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Path to success KOTA (RAJASTHAN) WORKSHEET-22
Path to success KOTA (RAJASTHAN) CHEMISTRY
TOPIC : Aldehydes and ketones DT. 29/11/2023
1. Common name of H3C – CH – CH2 – CHO is CH3 O CH3
Br (3) CH3 – CH2 – CH – C – CH – CH2 – CH3
(1) 3–Bromobutyraldehyde
(2) –Bromobutyraldehyde OH O

(3) –Bromobutyraldehyde (4) CH3 – CH – CH2 – C – H

(4) –Bromobutanol 7. Hydration of which of the following alkyne

O gives aldehyde
2. Names of –C – CH3 are (1) propyne
(2) ethyne
(1) Acetophenone (2) 1–phenyl ethanone
(3) 2–phenyl ethanone (4) both 1 & 2 (3) butyne
(4) pentyne
3. NO2– –CHO is 8. "DIBAL–H" can be used to prepare aldehyde from

(1) 4 – Nitrobenzaldehyde (1) Cyanide only

(2) 4 – Formyl nitrobenzene (2) Ester & isocyanides

(3) 4 – Nitrobenzene carbaldehyde (3) Cyanide & isocyanides
(4) Both 1 & 3 (4) Cyanide & ester
4. The bond angles around carbonyl group is/are 9. Benzaldehyde can be prepared from which of
(1) exactly 120° the following
(2) approximately 120° (1) By Rosenmund reaction
(3) always more than 120° (2) By Etard reaction
(4) None of the above
(3) By the use of CrO3 on Toluene
5. Carbonyl compounds have higher dipole
(4) All of the above
moment than ether due to
(1) Absence of resonance CH3
(i) Cl2/hv (twice)
(2) Presence of resonance between C=O 10. ?
(ii) H20/373K
bonds
(3) Due to single bond present in ether
CCl3 C(OH)3
(4) None of the above
(1) (2)
6. Which of the following is Di–sec. butyl ketone
O
COOH
(1) CH3 – C – CH2 – CH2 – CHO CHO
O (3) (4)
(2) C4H9 – C – C4H9

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Path to success KOTA (RAJASTHAN)

1 1 . Which of the following is "Gatterman–Koch O

Reaction" C2H5–C–Cl HCN
14. A B
AlCl3/CS2
CH3

CrO2Cl2 (1) A is phenyl propanone

(1) +
H3O (2) B is unsymetrical compound (Racemic
mixture)
(3) B on acidic hydration can give carboxylic
COCl
acid
(2) H2
Pd–BaSO4 (4) All of the above

15.  C H CH  Cd A  B  C

6 5 2
CH 3 COCl Cl 2
NaOH
CH3
CrO3/ A, B & C are
(3)
(CH3CO)2O (1) C6H5CH2COCH3, CH3COCH3, CHCl3
(2) C6H5CH 2COCH3, C6H5CH 2COOH, CHCl 3
CO + HCl (3) C6H5CH 2COCH3, C6H5COOH, CHCl 3
(4) Anhy AlCl3/CuCl (4) None of the above
1 6 . Correct order of B.P. is
1 2 . Which of the following is/are correct ? (1) C 3 H 7 CHO > C 4 H 9 OH > C 2 H 5 –O–C 2 H 5 >
C 4 H 10
O
(1) CH3CH2CN PhMgBr C2H5 – C – Ph (2) C 4 H 9 OH > C 2 H 5 –O–C 2 H 5 > C 3 H 7 CHO>
H2O C 4 H 10
(3) C 4H 9OH > C 3H 7CHO > C 2 H 5–O–C 2 H 5 >
O
(2) MeMgBr C 4 H 10
CH3 – CH – CN CH3 – CH – C – CH3
HO
CH3
2
CH3 (4) C4H10 > C4H9OH > C3H7CHO > C2H5–O–
C 2H 5
O 1 7 . Benzaldehyde is less reactive than propanal as
C – Ar/R
(3) + Ar/RCOCl
AlCl3 (1) the polarity of carbonyl group of
benzaldehyde is reduced due to resonance
(2) the polarity of carbonyl group of
(4) All are correct
benzaldehyde is increased due resonance
1 3 . In which of the following reagent is not (3) both (1) & (2)
correctly matched (4) None of the above
(1) Hexan  1  ol 
PC C
 Hexanal 1 8 . Reaction of HCN with carbonyl compound is
catalysed by base
(2) P  fluorotoluene 
CrO
 P  Fluorobenzaldehyde
3

 
(CH CO) O 3 2

(1) To generate stronger nucleophile CN

DIBAL  H
(3) Ethane nitrile 
 Ethanal
(2) HCN is strong acid no reaction take place
–
slowly
NHCrO3Cl
(4) But-2-enal Ethanal (3) Both (1) & (2)
(4) None of the above

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Path to success KOTA (RAJASTHAN)

1 9 . "Proton transfer" take place in bisulphite test 2 7 . Haloform test is given by compounds having

(1) As SO3 ion is more stable than SO3H O

(1) CH3 –C – group
(2) SO3H is more stable than SO3

(3) As proton starts the reaction O

(2) group
(4) None of the above CX3– C –

2 0 . Bisulphite test is given by OH

(1) All aldehyde (3) CH3– CH – group
(2) Aliphatic methyl ketone
(4) All of the above
(3) Glucose
(4) both (1) & (2) O

2 1 . Acetal & ketal are C – CH3

28.
H2CrO4
(1) gem–dialkoxy compounds A
(2) vic–dialkoxy compounds I2/NaOH
B+C
(3) gem-dihydroxy compounds
A, B & C are
(4) vic–dihydroxy compounds
2 2 . 2, 4–DNP test is not given by COOH COOH
(1) & CHI3
(1) Aldehyde (2) Ketone ,
(3) Glucose (4) Benzaldehyde
O O
2 3 . Which of the following can reduce carbonyl
C – OH C–H
compounds (2)
, & CHI3
(1) LiAlH4 & NaBH4
(2) Zn–Hg/HCl & NH2NH2/KOH
O
(3) Red P/HI COOH C – CH3
(4) All of the above (3) & CHI3
,
24. Sod. pot. Tartrate is
(1) Tollen's reagent (2) Fehling solution (4) None of the above
(3) Roschelle's salt (4) both (2) & (3) 2+ +
– 2Cu [Ag(NH3)2] –
RCOO – RCHO – RCOO
2 5 . Fehling solution reacts with & OH OH &
29.
(1) Aromatic aldehyde Red ppt A B Silver ppt

(2) Aliphatic aldehyde

Reaction A & B indicates
(3) Ketone
(1) Haloform & Tollen's reagent
(4) both (1) & (2)
(2) Fehling's & Canizarro's
2 6 . Fehling solution with aldehyde gives
(3) Aldol & Fehling's
(1) Black ppt (2) Reddish brown ppt
(4) Fehling's & Tollen's reagent
(3) purple ppt (4) white ppt

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Path to success KOTA (RAJASTHAN)

NH2NH2 CH3  CH 2  CHO 

HCHO(excess)
A  B
– A 33. conc. base
OH
30. C=O CH2OH
NH2NH2 (1) CH3 – C – CHO & HCHO
B
CH2OH
A & B are CH2OH
(2) CH3 – C – CH2OH + HCOO–
(1) alkane & amine
CH2OH
(2) Alkane & Aldoxime
OH
(3) Alkene & hydrazone (3) CH3 – CH2 – CH – CHO

(4) Alkane & Hydrazone CH2OH

(4) CH3 – C – CHO + CH3OH
OH
Dil. 
31. CH3CHO
NaOH
CH3 – CH – CH2 – CHO CH3 – CH = CH – CHO CH 2OH
Step-I Step-II
34. Match the following
Column - I
Step I & II are
O
(1) H+
(1) Aldol condensation + HO – NH2

(2) Perkin's reaction NO2

O
(3) Aldol reaction & Aldol condensation (2) + NH2 – NH NO2

(4) Aldol reaction & Cannizzaro's reaction O

C H+
O (3) CH3+ CH3CH2NH2
CHO
32. C – CH3 Product
KOH/293k O
H+
(4) R – CH = CH – CHO + NH2–C –NH–NH2
Product will be Column - II
N–OH
O (a)
(1) C CH3
–C = N – C2H5
(b) CH3
O
(2) CH = CH – C N – NH
NO2

(c)
OH O
NO2
(3) CH – CH2 – C
R – CH = CH – CH
(d) O
NH2 – C – NH – N
(4) CH = CH CHO
(1) 1-a, 2-b, 3-c, 4-d (2) 1-a, 2-c, 3-b, 4-d
(3) 1-d, 2-b, 3-c, 4-a (4) 1-b, 2-a, 3-d, 4-d

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Path to success KOTA (RAJASTHAN)

3 5 . Formalin is mainly used CH3 CH3

(1) to prepare acetic acid (IV) CH3–CH–C–CH–CH3
(2) to prepare bakallite & to prepare biological O
specimen
(1) I < II < III < IV
(3) to prepare fertilizers
(2) III < IV < I < II
(4) to prepare PVC
(3) IV < III < II < I
36. Arrange the following in order of reactivity towards NAR
(4) II < I < IV < III
(1) Butanone < Propanone < Propanal < Ethanal
39. Cyanohydrin of the following compound on
(2) Acetophenone > p–Tolualdehyde > p–
hydrolysis gives compound that can show optical
Nitrobenzaldehyde isomerism :
(3) Ethanal < Propanal < Propanone < Butanone (1) HCHO (2) CH3CHO
(4) Acetophenone > p–nitrobenzaldehyde > p– (3) CH3COCH3 (4) All the above
Tolualdehyde
40. Compound A and C in the following reaction are
37. Fill in the blanks :
(i) CH3MgBr H SO
O CH3CHO (A) 2 4 (B)
(ii) H2O 
[Ag(NH3)2]
(1) ?
CHO B2H6/THF
–
(C)
H2O2/OH
-H ? (1) Identical
AL
DI B
(2) CH3COCH2COOCH3 Na (2) Chain isomer
BH
4
? (3) Positional isomer
(4) Optical isomer
O3/Zn
(3) –CH3 ?
H2O O
41. C can be obtained by :
CH2
?
(4)
O
(1) C–Cl + (Ph)2Cd
dil. NaOH
(5) –CHO ?

+ OH
O
CH3CH2CHO
(2) C–Cl +
38. Arrange the following in the increasing order of
reactivity of NAR.
(I) CH2O (3) + CO + ZnCl2 + HCN
(II) CH3CHO
(III) CH3–CO–CH3 (4) None of the above

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Path to success KOTA (RAJASTHAN)

O CHO
OH
PCC NH2–NH–C–NH2 45. Conc. NaOH
42. Ph–CH–CH3 (A) (B) Product

Product (B) is :
What is the product obtained in the above reaction?
CH3 O
(1)
Ph–C=N–C–NH–NH2 COONa CH2OH

O (1) only (2) only

Ph–C=N–NH–C–NH2
(2)
CH3
COONa CHOH
2

O
(3) +
Ph–CH=N–N–C–NH2
(3)
CH3
CH3 CH2OH
O
(4) (4)
Ph–CH=N–C–NH2 +

43. The appropriate reagent for the following

transformation is
46. Of the following, which is the product formed when
cyclohexanone undergoes aldol condensation
O
followed by heating ?
CH2CH3
CH3

HO HO
(1)
(1) Zn(Hg), HCl (2) NH2NH2, OH– O
(3) H2/Ni (4) NaBH4

44. How many compounds in given below can react

with NaHSO3 (2)
OH
O
C–CH,3
HCHO, CH–C
3 –CH3,
O (3)
O O
CH–
3 CHO,

(1) 4 (2) 3
(4)
(3) 1 (4) 2
OH
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Path to success KOTA (RAJASTHAN)

47. For the reaction: 49. In Cannizzaro reaction given below :-

OH : OH
Ph–CHO + Ph–C–CH 3 Major 2PhCHO PhCH2OH + PhCO2
293K
O
The major product is : the slowest step is :-
CH3 (1) The abstraction of proton from the carboxylic
group
(1) Ph–C–CH 2–C–Ph
OH O (2) The deprotonation of PhCH2OH
Ph–C–O + Ph–CH 2–OH
(2)
O (3) The attack of : OH at the carboxyl group
O (4) The transfer of hydride to the carbonyl group
(3) Ph–CH–C–Ph 50. Mixture of Ph–CHO and H-CHO is treated with
OH conc. NaOH, then cannizzaro reaction involves
O
(4) (1) Oxidation of HCHO
Ph –CH=CH –C–Ph
48. The Cannizzaro reaction is not given by (2) Reduction of HCHO
(1) trimethylacetaldehyde
(3) Reduction of PhCHO
(2) acetaldehyde
(3) benzaldehyde (4) Both (1) and (3)
(4) formaldehyde

ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 4 4 2 2 3 2 4 4 3 4 4 4 4 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 3 1 1 1 4 1 3 4 4 2 2 4 1 4 4
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 3 2 2 2 2 1 3 2 3 1 2 2 2 3
Que. 46 47 48 49 50
Ans. 1 4 2 4 4

37. Fill in the blanks :

O
[Ag(NH3)2]
(1) ?
CHO
O
O
[Ag(NH3)2]
Ans.
CHO
COOH

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Path to success KOTA (RAJASTHAN)

?
(2) CH3COCH 2COOCH3

DIBAL–H
CH3COCH2CHO
Ans. CH3COCH2COOCH3
NaBH4
CH3CH – CH2 – COOCH3
OH

O3/Zn
(3) –CH3 ?
H2O

O2/Zn
Ans. –CH3 O+O –CH3
H2O

CH2
?
(4)

CH2
Cl–CH2–
Ans.
AlCl3

dil. NaOH
(5) –CHO + CH3CH3CHO ?


dil.
–CHO + CH3CH2CHO CHO –C=CH–
Ans. NaOH
CH3

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