tlkhfhzf; fy;tpj; jpizf;fsj;Jld; ,ize;J

njhz;ilkhdhW ntspf;fs epiyak; elhj;Jk;

jtizg; guPl;ir> khu;r; - 2020
Conducted by Field Work Centre, Thondaimanaru
In Collaboration with Provincial Department of Education
Northern Province
FWC
Term Examination, March - 2020

juk; :- 13 (2020) ,urhadtpay; - II A Neuk; :- 3 kzpj;jpahyk; 10 epkplk;

gFjp - II A
mikg;Gf; fl;Liu tpdhf;fs;
™ ehd;F tpdhf;fSf;Fk; tpil jUf.

g
(xt;nthU tpdhtpd; tpilf;Fk; 10 Gs;spfs; toq;fg;gLk;)

or
1) (A) milg;Gf;Fwpfspy; jug;gl;Ls;s ,ay;G FiwAk; tupirapy; gpd;tUtdtw;iw
xOq;FgLj;Jf. (fhuzq;fs; mtrpakpy;iy)
(i) HCHO, CO , CH Br, HCN (fhgdpd; kpd;ndjpu;jd;ik)

.
………………………………………………………………………………………………..
on
(ii) LiNO , NaNO , RbNO , KNO (ePupy; fiujpwd;)
………………………………………………………………………………………………..
(iii) Be, F, S, P (Kjyhk; madhf;fy; rf;jp)
ee
………………………………………………………………………………………………..
(iv) (3, 0, 0, +1/2) , (3, 1, 0, +1/2), (2, 0, 0, +1/2), (2, 1, 0, +1/2) (,yj;jpud; epug;gg;gLk;
xOf;fpd; rf;jp epiyfs;)
………………………………………………………………………………………………..
.b

(v) SO , SO , SO , SO (gpizg;Gf; Nfhzk;)

………………………………………………………………………………………………..
w

(vi) P, Cl, Al, Na (,yj;jpud; Vw;wrf;jp)

………………………………………………………………………………………………..
(6 x 5 = 30 Gs;spfs;)
w

(B)

(i) gpd;tUk; fl;likg;G Y}apapd; fl;likg;ig mbg;gilahff; nfhz;L fPNo

w

jug;gl;Ls;sJ. C, N, O, H Mfpa mZf;fs; njhlu;ghf

1. mZitr;#oTs;s VSEPR Nrhbfs;
2. mZitr; #oTs;s ,yj;jpud;NrhbNfj;jpu fzpjk;
3. mZitr; #oTs;s tbtk;.
4. mZtpd; fyg;ghf;fk; vd;gtw;iwf; Fwpg;gpLf.
H O H H
| || | |
:N C C C O C C H
| | |
H H H

Grade - 13 (2020) March – 2020 F.W.C 1 Chemistry II A

 mZf;fs; gpd;tUkhW ,yf;fkplg;gl;Ls;sd.

H O H H
| || | |
(ii) N C C C O C C H
| | |
H H H

N C C O
(i) VSEPR Nrhbfs;
(ii) ,yj;jpud; Nrhb Nfj;jpufzpjk;
(iii) tbtk;

g
(iv) fyg;ghf;fk;
(6 x 1 = 16 Gs;spfs;)

or
(ii) NkNy gFjp (i) ,y; jug;gl;Ls;s Y}apapd; fl;likg;gpy; gpd;tUk;
gpizg;Gf;fspd; cUthf;fj;Jld; rk;ge;jg;gl;l mZfyg;gpd; xgpw;wy;fis
,dk; fhz;f. gFjp (i) ,y; cs;sthW mZf;fs; ,yf;fkplg;gl;Ls;sd.

.
(i) N - C
(ii) C - O
(iii) C - O
on N ..........................
C ...........................
C ...........................
C
O
O
...................................
...................................
...................................
(iv) C - C C ............................ C ...................................
ee
(8 x 1 = 08 Gs;spfs;)
(iii) NkNy gFjp (i) jug;gl;l Y}apapd; fl;likg;gpy; gpizg;Gfspd;
cUthf;fj;Jld; rk;ge;jg;gl;l mZ xgpw;wy;fis ,dk; fhz;f.
.b

i. N - C N ...................... C ..................................
ii. C - O C ...................... O .................................
(4 x 1 = 04 Gs;spfs;)
w

(iv) gpd;tUk; %yf;$Wfspd; Y}apapd; Gs;spf;Nfhl;Lf; fl;likg;ig tiue;J

tbtj;ij ca;j;jwpf.
w

i. SO ii. CH Cl
w

(7 x 2 = 14 Gs;spfs;)

Grade - 13 (2020) March – 2020 F.W.C 2 Chemistry II A

 (C) gpd;tUk; tpdhf;fs; vijd; %yf;$wpd; (CH CH) C C fhgd; - fhgd;
gpizg;GfSf;fpilapyhd xU gpizg;G kw;Wk; ,uz;L gpizg;GfSld;
njhlu;Ggl;lJ. nghUj;jkhd tpilj;njuptpd; fPo; NfhbLf.
i. Nkw;gb vijd; %yf;$wpy; ,uz;L fhgd; mZf;fspdJk; fyg;G
xgpw;wy;fspd; gq;fspg;Gld; cUthf;fg;gLk; Nkw;nghUe;Jif tif vJ?
Neu;Nfhl;L Nkw;nghUe;Jif / gf;fthl;L Nkw;nghUe;Jif
ii. Nkw;gb nghUe;JifAld; njhlu;Ggl;l gpizg;G tif?
gpizg;G / gpizg;G

iii. Nkw;gb vijd; %yf;$wpd; ,uz;L fhgd; mZf;fspdJk; mZ xOf;Ffspd;

g
gq;fspg;Gld; njhlu;Ggl;l Nkw;nghUe;;Jif tif vJ?
Neu;Nfhl;L Nkw;nghUe;Jif / gf;fthl;L Nkw;nghUe;Jif

or
iv. Nkw;gb nghUe;JiffSld; njhlu;Ggl;l gpizg;G tif vJ?
gpizg;G / gpizg;G
(4 x 3 = 12 Gs;spfs;)

.
(D) gpd;tUk; on
Nrhbfis
%yf;$w;wpil ,uz;lhk; epiy tpirfspd; tifia / tiffis Fwpg;gpLf.
I. HCl ck; Ar
xt;nthd;wpYk; cs;s ,dq;fSf;fpilNa ,Uf;Fk;

ck; ...........................................................................................................................
II. C H OH ck; H O
ee
..........................................................................................................................
III. ck; H O ck; ........................................................................................................................ 100
(8 x 2 = 16 Gs;spfs;)
.b

2) (A) gpd;tUk; tpdhthdJ $l;lk; 15 %yfq;fspd; FNshiul;Lf;fSld; njhlu;Ggl;lJ.

(i) $l;lk; 15 %yfq;fs; cUthf;Fk; rhj;jpakhd FNshiul;Lf;fs; ahtw;iwAk;
Fwpg;gpl;L mtw;wpd; kpif ePUldhd rkg;gLj;jg;gl;l ,urhadr; rkd;ghLfisj;
w

jUf.
...............................................................................................................................................................................
w

...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
w

...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
(6 x 1 = 06 Gs;spfs;)
(6 x 3 = 18 Gs;spfs;)

Grade - 13 (2020) March – 2020 F.W.C 3 Chemistry II A

 (ii) Mtu;j;jz ml;ltizapy; ,uz;lhk; Mtu;j;jdj;jpy; cs;s $l;lk; 15 %yfk;
Q ,d; Kf;FNshiul;Lk; (QCl ). %d;whk; Mtu;j;jdj;jpy; cs;s $l;lk; 15
%yfk; R ,d; Kf;FNshiul;Lk; (RCl ) %yf;$w;W tbtj;jpy; xNu khjpupahf
mike;Js;s NghjpYk; mtw;wpf;fpilapyhd gpizg;Gf; Nfhzk; NtWgl;Lf;
fhzg;gLfpd;wJ. ,f; $w;iw RUf;fkhf tpsf;Ff.
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................

g
.................................................................................................................................................
(10 Gs;spfs;)

or
(B) gpd;tUk; ml;ltiz ‘3d’ njhFg;G %yfq;fspd; fw;wad;fs; Njhw;Wtpf;Fk; rpf;fy;
mad;fSld; njhlu;Ggl;lJ.
ml;ltizapy; Fwpg;gplg;gl;Ls;s 3d %yff; fw;wad;fs; jug;gl;Ls;s

.
,izapfSld; rpf;fy; mad;fisj; Njhw;Wtpg;gpd; mtw;iwf; Fwpg;gpl;L mjd;

cNyhf fw;wad;
on
epwq;fisAk; Fwpg;gpl;L fPo;tUk; ml;ltizia G+u;j;jp nra;f.

,izapapd; jd;ik

H O NH Cl
ee
I. rpf;fy; madpd; epwk;

II.
rpf;fy; madpd; epwk;
.b

III.
rpf;fy; madpd; epwk;

IV.
w

rpf;fy; madpd; epwk;

rpf;fy; mad; : 12 x 02 = 24 Gs;spfs;
epwk; : 12 x 01 = 12 Gs;spfs;
w

(C) gpd;tUk; %yf;$Wfs; xl;rpNaw;wpahfTk;> jho;jj

; pahfTk; njhopw;gLk;
re;ju;gg
; q;fSf;fhd rkg;gLj;jg;gl;l ,urhadr; rkd;ghLfisj; jUf.
w

SO
xl;rpNaw;wpahf :- .................................................................................................................
jho;jj
; pahf :- .................................................................................................................
H S
xl;rpNaw;wpahf :- .................................................................................................................
jho;jj
; pahf :- .................................................................................................................
NH
xl;rpNaw;wpahf :- .................................................................................................................
jho;jj
; pahf :- .................................................................................................................
(6 x 5 = 30 Gs;spfs;) 100

Grade - 13 (2020) March – 2020 F.W.C 4 Chemistry II A

03) (A) 25 C ,y; Fwpj;j nrwpTs;s xU %y nkd;dkpyk; HA ,d; 25 cm MdJ
0.1 moldm NaOH fiurypdhy; tYg;ghu;f;fg;gl;l NghJ fiurypy; Vw;gLk; pH
khw;wj;ij fPo;j; jug;gl;l tiuG Fwpf;fpd;wJ. (25 C ,y; K 1 x 10 mol dm )
,U fhl;bfs; X, Y vd;gtw;wpd; epwkhw;w pH tPr;Rf;fSk; mUfpy; jug;gl;Ls;sd.

fhl;b epwkhw;w pH tPrR

;
pH
X 4–6
C Y 8.5 – 10
B
5

g
A
Nru;f;fg;gl;l ,d;

or
0 25 50 fdtsT

(i) nkd;dkpy HA ,d; Muk;gr; nrwpT ahJ?

.
...............................................................................................................................................................................
...............................................................................................................................................................................
on
...............................................................................................................................................................................
...............................................................................................................................................................................
(05 Gs;spfs;)
(ii) nkd;dkpyj;jpd; madhf;f khwpyp Ka If; fzpf;Ff.
ee
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
.b

(10 Gs;spfs;)
(iii) Gs;sp A ,w;Fupa pH ngWkhdj;ijf; fzpf;f?
...............................................................................................................................................................................
w

...............................................................................................................................................................................
...............................................................................................................................................................................
(05 Gs;spfs;)
w

(iv) ,e;epakpg;gpd; rktY epiyf;Fupa Gs;sp C vdpy; Gs;sp C ,dhy; Fwpaplg;gLk;

pH ngWkhdj;ij fzpf;Ff.
w

...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
(15 Gs;spfs;)

Grade - 13 (2020) March – 2020 F.W.C 5 Chemistry II A

 (v) epakpg;G njhlu;ghf KbTg;Gs;sp> rktYg;Gs;sp vd;gtw;wpd; NtWghl;il
tpsf;Ff.
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
...............................................................................................................................................................................
(10 Gs;spfs;)
(vi) jug;gl;l fhl;bfs; X, Y vd;gtw;wpy; Nkw;gb epakpg;Gf;Fg; nghUj;jkhd fhl;b
vJ? fhuzk; jUf.

g
...............................................................................................................................................................................
...............................................................................................................................................................................

or
...............................................................................................................................................................................
(05 Gs;spfs;)
(B) Gwf;fzpf;fj;jf;f ntg;gf;nfhs;sTila xU ghj;jpuj;jpDs; 4 moldm HCl ,d;

.
25 cm fiury; vLf;fg;gl;L mjDs; J}shf;fg;gl;l MgCO jpz;kj;jpd; 2.1 g ,l;L

(i)
on
ed;F fyf;fg;gl;lJ. (Mg = 24 , O = 16, C = 12)
MgCO 2HCl MgCl
NkNy Fwpg;gplg;gl;l nrad;Kiwapd; NghJ ntsptplg;gl;l ntg;gj;jpidf;
H O CO > ∆H 40kJmol

fzpf;f.
ee
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
.b

.................................................................................................................................................................................
(10 Gs;spfs;)
(ii) fiurypd; mlu;j;jp 1.19 g cm vdTk; fiurypd; jd;ntg;gf; nfhs;ssT
4200Jkg K
w

vdTk; nfhz;L Nkw;gb fiurypy; Vw;gl;bUf;ff; $ba

ntg;gepiy cau;r;rpiaf; fzpf;f.
.................................................................................................................................................................................
w

.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
w

.................................................................................................................................................................................
(10 Gs;spfs;)
(iii) fpuigw;> H vd;gdtw;wpd; epak jfd ntg;gTs;Siwfs; KiwNa
393 , 286 vdj; jug;gl;Ls;sd.
mj;Jld; Mg 2HCl MgCl H vDk; jhf;fj;jpd; epak
ntg;gTs;Siw khw;wk; 470 vdTk; jug;gbd; MgCO ,d; Njhd;wy;
ntg;gTs;Siwiaf; fhz;f.
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................

Grade - 13 (2020) March – 2020 F.W.C 6 Chemistry II A

 .................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
(10 Gs;spfs;)
(iv) Zn 2 HCl ZnCl H vDk; jhf;fj;jpd; ntg;gTs;Siw khw;wk;
270 vdpd; Mg 2 ZnCl MgCl Zn vDk;

g
jhf;fj;jpw;Fupa ntg;gTs;Siw khw;wk; ahJ?
.................................................................................................................................................................................

or
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................

.
.................................................................................................................................................................................

on
.................................................................................................................................................................................
.................................................................................................................................................................................
.................................................................................................................................................................................
(10 Gs;spfs;)
ee
(C) A P vDk; jhf;fkhdJ gpd;tUk; ,U gbfspD}lhf eilngWtjhff; fUJf.

gb I : A I
gb II : I P
.b

,q;F I vd;gJ jhf;f ,ilepiyahFk;. gpd;tUk; re;ju;g;gq;fspy; A, P, I vd;gtw;wpd;

nrwpTfs; Neuj;Jld; khWgLk; tpjj;ij gUkl;lhd tiugpy; tiuf.
w

I. gb I tpiuthdJk; gb II xg;gPl;lstpy; nkJthdJk;

II. gb II MdJ gb I I tpl rpwpjsT tpiuthdJ.
w

nrwpT nrwpT
w

100
Neuk; Neuk;
I II

(2 x 5 = 10 Gs;spfs;)

Grade - 13 (2020) March – 2020 F.W.C 7 Chemistry II A

04) (A) P vd;gJ C H O vDk; mDgt #j;jpuj;ijf; nfhz;l rf;fukw;w xU Nru;it. P ,d;
jpUj;jkhd %yu;j;jpzpT 112 g mol MFk;. P MdJ xspapaw; njhopw;ghl;ilAk;
Nfj;jpufzpj rkgFjpaj; jd;ikiaAk; fhl;Lfpd;wJ. 1 %y; P MdJ 3 mol Na
cNyhfj;Jld; jhf;fkilfpd;wJ. vdpDk; mJ NaOH cld; jhf;fKwtpy;iy.
NH / AgNO cld; P MdJ ntz;zpw tPo;gbitf; nfhLj;j NghjpYk;
nts;spahbiaf; nfhLf;ftpy;iy.
1 %y; P MdJ 3 mol H / Pd cld; jhf;fKw;W Nru;it Q If; nfhLj;jJ. Q I
H /KMnO cld; gupfupj;jNghJ ngwg;gl;l Nru;it R MdJ 2, 4 - DNP cld;
nrk;kQ;rs; tPo;gbitf; nfhLj;jJ. mj;Jld; mJ NaHCO cld; thA tpisitAk;

g
nfhLj;jJ. R ,w;F Zn / Hg, con. HCl Nru;j;j NghJ S ngwg;gl;lJ. R MdJ PCl cld;
jhf;fp ngwg;gl;l Nru;it T MdJ CH MgCl cld; gupfupj;Jg; gpd; ePu;gg
; Fg;G nra;j

or
NghJ U vDk; xspapw; njhopw;ghLs;s Nru;it ngwg;gl;lJ.
(i) P – U tiuahd Nru;itfSf;Fg; nghUj;jkhd fl;likg;Gfis cupa

.
ngl;bfspy; tiuf.

on
ee
P Q R
.b

S T U
(6 x 5 = 30 Gs;spfs;)
w

(B) gpd;tUk; jhf;fj;jpl;lj;ijf; fUj;jpw; nfhs;f.

,j;jhf;fj;jpl;lj;jpy; xt;nthU gbapYk; cUthFk; tpisT A, B, C, D, E ,dhw;
w

Fwpg;gplg;gl;Ls;sJld; xt;nthU gbf;FKupa jhf;FnghUl;fs; a, b, c, e, f ,dhw;

Fwpg;gplg;gl;Ls;sd.
Br
w

C
|
CH CH Br jhf;fk; 2
| c jhf;fk; 4
jhf;fk; 1 D
A
a b
jhf;fk; 3 jhf;fk; 5
e= H /H O
B
Br
| jhf;fk; 6
C C C E
| f
CH

Grade - 13 (2020) March – 2020 F.W.C 8 Chemistry II A

 (i) tpisnghUl;fs; A, B, C, D, E kw;Wk; jhf;FnghUl;fs; a, b, c, f vd;gtw;iw
,dk;fz;L xt;nthU jhf;fj;Jf;fhd jhf;fg;nghwpKiw tifiaAk;
fPo;j;jug;gl;l ml;ltizapd; cupa epuy;fspy; vOJf.

jhf;fg;nghwpKiw
jhf;fk; jhf;FnghUs; tpisnghUs;
tif

jhf;fk; 1 a= A=

jhf;fk; 2 b= mkpy%yj;jhf;fk; B=

jhf;fk; 3 c= C=

g
jhf;fk; 4 D=

or
e= H /H O
jhf;fk; 5 E=

.
Br

jhf;fk; 6
on f=
|
C C
|
CH
C
ee
(60 Gs;spfs;)
(ii) B + C E jhf;fj;jpd; nghwpKiwia vOJf.
.b
w
w
w

(10 Gs;spfs;)
100

Grade - 13 (2020) March – 2020 F.W.C 9 Chemistry II A