Time : 1 Hour CHEMISTRY ISOMERISM Total Marks : 100
* SECTION - A [100]
1. Which among the given molecules can exhibit tautomerism ?
(A) I I I only (B) Both I and III (C) Both I and II (D) Both II and III
2. Which of the given compounds can exhibit tautomerism ?
Given :
(A) I I and III (B) I and II (C) I , I I and III (D) I and III
3. The number of structural isomers possible from the molecular formula C3 H9 N
is
(A) 5 (B) 2 (C) 3 (D) 4
4. The compound which shows metamerism is :
(A) C 5
H12 (B) C 3
H8 O (C) C 3
H6 O (D) C 4
H10 O
5. The correct statement regarding ethane conformation is :
(A) Rotation around carbon-carbon bond in ethane molecule is not possible, because
ethane molecule contains a pi (π) bond between the carbon and carbon and ethane has
very low melting point.
(B) Rotation around carbon-carbon bond in ethane molecule is not possible, because
ethane molecule contains both sigma (σ) bond, and pi (π) bond between the carbon
and carbon.
(C) Rotation around carbon-carbon bond in ethane molecule is possible because of
cylindrical symmetry of sigma (σ) bond between carbon-carbon atoms
(D) Rotation around carbon-carbon bond in ethane molecule is not possible, because
ethane molecule contains both sigma (σ) bond and pi (π) bond between the carbon and
carbon and ethane has very high boiling point.
Page 1
6. How many geometrical isomers are possible for the above compound ?
(A) 0 (B) 2 (C) 3 (D) 4
7. How many geometrical is isomers are possible for the above compound ?
(A) 0 (B) 2 (C) 3 (D) 4
8. How many geometrical isomers are possible for the above compound ?
(A) 0 (B) 2 (C) 3 (D) 4
9. C H3 − CH = CH − CH = CH − C H3 ; total number of geometrical isomer is
(A) 2 (B) 3 (C) 4 (D) 6
10. Which of the following compound does not show geometrical isomerism
(A)
(B)
(C)
(D)
11. Which of the following can show Geometrical isomerism
Page 2
(A) P h − CH = CH − CH 3
(B)
(C)
(D) All of above
12. Which of the following would exhibit cis-trans isomerism ?
(A) CH 3 C H2 CH = C H2 (B) ClCH = CHCl
(C) ClCH = CCl 2 (D) CH 2 = CH − COOH
13. Which can show geometrical isomerism ?
(A)
(B)
(C)
(D) H 3C − C ≡ C − C H3
14. Which of the following compounds does not have any geometrical isomer ?
(A)
(B)
(C)
(D)
15. Which of the following compounds will show geometrical isomerism ?
(A) 2− pentyne (B) 2− pentene
(C) 2− methyl propene (D) 2− methyl −2− butene
16. Which of the following can show Geometrical isomerism
(A) a, b, d (B) a, c, d (C) a, b, c (D) All of the above
17. Which is correct configuration of the given compound ?
(A) E (B) z (C) Cis (D) Trans
18. Which of the following compounds will show geometrical isomerism
(A) 2− Butene (B) Propene
(C) Ethylene (D) 2− Methyl −2− butene
19. The total number of geometrical isomers for the compound hexa −1, 3, 5− triene
is
(A) 2 (B) 3 (C) 4 (D) 5
20. Given : I and II are
(A) identical
(B) a pair of conformers
(C) a pair of geometrical isomers
(D) a pair of optical isomers
21. Total number of stereo isomers possible by given compound is
(A) 2 (B) 3 (C) 4 (D) 8
22. Incorrect statement
(A) A & B are diastereoisomers with respect to each other
(B) A & B are chain isomers
(C) S N 2 rate A > B
(D) S N 1 rate A > B
23. Configuration of the following compound is
(A) E (B) Cis (C) Trans (D) Z
24. How many meso isomers of C4 H8 C l2 will be ?
(A) 0 (B) 1 (C) 2 (D) 3
25. Total number of secondary amines (Excluding stereo isomer) possible with the
molecular formula C H N is
5 13
(A) 7 (B) 6 (C) 8 (D) 14
----- -----
