcyclohexane 246.84 0.821 -34.49 430 602 0.064 0.7671 53.0 47.77 6.386 0.00062 1.42090 1.41853

Alkylcyclohexanes, CsHis, M.W. 126.243:

112 n-Propylcydohexane 314.14 0.1689 -138.77 407.1 691 0.0605 0.7977 45.9 49.68 6.641 0.00050 1.43705 1.43478
113 Isopropylcyclohexane 310.61 0.1911 -128.85 411.B 692 0.0600 0.8063 44.0 50.22 6.713 0.00050 1.44087 1.43861
114 1-Methyl-l -ethylcyclohexane 305.92 0.8103 43.1 50.46 6.746 0.00050 1.4419 1.4397
115 l-Methyl-cis-2-ethylcyclohexane S1S.80 0.8139 42.4 50.69 6.777 0.00061 I.44S6 I.44IS
116 l-Methyl-£rans-2-ethylcyclohexane 305.10 0.798 45.8 49.7 6.64 0.00060 1.4381 1.4359
117 l-Methyl-cts-3-ethylcyclohexane 299.24 0.7879 48.1 49.07 6.559 0.00049 1.4326 1.4306
118 l-Methyl-fre?is-3-ethylcyclohexane 303.94 0.8054 44.2 50.16 6.706 0.00050 1.4374 1.4351
119 l-Methyl-cis-4-ethyIcyclohexane soe.u 0.8007 45.2 49.87 6.666 0.00050 1.4370 1.4347
120 l-Methyl-foms-4-ethylcyclohexane [Link] -114-13 0.7836 49.1 48.80 6.524 0.00059 1.4300 1.4287
121 1,1,2-Trimethylcyclohexane 293.4 0.2776 -20 402.7 661. S 0.0595 0.8041 44.4 50.08 6.695 0.00050 1.4382 1.4359
122 1,1,3-Trimethyloyolohexane 277.95 0.4202 -86.29 390.9 642 0.059B 0.7831 49.2 48.77 6.520 0.00054 1.42955 1.42725
123 1,1,4-Trimethylcyclohexane 275 0.7762 50.8 48.34 6.462 0.00053 1.4251 1.4228
124 l,«8-2,«'s-3-Trimethylcyclohexane SOB. 08 -120.98 0.8069 4S.9 50.26 6.718 0.00050 1.4403 1.4380
125 l,a's-2,!r-cms-3-Trimethylcyclohexane 304.12 -122.26 0.8073 43.8 50.28 6.722 0.00061 1.4899 1.4S76
126 1, trans-2, cis-3-Tri methylcyclohexane 291 0.785 48.7 48.9 6.54 0.00059 1.430 1.428
127 1, cis-2, cis-4-Trimethylcyclohexane [Link] -[Link] 0.7950 46. B 49.51 6.619 0.00059 1.4340 1.4317
128 1, cis-2, frans-4-Trimethylcyclohexane m.01 -133.29 0.7950 46.5 49.51 6.619 0.00059 1.4345 1.4322
129 1, trans-2, cis-4-Trimethylcyclohexane 292.41 -188.S0 0.792 47.2 49.3 6.59 0.00059 I.434I 1.4318
130 1, trans-2, (rans-4-Trimethylcyclohexane 286.23 0.S495 -122 388 645 0.0594 0.7760 50.8 48.33 6.461 0.00053 1.4266 1.4243
131 1, cis-3, cis-5-TrimethyIcyclohexane 281.17 -45.74 0.7737 51.4 48.18 6.441 0.00053 1.4266 1.4243
132 1, ci's-3, (rons-5-Tri methylcyclohexane 286.23 -119.92 0.7857 48.6 48.93 6.541 0.00054 1.4310 1.4287

Alkylcyclohexanes, CIOHM. M.W. 140.270:

133 n-Butylcyclohexane 357.77 0.0561 -102.444 467.0 741 0.0610 0.8031 44.7 50.02 6.687 0.00050 1.44075 1.43855
134 Isobutylcyclohexane 840.322 0.0906 -[Link] 452.6 726 0.0605 (0.799) (45.6) (49.8) (6.66) (0.00040) 1.4S8e 1.4364
135 sec-Butylcyclohexane SB4.71,0 0.0635 Glass 388.0 744 0.0605 (0.817) (41.7) (50.9) (6.80) (0.00040) 1.4467 1.4445
136 tert-Butylcyclohexane 340.8te 0.0967 -42.084 887.2 727 0.0601 (0.817) (41-7) (50.9) (6.80) (0.00041) 1.4469 1.4447
137 l-Methyl-4-isopropylcyclohexane 339.296 (0.10) -125.662 371.1 718 0.0600 (0.803) U4-7) (50.0) (6.69) (0.00041) 1.4373

Alkylcycloheptanes, C7 and C9:

138 Cycloheptane, C7H14, M.W. 98.189 245.84 0.79B + 18.0 540 601 0.064 0.8157 42.0 50.80 6.791 0.00061 1.4449 1.4424
139 Ethylcycloheptane, C9H18, M.W. 126.243 sm.o (0.13) <-22 426.2 718 0.0B99 (0.818) (41-5) (61.0) (6.81) 0.00042

Alkylcyclooctanes, Ca and C»:

140 Cyclooctane, C8Hi«, M.W. 112.216 304.09 0.222 +58.6 500 653 0.064 0.8405 36.9 52.35 6.998 0.00052 1.4587 1.4563
141 Methylcyclooctane, C9H18, M.W. 126.243 sts.e (0.15) 60.8 439.4 725 0.0593 0.839 (S7.2) (52.3) (6.99) (0.00042)

Cycloparaffins, Cg and C10:

142 Cyclononane, C9H18, M.W. 126.243 353.1 (0.12) 52 460 700 0.065 0.8545 34.1 53.22 7.114 0.00053 1.4666 1.4644
143 Cyclodecane, CIOHM, M.W. 140.270 396 50 430 741 0.065 0.8616 32.7 53.67 7.175 0.00048 1.4716 1.4695

Decahydronaphthalenes, CioHis, M.W. 138.254:

144 cj's-Decahydronaphthalene 384.47 0.0355 -45.36 0.9011 25.5 56.13 7.503 0.00051 1.4810 1.4788
145 trans- Decahydronaphthalene 369.16 0.0539 -22.69 0.8744 30.3 54.46 7.281 0.00055 1.4695 1.4672

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 ., for definitions of superscripts.

12
 1C1.2

TABLE 1C1.2—Cycloparafli ns (U.S . Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability
si on af the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,0 Liquid, Pressure , Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10« (np -nc)/d centistokes lb, deg Fahr Heat of
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form H20 Motor Method No.
Fahr Boiling (liquid) +COj (gas) (gas)-r-COj (gas) D357 D908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

96.2 96.1 0.953 87.8 0.2900 0.4332 153.0 20 034 130 850 18 676 121 970 1.3 7.8 77.2 87.3 83.0 97.4 102
97.9 97.8 0.767 0.43 105.8 0.3170 0.4397 136.3 20 000 129 040 18 639 120 260 1.2 71.1 86.2 74.8 88.2 103

97.5 97.4 0.861 0.51 110.8 0.3267 0.4411 131.5 20 022 132 250 18 661 123 260 0.95 6.6 40.8 65.4 45.6 65.1 104
98.6 98.4 113.7* 0.318 0.4356 124.9 19 997 130 920 18 636 122 010 (0.95) 85.9 95.7 87.3 98.0 105
96.0 95.9 107. 1* 0.322 0.4383 128.9 20 024 133 640 18 663 124 560 (0.95) 78.6 90.7 80.9 94.3 106
98.0 97.9 118.9* 0.327 0.4358 126.0 19 999 130 100 18 638 121 240 (0.95) 78.7 90.8 80.9 94.5 107
99.2 99.1 125.1* 0.324 0.4364 125.7 19 981 128 340 18 619 119. 590 (0.95) 71.0 71.7 108
97.2 97.1 115.3* 0.324 0.4436 129.7 20 009 131 640 18 648 122 690 (0.95) 64.2 83.8 66.9 83.5 109
97.2 97.1 116.4* 0.324 0.4423 129.4 20 009 131 320 18 648 122 390 (0.95) 68.2 85.0 67.2 84.7 110
97.2 97.1 126.9* 0.324 0.4383 124.9 19 982 127 790 18 623 119 100 (0.95) 62.2 83.4 68.3 82.8 111

97.5 97.4 1.000 0.58 121.6 0.3374 0.4490 122.9 20 024 133 160 18 663 124 110 (0.85) 14.0 47.7 17.8 42.8 112
96.6 96.5 120.0* ([Link]) (040) (120) (20 OSl) (185 000) (IS 669)i (125 500) (0.85) 61.1 81.4 62.8 79.6 113
(0.85) 76.7 88.6 68.7 85.7 114
(0.85) 115
(0.85) 116
(0.85) 117
(0.85) 118
(0.85) 119
(0.85) 120
(0.826) (0-42) (U7) (19 985) (184 000) (18 628) (125 000) (0.85) 87.7 97.0 95.7 +0.4* 121
)9.0 98.9 ([Link]) (0.42) (118) (19 992) (181 000) (18 830) (122 000) (0.85) 82.6 95.8 81.3 94.8 122
(0.85) 123
(0.85) 124
(0.85) 82.5 91.0 86.2 96.9 125
(0.85) 81.0 90.6 83.4 95.7 126
(0.85) 127
(0.85) 128
(0.85) 129
138.2* (0.819) (0.41) (ue) (20 002) (129 000) (18 639) (121 000) (0.85) 74.3' 87.9 72.9* 88.0 130
101 101 (0.85) 56.4 79.4 59.1 78.0 131
99 99 (0.85) 70.1 68.5 83.9 132

97.1 97.0 1.251 0.69 129.9 0.3416 0.4527 118.0 20 029 134 110 18 668 125 000 (0.75) 25.3 22.5 133
1S5.S (0.817) (0.89) (117) (20 032) (iss 000) (IS 664) (124 000) 134
(0.811) (0.39) (m) (20 029) (136 000) (18 666) (127 000) 135
118.5 ([Link]) (0.40) (112) (19 999) (136 000) (18 687) (127 000) 136
1SS.7 ([Link]) (0.42) (in) (20 010) (134 000) (18 647) (125 000) 137

«
101 101 (0.282) 0,4314 145.29 20 144 136 980 18 784 127 728 (1.1) 40.2l 65.3 38.8 59.8 138
(0.299) (0.88) (124) (19 970) (186 OOO) (IS 609) (127 000) 139

104 104 (0.280) 0.4510 137.5 20 186 141 450 18 826 131 910 (0.95) 58.2' 71.0' 140
(0.290) (0.87) (its) (to 04s) (140 000) (IS 88l) (131 000) 141

(0.2777) 0.444 130.0 20 212 143 970 18 852 134 280 (0.85) 142
0.450 123.1 20 200 145 120 18 839 135 340 (0.75) 143

95.5 0.S918 19 567 146 990 18 324 137 660 (0.76) 144
95.5 0.3856 19 532 142 390 18 289 133 330 (0.76) ... 145

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W, = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

13
 1C1.3
TABLE 1C1.3—Monoolefins and Diolefins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' <•> * the Liquid," no
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.at 1 Pres- Air at 1 Grav- ity*- c sion*' °
No. Compound atmos, sure at atmos, ity". 0 at 60
deg 100 F, deg Tem- 60 F/60 F F, deg V\3T) T
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at 68 F at 77 F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Monoolefins, C2 and C3:

l Ethene (ethylene), C2H4, M.W. 28.054 -154.62 -272.45" 7 29.8 48.58 0.0737
2 Propene (propylene), CsHt, M.W. 42.081 -53.90 m.i, -301.45" 6 69 196.9 0.0689 0.5220'' 139.6d 32.49'' 4.343'' 0.00189''

Monoolefins, C(Hs, M.W. 56.108:

3 1-Butene +20.75 6S.05 -301.63" 5 33 295.6 0.0685 0.6013'' 103.8* 37.43'' 5.004'' 0.00116"'
4 cis-2-Butene 38.69 4S.54 -218.06 6 10 324.37 0.0668 0.6271'' 94. I* 39.04'' 5.219'' 0.00098''
5 tfrarcs-2-Butene 33.58 49.80 -157.96 5 35 311.86 0.0680 0.6100'' 100.5d 37.97* 5.076'' 0.00107''
6 2-Methylpropene (isobutene) 19.59 6S.4O -220.61 5 SO 292.55 0.0682 0.6004'1 104.2d 37.37d 4.996d 0.00120d

Monoolefins, CsHio, M.W. 70.135:

7 1-Pentene 85.93 19.115 -265.39 5 90 376.93 0.0697 0.6457 87.6 40.20 5.374 0.00089 1.37148 1.36835
8 m-2-Pentene 98.48 15.122 -240.52 5 30 397 0.069 0.6608 82.6 41.14 5.500 0.00087 1.3830 1.3798
9 fra?is-2-Pentene 97.42 15.431 -220.46 5 30 396 0.069 0.6533 85.0 40.68 5.438 0.00090 1.3793 1.3761
10 2-Methyl-l-butene 88.08 18.399 -215.63 5 30 378 0.071 0.6557 84.3 40.83 5.458 0.00090 1.3778 1.3746
11 3-Methyl-l-butene 68.10 26.41 -271.28 5 10 351 0.069 0.6325 92.2 39.38 5.264 0.00095 1.3643 1.3611"
12 2-Methyl-2-butene 101.40 14.303 -208.77 5 00 387 0.073 0.6676 80.5 41.57 5.557 0.00087 1.3874 1.3842

Monoolefins, CsHi2. M.W. 84.162:

13 1-Hexene 146.26 6.006 -219.70 4 60 447.58 0.070 0.6780 77.2 42.21 5.643 0.00076 1.38788 1.38502
14 cts-2-Hexene 155.99 4.909 -222.07 (4 76.1) (472) (0.0668) 0.6920 73.0 43.09 5.760 0.00073 1.39761 1.39473
15 lrans-2-Hexene 154.18 5.089 -207.36 (4 74.1) (470) (0.0668) 0.6827 75.8 42.51 5.683 0.00072 1.39363 1.39073
16 «'s-3-Hexene 151.59 5.378 -216.09 (4 78.1) (W) (0.0668) 0.6847 75.2 42.63 5.699 0.00073 1.39479 1.39189
17 trans-3-Hexene 152.74 5.219 -172.16 (4 76.1) Un) (0.0668) 0.6821 76.0 42.47 5.677 0.00077 1.39429 1.39137
18 2-Methyl-l-pentene 143.78 6.298 -212.31 0.6848 75.1 42.64 5.700 0.00077 1.39200 1.38912
19 3-Methyl-l-pentene 129.50 8.443 -243.4 0.6721 79.0 41.85 5.594 0.00075 1.38422 1.38133
20 4-Methyl-l-pentene 128.94 8.499 -244.55 0.6686 80.1 41.63 5.565 0.00079 1.38267 1.37974
21 2-Methyl-2-pentene 153.14 5.173 -211.14 (4 76.1) (472) (0.0668) 0.6912 73.2 43.04 5.754 0.00073 1.40030 1.39739
22 3-Methyl-cis-2-pentene 153.85 5.143 -210.73 U 76.1) (472) (0.0668) 0.6980 71.2 43.46 5.810 0.00074 1.40157 1.39876
23 3-Methyl-irans-2-pentene 158.77 4.614 -217.22 (4 77.6) (479) (0.0668) 0.7023 70.0 43.73 5.846 0.00070 1.40452 1.40166
24 4-Methyl-m-2-pentene 133.48 7.734 -209.96 0.6741 78.4 41.97 5.610 0.00076 1.38793 1.38498
25 4-Methyl-trans-2-pentene 137.48 7.123 -221.44 0.6736 78.6 41.94 5.607 0.00080 1.38878 1.38583
26 2-Ethyl-l-butene 148.41 5.697 -204.77 0.6944 72.3 43.24 5.780 0.00074 1.39671 1.39380
27 2,3-Dimethyl-l-butene 132.09 7.968 -251.07 (4 70.S) (««) (0.06BS) 0.6830 75.7 42.53 5.685 0.00077 1.39022 1.38729
28 3,3-Dimethyl-l-butene 106.23 13.093 -175.34 (4 57.0) (42s) (0.065S) 0.6584 83.4 40.99 5.480 0.00090 1.37620 1.37313
29 2,3-Dimethyl-2-butene 163.76 4.163 -101.62 (4 S7.0) (484) (0.0668) 0.7129 67.0 44.39 5.934 0.00071 1.41235 1.40952

Monoolefins, C;H„, M.W. 98.189:

30 1-Heptene 200.55 1.964 -181.98 4 10 500.25 0.072 0.7015 70.2 43.68 5.839 0.00070 1.39980 1.39713
31 cis-2-Heptene 209.14 1.692 0.7116 67.3 44.1 5.90 0.00067 1.4069 1.4042
32 Iran z-% He ptene 208.31 1.720 -165.04 0.7057 69.0 43.94 5.874 0.00066 1.4045 1.4020
33 «'s-3-Heptene 204.35 1.864 0.7073 68.6 44.04 5.887 0.00071 1.4059 1.4033
34 (rans-3-Heptene 204.21 1.864 -213.95 0.7026 69.8 43.75 5.848 0.00070 1.4044 1.4017
35 2-Methyl-l-hexene 197.60 2.117 -153.08 0.7075 68.5 44.05 5.889 0.00071 1.4035 1.4008
36 3-MethyI-l-hexene 183.02 2.807 0.6959 71.8 43.33 5.792 0.00069 1.3965 1.3938
37 4-MethyI-l-hexene 188.11 2.542 -222.63 0.7030 69.8 43.77 5.851 0.00066 1.4000 1.3973
38 5-Methyl-l-hexene 185.56 2.672 0.6965 71.7 43.37 5.798 0.00070 1.3967 1.3940
39 2-Methyl-2-hexene 203.74 1.878 -202.64 0.7126 67.1 44.37 5.931 0.00067 1.4106 1.4079
40 3-Methyl-cis-2-hexene 207.07 1.761 -181.30 0.7202 65.0 44.85 5.996 0.00072 1.4126 1.4100
41 3-Methyl-(rans-2-hexene 203.32 1.893 -200.7 0.7188 65.4 44.76 5.984 0.00067 1.4118 1.4091
42 4-MethyI-cts-2-hexene 187.36 2.580 0.7040 69.5 43.84 5.860 0.00070 1.4026 1.3999
43 4-Methyl-irans-2-hexene 189.61 2.469 -194.25 0.7013 70.3 43.67 5.838 0.00070 1.4025 1.3998
44 5-Methyl-m-2-hexene 193.1 2.307 0.706 68.9 43.93 5.873 0.00053 1.404 1.401
45 5-Methyl-*rans-2-hexene 190.60 2.422 -191.81 0.6971 71.5 43.41 5.803 0.00070 1.4006 1.3979
46 2-Methyl-cis-3-hexene 187 2.615 0.698 71.2 43.4 5.80 0.00052 1.401 1.399
47 2-Methyl-(rcms-3-hexene 186.62 2.615 -222.83 0.6941 72.4 43.22 5.778 0.00074 1.4001 1.3974
48 3-Methyl-cis-3-hexene 203.72 1.800 0.7181 65.6 44.71 5.977 0.00081 1.41264 1.40995
49 3-MethyHrans-3-hexene 200.38 1.957 0.7144 66.6 44.49 5.947 0.00076 1.41090 1.40820

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

14
 1C1.3

TABLE 1C1.3—Monoolefins and Diolefins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,0 Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10' (nr—nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form H20 Motor Method Research Method No.
Fahr Boiling (liquid)+C02 (gas) (gas)+C02 (gas) D357 D908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
P F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

0.3622 207.57 2.7 34 75.6 +0.03* 1

0.3541 0.585 188.18 0
2.0 10 84.9 +0.2* 2

0.3548 0.535 167.94 20 672*" 103 630"' 19 313d 96 820d 1.6 9.3 80.8; 97.4 3
0.3269 0.5271 178.91 20 607*° 107 740d 19 246<i 100 620d (1.6) 83.5 100 4
0.3654 0.5351 174.39 20 580*" 104 650"* 19 219<* 97 730d (1.6) 5
58.8 0.3701 0.549 169.48 20 540*° 102 810i 19 md 96 000"* (1.6) 6

126.2 126.1 66.2 0.3635 0.5196 154.46 20 546 110 600 19 185 103 280 1.4 8.7 77.1 82.9 90.9 98.6 7
130 130 64.4 0.3366 0.5079 160.1 20 499 112 940 19 138 105 440 (1-4) 8
132 132 64.4 0.3601 0.5255 159.8 20 472 111 520 19 113 104 110 (1.4) 9
133 133 0.3705 0.5266 156.31 20 451 111 810 19 090 104 370 (1.4) 81.9 84.2 +0.2*= +0.3* 10
147.5 20 505 108 120 19 144 100 950 (1.4) n n n n 11
128 128° 0.3936 0.5211
135 135 55.0 0.3483 0.5119 161.26 20 404 113 570 19 043 106 000 (1.4) 84.7 85.8 97.3 99.2 12

122.0 121.9 0.34 73.0 0.3659 0.5116 144.4 20 465 115 670 19 104 107 980 (1-2) 63.4 76.3 76.4 91.7 13
124.6 124.8 7 5.8 0.3471 0.50 148.8 20 406 117 730 19 045 109 880 (1.2) 14
126.7 126.8 7 3.8 0.3667 0.522 147.7 20 397 116 100 19 036 108 360 (1-2) 80.8 83.2 92.7 98.4 15
130.0 129.7 8 ).6* 0.3405 0.51 146.6 20 431 116 620 19 070 108 860 (1-2) 16
128.8 129.0 8 ).6* 0.3672 0.51 147.9 20 395 115 970 19 034 108 232 (1.2) 80.1 82.3 94.0 17
124.9 124.4 0.3749 0.517 144.1 20 375 116 330 19 014 108 560 (1.2) 81.5 85.2 94.2 99.8 18
121.7 121.6 0.3995 0.52 137.4 20 435 114 500 19 074 106 880 (1-2) 81.2 82.2 96.0 +0.05* 19
122.2 122.5 0.3495 0.52 138.3 20 426 113 860 19 065 106 273 (1.2) 80.9 84.5 95.7 +0.5* 20
132.1 132.4 0.3490 0.50 148.0 20 330 117 170 18 969 109 320 (1.2) 83.0 85.0 97.8 99.5 21
128.0 128.3 0.3490 0.50 147.3 20 352 118 430 18 991 110 510 (1.2) 22
128.4 128.3 0.3490 0.50 149.6 20 352 119 160 18 991 111 200 (1-2) 81.0 84.0 97.2 100 23
126.0 126.0 0.3686 0.52 140.8 20 390 114 580 19 029 106 930 (1.2) 84.5 86.3 99.7 +0.2* 24
126.4 126.4 0.3915 0.52 142.8 20 366 114 360 19 005 106 720 (1-2) 82.6 98.0 +0.02* 25
123.6 123.5 0.3686 0.50 147.1 20 390 118 040 19 029 110 160 (1.2) 79.4 82.0 98.3 +0.3* 26
125.6 125.7 0.3970 0.51 139.9 20 354 115 900 18 993 108 150 (1.2) 82.8 85.5 +0.1* +0.3* 27
124.0 123.9 0.3491 0.523 131.0 20 388 111 910 19 027 104 440 (1.2) 93.3 +1.7* 28
132.9 133.2 0.3530 0.4881 151.40 20 316 120 740 18 955 112 650 (1.2) 80.5 84.0 97.4 98.5 29

118.3 118.2 0.44 81.0 0.3677 0.5068 136.2 20 408 119 350 19 047 111 390 (1.0) 50.7 68.9 54.5 80.2 30
122 322 0.50 135.6 20 375 120 880 19 014 112 810 (1.0) 31
124 124 0.519 135.6 20 356 119 770 18 995 111 760 (1.0) 68.8 78.9 73.4 89.5 32
122 122 9' .8' 0.50 135.6 20 377 120 160 19 016 112 140 (1.0) 90.2 33
124 124 W .8 0.51 135.6 20 358 119 260 18 997 111 280 (1.0) 79.3 84.6 89.8 98.2 34
121 121 0.514 135.6 20 342 119 990 18 981 111 960 (1.0) 78.8 85.0 90.7 98.6 35
120 120 0.51 133.8 20 392 118 310 19 031 110 420 (1.0) 71.5 80.0 82.2 94.8 36
120 120 0.51 133.8 20 390 119 510 19 029 111 530 (1-0) 74.0 83.6 86.4 96.8 37
120 120 0.51 133.8 20 380 118 340 19 019 110 440 (1.0) 64.0 78.6 75.5 91.8 38
127 127 0.50 135.6 20 314 120 690 18 953 312 600 (1.0) 79.2' 83.7 91.6! 98.4 39
127 127 0.50 135.6 20 326 122 050 18 965 113 880 (1-0) 80.0 84.0 92. il 97.4l 40
127 127 0.50 135.6 20 326 121 810 18 965 113 650 (1.0) 79.6' 83.8 91.5' 97.4' 41
122 122 0.51 133.8 20 361 119 510 19 000 111 520 (1.0) 98.6 42
124 124 0.51 133.8 20 342 118 940 18 981 110 980 (1.0) 83.0 85.8 96.8 +0.06* 43
122 122 0.51 133.8 20 349 119 780 18 988 111 770 (1.0) 44
124 124 0.51 133.8 20 331 118 160 18 970 110 250 (1.0) 81.01 85.0 94.4! +0.1* 45
122 122 0.51 133.8 20 351 118 430 18 990 110 510 (1.0) 46
124 124 0.51 133.8 20 333 117 670 18 972 109 790 (1.0) 82.0 85.7 97.9 +0.1* 47
127.4 127.1 0.50 137.8 20 325 121 670 18 964 113 520 (1.0) 96.0 48
126.8 127.4 0.50 136.5 20 340 121 140 18 979 133 040 (1.0) 81.4 85.1 96.4 98.8 49

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

15
 1C1.3
TABLE 1C1.3—Monoolefins and Diolefins (U.S. Units)

Density of tbe Refractive Index of

Critical Constants Liquid*' •• ' the Liquid," no
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
at 1 Pres- Air at 1 Grav- ity*. • sion** a
No. Compound atmos, sure at atmos, ity"' ' at 60
deg 100 F, deg Tem- 60F/60F F, deg V\aTj T
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at 68 F at77F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Monoolefins. C7H14 (continued):

50 2-Ethyl-l-pentene 201.2 1.972 0.712 67.2 44.3 5.92 0.00067 1.405 1.402
51 3-Ethyl-l-pentene 183.40 2.786 -197.47 0.7005 70.5 43.62 5.831 0.00070 1.3982 1.3955
52 2,3-DimethyI-l-pentene 183.70 2.770 -209.76 0.7097 67.9 44.19 5.907 0.00071 1.4033 1.4006
53 2,4-Dimethyl-l-pentene 178.89 3.167 -191.31 0.6988 71.0 43.51 5.817 0.00074 1.39852 1.39577
54 3,3-Di methyl-1-pentene 171.45 3.518 -209.90 0.7019 70.1 43.70 5.842 0.00066 1.3984 1.3958
55 3,4-Dimethyl-l-pentene 177.42 3.130 0.7022 70.0 43.72 5.845 0.00066 1.3992 1.3965
56 4,4-Dimethyl-l-pentene 162.52 4.483 -213.90 (4U4) (4*8) (0.0668) 0.6871 74.5 42.78 5.719 0.00073 1.39172 1.38895
57 3-EthyI-2-pentene 204.82 1.839 0.7249 63.7 45.14 6.034 0.00068 1.4148 1.4122
58 2,3-Dimethyl-2-pentene 207.32 1.752 -180.89 (439 4) (642) (0.0665) 0.7322 61.7 45.60 6.096 0.00069 1.4211 1.4185
59 2,4-Dimethyl-2-pentene 181.93 2.868 -197.87 0.6996 70.8 43.56 5.823 0.00070 1.40371 1.40090
60 3,4-Dimethyl-cts-2-pentene 192.65 2.328 ^172.09 0.7180 65.6 44.71 5.977 0.00072 1.4104 1.4078
61 3,4-Dimethyl-£rarcs-2-pentene 196.70 2.152 -191.62 0.7212 64.7 44.91 6.004 0.00072 1.4128 1.4101
62 4,4-Di methyl-cis-2-pentene 176.76 3.350 -211.85 0.7039 69.5 43.83 5.859 0.00070 1.40260 1.39989
63 4,4-Dimethyl-frcms-2-pentene 170.12 3.701 -175.41 0.6936 72.5 43.19 5.774 0.00074 1.39807 1.39525
64 3-Methyl-2-ethyl-l-butene 187.45 2.599 0.7135 66.8 44.43 5.939 0.00071 1.40518 1.40244
65 2,3,3-Trimethyl-l-butene 172.19 3.681 -165.71 U$o.s) (499) (0.065S) 0.7092 68.0 44.16 5.903 0.00071 1.40282 1.40007

Monoolefins, CSHK, M.W. 112.216:

66 1-Octene 250.32 0.656 -151.09 380 560.3 0.073 0.7193 65.2 44.79 5.987 0.00058 1.40870 1.40620
67 cis-2-Octene 258.17 0.596 -148.4 (iOl.7) (687) (0. 0663) 0.7287 62.7 45.38 6.066 0.00064 1.4150 1.4125
68 £nms-2-Octene 257.0 0.611 -125.9 (401. t) (ess) (0- 0663) 0.7243 63.8 45.10 6.029 0.00063 1.4132 1.4107
69 ets-3-Octene 253.2 0.657 0.725 63.6 45.1 6.03 0.00054 1.4135 1.4111
70 /rares-3-Octene 253.9 0.648 -166.0 (398.3) (581) (0. 066S) 0.7196 65.1 44.81 5.990 0.00067 1.4126 1.4102
71 cis-4-Octene 252.59 0.665 -181.7 (396.8) ($80) (0. 0663) 0.7256 63.5 45.18 6.040 0.00045 1.4148 1.4124
72 (rans-4-Octene 252.07 0.672 -136.81 (m.8) (S80) (0. 9668) 0.7185 65.4 44.74 5.981 0.00063 1.4118 1.4093
73 2-MethyU-heptene 246.7 0.748 -130.0 (S9S.8) (672) (0. 0663) 0.7248 63.7 45.13 6.033 0.00063 1.4123 1.4098
74 3-Methyl-l-heptene 232 1.001 0.715 66.4 44.5 5.95 0.00067 1.406 1.404
75 4-Methyl-l-heptene 235.0 0.938 0.721 64.7 44.9 6.00 0.00063 1.410 1.408
76 5-MethyI-l-heptene 235.9 0.922 0.7208 64.8 44.88 6.000 0.00067 1.4094 1.4069
77 6-Methyl-l-heptene 235.8 0.925 0.7163 66.0 44.60 5.962 0.00063 1.4070 1.4045
78 2-Methyl-2-heptene 252.7 0.663 0.7284 62.8 45.36 6.064 0.00064 1.4170 1.4145
79 3-Methyl-«'s-2-heptene 252 0.679 0.733 61.5 45.6 6.10 0.00055 1.419 1.417
80 3-Methyl-(rcms-2-heptene 252 0.679 0.733 61.5 45.6 6.10 0.00055 1.419 1.417
81 4-Methyl-cis-2-heptene 237 0.900 0.720 65.0 44.8 5.99 0.00063 1.410 1.408
82 4-Methyl-(rans-2-heptene 237 0.900 0.720 65.0 44.8 5.99 0.00063 1.410 1.408
83 5-Methy l-c*s-2-he ptene 244 0.781 0.727 63.1 45.3 6.06 0.00064 1.414 1.412
84 5-Methyl-fr*ans-2-heptene 244 0.781 0.727 63.1 45.3 6.06 0.00064 1.414 1.412
85 6-Methyl-cis-2-heptene 243 0.809 0.722 64.4 44.9 6.00 0.00054 1.412 1.410
86 6-Methyl-frams-2-heptene 243 0.809 0.722 64.4 44.9 6.00 0.00054 1.412 1.410
87 2-Methyl-cis-3-heptene 234 0.966 0.710 67.7 44.2 5.91 0.00066 1.407 1.405
88 2-Methyl-frans-3-heptene 234 0.945 0.710 67.7 44.2 5.91 0.00066 1.407 1.405
89 3-Methyl-cis-3-heptene 250 0.703 0.732 61.8 45.6 6.10 0.00064 1.418 1.416
90 3-Methyl-fr*ans-3-heptene 250 0.703 0.732 61.8 45.6 6.10 0.00064 1.418 1.416
91 4-Methyl-cis-3-heptene 252 0.679 0.729 62.6 45.4 6.07 0.00050 1.417 1.415
92 4-Methyl-(r<ms-3-heptene 252 0.679 0.729 62.6 45.4 6.07 0.00050 1.417 1.415
93 5-Methyl-cis-3-heptene 234 0.966 0.717 65.9 44.6 5.96 0.00054 1.410 1.408
94 5-Methyl-(rans-3-heptene 234 0.966 0.717 65.9 44.6 5.96 0.00054 1.410 1.408
95 6-Methyl-cis-3-heptene 239 0.8685 0.71Z 65.9 44.6 5.96 0.00054 1.410 1.408
96 6-Methyl-(rans-3-heptene 239 0.899 0.717 65.9 44.6 5.96 0.00054 1.410 1.408
97 2-Ethyl-l-hexene 248 0.728 0.7314 62.0 45.55 6.089 0.00064 1.4157 1.4132
98 3-Ethyl-l-hexene 230.5 1.025 0.719 65.3 44.8 5.99 0.00067 1.407 1.405
99 4-Ethyl-l-hexene 235 0.932 0.730 62.3 45.4 6.07 0.00050 1.412 1.410
'
NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64-
2. M.W. — molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

16
 1C1.3
TABLE 1C1.3—Monoolefins and Diolefins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Ca Dacity at Flammability

sion if the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,0 Liquid, Pressure Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10< (nr -nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form HaO Net, to form H2O Motor Method Research Method No.
Fahr Boiling (liquid)+COi (gas) (gasJ+COs (gas) D357 D 908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

125 125 0.50 135.6 20 352 120 670 18 991 112 600 (1.0) 50
121 121 0.51 133.8 20 401 119 140 19 040 111 190 (1.0) 81.6 84.2 95.6 +0.05* 51
125 125 0.50 133.8 20 325 120 250 18 964 112 190 (1.0) 84.2 86.4 99.3 +0.17* 52
121.7 122.2 0.51 127.9 20 320 118 370 18 959 110 440 (1.0) 84.6 87.3 99.2 +0.36* 53
120 120 0.51 131.9 20 353 119 090 18 993 111 130 (1.0) 86.1 87.3 +0.3* +0.6* 54
120 120 0.51 131.9 20 361 119 200 19 000 111 230 (1.0) 80.9 98.9 +0.1* 55
121.5 121.7 (p. see) 0.52 123.6 20 348 116 560 18 988 108 760 (1.0) 85.4 87.7 +0.4* +0.8* 56
127 127 0.49 135.6 20 336 122 890 18 975 114 670 (1.0) 80.6 84.1 93.7 97.6 57
130 130 ([Link]) 0.49 135.6 20 289 123 870 18 930 115 570 (1-0) 80.0 83.3 97.5 99.5 58
128.6 128.9 0.51 132.6 20 293 118 350 18 934 110 420 (1.0) 85.3' 86.4 100 +0.16* 59
127 127 0.50 133.8 20 298 121 510 18 937 113 360 (1.0) 82.2 85.1 96.0 99.5 60
127 127 0.50 135.6 20 296 122 040 18 935 113 860 (1.0) 61
123.5 124.2 0.51 127.7 20 372 119 540 19 011 111 560 (1.0) 90.2 +0.5* 62
123.2 123.6 0.51 129.2 20 300 117 400 18 939 109 530 (1.0) 90.9 94.5 +0.5* +0.9* 63
119.2 119.4 0.50 132.6 20 332 120 940 18 973 112 850 (1.0) 82.0 85.6 97.0 +0.1* 64
119.6 120.1 95.4* (0.394) 0.50 126.5 20 318 120 120 18 957 112 080 (1.0) 90.5 93.7 +0.5* +1.2* 65

116.9 116.8 0.557 0.364 90.5 0.3693 0.6057 129.3 BO see IBB S40 19 005 111, 170 (0.9) 34.7 57.7 28.7 63.5 66
118 118 101.3* (O.S8l) 0.50 132.1 (20 368) (IBS 733) (19 005) (115 500) (0.9) 56.5 73.0 56.3 78.7 67
120 120 101.3h (0.387) 0.516 131.8 (BO sm) (lBB 9B0) (18 998) (115 000) (0.9) 56.5 73.0 56.3 78.7 68
119 119 0.50 131.5 (0.9) 69
121 121 (0.377) 0.51 131.5 (BO 358) (IBB IBS) (18 998) (114 900) (0.9) 68.1 81.2 72.5 89.4 70
120 120 (0.870) 0.50 131.3 (B0 357) (IBS lit) (18 996) (m 900) (0.9) 71
122 122 (0.377) 0.51 131.1 (B0 31,7) (m sso) (18 987) (113 730) (0.9) 74.3 84.2 73.3 91.8 72
122 122 ([Link]) 0.512 130.0 (BO sis) (m 788) (18 9B9) (114 370) (0.9) 66.3 79.6 70.2 87.9 73
117 117 0.51 128.4 (0.9) 74
117 117 0.51 128.9 (0.9) 75
117 117 0.50 128.9 (0.9) 76
117 117 0.51 128.9 (0-9) 62.6 76.6 63.6 87.2 77
124 124 0.50 130.8 (0.9) 73. ll 81.6 79.8' 93.8 78
124 124 0.50 130.7 (0.9) 79
124 124 0.50 131.0 (0.9) 80
119 119 0.50 129.0 (0.9) 81
121 121 0.50 129.0 (0.9) 82
119 119 0.50 130.0 (0.9) 83
121 121 0.50 130.0 (0.9) 84
119 119 0.50 129.7 (0.9) 65.5 80.5 71.3 90.2 85
121 121 0.50 129.7 (0.9) 65.5 80.5 71.3 90.2 86
119 119 0.51 128.6 (0.9) 87
121 121 0.51 128.7 (0.9) 80.6! 85.0 94.6l 99.8 88
124 124 0.50 130.5 (0.9) 89
124 124 0.50 130.5 (0.9) 90
124 124 V 0.50 130.7 (0.9) 91
124 124 0.50 130.7 (0.9) 92
119 119 0.51 128.6 (0.9) 93
121 121 0.51 128.6 (0.9) 94
119 119 0.51 129.2 (0.9) 95
121 121 0.51 129.0 (0.9) 82.0 86.5 93.4 +0.03* 96
121 121 0.50 130.2 (0.9) 97
117 117 0.51 128.2 (0.9) 98
117 117 0.50 128.7 (0.9) ... 99

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

17
 1C1.3
TABLE 1C1.3—Monoolefins and Diolefins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' °' * the Liquid,*1 no
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.at 1 Pres- Air at 1 Grav- ity*. < sion*- a
No. Compound atmos, sure at atmos, ity <•• « at 60
deg 100 F, deg " Tem- 60 F/60 F F, deg V\dTJp
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at68F at77F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Monoolefins, CsHu (continued):

100 2,3-Di methyl-1-hexene 230.9 1.018 0.7321 61.8 45.20 6.042 0.00068 1.4113 1.4089
101 2,4-DimethyI-l-hexene 232.2 0.992 0.724 63.9 45.1 6.03 0.00068 1.411 1.409
102 2,5-Dimethyl-l-hexene 232.9 0.978 0.7217 64.5 44.94 6.008 0.00068 1.4105 1.4080
103 3,3-DimethyI-l-hexene 219 1.284 0.7183 65.5 44.73 5.980 0.00063 1.4070 1.4046
104 3,4-Dimethyl-l-hexene 234 0.966 0.728 62.9 45.3 6.06 0.00064 1.413 1.411
10S 3,5-Dimethyl-l-hexene 219 1.284 0.712 67.2 44.3 5.92 0.00067 1.404 1.402
106 4,4-Dimethyl-l-hexene 225.0 1.144 0.7241 63.9 45.09 6.028 0.00063 1.4102 1.4078
107 4,5-Dimethyl-l-hexene 228 1.074 0.732 61.8 45.6 6.10 0.00064 1.414 1.412
108 5,5-Di methyl-1-hexene 216.5 1.353 0.713 66.9 44.4 5.94 0.00067 1.4049 1.4024
109 3-Ethyl-«'s-2-hexene 250 0.703 0.741 59.4 46.1 6.16 0.00051 1.424 1.422
110 3-Ethyl-*rans-2-hexene 250 0.703 0.741 59.4 46.1 6.16 0.00051 1.424 1.422
111 4-Ethyl-czs-2-hexene 235 0.932 0.729 62.6 45.4 6.07 0.00064 1.412 1.410
112 4-Ethyl-£rans-2-hexene 235 0.932 0.729 62.6 45.4 6.07 0.00064 1.412 1.410
113 2,3-DimethyI-2-hexene 251.20 0.683 -175.2 (S96.8) (680) (0 0663) 0.7452 58.3 46.41 6.204 0.00065 1.4268 1.4244
114 2,4-DimethyI-2-hexene 231.1 1.014 0.7257 63.4 45.19 6.041 0.00068 1.4118 1.4094
115 2,5-Dimethyl-2-hexene 234.0 0.918 0.724 63.9 45.1 6.03 0.00068 1.4140 1.4115
116 3,4-Dimethyl-ct's-2-hexene 241 0.838 0.741 59.5 46.1 6.16 0.00051 1.418 1.416
117 3,4-Dirnethyl-irans-2-hexene 241 0.838 0.741 59.5 46.1 6.16 0.00051 1.418 1.416
118 3,5-DimethyI-«'s-2-hexene 234 0.966 0.729 62.6 45.4 6.07 0.00064 1.416 1.414
119 3,5-Dimethyl-frans-2-hexene 234 0.966 0.729 62.6 45.4 6.07 0.00064 1.416 1.414
120 4,4-Di methyl-cis-2-hexene 223 1.195 0.726 63.4 45.2 6.04 0.00063 1.413 1.411
121 4,4-Dimethyl-*rans-2-hexene 223 1.195 0.726 63.4 45.2 6.04 0.00063 1.413 1.411
122 4,5-Dimethyl-c*'s-2-hexene 230 1.037 0.729 62.6 45.4 6.07 0.00064 1.413 1.411
123 4,5-DimethyI-(rans-2-hexene 230 1.037 0.729 62.6 45.4 6.07 0.00064 1.413 1.411
124 5,5-Dimethyl-m-2-hexene 224.4 1.157 0.7215 64.6 44.93 6.006 0.00068 1.4113 1.4088
125 5,5- Di met hy l-*rans-2-hexene 219.4 1.278 0.7111 67.5 44.28 5.919 0.00067 1.4055 1.4030
126 3-Ethyl-3-hexene 241 0.838 0.733 61.5 45.6 6.10 0.00055 1.418 1.416
127 2,2-Dimethyl-ci's-3-hexene 221.77 1.308 -215.25 0.7172 65.8 44.66 5.970 0.00063 1.4099 1.4074
128 2,2-Dimethyl-/rans-3-hexene 213.53 1.477 0.7085 68.2 44.12 5.898 0.00071 1.4063 1.4037
129 2,3-Dimethyl-a's-3-hexene 237 0.900 0.732 61.8 45.6 6.10 0.00064 1.416 1.414
130 2,3-Dimethyl-/ra?is-3-hexene 237 0.900 0.732 61.8 45.6 6.10 0.00064 1.416 1.414
131 2,4-Dimethyl-cis-3-hexene 228.2 1.073 0.7223 64.4 44.98 6.013 0.00068 1.4140 1.4114
132 2,4-Dimethyl-irans-3-hexene 225.7 1.130 0.7191 65.2 44.78 5.986 0.00076 1.4126 1.4101
133 2,5-Dimethyl-c*s-3-hexene 216 1.556 0.714 66.7 44.4 5.94 0.00053 1.406 1.404
134 2,5-Dimethyl-(ro?is-3-hexene 216 1.373 0.714 66.7 44.4 5.94 0.00053 1.406 1.404
135 3,4-Di methyl-cis-3-hexene 252 0.679 0.751 56.9 46.8 6.26 0.00066 1.430 1.428
136 3,4-Dimethy Wrans-3-hexene 252 0.679 0.751 56.9 46.8 6.26 0.00066 1.430 1.428
137 2-n-propyl-l-pentene 243.9 0.789 0.7284 62.7 45.36 6.064 0.00064 1.4136 1.4111
138 2-Isopropyl-l-pentene 235 0.975 0.729 62.6 45.4 6.07 0.00064 1.414 1.412
139 3-Methyl-2-ethyl-l-pentene 234.5 0.948 0.733 61.5 45.6 6.10 0.00064 1.4142 1.4118
140 4-Methyl-2-ethyl-l-pentene 230.5 1.025 0.7240 63.9 45.08 6.026 0.00059 1.4105 1.4080
141 2-Methyl-3-ethyI-l-pentene 230 1.102 0.734 61.3 45.7 6.11 0.00064 1.415 1.413
142 3-Methyl-3-ethyl-l-pentene 234 0.966 0.7348 61.0 45.76 6.117 0.00060 1.418 1.416
143 4-Methyl-3-ethyl-l-pentene 225.5 1.132 0.7244 63.8 45.11 6.030 0.00068 1.4097 1.4072
144 2,3,3-Trimethyl-l-pentene 226.96 1.100 -92 (389.6) (ses) (o 0662) 0.7398 59.8 46.07 6.159 0.00069 1.4174 1.4151
145 2,3,4-Trimethyl-l-pentene 226 1.113 0.733 61.5 45.6 6.10 0.00055 1.415 1.413
146 2,4,4-Trimethyl-l-pentene 214.59 1.559 -136.22 (.383. e) WS) (o 0652) 0.7194 65.2 44.80 5.989 0.00063 1.4086 1.4060
147 3,3,4-Trimethyl-l-pentene 221 1.238 0.733 61.5 45.6 6.10 0.00055 1.4144 1.4120
148 3,4,4-Trimethyl-l-pentene 219 1.284 0.723 64.2 45.0 6.02 0.00063 1.412 1.410
149 2-Methyl-3-ethyl-2-pentene 242.6 0.744 0.743 58.9 46.3 6.19 0.00065 1.4247 1.4222
150 4-Methyl-3-ethyl-m-2-pentene 241 0.838 0.743 58.9 46.3 6.19 0.00065 1.424 1.422
151 4-Methyl-3-ethyl-(raras-2-pentene 237.7 0.889 0.7394 59.9 46.04 6.155 0.00060 1.4210 1.4183
152 2,3,4-Trimethyl-2-pentene 241.29 0.830 -171.9 0.7479 57.6 46.58 6.227 0.00061 1.4275 1.4249
153 2,4,4-Trimethyl-2-pentene 220.84 1.290 -159.36 (S85.0) (m) (o 0652) 0.7262 63.3 45.22 6.045 0.00063 1.4160 1.4135
154 3,4,4-Trimethyl-CT's-2-pentene 234 0.963 0.743 58.9 46.3 6.19 0.00065 1.423 1.421
155 3,4,4-TrimethyI-(rans-2-pentene 234 0.966 0.743 58.9 46.3 6.19 0.00065 1.423 1.421
156 3-Methyl-2-isopropyl-l-butene 219 1.284 0.726 63.4 45.2 6.04 0.00063 1.4085 1.4061
157 3,3-Dimethyl-2-ethyl-l-butene 230 1.037 0.732 61.8 45.6 6.10 0.00064 1.4159 1.4135

NOTES:
1. Valuesin parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

18
 1C1.3
TABLE 1C1.3—Monoolefins and Diolefins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,41 Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10' (w -nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form H20 Motor Method Research Method No
Fahr Boiling (liquid)+CO2 (gas) (gas)+COs (gas) D357 D908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmoa per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

122 122 0.50 128.1 (0.9) 83.6 88.1 96.3 10(

122 122 0.50 128.4 (0.9) 10
122 122 0.50 128.4 (0.9) 10
117 117 0.51 126.6 (0.9) 10
117 117 0.50 128.4 (0.9) 10
117 117 0.51 126.5 (0.9) 10
117 117 0.50 127.4 (0.9) 10
117 117 0.50 127.8 (0.9) 10
117 117 0.51 126.3 (0.9) 10
124 124 0.49 130.5 (0.9) 10
124 124 0.49 130.5 (0.9) 11
119 119 0.50 128.7 (0.9) 11
121 121 0.50 128.7 (0.9) 11
127 127 (0.399) 0.49 130.2 (20 269) (125 93S) (18 886) (in 341) (0.9) 79.3 93.1 97.1 11
124 124 0.50 128.2 (0.9) 11
124 124 0.50 128.9 (0.9) 82.2 85.3 95.2 +0.10* 11
124 124 0.49 129.4 (0.9) 11
124 124 0.49 129.4 (0.9) 11
124 124 0.50 128.1 (0.9) 11
124 124 0.50 128.1 (0.9) 11
119 119 0.50 127.0 (0.9) 12
121 121 0.50 127.0 (0.9) 12
119 119 0.50 128.1 (0.9) 12
121 121 0.50 128.1 (0.9) 12
119 119 0.50 127.3 (0.9) 12
121 121 0.51 126.5 (0.9) 12
124 124 0.50 129.4 (0.9) 12
119 119 0.51 123.1 20 348 121 670 18 987 US 530 (0.9) 88.0 +0.7* 12
121 121 0.51 124.1 20 276 119 780 18 915 111 740 (0.9) 89.0 91.9 +0.5* +1.6* 12
124 124 0.50 128.9 (0.9) 12
124 124 0.50 128.9 (0.9) 13
124 124 0.50 127.9 (0.9) 13
124 124 0.51 127.4 (0.9) 13
119 119 0.51 125.5 (0.9) 87.4' 90.6 +0.4* +1.1*'' 13
121 121 0.51 126.3 (0.9) 83.3 87.3 99.8 +0.25* 13
127 127 0.49 130.3 (0.9) 13
127 127 0.49 130.3 (0.9) 13
123 123 0.50 129.9 (0.9) 13
122 122 0.50 128.4 (0.9) 13
122 122 0.50 128.6 (0.9) 13
122 122 0.50 128.1 (0.9) 14
122 122 0.50 125.4 20 SOS 124 850 18 939 115 890 (0.9) 85.3 87.6 99.5 +0.24* 14
117 117 - 0.50 128.4 (0.9) 14
117 117 0.50 127.4 (0.9) 14
122 122 ([Link]) 0.49 127.6 (20 287) (125 lSl) (18 928) (US 750) (0.9) 85.7 87.2 +0.6* +0.9* 14
122 122 0.50 127.6 (0.9) 14
122 122 (0.874) 0.497 120.2 20S7S m 610 18 914 us 450 (0.9) 86.5 88.8 +0.6* +1.0* 14
117 117 0.50 126.8 (0.9) 14'
117 117 0.50 126.6 (0.9) 14i
127 127 0.49 129.7 (0.9) 82.0 85.6 95.6 99.4 14!
124 124 0.49 129.4 (0.9) 15(
124 124 0.49 129.0 (0.9) 151
127 127 0.49 129.5 (0.9) 80.9 84.4 96.8' +0.02* 155
125 125 ».o (0.374) 0.501 124.9 20 287 122 820 18 926 114 580 (0.9) 86.2 88.0 +0.3* +0.6* 15;
124 124 0.49 128.6 (0.9) 86.1! 88.0! +0.2* +0.5*'' 154
124 124 0.49 128.4 (0.9) 86.11 88.0l +0.2* +0.5* 155
122 122 0.50 126.6 (0.9) 156
122 122 0.50 128.1 (0.9) 157

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

19
 1C1.3

TABLE 1C1.3—Monoolefins and Diolefins (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' •• " the Liquid," nz>
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.at 1 Pres- Air at 1 Grav- ity*- ' sion*- a
Compound atmos, sure at atmos, ityo. c at 60
deg
Fahr
100 F,
psi
deg Tem- 60 F/60 F F, deg v\aTjP
Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at68F at77F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Monoolefins, CoHia, M.W. 126.243:

1-Nonene 296.40 0.219 -114.41 340 606 0.074 0.7334 61.4 45.67 6.105 0.00059 1.41572 1.41333
2-Methyl-l-octene 292.41 -107.77 0.7383 60.1 45.98 6.147 0.00060 1.4186 1.4162
2,3-Di methyl-2-heptene 293.2 (0.85) -16S.S (S61.» (0.0661) 0.739 60.0 46.02 6.152 0. 1.4S19

Monoolefins, CioH», M.W. 140.247:

1-Decene 339.08 -87.30 320 647 0.074 0.7450 58.4 46.39 6.202 0,00060 1.42146 1.41913
2-Methyl-l-nonene 335.1 -83.56 0.7493 57.3 46.66 6.238 0.00061 1.4241 1.4217

Diolefins, CsHU, M.W. 40.065:

Propadiene (allene) -30.1 (168) -213.3 (793) 248 (0.0649) 0.6S7d 40.90s

Diolefins, [Link], M.W. 54.092:

1,2-Butadiene + 51.53 (to) -213.16 (66$) ($39) (0.0649) 0.658* 83.5* 40.9* 5.47* 0.00098*
1,3-Butadiene 24.06 (60) -164.02 628 306 0.0654 0.6272d 94.1* 39.05* 5.220'' 0.00113*

Diolefins, CSH», M.W. 68.119:

1,2-Pentadiene 112.72 11.479 -215.09 (690.8 (446) (0.0649) 0.6977 71.3 43.44 5.807 0.00083 1.42091 1.41773
1, c*s-3-Pentadiene 111 11.811 -221.50 (682) (438) (0.0660) 0.6962 71.7 43.35 5.795 0.00082 1.43634 1.43291
1, tfrarcs-3-Pentadiene 107.64 12.692 -125.39 (579) (434) (0.0650) 0.6812 76.2 42.41 5.670 0.00085 1.4 1.42669
1,4-Pentadiene 78.73 21.91 -234.92 (649.6 (400) (0.O660) 0.6659 81.0 41.46 5.542 0.00083 l.i 1.38542
2,3-Pentadiene 118.86 10.143 -194.17 0.7002 70.6 43.60 5.829 0.00083 1.42842 1.42509
3-Methyl-l, 2-butadiene 105.49 13.5 -172.51 (679) (434) (0 0.6915 73.1 43.06 5.756 0.00086 1.42026 1.41692
2-Methyl-l,3-butadiene (isoprene) 16.672 -230.74 (412) (0.0660) 0.6861 74.7 42.72 5.711 0.00086 1.42194 1.41852

Diolefins, C.H., M.W. 82.146:

1,2-Hexadiene 169 0.7198 65.0 44.82 5.992 0.00072 1.4282 1.4252
1, cfs-3-Hexadiene 163.63 0.7127 67.0 44-38 6.983 0.00080 1.4410 1.4879
1, tra ws-3-Hexadiene 168.74 0.7087 68.2 44-18 6.900 0.00080 1.4406 1.4375
1, w's-4-Hexadiene 151.8 0.705 69.2 43.8 5.86 0.00066 1.4049 1.4018
1, (rans-4-Hexadiene 149.0 -217. 0.705 69.2 43.8 5.86 0.00066 1.4104 1.4073
1,5-Hexadiene 139.01 (7-1) -221, 9.7) (478) (0.0650) 0.6970 71.5 43.40 5.802 0.00078 1.4042 1.4010
2,3-Hexadiene 154.4 0.685 75.1 42.6 5.69 0.0H085 1.395 1.392
cis-2, m-4-Hexadiene 184.87 0.7393 69.9 46.04 6.154 0.0CO81 1.4606 1.4575
cis-2, (rans-4-Hexadiene 182.26 -HI. 0.7278 62.9 45.32 0.0C&1 1.4560 1.4529
*rans-2,*ra?is-4-Hexadiene 179.91 -48 0.7195 65.2 44.81 0.00081 1.4510 1.4479
3-Methyl-l, 2-pentadiene 158 0.720 65.0 44.8 5.99 0.00081 1.425 1.422
4-Methyl-l, 2-pentadiene 158 0.713 66.9 44.4 5.94 0.00080 1.424 1.421
2-Methyl-l, ds-3-pentadiene 169 0.724 63.9 45.1 6.03 0.00081 1.446 1.443
2-Methyl-l ,*rans-3-pentadiene 168.19 -179.69 0.724 63.9 45.1 6.03 0.00081 1.4448 1.4422
3-Methyl-l, cis-3-pentadiene 171 0.740 59.7 46.1 6.16 0.00079 1.452 1.449
3-Methyl-l ,fra?is-3-pentadiene 171 0.740 59.7 46.1 6.16 0.00079 1.452 1.449
4-Methyl-l ,3-pentadiene 170.6 (4J) -194.1 (514.4) (0.0650) 0.724 63.9 45.1 6.03 0.00081 1.4534 1.4503
2-Methyl-l ,4-pentadiene 133 0.699 70.9 43.5 5.82 0.00078 1.405 1.402
3-Methyl-l ,4-pentadiene 131 0.700 70.6 43.6 5.83 0.00070 1.405 1.402
2-Methyl-2,3-pentadiene 162 0.716 66.1 44.6 5.96 0.00067 1.425 1.422
2-Ethyl-l, 3-butadiene 167 0.722 64.5 44.9 6.00 0.00068 1.445 1.442
2,3-Dimethyl-l ,3-butadiene 155.79 (5.2) -104.87 (0.0650) 0.7314 62.0 45.55 6.089 0.00059 1.4394 1.4362

Diolefins, C7H12, M.W. 96.173:

2-Methyl-l, 5-hexadiene 190.6 (2.8) (471.7) (0.0850) 0.7248 68.8 45.11 6.031 0.00071
2-Methyl-2,4-hexadiene 232.7 (1.1) -102.3 (495.2) (0.0650) 0.7491 67.4 46.65 8.238 0.00068
2,4-Dimethyl-l, 3-pentadiene 199.7 (1-8) -173.2 (426.2) (421) (0.08 0.7410 59.6 46.16 0.00059

Diolefins, CsHu, M.W. 110.200:

2,6-Octadiene 266.1 (1-1) -104.8 (415.9) (607) (0.0690) 0.7483 67.6 46.60 1.230 0.00058
3-Methyl-l ,5-heptadiene 231.8 (1-4) -70.6 (405.6) (590) (0.O644) 0.7836 61.4 46.68 1.106 0.00063
2,5-Di methyl-1,5-hexadiene 237.8 (1-2) -104.1 (406.6) (591) (0.0670) 0.7465 68.3 46-49 '.215 0.00069
2,5-Dimethyl-2,4-hexadiene 274-1 (0.62) +67.1 (428.2) (624) (0 0.7666 63.8 47.69 •-S76 0.00056

Diolefins, CsHie, M.W. 124.227:

2,6-Di methyl-1,5- heptadiene 289 (0.45) -94.0 (390) (662) 0.7724 61.7 48.10 6.480 0.00063
2-Methyl-3-ethyl-l, 5-hexadiene (0.42) -94.0 (S83.6) (660) 0.7668 63.0 47.76 0.00062

Diolefins, CioHis, M.W. 138.254:

3,7-Di methyl-1,6-octadiene 322 (0.23) -94.0 368.9 (0.0645) 0.7621 54.2 47.46 6.345 0.00066

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.
20
 1C1.3
TABLE 1C1.3—Monoolefi ns and Diolefins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,0 Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10' (n*—ne)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form HaO Net, to form HtO Motor Method Research Method
Fahr No.
Boiling (liquid)-fCOj (gas) (gas)+CO, (gas) D 357 D908
Gas, Liquid Point, 1
at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

114.5 114.4 0.704 0.429 100.4 0.3703 0.505 123.8 20 327 124 280 18 966 115 960 (0.8) 158
116 116 0.510 (0.8) 159
([Link]) 0.50 (iii) (20 278) (124 900) (18 917) (lie 550) 160

113.0 112.9 0.877 0.505 111.4 0.3713 0.5041 118.5 20 S00 126 080 18 9SS 117 6S0 (0.7) 161
115 115 0.509 (0.7) 162

0.3439 (218) (20 710)" (11s 240) (19 755) 108 022 163

0.3458 0.5408 (181) 20 429^'' 111 930d 19 SJld 106 1401* (2.0) (12) 164
0.3412 0.5079 (m) 20 036'''° 104 780* 18 979* 99 250* 2.0 11.5 165

164.7 164.6 0.360 0.5US (160) 20 S47° 118 S40 19 227 111 830 (1.5) 166
243.9 243.8 0.321 0.5054 (160) 19 984" 115 990 18 864 109 490 (1.5) 167
245.8 245.7 0.354 0.5145 (158) 19 944° US 270 18 823 106 900 (1.5) 168
153.2 153.1 0.359 0.5066 (146) 20 151" 111 860 19 031 105 650 (1.5) 169
174.6 174.5 0.347 0.5m 20 295" 118 480 19 173 111 940 (1.5) 170
171.7 171.8 0.361 0.5266 (156) 20 280" 116 920 19 158 110 450 (l-o) 42.4 49.6 61.0 71.5 171
224.9 224.8 0.357 0.5191 (153) 19 951" 114 120 18 8S0 107 710 (1-5) 81.0 79.4 99.1 98.8 172

(1.2) 173
225 225 (1.2) 174
225 225 (1.2) 175
(1.2) 176
(1.2) 177
([Link]) (0.51) (184) (20 138) (117 005) (18 960) (110 160) (1.2) 37.6 43.3 71.1 80.7 178
(1-2) 179
225 225 (1-2) 80.7 80.0 97.1 97.2 180
225 225 (1.2) 80.7 80.0 97.1 97.2 181
225 225 (1-2) 80.7 80.0 97.1 97.2 182
(1-2) 183
(1-2) 184
225 225 (1.2) 185
225 225 (1.2) 186
225 225 (1-2) 187
225 225 (1.2) 188
225 225 (0.S40) (0.54) (145) (19 950) (120 502) (18 782) (us 427) (1.2) 189
(1.2) 190
(1.2) 191
(1.2) 192
225 225 (1.2) 193
225 225 (0.S72) (0.58) (HI) (19 890) (121 286) (18 708) (114 071) (1.2) 83.4 82.3 99.2 98.9 194

(0.S90) (0.58) (125) (20 077) (121 287) (18 925) (114 809) 195
(0.S59) (0.58) (137) (19 95S) (124 606) (18 758) (117 142) 196
(0.S7O) (0.55) (150) (19 868) (122 741) (18 675) (115 875) 197

(0.386) (0.47) ' (107) (20 107) (125 446) (18 895) (ll7 888) 198
(0.SS9) (0.48) (us) (20 111) (122 980) (18 899) (115 567) 199
(0.S68) (0.52) (114) (19 941) (124 113) (18 729) (116 569) 200
(0.868) (0.5%) (lie) (19 916) (127 US) (18 580) (118 612) 201

(0.875) (0.50) (109) (20 024) (128 934) (18 796) (l21 026) 202
(0.848) (0.47) (109) (20 105) (128 529) (18 873) (120 656) 203

(0.866) (0.47) (10s) (20 076) (127 565) (18 832) (119 660) ... 204

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.
21
 1C1.4

TABLE 1C1.4—Cycloolefins (U.S. Units)

Density ofa the Refractive Index of

Critical Constants Liquid*. < b the Liquid,0 nz>
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.at 1 Pres- Air at 1 Grav- ity*. « sion*. °
No. Compound atmos, sure at atmos, ity". ' at 60
deg 100 F, deg Tem- 60 F/60 F F, deg V\dT)p
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at 68 F at77F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Alkylcyclopentenes, CtHs, M.W. 68.119:

l Cyclopentene 111.62 -211.15 451.2 0.7776 50.5 48.43 6.474 0.00078 1.42246 1.41940

Alkylcyclopentenes, CsHio, M.W. 82.146:

2 1-Methylcyclopentene 167.86 -195.75 0.7844 48.9 48.85 6.530 0.00068 1.4322 1.4294
3 3-Methylcyclopentene 148.82 0.7674 52.9 47.79 6.389 0.00077 1.4210 1.4184
4 4-Methylcyclopentene 150.19 -257.53 0.7736 51.4 48.18 6.441 0.00072 1.4209 1.4184

Alkylcyclopentenes, C7H12, M.W. 96.173:

5 1-Ethylcyclopentene 223.39 -181.25 0.8031 44.7 50.01 6.685 0.00065 1.4412 1.4387
6 3-EthylcycIopentene 207.99 0.7878 48.1 49.07 6.560 0.00064 1.4315 1.4291
7 4-EthylcycIopentene 208.8 0.788 48.1 49.1 6.56 0.00074 1.431 1.429
8 1,2-Dimethylcyclopentene 222.4 -130.7 0.8027 44.8 49.99 6.683 0.00065 1.4448 1.4420
9 1,3-Dimethylcyclopentene 198 0.771 52.0 48.0 6.42 0.00072 1.428 1.425
10 1,4-Dimethylcy clopentene 199.8 0.766 53.2 48.33 6.461 0.00073 1.4283 1.4255
11 1,5-Dimethylcyclopentene 216 -180 0.785 48.7 48.8 6.52 0.00059 1.4331 1.4304
12 3,3-Dimethylcyclopentene 190 0.776 50.8 48.3 6.46 0.00073 1.423 1.420
13 3, cis-4-Dimethylcyclopentene 0.782 49.4 48.7 6.51 0.00073 1.4300 1.4272
14 3, <rans-4-DimethylcycIopentene
15 3, cis-5-Dimethylcyclopentene
16 3,(rans-5-Dimethylcyclopentene
17 4,4-Dimethylcyclopentene 190 0.776 50.8 48.3 6.46 0.00073 1.423 1.420

Alkylcyclopentenes, Cs to C10:
18 1-re-Propylcyclopentene, CsHi4, M.W. 110.200 268.2 0.8062 44.0 50.21 6.712 0.00055 1.4452 1.4428
19 1-n-Butylcyclopentene, CnHu, M.W. 124.227 313 0.8115 42.9 50.54 6.756 0.00056 1.4486 1.4463
20 1-rs-Pentylcyclopentene, CioHis, M.W. 138.254 354 0.8165 41.8 50.85 6.798 0.00051 1.4516 1.4494

Alkylcyclohexenes. CsHio, M.W'. 82.146:

21 Cyclohexene 181.35 -154.29 549.1 0.8160 41.9 50.82 6.794 0.00066 1.44654 1.44377

Alkylcyclohexenes, C7H12, M.W. 96.173:

22 1-Methylcj'dohexene 230.54 -184.72 0.8166 41.8 50.86 6.799 0.00066 1.45046 1.44784
23 3-Methylcyclohexene 216.45 -190.3 0.8057 44.1 50.18 6.708 0.00060 1.4435 1.4410
24 4-Methylcyclohexene 216.93 -175.7 0.8038 44.5 50.06 6.692 0.00060 1.4414 1.4389

Alkylcyclohexenes, C8Hu, M.W. 110.200:

29 1-Ethylcyclohexene 278.61 -165.90 0.8269 39.6 51.50 6.885 0.00057 1.45668 1.454S7
26 3-Ethylcyclohexene 268.9 0.8152 42.1 50.77 6.805 0.00056 1.4500 1.4476
27 4-Ethylcyclohexene 271 0.815 42.1 50.7 6.78 0.00056 1.449 1.447
28 1,2-Di methylcyclohexene 280.38 -119.40 0.8307 38.8 51.74 6.917 0.00057 1.4620 1.4594
29 1,3-Dimethylcyclohexene 261 0.807 43.8 50.3 6.72 0.00060 1.449 1.447
30 1,4-Dimethylcyclohexene 262 -74 0.806 44.1 50.22 6.713 0.00060 1.446 1.444
31 1,5-DimethyIcyclohexene 262 0.8096 43.3 50.42 6.740 0.00056 1.450 1.448
32 1,6-Dimethylcyclohexene 268 0.820 41.1 51.0 6.82 0.00056 1.456 1.453
33 3,3-Dimethylcyclohexene 246 0.809 43.4 50.3 6.72 0.00060 1.445 1.443
34 4,4-Dimethylcyclohexene 243.05 -101.99 0.8051 44.2 50.14 6.704 0.00055 1.4418 1.4394

Alkylcyclohexene, Cs and C10:

35 1-n-Propylcyclohexene, C»Hi«, M.W. 124.227
36 l-r»-Butylcyclohexene, CioHis, M.W. 138.254

37 4-VinyIcycIohexene, C8Hi2, M.W. 108.184 m.4 0.50 -m.07 (o.m) 87.7 52.14 6.96 0.00045 1.4641

38 1,5-CycIooctadlene, CsHu, M.W. 108.184 (SOB) 0.60 -[Link] 0.8865 28.1 55.29 7.S8 0.00034 1.49SS

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

22
 1C1.4
TABLE 1C1.4—Cycloolefins (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,0 Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10» (nr-nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H20 Net, to form H2O Motor Method Research Method No.
Fahr Boiling (liquid)+C02 (gas) (gas)+C02 (gas) D357 D908
Gas, Liquid Point, 1
at G8 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

118.7 118.7 <-14 0.2544 0.4196 19 672° 127 530 18 551 120 270 (1.5) 69.7 73.4 93.3 94.8 1

124 124 19.4 0.285 (0.441) 19 656 128 5S0 18 494 120 9S0 (1.2) 72.9 77.1 93.6 97.0 2
119 119 0.281 (0.452) 19 724 126 190 18 561 118 760 (1.2) 3
0.281 (0-4S7) 19 756 127 430 18 594 119 930 (1.2) 4

119 119 34.2 (0.4S1) 19 731 132 080 18 541 124 110 (1.0) 72.0 78.2 90.3 95.7 5
(0.460) 19 772 129 880 18 580 122 060 (1.0) 71.4 76.6 90.8 96.5 6
(0.4S9) 19 799 130 060 18 608 122 240 (1.0) 7
125.8 125.8 0.306 (0.4H) (1.0) 8
0.303 (0.46S) (1.0) 9
0.303 (0-44S) (1.0) 10
120.8 120.8 0.303 (0.46S) (1.0) 11
0.295 (0-442) (1.0) 12
0.299 (0.4S9) (1.0) 13
0.301 (0.4SS) (1.0) 14
0.301 (0.468) (1.0) 15
0.301 (0.47S) (1.0) 16
(0.4m) (1.0) 17

57.6 (0.458) (0.9) 18

77.0 (O.464) (0.8) 19
(0.470) (0.7) 20

117.2 117.1 -4.0 0.4244 19 647 1SS 680 18 485 125 770 (1-2) 63.0 68.1 83.9 88.4 21

119.3 120.0 ([Link]) 19 629 133 640 18 438 125 520 (1.0) 72.0' 75.6' 89.2' 92.7' 22
(0.450) 23
(0.4S0) 67.0 72.7 84.1 89.5 24

117.3 117.0 (0.449) (0.9) 70.5 75.4 85.0 91.2 26

(0.457) 19 683 135 700 18 471 127 340 (0.9) 26
(0.440) (0.9) 27
123 123 (0-451) (0.9) 72.2 77.3 89.7 93.5 28
120 120 (0.460) (0.9) 29
119 119 (0.44S) (0.9) 30
119 119 (O.44S) (0.9) 31
(0.460) (0.9) 32
(0-442) (0.9) 33
118 115 (0.421) (0.9) 80.0' 81.2 96.2 97.7 34

(0.457) 35
(0.402) 36

(0.4SS) 37

... ... ... 38

NOTES:
1. Values in parentheses are estimated. For methods of estimation,
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

23
 1C1.5
TABLE 1C1.5—Acetylenes (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' "• • the Liquid,0 no
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in SpecificGrav- Expan-
.at 1 Pres- Air at 1 Grav- ity*. ' sion*- °
No. Compound atmos, sure at atmos, ityo. 0 at 60
deg 100 F, deg Tem- 60F/60F F, deg V\BT) P
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at68F at 77 F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Acetylenes* C2 and Cs:

l Ethyne (acetylene), C2H2, M.W. 26.038 -119" -114" 890.4 95.31 0.0695 0.616" 98.6q
2 Propyne (methylacetylene), CaH4, M.W. 40.065 -9.78 -152.9 816.2 264.63 (0.0666) (0.6S) (98.l) (89.22) (6.248)

Acetylenes, CiHt, M.W. 54.092:

3 1-Butyne (ethylacetylene) 46.53 («») -194.30 (688.4) 375.0 (0.0664) 0.65d 86.1° 40.9d 5.47°
4 2-Butyne (dimethylacetylene) 80.56 21.5 -26.03 (7S7.4) 419 (O.O664) 0.6965 71.6 43.37 5.798 0.00087 1.3921 1.3893

Acetylenes, CsHs, M.W. 68.119:

5 1-Pentyne 104.31 13.5 -158.3 (687.8) 428 (0.0668) 0.6954 71.9 43.30 5.788 0.00087 1.3852 1.3826
6 2-Pentyne 132.91 7.6 -164.7 (609.9) (482) (0.0668) 0.7160 66.1 44.58 5.959 0.00080 1.4039 1.4009
7 3-MethyI-l-butyne 79.41 21.9 -130.5 0.672 79.1 41.8 5.59 0.00096 1.3723 1.3695

Acetylenes, CsHio, M.W. 82.146:

8 1-Hexyne 160.38 (4.9) -205.4 (612.9) (606) (0.066$) 0.7206 64.9 44.87 5.998 0.00076 1.3989 1.3960
9 2-Hexyne 184.14 -129.05 0.7360 60.7 45.83 6.127 0.00069 1.4138 1.4109
10 3-Hexyne 178.56 (8.6) -153.58 (BIS.8) (688) (0.0662) 0.7274 63.0 45.30 6.056 0.00068 1.4113 1.4088
11 3-Methyl-l-pentyne 135.9 0.7084 68.2 44.11 5.897 0.00071 1.3916 1.3891
12 4-Methyl-l-pentyne 142.09 -156.3 0.7092 68.0 44.16 5.903 0.00071 1.3930 1.3905
13 4-Methyl-2-pentyne 163.62 -166.54 0.7204 64.9 44.86 5.997 0.00067 1.4057 1.4032
14 3,3-DimethyI-l-butyne 99.88 -108.8 0.6733 78.6 41.92 5.604 0.00088 1.3736 1.3706

Acetylenes, C7H12, M.W. 96.173:

15 1-Heptyne 211.53 (1.8) -113.6 (470.S) (66%) (0.0662) 0.7375 60.4 45.93 6.140 0.00069 1.4087 1.4061
16 2-Heptyne 234 0.753 56.4 46.8 6.26 0.00061 1.4230 1.4204
17 3-Heptyne 224.89 -202.9 0.7428 59.0 46.26 6.184 0.00069 1.4189 1.4163
18 3-Methyl-l-hexyne 185 0.7232 64.1 45.03 6.020 0.00068 1.4001 1.3975
19 4-Methyl-l-hexyne 196 0.7374 60.3 45.92 6.139 0.00069 1.4076 1.4050
20 5-Methyl-l-hexyne 197.33 (*•«) -191 (492.s) (668) (0.0646) 0.7321 61.8 45.59 6.094 0.00068 1.4059 1.4033
21 4-Methyl-2-hexyne 211.17 -161.7 0.7433 58.9 46.29 6.188 0.00070 1.4170 1.4144
22 5-Methyl-2-hexyne 216.43 -135.2' 0.7425 59.1 46.24 6.181 0.00070 1.4176 1.4150
23 2-Methyl-3-hexyne 203.4 -177.9 0.7296 62.4 45.43 6.073 0.00068 1.4120 1.4094
24 3-Ethyl-l-pentyne 183 0.7318 61.9 45.57 6.092 0.00068 1.4035 1.4009
25 3,3-Dimethyl-l-pentyne 158 0.7124 67.1 44.36 5.930 0.00071 1.3934 1.3908
26 3,4-Dimethyl-l-pentyne 176 0.7283 62.8 45.35 6.062 0.00068 1.4018 1.3992
27 4,4-Dimethyl-l-penty ne 168.93 -103.0 0.7189 65.3 44.76 5.984 0.00067 1.3983 1.3957
28 4,4-Dimethyl-2-pentyne 181 0.7223 64.4 44.98 6.013 0.00068 1.4071 1.4045

Acetylenes, C8Hi4, M.W. 110.200:

29 1-Octyne 259.18 (fi.7S) -110.7 (418.8) (809) (0.066l) 0.7511 56.9 46.77 6.252 0.00061 1.4163 1.4138
30 2-Octyne 279.93 (0.54) -78.9 (4S0.6) (668) (o.066l) 0.7638 53.7 47.57 6.359 0.00062 1.4276 1.4251
31 3-Octyne 271.67 (0.68) -155 (426.2) (646) (o.066l) 0.7567 55.5 47.12 6.299 0.00061 1.4250 1.4223
32 4-Octyne 268.7 (0.68) -m.s (414.7) (644) (0.0661) 0.7666 66.8 47.06 6.290 0.00061 1.4248 1.4226

Acetylenes, G>Hu, M.W. 124.227:

33 1-Nonyne 303.3 ([Link]) -58 (889.4) (666) (0.0661) 0.7622 54.1 47.49 6.348 0.00062 1.4219 1.4195
34 2-Nonyne 323.4 0.7729 51.6 48.14 6.435 0.00058 1.4327 1.4303
35 3-Nonyne 314.8 0.7640 53.7 47.58 6.361 0.00057 1.4288 1.4264

Acetylenes, CioHu, M.W. 138.254:

36 1-Deeyne 345 -47 0.7712 52.0 48.03 6.421 0.00058 1.4272 1.4249
37 2-Decyne 364.3 0.7805 49.8 48.61 6.498 0.00058 1.4364 1.4341
38 3-Decyne 354.7 ... ... 0.7700 52.3 47.95 6.410 0.00058 1.4315 1.4292

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p.; 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

24
 1C1.5
TABLE 1C1.5—Acetylenes (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flam inability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid, <* Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10< (nF-nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form H2O Net, to form HiO Motor Method Research Method No.
Fahr Boiling (liquid)+C02 (gas) (gas)+CO, (gas) D357 D 908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

0 2.5 80 1
0.3966
0.3545 (176) (20 ess)0 (108 366) (19 680) (lOS 359) 2

0.3513 0.5946 (179) 20 453i'» 112 070'* 19 393d 106 260'* 3

0.3372 0.5474 (197) 20 281<,'<> 117 780"1 19 223'' 111 OSO"' 70.2 71.5 85.9 86.4 4

119 119 0.3609 (0.577) (w) 20 374° 118 110 19 251 111 600 5
0.3383 (0.536) (167) 20 263° 120 930 19 140 114 230 6
0.3579 (0.567) 20 340° 113 890 19 217 107 600 7

115 115 0 3640 (0.567) (no) (» 351) (122 250) (19 178) (116 202) 8
115 115 (0.532) 9
119 119 (0 332) (0.632) (1U) (20 269) (122 869) (19 099) (115 914) 10
(0.659) * . .. 11
114 114 (0.559) 73.1' 77.3' 91.6' 96.6' 12
(0.523) 13
114 114 (0.6S7) 14

113 113 0.3664 (0.659) (131) (20 SOS) (124 844) (19 112) (117 619) 15
([Link]) 16
(0.530) 17
(0.562) 18
(0.652) 19
(0.351) (0.652) (127) (20 170) (123 098) (18 974) (115 798) 20
(0.622) 21
(0.622) 22
(0.522) 23
(0.552) 24
(0.535) 25
(O.645) 26
(0.536) 27
117 117 (0.605) 28

111 111 0.3680 (0.564) (121) (20 279) (126 964) (19 066) (119 376) 51.5 66.1 50.5 75.9 29
(0.368) (0.627) (122) (20 224) (128 788) (19 012) (121 068) 30
(0.357) (OJ27) (121) (20 225) (127 679) (19 018) (119 9SS) 31
(0.348) (O.627) (120) (20 226) (127 402) (19 014) (119 767) 32

110 110 0.3694 (0.549) (US) (20 261) (128 800) (19 OSS) (120 99S) 33
(0.626) 34
(0.526) 35

108 108 0.3703 (0.546) 36

(0.625) 37
(0.625) 38

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. — molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

25
 1C1.6
TABLE 1C1.6—Alkylbenzenes Naphthalene , Indans, and Tetrahydronaphthalene (U.S. Units)

Density of the Refractive Index of

Critical Constants Liquid*' «• 6 the Liquid,3 UD
at 60 F Coeffi-
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
.at 1 Pres- Air at 1 Grav- ity*. ' sion*- °
No. Compound atmos, sure at atmos, ity"' " at 60
deg 100 F, deg Tem- 60 F/60 F F, deg V\dT)T
Fahr psi Fahr Pres- pera- Vol- API at 60 F,
sure, ture, ume, lb per lb per per deg at68F at 77 F
psi deg cu ft cu ft gal Fahr
Fahr per lb

Alkylbenzenes, Ce and C7:

1 Benzene, CeHe, M.W. 78.114 176.17 3.224 41.96 710.4 552.22 0.0531 0.8844 28.5 55.096 7.3653 0.00066 1.50112 1.49792
2 Methylbenzene (toluene), CjHs, M.W. 92.143 231.13 1.032 -138.94 595.9 605.55 0.0549 0.8718 30.8 54.309 7.2601 0.00060 1.49693 1.49413

Alkylbenzenes, CsHio, M.W. 106.168:

3 Ethylbenzene 277.16 0.371 -138.91 523.5 651.24 0.0564 0.8718 30.8 54.299 7.2589 0.00054 1.49588 1.49320
4 1,2-Dimethylbenzene (o-xylene) 291.97 0.264 -13.30 541.4 675.0 0.0557 0.8848 28.4 55.111 7.3673 0.00055 1.50545 1.50295
5 1,3-Dimethylbenzene (m-xylene) 282.41 0.326 -54.12 513.6 651.02 0.0567 0.8687 31.4 54.114 7.2339 0.00054 1.49722 1.49464
6 1,4-Dimethylbenzene (p-xylene) 281.05 0.342 + 55.86 509.2 649.6 0.0572 0.8657 31.9 53.924 7.2086 0.00054 1.49582 1.49325

Alkylbenzenes, C1H12, M.W. 120.195:

7 n-Propylbenzene 318.63 0.1409 -147.06 464.1 689.41 0.0586 0.8665 31.8 53.97 7.215 0.00054 1.49202 1.48951
8 Isopropylbenzene (cumene) 306.34 0.188 -140.82 465.4 676.4 0.0570 0.8663 31.8 53.96 7.214 0.00054 1.49145 1.48890
9 l-Methyl-2-ethylbenzene 329.32 0.1059 -113.44 440.9 712 0.061 0.8851 28.4 55.13 7.370 0.00050 1.50456 1.50208
10 1 -Methyl-3-ethylbenzene 322.39 0.1240 -139.98 411.5 687 0.065 0.8690 31.3 54.13 7.236 0.00054 1.49660 1.49406
11 1 -Methyl-4-ethy lbenzene 323.62 0.1US -80.17 426.2 693 0.063 0.8657 32.0 53.92 7.208 0.00054 1.49500 1.49244
12 1,2,3-Trimethylbenzene 349.01 0.0666 -13.65 501.0 736.48 0.0552 0.8987 26.0 55.98 7.483 0.00045 1.51303 1.51150
13 1,2,4-Tri methylbenzene 336.88 0.0878 -46.79 468.8 708.76 0.0573 0.8803 29.2 54.83 7.330 0.00049 1.50484 1.50237
14 1,3,5-Trimethylbenzene 328.54 0.10S6 -48.45 453.5 687.58 0.0577 0.8696 31.2 54.16 7.241 0.00054 1.49937 1.49684

Alkylbenzenes, C10H14, M.W. 134.222:

IS rc-Butylbenzene (1-phenylbutane) 361.95 0.0469 -126.29 418.7 729.3 0.0593 0.8646 32.1 53.85 7.199 0.00054 1.48979 1.48742
16 Isobutylbenzene (l-phenyl-2-methyIpropane) 343.02 0.0809 -60.61 440 711 0.0671 0.8576 33.5 53.42 7.141 0.00053 1.48646 1.48400
17 sec-Butylbenzene (2-phenylbutane) 344.00 0.0777 -103.78 418.0 786.6 0.0671 0.8664 31.5 53.97 7.215 0.00054 1.49020 1.48779
18 fert-Butylbenzene ([Link]-2-methylpropane) 336.47 0.0926 -72.19 4S0.0 728 0.0660 0.8710 31.0 54.25 7.252 0.00054 1.49266 1.49024
19 l-Methyl-2-w-propylbenzene 364.95 -76.49 0.8779 29.5 54.68 7.310 0.00049 1.4996 1.4975
20 l-Methyl-3-n-propylbenzene 359.62 -116.59 0.8653 32.0 53.90 7.205 0.00054 1.4935 1.4911
21 l-MethyI-4-n-propylbenzene 362.16 -82.59 0.8628 32.5 53.74 7.184 0.00054 1.4922 1.4898
22 l-Methyl-2-isopropylbenzene (o-cymene) 352.72 (0.070) -96.71 410.0 746 0.0671 0.8810 29.1 54.88 7.336 0.00055 1.5005 1.4983
23 l-MethyI-3-isopropylbenzene (wi-cymene) 347.14 (0.078) -82.68 426.2 789.6 0.0671 0.8654 32.0 53.90 7.205 0.00054 1.4929 1.4905
24 l-Methyl-4-isopropylbenzene (p-cymene) 350.83 (0.071) -90.22 410 716 0.0671 0.8617 32.7 53.67 7.175 0.00054 1.4909 1.4885
25 1,2-Diethy lbenzene 362.22 -24.20 0.8843 28.5 55.08 7.363 0.00050 1.50346 1.50106
26 1,3-Diethylbenzene 358.04 -119.00 0.8684 31.4 54.09 7.231 0.00054 1.49552 1.49310
27 1,4-Diethylbenzene 362.82 -45.08 406.5 724.66 0.8664 31.8 53.96 7.214 0.00054 1.49483 1.49245
28 1,2-Dimethyl-3-ethylbenzene 381.11 -57.12 0.8965 26.3 55.84 7.465 0.00056 1.5117 1.5095
29 1,2-Di methyl-4-ethy lbenzene 373.14 -88.41 0.8788 29.5 54.74 7.318 0.00055 1.5031 1.5009
30 1,3-Dimethyl-2-ethylbenzene 374.09 +2.75 0.8948 26.6 55.74 7.451 0.00056 1.5107 1.5085
31 1,3-Dimethyl-4-ethylbenzene 370.83 -81.12 0.8807 29.2 54.86 7.334 0.00055 1.5037 1.5015
32 1,3-Dimethyl-5-ethylbenzene 362.52 -119.73 0.8692 31.3 54.14 7.237 0.00054 1.4981 1.4958
33 1,4-Dimethyl-2-ethylbenzene 368.37 -64.7 0.8816 29.0 54.91 7.340 0.00049 1.5043 1.5020
34 1,2,3,4-Tetramethylbenzene (prehnitene) 401.16 +20.75 0.9094 24.1 56.64 7.572 0.00045 1.5203 1.5181
35 1,2,3,5-Tetramethylbenzene (isodurene) 388.47 -10.61 0.8946 26.7 55.72 7.449 0.00050 1.5130 1.5107
36 1,2,4,5-Tetramethylbenzene (durene) 386.31 + 174.62 430 756 0.8918r 27.2r 55.53r 7.423' 0.00044'' 1.5116r 1.50931"

Naphthalenes, CioHs, M.W. 128.174:

m
37 Naphthalene 424.38 + 176.51 587.5 887.50 0.051 1.178•• 11.4 • 73.5"• 9.82m• 0.00019"• 1.5898'

Alkylindans, CsHio, M.W. 118.179:

38 2,3-Dihydroindene (indan) 352.13 -60.47 0.9685 14.6 60.33 8.065 0.00042 1.5385 1.5358

Alkylindans, C10H12, M.W. 132.206:

39 l-Methyl-2,3-dihydroindene (1-methylindan) 375.1 0.947 17.9 59.0 7.89 0.00024 1.5266 1.5240
40 2-Methyl-2,3-dihydroindene (2-methyIindan) 376.5 0.949 17.6 59.1 7.90 0.00053 1.5220 1.5194
41 4-Methyl-2,3-dihydroindene (4-methylindan) 401.9 0.975 13.6 60.7 8.11 0.00049 1.5348 1.5322
42 5-Methyl-2,3-dihydroindene (5-methylindan) 395.6 0.953 17.0 59.3 7.93 0.00053 1.5336 1.5310

Tetrahydronaphlhalenes, G0H12, M.W. 132.206:

43 1,2,3,4-Tetrahy dronaphthalene 405.72 -32.38 0.9747 13.7 60.72 8.118 0.00043 1.54135 1.53919

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 :, lor definitions of superscripts.

26
 1C1.6
TABLE 1C1.6—Alkylbenzenes, Naphthalene, ndans, and Tetrahydronaphthalene (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion Df the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid.0 Liquid, Pressure , Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10< (TW -nc)/d centistokes lb, dcg Fahr Heat of Air Mixture
Vaporiza-
A niline tion at
P oint, the
deg Normal Gross, to form H2O Net, to form H20 Motor Method Research Method No.
]Fahr Boiling (liquid)+COi (gas) (gas)-f-C02 (gas) D357 D908
Gas, Liquid Point, 1
at 68 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb gal TEL TEL
per gal per gal

189.9 189.6 0.5870 <;-22 0.2429 0.4098 169.31 17 991 132 670 17 258 127 270 1.3' 7.9' +2.8* 1
185.0 184.7 0.5584 0.341 <--22 0.2598 0.4012 154.84 18 251 132 670 17 422 126 640 1.2' 7.1' +0.3* +1.7* +5.8* 2

175.0 174.7 0.6428 0.390 <:-22 0.2795 0.4114 144.0 18 493 134 410 17 595 127 880 0.99' 6.7' 97.9 +0.2* +0.8* +0.8* 3
180.4 180.1 0.740 0.428 <-4 0.2914 0.4418 149.1 18 445 136 070 17 546 129 430 1.1' 6.4' 100.0 100.0 4
180.9 180.6 0.591 0.366 -22 0.2782 0.4045 147.2 18 441 133 560 17 543 127 060 1.1' 6.4' +2.8* +6.0* +4.0* +6.0* 5
182.4 182.1 0.613 0.372 -22 0.2769 0.4083 144- S2 18 445 133 130 17 547 126 650 1.1' 6.6' +1.2* +5.1* +3.4* >+6* 6

166.7 166.4 0.7944 0.455 < -22 0.2934 04199 136.8 18 674 134 900 17 721 128 030 (0.88) 98.7 +2.0* +1.5* +4.3* 7
165.7 165.4 0. 740 <+5 0.2917 (0.414) 134.3 18 665 134 800 17 711 127 908 0.88' 6.5' 99.3 +0.5* +2.1* +4.3* 8
172.4 172.1 0.3050 (0.416) 139.0 18 645 137 580 17 692 130 549 (0.88) 92.1 92.9 +0.2* +0.35* 9
173.4 173.1 0.2934 (0-416) 137.8 18 637 135 030 17 684 128 119 (0.88) 100 +1.8* 10
173.9 173.6 0. 671 0.2923 (0-416) 137.4 18 634 134J80 17 680 127 596 (0.88) 97.0 11
176.0 175.7 0.2986 0.4236 143.2 18 601 139*370 17 649 132 230 (0.88) +0.06* +0.05* +0.5* +0.5* 12
178.2 177.9 0.3007 0.4203 140.4 18 590 136 420 17 637 129 430 (0.88) +0.6*'' +0.6* +1.4* +1.5* 13
177.8 177.5 < -22 0.2903 0.3876 139.6 18 584 134 740 17 631 127 810 (0.88) +0.6* >+6* 14

189.6 159.3 0.947 0.518 < -22 0.3022 0.4261 125.7 18 818 135 650 17 822 128 470 0.8 ' 5.8 94.5' +0.1* +0.4* +1.5* 15
160.8 160.5 (0.297) (0-421) 121.2 (IS 822) 1S4 580 (17 826) 127 450 (0.8) 98.0 +0.3* +1.6* +3.0* 16
159.0 158.7 ([Link]) (0.421) 121.6 (18 82S) 185 980 (17 828) 128 790 (0.8) 95.7 +0.1* +0.7* +1.5* 17
159.3 159.0 (0.S09) 0.4170 120.5 (18 791) 136 440 (17 795) 129 210 (0.8) +0.8* >+3* 18
166 166 (0.421) 126.4 (0.8) 92.2 95.7 +0.3* +0.6* 19
166 166 (0.421) 126.0 (0.8) +0.04* +0.6* +1.8* +3.8* 20
166 166 (O.421) 125.4 (0.8) 21
166 166 (0.S07) (0.41S) 122.9 (18 793) 1S8 OSS (17 795) ISO 710 (0.8) 96.0 97.7 +0.6* +1.5* 22
166 166 (0.299) (0.41S) 122.1 (l8 785) 185 510 (17 784) 128 S00 (0.8) 23
166 166 (0.289) 0.4149 122.2 (18 785) 1$4 950 (17 787) 127 780 0.85 5.5 97.7 +1.4* 24
166.2 165.9 (0.419) 126.3 (0.8) 25
166.9 166.6 (0.419) 126.1 (0.8) 97.0 +0.2* >+3* >+3* 26
168.2 167.9 (0.419) 126.1 (0.8) 95.2' 99.3 +0.6* +1.6* 27
170 170 (0.420) 130.0 (0.8) 91.9 93.3 +0.4* +0.4* 28
171 171 (0.420) 127.1 (0.8) 29
170 170 (O.42O) 128.7 (0.8) 30
171 171 (O.420) 128.1 (0.8) 95.9 98.8' +0.6* +1.2* 31
172 172 (O.42O) 126.9 (0.8) +0.2* +0.8* +2.7* >+6.0* 32
171 171 (0.420) 127.1 (0.8) 96.0 98.9' +0.6* +0.9* 33
174 174 0.4184 144.2 (0.8) +0.02* 99.7 +0.5* +0.5* 34
174 174 0.4217 140.3 (0.8) +0.2* 35
174r 174r 145.8 (0.8) 36

(297)' 0.29?5mm 17 302""" 169 920""" 16 721""" 164 210""" 0.9 5.9 37

(0.9) 89.8 90.8 +0.3* +0.5* 38

(0.8) 39
(0.8) 40
(0.8) 41
(0.8) 42

166 166 C-4 ... •• • 0.84' 5.0" 81.9 84.0 96.4 100.0 43

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

27
 1C1.7

TABLE 1C1.7—Styrenes and Indenes (U.S. Units)

Density of the Refractive

Critical Constants Liquid*' «' b Index of the
at 60 F Coeffi- Liquid,0 no
Boiling Freezing API cient of
Point Vapor Point in Specific Grav- Expan-
at 1 Pres- Air at 1 Grav- ity*' ' sion** a
No. Compound atmos, sure at atmos, ity,". « at 60
deg 100 F, deg Tem- 60 F/ F, deg V\dT)P
Fahr psi Fahr Pres- pera- Vol- 60 F API at 60 F,
sure, ture, ume, lb per lb per per deg at 68 at 77
psi deg cu ft cu ft gal Fahr F F
Fahr per lb

Styrenes, C8H8, M.W. 104.152:

1 Ethenylbenzene (styrene; vinylbenzene; phenylethylene) 293.29 (0.2.4) -23.10 680 706.0 0.0541 0.9110 23.8 56.75 7.586 0.0O057 1.54682 1.54395

Styrenes. CsHio, M.W. 118.179:

2 Isopropenylbenzene (a-methylstyrene; 329.9 (0.10) -9.8 680 751 0.066S 0.9138 23.3 56.92 7.609 0.00057 1.5386 1.5358
2-Phenyl-l-propene)
3 cis-1-Propenylbenzene (ds-/3-methylstyrene; 333.43 (0.089) -78.97 526 760 0.055S 0.9138 23.3 56.92 7.609 0.00057 1.5430 1.5402
cis-1-Phenyl-l-propene)
4 transJ-Propenylbenzene (*r<ms-/3-methylstyrene; 352.92 -20.76 526 760 0.056S 0.9115 23.7 56.78 7.590 0.00057 1.5506 1.5478
(raras-1-Phenyl-l-propene)
5 l-Methyl-2-ethenylbenzene (o-methylstyrene) 337.71 (0.086) -91.37 529 76S 0.0609 0.9165 22.9 57.09 7.632 0.00052 1.5437 1.5413
6 l-Methyl-3-ethenylbenzene (m-methylstyrene) 340.9 (0.10) -123.36 516 756 0.0616 0.9164 22.9 57.08 7.630 0.00046 1.5411 1.5385
7 l-Methyl-4-ethenylbenzene (p-methylstyrene) 343.0 (0.095) -29.43 514 757 0.0516 0.9261 21.3 57.69 7.712 0.00052 1.5420 1.5395

Styrenes, C10H12, M.W. 132.206:

8 cis-1-Phenyl-l-butene (ci's-/3-ethylstyrene) 372 0.9153 23.0 57.01 7.621 0.00051 1.5390 1.5364
9 *rans-l-Phenyl-l-butene (*rans-/3-ethylstyrene) 389.70 -45.4 0.9065 24.5 56.46 7.548 0.00051 1.5420 1.5394
10 2-Phenyl-l-butene (a-ethylstyrene) 360 0.896 26.4 55.8 7.46 0.00056 1.5288 1.5262
11 cis-2-Phenyl-2-butene (cis-ot, /3-dimethy lstyrene) 382.5 -10.3 0.9223 21.9 57.45 7.680 0.00052 1.5425 1.5401
12 ircms-2-Phenyl-2-butene (£rans-a,/3-dimethyIstyrene) 345 0.9003 25.6 56.08 7.497 0.00051 1.5217 1.5193
13 2-Methyl-l-phenyl-l-propene (13,/3-dimethylstyrene) 370.31 -59.8 0.9056 24.7 56.41 7.541 0.00056 1.5400 1.5376
14 l-Methyl-2-(cis-l'-n-propenyl)benzene 0.907 24.5 56.5 7.55 0.00051 1.539 1.537
(cis-o, /3-dimethylstyrene)
15 l-Methyl-2-(£nms--l'-«-propenyl)benzene 0.907 24.5 56.5 7.55 0.00051 1.539 1.539
(trans-o, /3-dimethylstyrene)
16 l-Methyl-3-(cz's-l'-?i-propenyl)benzene 0.900 25.7 56.0 7.49 0.00056 1.540 1.538
(cis-m, jS-dimethylstyrene)
17 l-Methyl-3-(*rcms-l'-?i-propenyl)benzene 0.900 25.7 56.0 7.49 0.00056 1.540 1.538
(trans-m, /3-dimethylstyrene)
18 l-Methyl-4-(czs-l'-n-propenyl) benzene 385 0.8941 26.7 55.69 7.445 0.00056 1.5392 1.5368
(cis-p, jfi-dimethylstyrene)
19 l-MethyI-4-(irans-l'-n-propenyl)benzene 394 -150 0.9104 23.9 56; 71 7.581 0.00051 1.543 1.541
(trans-p, jS-dimethy lstyrene)
20 l-Methyl-2-isopropenylbenzene (0, a-dimethylstyrene) 342.0 0.8938 26.8 55.67 7.442 0.00050 1.5155 1.5130
21 l-Methyl-3-isopropenylbenzene (wi, a-dimethylstyrene) 365 0.9095 24.1 56.65 7.573 0.00051 1.5335 1.5310
22 l-Methyl-4-isopropenylbenzene (p, a-dimethylstyrene) 367 0.9044 24.9 56.33 7.530 0.00051 1.5340 1.5315
23 l-Ethyl-2-ethenylbenzene (o-ethylstyrene) 369.1 -103.9 0.9103 23.9 56.70 7.580 0.00051 1.5380 1.5356
24 l-EthyI-3-ethenylbenzene (»i-ethylstyrene) 374.0 -150 0.8990 25.8 56.00 7.486 0.00056 1.5351 1.5325
25 l-Ethyl-4-ethenylbenzene (p-ethylstyrene) 378.1 -57.5 0.8970 26.2 55.87 7.469 0.00056 1.5376 1.5348
26 l,2-DimethyI-3-ethenylbenzene (2,3-dimethylstyrene)
27 1,2-Dimethyl-4-ethenylbenzene (3,4-dimethylstyrene) 0.915 23.1 57.0 7.62 0.00051 1.5464 1.5438
28 l,3-Dimethyl-2-ethenylbenzene (2,6-dimethylstyrene) 0.910 24.0 56.6 7.57 0.00051 1.535 1.533
29 l,3-Dimethyl-4-ethenylbenzene (2,4-dimethylstyrene) 0.910 24.0 56.6 7.57 0.00051 1.5423 1.5397
30 l,3-Dimethyl-5-ethenylbenzene (3,5-dimethylstyrene) 0.903 25.1 56.2 7.51 0.00051 1.5382 1.5356
31 1,4-Dimethyl-2-ethenylbenzene (2,5-dimethylstyrene) 0.911 23.8 56.7 7.58 0.00057 1.540 1.538

32 Phenylacetylene, M.W. 102.136 287.06 (0.S4) -40 611.4 720 0.0526 (0.9SS) (20.2) (58.l) (7.77) 0.00048 1.5485

Alkylindenes, CgHs, M.W. 116.163:

33 Indene 360.45 +29.3 1.0006 9.9 62.33 8.332 0.00050 1.5764 1.5737

Alkylindenes, C10H10, M.W. 130.190:

34 1-Methylindene 390 0.977 13.3 60.8 8.13 0.00024 1.5616 1.5591
35 2-Methylindene 406 176 0.981r 12.7' 61.1' 8.17r 0.00037' 1.5652' 1.5627'
36 3-MethyIindene 401 0.979 13.0 61.0 8.15 0.00037 1.5621 1.5596
37 4-Methylindene 408 0.996 10.6 62.0 8.29 0.00043 1.568 1.566
38 5-Methylindene 405 0.984 12.3 61.3 8.19 0.00037 1.566 1.564
39 6-Methylindene 405 0.984 12.3 61.3 8.19 0.00037 1.566 1.564
40 7-Methylindene 408 ... 0.996 10.6 62.0 8.29 0.00043 1.568 1.566

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W = molecular weight.
3. See Appendix I, p. 61 ., for definitions of superscripts.

28
 1C1.7
TABLE 1C1.7—Styrenes and Indenes (U.S. Units)

Specific Disper- Kinematic Vis- Heat Capacity at Flammability

sion of the cosity of the 60 F and Constant Heat of Combustion of the Liquid Limits, Volume
Liquid,0 Liquid, Pressure, Btu per at 60 F and Constant Pressure* Percent in ASTM Octane Numbers
10' (nr-nc)/d centistokes lb, deg Fahr Heat of Air Mixture
Vaporiza-
Aniline tion at
Point, the
deg Normal Gross, to form HaO Net, to form HjO Motor Method Research Method No.
Fahr Boiling (liquid)+C02 (gas) (gas)+C02 (gas) D357 D908
Gas, Liquid Point, 1
at G8 at 77 at 100 at 210 Ideal at 1 atmos, Btu Lower Higher
F F F F State atmos per lb With With
Btu per Btu per Btu per Btu per Clear 3 ml Clear 3 ml
lb gal lb TEL TEL
per gal per gal

265 0.2711 0.4122 (Ml) 18 180 137 870 17 416 132 290 +0.2* +0.1" >+3* +2.5*

265 0.285 (140) (18 StS) (139 600) (17 615) (133 400) (0.9) +0.1" +2.1* +1.8*

265 0.285 ([Link]) (139) (18 384) (139 700) (17 676) (133 600) (0.9) 91.7 +0.5* +0.5*

265 0.287 (0.435) (18 S84) (139 700) (17 576) (lSS 600) (0.9) 92.1 91.4 +0.4* +0.4*

265 265 0.285 (0.4W) (18 S48) (140 200) (17 541) (134 000) (0.9)
265 265 0.285 (.0.416) (1S7) (18 S4S) (HO 100) (17 535) (134 000) (0.9)
265 265 0.285 (0.416) (138) (18 339) (141 600) (17 531) (135 400) (0.9)

(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
Co.s) 91.7 +0.5*
(0.8)

(0.8)

(0.8)

(0.8)

(0.8)

(0.8)

(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
(0.8)
(0.8)

(0.36) (0.5 (161)

+0.7* +0.4* +2.3* +1.4*

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

29
 1C1.8
TABLE 1C1.8—Gaseous Hydrocarbons, d to C6 (U.S. Units)

Heat of Combustion Air Required for

Compressibility Specific Volume* of the Real Gas* at Combustion of the
Factor of the Gas, Specific of the Gas at 60 F Heat 60 F and Constant Real Gas •at60F
Z = PV/RT Gravity* and 1 atmos Capacity Pressure, Btu and 1 atmos
of Real of the Gas » per cu ft
Gas, at at Constant
No. Compound 60 F and Pressure
1 atmos, at60F
Referred to and 1 Gross,
Under At 60 F Air as cu ft gas atmos, to form Net, to cu ft air
critical and 1 Unity cu ft gas per gal Btu per lb, H20 form H2O per cu lb air
condi- .atmos, Z per lb gas liquid deg Fahr (liquid) (gas) + ft gas per lb gas
tions, Zp + CO* CO* (gas)
(gas)

Paraffins, Ci to d:
1C1.1 1 Methane, CH(, M.W. 16.043 0.288 0.9981 0.55469 23.6107 0.5266 1011.5 910.73 9.561 17.235
2 Ethane, C2He, M.W. 30.070 0.284 0.9916 1.0465 12.5148 39.47* 0.4097 1783.5 1631.4 16.841 16.092
3 Propane, CaHs, M.W. 44.097 0.281 0.9820 1.5496 8.4513 35.744"* 0.3881 2563.1 2358.0 24.294 15.676

Paraffins, [Link], M.W. 58.124:

4 ft-Butane 0.274 0.9667 2.0749 6.3119 30.766'' 6.3867 3373.7 3113.8 32.082 15.461
5 2-Methylpropane (isobutane) 0.283 0.9696 2.0687 6.3308 29.725'' [Link] 3354.1 3094.6 31.986 15.461

Paraffins, CsHu, M.W. 72.151:

6 n-Pentane 0.262 0.9549° 2.6073" 5.3795" 28.298" 0.4057" 3913.8" 3624.3" 39.971" 15.329
7 2-Methylbutane (isopentane) 0.273 0.9544" 2.6091s 5.2338" 27.259" 0.3948" 4015.8" 3715.9" 39.998" 15.329
8 2,2-DimethyIpropane (neopentane) 0.269 0.9510 2.6181 5.0022 24.882'' (0.8866) 4188.9 3871.8 40.137 15.329

Cycloalkanes, Cs to C&:
1C1.2 1 Cyclopropane, M.W. 42.081 0.28 0.982S 1.4783 8.8589 41.631'' ([Link]) 2413.2 2259.5 21.858 14.784
15 Cyclobutane, M.W. 56.108 0.28 {p.97) 1.20 6.56 38.3d (0.297) 3207 2999 29.5 14.784
23 Cyclopentane, M.W. 70.135 0.276 0.9867° 2.5070s 5.8355" 36.507" 0.3116" 3450.7" 3224.8 37.067" 14.784

Monoolefins, C: and C«:

1C1.3 1 Ethene, CjH), M.W. 28.054 0.276 0.99S8 0.9742 13.4440 0.3624 1609.4 1508.2 14.403 14.784
2 Propene, CsHe, M.W. 42.081 0.275 0.98U 1.4752 8.8779 38.640'' 0.3541 2370.3 2216.9 21.811 14.784

Monoolefins, C,H8, M.W. 56.108:

3 1-Buteixe 0.277 0.9704 1.9953 6.5637 32.906'' 0.3551 3174.1 2966.7 29.501 14.784
4 c*s-2-Butene 0.271 0.9661 2.0042 6.5347 34.165'' 0.3269 3180.2 2971.9 29.632 14.784
5 Zrans-2-Butene 0.274 0.9662 2.0040 6.5353 33.233'' 0.3654 3174.8 2966.5 29.629 14.784
6 2-Methylpropene 0.275 0.9889 1.9984 6.5536 32.802'' 0.3701 3159.4 2951.7 29.546 14.784

Monoolefins, CsHw, M.W. 70.135:

7 1-Pentene 0.32 0.9560' 2.5345" 5.4256" 29.207" 0.3782" 3812.4" 3566.8" 37.479" 14.784
8 cis-2-Pentene 0.28 (0.969)° 2.524" 5.574" 30.71" 0.3590" 3703" 3463" 37.32" 14.784
9 trans-2-Pentene 0.28 (0.959)o 2.524" 5.563' 30.30" 0.3803" 3705" 3465" 37.31" 14.784
10 2-Methyl-l-butene 0.28 0.9561s 2.5344" 5.4474" 29.782" 0.3866" 3780.0" 3533.8" 37.472" 14.784
11 3-Methyl-l-butene 0.28 (0.968)' 2.526" 5.264" 27.76" 0.3986" 3923" 3665" 37.35" 14.784
12 2-Methyl-2-butene 0.28 0.9564" 2.5338" 5.5818" 31.070" 0.3710" 3680.1" 3441.5" 37.463" 14.784

Dioleflns, C3H,, M.W. 40.065:

163 Propadiene (allene) 0.9818 1.4068 9.3095 50.990'' 0.3439 2242 2140 19.419 13.803

Dioleflns, C<Hs, M.W. 54.092:

164 1,2-Butadiene (0.969) 1.926 6.799 37.3d 0.3458 3033 2878 27.08 14.057
165 1,3-Butadiene 0.270 (0.966) 1.934 6.770 35.40'' 0.3412 2985 2829 27.19 14.057

Dioleflns, CsHs, M.W. 68.119:

166 1,2-Pentadiene (0.96S)° 2.442" 5.910" 34.37" 0.389" 3468" 3284" 34.68" 14.207
167 1, cis-3-Pentadiene (o.96S)« 2.442" 5.895" 34.22" 0.351" 3415" 3230" 34.68" 14.207
168 1, trans-3- Pentadiene (0.962)° 2.444" 5.851" 33.23" 0.380" 3434" 3247" 34.72" 14.207
169 1,4-Pentadiene (0.966)° 2.459" 5.518" 30.63" 0.370" 3677" 3478" 34.93" 14.207
170 2,3-Pentadiene (0.96S)° 2.442" 5.973" 34.87" 0.375" 3423" 3241" 34.68" 14.207
171 3-Methyl-l ,2-butadiene (0.96S)° 2.442" 5.835" 33.64" 0.384" 3502" 3314" 34.68" 14.207
172 2-Methyl-l,3-butadiene (isoprene) (0.962)° 2.444" 5.703" 32.62" 0.377" 3525" 3331" 34.72" 14.207

Cyclooleflns: M.W. 68.119

1C1.4 1 Cyclopentene C5H8, (0.964)° 2.439" 5.904" 38.28" 0.2833" 3356" 3171" 34.65 14.207

Acetylenes, C2 and Cs:

1C1.5 1 Ethyne (acetylene), CiH2, M.W. 26.038 0.271 0.9926 0.9053 14.466 0.3966 1483.7 1433.0 12.019 13.274
2 Propyne (methylacetylene), CiH^ M.W. 40.065 0.276 0.98S6 1.4058 9.3161 48.930'' 0.3545 2232.8 2130.5 19.405 13.803

Acetylenes, C(H6, M.W. 54.092:

3 1-Butyne 0.9660 1.9344 6.7705 37.1"* 0.3513 3049 2893 27.194 14.057
4 2-Butyne (0.966)° 1.9346" 7.039" 40.87" 0.3455" 2910" 2761" 27.19" 14.057

Acetylenes, CsHs, M.W. 68.119:

5 1-Pentyne (0.959)° 2.452" 6.798" 33.61" 0.387" 3541" 3352" 34.83" 14.207
6 2-Pentyne (0.964)" 2.440" 6.124" 36.55" 0.371" 3333" 3157" 34.66" 14.207
7 3-Methyl-l-butyne (0.96l)° 2.472" 5.496" 30.8" 0.368" 3729" 3527" 35.12" 14.207

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.
30
31
1C1.9
TABLE 1C1.9—Paraffins (Metric Units)

Refractive _ Specific Kinematic

Density of the Liquid," Index of1 the Dispersion of Viscosity^ of
it g per ou cm Liquid," %D the Liquid," the Liquid,
dp 10<(n* —nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, Point of the Aniline
No. Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20 C 25 C 20 C 25 C 20 C 25 C C C per cm

Paraffins, Ci to Cs:
1 Methane, CH«, M.W. 16.043 -161.495 0.0160 -182.48" 0.26>
2 Ethane, CiH6, M.W. 30.070 -88.60 0.0244 -183.27* 0.8580 0.SS99 0.8185
3 Propane, CsHs, M.W. 44.097 -42.045 0.0298 -187.69" 0.5076"* 0.5005d 0.4928"*

Paraffins, CiHio, M.W. 58.124:

4 n-Butane -0.50 0.0347 -138.362 0.5847"* 0.5788"* 0.5730"* 1.3326"* 1.3292"* 83.1
5 2-Methylpropane (isobutane) -11.72 0.0337 -159.605 0.5633d 0.5572"* 0.5510"* 107.6

Paraffins, CsHi2, M.W. 72.151:

6 n-Pentane +36.064 0.03856 -129.730 0.63087 0.62622 0.62137 1.35748 1.35472 98.1 98.0 0.330"* 15.48 70.7
7 2-Methylbutane (isopentane) 27.843 0.03815 -159.905 0.62463 0.61965 0.61460 1.35373 1.35088 98.7 98.6 14.46 77.0
8 2,2-Dimethylpropane (neopentane) 9.499 0.0361 -16.57 0.5967"* 0.5910"* 0.5851"* 1.342"* 1.339"* 98"* 98"* 102*

Paraffins, CnHu, M.W. 86 178:

9 n-Hexane 68.732 0.04191 -95.322 0.66382 0.65935 0.65479 1.37486 1.37226 98.1 98.0 0.4137 17.90 68.6
10 2-Methylpentane 60.261 0.04141 -153.681 0.65774 0.65313 0.65840 1.37145 1.36873 98.7 98.6 16.87 73.8
11 3-Methylpentane 63.272 0.04182 0.66878 0.66429 0.65974 1.37652 1.37386 97.2 97.1 17.60 69.3*
12 2,2-Dimethylbutane 49.731 0.04117 -99.843 0.65390 0.64914 0.64444 1.36876 1.36595 99.9 99.8 15.81 81.2*
13 2,3-Dimethylbutane 57.978 0.04173 -128.543 0.66622 0.66162 0.65700 1.37495 1.37231 98.4 98.3 16.87 71.9*

Paraffins, CjHis, M.W. 100.205:

14 n-Heptane 0.04479 -90.581 0.68799 0.68374 0.67949 1.38764 1.38511 97.8 97.7 0.5214 0.3425"1 19.80 69.7
15 2-Methylhexane 90.049 0.04431 -118.271 0.68285 0.67857 0.67437 1.38485 1.38227 98.4 98.5 18.80 74.0
16 3-Methylhexane 91.847 0.04459 0.69150 0.68711 0.68293 1.38864 1.38609 97.5 97.4 19.30 70.5
17 3-Ethylpentane 93.473 0.04482 -118.599 0.70258 0.69814 0.69393 1.39339 1.39084 95.7 95.7 19.94 65.7
18 2,2-Dimethylpentane 79.191 0.04394 -123.811 0.67805 0.67383 0.66951 1.38215 1.37955 99.4 99.3 17.55 77.6
19 2,3-Dimethylpentane 89.781 0.04482 0.69938 0.69506 0.69089 1.39196 1.38945 96.4 96.2 19.47 67.6
20 2,4-Dimethylpentane 80.494 0.04376 -119.238 0.67710 0.67268 0.66830 1.38145 1.37882 98.7 98.6 17.66 78.8
21 3,3-Dimethylpentane 86.060 0.04509 -134.45 0.69741 0.69325 0.68906 1.39092 1.38842 97.4 97.1 19.10 70.5
22 2,2,3-Trimethylbutane 80.876 0.04484 -24.897 0.69440 0.69009 0.68586 1.38944 1.38692 98.7 98.3 18.26 72.2

Paraffins. CsHis, M.W. 114.232:

23 n-Octane 125.675 0.04738 -56.764 0.70652 0.70250 0.69847 1.39743 1.39505 98.1 98.0 0.6476 0.4039 21.26 70.6
24 2-Methylheptane 117.653 0.04691 -108.993 0.70188 0.69790 0.69390 1.39494 1.39257 98.6 98.5 20.14 74*
25 3-Methylheptane 118.932 0.04712 -120.547 0.70989 0.70580 0.70173 1.39848 1.39610 97.6 97.5 20.70 72.2*
26 4-Methylheptane 117.715 0.04695 -120.953 0.70880 0.70461 0.70053 1.39792 1.39553 97.6 97.5 20.54 71.6*
27 3-Ethylhexane 118.541 0.04719 0.71759 0.71356 0.70946 1.40162 1.39919 96.5 96.4 21.04 68.7*
28 2,2- Dimethylhexane 106.842 0.04650 -121.18 0.69949 0.69526 0.69110 1.39349 1.39104 99.8 99.7 19.14 78*
29 2,3-Dimethylhexane 115.612 0.04724 0.71631 0.71212 0.70807 1.40113 1.39880 97.1 97.0 20.53 70.6*
30 2,4-Dimethylhexane 109.432 0.04664 0.70447 0.70034 0.69618 1.39534 1.39291 97.9 97.8 19.59 73.4*
31 2,5-Dimethylhexane 109.106 0.04646 -91.148 0.69773 0.69352 0.68932 1.39246 1.39004 99.1 99.0 19.28 78.0*
32 3,3-Dimethylhexane 111.973 0.04741 -126.10 0.71407 0.70998 0.70594 1.40009 1.39782 97.4 97.3 20.18 72*
33 3,4-Dimethylhexane 117.731 0.04752 0.72336 0.71921 0.71514 1.40406 1.40180 96.7 96.6 21.18 68.0*
34 2-Methyl-3-ethylpentane 115.655 0.04748 -114.952 0.72336 0.71930 0.71520 1.40401 1.40167 96.2 96.1 21.05 67.2*
35 3-Methyl-3-ethylpentane 118.266 0.04844 -90.842 0.73119 0.72740 0.72352 1.40775 1.40549 95.9 95.8 21.53 65.9*
36 2,2,3-Trimethylpentane 109.845 0.04755 -112.26 0.71999 0.71600 0.71205 1.40295 1.40066 97.3 97.2 20.22 70.8*
37 2,2,4-Trimetbylpentane 99.238 0.04651 -107.373 0.69597 0.69191 0.68779 1.39145 1.38898 100.6 100.5 18.32 79.5*
38 2,3,3-Trimethylpentane 114.765 0.04833 -100.934 0.73005 0.72617 0.72230 1.40750 1.40522 96.2 96.1 21.10 67.0*
39 2,3,4-Trimethylpentane 113.472 0.04761 -109.197 0.72304 0.71904 0.71501 1.40422 1.40198 97.0 96.9 20.68 68.3*
40 2,2,3,3-Tetramethylbutane 106.47 0.0476 +100.69 ...

NOTES:
1. Values in. parentheses are estimated. For methods of estimation, see p.' 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

32
 1C1.9

TABLE 1C1.9—Paraffins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure0
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HJO (liquid) + H20(gas) +
Pres- pera- ume, (1 atmos) COi (gas) COi (gas)
sure, ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
deg- deg- g. deg per cal per per cal per mole cal per g mole cal per g
g. deg
mole Cent mole Cent mole g mole g

45.44 -82.57 0.099 8.634 0.6320 1.955 121.87 -17.889 -12.144 0

1
48.16 +32.27 0.148 12.58 0.4184 36.10 1.2006 1.200 39.91 3.517 116.97 -20.236 -22.500'' -7.860 370.56*° 12 324"* 339.001' 11 274<! 2
41.94 96.67 0.203 17.57 0.3985 26.56 0.6023 3.605 81.76 4.487 101.76 -24.820 -28.789'* -5.614 526.63*° 11 943d 484.5&d 10 989<i 3

37.47 152.03 0.255 28.03 0.3963 33.41 0.5748 5.035 86.63 5.352 92.09 -30.15 -35.34d -4.08 682.45*° 11 742* 629.86° 10 837* 4
36.00 134.99 0.263 23.14 0.3981 33.85 0.5824 4.570 78.63 5.090 87.58 -32.15 -36. »5d -5.00 680.84*° 11 714* 628.25° 10 810"* 5

33.25 196.5 0.304 28.73 0.3982 89.99 0.5548 6.316 87.54 6.160 85.38 -35.00 -41.40 -2.00 -2.30 838.77° 11 626 775.66 10 751 6
33.37 187.28 0.306 28.39 0.3935 39.406 0.54620 5.937 82.29 5.901 81.79 -36.92 -42.95 -3.50 -3.60 837.21° 11 604 774.10 10 730 7
31.57 160.63 0.303 28.71 0.3976 40.8 0.566 6.228 72.S9 5.438 75.37 -40.26 -45.61d -4.06 884.64d- ° 11 566d 771.42* 10 692d 8

29.73 234.3 0.370 34.20 0.3969 46.72 0.5422 7.541 87.51 6.896 80.03 -39.94 -47.52 -0.05 -1.03 995.01 11 547 921.37 10 692 9
29.71 224.35 0.367 34.26 0.3976 46.212 0.53628 7.138 82.83 6.643 77.09 -41.66 -48.82 -1.19 -1.97 993.71 11 532 920.07 10 677 10
30.83 231.3 0.367 33.11 0.8919 45.3 0.526 7.236 83.97 6.711 77.88 -41.01 -48.28 -0.66 -1.34 994.25 11 538 920.61 10 683 11
30.40 215.63 0.359 S3.7 8 0.3920 45.42 0.5271 6.618 76.80 6.287 72.96 -44.32 -51.00 -2.26 -2.90 991.52 11 506 917.88 10 652 12
30.86 226.83 0.358 33.59 0.3898 45.11 0.5235 6.961 80.78 6.519 75.65 -42.47 -49.48 -0.96 -1.69 993.05 11 524 919.41 10 670 13

27.00 267.1 0.432 39.76 0.8968 58.76 0.5866 8.736 87.19 7.576 75.61 -44.88 -53.63 1.93 0.26 1151.27 11 490 1067.11 10 650 14
26.98 257.22 0.421 (89.6) (0.895) 68.28 0.5317 8.319 83.03 7.330 73.16 -46.59 -54.93 0.81 -0.67 1149.97 11 477 1065.81 10 637 15
27.77 262.10 0.404 (39.6) (0.895) 52.3 0.522 8.386 83.69 7.359 73.44 -45.94 -54.35 1.12 -0.39 1150.55 11 483 1066.39 10 643 16
28.53 267.49 0.416 (39.6) (0.896) 62.48 0.6237 8.420 84.04 7.399 73.84 -45.33 -53.77 2.61 1.12 1151.13 11 489 1066.97 10 649 17
27.37 247.35 0.416 Uo.i) (0.400) 62.85 0.5274 7.752 77.37 6.970 69.56 -49.27 -57.05 -3.03 -1.15 1147.85 11 456 1063.69 10 616 18
28.70 264.20 0.393 39.67 0.3959 52 0.52 8.185 81.69 7.263 72.49 -47.60 -55.81 0.18 -1.27 1149.09 11 468 1064.93 10 628 19
27.01 246.64 0.418 (89.3) (0.893) 63.69 0.6848 7.8'61 78.45 7.051 70.37 -48.28 -56.17 0.79 -0.47 1148.73 11 465 1064.57 10 625 20
29.07 263.25 0.414 (40.1) (0.400) 51.4 0.513 7.893 78.77 7.086 70.72 -48.15 -56.07 0.65 -0.69 1148.83 11 466 1064.67 10 626 21
29.15 258.02 0.398 89.04 0.8896 61.03 0.6093 7.658 76.43 6.919 69.05 -48.94 -56.63 1.03 -0.16 1148.27 11 460 1064.11 10 620 22

24.54 295.68 0.492 45.32 (0.8968)

60.73 0.5817 9.916 86.81 8.225 72.01 -49.82 -59.74 3.91 1.54 1307.53 11 447 1212.85 10 618 23
24.52 286.49 0.488 (46.1) (0.895)60.13 0.5264 9.484 83.03 8.08 70.7 -51.49 -60.98 2.83 0.92 1306.28 11 436 1211.60 10 607 24
25.13 290.52 0.464 (44-6) (0.89) 59.67 0.5223 9.521 83.35 8.10 70.9 -50.82 -60.34 3.29 1.12 1306.92 11 442 1212.24 10 613 25
25.09 288.59 0.476 (44-5) (0.39) 60.01 0.5254 9.483 83.02 8.101 70.92 -50.88 -60.17 4.01 1.86 1307.09 11 443 1212.41 10 614 26
25.74 292.34 0.455 44-98 0.393858.0 0.51 9.476 82.96 8.033 70.33 -50.40 -59.88 4.03 1.80 1307.39 11 446 1212.71 10 617 27
24.96 276.72 0.478 (46) (O.46) 59.2 0.518 8.913 78.03 7.71 67.5 -53.71 -62.63 2.56 0.72 1304.64 11 422 1209.96 10 593 28
25.94 290.34 0.468 44-84 0.3926 59.0 0.52 9.272 81.17 7.936 69.48 -51.12 -60.40 3.59 2.17 1306.86 11 441 1212.18 10 612 29
25.23 280.37 0.472 (*») (0.38) 60.0 0.53 9.027 79.03 7.79 68.2 -52.44 -61.47 2.80 0.89 1305.80 11 432 1211.12 10 603 30
24.54 276.91 0.482 (43) (0.88) 59.56 0.5214 9.049 79.22 7.80 68.3 -53.21 -62.26 2.50 0.59 1305.00 11 425 1210.32 10 596 31
26.19 288.87 0.443 (44-5) (0.89) 58.94 0.5160 8.972 78.55 7.76 68.0 -52.61 -61.58 3.17 1.23 1305.68 11 431 1211.00 10 602 32
26.57 295.70 0.466 44-49 0.8896 58.0 0.51 9.316 81.56 7.953 69.63 -50.91 -60.23 3.68 2.03 1307.04 11 443 1212.36 10 614 33
26.65 293.94 0.443 44.63 0.3898 58.0 0.51 9.208 80.61 7.879 68.98 -50.48 -59.69 4.49 3.03 1307.58 11 448 1212.90 10 619 34
27.71 303.43 0.455 (44-89) (0.3886) 57.0 0.50 9.081 79.50 7.838 68.62 -51.38 -60.46 4.18 2.69 1306.80 11 441 1212.12 10 612 35
26.94 290.35 0.436 (49) (0.40) 58.0 0.51 8.824 77.25 7.65 67.0 -52.61 -61.44 4.09 2.22 1305.83 11 432 1211.15 10 603 36
25.34 270.81 0.468 44.24 0.3873 57.02 0.4992 8.397 73.51 7.411 64.88 -53.57 -61.97 3.42 1.65 1305.29 11 428 1210.61 10 599 37
27.83 300.41 0.455 (44-6) (0.89) 58.69 0.5138 8.896 77.88 7.73 67.7 -51.73 -60.63 4.52 2.54 1306.64 11 439 1211.96 10 610 38
26.94 293.26 0.461 46.6$ 0.3985 59.39 0.5199 9.013 78.91 7.684 67.27 -51.96 -60.98 4.49 2.54 1306.28 11 436 1211.60 10 607 39
28.3 294.8 0.461 46.03 0.4030 ... 10.24/ 89.6' 7.51 65.7 -53.99 -64.23 5.35 3.13 ... ... 40

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

33
 1C1.9

TABLE 1C1.9—Paraffins (Metric Units)

Refractive Specific Kinematic

Density of the Liquid," Index of the Dispersion of Viscosity of
g per cu cm Liquid,0 nj> the Liquid," the Liquid,
dp 10* (np-nc)/d centistokes Surface
at 1 Freezing Tensior
Boiling atmos, . Point of the Aniline
No. Compound Point at deg in Air at Liquid0 Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent
mm at at
at at c, Cent
at at at at at 37.78 98.89 dynes
Hg 15 C 20C 25 C 20C 25 C 20C 25 C C C per cm

Paraffins, CSHM, M.W. 128.259:

41 n-Nonane 150.818 0.04967 -53.489 0.72144 0.71761 0.71379 1.40542 1.40311 97.4 97.2 0.8087 0.4766 22.44 73.7
42 2-Methyloctane 143.28 0.0480 -80.37 0.7173 0.7134 0.7095 1.4031 1.4008 98.5 98.4 21.41 77.5*
43 3-Methyloctane 144.23 0.049 -107.6 0.7242 0.7205 0.7168 1.4063 1.4040 97.6 97.5 21.87 75.0*
44 4-Methyloctane 142.44 0.0492 -113.2 0.7242 0.7202 0.7163 1.4062 1.4039 97.6 97.5 21.87 74.5*
45 3-Ethylheptane 143.0 0.050 0.7306 0.7265 0.7225 1.4093 1.4070 96.7 96.6 22.34 73''
46 4-Ethylheptane 141.2 0.050 0.7322 0.7281 0.7241 1.4096 1.4073 96.7 96.6 22.34 68*
47 2,2-Di methylheptane 132.70 0.049 -112.99 0.7144 0.7105 0.7066 1.4016 1.3993 99.6 99.5 20.34 79*
48 2,3-Dimethy Iheptane 140.5 0.050 0.7299 0.7260 0.7221 1.4085 1.4062 97.3 97.2 21.87 73.2*
49 2,4-Dimethylheptane 132.90 0.049 0.7192 0.7153 0.7115 1.4034 1.4011 97.9 97.8, 20.84 78*
50 2,5-Dimethylheptane 136.0 0.049 0.7208 0.7167 0.7127 1.4038 1.4015 97.9 97.8 20.84 78*
51 2,6-Dimethylheptane 135.22 0.049 -102.9 0.7130 0.7089 0.7049 1.4007 1.3983 99.0 98.9 20.38 80.0*
52 3,3-Dimethylheptane 137.02 0.0489 0.7296 0.7256 0.7216 1.4088 1.4063 97.5 97.4 21.55 74*
53 3,4-Dimethylheptane 140.6 0.050 0.7353 0.7314 0.7275 1.4111 1.4089 96.9 96.8 22.34 70*
54 3,5-DimethyIheptane 136.0 0.049 0.7262 0.7225 0.7186 1.4067 1.4044 97.0 96.9 21.31
58 4,4-Dimethylheptane 135.2 0.049 0.7296 0.7256 0.7216 1.4076 1.4053 97.5 97.4 21.55
56 2-Methyl-3-ethylhexane 138.0 0.050 0.7375 0.7335 0.7295 1.4120 1.4097 96.7 96.6 22.34
57 2-Methyl-4-ethylhexane 133.8 0.049 0.7276 0.7235 0.7195 1.4068 1.4046 97.0 96.9 21.31
58 3-Methyl-3-ethylhexane 140.6 0.050 0.7451 0.7411 0.7371 1.4140 1.4120 96.0 95.9 22.76
59 3-Methyl-4-ethylhexane 140.4 0.051 0.7437 0.7400 0.7363 1.4149 1.4128 95.6 95.5 22.80
60 2,2,3-Trimethylhexane 133.61 0.049 0.7333 0.7295 0.7257 1.4105 1.4082 97.4 97.3 21.41 72*
61 2,2,4-Trimethylhexane 126.55 0.0491 -120.0 0.7193 0.7156 0.7118 1.4033 1.4010 98.9 98.8 20.09 78*
62 2,2,5-Trimethylhexane 124.093 0.04838 -105.763 0.71923 0.70719 0.70320 1.39972 1.39728 98.8 99.0 19.60 82.7
63 2,3,3-Trimethylhexane 137.69 0.049 -116.794 0.7414 0.7375 0.7345 1.4141 1.4119 96.4 96.3 21.95
64 2,3,4-Trimethylhexane 139.06 0.050 0.7430 0.7392 0.7354 1.4144 1.4120 96.5 96.4 22.34
65 2,3,5-Tri methy lhexane 131.35 0.0492 -127.8 0.7260 0.7219 0.7179 1.4061 1.4037 97.9 97.8 20.82 76
66 2,4,4-Triraethylhexane 130.660 0.04960 -113.370 0.72747 0.72379 0.72005 1.40745 1.40515 98.2 98.2 20.75
67 3,3,4-Trimethylhexane 140.48 0.049 -101.18 0.7495 0.7454 0.7414 1.4178 1.4154 95.4 95.3 22.79
68 3,3-Diethylpentane 146.186 0.05153 -33.090 0.75711 0.75357 0.74998 1.42051 1.41837 94.6 94.3 23.29 65*
69 2,2-Dimethyl-3-ethylpentane 133.84 0.051 -99.468 0.7385 0.7348 0.7310 1.4123 1.4102 96.4 96.3 21.92
70 2,3-Dimethyl-3-ethylpentane 144.7 0.050 0.7588 0.7548 0.7508 1.4221 1.4197 94.7 94.6 23.40 66*
71 2,4-Dimethyl-3-ethylpentane 136.70 0.0504 -122.36 0.7418 0.7379 0.7341 1.4137 1.4115 96.5 96.4 22.34
72 2,2,3,3-Tetramethylpentane 140.292 0.05124 -9.89 0.76031 0.75664 0.75297 1.42360 1.42140 96.1 95.9 22.93 68*
73 2,2,3,4-Tetramethylpentane 133.029 0.05030 -121.09 0.74271 0.73893 0.73522 1.41472 1.41246 96.8 96.8 21.54
74 2,2,4,4-Tetramethylpentane 122.292 0.04932 -66.20 0.72331 0.71946 0.71561 1.40694 1.40459 100.8 101.0 19.92 75*
75 2,3,3,4-Tetramethylpentane 141.567 0.04223 -102.103 0.75842 0.75471 0.75111 1.42222 1,42003 95.5 95.5 22.88

Paraffins, C10H22. M.W. 142.286:

76 n-Decane 174.154 0.05172 -29.643 0.73388 0.73003 0.72623 1.41189 1.40967 98.1 98.0 1.004 0.5591 23.37 77.0
77 2-Methylnonane 167.03 0.051 -74.62 0.7304 0.7264 0.7225 1.4100 1.4075 99.0 99.0 80.3*
78 3-Methylnonane 167.8 0.051 -84.77 0.7373 0.7334 0.7296 1.4125 1.4103 98.0 98.0 78.25*
79 4-Methylnonane 165.7 0.051 -98.7 0.7362 0.7322 0.7283 1.4118 1.4095 98.0 98.0 78.3*
80 5-Methylnonane 165.1 0.051 -87.67 0.7365 0.7326 0.7288 1.4122 1.4100 98.0 98.0 77.9*
81 3-Ethylootane 166.5 0.052 0.7438 0.7399 0.7359 1.4156 1.4136 96.0 96.0 75*
82 4-Ethyloctane 163.67 0.052 0.7419 0.7381 0.7343 1.4151 1.4131 96.0 96.0
83 2,2-Dimethyloetane 156.9 0.051 0.7281 0.7245 0.72O8 1.4082 1.4060 100.0 100.0 81
84 2,3-Dimethy loctane 164.34 0.051 0.7418 0.7379 0.7341 1.4149 1.4127 97.0 97.0 75*
85 2,4-Dimethyloctane 155.9 0.051 0.7302 3.7264 3.7226 1.4091 1.4069 98.0 98.0 80*
86 2,5-Dimethylootane 158.5 0.051 0.7341 5.7302 3.7264 1.4112 1.4089 99.0 99.0 77*
87 2,6-Dimethyloctane 160.41 0.0521 0.7317 0.7276 3.7236 1.4106 1.4084 99.0 99.0 78*
88 2,7-Dimethyloctane 159.89 0.051 -54.0 0.7282 3.7242 3.7202 1.4086 1.4062 98.7 98.6 79.0
89 3,3-Dimethyloctane 161.2 0.052 0.7429 3.7390 3.7351 1.4165 1.4142 97.0 97.0 75*
90 3,4-Dimethyloctane 163.4 0.052 0.7487 3.7448 3.7410 1.4182 1.4159 97.0 97.0 73*
91 3,5-Dimethyloctane 159.4 0.051 0.7405 3.7367 3.7329 1.4139 .4115 97.0 97.0
92 3,6-Dimethyloctane 160.8 0.051 0.7402 3.7363 3.7324 .4139 .1115 97.0 97.0 76*
93 4,4-Dimethyloctane 157.5 0.052 0.7382 3.7347 1.7312 .4144 .4122 97.0 97.0
94 4,5-Dimethyloctane 162.15 0.052 0.7607 3.7470 (1.7432 1.4190 1.4167 95.9 95.8 74*

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p* 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 .', for definitions of superscripts.

34
 1C1.9
TABLE 1C1.9—Paraffins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure*
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No,

Tem- Vol- Ideal State 1 atmos at25C Boiling Point H2O (liquid) + HiO (gas) +
Pres- pera- ume, (1 atmos) CO* (gas) COi (gas)
sure, ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
deg- g, deg deg- g. deg per cal per per cal per mole cal per g mole cal per g
mole Cent mole Cent mole g mole g

22.6 321.49 0.548 50.60 0.3945 67.97 0.5300 11.100 86.55 8.823 68.80 -54.56 -65.67 6.11 3.02 1468.95 11 414 1368.76 10 694 41
22.6 313.6 0.541 («) (0-40) 67.6 0.527 10.73 83.66 8.76 68.3 -56.34 -67.07 1462.54 11 403 1357.35 10 583 42
23.1 317.0 0.529 to) (040) 66.7 0.520 10.72 83.59 8.79 68.5 -55.84 -60.56 1463.05 11 407 1357.86 10 587 43
23.1 314.5 0.523 to) (040) 67 0.52 10.63 82.88 8.75 68.2 -55.84 -66.47 1463.14 11 408 1357.95 10 588 44
23.7 317.4 0.511 (») (0.39) 66 0.51 10.63 82.88 8.78 68.5 -55.36 -65.95 1463.66 11 418 1358.47 10 592 45
23.6 314.8 0.505 66 0.51 10.71 83.5 8.76 68.3 -55.36 -65.86 1463.75 11 412 1358.56 10 592 46
22.9 304.6 0.526 (62.6) (0-41) 66.2 0.516 10.11 78.83 8.31 64.8 -58.76 -68.87 1460.74 11 889 1855.55 10 669 47
23.7 316.5 0.515 66 0.51 10.42 81.25 8.63 67.3 -55.64 -66.95 1462.66 11 404 1357.47 10 584 48
23.1 303.7 0.517 67 0.52 10.26 80.00 8.45 65.9 -57.46 -67.73 1461.88 11 398 1356.69 10 578 49
23.2 308.0 0.522 67 0.52 10.34 80.62 8.51 66.4 -57.46 -67.82 1461.79 11 397 1356.60 10 577 50
22.7 304.8 0.535 (SO) (0.39) 68 0.53 10.35 80.70 8.49 66.2 -57.94 -68.33 1461.28 11 393 1356.09 10 573 51
24.0 315.4 0.506 65.8 0.513 10.18 79.38 8.44 65.8 -57.62 -67.80 1461.81 11 397 1356.62 10 577 52
24.3 318.8 0.503 65 0.51 10.42 81.25 8.69 67.8 -56.06 -66.43 1463.18 11 408 1357.99 10 588 53
23.7 310.1 0.510 66 0.52 10.34 80.62 8.52 66.4 -56.98 -67.30 1462.31 11 401 1357.12 10 581 54
24.0 312.3 0.501 66 0.51 10.09 78.67 8.45 65.9 -57.62 -67.71 1461.90 11 398 1356.71 10 578 55
24.2 315.1 0.497 65 0.51 10.33 80.55 8.60 67.1 -56.06 -66.35 1463.26 11 409 1358.07 10 588 56
23.7 307.0 0.504 66 0.52 10.25 79.92 8.52 66.4 -56.98 -67.21 1462.40 11 402 1357.21 10 582 57
25.2 324.4 0.487 64 0.50 10.25 79.92 8.54 66.6 -56.22 -66.41 1463.20 11 408 1358.01 10 588 58
24.8 320.7 0.490 64 0.50 10.41 81.17 8.70 67.8 -55.58 -65.92 1463.69 11 412 1358.50 10 592 59
24.6 314.9 0.498 66 0.51 9.97 77.74 8.31 64.8 -57.59 -67.56 im-05 11 899 1366.86 10 579 60
23.5 300.5 0.507 (so) (0.39) 67 0.52 9.73 75.87 8.13 63.4 -57.87 -67.60 1462.01 11 399 1366.82 10 579 61
23.0 294.9 0.519 (SO) (0.S9) 68 0.53 9.602 74.87 8.07 62.9 -60.51 -70.11 1469.60 11 879 1854.31 40 659 62
25.2 323.0 0.491 (so) (0.S9) 65 0.51 10.05 78.36 8.36 65.2 -57.13 -67.18 146248 a 402 1867.24 10 582 53
24.9 321.4 0.494 65 0.51 10.21 79.61 8.53 66.5 -56.76 -66.91 1462.70 11 404 1357.51 10 584 64
23.7 306.1 0.509 (49) ([Link]) 66 0.52 9.901 77.20 8.32 64.9 -57.98 -67.88 1461.73 11 397 1356.54 10 676 65
24.0 308.5 0.500 (so) (0.39) 66 0.52 9.81 76.49 8.20 63.9 -57.15 -66.96 1462.65 11 404 135746 10 584 66
25.9 329.2 0.484 (so) (0.39) 64 0.50 10.13 78.99 8.40 65.5 -56.20 -66.33 1463.28 11 409 1868.09 10 589 67
26.4 336.9 0.473 (AS) (0.38) 63 0.49 10.41 81.17 8.60 67.1 -55.41 -65.82 1463.79 11 413 1358.60 10 593 68
25.2 317.4 0.486 (SO) (0.39) 65 0.51 9.96 77.66 8.32 64.9 -55.21 -65.17 146444 11 418 1369.25 10 598 69
26.5 333.7 0.477 63 0.49 10.20 79.53 8.44 65.8 -55.56 -65.67 1463.94 11 414 1358.75 10 594 70
24.9 318.1 0.489 (49) (0.88) 65 0.51 10.12 78.91 8.46 66.0 -54.34 -64.46 1465.15 11 423 1859.96 10 60S 71
27.0 337.7 0.478 to) (0.40) 63 0.49 9.84 76.73 8.43 65.7 -56.61 -66.51 1463.10 11 407 1357.91 10 587 72
25.3 319.0 0.490 (so) (0.89) 65 0.51 9.76 76.10 8.19 63.9 -56.73 -66.37 1463.24 11 408 1358.05 10 588 73
23.3 298.2 0.504 (SI) (040) 67 0.52 9.12 71.11 7.85 61.2 -57.69 -66.92 1462.69 11 404 1357.50 10 584 74
26.6 335.9 0.481 (so) (0.39) 63 0.49 10.00 77.97 8.35 65.1 -56.51 -66.43 1463.18 11 408 1357.99 10 588 75

20.7 344.5 0.603 56.07 0.3941 76.16 0.6288 12.276 86.28 9.387 65.98 -59.63 -71.92 7.98 4.18 1620.06 11 386 1504.35 10 573 76
20.7 337.2 0.596 («) (041) 74.6 0.524 12.2 85.7 9.37 65.9 -61.25 -73.20 1618.78 11 377 1503.07 10 564 77
21.1 340.4 0.582 (ss) (041) 74.0 0.520 12.0 85.0 9.35 65.7 -60.77 -72.68 1619.30 11 381 1503.59 10 567 78
21.1 337.4 0.575 (S8) (041) 74.8 0.526 11.9 84.3 9.27 65.2 -60.77 -72.58 1619.40 11 381 1503.69 10 568 79
21.1 336.6 0.573 (ss) (041) 74.4 0.522 11.9 83.6 9.25 65.0 -60.77 -72.54 1619.44 11 382 1503.73 10 568 80
21.6 340.6 0.561 73 0.51 11.7 83.6 9.25 65.0 -60.29 -72.96 1619.02 11 379 1503.31 10 565 81
21.5 336.6 0.552 73 0.51 11.5 82.2 9.15 64.3 -60.29 -71.92 1620.06 11 386 1504.35 10 573 82
21.0 328.9 0.580 73.1 0.514 11.7 80.8 9.01 63.3 -63.95 -75.32 1616.66 11 362 1500.95 10 549 83
21.6 340.1 0.567 73 0.51 11.5 82.2 9.13 64.2 -61.47 -73.07 1618.90 11 378 1503.20 10 565 84
21.2 326.3 0.566 74 0.52 11.6 80.8 9.04 63.5 -62.39 -73.82 1618.16 11 373 1502.45 10 559 85
21.2 330.0 0.569 74 0.52 11.7 81.5 9.04 63.5 -62.39 -73.86 1618.12 11 372 1502.41 10 559 86
21.2 330.0 0.576 74 0.52 11.8 82.2 9.13 64.2 -62.39 -73.96 1618.02 11 372 1502.31 10 558 87
20.7 329.9 0.590 (57) (0.40) 73.6 0.517 11.4 82.9 9.14 64.2 -62.87 -74.48 1617.50 11 368 1501.79 10 555 88
21.9 339.1 0.557 72.8 0.512 11.6 80.1 8.99 63.2 -62.55 -73.92 1618.06 11 372 1502.35 10 559 89
22.1 340.9 0.551 72 0.51 11.5 81.5 9.09 63.9 -60.99 -72.52 1619.46 11 382 1503.75 10 568 90
21.6 333.2 0.555 73 0.51 11.6 80.8 9.02 63.4 -61.91 -73.34 1618.64 11 376 1502.93 10 563 91
21.6 335.2 0.562 73 0.51 11.3 81.5 9.10 64.0 -61.91 -73.44 1618.54 11 375 1502.83 10 562 92
21.8 333.8 0.548 73 0.52 11.5 79.4 8.90 62.6 -62.55 -73.78 1618.20 11 373 1502.49 10 560 93
22.1 339.1 0.546 72 0.51 11.6 80.8 9.05 63.6 -60.99 -72.45 1619.52 11 382 1503.82 10 569 94

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p^ 64*
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

35
 IC1.9

TABLE 1C1.9—Paraffins (Metric Units)

Refractive # Specific Kinematic

Density of the Liquids Index of the
at g per cu cm Liquid,0 nx>
Dispersion of
the Liquid,0
Viscosity of
the Liquid,
dp 10' (,nF-nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, Point of the Aniline
Compound Point at deg in Air at Liquid0 Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20 C 25 C 20 C 25 C 20 C 25 C C C per cm

Paraffins, C10H22 (continued):

4-re-Propylheptane 157.5 0.051 0.7397 0.7359 0.7321 1.4135 1.4113 95.1 95.1 76"
4-Isopropylheptane 158.9 0.051 0.7430 0.7392 0.7354 1.4155 1.4132 97 97
2-Methyl-3-ethylheptane 161.2 0.052 0.7474 0.7436 0.7398 1.4174 1.4151 96 96
2-Methyl-4-ethylheptane 156.2 0.051 0.7398 0.7360 0.7322 1.4137 1.4114 96 96
2-Methyl-5-ethylheptane 159.7 0.051 0.7393 0.7356 0.7318 4134 1.4111 96 96
3-MethyI-3-ethylheptane 163.8 0.053 0.7539 0.7501 0.7463 1.4208 1.4185 97 97 73"
3-Methyl-4-ethylheptane 162.2 0.052 0.7543 0.7504 0.7466 1.4206 1.4183 96
3-Methyl-5-ethylheptane 158.2 0.051 0.7445 0.7406 0.7368 1.4164 1.4141 96 96
4-Methyl-3-ethylheptane 163.0 0.052 0.7544 0.7506 0.7468 4207 1.4184 96 96
4-Methyl-4-ethylheptane 160.8 0.053 0.7548 0.7510 0.7472 1.4210 1.4187 97 97
2,2,3-TrimethyIheptane 157.6 0.052 0.7461 0.7423 0.7385 1.4168 1.4145 97 97 74*
2,2,4-Trimethylheptane 148.3 0.051 0.7313 0.7275 0.7237 1.4092 1.4069 100 100
2,2,5-Trimethylheptane 150.8 0.051 0.7320 0.7281 0.7243 1.4101 1.4078 100 100
2,2,6-Tri methylheptane 148.95 0.051 -106.0 0.7277 0.7238 0.7200 4078 4055 98 98
2,3,3-Trimethylheptane 160.2 0.053 0.7527 0.7488 0.7450 1.4202 4179 96 96
2,3,4-Trimethylheptane 159.9 0.052 0.7523 0.7485 0.7447 1.4195 1.4172 97 97
2,3,5-Trimethylheptane 160.7 0.051 0.7490 0.7451 0.7413 1.4169 1.4146 97 97
2,3,6-Trimethylheptane 156.0 0.051 0.7385 0.7347 0.7309 1.4131 4108 97 97
2,4,4-Trimethylheptane 151.0 0.052 0.7384 0.7346 0.7308 1.4143 1.4120 97 97
2,4,5-Trimethylheptane 156.5 0.051 0.7450 0.7411 0.7373 1.4160 1.4137 97 97
2,4,6-Trimethy Iheptane 147.6' 0.050 0.7265 0.7228 0.7190 1.4071 1.4048 97 97 82*
2,5,5-Trimethylheptane 152.82 0.052 0.7438 0.7400 0.7362 4149 1.4126 97 97
3,3,4-Trimethylheptane 161.9 0.053 0.7604 0.7565 0.7527 1.4236 4213 97 97
3,3,5-Trimethylheptane 155.70 0.052 0.7466 0.7428 0.7390 1.4170 1.4147 97 97 70*
3,4,4-Trimethylheptane 161.1 0.053 0.7612 0.7573 0.7535 1.4235 4212 97 97
3,4,5-Trimethylheptane 162.5 0.052 0.7596 0.7557 0.7519 1.4229 1.4206 97 97
2-Methyl-3-isopropylhexane 166.7 0.052 0.7512 0.7474 0.7436 1.4195 1.4172 98 98
3,3-Diethylhexane 166.3 0.053 0.7652 0.7613 0.7575 1.4258 1.4235 95 95 69*
3,4-Diethy lhexane 163.9 0.052 0.7548 0.7510 0.7472 1.4190 1.4167 94.7 94.6 73*
2,2-Di methyl-3-ethylhexane 156.1 0.052 0.7523 0.7485 0.7447 1.4197 1.4174 97 97
2,2-Dimethyl-4-ethylhexane 147 0.051 0.7377 0.7340 0.7302 4131 1.4107 97 97
2,3-Dimethyl-3-ethylhexane 163.7 0.054 0.7676 0.7637 0.7599 1.4270 1.4247 97 97
2,3-Di methyI-4-ethy lhexane 160.9 0.052 0.7592 0.7554 0.7516 1.4226 1.4203 97 97
2,4-Dimethyl-3-ethylhexane 160.1 0.052 0.7591 0.7552 0.7514 1.4225 1.4202 97 97
2,4, Dimethyl-4-ethylhexane 161.1 0.052 0.7600 0.7563 0.7525 4235 1.4212 97 97
2,5-Dimethyl-3-ethylhexane 154.1 0.051 0.7445 0.7406 0.7368 1.4157 1.4134 97 97
3,3-Dimethyl-4-ethylhexane 162.9 0.053 0.7674 0.7636 0.7598 1.4269 1.4246 97 97
3,4-DimethyI-3-ethylhexane 162.1 0.054 0.7673 0.7634 0.7596 1.4267 1.4244 97 97
2,2,3,3-Tetramethylhexane 160.34 0.0538 0.76800 0.76444 0.76087 1.42818 1.42600 97 97
2,2,3,4-Tetramethylhexane 158.8 0.052 0.7589 0.7551 0.7513 1.4216 1.4193
2,2,3,5-Tetramethylhexane 148.4 0.051 0.7420 0.7378 0.7336 1.4142 1.4119
2,2,4,4- Tetramethy lhexane 153.8 0.051 0.7499 0.7462 0.7424 1.4208 1.4185
2,2,4,5-Tetramethylhexane 147.90 0.0512 0.73933 0.73544 0.73159 1.41318 1.41095
2,2,5,5-Tetramethylhexane 137.47 0.0500 -12.59 0.72272 0.71873 0.71478 1.40550 1.40316 102 102
2,3,3,4-Tetramethylhexane 164.62 0.0054 0.7731 0.7694 0.7656 1.4298 1.4275 97 97
2,3,3,5-Tetramethylhexane 153.1 0.052 0.7525 0.7487 0.7449 1.4196 1.4173 97 97
2,3,4,4-Tetramethylhexane 161.6 0.054 0.7663 0.7624 0.7586 1.4267 1.4244 97 97
2,3,4,5-Tetramethylhexane 156.2 0.053 0.7531 0.7494 0.7456 1.4204 1.4181 98 98
3,3,4,4-Tetramethylhexane 170.0 0.054 0.7859 0.7824 0.7789 1.4368 1.4346 97 97 64*
2,4-Dimethyl-3-isopropylpentane 157.06 0.0544 -81.67 0.76208 0.75828 0.75455 1.42463 1.42248 97 97
2-Methyl-3,3-diethylpentane 169.7 0.055 0.7831 0.7793 0.7755 1.4343 1.4320 97 97
2,2,3-Trimethyl-3-ethylpentane 169.5 0.054 0.7857 0.7818 0.7780 1.4420 1.4397 97 97
2,2,4-Trimethyl-3-ethyl pentane 155.3 0.053 0.7612 0.7571 0.7531 1.4223 1.4199 98 98
2,3,4-Trimethyl-3-ethylpentane 169.47 0.052 0.7812 0.7773 0.7735 1.4333 1.4310 97 97
2,2,3,3,4-Pentamethylpentane 166.08 0.0552 -36.43 0.78336 0.78007 0.77673 1.43606 1.43412 97 97
2,2,3,4,4-Pentamethylpentane 159.31 0.0537 -38.73 0.77037 0.76701 0.76359 1.43069 1.42868

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

36
 1C1.9
TABLE 1C1.9—Paraffins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure*
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HjO (liquid)+ H20(gas) +
Pres- pera- ume, (1 atmos) CO, (gas) COi (gas)
sure, ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
per cal per per cal per mole cal per g mole cal per g
deg- g. deg deg- g. deg
mole Cent rade Cent mole g mole g

21.5 328.0 0.545 73 0.62 11.6 81.5 9.11 64.0 -60.29 -71.81 1620.16 11 387 1504.46 10 573 95
22.0 334.6 0.537 73 0.51 11.3 79.4 8.95 62.9 -60.99 -72.31 1619.66 11 383 1503.36 10 570 96
22.0 337.8 0.544 72 0.51 11.5 80.8 9.02 63.4 -60.99 -72.42 1619.56 11 382 1503.85 10 569 97
21.6 328.7 0.545 73 0.52 11.3 79.4 8.93 62.8 -61.91 -73.20 1618.78 11 377 1503.07 10 564 98
21.6 333.7 0.555 73 0.52 11.5 80.8 9.02 63.4 -61.91 -73.34 1618.64 11 376 1502.93 10 563 99
22.8 346.9 0.532 72 0.51 11.4 80.1 8.97 63.0 -61.15 -72.48 1619.50 11 382 1503.74 10 569 100
22.5 341.3 0.530 72 0.51 11.4 80.1 9.00 63.3 -60.51 -71.90 1620.08 11 386 1504.37 10 573 101
22.0 333.6 0.541 73 0.51 11.4 80.1 9.01 63.3 -61.43 -72.82 1619.16 11 380 1503.45 10 566 102
22.5 342.2 0.533 72 0.51 11.5 80.8 9.02 63.4 -60.51 -71.94 1620.04 11 386 1504.33 10 573 103
22.8 342.7 0.525 72 0.51 11.2 78.7 8.92 62.7 -61.15 -72.38 1619.60 11 383 1503.89 10 569 104
22.4 338.7 0.546 73 0.51 11.2 78.7 8.87 62.3 -62.81 -73.95 1618.02 11 372 1502.32 10 558 105
21.4 321.4 0.552 74 0.52 10.9 76.6 8.70 61.1 -62.89 -73.78 1618.20 11 373 1502.49 10 560 106
21.4 324.9 0.559 74 0.52 11.0 77.3 8.76 61.6 -65.09 -76.09 1615.88 11 357 1500.18 10 543 107
21.0
22.9
320.3
344.5
0.573
0.538
(«i) ( 7.S8) 75
72
0.53
0.51
11.1
11.2
78.0
78.7
8.78
8.89
61.7
62.5
-65.57
-61.89
-76.60
-73.06
1615.38
1618.92
11
11
353
378
1499.67
1503.21
10
10
540
565
108
109
22.6 340.7 0.538 72 0.50 11.3 79.4 8.92 62.7 -61.69 -72.95 1619.02 11 379 1503.32 10 565 110
22.1 339.7 0.547 72 0.51 11.3 79.4 8.88 62.4 -62.61 -73.84 1618.14 11 372 1502.43 10 559 111
21.6 331.1 0.560 73 0.52 11.3 79.4 8.92 62.7 -63.09 -74.35 1617.62 11 369 1501.92 10 556 112
21.9 327.2 0.541 73 0.52 10.8 75.9 8.69 61.1 -61.97 -72.86 1619.12 11 379 1503.41 10 566 113
22.1 333.8 0.544 73 0.51 11.2 78.7 8.87 62.3 -62.61 -73.80 1618.18 11 373 1502.47 10 559 114
21.2 317.2 0.560 75 0.53 11.1 78.0 8.82 62.0 -64.01 -75.10 1616.88 11 364 1501.17 10 550 115
21.9 329.8 0.550 73 0.51 11.0 77.3 8.79 61.8 -64.17 -75.20 1616.78 11 363 1501.07 10 550 116
23.4 349.0 0.526 71 0.50 11.2 78.7 8.89 62.5 -61.41 -72.58 1619.40 11 381 1503.69 10 568 117
22.3 336.0 0.537 73 0.51 11.0 77.3 8.76 61.6 -61.49 -72.49 1619.48 11 382 1503.78 10 569 118
23.4 347.9 0.524 71 0.50 11.1 78.0 8.86 62.3 -61.13 -72.26 1619.72 11 383 1504.01 10 570 119
23.1 346.5 0.529 71 0.50 11.3 79.4 8.95 62.9 -61.21 -72.50 1619.48 11 382 1503.77 10 569 120
22.6 350.3 0.529 72 0.51 11.1 78.0 8.75 61.5 -61.69 -72.81 1619.16 11 380 1503.46 10 566 121
23.8 354.8 0.510 71 0.50 11.3 79.4 8.99 63.2 -59.83 -71.16 1620.82 11 391 1505.11 10 578 122
23.0 345.8 0.519 72 0.51 11.4 80.1 9.00 63.3 -60.03 -71.42 1620.56 11 389 1504.85 10 576 123
22.8 338.6 0.526 72 0.51 11.0 77.3 8.77 61.6 -62.33 -73.32 1618.66 11 376 1502.95 10 563 124
21.9 321.6 0.539 74 0.52 10.8 75.9 8.66 60.9 -62.41 -73.27 1618.70 11 376 1502.10 10 563 125
23.9 353.8 0.516 70 0.49 11.2 78.7 8.89 62.5 -60.49 -71.66 1620.32 11 388 1504.61 10 574 126
23.1 344.2 0.524 71 0.50 11.2 78.7 8.90 62.6 -61.21 -72.43 1619.54 11 382 1503.84 10 569 127
23.1 343.1 0.522 71 0.50 11.2 78.7 8.88 62.4 -61.21 -72.40 1619.58 11 382 1503.87 10 569 128
23.4 347.9 0.524 71 0.50 11.1 78.0 8.86 62.3 -60.57 -71.70 1620.28 11 387 1504.57 10 574 129
22.1 330.4 0.537 73 0.51 11.1 78.0 8.80 61.9 -62.61 -73.70 1618.28 11 373 1502.57 10 560 130
23.9 352.6 0.513 70 0.49 11.1 78.0 8.87 62.3 -60.93 -72.06 1619.92 11 385 1504.21 10 572 131
23.9 351.5 0.511 70 0.49 11.1 78.0 8.84 62.1 -60.01 -71.11 1620.86 11 392 1506.16 10 578 132
24.3 355.1 0.518 70 0.49 10.8 75.9 8.69 61.1 -61.43 -72.31 1619.66 11 383 1503.96 10 570 133
23.4 347.3 0.525 71 0.50 10.9 76.6 8.70 61.1 -60.83 -71.73 1620.24 11 387 1504.54 10 574 134
22.4 328.2 0.540 73 0.52 10.8 75.9 8.66 60.9 -64.43 -75.23 1616.74 11 363 1501.04 10 549 135
22.2 337.2 0.535 72 0.51 10.4 73.1 8.38 58.9 -61.59 -72.05 1619.92 11 385 1504.22 10 572 136
21.9 325.4 0.544 73 0.52 10.6 74.5 8.56 60.2 -63.59 -74.28 1617.70 11 369 1501.99 10 556 137
21.2 309.8 0.557 75 0.53 10.4 73.1 8.43 59.3 -68.27 -78.73 1613.24 11 338 1497.54 10 525 138
24.5 360.0 0.514 70 0.49 11.1 78.0 8.84 62.1 -60.75 -71.82 1620.16 11 387 1504.45 10 573 139
22.9 337.0 0.531 72 0.51 10.8 75.9 8.67 60.9 -61.31 -72.14 1619.84 11 384 1504.13 10 571 140
23.9 353.5 0.518 70 0.50 11.0 77.3 8.76 61.6 -59.91 -70.88 1621.10 11 393 1505.39 10 580 141
23.1 340.2 0.530 72 0.51 11.0 77.3 8.81 61.9 -62.39 -73.45 1618.52 11 375 1502.82 10 562 142
25.4 373.7 0.506 68 0.48 10.1 71.0 8.37 58.8 -60.03 -71.04 1620.94 11 392 1505.23 10 579 143
23.1 341.4 0.521 71 0.50 10.9 76.6 8.69 61.1 -62.39 -73.31 1618.66 11 376 1502.96 10 563 144
25.0 366.8 0.501 69 0.49 11.3 79.4 8.97 63.0 -59.09 -70.36 1621.62 11 397 1505.91 10 584 145
25.4 373.0 0.503 68 0.48 11.0 77.3 8.72 61.3 -60.03 -71.01 1620.96 11 392 1505.26 10 579 146
23.4 342.3 0.518 71 0.50 10.7 75.2 8.64 60.7 -60.83 -71.26 1620.36 11 388 1504.65 10 575 147
25.1 369.3 0.506 69 0.49 11.1 78.0 8.85 62.2 -59.83 -70.93 1621.04 11 393 1505.34 10 580 148
25.5 370.8 0.508 69 0.48 10.8 75.9 8.69 61.1 -58.57 -69.38 1622.60 11 404 1506.89 10 591 149
23.7 354.2 0.521 70 0.49 10.4 73.1 8.44 59.3 -59.57 -70.07 1621.90 11 399 1506.20 10 586 150

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

37
 1C1.10

TABLE 1C1.10—Cycloparaffins (Metric Units)

Refractive _ Specific Kinematic

Density of the Liquid," Index of the Dispersion of Viscosity of
dt g per cu cm Liquid,a no the Liquid,*1 the Liquid,
dp 10< (ni—nc)/d centistokes Surface
at 1 Freezing
Boiling atmos, . Point of the Aniline
No. Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per
mm
deg Cent
at at at at at at
at at c, Cent
at 37.78 98.89 dynes
Hg 15 C 20C 25 C 20C 25 C 20C 25 C C C per cm

Alkylcyclopropanes, Cs and C4:

1 Cyclopropane, CsHs, M.W. 42.081 -32.80 0.0306 -127.42 [Link]
2 Methylcyclopropane, CiH8, M.W. 56.108 +0.73 0.040 -177.3

Alkylcyclopropanes, CsHio, M.W. 70.135:

3 Ethyloyclopropane 35.92 0.040 -149.23C 0.6889 0.6840 0.6790 1.3786 1.3756
4 1,1-Dimethylcyclopropane 20.62 0.040 -108.9 0.6649 0.6604 0.6554'* 1.3669
5 l,cis-2-DimethyIcyclopropane 37.02 0.040 -140.883 0.6988 0.6939 0.6889 1.3829 1.3800 98 98
6 1 ,trans-2-T>i methylcyclopropane 28.20 0.040 -149.58 0.6748 0.6698 0.6648 1.3713 1.3683 101 101

Alkylcyclopropanes, CtHij, M.W. 84.162:

7 w-Propylcyclopropane 69.14 0.040 0.7161 0.7112 0.7062 1.3930 1.3905
8 Isopropylcyclopropane 58.31 0.040 -112.92 0.7036 0.6986 0.6936 1.3865 1.3835
9 1-Methyl-l-ethylcyclopropane 56.76 0.040 -130.2 0.7068 0.7018 0.6968 1.3887 1.3857
10 l-Methyl-ci's-2-ethylcy c lop ropane 67.00 0.040 0.7194 0.7146 0.7096 1.3953 1.3923
11 l-Methyl-(r<ms-2-ethyl 0 yclopropane 58.65 0.040 0.6985 0.6935 0.6885 1.3846 1.3816
12 1,1,2-Trimethylcycloprop ane 52.43 0.039 -138.192 0.6996 0.6947 0.6897 1.3864 1.3834 110 110
13 l,czs-2,Cis-3-Trimethyl cyclopropane 66 0.040 0.7230 0.7180 0.7130 1.3970 1.3940
14 l,cis-2,*rara3-3-Trimethyleyclopropane 59.7 0.040 0.7028 0.6979 0.6929 1.3873 1.3843

Alkylcyclobutanes, C4 and Cs:

15 Cyclobutane, CjHs, M.W. 56.108 12.51 0.0360 -90.70" 0.6997d 0.6943i 0.6890'' 1.365'' 1.362li
16 Methylcyclobutane, C5H10, M.W. 70.135 36.3 0.04 0.6977 0.6930 0.6884 1.3836 1.3810

Alkylcyclobutanes, C6Hi2, M.W. 84.162:

17 Ethylcyclobutane 70.59 0.04 -142.762 0.7326 0.7279 0.7232 1.4020 1.3994 99 99 38 7*
18 1,1-Dimethylcyclobutane 56 0.04 0.718 0.713 0.708 1.396 1.393
19 1, cfs-2-Dimethylcyclobutane 68 0.04 0.741 0.736 0.731 1.404 1.401
20 1 ,<nms-2-Dimethylcydobutane 60 0.04 0.718 0.713 0.708 1.395 1.392
21 1, cfs-3-Dimethylcyclobutane 60.5 0.04 0.7153 0.7106 0.7060 1.3933 1.3908
22 1, (rans-3-Dimethylcyclobutane 57.5 0.04 0.7061 0.7016 0.6970 1.3896 1.3871

Alkylcyclopentanes, C6 and Ce:

23 Cyclopentane, CsHio, M.W. 70.135 49.252 0.04003 -93.839 0.75016 0.74536 0.74043 1.40645 1.40363 94.3 94.2 0.499 21.82 16.8
24 Methylcyclopentane, CsHn, M.W. 84.162 71.804 0.04274 -142.469 0.75338 0.74862 0.74392 1.40970 1.40700 96.2 96.1 0.565 21.61 33.0

Alkylcyclopentanes, C7H14, M.W. 98.189:

25 Ethylcyclopentane 103.467 0.04623 -138.458 0.77084 0.76645 0.76215 1.41981 1.41730 95.5 95.4 0.619 0.39 23.37 36.7
26 1,1-Dimethylcyclopentane 87.482 0.04497 -69.761 0.75897 0.75446 0.74989 1.41356 1.41091 97.3 97.2 21.23 45*
27 1, cis-2-DimethyIcyclopentane 99.532 0.04603 -53.893 0.77707 0.77260 0.76805 1.42217 1.41963 97.4 97.3 39.9*
28 1, trans-2-Dimethylcyclopentane 91.866 0.04521 -117.57 0.75592 0.75142 0.74684 1.41200 1.40941 96.5 96.4 46.7*
29 1, ds-3-Dimethylcyclopentane 90.770 0.04518 -133.711 0.74934 0.74477 0.74023 1.40894 1.40633 97.4 97.3
30 1, (rans-3-Dimethylcyclopentane 91.722 0.04525 -133.984 0.75320 0.74878 0.74433 1.41074 1.40813 96.2 96.1 49.9*

Alkylcyclopentanes, CsHie, M.W. 112.216:

31 ra-Propylcyclopentane 130.961 0.04888 -117.334 0.78038 ).77631 1.77227 1.42626 I.42389 95.7 95.6 0.724 0.46 44.5
32 Isopropylcyclopentane 126.429 0.04913 -111.364 0.78035 1.77651 1.77257 .42582 1.42350 95.6 95.5
33 1-MethyH-ethylcyclopentane 121MB 0.04863 -143.814 0.78521 ().78091 (1.77668 .42718 .42476 95.9 95.8
34 l-Methyl-as-2-ethylcyclopentane 128.061 0.04897 -105.93 0.78937 (1.78520 (1.78111 .42933 .42695 94.7 94.6 47.5*
35 l-Methyl-frans-2-ethylcyclopentane 121.2 0.049 -150.0 0.7730 ( .7690 ( .7649 1 .4219 .4195 95 95 52.2*
36 l-Methyl-cts-3-ethylcyclopentane 121.1 0.049 0.771 { .767 C .763 1 .419 1 .417 95 95
37 l-Methyl-irans-3-ethyIcyclopentane 121.1 0.049 0.771 C .767 C .763 1 .419 1 .417 95 95
38 1,1,2-Trimethylcyclopentane 113.734 0.04818 -21.63 0.77691 C .77250 C .76815 1 .42298 1 .42051 97.0 96.9
39 1,1,3-Trimethylcyclopentane 104.895 0.04724 -142.45 0.75256 C .74823 0 .74390 1 .41119 1 .40870 98.7 98.6
40 1, cis-2, czs-3-Trimethylcyclopentane 123.0 0.049 -116.423 0.7833 0 .7792 0 .7751 1 .4262 1 .4238 96 96 41.0
41 1, ct's-2, (rans-3-Trimethylcyclopentane 117.5 0.048 -112 0.7746 0 .7704 0 .7661 1 .4218 1 .4194 96 96 41.0
42 l,irans-2,cis-3-Trimethylcyclopentane 11041 0.048 -112.694 0.7579 0 .7535 0 .7492 1 .4138 1 .4114 96 96 41.0
43 l,as-2,«s-4-Trimethylcyclopentane 116.76 0.048 -[Link] 0.7758 0 .762 0 .768 1 4186 1 416$ 96 96
44 l,cis-2,*rans-4-Trimethylcyclopentane 116.737 0.04827 -132.56 0.76771 0 .76343 0 .75918 1 .41855 1 .41612 95.8 95.7
45 l,*rans-2,ds-4-Trimethylcyclopentane 109.293 0.04738 -130.79 0.75160 0 .74725 0 .74300 1 .41060 1 .40812 96.9 96.8

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64,
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

38
 1C1.10
TABLE 1C1.10-•Cycloparaffins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure0
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HiO (liquid)+ H20(gas) +
Pres- pera- ume, (1 atmos) COj (gaa) COi (gas)
sure, ture, liter Gas, Liquid Gas, Liquid
atmos dee per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
deg- g, aeg deg- g. deg per cal per per cal per
mole cal per g mole cal per g
mole Cent mole Cent mole g mole -B

84.23 124.66 0.17 4.79 114 0

1
2

3
4
5
6

7
8
9
10
11
12
13
14

49.2 186.8 0.21 23.8 0.425 5.65 101 5.78 103 6.42 0.77 650.23" 11 589 608.16 10 839 15
33.2 0.474 16

17
18
19
20
21
22

44.49 238.60 0.260 19.82 0.2826 30.32 0.4323 6.818 97.22 6.524 93.03 -18.41 -25.28 9.28 8.72 786.55" 11 215 733.96 10 465 23
37.35 259.64 0.319 26.24 0.3118 37.93 0.4507 7.56 89.83 6.916 82.18 -25.34 -32.92 8.71 7.68 941.28 11 184 878.17 10 434 24

33.53 296.37 0.375 31.49 0.3207 0.4530 8.72 88.81 7.715 78.58 -30.33 -39.06 10.70 8.99 1097.50 11 177 1023.87 10 427 25
35 274 0.36 31.86 0.3245 44M 0.4548 8.079 82.29 7.239 73.73 -33.02 -41.12 9.36 7.99 1095.44 11 156 1021.81 10 406 26
34 292 0.37 32.06 0.3265 45.12 0.4595 8.549 87.07 7.576 77.16 -30.94 -39.50 10.95 9.31 1097.06 11 173 1023.43 10 423 27
34 280 0.36 32.14 0.3274 44.2 0.450 8.259 84.12 7.375 75.12 -32.64 -40.92 9.20 7.72 1095.64 11 158 1022.01 10 408 28
34 278 0.36 32.14 0.3274 46.04 0.4587 8.200 83.52 7.332 74.68 -32.44 -40.66 9.40 7.98 1095.90 11 161 1022.27 10 411 29
34 280 0.36 32.14 0.3274 (it) (0.48) 8.248 84.01 7.361 74.97 -31.90 -40.17 9.94 8.47 1096.39 11 166 1022.76 10 416 30

29.80 330 0.426 36.96 0.3294 61.69 0.4606 9.91 88.3 8.151 72.64 -35.37 -45.19 12.58 10.37 1253.74 11 172 1169.59 10 422 31
29.60 328 0.422 (se) (0.3$) (47) (0.42) 9.5 84.7 8.15 72.6 (1263.9) 0/ 176) (1169.8) (10 42S) 32
[Link] 319 0.422 (89) (0.35) (63) (0.47) 9.3 82.9 8.04 71.7 (ms.o) (U 167) dl68.8) (10 417) 33
$9.50 323 0.421 (se) (0.32) (47) (O.42) 9.6 85.6 8.25 73.5 (1252.5) (11 160) dl68.l) (10 410) 34
29.00 316 0.421 (86) (0.32) (47) (0.42) 9.4 83.8 8.07 71.9 (1252.9) (ll 166) (1168.7) (10 416) 35
$9.00 314 0.421 (se) (0.32) (47) (0.42) 9.4 83.8 8.08 72.0 (1262.1) (It 158) (1167.9) (10 408) 36
28.60 $14 0.421 (36) (0.S2) (47) (0.42) 9.3 82.9 8.05 71.7 (1262.9) (ll 186) (1168.7) (10 418) 37
29.00 306.4 0.417 (S7) ([Link]) (60) (0.45) 8.9 79.3 7.79 69.4 (1260.2) (11 142) (1166.1) (lO 392) 38
27.90 296.4 0.417 (S7) ([Link]) (BO) (0.46) 8.6 76.6 7.57 67.5 (1250.7) (11 148) (1166.6) (10 896) 39
29.00 SIS 0.418 (se) (0.82) (48) (0.4S) 9.3 82.9 8.04 71.7 (1261.6) (11 153) (U67.4) (10 403) 40
28.60 307 O.4I6 (se) {0.32) US) (0.43) 9.1 81.1 7.92 70.6 (1249.6) (ll 1S7) (1165.6) (10 387) 41
$7.90 299 0.416 (86) (0.32) (48) (0.43) 8.8 78.4 7.72 68.8 (1250.0) (11 140) (1165.8) (10 390) 42
28.50 307 0.416 (36) (0.32) (48) (0.43) 9.1 81.1 7.90 70.4 (1249.8) (ll 1S7) (1165.6) (10 387) 43
28.40 SOS 0.416 (se) (0.32) (48) (0.4S) 9.1 81.1 7.90 70.4 (I249.7) (11 137) (1166.6) (10 387) 44
27.76 298 O.4I6 (se) (0.82) (48) (0.43) 8.8 78.4 7.74 69.0 (1249.8) (11 138) (1165.6) (10 388) 45

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p..
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

39
 1C1.10

TABLE 1C1.10—Cycloparaffins (Metric Units)

Refractive Specific Kinematic

Density of the Liquid,* Index of the Dispersion of Viscosity of
dt g per cu cm Liquid," TID the Liquid," the Liquid,
dp 10' (tip-nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, Point of the Aniline
No. Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20C 25 C 20 C 25 C 20C 25 C C C per cm

Alkylcyclopentanes, OHis, M.W. 126.243:

46 ra-Butylcyclopentane 156.62 0.0512 -107.970 0.7884 0.7846 0.7808 1.4316 1.4293 96 96 0.908 0.53 48.7
47 Isobutylcyclopentane 147.97 0.05 -115.217 0.7849 0.7809 0.7769 1.4298 1.4273 100 100
48 sec-Butylcyclopentane 154.37 0.05 0.7985 0.7945 0.7905 1.4357 1.4332
49 ieri-Butylcyclopentane 144.87 0.05 -95.8 0.7950 0.7910 0.7870 1.4338 1.4313 96 96
50 1-Methyl-l-tt-propylcyclopentane 146 0.05 0.8030 0.799 0.795 1.437 1.435
51 l-Methyl-ca's-2-n-propylcycIopentane 152.60 0.05 -104 0.7961 0.7921 0.7881 1.4343 1.4318 95 95 54.5*
52 l-Methyl-fryzns-2-tt-propylcyclopentane 146.39 0.05 -123 0.7815 0.7775 0.7735 1.4274 1.4249 97 97 54.5h
53 l-Methyl-cis-3-«-propylcyclopentane 148 0.05 0.784 0.780 0.776 1.426 1.424
54 l-Methyl-/rarcs-3-n-propylcyclopentane 148 0.05 0.784 0.780 0.776 1.426 1.424
55 1-Methyl-l-isopropylcyclopentane 148 0.05 0.803 0.799 0.795 1.436 1.434
56 l-Methyl-cis-2-isopropylcyclopentane 148 0.05 0.797 0.792 0.788 1.434 1.432
57 l-Methyl-frcms-2-isopropylcyclopentane 141 0.05 0.784 0.780 0.776 1.429 1.427
58 l-Methyl-m-3-isopropylcyclopentane 142 0.05 <-80 0.784 0.780 0.777 1.426 1.424
59 l-Methyl-*rans-3-isopropylcycIopentane 142 0.05 <-80 0.784 0.780 0.777 1.426 1.424
TO 1,1-Diethylcyclopentane 150.5 0.05 0.8068 0.8028 0.7988 1.4388 1.4363
61 1 ,cj's-2-Diethylcyclopentane 153.58 0.05 -118 0.8001 0.7960 0.7920 1.4355 1.4330 95 95 52.9h
62 1, (rans-2-Diethylcyclopentane 147.55 0.05 -95 0.7873 0.7832 0.7792 1.4295 1.4270 96 96 52.9h
63 l,cts-3-Diethylcyclopentane 150 0.05 0.792 0.787 0.783 1.430 1.428
64 1 ,(rans-3-Diethylcyelopentane 150 0.05 0.792 0.787 0.783 1.430 1.428
65 1, l-Dimethyl-2-ethylcyclopentane 138 0.05 0.794 0.788 0.784 1.432 1.430
66 l,l-Dimethyl-3-ethylcyclopentane 134 0.05 0.774 0.770 0.766 1.421 1.419
67 1, Ci's-2-Dimethyl-l-ethyIcyclopentane 144 0.05 0.803 0.799 0.795 1.437 1.435
68 l,(ra«s-2-Dimethyl-l-ethylcyclopentane 144 0.05 0.800 0.796 0.792 1.435 1.433
69 l,cis-2-Dimethyl-cis-3-ethylcyclopentane 152 0.05 0.800 0.796 0.792 1.434 1.432
70 l,c{s-2-Dimethyl-toms-3-ethylcyclopentane 145 0.05 0.792 0.788 0.784 1.431 1.429
71 1, *rans-2-Dimethyl-m-3-ethylcyclopentane 138 0.05 0.773 0.768 0.764 1.422 1.420
72 l,/raws-2-Dimethyl-*rans-3-ethylcyclopentane 145 0.05 0.789 0.784 0.780 1.428. 1.426
73 1, c*s-2-Dimethyl-c*s-4-ethylcyclopentane 147 0.05 0.800 0.796 0.792 1.432 1.430
74 1, cis-2-DimethyI-*r<ms-4-ethylcyclopentane 147 0.05 0.785 0.781 0.777 1.426 1.424
75 l,*rans-2-Dimethyl-m-4-ethylcyclopentane 140 0.05 0.772 0.769 0.765 1.420 1.418
76 1, cis-3-Dimethyl-l-ethylcycIopentane 136 0.05 0.777 0.774 0.770 1.423 1.421
77 l,tfrans-3-Dimethyl-l-ethyIcyclopentane 136 0.05 0.782 0.778 0.774 1.425 1.423
78 l,cz's-3-Dimethyl-cts-2-ethylcyclopentane 152 0.05 0.793 0.789 0.785 1.432 1.430
79 1, m-3-Dimethy Wrans-2-ethylcyclopentane 137 0.05 0.769 0.766 0.762 1.421 1.419
80 1, trans-3-Di methyl-cz's-2-ethyIcyclopentane 144 0.05 0.789 0.784 0.780 1.429 1.427
81 1, m-3-Dimethyl-C2's-4-ethylcyclopentane 145 0.05 0.793 0.789 0.785 1.430 1.428
82 1, cis-3-Dimethyl-*ra?is-4-ethylcyclopentane 137 0.05 0.769 0.766 0.762 1.420 1.418
83 1, (r(ms-3-Dimethyl-c*s-4-ethylcyclopentane 137 0.05 0.772 0.769 0.765 1.421 1.419
84 1, irarcs-3-DimethyI-*rans-4-ethylcyclopentane 145 0.05 0.782 0.778 0.774 1.425 1.423
85 1,1,2,2-Tetramethylcyclopentane 133 0.05 0.798 0.794 0.790 1.434 1.432
86 .1,1, cis-2, c/s-3-Tetramethylcyclopentane 138 0.05 0.784 0.779 0.775 1.426 1.424
87 1,1, cis-2, *ra?zs-3-Tetramethylcyclopentane 130 0.05 0.771 0.767 0.763 1.421 1.419
88 1,1, cis-2, ci's-4-Tetramethylcyclopentane 130 0.05 0.777 0.774 0.770 1.424 1.422
89 1,1, cis-2, irans-4-Tetramethylcyclopentane 130 0.05 0.768 0.763 0.759 1.419 1.417
90 1,1,3,3-Tetramethylcyclopentane 118.0S 0.05 -88.377 0.7549 0.7509 0.7469 1.4125 1.4101
91 1,1, cis-3, cis-4-Tetramethylcyclopentane [Link] 0.05 -106.496 0.7710 0.7670 0.7630 1.4209 1.4189
92 1,1, cis-3, (mns-4-Tetramethylcy clopentane 121.62 0.05 -93.14 0.7626 0.7486 0.744S 1.411S 1.4095
93 1,2,2, m-3-Tetramethylcyclopentane 138 0.05 0.785 0.781 0.777 1.427 1.425
94 1,2,2, (mns-3-Tetramethylcyclopentane 138 0.05 0.793 0.789 0.785 1.431 1.429
95 1, cis-2, cis-3, cis-4-Tetramethylcyclopentane U7.S2 0.05 -100.20 0.7964 0.7924 0.7S84 1.4SSX 1.4S08
96 1, cis-2, cis-3, ira7is-4-TetramethylcycIopentane lp.73 0.05 0.7 80S 0.7763 0.7723 1.4248 1.4224
97 1, cis-2,trans-3, cts-4-TetramethyIcyclopentane 183.87 0.05 -110.61 0.7709 0.7669 0.7629 1.4208 1.4184
98 1, cis-2, trans-3, 142.96 0.05 -111.33 0.7773 0.77SS 0.7693 1.4297 1.4273
trans-4-Tetramethylcyclopentane
99 l,ir(ms-2, cis-3, 127.24 0.05 0.7602 0.7662 0.7622 1.4166 1.4131
frans-4-Tetramethylcyclopentane
100 1, trans-2, lrans-3, 134.64 0.05 -113.11 0.7727 0.7687 0.7647 1.4219 1.4196
cis-4-Tetramethylcyclopentane

Alkylcyclopentanes, C10H20, M.W. 140.270:

101 ra-Pentylcydopentane 180.5 0.053 -83 0.7951 0.7912 0.7874 1.4358 1.4336 96 96 1.1 28 0.62

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p.. 61 , for definitions of superscripts.
40
 1C1.10
TABLE 1C1.10—Cycloparaffins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure"
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at25C Boiling Point H2O (liquid) + H2O (gas) +
Pres- pera- ume, (1 atmos) C02 (gas) CO* (gas)
sure, ture, liter Gas, Liquid Gas, Liquid
atmos dee per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal cal per kcal State State kcal per kcal per
deg- g. dee deg- g. deg per per cal per mole cal per g mole cal per g
rade Cent molc Cent mole e mole g

£6.90 358 0.482 42.42 0.3360 58.64 0.4645 11.00 87.1 8.69 68.8 -40.19 -51.19 14.89 11.73 1410.10 11 170 1315.43 10 420 46
27.00 352.5 0.478 (40) (0. St) (0.41) (8.28) (65.6) (1406.4) (11 141) (1311.8) (10 391) 47
$7.00 360.6 0.478 Uo) (o.s$) («) (0.41) (8.35) (66.1) (1408.0) (11 138) (lSll.S) (10 S88) 48
£7.40 $49 0.474 [[Link]) (0.42) (8.14) (65.5) (1404-1) (11 m) (1309.4) (10 373) 49

£7.05 350.3 0.478 (42) {[Link]) («) (0-42) (8.6S) (68.4) (1406.1) (ll 1S9) (1311.4) (10 S89) 51
[Link] 343 0.478 (.42) ([Link]) (») (0-42) (8.35) (68.$) (14O5.O) (11 ISO) (ISIO.S) (10 380) 52
53
54

56
57
$6.30 336 0.474 (4$) ([Link]) («) (0.41) (8.07) (63.9) (1405.5) (it m) (1310.8) (10 S84) 58
16.30 336 0.474 (4$) ([Link]) («) (0.41) (8.07) (6S.9) (HOLS) (11 134) (mo. 8) (10 384) 59

8740 351.4 0.478 (40) ([Link]) («) (0.41) (8.63) (68.4) (1404-6) (11 w) (1309.9) (10 377) 61
86.70 344-r 0.478 (40) ([Link]) («) (0.41) ([Link]) (66.$) (1404-9) (11 ISO) (mo.x) (10 S80) 62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98

99

100

47.89 0.3414 66.0 0.470 12.18 86.8 9.31 66.4 -45.15 16.68 1566.36 11 167 1461.17 10 417 101

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.
41
 IC1.10

TABLE 1C1.10—Cycloparaffins (Metric Units)

Refractive t Specific Kinematic

dl Density of the Liquid," Index of the Dispersion of Viscosity of
g per cu cm Liquid," riD the Liquid," the Liquid,
dp 10< (,nt—nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, , Point of the Aniline
No. Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20C 25 C 20 C 25 C 20 C 25 C C C per cm

Alkylcyclohexanes, C6 and C7:

102 Cyclohexane, CsHu, M.W. 84.162 80.719 0.04376 6.541 0.78312 0.77853 0.77387 1.42623 1.42354 96.2 96.1 0.953 24.38 31.0
103 Methylcyclohexane, C7HU, M.W. 98.189 100.934 0.04671 -126.596 0.77369 0.76937 0.76504 1.42312 1.42058 97.9 97.8 0.767 0.43 23.17 41.0

Alkylcyclohexanes, CsHiu, M.W. 112.216:

104 Ethylcyclohexane 131.795 0.04969 -111.311 0.79189 0.78790 0.78388 1.43304 1.43073 97.5 97.4 0.861 0.51 25.12 43.8
105 1,1-Dimethylcyelohexane 119.550 0.04920 -33.490 0.78505 0.78092 0.77675 1.42900 1.42662 98.6 98.4 23.61 45.4/l
106 1, cis-2-Dimethylcyclohexane 129.739 0.04988 -49.994 0.80027 0.79625 0.79220 1.43596 1.43358 96.0 95.9 25.19 41.7*
107 1, fnms-2-Dimethylcyclohexane 123.428 0.04951 -88.164 0.77990 0.77599 0.77202 1.42695 1.42470 98.0 97.9 23.57 48.3''
108 1, czs-3-Dimethylcyclohexane 120.095 0.04880 -75.539 0.77013 0.76601 0.76194 1.42294 1.42063 99.2 99.1 22.64 51.7*
109 1, frans-3-Dimethylcyclohexane 124.459 0.04910 -90.079 0.78889 0.78470 0.78053 1.43085 1.42843 97.2 97.1 24.16 46.3''
110 1, cis-4-Dimethylcyclohexane 124.330 0.04921 -87.406 0.78697 0.78283 0.77868 1.42966 1.42731 97.2 97.1 23.96 46.9''
111 1 ,(ra7is-4-DimethyIcyclohexane 119.358 0.04903 -36.940 0.76680 0.76253 0.75883 1.42090 1.41853 97.2 97.1 22.52 52.7*

Alkylcyclohexanes, CsHis, M.W. 126.243:

112 n-PropylcycIohexane 156.747 0.05200 -94.874 0.79732 0.79358 0.78975 1.43705 1.43478 97.5 97.4 1.000 0.58 49.8
113 Isopropylcyclohexane 154.785 0.05210 -89.360 0.80597 0.80219 0.79831 1.44087 1.43861 96.6 96 5 48.9*
114 1-Methyl-l-ethylcyclohexane 152.18 0.05 0.8098 0.8062 0.8025 1.4419 1.4397
115 l-MethyI-cts-2-ethylcyclohexane 156.00 0.05 0.8135 0.8097 0.8059 1.4436 1.4413
116 l-Methyl-£raws-2-ethylcyclohexane 151.72 0.05 0.798 0.794 0.790 1.4381 1.4359
117 l-Methyl-o's-3-ethylcyclohexane 148.467 0.05 0.7875 0.7837 0.7799 1.4326 1.4306
118 l-Methyl-irans-3-ethyIcyclohexane 151.08 0.05 0.8050 0.8012 0.7974 1.4374 1.4351
119 l-MethyI-ds-4-ethylcyclohexane 152.30 0.05 0.8003 0.7965 0.7927 1.4370 1.4347
120 l-MethyWrons-4-ethylcyclohexane 149.81 0.05 -81.181 0.7882 0.7794 0.7756 1.4800 1.4287
121 1,1,2-Trimethylcyclohexane 145.2 0.05 -29 0.8037 0.8000 0.7963 1.4382 1.4359
122 1,1,3-Trimethylcyclohexane 136.640 0.05089 -65.716 0.78275 0.77881 0.77495 1.42955 1.42725 99.0 98 9
123 1,1,4-TrimethylcyeIoliexane 135 0.05 0.7759 0.7722 0.7685 1.4251 1.4228
124 l,c3s-2,cis-3-Trimethylcyclohexane 151.68 0.05 -84.99 0.8065 0.8027 0.7989 1.4403 1.4880
125 1, cis-2, *rans-3-Trimethylcyclohexane 151.18 0.05 -85.70 0.8069 0.8031 0.7993 1.4399 1.4876
126 l,(rans-2,cis-3-Trimethylcyclohexane 144 0.05 0.785 0.781 0.777 1.430 1.428
127 l,cts-2,cis-4-Trimethylcyclohexane 148.59 0.05 -77.4a 0.792 0.787 0.783 1.4340 I.4317
128 1, cis-2, frans-4-Trimethylcyclohexane 146.67 0.05 -91.83 0.7946 0.7908 0.7870 1.4345 1.4322
129 1, trans-2, cis-4-Trimethylcyclohexane 144-67 0.05 -83.50 0.7946 0.7908 0.7870 1.4341 1.4318
130 1, trans-2, (rarcs-4-Trimethylcyclohexane 141.24 0.05 -86 0.7757 0.7720 0.7683 1.4266 1.4243 59.0*
131 1, cis-3, cis-5-Tri methylcyclohexane 138.43 0.05 -43.19 0.7733 0.7697 0.7660 1.4266 1.4243 101 101
132 l,m-3,(raras-5-Trimethylcyclohexane 141.24 0.05 -84.40 0.7853 0.7817 0.7780 1.4310 1.4287 99 99

Alkylcyclohexanes, GOHM, M.W. 140.270:

133 n-Butylcyclohexane 180.981 0.05412 -74.691 0.80276 0.79916 0.79549 1.44075 1.43855 97.1 97.0 1.251 0.69 54.4
134 Isobutylcyclohexane m.m -94.780 0.799 0.796 0.793 1.4386 1.4864 57.4
135 sec-Butylcyclohexane 179.300 Glass 0.817 0.814 0.811 1.4467 1.4445
136 (er/-Butylcyclohexane 171.570 -41.158 0.817 0.814 0.811 1.4469 1.4447 53.8
137 l-Methyl-4-isopropylcyclohexane 170.720 -87.590 0.803 0.800 0.797 1.4373 56.5

Alkylcycloheptanes, C7 and Cg:

138 Cycloheptane, C7HU, M.W. 98.189 118.80 0.0482 -8.04 0.8154 0.8110 0.8066 1.4449 1.4424 101 101
139 Ethylcycloheptane, CsHis, M.W. 126.243 16S.S <-S0 0.818 0.815 0.811

Alkylcyclooctanes, Cs and C9:

140 Cyolooctane, CsHiu, M.W. 112.216 151.16 0.0518 +14.82 0.8401 0.8361 0.8320 1.4587 1.4563 104 104
141 Methyloyclooctane, C9H18, M.W. 126.243 162.0 16.8 0.839 0.835 0.832

Cycloparaffins, Cs and C10:

142 Cyclononane, CsHis, M.W. 126.243 178.4 0.05 11 0.8541 0.85O2 0.8463 1.4666 1.4644
143 Cyclodecane, C«H», M.W. 140.270 202 0.05 10 0.8613 3.8575 0.8538 1.4716 1.4695

Decahydronaphthalenes, CioHis, M.W. 138.254:

144 czs-Decahydronaphthalene 195.815 0.0550 -42.98 0.9006 3.8967 0.8929 1.48098 1.47878 35.3
145 trans- Decahydronaphthalene 187.310 0.0564 -30.382 0.8740 3.86969 3.86590 1.46932 1.46715 ... 35.3

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

42
 1C1.10
TABLE 1C1.10—Cycloparaffins (Metric Units)

Heat of F ree Energy

Critical Heat Capacity at 25 C and Heat of Vaporization F ormation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C , kcal per mole al 25 C, kcal at 25 C and Constant Pressure3
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at25C Boiling Point HjO (liquid) + H,0 (gas) +
Pres- pera- ume, (1 atmos) CO2 (gas) COJ (gas)
sure, ture, liter C5as, Li quid G as, Liquid
atmos deg per I deal Id eal
Cent mole cal per cal per cal per cal per kcal kcal tate St ate kcal per kcal per
deg- g, deg deg- per ca 1 per per cal per
g. deg mole cal per g mole cal per g
mole Cent mole Cent mole g mole g

40.2 280.4 0.308 25.40 0.3018 37.36 0.4439 7.896 33.83 7.16 85.08 29.44 37.34 7 58 6.37 936.86 11 131 873.75 10 382 102
34.26 299.04 0.368 32.27 0.3287 44.10 0.4492 8.451 36.07 7.44 75.78 36.99 - 45.45 6 52 4.86 1091.13 11 112 1017.48 10 362 103

30 336 0.45 37.96 0.3383 50.62 0.4511 9.674 36.21 8.20 73.08 41.05 50.72 9 38 6.96 1248.23 11 123 1164.08 10 373 104
29 318 0.45 36.9 0.329 50.01 0.4457 9.043 30.59 7.79 69.42 - 43.26 52.31 8 42 6.34 1246.65 11 109 1162.50 10 359 105
29 333 0.46 37.4 0.333 50.24 0.4477 9.492 34.59 S.04 71.65 - 41.15 - 50.64 9 85 7.50 1248.31 11 124 1164.16 10 374 106
29 323 0.46 38.0 0.339 50.05 0.4460 9.168 31.71 7.86 70.05 43.02 - 52.19 8 24 6.06 1246.76 11 110 1162.61 10 360 107
29 318 0.45 37.6 0.335 50.04 0.4460 9.137 31.43 7.84 69.87 - 44.16 53.30 7 13 5.02 1245.65 11 100 1161.50 10 350 108
29 S2S 0.46 37.6 0.335 50.87 0.4533 9.369 33.50 8.09 72.1 42.20 51.57 8 68 6.44 1247.38 11 116 1163.23 10 360 109
29 S25 0.46 37.6 0.335 50.69 0.4518 9.329 33.14 8.07 71.9 42.22 - 51.55 9 07 6.85 1247.40 11 116 1163.25 10 366 110
29 317 0.45 37.7 0.336 50.25 0.4478 9.053 30.68 7.79 69.42 44.12 53.18 7 58 5.50 1245.78 11 101 1161.63 10 352 111

17.70 S -e 0.477 44.03 0.3488 57.85 0.4683 10.790 U.48 8.62 68.3 46.20 - 56.98 11 31 i3.22 1404.34 11 124 1309.67 10 374 112
28.00 S 0.473 (42) ([Link]) («) (0.41) (8.S5) (66) (1406.6) (11 US) 1311.9 10 S9S 113
114
115
116
117
118
119
120
27.40 "0 0.469 (i») (0.34)
([Link])
(54) (0.4S) (8.2) (65) (1403.3) (ll 117) 1S08.6 10 S67 121
26.60 S,19 0.469 (42) (H) (0.4s) (8-8) (es) (1403.8) (11 121) 1309.2 10 371 122
123
124
125
126
127
128
129
26.40 Sit 0.468 (42) ([Link]) («} (0.42) (8.1) (64.5) (1404-6) (ll 127) 1309.9 10 S76.5 130
131
132

SI. 10 S94 0.5S4 49.50 0.3529 64.78 0.4619 11.957 Ii5.26 9.20 65.6 50.95 - 62.91 13 49 9.69 1560.78 11 127 1455.59 10 377 133
SO. 80 S86 0.530 {46) ([Link]) («) (0.40) (9-1) (<w) (156S.0) (11 14S) 1457.8 10 393 134
26.40 396 0.530 (46) ([Link]) (*«) (0.40) (8.9) (63) (1562.7) (11 142) 1457.5 10 S92 135
26.36 386 0.526 (48) (0.34) (67.5) (0.41) (8-7) (62) (1560.3) (ll 125) 1455.1 10 375 136
2S.0B 381 0.525 (46) ([Link]) (eo) (0.4S) (8.7) (62) (1561.1) (11 131) 1456.0 10 S81 137

37 316 0.39 (28.5) (0.29) 43.20 O.44OO 9.210 <33.81 7.930 80.77 28.5 37.7 5.9 1098.9 11 192 1025.3 10 442 138
29.00 S81 0.472 I SB) ([Link]) (49) (0.S9) (8.6) (69) (1402.4) (ll 109) 1S07.7 10 S59 139

34 345 0.45 (32.5) (0.29) 51.60 0.4589 10.36 ()2.33 8.58 76.47 - 30.1 40.4 1 .1 1258.5 11 215 1174.4 10 465 140
29.90 S8S 0.467 (38) ([Link]) (48) (0.38) (8.6) (68) (1407.6) (ll 160) 1312.8 10 400 141

31 371 0.51 (37) (0.29) 57.0 0.452 11.6 31.89 9.12 72.25 - 32.5 44.1 1417.2 11 230 1323.0 10 480 142
29 394 0.57 64.2 0.458 12.8 <31.26 9.60 68.44 32.5 49.5 1574.2 11 223 1469.0 10 473 143

66.45 0.4011 41.13 - 52.45 . 16.52 1502.92 10 872 1408.24 10 187 144
54-61 0.3950 44.15 55.14 . 13.34 1500.23 10 852 1405.55 10 167 145

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64'.
2. M.W, — molecular weight.
3. See Appendix I, p. 61 .for definitions of superscripts.

43
 1C1.11
TABLE 1C1.11—Monoolefins and Diolefms (Metric Units)

Refractive t Specific Kinematic

Density of the Liquid," Index of the Dispersion of Viscosity of
dt g per eu cm Liquid," nz> the Liquid," the Liquid,
dp 10* (flF-nc)/d centistokes Surface
atl Freezing Tension
Boiling atmos, , Point of the Aniline
No. Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per dcg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20 C 25 C 20 C 25 C 20 C 25 0 C C per cm

Monoolefins, C» and Ci:

1 Ethene (ethylene), CiHi, M.W. 28.054 -103.68 0.0224 -169.14*
2 Propene (propylene), CsHe, M.W. 42.081 -47.72 0.0289 -185.25s 0.5226'' 0.5139'' 0.5053''

Monoolefins, C<Hs, M.W. 56.108:

3 1-Butene -6.25 0.0337 -185.35" [Link] 0.5951'' 0.5888''
4 cis-2-Butene +3.718 0.0345 -138.922 0.6271* 0.6213'' 0.6154''
5 £rans-2-Butene 0.88 0.0345 -105.533 0.6100'' 0.6042'' 0.5984''
6 2-Methylpropene (isobutene) -6.896 0.0336 -140.337 0.6005'' 0.5942'' 0.5879'' 14.9

Monoolefins, CjHio, M.W. 70.135:

7 1-Pentene +29.959 0.03801 -165.219 0.64563 0.64048 0.63531 1.37148 1.36835 126.2 126.1 15.45 19.0
S cis-2-Pentene 36.932 0.03830 -151.402 0.6607 0.6556 0.6504 1.3830 1.3798 130 130 16.8 18.3
9 (rans-2-Pentene 36.343 0.03824 -140.257 0.6534 0.6482 0.6431 1.3793 1.3761 132 132 16.42 18.3
10 2-Methyl-l-butene 31.154 0.03778 -137.572 0.6558 0.6504 0.6451 1.3778 1.3746 133 133 15.9
11 3-Methyl-l-butene 20.054 0.03721 -168.490 0.6326 0.6272 0.6219'' 1.3643 1.3611'' 128 128"' 13.8'
12 2-Methyl-2-butene 38.558 0.03844 -133.759 0.6676 0.6623 0.6570 1.3874 1.3842 135 135 17.14 12.8

Monoolefins, CeHi2, M.W. 84.162:

13 1-Hexene 63.475 0.04149 -139.832 0.67777 0.67315 0.66846 1.38788 1.38502 122.0 121.9 0.34 17.90 22.8
14 as-2-Hexene 68.883 0.04161 -141.152 0.69186 0.68718 0.68250 1.39761 1.39473 124.6 124.8 26.0
15 (rans-2-Hexene 67.875 0.04164 -132.979 0.68256 0.67793 0.67325 1.39363 1.39073 126.7 126.8 26.0
16 a's-3-Hexene 66.441 0.04162 -137.829 0.68450 0.67988 0.67520 1.39479 1.39189 130.0 129.7 27.0h
17 traws-3-Hexene 67.079 0.04140 -113.420 0.68197 0.67709 0.67231 1.39429 1.39137 128.8 129.0 27.0*
18 2-Methyl-l-pentene 62.103 0.04129 -135.730 0.68467 0.67985 0.67503 1.39200 1.38912 124.9 124.4
19 3-Methyl-l-pentene 54.168 0.04135 -153.0 0.67199 0.66743 0.66285 1.38422 1.38133 121.7 121.6
20 4-Methyl-l-pentene 53.856 0.04098 -153.64 0.66849 0.66368 0.65892 1.38267 1.37974 122.2 122.5
21 2-Methyl-2-pentene 67.299 0.04139 -135.080 0.69106 0.68648 0.68185 1.40030 1.39739 132.1 132.4
22 3-Methyl-«'s-2- pentene*" 67.694 0.04175 -134.850 0.69779 0.69319 0.68856 1.40157 1.39876 128.0 128.2
23 3-Methyl-tran$-2-pentenex 70.430 0.04171 -138.457 0.70210 0.69759 0.69300 1.40452 1.40166 128.4 128.3
24 4-Methyl-cis-2-pentene 56.377 0.04083 -134.421 0.67392 0.66916 0.66439 1.38793 1.38498 126.0 126.0
25 4-Methyl-(rans-2-pentene 58.602 0.04083 -140.803 0.67348 0.66860 0.66378 1.38878 1.38583 126.4 126.4
26 2-Ethyl-l-butene 64.672 0.04109 -131.537 0.69427 0.68956 0.68479 1.39671 1.39380 123.6 123.5
27 2,3-Dimethyl-l-butene 55.607 0.04090 -157.261 0.68291 0.67808 0.67323 1.39022 1.38729 125.6 125.7
28 3,3-Dimethyl-l-butene 41.238 0.04006 -115.22 0.65830 0.65308 0.64793 1.37620 1.37313 124.0 123.9
29 2,3-Dimethyl-2-butene 73.197 0.04193 -74.235 0.71269 0.70808 0.70345 1.41235 1.40952 132.9 133.2

Monoolefins, C7H„, M.W. 98.189:

30 1-Heptene 93.641 0.04447 -118.88e 0.70130 0.69696 0.69265 1.39980 1.39713 118.3 118.2 0.44 19.80 27.2
31 cis-2-Heptene 98.41 0.0456 0.7117 0.7071 0.7028 1.4069 1.4042 122 122
32 (rans-2-Heptene 97.95 0.0455 -109.466 0.7055 0.7012 0.6969 1.4045 1.4020 124 124
33 ct's-3-Heptene 95.75 0.0452 0.7071 0.7028 0.6985 1.4059 1.4033 122 122
34 (rans-3-Heptene 95.67 0.0451 -136.64 0.7024 0.6981 0.6938 1.4044 1.4017 124 124
35 2-Methyl-l-hexene 92.00 0.0445 -102.820 0.7073 0.7029 0.6985 1.4035 1.4008 121 121
36 3-Methyl-l-hexene 83.90 0.0432 0.6957 0.6914 0.6871 1.3965 1.3938 120 120
37 4-Methyl-l-hexene 86.73 0.0437 -141.46 0.7027 0.6985 0.6942 1.4000 1.3973 120 120
38 5-Methyl-l-hexene 85.31 ,0.0434 0.6964 0.6920 0.6877 1.3967 1.3940 120 120
39 2-Methyl-2-hexene 95.41 0.0451 -130.356 0.7125 0.7O81 0.7038 1.4106 1.4079 127 127
40 3-Methyl-cis-2-hexene 97.26 0.0454 -118.500 0.7200 0.7157 0.7114 1.4126 1.4100 127 127
41 3-MethyWrans-2-hexene 95.18 0.0451 -129.3 0.7186 0.7143 0.7100 1.4118 1.4091 127 127
42 4-Methyl-«'s-2-hexene 86.81-" "0.0436 0.7039 0.6995 0.6952 1.4026 1.3999 122 122
43 , 4-Methyl-(rans-2-hexene 87.56 0.0438 -125.692 0.7011 0.6968 0.6925 1.4025 1.3998 124 124
44 5-Methyl-cis-2-hexene 89.5 0.0441 0.705 0.7O2 0.697 1.404 1.401 122 122
45 5^Methyl-(ra«s-2-hexene 88.11 0.0439 -124.341 0.6970 0.6926 0.6883 1.4006 1.3979 124 124
46 2-Methyl-cts-3-hexene 86.0 0.0436 0.697 0.694 0.690 1.401 1.399 122 122
47 2-Methyl-*«ms-3-hexene 85.90 0.0435 -141.574 0.6939 0.6896 0.6853 1.4001 1.3974 124 124
48 3-Methyl-cis-3-hexene 95.400 0.04435 0.71794 0.71285 0.70793 1.41264 1.40995 127.4 127.1
49 3-Methyl-fra^s-3-hexene 93.540 0.04433 0.71426 0.70963 0.70504 1.41090 1.40820 126.8 127.4

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. — molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

44
 1C1.11
TABLE 1C1.11—Monoolefins and Diolefins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure"
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HsO (liquid)+ H20 (gas) +
pera- ume, (1 atmos) C02 (gas) COj (gas)
Pressure ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole c al per cal per cal per cal per kcal kcal State State kcal per kcal per
per cal per per cal per mole mole
deg- g, deg deg- g, deg cal per g cal per g
mole Cent mole Cent mole g mole g

49.66 9.21 0.129 10.41 0.3711 3.237 115.39 12.496 16.282 0

1
45.5 91.6 0.181 15.27 0.3629 25.7 0.611 4.402 104.62 4.879 14.990 0
2

39.7 146.4 0.240 20.47 0.3649 30.8 0.549 4.81 85.73 5.238 93.36 -0.01 -4.98 17.05 0
644.49 11 486 602.41 10 737 3
41.5 162.43 0.234 18.86 0.3362 30.15 0.5374 5.29 94.29 5.580 99.46 -1.65 -7.06 15.76 0 642.41 11 450 600.33 10 700 4
40.5 155.48 0.238 20.99 0.3741 30.49 0.5435 5.10 90.90 5.439 96.94 -2.65 -7.88 15.07 0
641.58 11 435 599.50 10 685 5
39.48 144.75 0.239 21.30 0.3796 31.3 0.558 4.92 87.7 5.286 94.22 -4.04 -9.11 13.88 0
640.36 11 413 598.28 10 663 6

40 191.63 0.305 26.19 0.3734 37.12 0.5293 6.088 86.81 6.022 85.87 -5.00 -11.14 18.82 18.72" 800.68 11 416 748.09 10 666 7
36 203 0.30 24.32 0.3468 36.-26 0.5170 6.41 91.4 6.24 89.0 -6.49 -12.96 17.43 17.18" 798.87 11 390 746.27 10 640 8
36 202 0.30 25.92 0.3696 37.52 0.5350 6.38 91.0 6.23 88.8 -7.59 -14.02 16.51 16.27" 797.81 11 375 745.22 10 626 9
34 192 0.31 26.69 0.3806 37.57 0.5357 6.181 88.14 6.094 86.90 -8.68 -14.92 15.68 15.55" 796.92 11 363 744.32 10 613 10
35 177 0.30 28.35 0.4042 37.30 0.5319 5.70 81.3 5.75 82.0 -6.92 -12.76 17.66 17.76" 799.07 11 393 746.47 10 643 11
34 197 0.32 25.10 0.3579 [Link] 0.5108 6.468 92.23 6.287 89.65 -10.17 -16.68 14.29 14.00" 795.15 11 337 742.55 10 587 12

31 230.88 0.37 31.63 0.3758 4S.81 0.5BOO 7.32 86.98 6.76 80.3 -9.92 -17.28 20.80 19.97 956.92 11 371 893.80 10 621 13
(SB.40) (B44) ([Link]) 30.04 0.3570 43 0.51 7.52 89.4 6.96 82.7 -12.49 -20.04 19.59 18.62 954.16 11 338 891.04 10 588 14
(SB.26) (B4S) ([Link]) 31.64 0.3760 44.5 0.529 7.54 89.6 6.91 82.1 -12.86 -20.43 19.10 18.16 953.77 11 333 890.65 10 583 15
([Link]) (m) (0.S51) 29.55 0.3511 44 0.52 7.47 88.8 6.86 81.5 -11.35 -18.85 19.97 19.06 955.35 11 352 892.23 10 602 16
(SB.40) (B44) ([Link]) 31.75 0.3773 44 0.52 7.54 89.6 6.92 82.2 -12.98 -20.55 19.51 18.58 953.65 11 332 890.53 10 582 17
32.41 0.3851 44.5 0.529 7.29 86.6 6.74 80.1 -14.16 -21.48 17.44 16.64 952.72 11 321 889.60 10 571 18
34.64 0.4116 44 0.52 6.83 81.2 6.43 76.4 -11.80 -18.66 19.46 18.84 955.54 11 354 892.42 10 604 19
30.23 0.3592 44 0.53 6.86 81.5 6.47 76.9 -12.22 -19.11 19.57 18.96 955.09 11 349 891.97 10 599 20
(SB.40) (H4) ([Link]) 30.26 0.3596 43 0.51 7.55 89.7 6.93 82.3 -15.96 -23.54 16.37 14.58 950.66 11 296 887.54 10 546 21
(SB.40) (m) ([Link]) 30.26 0.3596 43 0.51 7.49 89.00 6.89 81.87 -15.03 -22.55 17.16 16.24 951.65 11 308 888.53 10 558 22
([Link]) (B48) (0.351) 30.26 0.3596 43 0.51 7.67 91.14 7.00 83.18 -14.89 -22.59 17.68 16.68 951.61 11 308 888.49 10 558 23
31.92 0.3793 44 0.52 7.04 83.7 6.59 78.3 -13.70 -20.78 17.22 16.55 953.42 11 329 890.30 10 579 24
33.80 0.4016 44 0.52 7.16 85.1 6.68 79.4 -14.66 -21.86 17.50 16.77 952.34 11 316 889.22 10 566 25
31.92 0.3793 43 0.51 7.41 88.1 6.88 81.8 -13.36 -20.80 18.73 17.86 953.40 11 329 890.28 10 579 26
(SB.00) (BB8) (0.34S) 34.29 0.4075 44 0.52 6.97 82.8 6.55 77.8 -15.48 -22.49 17.13 16.48 951.71 11 309 888.59 10 559 27
(Sl.10) (sir) (0.343) 50.23 0.3592 45.1 0.536 6.36 75.6 6.13 72.8 -14.48 -20.89 17.53 17.19 953.31 11 328 890.19 10 578 28
([Link]) (BBl) (0.351) 50.48 0.3622 41.75 0.4961 7.776 92.40 7.083 84.17 -16.41 -20.22 16.65 15.58 949.98 11 288 886.86 10 538 29

28 260.14 0.44 37.10 0.3779 BOM 0.5158 8.52 86.8 7.43 75.7 -14.66 -23.19 22.95 21.46 1113.37 11 SS9 1039.14 10 589 30
50 0.51 8.6 87.6 7.4 75.4 -25.09 1111.49 11 321 1037.85 10 571 31
51.4 0.524 8.6 87.6 7.4 75.4 -26.09 1110.49 11 311 1036.85 10 560 32
50 0.51 8.5 86.6 7.4 75.4 -24.99 1111.59 11 322 1037.95 10 572 33
51 0.52 8.5 86.6 7.4 75.4 -25.99 1110.59 11 312 1036.95 10 562 34
51.2 0.522 8.4 85.6 7.4 75.4 -26.90 1109.68 11 302 1036.04 10 552 35
51 0.52 8.2 83.5 7.3 74.4 -24.16 1112.42 11 330 1038.78 10 580 36
51 0.52 8.3 84.5 7.3 74.4 -24.26 1112.32 11 329 1038.68 10 579 37
51 0.52 8.2 83.5 7.3 74.4 -24.80 1111.78 11 324 1038.14 10 574 38
50 0.51 8.5 86.6 7.4 75.4 -28.40 1108.18 11 287 1034.54 10 537 39
50 0.51 8.5 86.6 7.4 75.4 -27.76 1108.82 11 294 1035.18 10 543 40
50 0.51 8.5 86.6 7.4 75.4 -27.76 1108.82 11 294 1035.18 10 543 41
51 0.52 8.3 84.5 7.3 74.4 -25.86 1110.72 11 313 1037.08 10 563 42
51 0.52 8.3 84.5 7.3 74.4 -26.96 1109.72 11 303 1036.08 10 553 43
51 0.52 8.3 84.5 7.3 74.4 -26.50 1110.08 11 306 1036.44 10 556 44
51 0.52 8.3 84.5 7.3 74.4 -27.50 1109.08 11 296 1035.44 10 546 45
51 0.52 8.2 83.5 7.3 74.4 -26.40 1110.18 11 307 1036.54 10 557 46
51 0.52 8.2 83.5 7.3 74.4 -27.40 1109.18 11 297 1035.54 10 547 47
50 0.51 8.71 88.7 7.52 76.6 -18.99 -27.72 1108.84 11 B9S [Link] 10 543 48
50 0.51 8.56 87.2 7.45 75.9 -18.37 -26.95 1109.61 11 301 1035.98 10 SSI 49

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 !, for definitions of superscripts.

45
 1C1.11

TABLE 1C1.11—Monoolefins and Diolefins (Metric Units)

Refractive t Specific Kinematic

Density of the Liquid,0 Index of the Dispersion of Viscosity of
it g per cu cm Liquid," nD the Liquid," the Liquid,
dp 10« (.np-nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, _ Point of the Aniline
Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20 C 25 C 20 C 25 C 20 C 25 C C C per cm

Monoolefins, C7H14 (continued):

2-Ethyl-l-pentene 94.0 0.0449 0.712 0.708 0.704 1.405 1.402 125 125
3-Ethyl-l-pentene 84.11 0.0433 -127.484 0.7003 0.6960 0.6917 1.3982 1.3955 121 121
2,3-Dimethyl-l-pentene 84.28 0.0433 -134.31 0.7095 0.7052 0.7009 1.4033 1.4006 125 125
2,4-Dimethyl-l-pentene 81.604 0.04391 -124.061 0.69859 0.69408 0.68964 1.39852 1.39577 121.7 122.2
3,3-Dimethyl-l-pentene 77.47 0.0422 -134.389 0.7016 0.6974 0.6931 1.3984 1.3958 120 120
3,4-Dimethyl-l-pentene 80.79 0.0427 0.7019 0.6977 0.6934 1.3992 1.3965 120 120
4,4-Dimethyl-l-pentene 72.510 0.04361 0.68687 0.68247 0.67802 1.39172 1.38895 121.5 121.7
3-Ethyl-2-pentene 96.01 0.0452 0.7247 0.7204 0.7161 1.4148 1.4122 127 127
2,3-Dimethyl-2-pentene 97.40 0.0454 -118.27 0.7321 0.7277 0.7234 1.4211 1.4185 130 130
2,4-Dimethyl-2-pentene 83.295 0.04320 -127.704 0.69938 0.69490 0.69050 1.40371 1.40090 128.6 128.9
3,4-DimethyI-c*s-2-pentene 89.25 0.0441 -113.385 0.7178 0.7135 0.7092 1.4104 1.4078 127 127
3,4-Dimethyl-toms-2-pentane 91.50 0.0445 -124.236 0.7210 0.7167 0.7124 1.4128 1.4101 127 127
4,4-Dimethyl-cts-2-pentene 80.424 0.04416 -135.47 0.70370 0.69941 0.69508 1.40260 1.39989 123.5 124.2
4,4-Dimethyl-£rans-2-pentene 76.734 0.04277 -115.227 0.69347 0.68883 0.68428 1.39807 1.39525 123.2 123.6
3-Methyl-2-ethyl-l-butene 86.361 0.04392 0.71333 0.70876 0.70427 1.40518 1.40244 119.2 119.4
2,3,3-Trimethyl-l-butene 77.885 0.04398 -109.84 0.70899 0.70464 0.70022 1.40282 1.40007 119.6 120.1 35.2*

Monoolefins, CsHJe, M.W. 112.216:

1-Octene 121.288 0.04711 -101 0.71900 0.71490 0.71083 1.40870 1.40620 116.9 116 0.557 0 21.28
cis-2-Oetene 125.65 0.046 -100. 0.7285 0.7243 0.7201 1.4150 1.4125 118 118
(rans-2-Octene 125.0 0.046 -87 0.7240 0.7199 0.7157 1.4132 1.4107 120 120
ci'«-3-Octene 122.9 0.046 0.7244 0.721 0.717 1.4135 1.4111 119 119
(rans-3-Octene 123.3 0.046 -110 0.7194 0.7152 0.7110 1.4126 1.4102 121 121
cis-4-Octene 122.55 0.046 -118 0.7252 0.7212 0.7170 1.4148 1.4124 120 120
*rans-4-Octene 122.26 0.046 0.7183 0.7141 0.7099 1.4118 1.4093 122 122
2-Methyl-l-heptene 119.3 0.046 0.7245 0.7205 0.7164 1.4123 1.4098 122 122
3-Methyl-l-heptene 111 0.045 0.7149 0.711 0.707 1.406 404 117 117
4-Methyl-l-heptene 112.8 0.045 0.7213 0.717 0.713 1.410 1.408 117 117
5-Methyl-l-heptene 113.3 0.045 0.7205 0.7164 0.7122 1.4094 1.4069 117 117
6-Methyl-l-heptene 113.2 0.045 0.7160 0.7120 0.7079 1.4070 1.4045 117 117
2-Methyl-2-heptene 122.6 0.046 0.7282 0.7241 0.7200 1.4170 1.4145 124 124
3-Methyl-cis-2-heptene 122 0.046 0.7325 0.729 0.725 1.419 1.417 124 124
3-Methyl-<rctns-2-heptene 122 0.046 0.7325 0.729 0.725 1.419 1.417 124 124
4-Methyl-cts-2-heptene 114 0.045 0.7197 0.716 0.712 1.410 1.408 119 119
4-Methyl-(rans-2-heptene 114 0.045 0.7197 0.716 • 0.712 1.410 1.408 121 121
5-Methyl-cfs-2-heptene 118 0.046 0.7277 0.723 0.719 1.414 1.412 119 119
5-Methyl-(rams-2-heptene 118 0.046 0.7277 0.723 0.719 1.414 1.412 121 121
6-Methyl-cis-2-heptene 117 0.046 0.7212 0.718 0.714 1.412 1.410 119 119
6-Methyl-irans-2-heptene 117 0.046 0.7212 0.718 0.714 1.412 1.410 121 121
2-Methyl-c«-3-heptene 112 0.045 0.7101 0.706 0.702 1.407 1.405 119 119
2-MethyI-(rans-3-heptene 112 0.045 0.7101 0.706 0.702 1.407 1.405 121 121
3-Methyl-cis-3-heptene 121 0.046 0.7325 0.728 0.724 1.418 1.416 124 124
3-Methyl-toms-3-heptene 121 0.046 0.7325 0.728 0.724 1.418 1.416 124 124
4-MethyI-«s-3-heptene 122 0.046 0.7292 0.725 0.721 1.417 1.415 124 124
4-MethyWrcms-3-heptene 122 0.046 0.7292 0.725 0.721 1.417 1.415 124 124
5-Methyl-czs-3-heptene 112 0.045 0.7164 0.713 0.709 1.410 1.408 119 119
5-Methyl-*r<ms-3-heptene 112 0.045 0.7164 0.713 0.709 1.410 1.408 121 121
6-Methyl-ci's-3-heptene 115 0.045 0.7164 0.713 0.709 1.410 1.408 119 119
6-Methyl-£rcms-3-heptene 115 0.045 0.7164 0.713 0.709 1.410 1.408 121 121
2-Ethyl-l-hexene 120 0.046 0.7312 0.7270 0.7228 1.4157 1.4132 121 121
3-Ethyl-l-hexene 110.3 0.046 0.7197 0.715 0.711 1.407 1.405 117 117
4-Ethyl-l-hexene 113 0.046 0.7292 0.726 0.722 1.412 1.410 117 117

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2 M.W. = molecular weight.
3. See Appendix I, p. 61 t for definitions of superscripts.

46
 1C1.11

TABLE 1C1.11—Monoolefins and Diolefins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure*
per mole

Gas. Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HjO (liquid)+ H20 (gas) +
pera- ume, (1 atmos) C02 (gas) C02 (gas)
Pressure, ture, liter Gas, Liquid Gas, Liquid
atrnos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
g, deg cal per per cal per mole mole cal per g
de e- B, deg deg- per cal per g
mc le Cent mole Cent mole g mole g

50 0.51 8.4 85.6 7.4 75.4 -26.26 1110.30 11 308 1036.67 10 558 50
51 0.52 8.2 83.5 7.3 74.4 -23.54 1113.02 11 335 1039.39 10 585 51
50 0.51 8.2 83.5 7.3 74.4 -27.72 1108.84 11 293 1035.21 10 543 52
51 0.52 7.91 80.6 6.98 71.1 -20.04 -27.97 1108.59 // 290 1084.96 10 540 53
51 0.52 8.0 81.5 7.2 73.3 -26.17 1110.39 11 309 1036.76 10 559 54
51 0.52 8.1 82.5 7.2 73.3 -25.72 1110.84 11 313 1037.21 10 563 55
(28.20) (BSS) (0400) (37 j (0 38) 52 0.53 7.45 75.9 6.75 68.7 -18.96 -26.43 [Link] 11 806 1036.50 10 566 56
50 0.50 8.5 86.6 7.4 75.4 -27.14 1109.42 11 299 1035.79 10 549 57
(29.90) 283 (0.4O8) (88 ) (0 39) 49 0.50 8.5 86.6 7.4 75.4 -29.62 1106.94 11 273 1033.31 10 524 58
51 0.52 8.20 83.5 7.24 73.7 -21.20 -29.42 1107.14 11 276 1083.51 10 626 59
50 0.51 8.3 84.5 7.3 74.4 -29.22 1107.34 11 278 1033.71 10 528 60
50 0.51 8.4 85.6 7.4 75.4 -29.32 1107.24 11 277 1033.61 10 527 61
51 0.52 7.79 79.3 6.97 71.0 -17.36 -25.17 1111.39 11 819 1037.76 10 669 62
... 51 0.52 7.85 80.0 7.05 71.8 -21.24 -29.11 1107.45 11 279 1088.82 10 529 63
50 0.51 8.20 83.5 7.24 73.7 -19.04 -27.26 1109.80 11 297 1085.67 10 648 64
(18.60) 259 (0.400) (39 ) (0 40) 50 0.51 7.68 78.2 6.90 70.3 -20.43 -28.13 1108.43 11 289 1034.80 10 539 65

26 293.5 0.51 42 56 0.3793 57.65 0.5138 9.70 86.4 8.07 71.9 -19.41 -29.11 25.37 22.92 1269.88 11 316 1185.67 10 666 66
(27.40) (S08) (0.464) (43 ) (0.39) 57 0.51 9.6 85.6 8.24 73.4 (mi.2) (11 329) (1187.0) (10 679) 67
([Link]) (S07) (0.464) (45 ) (0.40) 58.3 0.520 9.6 85.6 8.22 73.3 (1270.5) (ll 328) (1186.4) (10 573) 68
57 0.51 9.5 84.7 8.20 73.1 69
(27.10) (sos) (0.404) (43 ) . (0.39) 58 0.52 9.6 85.6 8.20 73.1 (mo.6) (it S24) (1186.4) (10 678) 70
(i7.00) (SOi) (0.464) (43 ) (0.38) 57 0.51 9.5 84.7 8.19 73.0 (1271. i) (11 329) (1187.0) (10 679) 71
(27.00) (304) (0.464) (43 ) (0.89) 58 0.52 9.5 84.7 8.18 73.0 (1270.0) (ll 818) (1185.8) (10 568) 72
($6.80) ($00) (O.464) (45 ) (0-40) 57.9 0.516 9.4 83.8 8.11 72.3 (1267.7) (ll 297) (1183.5) (10 547) 73
58 0.52 9.2 82.0 8.01 71.4 74
58 0.52 9.3 82.9 8.04 71.7 75
57 0.51 9.3 82.9 8.04 71.7 76
58 0.52 9.3 82.9 8.04 71.7 77
57 0.51 9.5 84.7 8.16 72.7 78
57 0.51 9.5 84.7 8.15 72.6 79
... 57 0.51 9.5 84.7 8.17 72.8 80
58 0.51 9.3 82.9 8.05 71.7 81
58 0.51 9.3 82.9 8.05 71.7 82
57 0.51 9.4 83.8 8.11 72.3 83
57 0.51 9.4 83.8 8.11 72.3 84
58 0.51 9.4 83.8 8.09 72.1 85
58 0.51 9.4 83.8 8.09 72.1 86
58 0.52 9.3 82.9 8.02 71.5 87
58 0.52 9.3 82.9 8.03 71.6 88
57 0.51 9.5 84.7 8.14 72.6 89
57 0.51 9.5 84.7 8.14 72.5 90
57 0.51 9.5 84.7 8.15 72.6 91
57 0.51 9.5 84.7 8.15 72.6 92
58 0.52 9.3 82.9 8.02 71.5 93
58 0.52 9.3 82.9 8.02 71.5 94
58 0.52 9.3 82.9 8.06 71.8 95
58 0.52 9.3 82.9 8.05 71.7 96
57 0.51 9.5 84.7 8.12 72.4 97
58 0.52 9.2 82.0 8.00 71.3 98
57 0.51 9.3 82.9 8.03 71.6 99

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p.'. 61', for definitions of superscripts.

47
 [Link]
TABLE 1C1.11—Monoolefins and Diolefins (Metric Units)

Refractive t Specific Kinematic

Density of the Liquid,*1 Index of the Dispersion of Viscosity of
1L g per ou cm Liquid,11 no the Liquid,a the Liquid,
dp 10* (nj— nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, . Point of the Aniline
No. Compound Point at deg in Air at Liquid0 Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at c, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20 C 25 C 20 C 25 C 20 C 25 C C C per cm

Monoolefins* CsHie (continued):

100 2,3-Dimethy 1-1-hexene 110.5 0.046 0.7257 0.7214 0.7172 1.4113 1.4089 122 122
101 2,4-Dimethyl-l-hexene 111.2 0.046 0.726 0.720 0.716 1.411 1.409 122 122
102 2,5-Dimethyl-l-hexene 111.6 0.046 0.7215 0.7172 0.7129 1.4105 1.4080 122 122
103 3,3-DimethyI-l-hexene 104 0.046 0.7181 0.7140 0.7099 1.4070 1.4046 117 117
104 3,4-Dimethy I-1-hexene 112 0.046 0.728 0.724 0.720 1.413 1.411 117 117
105 3,5-Dimethyl-l-hexene 104 0.045 0.712 0.708 0.704 1.404 1.402 117 117
106 4,4-Dimethyl-l-hexene 107.2 0.046 0.7239 0.7198 0.7157 1.4102 1.4078 117 117
107 4,5-Dimethyl-l-hexene 109 0.046 0.732 0.728 0.724 1.414 1.412 117 117
108 5,5-Dimethyl-l-hexene 102.5 0.047 0.713 0.709 0.705 1.4049 1.4024 117 117
109 3-Ethyl-ct's-2-hexene 121 0.046 0.740 0.737 0.733 1.424 1.422 124 124
110 3-EthyI-£rans-2-hexene 121 0.046 0.740 0.737 0.733 1.424 1.422 124 124
111 4-Ethyl-ci's-2-hexene 113 0.046 0.732 0.725 0.721 1.412 1.410 119 119
112 4-Ethyl-*«ms-2-hexene 113 0.046 0.732 0.725 0.721 1.412 1.410 121 121
113 2,3-Dimethyl-2-hexene 121.78 0.046 -115.1 0.7450 0.7408 0.7366 1.4268 1.4244 127 127
114 2,4-Dimethyl-2-hexene 110.6 0.047 0.7255 0.7213 0.7171 1.4118 1.4094 124 124
115 2,5-Dimethyl-2-hexene 112.2 0.045 0.724 0.720 0.716 1.4140 1.4115 124 124
116 3,4-Dimethyl-cts-2-hexene 116 0.046 0.740 0.737 0.733 1.418 1.416 124 124
117 3,4-Dimethyl-(rans-2-hexene 116 0.046 0.740 0.737 0.733 1.418 1.416 124 124
118 3,5-Dimethyl-cis-2-hexene 112 0.045 0.729 0.725 0.721 1.416 1.414 124 124
119 3,5-Dimethyl-irans-2-hexene ' 112 0.045 0.729 0.725 0.721 1.416 1.414 124 124
120 4,4-DimethyI-cis-2-hexene 106 0.046 0.726 0.722 0.718 1.413 1.411 119 119
121 4,4-Dimethyl-*r<ms-2-hexene 106 0.046 0.726 0.725 0.718 1.413 1.411 121 121
122 4,5-Dimethyl-ctV2-hexene 110 0.046 0.729 0.725 0.721 1.413 1.411 119 119
123 4,5-Dimethyl-(rans-2-hexene 110 0.046 0.729 0.725 0.721 1.413 1.411 121 121
124 5,5-Dimethyl-as-2-hexene 106.9 0.047 0.7213 0.7169 0.7125 1.4113 1.4088 119 119
125 5,5-Dimethyl-f«ms-2-hexene 104.1 0.046 0.7109 0.7066 0.7023 1.4055 1.4030 121 121
126 3-EthyI-3-hexene 116 0.046 0.732 0.729 0.725 1.418 1.416 124 124
127 2,2-Dimethyl-cis-3-hexene 105.43 0.045 -137.361 0.7170 0.7128 0.7086 1.4099 1.4074 119 119
128 2,2-Dimethyl-(rans-3-hexene 100.85 0.045 0.7084 0.7039 0.6995 1.4063 1.4037 121 121
129 2,3-Dimethyl-c?s-3-hexene 114 0.046 0.732 0.728 0.724 1.416 1.414 124 124
130 2,3-Dimethyl-£rans-3-hexene 114 0.046 0.732 0.728 0.724 1.416 1.414 124 124
131 2,4-DimethyI-ct's-3-hexene 109.0 0.045 0.7221 0.7178 0.7135 1.4140 1.4114 124 124
132 2,4-Dimethyl-ircms-3-hexene 107.6 0.046 0.7190 0.7145 0.7101 1.4126 1.4101
133 2,5-DimethyI-cis-3-hexene 102 0.045 0.713 0.710 0.706 1.406 1.404 119 119
134 2,5-Dimethyl-ira«s-3-hexene 102 0.045 0.713 0.710 0.706 1.406 1.404 121 121
135 3,4-Dimethy l-cis-3-hexene 122 0.046 0.752 0.747 0.743 1.430 1.428 127 127
136 3,4-Dimethyl-(rans-3-hexene 122 0.046 0.752 0.747 0.743 1.430 1.428 127 127
137 2-n-Propyl-l-pentene 117.7 0.046 0.7282 0.7240 0.7198 1.4136 1.4111 123 123
138 2-Isopropyl-l-pentene 113 0.046 0.729 0.725 0.721 1.414 1.412 122 122
139 3-Methyl-2-ethyl-l-pentene 112.5 0.046 0.732 0.729 0.725 1.4142 1.4118 122 122
140 4-Methyl-2-ethyl-l-pentene 110.3 0.046 0.7237 0.7195 0.7152 1.4105 1.4080 122 122
141 2-Methyl-3-ethyl-l-pentene 110 0.046 0.734 0.730 0.726 1.415 1.413 122 122
142 3-Methyl-3-ethyl-l-pentene 112 0.047 0.7346 0.7305 0.7264 1.418 1.416 117 117
143 4-Methyl-3-ethyl-l-pentene 107.5 0.047 0.7242 0.7200 0.7158 1.4097 1.4072 117 117
144 2,3,3-Trimethyl-l-pentene 108.31 0.047 -69 0.7396 0.7352 0.7308 1.4174 1.4151 122 122
145 2,3,4-Trimethy 1-1-pentene 108 0.046 0.732 0.729 0.725 1.415 1.413 122 122
146 2,4,4-Trimethyl-l-pentene 101.44 0.046 -93.453 0.7192 0.7150 0.7108 1.4086 1.4060 122 122
147 3,3,4-Trimethyl-l-pentene 105 0.047 0.732 0.729 0.725 1.4144 1.4120 117 117
148 3,4,4-Trimethy I-1-pentene 104 0.046 0.723 0.719 0.715 1.412 1.410 117 117
149 2-Methyl-3-ethyl-2-pentene 117.0 0.046 0.744 0.739 0.735 1.4247 1.4222 127 127
150 4-Methyl-3-ethyl-m-2-pentene 116 0.047 0.744 0.739 0.735 1.424 1.422 124 124
151 4-Methyl-3-ethyl-ir<ms-2-pentene 114.3 0.047 0.7391 0.7350 0.7308 1.4210 1.4183 124 124
152 2,3,4-Trimethyl-2-pentene 116.27 0.046 -113.3 0.7477 0.7434 0.7391 1.4275 1.4249 127 127
153 2,4,4-Trimethyl-2-pentene 104.91 0.047 -106.314 0.7259 0.7218 0.7176 1.4160 1.4135 125 125 32.2
154 3,4,4-Trimethyl-cis-2-pentene 112 0.046 0.744 0.739 0.735 1.423 1.421 124 124
155 3,4,4-Trimethyl-fra7is-2-pentene 112 0.046 0.744 0.739 0.735 1.423 1.421 124 124
156 3-Methyl-2-isopropyl-l-butene 104 0.046 0.726 0.722 0.718 1.4085 1.4061 122 122
157 3,3-Dimethyl-2-ethyl-l-butene 110 0.046 0.732 0.728 0.724 1.4159 1.4135 122 122

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64..
2. M.W. = molecular weight.
3. See Appendix I, p. 61., for definitions of superscripts.

48
 1C1.11
TABLE 1C1.11—Moiioolefins and Diolefins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure"
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HjO (liquid) + HjO (gas) +
pera- ume, (1 atmos) C02 (gas) C02 (gas)
Pressure ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole ciil per cal per cal per cal per kcal
cal per
kcal
cal per State State kcal per kcal per
ieg- g, deg deg- g, deg per per mole cal per g mole cal per g
1nole Cent mole Cent mole g mole g

57 0.51 9.2 82.0 7.99 71.2 100

57 0.51 9.2 82.0 8.01 71.4 101
58 0.51 9.3 82.9 8.01 71.4 102
58 0.51 9.1 81.1 7.90 70.4 103
57 0.51 9.3 82.9 8.01 71.4 104
58 0.52 9.1 81.1 7.89 70.3 105
57 0.51 9.1 81.1 7.95 70.9 106
57 0.51 9.2 82.0 7.97 71.0 107
58 0.52 9.0 80.2 7.88 70.2 108
56 0.50 9.5 84.7 8.14 72.5 109
56 0.50 9.5 84.7 8.14 72.5 110
57 0.51 9.3 82.9 8.03 71.6 111
57 0.51 9.3 82.9 8.03 71.6 112
(27.00) (.m) (o.m) ( <«) (0' i') 56 0.50 9.5 84.7 8.12 72.4 (1265.1) (ll 274) (1180.9) (10 524) 113
57 0.51 9.2 82.0 8.00 71.3 114
57 0.51 9.3 82.9 8.04 71.7 115
56 0.50 9.4 83.8 8.07 71.9 116
56 0.50 9.4 83.8 8.07 71.9 117
57 0.51 9.3 82.9 7.99 71.2 118
57 0.51 9.3 82.9 7.99 71.2 119
57 0.51 9.1 81.1 7.92 70.6 120
57 0.51 9.1 81.1 7.92 70.6 121
57 0.51 9.2 82.0 7.99 71.2 122
57 0.51 9.2 82.0 7.99 71.2 123
58 0.51 9.1 81.1 7.94 70.8 124
58 0.52 9.1 81.1 7.89 70.3 125
57 0.51 9.4 83.8 8.07 71.9 126
58 0.52 8.9 79.3 7.68 68.4 -30.21 1268.72 11 806 1184.56 10 556 127
58 0.52 8.9 79.3 7.74 69.0 -34.65 1264.28 11 268 1180.13 10 516 128
57 0.51 9.3 82.9 8.04 71.7 129
57 0.51 9.3 82.9 8.04 71.7 130
58 0.51 9.2 82.0 7.98 71.1 131
58 0.51 9.2 82.0 7.95 70.9 132
58 0.52 8.9 79.3 7.83 69.8 133
58 0.52 9.0 80.2 7.88 70.2 134
56 0.50 9.5 84.7 8.13 72.5 135
56 0.50 9.5 84.7 8.13 72.5 136
57 0.51 9.4 83.8 8.10 72.2 137
57 0.51 9.3 82.9 8.01 71.4 138
57 0.51 9.3 82.9 8.02 71.5 139
57 0.51 9.2 82.0 7.99 71.2 140
57 0.51 9.0 80.2 7.82 69.7 -32.92 1286.01 11 282 1181.86 10 529 141
57 0.51 9.3 82.9 8.01 71.4 142
57 0.51 9.2 82.0 7.95 70.9 143
(26.51) (296) (0.457) 0,$) (o\w) 57 0.51 9.2 82.0 7.96 70.9 (1266.2) (ll 284) (1182.0) (10 5S4) 144
57 0.51 9.2 82.0 7.96 70.9 145
(26.10) (m) (o.m) 0tS) (0..») 57.0 0.508 8.5 75.8 7.50 66.8 -34.81 1264-12 11 265 1179.97 10 515 146
57 0.51 9.1 81.1 7.91 70.5 147
57 0.51 9.1 81.1 7.90 70.4 148
56 0.50 9.4 83.8 8.09 72.1 149
56 0.50 9.4 83.8 8.07 71.9 150
57 0.50 9.3 82.9 8.05 71.7 151
56 0.50 9.4 83.8 8.08 72.0 152
(26.20) (290) ([Link]) Q s) (O.i 8) 57.3 0.511 8.9 79.3 7.79 69.4 -34.04 1264.89 It 272 1180.74 10 522 153
56 0.50 9.3 82.9 8.02 71.5 154
56 0.50 9.3 82.9 8.01 71.4 155
57 0.51 9.1 81.1 7.90 70.4 156
57 0.51 9.2 82.0 7.99 71.2 157

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

49
 1C1.11

TABLE 1C1.11—Monoolefins and Diolefins (Metric Units)

Refractive _ Specific Kinematic

Density of the Liquid,1 Index of1 the Dispersion of Viscosity of
dl g per cu cm Liquid," no the Liquid,'" the Liquid,
dp 10' (,nF-nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, _ Point of the Aniline
No. Compound Point at den in Air at Liquid0 Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20C 25 C 20C 25 C 20C 25 C C C per cm

Monoolefins, CgHis, M.W. 126.243:

188 1-Nonene 146.887 0.04944 -81.34 0.73311 0.72920 0.72529 1.41572 1.41333 114.5 114.4 0.704 0.429 22.56 38.0
159 2-Methyl-l-octene 144.67 0.049 -77.65 0.7381 0.7340 0.7299 1.4186 1.4162 116 116
160 2,3-Dimethyl-2-heptene 145.2 -108.5 0.739 0.735 0.731 1.4319

Monoolefins, CIOHM, M.W. 140.270:

161 1-Decene 170.599 0.05157 -66.276 0.74465 0.74079 0.73691 1.42146 1.41913 113.0 112.9 0.877 0.505 23.54
162 2-Methyl-l -nonene 168.4 0.051 -64.20 0.7490 0.7451 0.7412 1.4241 1.4217 115 115

Diolefins, CaHi, M.W. 40.065:

163 Propadiene (allene) -34.5 0.033 -136.3 0.6575"

Diolefins, C(H6, M.W. 54.092:

164 1,2-Butadiene + 10.85 0.0351 -136.201 0.657"* 0.652'* 0.646"*
166 1,3-Butadiene -4.411 0.03377 -108.902 0.6274"* 0.6211"* 0.6149"*

Diolefins, CsHs, M.W. 68.119:

166 1,2-Pentadiene +44.846 0.03867 -137.27 0.69753 0.69255 0.68758 1.42091 1.41773 164.7 164.6
167 1 ,cis-3-Pentadiene 44.058 0.03875 -140.833 0.69609 0.69100 0.68590 1.43634 1.43291 243.9 243.8
168 1, (rans-3-Pentadiene 42.022 0.03879 -87.440 0.68104 0.67601 0.67100 1.43008 1.42669 245.8 245.7
169 1,4-Pentadiene 25.959 0.03720 -148.289 0.66582 0.66074 0.65569 1.38876 1.38542 153.2 153.1
170 2,3-Pentadiene 48.255 0.03871 -125.652 0.70010 0.69500 0.68998 1.42842 1.42509 174.6 174.5
171 3-Methyl-l, 2-butadiene 40.827 0.03826 -113.615 0.69146 0.68605 0.68062 1.42026 1.41692 171.7 171.8
172 2-Methyl-l,3-butadiene (isoprene) 34.057 0.03818 -145.964 0.68602 0.68093 0.67585 1.42194 1.41852 224.9 224.8

Diolefins, CtHio, M.W. 82.146:

173 1,2-Hexadiene 76 0.044 0.7196 0.7149 0.7102 1.4282 1.4252
174 1 ,m-3-Hexadiene 7S.07 0.043 0.7125 0.7079 9.7083 1.4410 1.4379 225 225
175 1, rtnms-3-Hexadiene 7S.19 0.043 -102 4 0.7085 0.7039 0.6993 1.4406 1.4375 225 225
176 l,cis-4-Hexadiene 66.3 0.042 0.704 0.700 0.695 I.4O49 1.4018
177 1, /raws-4-Hexadiene 65.0 0.042 -138 7 0.704 0.700 0.695 1.4104 1.4073
178 1,5-Hexadiene 59.45 0.042 -140 693 0.6969 0.6923 0.6878 1.4042 1.4010
179 2,3-Hexadiene 68.0 0.043 0.685 0.680 0.675 1.395 1.392
180 cis-2, cis-4-Hexadiene 84.93 0.044 -69 34 0.7390 0.7344 0.7298 1.4606 1.4575 225 225
181 cis-2, *rans-4-Hexadiene 83.47 0.044 -96 1 0.7275 0:7229 0.7183 1.4560 t.4529 225 225
182 trans-2, transA- Hexadiene 82.17 0.044 -44 9 0.7193 0.7147 1.7101 1.4510 1.4479 225 225
183 3-Methyl-l ,2-pentadiene 70 0.043 0.720 0.715 0.710 1.425 1.422
184 4-Methyl-l ,2-pentadiene 70 0.043 0.713 0.708 0.7O3 1.424 1.421
185 2-Methyl-l, cts-3-pentadiene 76 0.044 0.725 0.719 0.714 1.446 1.443 225 225
186 2-Methyl-l, irans-3-pentadiene 75.66 0.044 -117 551 0.725 0.719 0.714 1.4448 .4422
187 3-Methyl-l, cts-3-pentadiene 77 0.044 0.741 0.735 0.730 1.452 1.449 225 225
188 3-Methyl-l, *r<ms-3-pentadiene 77 0.044 0.741 0.735 0.73O 1.452 1.449 225 225
189 4-Methyl-l, 3-pentadiene 76.98 0.044 -125 91 0.725 0.719 0.714 1.4534 .4503 225 225
190 2-Methyl-l, 4-pentadiene 56 0.041 0.699 0.694 0.689 1.405 1.402
191 3-Methyl-l, 4-pentadiene 55 0.041 0.700 0.695 0.69O 1.405 1.402
192 2-Methyl-2,3-pentadiene 72 0.043 0.716 0.711 0.7O6 1.425 1.422
193 2-Ethyl-l, 3-butadiene 75 0.044 0.721 0.717 0.712 1.445 1.442 225 225
194 2,3-Dimethyl-l,3-butadiene 68.77 0.043 -76 039 0.7312 0.7267 0.7222 1.4394 .4362 225 225

Diolefins, CjHu, M.W. 96.173:

195 2-Methyl-l, 5-hexadiene 88.1 -128.8 0.7244 0.7198 0.7153
196 2-Methyl-2,4-hexadiene 111.5 -74.6 0.7488 0.7449 0.7411
197 2,4-Di methyl-1,3-pentadiene 93.2 -114.0 0.7407 0.7368 0.7329

Diolefins, C8Hi4, M.W. 110.200:

198 2,6-Octadiene (dicrotyl) 124.5 -76.0 0.7484 0.7445 0.74O6
199 3-Methyl-l, 5-heptadiene 111.0 -57.0 0.7333 0.7291 0.725O
200 2,5-Dimethyl-l,5-hexadiene 114.3 -75.6 0.7462 0.7423 0.7S84
201 2,5-Dimethyl-2,4-hexadiene 134.5 + 13.94 0.7653 0.7615 0.7577

Diolefins, C9Hi6, M.W. 124.227:

202 2,6-Dimethyl-l, 5-heptadiene 143 -70.0 0.7721 0.7684 0.7648
203 2-Methyl-3-ethy 1-1,5-hexadiene 145 -70.0 0.7665 0.7629 1.7594

Diolefins, CioHis, M.W. 138.254:

204 3,7-Dimethyl-l,6-octadiene 161 -70.0 0.7618 0.7580 1.7542

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.
50
 1C1.11

TABLE 1C1.11—Monoolefins and Diolefins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure"
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HjO (liquid)+ H20 (gas)-l-
pera- ume, (1 atmos) C02 (gas) COj (gas)
ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal
cal per
kcal
cal per State State kcal per kcal per
deg- g, deg deg- g, deg per per mole cal per g mole cal per g
mole Cent mole Cent mole g mole B

23 319 0.58 48.03 0.3805 64.7 0.512 10.88 86.18 8.68 68.8 -24.70 -35.58 27.01 23.84 1425.70 11 294 1331.02 10 544 158
64.8 0.513 159
($4.60) (S$8) (0.5$l) (so) (0.40) (64) (0.61) (7.79) (61.7) (14$3.8) (11 $79) (1S$9.$) (10 5$9) 160

22 342 0.65 53.49 0.3814 71.78 0.5118 12.06 85.98 9.24 65.9 -29.48 -41.54 29.17 25.31 168$.1$ 11 $79 1476.93 10 6$9 161
71.6 0.510 162

(54.0) 120 (0.16$) 14.10 0.3520 (4.85) (m) 45.92 48.37 (46l)"-° (11 610)" (440)"-° (10 980)" 163

(44-4) (171) (0.$19) 19.15 0.3540 29.78 0.5506 5.71 105.6 (6-44) (101) 38.78 32.78 47.43 614.13" 11 353 582.58 10 770 164
42.7 152 0.221 19.01 0.3515 28.10 0.5195 5.03 93.0 (6. $3) (97) 26.34 21.17 36.01 602.32" 11 135 570.76 10 552 165

(40.$) ($30) (0.$76) 25.2 0.370 SO.05 0.5Z9S 6.85 100.5 (6.06) (ss.9) 33.62 26.74 49.11 48.55 770. $6° 11 S07 718.18 10.690 166
(S9.6) ($$6) (0.$76) 22.6 0.332 35.034 0.514S4 6.77 99.3 (6.06) (88.9) 19.78 12.97 35.96 35.61 756.48° 11 105 714.41 10 488 167
(S9.4) ($$s) (o.m) 24.7 0.363 35.68 0.6$88 6.64 97.4 (5.98) (87.8) 18.12 11.44 34.57 34.52 754.95° 11 08S 71$.88 10 465 168
(sr.i) ($04) (0.$76) 25.1 0.369 36.09 0.516$ 6.01 88.1 (5.63) (81.1) 25.42 19.33 40.91 40.86 76$.84° 11 198 7$0.76 10 581 169
24.2 0.355 36.414 0.63460 7.05 103.4 31.80 24.72 47.92 47.07 768.$3° 11 $78 7$6.16 10 660 170
(S9.4) ($$s) (o.m) 25.2 0.370 S6.43 0.5348 6.68 98.0 (5.91) (86.7) 30.92 24.19 47.39 46.93 767.70° 11 $70 7$5.6$ 10 66$ 171
(S8.00) ($11) (o.m) 25.0 0.367 36.101 0.63001 6.32 92.7 (5.79) (85.1) 18.10 11.72 34.87 34.72 755. $4° 11 087 713.16 10 469 172

173
174
175
176
177
(34.00) ($48) ([Link]) ($8) (0.34) Us) (0.6$) (6.1$) (74.6) (9$0.0) (ll $00) (867.4) (10 660) 178
179
180
181
182
183
184
185
186
187
188
(35.00) ($65) ([Link]) ($9.6) (0.36) (46) (0.65) (6.6$) (80.6) (91$.0) (11 103) (859.4) (10 463) 189
190
191
192
193
(S4.90) (m) ([Link]) («) (0.S8) (48) (0.59) (6-44) (78.4) (908.6) (it 061) (855.9) (10 420) 194

(s$.w) ($80) (0.S90) (38.6) (0.40) (58) (0.69) (6.68) (69.5) (1073.8) (ll 166) (lOW.6) (10 509) 195
(33.70) (309) (0.390) (S6.5) [0.37) («) (0.64) (7.3$) (76.$) (1067.1) (ll 097) (1004-0) (10 440) 196
($9.00) ($16) (0.S90) (36.6) (0.88) (U) (0.66) (8.0$) (83.4) (106$.l) (it 045) (999.0) (10 388) 197

($[Link]) [319) (0.476) (38.6) (0.35) (S3) (0.48) (6.56) (69.6) (l$S$.S) (11 18S) (1158.7) (10 616) 198
($7.60) (sw) (0.44s) (S8.5) (0.36) (0.49) (6.9$) (6$.8) (l$S$.6) (11 186) (1158.9) (W 517) 199
($7.60) (S10.6) (0-461) (4$) [0.38) («) (0.53) (6.98) (63.4) (im.i) (ll 090) (1148.4) (10 4$$) 200
($8.80) (S$9) (0.455) (4$) (0.S8) (58) (0.53) (7.66) (69.5) (i$$o.o) (ll 071) (U46.S) (10 4OS) 201

($6.54) (344) (0.504) (48) [0.39) (63) (0.61) (7.6S) (60.6) (1S8S.4) (ll 136) (l$99.$) (10 469) 202
($6.10) (349) (0.500) (46) (0.86) (60) (O.48) (7.5S) (60.6) (1888.9) (11 181) (lS04.7) (10 604) 203

($5.10) (367) (0.557) (6$.5) (0.S8) (66) (O.48) (7.9$) (67.3) ... (154s.7) (ll 166) (1449.0) (10 481) 204

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. ;M.W. — molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts. 51
 TCI .12

TABLE 1C1.12—Cycloolefins (Metric Units)

Refractive # Specific Kinematic

at Density of the Liquid," Index of the Dispersion of Viscosity of
g per cu cm Liquid," 71.D the Liquid," the Liquid,
dp 10' (nr-nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, Point of the Aniline
No. Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20 C 25 C 20C 25 C 20C 25 C C C per cm

Alkylcyclopentenes, CsHa, M.W. 68.119:

1 Cyclopentene 44.232 0.03928 -135.082 0.77750 0.77197 0.76651 1.42246 1.41940 118.7 118.7 <-10

Alkylcyclopentenes, CsHio, M.W. 82.146:

2 l-Methylcyclopentene 75.48 0.0431 -126.527 0.7842 0.7795 0.7748 1.4322 1.4294 124 124 -7.0
3 3-Methylcyclopentene 64.90 0.0418 0.7673 0.7622 0.7572 1.4210 1.4184 119 119
4 4-MethylcycIopentene 65.66 0.042 -160.85 0.7735 0.7684 0.7634 1.4209 1.4184

Alkylcyclopentenes, C7H12, M.W. 96.173:

5 1-Ethylcyclopentene 106.33 0.0467 -118.47 0.8028 0.7982 0.7936 1.4412 1.4387 119 119 + 1.2
6 3-Ethylcyclopentene 97.77 0.0458 0.7877 0.7830 0.7784 1.4315 1.4291
7 4-Ethylcyclopentene 98.2 0.046 0.789 0.783 0.778 1.431 1.429
8 1,2-DimethylcycIopentene 105.8 0.0467 -90.4 0.8024 0.7976 0.7928 1.4448 1.4420 125.8 125.8
9 1,3-Dimethylcyclopentene 92 0.045 0.771 0.766 0.761 1.428 1.425
10 1,4-DimethyIcyclopentene 93.2 0.046 0.7764 0.7714 0.7664 1.4283 1.4255
11 1,5-Dimethylcyclopentene 102 0.046 -118 0.784 0.780 0.775 1.4331 1.4304 120.8 120.8
12 3,3-Dimethylcy clopentene 88 0.045 0.776 0.771 0.766 1.423 1.420
13 3, cis-4-Dimethylcy clopentene 0.782 0.777 0.772 1.4300 1.4272
14 3, (rarcs-4-Dimethylcyclopentene
15 3,czs-5-Dimethylcyclopentene
16 3, (rans-5-Dimethylcyclopentene
17 4,4-Dimethylcyclopentene 88 0.045 0.776 0.771 0.766 1.423 1.420

Alkylcyclopentenes, Cs to Go:
18 1-n-Propylcyclopentene, C8Hi4, M.W. 110.200 131.2 0.048 0.8059 0.8018 0.7978 1.4452 1.4428 14.2
19 1-m-Butylcyclopentene, CHis, M.W. 124.227 156 0.051 0.8112 0.8073 0.8035 1.4486 1.4463 25.0
20 1-re-Pentylcyclopentene, CwHis, M.W. 138.254 179 0.053 0.8161 0.8123 0.8085 1.4516 1.4494

Alkylcycloheienes, CeHio, M.W. 82.146:

21 Cyclohexene 82.974 0.04381 -103.493 0.81572 0.81094 0.80607 1.44654 1.44377 117.2 117.1 -20.0

Alkylcycloheienes, C7H12, M.W. 96.173:

22 1-Methylcyclohexene 110.300 0.04665 -120.397 0.8163 0.81146 0.80658 1.45046 1.44784 119.3 120.0
23 3-MethylcycIohexene 102.47 0.0463 -123.5 0.8054 0.8010 0.7966 1.4435 1.4410
24 4-Methylcyclohexene 102.74 0.0461 -115.4 0.8035 0.7991 0.7947 1.4414 1.4389

Alkylcycloheienes. CsHu, M.W. 110.200:

25 1-Ethylcyclohexene 137.006 0.04915 -109.947 0.8276 0.82212 0.81765 1.45668 1.45437 117.3 117.0
26 3-Ethylcyclohexene 131.6 0.0500 0.8059 0.8104 0.8059 1.4500 1.4476
27 4-Ethylcyclohexene 133 0.049 0.814 0.810 0.806 1.449 1.447
28 1,2-Dimethylcyclohexene 137.99 0.0500 -84.113 0.8302 0.8262 0.8220 1.4620 1.4594 123 123
29 1,3-Dimethylcyclohexene 127 0.050 0.807 0.803 0.799 1.449 1.447 120 120
30 1,4-DimethyIcyclohexene 128 0.049 -59 0.806 0.802 0.798 1.446 1.444 119 119
31 1,5-Dimetbylcyclohexene 128 0.049 0.8092 0.8051 0.8009 1.450 1.448 119 119
32 1,6-Dimethylcyclohexene 131 0.049 0.819 0.815 0.811 1.456 1.453
33 3,3-Dimethylcyclohexene 119 0.048 0.808 0.804 0.800 1.445 1.443
34 4,4-Dimethylcyclohexene 117.25 0.0477 -74.44 0.805 0.8008 0.7968 1.4418 1.4394 115 115

Alkylcycloheienes, Cs and C10:

35 1-n-Propylcyclohexene, CDHH, M.W. 124.227
36 1-n-Butylcyclohexene, CioHis, M.W. 138.254

37 4-Vinylcyclohexene, C8Hi2, M.W. 108.184 m.o -10S.9S 0.834 0.8S0S 0.886 I.464I ...
38 1,5-Cyclooctadiene, CSHK, M.W. 108.184 160.0 -66.1,06 0.886 0.88SS 0.880 1.49SS ...

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 . for definitions of superscripts.

52
 1C1.12
TABLE 1C1.12—Cycloolefins (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure0
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point H2O (liquid)+ H20 (gas)-r-
pera- ume, (1 atmos) COj (gas) CO, (gas)
ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
per cal per per cal per
deg- g, deg deg- g, deg mole cal per g mole cal per g
mole Cent mole Cent mole g mole g

17.95 0.2635 29.24 0.4293 7.73 1.02 26.48 744.55" 10 931 702.47 10 313 1

24.1 0.293 (S6.9) (0.449) -0.96 -8.71 897.17 10 922 844-68 10 281 2
23.9 0.291 (S7.8) (O.46O) -5.68 900.22 10 960 847.62 10 319 3
23.9 0.291 (S6.7) (0.435) -4.22 901.68 10 977 849.08 10 337 4

(U-l) (0.459) -4.91 -13.95 1054.32 10 964 991.20 10 307 5

(46.0) (O.468) -11.79 1056.48 10 986 993.36 10 330 6
(48.0) (0.447) -10.33 1057.94 11 001 994.82 10 345 7
30.3 0.315 (U-4) (0.462) 8
30.1 0.313 (45.S) (0.471) 9
30.0 0.312 (4S.4) {0-461) 10
30.1 0.313 (45.3) (0.471) 11
29.4 0.306 (43. S) (0.450) 12
29.8 0.310 (43.0) (0.447) 13
30.0 0.312 (44-3) (0.461) 14
30.0 0.312 (U-9) (0.466) 15
30.0 0.312 (46.B) (O.48O) 16
(41.6) (0-481) 17

(61.4) (0.466) -9.84 -20.06 1210.58 10 986 1136.94 10 318 18

(68.6) (0.472) -14.76 -26.16 1366.85 11 004 1282.69 10 326 19
(65.9) (0.477) -19.69 -32.27 1523.11 11 018 1428.43 10 333 20

25.10 0.306 35.64 0.4339 -1.08 -9.13 896.75 10 916 844.16 10 276 21

(48.1) (0.448) 9.04 94-0 -10.38 -19.42 1048.85 10 907 985.73 10 250 22
(u-o) (O.468) 23
(42.2) (0.438) 24

(60.4) (0.467) 10.38 93.7 -15.17 -25.50 1205.11 10 937 1131.47 10 268 25
(61.8) (0.465) 26
(49.4) (0.448) 27
(60.6) (0.469) 28
(61.6) (O.468) 29
(49.7) (0.451) 30
(49.7) (0.451) 31
(61.5) (0.468) 32
(49.6) (O.450) 33
(47.3) (O.429) 34

(67.6) (0.464) -20.10 -31.61 1361.37 10 960 1277.21 10 282 35

(64.9) (0.469) -25.02 -37.71 1517.64 10 978 1422.96 10 293 36

(47.7) (0-441) 37

38

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W, = molecular weight.
3. See Appendix I, p. 61 ', for definitions of superscripts.

53
 1C1.13

TABLE 1C1.13—Acetylenes (Metric Units)

Refractive t Specific Kinematic

Density of the Liquid," Index of the Dispersion of Viscosity^ of
dt g per eu cm Liquid," no the Liquid," the Liquid,
dp 10< (ni— nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, , Point of the Aniline
No. Compound Point at deg in Air at Liquid0 Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per
mm
deg Cent
at at at at at at
at at c, Cent
at 37.78 98.89 dynes
Hg 15 C 20C 25 C 20C 25 C 20C 25 C C C per cm

Acetylenes, & and Cj:

1 Ethyne (acetylene), CsHs, M.W. 26.038 -S4P 0.018 -81' 0.6164?
2 Propyne (methylacetylene), C3H4, -23.21 0.030 -102.7 0.6711"
M.W. 40.065

Acetylenes, C4H6, M.W. 54.092:

3 1-Butyne (ethylacetylene) 8.07 0.036 -125.721 0.65"* 0.65d 0.65d
4 2-Butyne (dimethylacetylene) 26.98 0.037 -32.240 0.6965 0.6910 0.6856 1.3921 1.3893

Acetylenes, CtHs, M.W. 68.119:

5 1-Pentyne 40.17 0.039 -105.7 0.6953 0.6901 0.6849 1.3852 1.3826 119 119
6 2-Pentyne 56.06 0.041 -109.3 0.7158 0.7107 0.7055 1.4039 1.4009
7 3-Methyl-l-butyne 26.34 0.038 -89.7 0.672 0.666 0.660 1.3723 1.3695

Acetylene, CcHio, M.W. 82.146:

8 1-Hexyne 71.32 0.042 -131.9 0.7204 0.7155 0.7106 1.3989 1.3960 115 115
9 2-Hexyne 84.52 0.04 -89.47 0.7358 0.7313 0.7268 1.4138 1.4109 115 115
10 3-Hexyne 81.42 0.04 -103.10 0.7273 0.7227 0.7182 1.4113 1.4088 119 119
11 3-Methyl-l-pentyne 57.7 0.04 0.7082 0.7037 0.6992 1.3916 1.3891
12 4-Methyl-l-pentyne 61.16 0.04 -104.6 0.7090 0.7045 0.7000 1.3930 1.3905 114 114
13 4-Methyl-2-pentyne 73.12 0.04 -110.30 0.7202 0.7157 0.7112 1.4057 1.4032
14 3,3-Dimethyl-l-butyne 37.71 0.04 -78.2 0.6732 0.6678 0.6623 1.3736 1.3706 114 114

Acetylenes, C7H12, M.W. 96.173:

15 1-Heptyne 99.74 0.045 -80.9 0.7374 0.7328 0.7283 1.4087 1.4061 113 113
16 2-Heptyne 112 0.05 0.752 0.748 0.744 1.4230 1.4204
17 3-Heptyne 107.16 0.05 -130.5 0.7427 0.7381 0.7336 1.4189 1.4163
18 3-Methyl-l-hexyne 85 0.04 0.7230 0.7185 0.7140 1.4001 1.3975
19 4-MethyI-l-hexyne 91 0.04 0.7372 0.7327 0.7282 1.4076 1.4050
20 5-Methyl-l-hexyne 91.85 0.04 -124 0.7320 0.7274 0.7229 1.4059 1.4033
21 4-Methyl-2-hexyne 99.54 0.05 -107.6 0.7431 0.7386 0.7341 1.4170 1.4144
22 5-Methyl-2-hexyne 102.46 0.05 -92.9e 0.7423 0.7378 0.7333 1.4176 1.4150
23 2-Methyl-3-hexyne 95.2 0.04 -116.6 0.7294 0.7249 0.7204 1.4120 1.4094
24 3-EthyI-l-pentyne 84 0.04 0.7316 0.7271 0.7226 1.4035 1.4009
25 3,3-Dimethyl-l-pentyne 70 0.04 0.7122 0.7077 0.7032 1.3934 1.3908
26 3,4-Dimethyl-l-pentyne 80 0.04 0.7281 0.7236 0.7191 1.4018 1.3992
27 4,4-DimethyI-l-penty ne 76.07 0.04 -75.0 0.7186 0.7142 0.7097 1.3983 1.3957
28 4,4-DimethyI-2-penty ne 83 0.04 0.7222 0.7176 0.7131 1.4071 1.4045 117 117

Acetylenes, C8Hu, M.W. 110.200:

29 1-Octyne 126.21 0.0469 -79.3 0.7508 0.7468 0.7426 1.4163 1.4138 111 111
30 2-Octyne 137.74 0.048 -61.e 0.7636 0.7594 0.7552 1.4276 1.4251
31 3-Octyne 133.15 0.048 -104 0.7564 0.7522 0.7479 1.4250 1.4223
32 4-Octyne m.e -102.5 0.766 0.761 0.747 1.4U8 1.4M6

Acetylenes, C9Hi«, M.W. 124.227:

33 1-Nonyne 150.7 0.049 -50 0.7623 0.7579 0.7538 1.4219 1.4195 110 110
34 2-Nonyne 161.9 0.050 0.7727 0.7686 0.7645 1.4327 1.4303
35 3-Nonyne 157.1 0.050 0.7637 0.7597 0.7556 1.4288 1.4264

Acetylenes, CioHn, M.W. 138.254:

36 1-Decyne 174 0.052 -44 0.7710 0.7670 0.7631 1.4272 1.4249 108 108
37 2-Deoyne 184.6 0.052 0.7802 0.7763 0.7724 1.4364 1.4341
38 3-Decyne 179.3 0.052 0.7697 0.7658 0.7619 1.4315 1.4292

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.

54
 1C1.13

TABLE 1C1.13—Acetylenes (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure0
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HjO (liquid) + H20 (gas)-r-
pera- ume, (1 atmos) CO* (gas) COi (gas)
ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
cal per per cal per mole mole
deg- g, deg deg- g, deg per cal per g cal per g
mole Cent mole Cent mole g mole g

60.59 36.17 0.113 10.499 0.4032 54.194 0

50.000 1
55.54 129.24 0.164 14.50 0.3618 (3.90) (97.s) 44.319 46.313 (460)" •" (ll 470)" (438)" (10 940)" 2

{46.60) 190.5 {0.221) 19.46 0.3597 32.79 0.6062 5.67 104.8 (6.37) (99.5) 39.48 33.70 48.30 614.85° 11 367 583.30 10 783 3
{SO.18) 215 (0.221) 18.63 0.3444 29.92 0.5532 6.38 117.9 (s.9l) (109.6) 34.97 28.54 44.32 609.69" 11 271 578.13 10 688 4

{40.00) 220 {0.278) 25.18 0.3697 {40.1) (0.587) 6.79 99.7 (5.94) (87.3) 34.50 27.67 50.16 771.18° 11 321 729.10 10 703 5
(41-60) (260) 0.278 23.59 0.3463 {87.2) (0.546) 7.35 107.9 (6.32) (92.8) 30.80 23.43 46.41 766.95° 11 259 724.87 10 641 6
25.02 0.3673 {89.3) (0.577) 6.16 90.4 32.60 26.35 49.12 769.86° 11 302 727.79 10 684 7

{S4.90) {26S ) {0.SS4) 30.65 0.3731 (47.8) (0.576) (6.39) (77.8) 29.55 52.17 (929.7) (11 818) (877.2) (10 679) 8
(44-4) (0.541) 9
(S6.10) (281 (0.384) {a) {0.34) iu-i) (0.541) (6.68) (80.0) (925.5) (11 267) (873.0) (10 628) 10
{46.6) (0.668) 11
{46.6) (0.568) 12
(43.7) (0.532) 13
(44-9) (0.646) 14

([Link]) {289 {0.S91) 36.11 0.3755 (64.8) (0.567) (7.00) (72.8) 24.62 54.18 (1086.8) (11 291) (1022.8) (10 636) 15
{61.7) (0.6S8) 16
(61-7) (0.638) 17
{68.9) (0.560) 18
{63.9) (0.560) 19
{[Link]) {292 {0.389) {[Link]) {63.9) ([Link]) (6.79) (70.6) (1078.7) (11 217) (1016.7) (10 662) 20
(si.o) ([Link]) 21
(61.0) ([Link]) 22
{60.9) ([Link]) 23
(58.8) ([Link]) 24
{52.2) (0.64s) 25
{63.2) (0.653) 26
{62.2) (0.54s) 27
(49.3) (0.618) 28

{28.60) (S2l) {0.448) 41.58 0.3773 (61.8) (0.661) (7.41) (67.S) 19.70 56.19 (1242.8) (ll 278.6) (1169.3) (10 61l) 29
([Link]) (S48) {0.448) (42) {0.38) (69.0) (0.636) (7.47) (67.8) (l2S9.4) (ll 24S) (1165.9) (10 681) 30
{29.00) {S41) (0-448) (H) (0.87) (69.0) ([Link]) (7.41) (67. 8) (1239.5) (11 248.6) (1166.0) (10 582) 31
{28.90) (840) (0-448) (40) ([Link]) (69.0) (0.5S5) (7.35) (66.7) (1239.5) (ll 249) (1166.0) (10 582) 32

(26.60) {346) (0.606) 47.04 0.3787 (69.1) (0.666) (7.80) (62.8) 14.77 58.20 (1399.8) (ll 277) (1S1S.8) (10 600) 33
(66.2) ([Link]) 34
(66.2) ([Link]) 35

52.51 0.3798 (76.4) (0.552) 9.85 60.20 36

(73.6) (0.681) 37
(73.6) (0.6SI) 38

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 ', for definitions of superscripts.

55
 1C1.14

TABLE 1C1.14—Alkylbenzenes, Naphthalene, Indans, and Tetrahydronaphthalene (Metric Units)

Refractive _ Specific Kinematic

Density of the Liquid,0 Index of the Dispersion of Viscosity of
dt g per cu cm Liquid,° tij> the Liquid," the Liquid,
dp 10' (nz—nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, , Point of the Aniline
No. Compound Point at deg in Air at Liquid0 Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 98.89 dynes
Hg 15 C 20C 25 C 20C 25 C 20C 25 C C C per cm

Alkylbenzenes, Ce and C7:

l Benzene, Curls, M.W. 78.114 80.094 0.04271 + 5.531 0.88415 0.87889 0.87368 1.50112 1.49792 189.9 189.6 0.5870 28.18 <-30
2 Methylbenzene (toluene), CTHS. M.W. 92.143 110.629 0.04630 -94.965 0.87144 0.86696 0.86231 1.49693 1.49413 185.0 184.7 0.5584 0.341 27.92 <-30

Alkylbenzenes, CBHU, M.W. 106.168:

3 Ethylbenzene 136.200 0.04898 -94.949 0.87139 0.86700 0.86262 1.49588 1.49320 175.0 174.7 0.6428 0.390 28.48 <-30
4 1,2-Dimethylbenzene (o-xylene) 144.429 0.04969 -25.167 0.88438 0.88018 0.87594 1.50545 1.50295 180.4 180.1 0.740 0.428 29.48 <-30
5 1,3-Dimethylbenzene (m-xylene) 139.118 0.04903 -47.844 0.86834 0.86415 0.85988 1.49722 1.49464 180.9 180.6 0.591 0.366 28.08 <-30
6 1,4-Dimethylbenzene (p-xylene) 138.S60 0.04917 +13.258 0.86530 0.86103 0.85667 1.49582 1.49325 182.4 182.1 0.613 0.372 27.76 <-30

Alkylbenzenes, C9H12, M.W. 120.195:

7 n-Propylbenzene 159.241 0.05143 -99.479 0.86610 0.86202 0.85778 1.49202 1.48951 166.7 166.4 0.7944 0.455 28.45 <-30
8 Isopropylbenzene (cumene) 152.413 0.05074 -96.010 0.86594 0.86177 0.85749 1.49145 1.48890 165.7 165.4 0.740 27.68 <-15
9 l-MethyI-2-ethylbenzene 165.180 0.05163 -80.800 0.88467 0.88067 0.87655 1.50456 1.50208 172.4 172.1 29.66
10 l-Methyl-3-ethylbenzene 161.330 0.05111 -95.544 0.86866 0.86450 0.86038 1.49660 1.49406 173.4 173.1 28.52
11 l-Methyl-4-ethylbenzene 162.014 0.05148 -62.317 0.86530 0.86116 0.85700 1.49500 1.49244 173.9 173.6 0.671 28.28
12 1,2,3-Trimethylbenzene 176.116 0.05263 -25.360 0.89824 0.89436 0.89042 1.51393 1.51150 176.0 175.7 30.76
13 1,2,4-Trimethyl benzene 169.380 0.05187 -43.77 0.87985 0.87580 0.87178 1.50484 1.50237 178.2 177.9 29.19
14 1,3,5-Trimethylbenzene (mesitylene) 164.743 0.05100 -44.694 0.86915 0.86516 0.86109 1.49937 1.49684 177.8 177.5 28.31 <-30

Alkylbenzenes, C10H11, M.W. 134.222:

15 n-Butylbenzene (l-phenylbutane) 183.305 0.05358 -87.940 0.8642 0.86011 0.85605 1.48979 1.48742 159.6 159.3 0.947 0.518 <-30
16 Isobutylbenzene 172.789 0.05319 -51.45 0.8573 0.85319 0.84905 1.48646 1.48400 160.8 160.5
(l-phenyl-2-methylpropane)
17 sec-Butylbenzene (2-phenylbutane) 173.336 0.05313 -75.436 0.8661 0.86205 0.85795 1.49020 1.48779 159.0 158.7
18 ieri-Butylbenzene 169.148 0.05269 -57.881 0.87059 0.86648 0.86238 1.49266 1.49024 159.3 159.0
(2-phenyl-2-methylpropane)
19 l-MethyI-2-propylbenzene 184.97 0.0535 -60.273 0.8783 0.8736 0.8697 1.4996 1.4975 166 166
20 1-Methy 1-3-propylbenzene 182.01 0.0530 -82.548 0.8650 0.8609 0.8569 1.4935 1.4911 166 166
21 l-Methyl-4-propylbenzene 183.42 0.0535 -63.662 0.8624 0.8584 0.8544 1.4922 1.4898 166 166
22 l-MethyI-2-isopropylbenzene (o-cymene) 178.18 0.0529 -71.506 0.8807 0.8766 0.8726 1.5005 1.4983 166 166
23 l-Methyl-3-isopropylbenzene (m-cymene) 175.08 0.0524 -63.712 0.8650 0.8610 0.8570 1.4929 1.4905 166 166
24 l-Methyl-4-isopropylbenzene (p-cymene) 177.13 0.0528 -67.901 0.8613 0.8573 0.8533 1.4909 1.4885 166 166
25 1,2-Diethylbenzene 183.458 0.05340 -31.221 0.88386 0.87994 0.87590 1.50346 1.50106 166.2 165.9
26 1,3- Diethylbenzene 181.136 0.05293 -83.891 0.86802 0.86392 0.85991 1.49552 1.49310 166.9 166.6
27 1,4-Diethylbenzene 183.787 0.05351 -42.825 0.86594 0.86194 0.85792 1.49483 1.49245 168.2 167.9
28 1,2-D i methyl-3-ethylbenzene 193.95 0.0554 -49.51 0.8961 0.8921 0.8881 1.5117 1.5095 170 170
29 1,2-DimethyI-4-ethylbenzene 189.52 0.0563 -66.896 0.8785 0.8745 0.8706 1.5031 1.5009 171 171
30 1,3-Dimethyl-2-ethylbenzene 190.05 0.0561 -16.25 0.8945 0.8904 0.8864 1.5107 1.5085 170 170
31 1,3-Dimethyl-4-ethylbenzene 188.24 0.0555 -62.847 0.8804 0.8763 0.8723 1.5037 1.5015 171 172
32 1,3-DimethyI-5-ethylbenzene 183.62 0.0542 -84.293 0.8688 0.8648 0.8608 1.4981 1.4958 172 172
33 1,4-Di methyl-2-ethyl benzene 186.87 0.0533 -53.7 0.8811 0.8772 0.8732 1.5043 1.5020 171 171
34 1,2,3,4-Tetramethylbenzene (prehnitene) 205.09 0.055 -6.25 0.9088 0.9052 0.9015 1.5203 1.5181 174 174
35 1,2,3,5-Tetramethylbenzene (isodurene) 198.04 0.055 -23.671 0.8941 0.8903 0.8865 1.5130 1.5107 174 174
36 1,2,4,5-Tetramethylbenzene (durene) 196.84 0.054 +79.234 0.8910 0.8875' 0.8837' 1.5116' 1.5093' 174' 174'

Naphthalenes, CioH8, M.W. 128.174:

37 Naphthalene 217.991 0.05809 +80.284 1.175°"" (1.5898)" (297)*

Alkylindans, CsHio, M.W. 118.179:

38 2,3-Dihydroindene (indan) 177.85 0.055 -51.371 0.9679 0.9640 0.9600 1.5385 1.5358

Alkylindans, CioHu, M.W. 132.206:

39 l-Methyl-2,3-dihydroindene(l-methylindan) 190.6 0.055 0.947 0.942 0.938 1.5266 1.5240
40 2-Methyl-2,3-dihydroindene (2-methylindan) 191.4 0.055 0.949 0.944 0.940 1.5220 1.5194
41 4-Methyl-2,3-dihydroindene(4-methylindan) 205.5 0.055 0.974 0.970 0.966 1.5348 1.5322
42 5-Methyl-2,3-dihy droindene (5-methylindan) 202.0 0.055 0.952 0.948 0.944 1.5336 1.5310

Tetrahydronaphthalenes, C10H12, M.W. 132.206:

43 1,2,3,4-Tetrahydronaphthalene 207.62 0.0575 -35.769 0.9742 0.9695 0.9660 1.54135 1.53919 166 166 ... <-20

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p., 61., for definitions of superscripts.

56
 1C1.14

TABLE 1C1.14—Alkylbenzenes, Naphthalene, Indans, and Tetrahydronaphthalene (Metric Units)

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure0
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 5 5C Boiling Point H2Q (liquid) + HiO (gas) +
pera- ume, (1 atmos) COz (gas) COi (gas)
ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal cal per kcal cal per State State kcal per kcal per
deg- g, deg deg- g, deg per per mole cal per g mole cal per g
Cent mole Cent mole mole E
rade |

48.34 289.01 0.259 19.68 0.2620 32.52 0.4163 8.090 103.57 7.352 94.13 19.820 11.718 30.989 29.756 780.98 9 999 749.42 9595 1
40.55 318.64 0.316 24.77 0.2688 S7.68 0.4079 9.080 98.55 7.931 86.08 11.950 2.883 29.228 27.220 934.50 10 143 892.42 9686 2

35.62 344.02 0.374 30.69 0.2891 44.46 0.4188 10.098 95.12 8.50 80.07 7.145 -2.953 31.233 28.638 1091.03 10 277 1038.43 9782 3
36.84 357.2 0.369 31.85 0.3000 44.89 0.4228 10.381 97.79 8.80 82.9 4.540 -5.841 29.177 26.370 1088.16 10 250 1035.56 9755 4
34.95 343.90 0.376 30.49 0.2872 43.77 0.4123 10.195 96.03 8.59 81.86 4.120 -6.075 28.405 25.730 1087.92 10 248 1035.32 9752 5
34.65 343.1 0.379 30.32 0.2856 43.94 0.4139 10.128 95.40 8.529 80.34 4.290 -5.838 28.952 26.310 1088.16 10 250 1035.56 9755 6

31.58 365.23 0.440 36.41 0.3030 51.32 0.4270 11.050 91.94 9.14 76.0 1.891 -9.159 32.831 29.844 1247.19 10 377 1184.07 9852 7
31.67 358.0 0.428 36.26 0.3017 {50.6) {0.421) 10.789 89.77 8.97 74.6 0.940 -9.848 32.738 29.708 1246.52 10 372 1183.40 9846 8
30 378 0.46 37.74 0.3140 {60.9) {0.42S) 11.40 94.9 9.29 77.3 0.290 -11.110 31.323 27.973 1245.26 10 361 1182.14 9836 9
28 364 0.49 36.38 0.3027 {60.9) {O.42S) 11.21 93.3 9.21 76.6 -0.460 -11.670 30.217 26.977 1244.71 10 357 1181.59 9831 10
29 367 0.47 36.22 0.3014 {60.9) {0.42S) 11.41 94.90 9.18 76.4 -0.780 -11.920 30.281 27.041 1244.45 10 354 1181.33 9829 11
34.09 391.38 0.414 36.85 0.3066 51.73 0.4304 11.726 97.57 9.57 79.6 -2.287 -14.013 29.322 25.679 1242.36 10 337 1179.24 9812 12
31.90 375.98 0.430 37.10 0.3087 51.37 0.4274 11.458 95.34 9.38 78.0 -3.327 -14.785 27.915 24.462 1241.58 10 331 1178.46 9805 13
30.86 364.21 0.433 35.91 0.2988 47.92 0.3987 11.348 94.42 9.33 77.6 -3.836 -15.184 28.176 24.832 1241.19 10 327 1178.07 9802 14

28.49 387.4 0.497 41.85 0.3118 68.16 0.4SSS 11.98 89.26 9.38 69.89 -3.30 -15.26 31.08 1403.46 10 457 1329.82 9908 15
30 377 047S (*•) ([Link]) {67.5) (0.428) 11.82 88.06 9.04 67.36 {1404.7) (10 466) (mi.2) (9919) 16

29.12 391.4 0.478 (42) (0.S1) {67.6) (0.428) 11.83 88.14 9.07 67.58 (1404-8) {lO 467) (issi.s) {9919) 17
29. $6 S87 0.461 Us) (fi.82) 57.13 0.4257 11.73 87.40 8.99 66.98 {1402. s) {10 449) (1328.8) (9901) 18

{67.4) {0.428) 12.59 93.81 9.43 70.26 19

{67.4) {0.428) 12.45 92.76 9.40 70.04 20
{67.4) {O.428) 12.41 92.47 9.36 69.74 21
28.68 S97 0.478 Us) (0.S2) {66.7) (0.422) 12.10 90.16 9.17 68.32 (1402.5) (10 460) (1329.0) (9902) 22
29.00 S9S.1 0.478 (42) [[Link]) {66.7) (0.422) 11.94 88.96 9.11 67.88 (1401.9) (10 446) (1328.4) (9898) 23
28 380 0.478 (S4) {0.26) 56.68 0.4223 12.02 89.56 9.12 67.95 (1401.9) {10 445) {1S28.4) (9898) 24
{67.2) (0.426) 12.61 93.96 9.42 70.19 25
{67.2) {0.426) 12.55 93.51 9.41 70.11 26
27.66 384.81 {67.2) (0.426) 12.54 93.44 9.41 70.11 27
{67.3) {O.427) 13.11 97.68 9.70 72.27 28
(67.3) (0.427) 12.89 96.04 9.62 71.68 29
{67.S) (0.427) 12.88 95.97 9.60 71.53 30
{67.3) (0.427) 12.74 94.92 9.56 71.23 31
(57.s) (O.427) 12.52 93.29 9.47 70.56 32
{67.8) (0.427) 12.58 93.73 9.48 70.63 33
56.96 0.4244 13.66 101.78 10.76 80.17 34
57.54 0.4287 13.34 99.39 10.47 78.01 35
29 402 13.27 98.87 10.88 81.07 36

39.98 475.28 0.41 $9.60mm 0.3090•z 36.14 18.77""" 44.40""" 1232.54""" 9616""" 1190.46""" 9296""" 37

38

39
40
41
42

61.97 0.S9S1 43

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61., for definitions of superscripts.

57
 1C1.15 TABLE 1C1.15—Styrenes and Indenes (Metric Units)

Refractive Specific Kinematic

Density of the Liquid," Index of the Dispersion of Viscosity of
tit g pec eu cm Liquid," nj> the Liquid," the Liquid,
dp 10' (,nF-nc)/d centistokes Surface
at 1 Freezing Tension
Boiling atmos, Point of the Aniline
No. Compound Point at deg in Air at Liquid" Point,
1 atmos, Cent 1 atmos, at 25 deg
deg Cent per deg Cent at at C, Cent
mm at at at at at at at 37.78 dynes
Hg 15 0 -20 O 25 0 20 C 25 C 20 O 25 C C pec cm

Styrenes, C«Hs, M.W. 104.152:

Ethenylbenzene (styrene; vinylbenzene; 145.16 -30.610 1.54395
phenylethylene)

Styrenes, CjHio, M.W. 118.179:

Isopropenylbenzene (a-methylstyrene; 165.5 0.055 -23.2 0.9134 0.9090 0.9016 1.5386 1.5358 265 265
2-Phenyl-l-propene)
cts-1-Propenylbenzene (cis-0-methylstyrene; 167.46 0.055 -61.65 0.9134 0.9090 0.9046 1.5430 1.5402 265 265
cis-l-Phenyl-l-propene)
irans-1-Propenylbenzene (lmna-@- 178.29 0.056 -29.31 0.9112 0.9067 0.9023 1.5506 1.5478 265 265
methylstyrene; iraras-1-Phenyl-l-propene)
l-MethyI-2-ethenylbenzene 169.84 0.051 -68.54 0.9161 0.9119 0.9077 1.5437 1.5413 265 265
(o-methylstyrene)
l-Methyl-3-ethenylbenzene 171.6 0.052 -86.31 0.9159 0.9118 0.9076 1.5411 1.5385 265 265
(m-methylstyrene)
l-Methyl-4-ethenylbenzene 172.8 0.052 -34.13 0.9257 0.9215 0.9173 1.5420 1.5395 265 265
(p-methylstyrene)

Styrenes, C10H12, M.W. 132.206:

cis-1-Phenyl-l-butene (cts-jS-ethylstyrene) 189 0.05 0.9148 0.9107 0.9065 1.5390 1.5364
/rans-1-Phenyl-l-butene 198.72 0.05 -43.0 0.9060 0.9019 0.8977 1.5420 1.5394
0r<ms-/3-ethylstyrene)
2-Phenyl-l-butene (a-ethylstyrene) 182 0.05 0.896 0.891 0.887 1.5288 1.5262
cis-2-Phenyl-2-butene 194.7 0.05 0.9219 0.9178 0.9138 1.5425 1.5401
{cis-ct ,|3-dimethylstyrene)
tnms-2-Phenyl-2-butene 0.05 0.8999 0.8958 0.8918 1.5217 1.5193
(trana-ct, /3-dimethylstyrene)
2-Methyl-l-phenyl-l-propene 187. 0.05 0.9052 0.9011 0.8971 1.5400 1.5376
(/3 ,/3-dimethylstyrene)
l-Methyl~2-(«s-l'-n-propenyl) benzene 0.907 0.902 0.898 1.539 1.537
(cis-o,|9-dimethylstyrene)
l-Methyl-2-((raras-l'-n-propenyl)benzene 0.907 0.902 0.898 1.539 1.537
(trans-o ,/3-dimethylstyrene)
l-Methyl-3-(cis-l'-n-propenyl) benzene 0.899 0.895 0.891 1.540 1.538
(cis-m ,/3-dimethylstyrene)
l-Methyl-3-(*rara$-l'-rc-propenyl)benzene 0.899 0.895 0.891 1.540 1.538
(trans-m ,/3-dimethylstyrene)
l-Methyl-4~(cts-l'-n-propenyl)benzene 0.05 0.8937 0.8896 0.8856 1.5392 1.5368
(cfs-p,/3-dimethylstyrene)
l-Methyl-4-(*mws-l'-w-propenyl) benzene 0.05 0.9100 0.9059 0.9019 1.543 1.541
((r<ms-p,j3-dimethylstyrene)
l-Methyl-2-isopropenylbenzene 172.2 0.05 0.8933 0.8893 0.8853 1.5155 1.5130
(a, a-dimethylstyrene)
l-Methyl-3-isopropenylbenzene 185 0.05 0.9091 0.9050 0.9010 1.5335 1.5310
(m, a-dimethylstyrene)
l-Methyl-4-isopropenylbenzene 0.05 0.9039 0.8999 0.8959 1.5340 1.5315
(p, a-dimethylstyrene)
l-Ethyl-2-ethenylbenzene (o-ethylstyrene) 187.3 0.052 -75.5 0.9099 0.9058 0.9017 1.5380 1.5356
l-Ethyl-3-ethenylbenzene (wi-ethylstyrene) 190.0 0.053 -101 0.8987 0.8945 0.8904 1.5351 1.5325
l-Ethyl-4-ethenylbenzene (p-ethylstyrene) 192.3 0.053 -49.7 0.8966 0.8925 0.8884 1.5376 1.5348
1,2-Dimethyl-3-ethenylbenzene
(2,3-dimethylstyrene)
27 1,2-Dimethyl-4-ethenylbenzene 0.915 0.910 0.906 1.5464 1.5438
(3,4-dimethylstyrene)
1,3-Dimethyl-2-ethenylbenzene 0.909 0.905 0.901 1.535 1.533
(2,6-dimethylstyrene)
1,3-Dimethyl-4-ethenylbenzene 0.909 0.905 0.901 1.5423 1.5397
(2,4-dimethylstyrene)
1,3-Dimethyl-5-ethenylbenzene 0.902 0.898 0.894 1.5382 1.5356
(3,5-dimethylstyrene)
1,4-Dimethyl-2-ethenylbenzene 0.910 0.906 0.902 1.540 1.538
(2,5-dimethylstyrene)

Phenylacetylene, M.W. 102.136 [Link] -40 (0.929) {0.925)

Alkylindenea, C,H», M.W. 116.163:

Indene 182.47 0.0516 1.0000 0.9918 1.5764' 1.5737

Alkylindenes, CuHio, M.W. 130.190:

1-Methylindene 199 0.054 0.976 0.973 0.970 1.5616 1.5591
2-Methylindene 208 0.055 +80 0.981'' 0.977 0.974 1.6652' 1.5627'
3-Methylindene 205 0.054 0.979 0.975 0.972 1.5621 1.5596
4-Methylindene 209 0.055 0.995 0.992 0.989 1.568 1.566
5-MethylIndene 207 0.055 0.984 0.980 0.977 1.566 1.564
6-Methylindene 207 0.055 0.984 0.980 0.977 1.566 1.564
7-MethyIindene 209 0.055 0.995 0.992 0.989 1.568 1.566

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, page 61 , for definitions of superscripts. 58
 TABLE 1C1.15—Styrenes and Indenes (Metric Units) 1C1.15

Heat of Free Energy

Critical Heat Capacity at 25 C and Heat of Vaporization Formation at 25 of Formation Heat of Combustion of the Liquid
Constants Constant Pressure at Saturation Pressure C, kcal per mole at 25 C, kcal at 25 C and Constant Pressure0
per mole

Gas, Liquid at at the Normal Gross, to form Net, to form No.

Tem- Vol- Ideal State 1 atmos at 25 C Boiling Point HjO (liquid)+ H*0 (gas)+
pera- ume, (1 atmos) COi (gas) CO2 (gas)
ture, liter Gas, Liquid Gas, Liquid
atmos deg per Ideal Ideal
Cent mole cal per cal per cal per cal per kcal kcal State State kcal per kcal per
per cal per per cal per mole mole cal per g
deg- g. deg deg- g, <*eg cal per g
mole Cent mole Cent mole mole g

S9.47 S74-4 0.S69 29.18 0.2802 43.70 0.4196 (.8.74) 8S.9 35.22 24.83 61.10 1050.51 10 087 1008.44 9683 1

S9.47 S99 0.408 34.7 0.294 (61.2) (0.444) (9.20) 77.8 27.00 49.84 (1204.0) (10 189) (1151.6) (9744) 2

SS.79 404 0.408 34.7 0.294 (62.4) (0.443) (9.1S) 77.3 29.00 51.84 (1208.l) (10 m) (1165.6) (9779) 3

SB.79 404 0.408 34.9 0.295 (62.4) (0.443) (9.1S) 77.3 28.00 51.08 (1208.l) (10 223) (1155.6) (9779) 4

$6.00 406 0.S76 34.7 0.294 (SO.l) (0.4H) (9.26) 78.4 28.30 51.14 (1205.7) (to 20s) (1153.2) (9759) 5

36.11 402 0.S81 34.7 0.294 (60.1) (0.4H) ([Link]) 76.2 27.60 50.02 (1205.S) (10 200) (1152.8) (9755) 6

Si. 98 40S 0.S81 34.7 0.294 (50.1) (0.4*4) (9.07) 76.7 27.40 50.24 (1205.2) (10 198) (U52.7) (9765) 7

8
9

10
11

12

13

14

15

16

17

18

19

20

21

22

23
24
25
26

27

28

29

30

31

46.82 S82 0.441 (S7) (0.S6) (60) (0.59) « .67) (8S.9) (871.S) (8532) (839.8) (822S) 32

33

34
35
36
37
38
39
... 40
"
NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p, 64.
2. M.W. = molecular weight.
3. See Appendix I, p./ 61 , for definitions of superscripts. 59
 1C1.16

TABLE 1C1.16—Gaseous Hydrocarbons, Ci to CB (Metric Units)

Heat of Combustion of the Ideal Gas at 25 C and Constant Pressure

No.• Compound* Gross, to form H2O (liquid) + CO2 (gas) Net, to form H2O (gas) + CO2 (gas)

kcal per mole cal per g kcal per mole cal per g

Paraffins. Ci lo C:
ICl.l 1 Methane, CH4, M.W. 16.043 212.80 13 265 191.76 11 954
2 Ethane, CiHs, M.W. 30.070 372.82 12 399 341.26 11 350
3 Propane, CiHs, M.W. 44.097 530.60 12 034 488.53 11 079

Paraffins, C«H,o, M.W. 58.124:

4 n-Butane 687.64 11 831 635.05 10 927
5 2-Methylpropane (isobutane) 685.64 11 797 633.05 10 892

Paraffins, CsHi2, M.W. 72.151:

6 n-Pentane 845.16 11 715 782.05 10 840
7 2-Methylbutane (isopentane) 843.24 11 688 780.13 10 813
8 2,2-Dimethyl propane (neopentane) SS9.89 // 642 770.77 10 768

[Link], C< to Cs:

1C1.2 1 Cyclopropane, CjHt, M.W. 42.081 499.85 11 878 468.29 11 128
15 Cyclobutane, C.H8, M.W. 56.108 655.79 11 688 613.72 10 938
23 Cyclopentane, CjHio, M.W. 70.135 793.42 11 313 740.83 10 563

Monoolefins, C2 and Cs:

1C1.3 1 Ethene (ethylene), C2H4, M.W. 28.054 337.23 12 022 316.19 11 272
2 Propene (propylene), CjHt, M.W. 42.081 491.99 11 692 460.43 10 942

Monoolefins, C<Hs, M.W. 56.108:

3 1-Butene 649.45 11 576 607.37 10 826
4 ctV2-Butene 647.81 11 547 605.73 10 797
5 frans-2-Butene 646.81 11 529 604.73 10 779
6 2-Methylpropene (ieobutene) 645.43 11 505 603.36 10 755

Monoolefins, CsHio, M.W. 70.135:

7 1-Pentene 806.82 11 504 754.23 10 754
8 cis-2-Pentene 805.34 11 484 752.74 10 734
9 (rons-2-Pentene 804.26 11 468 751.66 10 718
10 2-Methyl-l-butene 803.17 11 453 750.57 10 703
11 3-Methyl-l-butene 804.93 11 478 752.33 10 728
12 2-Methyl-2-butene 801.68 11 431 749.08 10 681

Diolefins, C>H<, M.W. 40.065:

163 Propadiene (allene) 464.71 11 600 443.67 11 075

Diolefins, C<Hi, M.W. 54.092:

164 1,2-Butadiene 619.93 11 461 588.37 10 878
165 1,3-Butadiene 607.49 11 231 575.93 10 648

Diolefins, CiHs, M.W. 68.119:

166 1,2-Pentadiene 777.14 11 408 735.0S 10 791
167 1, cis-3-Pentadiene 76S.29 11 205 721.22 10 588
168 1 ,<rans-3-Pentadiene [Link] 11 181 719.56 10 66S
169 1,4-Pentadiene 768.9S 11 m 726.85 10 670
170 2,3-Pentadiene 775.S2 11 S82 7SS.25 10 764
171 3-Methyl-l,2-butadiene 7744S 11 S69 7S2.S5 10 751
172 2-Methyl-l ,3-butadiene (isoprene) 761.6S 11 181 719.54 10 562

1C1.4 1 Cyclopentene, CsHs, M.W. 68.119 751.26 11 030 709.18 10 412

Acetylenes, C2 and Cs:

1C1.5 1 Ethyne (acetylene), C2H2, M.W. 26.038 310.62 11 930 300.10 11 526
2 Propyne (methylacetylene), CsH4, M.W. 40.065 463.11 11 560 442.07 11 035

Acetylenes, CiHs, M.W. 54.092:

3 1-Butyne (ethylacetylene) 620.64 11 474 589.08 10 891
4 2-Butyne (dimethylacetylene) 616.13 11 391 584.57 10 807

Acetylenes, CsHs, M.W. 68.119:

5 1-Pentyne 778.03 11 422 735.95 10 805
6 2-Pentyne 774.33 11 368 732.25 10 750
7 3-Methyl-l-butyne 776.13 11 395 734.05 10 777

NOTES:
1. Values in parentheses are estimated. For methods of estimation, see p. 64.
2. M.W. = molecular weight.
3. See Appendix I, p. 61 , for definitions of superscripts.
60
 1C1.17

TABLE 1C1.17—Appendixes

I. KEY TO FOOTNOTES

k 9
* Calculated values, see Appendix III. The + sign and the number, folio wing Specific gravity —119 F/60 F (sublima-
"For the air-saturated hydrocarbon at signify that the octane number of the com- tion point).
r
1 atmos. pound corresponds to that of 2,2,4-tri- For the undercooled liquid below the
6
Apparent values from weights in air. methylpentane with the indicated number normal freezing point.
"Absolute values from weights in vac- of milliliters of tetraethyl lead added. *At 185 F (85 C).
1
uum. Average value from octane numbers of ' Determined at 212 F.
d
At saturation pressure. more than one sample. " Determined at 302 F.
e m
At saturation pressure (triple point). Extrapolated to room temperature " Value for the ideal gas.
! w
For solid-vapor equilibrium. from higher temperatures. Formerly labeled "trans",
x
" At boiling point. " Too volatile to run as a liquid in the Formerly labeled "cis".
* Critical solution temperature instead CFR engine. "At 15.56 C.
0 1
of aniline point. For heats of combustion of gaseous hy- Approximate value.
i mm
Apparent values for methane at 60 F drocarbons, Ci to C5, see Table 1C1.8. For the solid phase.
p
(15.56 C). At sublimation point.

II. UNITS AND CONVERSION FACTORS

Molecular weights (M.W.): Based on the 15.9994, hydrogen = 1.0080, and carbon = International Practical Temperature Scale
1969 atomic weight table, see reference 12.011. of 1968 (IPTS-68), see reference (66).
(95 Y, in which atomic weight of oxygen = Temperature: Temperatures in degrees Other constants: Fundamental constants
centigrade (Celsius) are given on the and conversion factors are given in Sect. 1 A.

III. DEFINITIONS OF PROPERTIES2

Density of Liquids <4pp(lb per cu ft) API gravity is calculated by:

(1) Metric Unit Tables: Values of the = [d(lbpercuft) — d (air, lb per cu ft)] 141.5
absolute density, d, of the air saturated deg API = 131.5
sp gr 60 F/60 F"
hydrocarbon in vacuum are reported at rf(brass, lb per cu ft)
X
15 C, 20 C, and 25 C in g per cu cm: d(brass, lb per cu ft) — d(air, lb per cu ft) Refractive Index of Liquids
d(g per cu cm) = 0.999972 d(g per ml) Since density of air at 60 F is 0.0762 lb (1) Metric Unit Tables: Values of the
per cu ft and density of brass is 524 lb per refractive index, wz>, of the air saturated
(2) U.S. Unit Tables: Specific gravity, hydrocarbon relative to air at the sodium
cu ft, this formula reduces to:
D-line (5892.6 1) are reported at 20 C
60F/60F=,/y-5fKC'SPerCUCm) ,
a (water, 15.56 C, g per cu cm) dapp(lb per cu ft) and 25 C. The specific dispersion given at
20 C and 25 C is defined as 104 (nF - nc)/d,
_ d (15.56 C, g per cu cm) = 62.43700 d(g per cu cm) - 0.0762 where np = refractive index for the hydro-
0.999024 gen F-line (4861.3 A), no = refractive
<4pp(lb per gal) index of the hydrogen C-line (6562.8 A),
Densities at 60 F, dapp(lb per cu ft) and and d = density, in g per cu cm.
<4PP (lb per gal), are the apparent densities = 0.133681 dapp(lb per cu ft)
in air of the air saturated hydrocarbon: (2) U.S. Unit Tables: Values of refrac-
Density at other temperatures can be tive index and dispersion at 68 F and 77 F
d(60F, lb per cu ft) calculated from density at 60 F by: are the same as those in the metric tables
= 62.42795 d (15.56 C, g per cu cm) d(60F) at 20 C and 25 C, respectively.
d(idegFahr) =

H(f)]
1
The boldface numbers in parentheses refer to refer- Viscosity of Liquids
ences listed in Appendix V. (t - 60)
2
Calculated values are indicated in U.S. Unit Tables (1) Metric Unit Tables: The kinematic
by asterisks (*), see column headings. viscosity in centistokes is reported for

61
 1C1.17

temperatures of 37.78 C and 98.89 C. The change in enthalpy for the reaction: and for the net heat of combustion is:
kinematic viscosity, n, is related to the
absolute viscosity, n, by: CaH& (liquid, 25 C, 1 atmos)
aCP(C02> gas) + ^ <?P(H20, gas)

^ (stokes) =
r\ (poise)
d(g per cu cm) + H)« '2 (ideal gas, 25 C, 1 atmos)
ACV
M.W.

The absolute viscosity is referred to a value f« + ij GP(02, gas)

>a CO2 (ideal gas, 25 C, 1 atmos)
of 1.002 centipoises for water at 20 C.
— Cj,(CaHi,)
(2) U.S. Unit Tables: The kinematic M.W.
+ - H2O (ideal gas, 25 C, 1 atmos)
viscosity reported at temperatures of 100 F
[1.854a+2.3476]
and 210 F are the same as those in the • CP(CaH-b)
metric unit tables at 37.78 C and 98.89 C, These two types of heat of combustion M.W.
respectively. The absolute viscosity in are related at 25 C by: Cj^dHi,) is the specific heat of the liquid
lb (force) sec per sq in. may be calculated hydrocarbon in Btu per (lb)(deg Fahr).
from the kinematic viscosity by: AH (net, kcal per mole) The heat capacities of other substances are
<?P(C02, gas) = 8.874 Btu per (lb-mole) (deg
7j[lb (force) sec per sq in.] = 2.32328 = A/? (gross, kcal per mole) + 5.25956 Fahr), <?P(02, gas) = 7.020 Btu per (lb-mole)
X lO -7
ix (stokes) d(lb per cu ft) (deg Fahr), <?j,(H20, liquid) _= 18.000 Btu
where the enthalpy of vaporization of one- per (lb-mole) (deg Fahr), and Cj,(H20, gas) =
half mole of water from the liquid to the 8.025 Btu per (lb-mole)(deg Fahr). The
Heat of Vaporization ideal gas is 5.2595 kcal per mole. The heat gross and net heats of combustion at 60 F
of combustion in cal per g is obtained by: are related by:
(1) Metric Unit Tables: The heat of
vaporization, X, is defined as the enthalpy Aff(net, Btu per lb)
Affoomb (cal per g)
of the real gas at the equilibrium vapor
pressure minus the enthalpy of the liquid _ 1000Ai?Comb (kcal per mole) 9550.76
= Q (gross, Btu per lb) +
at the same pressure and temperature. M.W.
~ M.W.
The two units reported are related by:
The heat of combustion in Btu per gal is
X(cal per mole) where AffCOmb represents either the net or calculated from the value in Btu per lb by:
X(calper g) = gross heat of combustion. The molecular
M.W.
weights used in this conversion were based Aff(Btu per gal)
Where direct calorimetric data are not on the 1962 atomic weights where carbon is
12.01115 and hydrogen is 1.00797. = Aff (Btu per lb)d(lb per gal)
available, the heat of vaporization was
calculated from the equilibrium vapor
pressure, p*, by: (2) U.S. Unit Tables: The gross and Heat of Formation of Gas and Liquid
net heats of combustion at 60 F in Btu (Metric Unit Tables)
dp* per lb were calculated from the corre-
X(cal per mole) = T -r=- The enthalpy of formation of the liquid
sponding values reported in the metric hydrocarbon, CH&, from the elements
unit tables at 25 C by: C (graphite) and H2(gas) at 25 C is ob-
X [7(gas)- V(liquid)]
tained from the heat of combustion by:
Aff(Btuperlb60F)
(2) U.S. Unit Tables: The heat of AHf (kcal per mole)
vaporization at the normal boiling point
was calculated from the corresponding = 1.798796AH (cal per g, 25 C)
= Q (gross, kcal per mole)
value in the metric unit tables by:
+ AC3,(60- 77) + aAff/°(C02, gas)
X(Btu per lb) = 1.798796 X(cal per g)
ACP is the total heat capacity of the prod- + ^A#/°(H20, liquid)
ucts of the combustion of one pound of
Heat of Combustion of the Liquid hydrocarbon minus the total heat capacity
= Q (gross, kcal per mole)
(1) Metric Unit Tables: The gross heat of of the reactants. For the gross heat of
combustion, Q, of the hydrocarbon CaH& is combustion, this is: - 24.051a - 34.15756
the change in enthalpy for the reaction:
The enthalpy of formation in the ideal gas
CaH& (liquid, 25 C, 1 atmos) j 00,(00,, gas) + ^ dJ,(HaO, liquid) state is related to the enthalpy of forma-
tion of the liquid by:
M.W.
+ I a + - j O2 (ideal gas, 25 C, 1 atmos) AHf (ideal gas, kcal per mole)
(a + ^Cp(02,gas)l = AHf (liquid, kcal per mole)
—» a C02 (ideal gas, 25 C, 1 atmos)
-Cp(CaSb) + X (kcal per mole)
M.W.
+ - H20 (liquid, 25 C, 1 atmos)
[1.854a + 7.2456] + [S° (ideal gas, kcal per mole)
Cp(CaRb)
The net heat of combustion, AH, is the M.W. — H(real gas, kcal per mole)]

62
 1C1.17

The difference between the enthalpy of the unit value at the same temperature by: gas at 1 atmos is calculated from z by:
real and ideal gas, as shown by the last 0.73203z:F(degR.)
term, is calculated at the equilibrium vapor Cj,[Btuper (lb) (deg Fahr)] 7 (cu ft per lb) =
pressure at 25 C. M.W.
= 0.99933Cp[cal per (g) (deg K)] The volume of real gas per gallon of liquid
Free Energy of Formation of Gas at the same temperature, is calculated by:
and Liquid (Metric Unit Tables) Heat of Combustion of the Gas
The free (Gibbs) energy of formation of V (cu ft per gal) = V (real gas, cu ft per lb)
(1) Metric Unit Tables: Enthalpies of
the liquid and gaseous hydrocarbon from combustion are reported in Table 1C1.16 X d (liquid, lb per gal)
the elements at 25 C and 1 atmos is cal- for the ideal gas at 25 C and 1-atmos
culated from the corresponding enthalpy pressure. The gross and net heats of com- The specific gravity of the hydrocarbon
of formation and entropy of formation. bustion are defined the same way for the gas relative to air at 1 atmos and the same
hydrocarbon in the gaseous state as for temperature is given by:
AGf (liquid, kcal per mole)
the liquid. The heat of combustion for the 7 (hydrocarbon gas, cu ft per lb)
= AHf (liquid, kcal per mole) gas is related to that for the liquid by: Sp gr. =
7 (air, cu ft per lb)
- TA&[liquid, kcal per (mole) (deg K)] AHoomh (ideal gas) = AHcomb (liquid) — X The average molecular weight of dry air,
including 0.003 mole fraction C02, is 28.964.
AGf (ideal gas, kcal per mole) + [H(real gas) — H"(ideal gas)] The specific volume of dry air at 60 F and
1 atmos is 13.0965 cu ft per lb. Values at
= AHf (ideal gas, kcal per mole) (2) U.S. Unit Tables: .Enthalpies of other temperatures were calculated from
combustion are reported in Table 1C1.8 the tables in reference (27)'.
— !TAjS[ideal gas, kcal per (mole) (deg K)] for the real gas at 60 F and 1-atmos The quantity of air required for the
The free energy of formation in the ideal pressure for those compounds that boil at combustion of the gaseous hydrocarbon
gas at 1 atmos is related to the free energy or below 60 F, and at the normal boiling was based on the chemical reaction:
of formation of the liquid by: point and 1 atmos pressure for those com-
pounds that boil above 60 F. The heat CoH6(gas) + (a-r-^02(gas)
AQ{°(idealgas) = AGf(liquid)- RTlnp* (enthalpy) of combustion for the real gas
is calculated from that of the liquid at the —> aCOi (gas) + H20 (gas or liquid)
+ [G° (ideal gas)] - [(?(real gas)] 'same temperature by:
where the difference between the free Since the mole fraction of oxygen in dry air
energy of the real and ideal gas is calculated AHcomb (real gas) = AHCOmb (liquid) — X is 0.2095, the mass of air required for the
at the equilibrium vapor pressure, p*, in combustion of 1 lb of hydrocarbon is:
and the conversion to units of Btu per cu
atmospheres. ft is made by: lb air per lb hydrocarbon

K)
Heat Capacity of the Liquid and Gas AH00mb (real gas, Btu per cu ft)
28.964
(1) Metric Unit Tables: The heat capac-
ity at constant pressure is reported for the _ AH00mh (real gas, Btu per lb)
liquid and ideal gas at 25 C and 1-atmos 7 (real gas, cu ft per lb) 0.2095 M.W.
pressure. This is related to the enthalpy by.

-Jp -(dJL\
~\dTjP
Volume of the Real Gas and Related
Properties (U.S. Unit Tables)
138 *4+i)
The compressibility factor, z, the volume M.W.
The heat capacity observed for a liquid in
equilibrium with the vapor is C„. This may of the real gas, and the specific gravity of This is independent of pressure or tempera-
be converted to the heat capacity at con- the real gas are reported in Table 1C1.8 at ture. Since the weight fraction of oxygen in
stant pressure by: 60 F and 1 atmos for those compounds air is 0.23145, the volume of air (including
that boil at or below 60 F, and at the normal CO2) per pound-mole of oxygen at 1 atmos

"'©.
aY + C boiling point and 1-atmos pressure for
C, S those compounds that boil above 60 F.
dT
The compressibility factor is defined as: 31.99887 (air, cu ft per lb)
V
dp*/dT is the temperature derivative of 0.23145
the vapor pressure. The heat capacity of pV
an ideal gas is equal to the observed values z = = 138.2537(air, cu ft per lb)
BT
extrapolated to zero pressure. It should be At 60 F, V = 1810.63 cu ft per lb-mole of
noted that: where 7 is the volume of the real gas at 02. The volume of air required for the
temperature T and 1-atmos pressure. Under combustion of 1 cu ft of real hydrocarbon
Cp[cal per (g) (deg K)] these conditions, the compressibility co- gas at the same temperature is:
_ (?g[cal per (mole) (deg K)] efficient can be calculated accurately from
M.W. the second virial coefficient, B, by:

(2) U.S. Unit Tables: The specific heat

is reported for the liquid and ideal gas at ^ BT 7 (real gas) BTz
60 F and 1 atmos in Btu per (lb) (deg Fahr). 1
The boldface numbers in parentheses refer to refer-
This is related to the corresponding metric The specific volume of the hydrocarbon ences listed in Appendix V.

63
1C1.17

ESTIMATED VALUES
Estimated values of properties are the second virial coefficient as described in where n is the number of carbon atoms in
written in parentheses in the tables. In the section on "Definitions of Properties." the molecule. The heat capacity of the ideal
general, references to methods of estima- The second virial coefficients were either^ gas was estimated by the method described
tion may be found in Appendix IV, Key to taken from reference (29) or estimated by in reference (79).
References. the methods described in reference (56) or Where a reference is not given, the esti-
Estimated heats of combustion were (73). These various sources are identified mated flammability limits were supplied by
first calculated for the gas phase by the for specific compounds in Appendix IV, M.G. Zabetakis, Chief, Branch of Gas
method described in reference (80) and Key to References. Explosives, Explosives Research Labora-
then converted to the liquid phase by In those cases where a reference is not tory, U.S. Bureau of Mines [reference
adding the heat of vaporization. Con- given in Appendix IV, the estimated heat (91 )2- These estimates were obtained by
version to the various units listed in the capacity of the liquid was calculated by comparison with values for other hydro-
U.S. and metric tables was made by the the formula: carbons and checked with a master plot.
methods in the section on "Definitions of
Properties." CpQiquid, cal per (g) (deg K)]
Compressibility factors for the real gas _ C„[ideal gas, cal per (g) (deg K)]
in Table 1C1.8 were either taken from
reference (2) or (27) or calculated from 0.400 + 0.0125M

64
 1C1.17
IV. KEY TO REFERENCES
NOTE: For sources of data on compounds and properties not listed here, see Appendix III (p. 61 '.) on calculated and estimated values or references as follows:
(1) Octane numbers: reference (4)
(2) All others: reference (2).

c ritical
Constants Heat
Heat of Heat Flam-
Vapor Freez- o Heat Den- Refrac- Capac- Vapori of m abil- Aniline Point Com-
No. Compound Boiling Pres- ing Capac- sity, tive ity, zation Com- ity or Critical pressi-
Point sure Point 3 ity, Liquid Index, Ideal at bus- Limits Solution bility
V u Liquid Liquid Gas Normal tion, (Meas- Temperature Factor
3
a S Boiling Liquid ured)
fi
<u
Point
FM H s>

Paraffins:
Methane 62 26
Ethane 26,94
Propane 51 26,94

n-Butane SO 26,94 57
2-Methylpropane (isobutane) 50 57

n-Pentane 65 26,92 12, 32, 41,

78,90
2-Methylbutane (isopentane) 26 12, 32, 41,
82,90
2,2-DimethyIpropane (neopentane) 72 26

n-Hexane 65 26,92 12, 30, 32,

78,90
2-MethyIpentane 26
3-Methylpentane
2,2-Dimethylbutane 85 26
2,3-Dimethy lbutane

n-Heptane 84 92,94 12, 30, 32,

41, 53, 57,
78,90

2-Methylhexane 10 30, 32, 41,

90
3-Methylhexane 10 30, 32, 41,
43

3-Ethylpentane 54 10 30,32
2,2-Dimethylpentane 54 10 30, 32, 90
2,3-Dimethylpentane 30, 32, 41, 90

2,4-Dimethylpentane 54 10 30, 32, 90

3,3-Dimethylpentane 10 30, 32, 90
2,2,3-Trimethylbutane 54 84 30, 32, 90

n-Octane 65 11,12, 30,

32, 37, 58,
78,90

2-Methylheptane 65 30,58
3-Methylheptane 79 58,90
4-Methylheptane 79 58
3-Ethylhexane 9 58
2,2-Dimethylhexane 79 38
2,3-Dimethylhexane 9 58,90
2,4-Dimethy lhexane 79 58
2,5-Dimethylhexane 79 58,90
3,3-Dimethy lhexane 79 38
3,4-D imethy lhexane 58,90
2-Methyl-3-ethylpentane 68
3-Methyl-3-ethylpentane 7 90
2,2,3-Trimethylpentane 79 90
2,2,4-Trimethy lpentane 7 32, 53, 90
2,3,3- Trimethy lpentane 79 38
2,3,4-Trimethylpentane 9 38
2,2,3,3-Tetramethy lbutane 79

n-Nonane 65 45 67,94 32, 41, 78, 90

2-Methyloctane 79 87
3-MethyIoctane 79 87'
4-Methyloctane 79 87
3-Ethylheptane 79 38

4-Ethylheptane
2,2-Dimethylheptane 79 45 38
2,3-Dimethy lheptane 38
2,4-Dimethy lheptane
2,5-Dimethylheptane 38

65
1C1.17
KEY TO REFERENCES—Continued
Critical
Constants Heat
Heat of Heat Flam-
Vapor Freez- Heat Den- Refrac- Capac- Vapori- of mabil- Aniline Point Com-
No. Compound Boiling Pres- ing Capac- sity, tive ity, zation Com- ity or Critical pressi-
Point sure Point ity, Liquid Index, Ideal at bus- Limits Solution bility
Liquid Liquid Gas Normal tion, (Meas- Temperature Factor
Boiling Liquid ured)
Point

Paraffins—Continued:
2,6-Dimethy Iheptane 79
3,3-Dimethylheptane
3,4-Dimethylheptane

2,2,3-Trimethylhexane 45 38
2,2,4-Trimethylhexane 79 45 38
2,2,5-Trimethylhexane 79 45 38
2,3,3-Trimethylhexane 79 45 38

2,3,5-Trimethylhexane 79 45
2,4,4-Trime thy lhexane 79 45
3,3,4-Tr imethylhexane 79 45
3,3-Diethylpentane 79
2,2-Dimethyl-3-ethylpentane 79

2,3-Dimethyl-3-ethylpentane
2,4-Dimethy 1-3-ethylpentane 79 45
2,2,3,3-Tetramethy lpentane 79 38
2,2,3,4-Tetrame thy lpentane 79
2,2,4,4-Tetramethy lpentane 79
2,3,3,4-Tetramethylpentane 79

n-Decane 65 94 15, 32, 37

41,78
2-Methylnonane 79 67 15
3-Methylnonane 79 15
4-Methylnonane 79 15
5-Methylnonane 79 16

3-Ethyloctane 38

2,2-Dimethyloctane 38
2,3-DimethyIoctane
2,4-Dimethyloctane

2,5-Dimethyloctane
2,6-Dimethyloctane 38
2,7-Dimethyloctane 79 38,41
3,3-Dimethyloctane
3,4-Dimethyloctane

3,6-Dimethyloctane 38
4,5-D ime thy Ioc tane 38
4-n-Propylheptane 38
3-Methyl-3-ethylheptane 38
2,2,3-Trime thy Iheptane

2,2,6-Trimethylheptane 28 79 38
2,4,6-Trimethy Iheptane 38
3,3,5-Trimethylheptane 38
3,3-D iethy lhexane 38
2,2-Dimethy 1-3-ethylhexane 38

2,2,3,4-Tetramethylhexane
2,2,5,5-Tetramethy lhexane
3,3,4,4-Tetramethylhexane 38

Cycloparaffins:
Cyclopropane 26 29
Ethylcyclobutane 26 90

Cyclopentane 11, 18, 32,

33, 41, 42,
78
Methylcyclopentane 44 55 11, 18, 21,
32, 33, 41,
'42, 78

Ethylcyclopentane 26 18, 32, 33,

41,42
1,1-Dimethylcyclopentane 49 28
1 ,cis-2-Dimethylcyclopentane 49 17

66
 1C1.17
KEY TO REFERENCES—Continued
C ritical
Constants Heat
Heat of Heat Flam-
Vapor Freez- Heat Den- Refrac- Capac- Vapori- of mabil- Aniline Point Com-
No. Compound Boiling Pres- ing (- Capac- sity, tive ity, zation Com- ity or Critical pressi-
Point sure Point 3 ity, Liquid Index, Ideal at bus- Limits Solution bility
a> o Liquid Liquid Gas Normal tion, (Meas- Temperature Factor
D ft s Boiling Liquid ured)
in
S Point
& £-< l>

1C1.2 Cycloparaffins—Continued: -
28 1, tra ns-2-DimethyIcyclopentane 17,43
29 l,cts-3-Dimethylcyclopentane 49
30 1, irans-3-Dimethylcyclopentane 18, 20, 32,
33, 41, 42,
43
31 n-Propylcyclopentane 77 77 77 63 18, 32, 33,
41,42
32 Isopropylcyclopentane 77 77 77 79 47,80
33 1-Methyl-l-ethyleyclopentane 7 77 77 77 79 47,80
34 l-Methyl-cis-2-ethylcyclopentane 77 77 77 79 47,80 25
35 l-Methyl-*rans-2-ethylcycIopentane 25 77 77 77 79 47,80 25
36 l-Methyl-cis-3-ethylcyclopentane 77 77 77 79 47,80
37 l-Methyl-(rons-3-ethylcycIopentane 77 77 77 79 47,80

38 1,1,2-TrimethyIcyclopentane 77 77 77 79 47,80
39 1,1,3-Trimethylcyclopentane 77 77 77 79 47,80
40 l,ct's-2,cis-3-Trimethylcyclopentane 77 77 77 79 47,80
41 1,cis-2, *rans-3-Trimethylcyclopentane 77 77 77 79 47,80 41
42 l,/TO«s-2,ci.s-3-Triniethy]cye]opentane 5 77 77 77 79 47,80 41

43 1, cis-2, cis-4-Trimethyleyclopentane S 5 77 77 77 5 5 79 47,80

44 1, cis-2, <r<ms-4-Trimethylcy clopentane 77 77 77 79 47,80
45 1, trans-2, cis-4-Trimethy lcyclopentane 77 77 77 79 47,80
46 n-Butylcyclopentane 47 77 77 77 63 18, 32,33,
41,42
47 Isob utylcyclopentane 47 77 77 77 79 47 47,80

48 sec-Butylcyclopentane 47 77 77 77 79 47 47,80
49 teri-Butylcyclopentane 47 77 77 77 79 47 47,80
51 l-Methyl-cis-2-n-propylcyclopentane 47 77 77 77 79 47 47,80 24
52 l-Methyl-/rans-2-n-propylcyclopentane 47 77 77 77 79 47 47,80 24
58 l-Methyl-cis-3-isopropylcyclopentane 47 77 77 77 79 47 47,80

59 l-Methyl-(rans-3-isopropyIcyclopentane 47 77 77 77 79 47
61 1 ,cis-2-Diethylcyclopentane 47 77 77 77 79 47 23
62 1, *rans-2-Diethylcyclopentane 47 77 77 77 79 47 23
90 1,1,3,3-Tetramethylcyclopentane 6 6
91 1, l-cis-3,cis-4-Tetramethylcyclopentane 6 6 6
92 1, l-cis-3, toms-4-Tetramethy lcyclopentane 6 5 5 5,6
95 1,cis-2,cis-4-Tetramethylcyclopentane 5 5 5 5
96 1,cis-2, cis-3, trans-i- Tetramethy lcyclopentane 5 5 5
97 1, cis-2, £rans-3,cis-4-Tetramethylcyclopentane 5 5 5 5
98 1, cis-2, <rans-3,/rans-4-Tetramethylcyclo- 5 5 5 5
pentane
99 1, trans-2 ,cis-3, (rans-4-Tetramethylcyclo- 5 5 5
pentane
100 1, trans-2 ,trans-3, cis-4-Tetramethylcyclo- 5 5 5 5
pentane
101 w-Pentylcyclopentane
102 Cyclohexane 76

103 Methyleyclohexane 26 11,18, 21,

22, 23, 32,
53, 82, 90
104 Ethylcyclohexane 32,42
105 1,1-Dimethy lcyclohexane 59
106 1 ,ci s-2-Dimethylcyclohexane 41, 59, 97

107 1, (rans-2-D imethy lcyclohexane 59

108 1 ,cis-3-Dimethylcyclohexane 59
109 1, frans-3-Dimethylcyclohexane 77 59
110 l,cis-4-Dimethylcyclohexane 77 41,59
111 1, irans-4-Dimethylcyelohexane 59

112 n-Propylcyclohexane 77 77 77 35 32,42

113 Isopropylcyclohexane 77 77 77 79 47 47,80
115 1-Methyl, cis-2-ethy lcyclohexane 5 5 5
117 1-Methyl,cis-3-ethylcyclohexane 7 5 5,6
118 1-Methyl, irans-3-ethylcyclohexane 5 5 5
119 1-Methyl,cis-4-ethylcyclohexane 6 5 5
120 1-Methyl, «rons-4-ethylcyclohexane 6 6 5 5
121 1,1,2-Trimethylcyclohexane 47 77 77 77 79 47 47,80

67
 1C1.17
KEY TO REFERENCES—Continued
Critical
Constants Heat
Heat of Heat Flam-
Vapor Freez- Heat Den- Refrac- Capac- Vapori- of mabil- Aniline Point Com-
No. Compound Boiling Pres- ing (* Capac- sity, tive ity, zation Com- ity or Critical pressi-
Point sure Point *i ity, Liquid Index, Ideal at bus- Limits Solution bility
u
0) U V Liquid Liquid Gas Normal tion, (Meas- Temperature Factor
3 Q. E Boiling Liquid ured)
3 Point
3
£ 4)
EH >
1C1.2 Cycloparaffins—Continued:
122 1,1,3-Trimethylcyclohexane 77 77 77 79 47 47,80
124 l,cts-2,cts-3-Trimethylcyclohexane 5 5 5 5
125 l,ci«-2,*rans-3-TrimethyIcycIohexane 5 5 5 5
127 1, cis-2, c?V4-Tr imethylcyclohexane 5 5 5 5
128 l,cis-2,flrans-4-TrimethylcycIohexane 5 5 5 5
129 1, trans-2, ct's-4-Trimethy lcyolohexane 5 5 5 5
130 l,(raKs-2,frans-4-Trimethylcyclohexane 47 77 77 77 88
133 n-Butylcyclohexane 77 77 77 35 79 35 32,42
134 Isob utylcyclohexane 3 81 77 77 77 3 3 79 47 47,80 28
135 sec-Butylcyclohexane 3 3 77 77 77 3 3 79 47 47,80
136 *er/-Butylcyclohexane 3 3 77 77 77 3 3 79 47 47,80 28
137 l-MethyI-4-isopropylcydohexane 3 47 3 77 77 77 79 47 47,80 28

138 Cycloheptane 36 36 79
139 Ethylcycloheptane 28 47 77 77 77 28 79 47,80
140 Cyclooctane 39 36 79 47 47,80
141 Methylcyclooctane 28 47 77 77 77 28 79 '47 47,80
142 Cyclononane 47 79

143 Cyclodecane
144 crs-Decahydronaphthalene 61 32
145 trans- Decahydro naphthalene 61 32

1C1.3 Monoolefins and Diolefins:

1 Ethene (ethylene) 26 29
2 Propene (propylene) 48 26 29
3 1-Butene 69 26 29
4 cts-2-Butene 48 29
5 (rons-2-Butene 48 29
6 2-Methylpropene (isobutene) 48 57 29

7 1-Pentene 26 32 29
8 «'s-2-Pentene 28, 32, 96 73
9 (rans-2-Pentene 28, 32, 96 73
10 2-Methyl-l-butene 29
11 3-Methyl-l-butene 29
12 2-MethyI-2-butene 12, 32, 41, 29
53

13 1-Hexene 60 32
14 cis-2-Hexene 8 8 8 32
15 frans-2-Hexene 8 8 8 32
16 cts-3-Hexene 8 8 8 28
17 (rans-3-Hexene 8 8 8 28

21 2-MethyI-2-pentene 8 8 8
22 3-Methyl-«'s-2-pentene 8 8 8
23 3-MethyI-irans-2-pentene 8 8 8
27 2,3-Dimethyl-l-butene 8 8 8
28 3,3-Dimethyl-l-butene 8 8 8
29 2,3-DimethyI-2-butene 8 8 8

30 1-Heptene 60 74 32
33 cis-3-Heptene 28
34 *rans-3-Heptene 28
48 3-Methyl-cis-3-hexene 74
49 3-MethyI-(rans-3-hexene 74
53 2,4-DimethyI-l-pentene 74
56 4,4-Dimethyl-l-pentene 8 8 8 79 47,80
58 2,3-Dimethyl-2-pentene 8 8 8 79 47,80
65 2,3,3-Trimethy I-1-butene 8 8 8 79 47,80 19

66 1-Ootene 60 74
67 cts-2-Octene 8 8 8 79 47,80
68 (rans-2-Octene 8 8 8 79 47,80
70 trans-3-Octene 8 8 8 79 47,80
71 cts-4-Octene 8 8 8 79 47,80
72 irans-4-Octene 8 8, 8 79 47,80

73 2-MethyI-l-heptene 8 8 8 79 47,80
113 2,3-Dimethy i-2-hexene 8 8 8 79 47,80
127 2,2-DimethyI-cts-3-hexene ... 74

68
 1C1.17
KEY TO REFERENCES—Continued
Critical
Constants Heat
Heat of Heat Flam-
Vapor Freez- Heat Den- Refrac- Capac- Vapori- of mabil- Aniline Point Com-
No. Compound Boiling Pres- ing Capac- sity, tive ity, zation Com- or Critical pressi-
Point sure Point ity, Liquid Index, Ideal at bus- Limits Solution bility
0) u o Liquid Liquid Gas Normal tion, (Meas- Temperature Factor
G S Boiling Liquid ured)
tn
S 3
Point
0<

1C1.3 Monoolefins and Dioleftns—Continued:

128 2,2-Dimethyl-(r<m8-3-hexene 74
141 2-MethyI-3-ethyI-l-pentene 74
144 2,3,3-Trimethyl-l-pentene 8 8 8
146 2,4,4-Trimethyl-l-pentene 8 8 8
153 2,4,4-Trimethy 1-2-pentene 8 8 8 53

158 1-Nonene 32
160 2,3-D imethyl-2-heptene 47 8 8 8 79 47,80
161 1-Decene 28

163 Propadiene (allene) 47 47 2,47 29

164 1,2-Butadiene 47 47 56
165 1,3-Butadiene 47 47 73
166 1,2-Pentadiene 47 39 56
167 1, cis-3-Pentadiene 47 39 56

168 1, *rans-3-Pentadiene 47 39 56
169 1,4-Pentadiene 47 39 56
170 2,3-Pentadiene 47 39 56
171 3-Methyl-l ,2-butadiene 70 47 39 56
172 2-Methy 1-1,3-butadiene (isoprene) 47 39 56

174 1 ,cis-3-Hexadiene 5 5 5
175 1, *rans-3-Hexadiene 5 5 5 5
176 1, cis-4-Hexa diene 5 b
177 1, (rans-4-Hexadiene 5 5 5

178 1,5-Hexadiene 47 8 8 8 79 47 47,80

180 «3-2,«s-4-Hexadiene 5 5 5 5
181 cis-2, frans-4-Hexadiene 5 5 5 5
182 trans-2, (rans-4-Hexadiene 5 5 5 5

186 2-Methyl-l ,tams-2-pentadiene 6 6 5,6

189 4-Methyl-l ,3-pentadiene 5 47 5 8 8 8 5 79 47 47,80
194 2,3-DimethyI-l, 3-butadiene 47 8 8 8 79 47 47,80
195 2-Methyl-l, 5-hexadiene 28 47 28 8 8 8 79 47 47,80
196 2-Methyl-2,4-hexadiene 28 47 28 8 8 8 79 47 47,80

197 2,4-Dimethyl-l ,3-pentadiene 28 47 28 8 8 8 79 47 47,80

198 2,6-Octadiene 28 47 28 8 8 8 79 47 47,80
199 3-Methyl-l ,5-heptadiene 28 47 28 8 8 8 79 47 47,80
200 2,5-Dimethy 1-1,5-hexadiene 28 47 28 8 8 8 79 47 47,80
201 2,5-Dimethyl-2,4-hexadiene 28 47 28 8 8 8 79 47 47,80
202 2,6-Dimethyl-l, 5-heptadiene 28 47 28 8 8 8 28,40 79 47 47,80
203 2-Methyl-3-ethy 1-1,5-hexadiene 28 47 28 8 8 8 28,40 79 47 47,80
204 3,7-Dimethyl-l, 6-octadiene 28 47 28 8 8 8 28,40 79 47 47,80

1C1.4 Cyclooleflns:
1 Cyclopentene 32,42 56
2 1-Methylcyclopentene 76 44 32,42
3 3-Methylcyclopentene 76
4 4-Methylcyclopentene 76
5 1-Ethylcyclopentene 76 32,42
6 3-EthyIcyclopentene 76
7 4-Ethylcyclopentene 76
8 1,2-DimethyIcyclopentcne 76
9 1,3-Dimethylcyclopentene 76
10 1,4-Dimethylcyclopentene 76
11 1,5-Dimethylcyclopentene 76
12 3,3-Dimethylcyclopentene 76
13 3,m-4-Dimethylcyclopentene 76
14 3,<rans-4-Dimethylcyclopentene 76
15 3, cts-5-Dimethylcyclopentene 76
16 3,-*ra«5-5-DimethyIcyclopentene 76
17 4,4-Dimethylcyclopentene 76
18 1-n-Propylcyclopentene 76 32,42
19 1-n-Butylcyelopentene 76 32,42
20 1-ft-Pentylcyclopentene 78

21 Cyclohexene 76 44 32, 41, 53

... j
22 1-Methylcyclohexene 76 16
23 3-Methylcyclohexene 76 ... ...

69
 1C1.17
KEY TO REFERENCES—Continued
Critical
Constants Heat
Heat of Heat Flam-
Vapor Freez- Heat Den- Refrac- Capac- Vapori- of mabil- Aniline Point Com-
No. Compound Boiling Pres- ing u
D
Capac- sity, tive I ty, zation Com- ity or Critical pressi-
Point sure Point ity, Liquid Index, Ideal at bus- Limits Solution bility
a> Liquid Liquid Gas Normal tion, (Meas- Temperature Factor
3
c sa
o
Boiling Liquid ured)
Point
CO
S
£ H >

1C1.4 Cycloolefins—Continued:
24 4-Methy lcyclohexene 76
25 1-Ethylcyclohexene 76 16
26 3-Ethylcyclohexene 76
27 4-Ethylcyclohexene 76
28 1,2-Dimethylcyclohexene 76
29 1,3-Dimethylcyclohexene 76
30 1,4-Dimethylcyclohexene 76
31 1,5-DimethylcycIohexene 76
32 1,6-Dimethy lcyclohexene 76
33 3,3-Dimethy ley clohexene 76
34 4,4-Dimethy lcyclohexene 76
35 l-w-Propylcyclohexene 76
36 1-n-Butylcyclohexene 76
37 4-Vinylcyclohexene 71 71 71 76 71 71
38 1,5-Cyclooc tadiene 71 71 71 71 71

1C1.S Acetylenes:
1 Ethyne (acetylene) 28,40 26 27
2 Propyne (methylacetylene) 8 28,40 47 29
3 1-Butyne (ethylacetylene) 47 8 8 47 29
4 2-Butyne (dimethylacetylene) 8 8 47 56
5 1-Pentyne 8 8 76 47 56
6 2-Pentyne 8 8 8 76 47 56
7 3-Methyl-l-butyne 76 56
8 1-Hexyne 47 8 8 8 76 47 2,47
9 2-Hexyne 76
10 3-Hexyne 47 8 8 8 76 79 47 47,80
11 3-Methyl-l-pentyne 76
12 4-Methyl-l-pentyne 76
13 4-Methyl-2-pentyne 76
14 3,3-Dimethyl-l-butyne 76
15 1-Heptyne 47 8 8 8 76 47 47,80
16 2-Heptyne 76
17 3-Heptyne 76
18 3-Methyl-l-hexyne 76
19 4-Methyl-l-hexyne 76
20 5-Methyl-l-hexyne 47 8 8 8 76 79 47 47,80
21 4-Methyl-2-hexyne 76
22 5-Methyl-2-hexyne 76
23 2-Methyl-3-hexyne 76
24 3-Ethyl-l-pentyne 76
25 3,3-Dimethyl-l-pentyne 76
26 3,4-Dimethy 1-1-penty ne 76
27 4,4-Dimethyl-l-pentyne 76 ...
28 4,4-Dimethyl-2-pentyne 76

29 1-Octyne 47 8 8 8 76 79 47,80
30 2-Octyne 47 52 8 8 8 76 79 47 47,80
31 3-Octyne 47 8 8 8 76 79 47 47,80
32 4-Octyne 28 47 52 8 8 8 76 28 3 1,52 47 2,47 ...
33 1-Nonyne 47 8 8 8 76 47 2,47
34 2-Nonyne 76
35 3-Nonyne 76
36 1-Decyne 76
37 2-Decyne 76
38 3-Decyne 76

1C1.6 Alkylbenzenes, Naphthalene, Indans, and

Tetrahydronaphthalene:
1 Benzene 7 93 12,42
2 Methylbenzene (toluene) ... 75 75 93 42
3 Ethylbenzene 93 42
4 1,2-Dimethylbenzene (o-xylene) 93 12
5 1,3-Dimethylbenzene (wi-xylene) 93 28

6 1,4-Dimethy lbenzene (p-xylene) 7 93 28

7 re-Propylbenzene 64 34,42
8 Isopropy lbenzene (cumene) 76 93 12
9 l-Methyl-2-ethylbenzene 76
10 l-Methyl-3-ethylbenzene 76

70
 1C1.17
KEY TO REFERENCES—Continued
Critical
Constants Heat
Heat of Heat Flam-
Vapor Freez- Heat Den- Refrac- Capac- Vapori- of mabil- Aniline Point Com-
No. Compound Boiling Pres- ing 3
Capac- sity, tive ity, zation Com- ity or Critical pressi-
Point sure Point ity, Liquid Index, Ideal at bus- Limits Solution bility
u
0>
o Liquid Liquid Gas Normal tion, (Meas- Temperature Factor
ty Boiling Liquid ured)
3
to C. S
in £ _3 Point
<o
PN

1C1.6 Alkylbenzenes, Naphthalene, Indans, and

Tetrahydronaphthalene—Continued:
11 l-Methyl-4-ethylbenzene 76
12 1,2,3-Trimethy lbenzene
13 1,2,4-Trimethylbenzene
14 1,3,5-Trimethy lbenzene 42
15 n-Butylbenzene (1-phenylbutane) 64 26 34,42

16 Isobutylbenzene (l-phenyl-2-methyl- 77 76 76 47,80

propane)
17 sec-Butylbenzene (2-phenylbutane) 77 77 77 76 76 47,80
18 (erf-Butylbenzene (2-phenyI-2-methyl- 77 77 77 76 76 47,80
propane)
19 l-Methyl-2-propylbenzene 76
20 l-Methyl-3-propylbenzene 76
21 l-Methyl-4-propylbenzene 76

22 l-Methyl-2-isopropylbenzene (o-cymene) 28 77 77 76 76 47,80

23 l-Methyl-3-isopropyIbenzene (m-cymene) 77 77 77 76 76 47,80
24 l-Methyl-4-isopropylbenzene (p-cymene) 77 76 47,80
36 1,2,4,6-Tetramethylbenzene (durene)
37 Naphthalene 61
43 1,2,3,4-Tetrahydronaphthalene 61

1C1.7 Styrenes and Indenes:

1 Ethenylbenzene (styrene; vinylbenzene; 47 77 77 77 28 26
phenylethylene)
2 Isopropenylbenzene (a-methylstyrene; 47 77 77 77 76 28 2,47
2-Phenyl-l-propene)
3 ci8- 1-Propenylbenzene (cts-j3-methylstyrene; 47 77 77 77 76 28 2,47
cifi-1-Phenyl-l-propene)
4 irans-1-Propenylbenzene (trans-(3-methy\- 47 77 76 28 2,47
styrene; trans-1-Phenyl-1-propene)
5 l-Methyl-2-ethenylbenzene (o-methyl- 47 77 77 77 76 28 2,47
styrene)
6 l-Methyl-3-ethenylbenzene (m-methyl- 47 77 77 77 76 28 2,47
styrene)
7 l-Methenyl-4-ethenylbenzene (p-methyl- 47 77 77 77 76 28 2,47
styrene)

32 Phenylacetylene 28 47 28 77 77 77 28 2i 79 28 47,80

V. REFERENCES

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72