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H&H Lect05

The document outlines the preparation and reactions of haloarenes, including halogenation and various substitution reactions. It discusses the stability of intermediates and the conditions required for reactions to occur, emphasizing the role of electrophiles and free radicals. Additionally, it mentions specific reactions such as the Balasubramanian and Grignard reactions, highlighting the unique properties of haloarenes in chemical processes.

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33 views8 pages

H&H Lect05

The document outlines the preparation and reactions of haloarenes, including halogenation and various substitution reactions. It discusses the stability of intermediates and the conditions required for reactions to occur, emphasizing the role of electrophiles and free radicals. Additionally, it mentions specific reactions such as the Balasubramanian and Grignard reactions, highlighting the unique properties of haloarenes in chemical processes.

Uploaded by

ekuaru10
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
Oo —— — Preperation of Haloarven es: - jNvcieae HALOGENATION P Atel c = Ale wos +d, >t 310- 320K (O] ste ; = mr Clectephillic subs. ___Elerropwite = 28 a > e - - - L® Gren em exation of dlectno plite aL — Ad, tu, —> Ara,© +u® L t “Aes eR eee Ald, er oS ix Cl- ap clus te braeme of Rone paix id 6- & f- ee tousrels Taio Se Ow rer “eT La LAs “tH, ¢ ake Eve © So, ibis o}p ce Se} aa +4 oy ae Stele chain Sube Htulion ate free radical g = | ee = : ae (O] + ty = fe] thr | HIo, + HL —> Hho +t, | [snigns the egbyn tn forwarel diction) - ia CHC, Es | oO 167 2? fant 12 ee sou oe oes TL a olinzonium Sali! ———————— % NHS > ol “+ HONO+ HU ae 3 —— ———Betnane bladed — Aniline Note :-* 24 “the temperate © nev RsTs then as as —— ee ete pe al ped s Sanches reachon me cuct] Hee A me (Ol ————, foltn Bala -schiemenn reaction re PO + Sim go +N, +B — |B Grattermonn's Tesetion: — OS au ~ a +o te fe J ee ae z : | kz y 7 +I fey _% Hurmdsdiceter'e veschon ! | ey ae Oy Sto rat a thet CI tee, + Ager. F * Phenet doant undergo nuchaphstie Subs babe | h oony$ halide oo luy g b — Dur te reornn ¢-0 bond in prone! acquire owhal clonbte bond Charctir as shown below. t we te vohich co bond fs diffindt te a“ - | ee +o r re Ao 4 ae é- << [ie eae {| <3 927 | es ee - i ae Wve : ~ — oH = _ _ a z - nm —¥v “4 - 7 ; | Chemresd properties: = — Halvarunes are exivemely Lew reachie towels philic cabstitution — olay? _ + Retenomes eet ea Selmore Coavhen Cef c-x bend) s}* ft a = oO - ReeH,- x _ “Imo S-cheraéhe => mere elecwnegctint > Morghe: L = 4: Instability of prongs cation / | ese > /_~y@ +a© —_ | ; { rt 1 Doses prten: x _N plilue Subs. Can oeeur only in te wren of rate Concltions | e+ 7 ‘ents (3) te CS | %_presene of Ee, peak: -NO, ,- CN ete. ato Ip ties 2 octiyahs the bal deel rely le T ~ re cing ft ; [eo Cae Talen LOT — ee - on ; = AD itsnao , ee esl Greet — a - eH : Nest = - gree 5 cer™ — x HDi net nen _ faa a diy us tor a | Baa T Oita th ti Ney ar NSE er neh — Don a | “5 | = = aes ; [Her R.D-s Jessa involv the cleavage of cH bend. Gncteool £-Ds involve dhe oddack ef nueleo pltle tou) mn _eheclavplilie Carbon ; e, woite ot veaclion dep ends ™M the Hecke pl piultiealy | Roe 2_qreste Ihe elelre pliticity of ERGERDE nine | &B iS Av-GY Av-Ov 2? Aver 7 [ Nofe tk In contrast oxoley of rechvily « fo otek bolas : te she role = I> RBr> RU > dh nthe presence of flow poir — - samen a Je oo direction a Misceblamenus Yeactons ! Baty Seocken COD + anos aKoy 5 atest (O>{oyY Ai pheng loude ity yun: { ODL Anat cht, Ueto, Tetuene. ULtmonv's Teacton’ rttu+1fLO\ +> (ONO (Oy + XD sey {OxXo> Formation of 194 nard!s 7 (Oat me (oO ar

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