Time : 1 Hour NEET ISOMERISM Total Marks : 180
* SECTION - A [180]
1. Which among the given molecules can exhibit tautomerism ?
(A) I I I only (B) Both I and III (C) Both I and II (D) Both II and III
2. Which of the given compounds can exhibit tautomerism ?
Given :
(A) I I and III (B) I and II (C) I , I I and III (D) I and III
3. The number of structural isomers possible from the molecular formula C3 H9 N
is
(A) 5 (B) 2 (C) 3 (D) 4
4. The compound which shows metamerism is :
(A) C 5
H12 (B) C 3
H8 O (C) C 3
H6 O (D) C 4
H10 O
5. Which one is most stable conformers of n− butane?
(A)
(B)
Page 1
(C)
(D)
6. Which of the following is most stable conformer of Butane ?
(A)
(B)
(C)
(D)
7. The correct statement regarding ethane conformation is :
(A) Rotation around carbon-carbon bond in ethane molecule is not possible, because
ethane molecule contains a pi (π) bond between the carbon and carbon and ethane has
very low melting point.
Page 2
(B) Rotation around carbon-carbon bond in ethane molecule is not possible, because
ethane molecule contains both sigma (σ) bond, and pi (π) bond between the carbon
and carbon.
(C) Rotation around carbon-carbon bond in ethane molecule is possible because of
cylindrical symmetry of sigma (σ) bond between carbon-carbon atoms
(D) Rotation around carbon-carbon bond in ethane molecule is not possible, because
ethane molecule contains both sigma (σ) bond and pi (π) bond between the carbon and
carbon and ethane has very high boiling point.
8. Number of isomers of molecular formula C2 H2 Br2 are
(A) 1 (B) 2 (C) 3 (D) 0
9. The number of geometrical isomers in case of a compound with the structure
C H − CH = CH − CH = CH − C H
3 is
2 5
(A) 4 (B) 3 (C) 2 (D) 5
10. Which pair show cis-trans isomerism
(A) Maleic-fumaric acid (B) Lactic-tartaric acid
(C) Malonic-succinic acid (D) Crotonic-acrylic acid
11. Which one of the following will not show geometrical isomerism
(A)
(B)
(C)
(D)
12. Which of the following compounds will exhibit cis-trans isomerism
(A) 2−butene (B) 2−butyne (C) 2−butanol (D) Butanone
13. Which of the following show geometrical isomerism
(A) C 2 H5 Br (B) (CH 2 )(COOH )2 (C) (CH ) 2 (COOH )2 (D) C 2 H6
Page 3
14. Which kind of isomerism is possible for 1− chloro−2−nitroethene
(A) Functional group isomerism (B) Position isomerism
(C) E/Z isomerism (D) Optical isomerism
15. I U P AC name for the below compound is :
(A) E − 3− iodo−4−chloro−3−pentene (B) E − 2− chloro−3−iodo−2−pentene
(C) Z − 2− chloro−3−iodo−2−pentene (D) Z − 3− iodo−4−chloro−3−pentene
16. Which of the following can not show geometrical isomerism ?
(A)
(B) CH 3
− CH = CH − C H3
(C)
(D)
17. Correct configuration of following compound is :-
(A) E (B) Z (C) R (D) S
18. Which of the following can show geometrical isomerism :-
(A)
Page 4
(B)
(C)
(D) All of above
19. Which among the following has E configuration?
(A)
(B)
(C)
(D)
20. Which compound is Z but not cis
(A)
(B)
(C)
Page 5
(D)
21. Which of the following compound has trans as well as Z configuration around
double bond
(A)
(B)
(C)
(D)
22. Which can show geometrical isomerism ?
(A)
(B)
(C)
(D) H 3C − C ≡ C − C H3
23. Which of the following does not show geometrical isomerism ?
(A) CH 3 − CH = CH − C H3
(B) HClC = C = CHCl
(C)
(D)
24. Which of the following compound will not show geometrical isomerism across
the π -bond?
(A)
(B)
(C)
(D)
25. How many geometrical isomers are possible for the above compound ?
(A) 0 (B) 2 (C) 3 (D) 4
26. How many geometrical isomers are possible for the above compound ?
(A) 0 (B) 2 (C) 3 (D) 4
27. How many geometrical is isomers are possible for the above compound ?
(A) 0 (B) 2 (C) 3 (D) 4
28. How many geometrical isomers are possible for the above compound ?
(A) 0 (B) 2 (C) 3 (D) 4
29. C H3 − CH = CH − CH = CH − C H3 ; total number of geometrical isomer is
(A) 2 (B) 3 (C) 4 (D) 6
30. Which of the following compound does not show geometrical isomerism
(A)
(B)
(C)
(D)
31. Which of the following can show Geometrical isomerism
(A) P h − CH = CH − CH 3
(B)
(C)
(D) All of above
32. Which of the following would exhibit cis-trans isomerism ?
(A) CH 3 C H2 CH = C H2 (B) ClCH = CHCl
(C) ClCH = CCl 2 (D) CH 2 = CH − COOH
33. Which can show geometrical isomerism ?
(A)
(B)
(C)
(D) H 3C − C ≡ C − C H3
34. Which of the following compounds does not have any geometrical isomer ?
(A)
(B)
(C)
(D)
35. Which of the following compounds will show geometrical isomerism ?
(A) 2− pentyne (B) 2− pentene
(C) 2− methyl propene (D) 2− methyl −2− butene
36. Which of the following can show Geometrical isomerism
(A) a, b, d (B) a, c, d (C) a, b, c (D) All of the above
37. Which is correct configuration of the given compound ?
(A) E (B) z (C) Cis (D) Trans
38. Which of the following compounds will show geometrical isomerism
(A) 2− Butene (B) Propene
(C) Ethylene (D) 2− Methyl −2− butene
39. The total number of geometrical isomers for the compound hexa −1, 3, 5− triene
is
(A) 2 (B) 3 (C) 4 (D) 5
40. Given : I and II are
(A) identical
(B) a pair of conformers
(C) a pair of geometrical isomers
(D) a pair of optical isomers
41. Total number of stereo isomers possible by given compound is
(A) 2 (B) 3 (C) 4 (D) 8
42. Incorrect statement
(A) A & B are diastereoisomers with respect to each other
(B) A & B are chain isomers
(C) S N 2 rate A > B
(D) S N 1 rate A > B
43. Configuration of the following compound is
(A) E (B) Cis (C) Trans (D) Z
44. How many meso isomers of C4 H8 C l2 will be ?
(A) 0 (B) 1 (C) 2 (D) 3
45. Total number of secondary amines (Excluding stereo isomer) possible with the
molecular formula C H N is
5 13
(A) 7 (B) 6 (C) 8 (D) 14
----- -----
