Safety Data Sheet Page: 1 of 10

PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2

SECTION 1: IDENTIFICATION OF THE SUBSTANCE

Product name Propylene (Chemical Grade)
Hydrocarbons, Olefins (Alkenes, mainly Propylene) and Paraffins (Alkanes, mainly
Chemical Family
Propane)
CAS Number 115-07-1
REACH Registration
01-2119447103-50-0094
Number
Chemical Name Propylene
Synonyms Propene
Raw material for chemicals and petrochemical applications, fuel gas products.
Type of use Purification of propylene and production of polypropylene, propylene copolymers,
chemical synthesis etc.
Company Customer Service
„HIP-Petrohemija“ Pancevo
Tel: +381(0)13 307 000
Spoljnostarcevacka 82
Fax: +381(0)13 310 207
26000 Pancevo
Email (competent person): prodaja@[Link]
Republic of Serbia
Webpage: [Link]
Supplier REACHLaw Ltd. (acting as Tel: +358(0) 9 412 3055
only representative according to
REACH Article 8)
Fax:+358(0) 9 412 3049
Keilaranta 15 Email (competent person): SDS@[Link]
02150, Espoo, Finland Webpage: [Link]

Emergency Contact (24h) See Section 16. for the list of telephone numbers of poison centers in the European
Economic Area

SECTION 2: HAZARD IDENTIFICATION

CLP: F+ – Extremely flammable;
GHS: DANGER! Flammable gases, category 1, H220; DANGER! Liquefied gases; H280.
Adverse environmental effects Not classified as dangerous. The product evaporates readily.
Adverse physical-chemical effects The gas is heavier than air and may travel along the ground; distant ignition
possible and may accumulate in low ceiling spaces causing deficiency of
oxygen. Risk of explosion if heated. Vapours may form explosive mixtures
with air. High risk of fire in case of leakage.
Signs and Symptoms of Acute Exposure
Skin Vapours are not irritating. Direct contact to skin with liquefied product or cold vapour may cause freeze
burns and frostbite. Product does not penetrate through the skin
Inhalation This product is mildly asphyxiate gas that can cause unconsciousness/death if OXYGEN level is
sufficiently reduced. Inhalation of high concentrations may cause central nervous system depression such
as dizziness, drowsiness, headache, and similar narcotic symptoms, nausea and loss of coordination and
in extreme conditions coma and possibly death. High concentrations may trigger heartbeat irregularities
and possible cardiac sensitization
Eyes Vapours are not irritating. Contact with liquid or cold vapour may cause frostbite, freeze burns and
permanent eye damage.
Ingestion Ingestion is unlikely. Contact with liquefied product may cause frostbite and freeze burns
Chronic Health Effects Not Classifiable as Human Carcinogen
Conditions Aggravated by Exposure Individuals with pre-existing conditions of the heart, lungs, and blood may
have increased susceptibility to symptoms of asphyxia (lack of oxygen)
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PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2

SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS

EU Inventory All components listed on European Inventory of Existing Chemical Substances (EINECS)

EU Inventory
Component Name CAS # Index No. Concentration Wt.%
EC #
Propylene 115-07-1 204-062-1 601-011-00-9 93 - 96%
Propane 74-98-6 200-827-9 601-003-00-5 4 -7%

Component 1: Propylene
Classification and
Labeling
CLP GHS

Pictogram

Clasification
Danger! Danger!
(Hazard Class and F+; Extremely flammable
Flam. Gas, 1 Liquefied gases
Category Code– GHS)
Risk Phrases (Hazard R12 Extremely flammable H220 – Extremely flammable H280 – Contains gas under
statement –GHS) gas pressure; may explode if heated

Component 2: Propane
Classification and
Labeling
CLP GHS

Pictogram

Clasification
Danger! Danger!
(Hazard Class and F+; Extremely flammable
Flam. Gas, 1 Liquefied gases
Category Code– GHS)
Risk Phrases (Hazard R12 Extremely flammable H220 – Extremely flammable H280 – Contains gas under
statement –GHS) gas pressure; may explode if heated

SECTION 4: FIRST AID MEASURES

General DANGER! EXTREMELY FLAMMABLE LIQUEFIED GAS! This product does not contain
oxygen and may cause asphyxia if released in a confined area. Simple hydrocarbons can cause
irritation and central nervous system depression at high concentrations. May cause dizziness
and drowsiness. Can form explosive mixtures with air. May cause frostbite. Can cause rapid
suffocation. Rescue workers may require self-contained breathing apparatus. Extremely
flammable. Prompt medical attention is mandatory in all cases of overexposure to propylene.
Rescue personnel should be equipped with self-contained breathing apparatus and be cognizant
of extreme fire and explosion hazard.
Inhalation Move affected individual to non-contaminated air. Loosen tight clothing such as a collar, tie,
belt or waistband to facilitate breathing. Seek immediate medical attention if the individual is
not breathing, is unconscious or if any other symptoms persist. WARNING: Contact through
mouth-to-mouth resuscitation may pose a secondary risk to the rescuer. Avoid mouth-to-mouth
contact by using a mouth shield or guard to perform artificial respiration..
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PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2
Skin For skin contact, wash immediately with soap and water. DO NOT USE HOT WATER. Seek
medical attention if symptoms develop or persist. Thaw frostbite slowly with lukewarm water. DO
NOT RUB affected area. Do not pull off adherent clothing or objects. Seek medical attention at
once.
Eyes If can be done safely remove contact lenses. Immediately flush eyes with cold water for at least
15 minutes, while holding eyelids open. DO NOT USE HOT WATER. Seek medical attention if
symptoms develop or persist.
Ingestion Not probable
Note to Physician Treat unconsciousness, frostbite, nausea, hypotension, seizures and cardiac arrhythmia in the
conventional manner. Administer oxygen by mask if there is respiratory distress. Treatment of
overexposure should be direct at controlling the symptoms and clinical condition of a patient.
After adequate first aid, no further treatment is necessary unless symptoms reappear.

SECTION 5: FIRE FIGHTING MEASURES

Flammable Properties Extremely flammable, gas/air mixtures are explosive. High risk of fire in case of
leakage.
Extinguishing Media Dry chemical, foam, carbon dioxide, and water fog. Do not use water jets. Foam
cover may help suppress evolution of flammable gas. Use massive quantities of
water to cool fire-exposed containers and to protect personnel. Do not attempt to
extinguish a leaking gas fire unless leak source can be isolated and shut off. Let
uncontrolled fires burn off.
Extinguishing Media (which shall DO NOT ATTEMPT TO EXTINGUISH A LEAKING GAS FIRE UNLESS
not be used for safety reasons) LEAK SOURCE CAN BE ISOLATED AND SHUT OFF. Monitor water run-off
for flammability, and prevent from entering drains and sewers, or other confined
or underground spaces.
Hazardous Combustion Products Upon decomposition, this product emits carbon monoxide, carbon dioxide, and/or
low molecular weight hydrocarbons
Protective Equipment/Clothing Full-face self-contained breathing apparatus, thermal protective clothing.
Fire Fighting Guidance Keep unnecessary personnel away. Move containers from fire area if you can do
so without risk. Fight fire from maximum distance, use unmanned holders, or
monitor nozzles. Immediately withdraw in case of fire and container venting or
heat discoloration of a container. Fire fighters should wear full-face, self-
contained breathing apparatus and thermal protective clothing. Avoid inhaling
any smoke and combustion materials. Remove and clean or destroy any
contaminated clothing. Cool containers with flooding quantities of water until well
after the fire is out. Control runoff waters to prevent entry into sewers, drains,
underground or confined spaces and waterways.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Extra personal protection Wear self-contained breathing apparatus when entering area unless atmosphere is prove
safe.
Environmental Avoid entry of product into drains, sewers, or waterways.
precautions
Recommended methods Evacuate area. Ensure adequate air ventilation. Do not touch spilled material. No
for cleaning and disposal smoking or open flames permitted in storage, use or handling areas. Eliminate ignition
sources. Dissipate static electricity during transfer or processing by proper earthing
(grounding) and bonding of containers and equipment.
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PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2

SECTION 7: HANDLING AND STORAGE

Handling Keep locked up or secured. This material can be stored as a flammable gas or liquid depending on the
temperature and pressure. Handle in fully enclosed, grounded, properly designed and approved transfer
and storage systems. Use with adequate ventilation. Avoid inhalation. Keep away from uncontrolled
heat and incompatible materials. Ground all handling and transfer equipment to dissipate build-up of
static electricity. Wear suitable protective equipment including thermally protective gloves. No
smoking or open flames permitted in storage, use or handling areas. If used in refrigeration, check
drains are they not plugged and valves are working and not plugged by ice formed from the vaporizing
liquid.
Storage Storage area should be clearly identify, well illuminated, clear of obstruction and accessible only to
trained and authorized personnel. Store in grounded, properly designed and approved pressure
containers and away from incompatible materials. Store and use away from heat, sparks, open flame, or
any other ignition source. Store according to applicable codes or regulations for liquefied pressurized
gases as applicable to: cylinders, vessels, piping, buildings, rooms, cabinets, allowable quantities and
minimum storage distances. Have appropriate extinguishing capability in storage area (e.g. sprinkler
system, portable fire extinguishers) and flammable gas detectors. Storage pressure vessels should be
above ground and dike. Keep cylinders secure while in storage or in transportation.
Specific use(s) Raw material for chemicals and petrochemical applications, fuel gas products. Purification of
propylene and production of polypropylene, propylene copolymers, chemical synthesis etc. Handling
with materila according to Section 7 part Handling.

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

ACGIH exposure limit lists have been checked for major components listed with CAS registry numbers. Other exposure
limits may apply, check with proper authorities.
Propylene TLV: 500 ppm as TWA; 860 mg/m3
Propane TLV: 1000 ppm as TWA
Chemical Safety Report Yes
Derived No Effect Levels (DNEL) For information please contact the manufacturer
Predicted No Effect Concentration (PNEC) (Section 1 Part Company)
Engineering methods include mechanical ventilation (dilution and local exhaust) process or personal enclosure, remote and
automated operation, control of process conditions, leak detection and repair systems, and other process modifications.
Ensure all exhaust ventilation systems are discharge to outdoors, away from air intakes and ignition sources. Supply
sufficient replacement air to make up for air removed by exhaust systems. Administrative (procedure) controls and use of
personal protective equipment may also be required.
Personal protective equipment should not be considered a long-term solution to exposure control. Persons in ill health
where such illness would be aggravated by exposure to product should not be allowed to work with or handle this product
Inhalation If engineering controls and ventilation is not sufficient to prevent build-up of aerosols or vapours
and/or oxygen concentrations are low, appropriate air supplied breathing apparatus should be use.
Hand Use impervious gloves designed to prevent freezing of body tissues if contact with liquefied gas is
possible. Wear chemical-resistant safety footwear with good traction to prevent slipping.
Eyes Wear safety glasses. Use of chemical goggles under a full-face shield is recommended if contact
with liquefied vapour is possible.
Skin Work clothing that sufficiently prevents skin contact and prevents freezing of body tissues if
contact with liquefied gas is possible should been worn, such as coveralls and/or long sleeves and
pants. Fire resistant (i.e., Nomex) or natural fibber clothing (i.e., cotton or wool) is recommended.
Synthetic clothing can generate static electricity and would not recommend where flammable
vapour releases may occur.
Environmental Environmental exposure controls should be in accordance with applicable regional, national, and
exposure controls local laws and regulations.
 Safety Data Sheet Page: 5 of 10

PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical state and Gas at ambient temperature, Explosive Properties Gas/air mixtures are explosive
Appearance liquid under pressure Oxidizing Properties May react with strong oxidizing
Colour Colourless agents
Odour Sweetish Vapour Pressure 10.3 atm (at 21°C)
Evaporation Rate Not applicable
Odour Threshold 22000 - 36000 mg/m3, 23 ppm o
Relative Density at 15 C 0.52
pH Not applicable (water=1)
Boiling Point/Boiling -48°C Solubility (Water) Slight 200 mg/l at 25oC
Range
Melting Point -185°C Partition Coefficient 1.77
Flash Point -107.8°C Octanol/Water (Log Pow)
Auto-ignition 455°C Viscosity Not applicable
Flammability classification Extremely flammable Relative Vapour Density 1.4
(2F) (air=1)
Lower Flammable 2% Evaporation Immediate at 20°C.
(explosion) Limit Additional Physical and /
Upper Flammable 11 % Chemical Properties
(explosion) Limit

SECTION 10: STABILITY AND REACTIVITY

Chemical Stability This product is stable under normal use conditions for shock, vibration, pressure, or
temperature. Unstable at high temperature/pressure
Conditions to Avoid Keep away from heat, sparks, or open flame.
Substances to Avoid Nitrates, per chlorates, nitrogen oxides including nitrogen dioxide, nitrous oxide
and nitrogen tertoxide. Many materials become brittle after contact with liquefied
gases, and may fail without warning. Carefully select and test equipment, gaskets,
and hoses periodically to ensure integrity and compatibility.
Decomposition Products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or
low molecular weight hydrocarbons.
Hazardous Polymerization Hazardous polymerization can occur at elevated temperature and pressure in the
presence of a catalyst
Reactions with Air and Water Vapours may form an explosive mixture with air. May polymerize explosively
when heated or involved in a fire. May react vigorously with oxidizing agents.
Liquefied gas may explode on contact with hot water (45°C - 75°C).
Advice to prevent explosion Keep away from heat, sparks and open flame.

SECTION 11: TOXICOLOGICAL INFORMATION

Acute Toxicity
Inhalation of propylene can produce narcosis and anaesthesia; however, these effects are only seen at very high
concentrations (reports indicate 688.000 mg/m3 to induce narcosis in humans). Excessive exposures may cause headache,
dizziness, nausea, loss of coordination, and in extreme conditions coma and possibly death. High concentrations may
trigger heartbeat irregularities and possible cardiac sensitization. In the gaseous state propylene was NOT been expected to
be irritating to the skin or eyes. However, should skin or eye contact occur with this product in its liquid state, tissue
freezing, severe cold burn, and/or frostbite may result.
4h Inhalation Rat LC50 50,000 ppm
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PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2
Repeated Dose Toxicity
Repeated exposure to propylene produces no clinical effects in animals exposed to concentrations up to 10,000 ppm, one-
half of the lower flammability limit for 103 weeks (6 hours per day, 5 days per week). In the nasal cavity, propylene
induced nasal lesions of relatively mild nature and relatively few animals was been affected.
Chronic Toxicity
Carcinogenicity ACGIH - A4 - Not Classifiable as a Human Carcinogen
OSHA - /
IARC - Group 3 – Not classifiable as to its carcinogenicity to humans
NTP - /
Mutagenic effects Not a known mutagen
Teratogenic effects Not a known teratogen.
Special Remarks on Other Toxic Effects on Humans
Propylene that is inhaling was been largely exhaled unchanged. A small fraction may be metabolize and transport in blood
as propylene oxide. There is no known health effect found to be associated with this metabolism in 2-year cancer studies
or in studies of potential adverse genetic effects.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity – Fish: LC50: 51.7 mg/l 96 hours
Acute toxicity Daphnia magna: LC50: 28.2 mg/l 48 hours
Green algae: EC50: 12.1 mg/l 96 h
Mobility Gas at ambient coditions.
Persistence and Degradability
Air This material evaporates rapidly into the atmosphere. In the air these product have the potential to
degrade rapidly through indirect photolytic processes mediated primarily by hydroxyl radicals. This is
expecting to be the dominant route of loss and degradation process. Photo-oxidation half lives is 14.6
hours (hydroxyl radicals) and 23.7 hours (ozone).
Soil Bacteria from soil can degrade it.
Water Bacteria from surface water can degrade it. Aqueous photolysis and hydrolysis will not contribute to
the transformation in aquatic environments because they are either poorly or not susceptible to these
reactions.
Bioaccumulation Biodegradation of this product may occur in soil and water. Volatilization is expecting to be the most
important removal process in soil and water.
Biodegradation Product is not expected to bio accumulate. This product does not concentrate or accumulate in the
food chain.
Environmental Liquid release had only expected to cause localized, non-persistent environmental damage, such as
adverse effects freezing. This product has not considered harmful to aquatic life, and has limited absorption into soil
and sediment.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste disposal
The use, mixing or processing of this product may alter this product. Since emptied containers retain product/material
residue, follow safe handling/label warnings even after container was been emptied.
DO NOT ATTEMPT TO DISPOSE OF BY UNCONTROLLED IGNITION.
It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated
to determine the proper waste classification and disposal methods in compliance with applicable regulations. Disposal
should be in accordance with applicable regional, national, and local laws and regulations
 Safety Data Sheet Page: 7 of 10

PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2

SECTION 14: TRANSPORT INFORMATION

UN Number 1038
H.I.N. (Kemler Number) 223

223
1038
Road (ADR) / Rail (RID)/ Water (ADNR)
Proper Shipping Name ETHYLENE, REFRIGERATED Required label(s)
LIQUID
UN Number 1038
Hazard class 2 (2.1 flammable gas)
Transport category 3F
Packaging group /

Marine (IMO)
Proper Shipping Name ETHYLENE, REFRIGERATED Required label(s)
LIQUID
UN Number 1038
IMDG class 2 (2.1 flammable gas)
EmS category F-D, S-U
Packaging group /

Air Transport (IATA/ICAO)

Proper Shipping Name ETHYLENE, REFRIGERATED Required label(s)
LIQUID
UN Number 1038
ICAO/IATA class 2 (2.1 flammable gas)
Packaging group /
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PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2

SECTION 15: REGULATORY INFORMATION

Regulatory information The SDS has been prepared according to EC REGULATION No. 1907/2006
REACH. The product has been classified as dangerous according to EC
REGULATIONs, No. 1272/2008/EC, No. 1999/45/EC and No. 67/548/EEC.

Propylene
CAS # (IUPAC) 115-07-1 (Propylene)
EU Inventory EC # 204-062-1
Index No. 601-011-00-9
Classification and
Labeling
CLP GHS

Pictogram

Clasification
Danger! Danger!
(Hazard Class and F+; Extremely flammable
Flam. Gas, 1 Liquefi ed gases
Category Code– GHS)
Risk Phrases (Hazard R12 - Extremely H220 – Extremely flammable gas
Statement –GHS) Flammable H280 – Contains gas under pressure; may explode if heated
Safety Phrases S9 - Keep container in a Prevention
(Precautionary Statements well ventilated place P210 Keep away from heat/sparks/open
precautionary
– GHS) S16 - Keep away from flames/hot surfaces – No smoking.
statements
sources of ignition
S33 - Take precautionary P377 Leaking gas fire – do not extinguish
Response
measures against static unless leak can be stopped safely
precautionary
charges P381 Eliminate all ignition sources if safe
statements
to do so.
Storage
P410+P403 Protect from sunlight. Store
precautionary
in a well ventilated place.
statements
Disposal
precautionary /
statements
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PROPYLENE SDS No.: 20

Date of issue: 26.11.2010. Version (en): 2

SECTION 16: OTHER INFORMATION

Training Personnel handling the product need to be demonstrably with its hazardous properties, with health
advice and environmental protection principles related to the product and first aid principles.
Recommended THE PRODUCT IS RESTRICTED TO PROFESSIONAL USAGE. Ensure all national/local
uses regulations are observed. Ensure operators understand the flammability hazard. The hazard of
asphyxiation is often overlooked and must be stressed during operator training. This Safety Data
Sheet has been established in accordance with the applicable European. Directives and applies to
all countries that have translated the Directives in their national laws. Details given in this
document are believed to be correct at the time of going to press. Whilst proper care has been
taken in the preparation of this document, no liability for injury or damage resulting from its use
can be accepted. Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the
information contained herein, and assume no responsibility regarding the suitability of this
information for the user’s intended purposes or for the consequences of its use. Each individual
should make a determination as to the suitability of the information for their particular purpose.

List of telephone numbers of poison centres in the European Economic Area

AUSTRIA (Vienna Wien) +43 1 40 400 2222
BELGIUM (Brussels Bruxelles) +32 70 245 245
BULGARIA (Sofia) +359 2 9154 409 / +359 887 435 325
CZECH REPUBLIC (Prague Praha) +42 2 2491 9293 or +42 2 2491 5402
DENMARK (Copenhagen) +45 35 31 54 04
FINLAND (Helsinki ) +358 9 471 977
FRANCE (Paris) +33 1 40 05 48 48
GERMANY (Berlin) +49 30 450 653565
GREECE (Athens Athinai) +30 10 779 3777
HUNGARY (Budapest) +36 80 20 11 99
ICELAND (Reykjavik) +354 525 111, +354 543 2222
IRELAND (Dublin) +353 1 8379964
ITALY (Rome) +39 06 305 4343
LATVIA (Riga) +371 704 2468
LITHUANIA (Vilnius) +370 2 36 20 52, +370 2 36 20 92
NETHERLANDS (Bilthoven) +31 30 274 88 88
NORWAY (Oslo) +47 22 591300
POLAND (Gdansk) +48 58 301 65 16 or +48 58 349 2831
PORTUGAL (Lisbon Lisboa ) 808 250 143 (for use only in Portugal), +351 21 330 3284
ROMANIA (Bucharest) +40 21 230 8000;
SLOVAKIA (Bratislava) +421 2 54 77 4 166
SLOVENIA (Ljubljana) + 386 41 650 500
SPAIN (Barcelona) +34 93 227 98 33 or +34 93 227 54 00 bleep 190
SWEDEN (Stockholm) +46 8 33 12 31 (International) 112 (National)
UNITED KINGDOM (London) 0870 243 2241
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PROPYLENE SDS No.: 20

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Key/Legend
ACGIH American Conference of Governmental Industrial Hygienists
ADNR European Agreement concerning the International Carriage of Dangerous Goods by inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
CAS Chemical Abstract Service
EPA Environmental Protection Agency
EU European Union
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods
IMO International Maritime Organization
LC50 Lethal Concentration, concentration of a chemical which kills 50% of a sample population
LD50 Lethal Dose, dose of a chemical which kills 50% of a sample population
NFPA National Fire Protection Association
NTP National Toxicology Programme
OSHA Occupational Safety and Health Administration
RID International Rule for Transport of Dangerous Substances by Railway
TLV Threshold Limit Value
TWA Time Weighted Averages
This information applies to the PRODUCT AS SUCH and conforming to specifications of „HIP- PETROHEMIJA“
Pancevo.
In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear.
The information contained is based on our knowledge of the product, at the date of publishing and it is given quite
sincerely. However the revision of some data is in progress. Users are advised of possible additional hazards when the
product is used in applications for which it was not intended.
This sheet shall only be used and reproduced for prevention and security purposes.
The references to legislative, regulatory and codes of practice documents cannot be considered as exhaustive.
It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning the
use, the possession and the handling of the product.
It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into
contact with the product. (usage, storage, cleaning of containers, other processes) the totality of the information
contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of
environment.
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