A+B→R T=55ºC

Ca0 1M t, min Ca,M Ca0-Ca

Cb0 1M 0 1 0
2 0.9 0.1
5 0.78 0.22
15 0.54 0.46
28 0.39 0.61
50 0.26 0.74
80 0.18 0.82
100 0.15 0.85
mol/l

n=2
6
f(x) = 0.0567571437267495 x
5 R² = 0.999984210681547

4
1/Ca-1/Ca0

0
0 20 40 60 80 100

t, min
 n=0
0.9
Ln( Ca0/Ca) 1/Ca-1/Ca0 f(x) = 0.0106770990069215 x
0.8 R² = 0.879416867830008
0 0
0.7
0.10536052 0.11111111
0.24846136 0.28205128 0.6

Ca0-Ca, mol/l
0.61618614 0.85185185 0.5
0.94160854 1.56410256 0.4
1.34707365 2.84615385 0.3
1.71479843 4.55555556
0.2
1.89711998 5.66666667
0.1
1/t l/mol
0
0 20 40 60 80 100

t, min

n=1
2
f(x) = 0.0216325817117802 x
1.8 R² = 0.962552330915728
1.6
1.4
Ln( Ca0/Ca)

1.2
1
0.8
0.6
0.4
0.2
0
80 100 120 0 20 40 60 80 100

t, min
80 100 120

80 100 120
A+2B→R

Ca0 1M t,min Ca, M Ca0-Ca

Cb0 2M 0 1 0
2 0.902 0.098
5 0.793 0.207
7 0.69 0.31
11 0.569 0.431
16 0.433 0.567
25 0.287 0.713
35 0.171 0.829
mol/l
Ln( Ca0/Ca) 1/Ca-1/Ca0
0 0 n=0
0.10314076 0.10864745
0.9
0.23193206 0.26103405 f(x) = 0.0277891540130152 x
0.8
0.37106368 0.44927536 R² = 0.961431334418455
0.7
0.56387484 0.75746924

Ca0-Ca, mol/l
0.6
0.83701755 1.30946882 0.5
1.24827306 2.48432056 0.4
1.76609172 4.84795322 0.3
1/t l/mol 0.2
0.1
0
0 5 10 15 20 25 30 35

t, min

n=1
2
1.8
1.6 f(x) = 0.0505762813669172 x
Ln( Ca0/Ca), 1/min

1.4 R² = 0.999688155594069
1.2
1
0.8
0.6
0.4
0.2
0
0 5 10 15 20 25 30 35

t, min
=0

20 25 30 35 40

t, min

=1

20 25 30 35 40

t, min
A+2B→R

Ca0 3M t,s Ca, M Ca0-Ca

Cb0 6M 0 3 0
110 2.706 0.294
275 2.38 0.62
385 2.07 0.93
605 1.707 1.293
880 1.299 1.701
1375 0.861 2.139
1925 0.513 2.487
mol/l
Ln( Ca0/Ca) 1/Ca-1/Ca0
0 0 n=0
0.10314076 0.03621582 3
0.2315118 0.08683473 f(x) = 0.00151573259712088 x
2.5 R² = 0.961452909488491
0.37106368 0.14975845
0.56387484 0.25248975

Ca0-Ca, mol/l
2
0.83701755 0.43648961
1.5
1.24827306 0.82810685
1.76609172 1.61598441 1
1/t l/mol 0.5

0
0 500 1000 1500 2000 2

t,s

n=1
2
1.8
1.6 f(x) = 0.000919552177234718 x
Ln( Ca0/Ca),1/seg

1.4 R² = 0.999685130092337
1.2
1
0.8
0.6
0.4
0.2
0
0 500 1000 1500 2000 2500

t,s
 1500 2000 2500

1500 2000 2500

Experimento CA, M CB, M -rA0, mol/(l*s) Ln(-Ra)0
1 0.01 0.2 5.4 1.68639895
2 0.02 0.2 10.8 2.37954613
3 0.04 0.2 21.5 3.06805294
4 0.06 0.2 32.3 3.47506723
5 0.2 0.0202 10.2 2.32238772
6 0.2 0.0404 21.6 3.07269331
7 0.2 0.0606 32.4 3.47815842
8 0.2 0.0808 43.3 3.76815264

Cb0 = cte

f(x) = 0.997594477563593 x + 6.280886471

R² = 0.999997121442322

a= 0.9976 Ln(-Ra)0, mol/l*s

b= 1.0431
n= 2.0407

-5 -4.5 -4 -3.5

LnCa0, Mol/l
 LnCa0 LnCb0
-4.60517019
-3.91202301
-3.21887582
-2.81341072
-3.90207267
-3.20892549
. -2.80346039
-2.51577831

Ca0=cte

3.5 f(x) = 1.04314802236329 x + 6.40199227477

997594477563593 x + 6.2808864715428 R² = 0.999574785666578
99997121442322 3

Ln(-Ra)0, mol/l*s
2.5

1.5

0.5

0
-4 -3.5 -3 -2.5 -4 -3.8 -3.6 -3.4 -3.2 -3

LnCa0, Mol/l LnCa0, Mol/l

 4
4314802236329 x + 6.40199227477462 3.5
9574785666578
3

2.5

1.5

0.5

0
-3.6 -3.4 -3.2 -3 -2.8 -2.6 -2.4

LnCa0, Mol/l
Experimento CA, M CB, M -rA0, mol/(l*s) Ln(-Ra)0
1 0.05 0.5 7.236 1.97906857
2 0.1 0.5 14.472 2.67221575
3 0.2 0.5 28.81 3.36072255
4 0.3 0.5 43.282 3.76773684
5 0.5 0.015 13.688 2.61651954
6 0.5 0.0297 28.944 3.36536293
7 0.5 0.041 43.416 3.77082804
8 0.5 0.055 58.022 4.06082225

Cb0= cte
a= 0.9976
b= 1.1225 f(x) = 0.997594477563593 x + 4.96798971207
n= 2.1201 R² = 0.999997121442322

Ln(-Ra)0, mol/l*s

-3.5 -3 -2.5 -2 -1.

LnCa0, mol/l
 LnCa0 LnCb0
-2.99573227
-2.30258509
-1.60943791
-1.2039728
-4.19970508
-3.51660823
-3.19418321
-2.90042209

Ca0= cte
4
7594477563593 x + 4.96798971207989 3.5
997121442322
f(x) = 1.1224528615711 x + 7.32890946841081
3
R² = 0.999009182885858
Ln(-Ra)0, mol/l*s
2.5

1.5

0.5

0
-2.5 -2 -1.5 -1
-4.4 -4.2 -4 -3.8 -3.6 -3.4 -3.2
LnCa0, mol/l
LnCb0, mol/l
 4.5
4
615711 x + 7.32890946841081
2885858 3.5
3
2.5
2
1.5
1
0.5
0
-3.8 -3.6 -3.4 -3.2 -3 -2.8

LnCb0, mol/l
Experimento CA, M CB, M -rA0, mol/(l*s) Ln(-Ra)0
1 0.0521 0.2 0.004752 -5.3491897
2 0.1204 0.2 0.009504 -4.65604252
3 0.233 0.2 0.01892 -3.96753572
4 0.371 0.2 0.028424 -3.56052142
5 0.5 0.0345 0.008976 -4.71320093
6 0.5 0.06831 0.019008 -3.96289534
7 0.5 0.0943 0.028512 -3.55743023
8 0.5 0.1265 0.038104 -3.26743602

Cb0=cte

-3.5 -3 -2.5 -2

a= 0.9221
b= 1.1236

Axis Title
n= 2.0457

f(x) = 0.922065296540828 x − 2.6

R² = 0.997722558457712

Cuando Cb0 cte

Axis Title
Lnk +b*LnCb0 -2.6499
Lnk=lnrA-b*LnCb0 -0.84153556
k= 0.43104811 l/mol*s

Cuando Ca0 cte

Lnk +a*LnCa0 -0.9316

Lnk=lnrA-b*LnCb0 -0.29244898
k= 0.74643332 l/mol*s

k media= 0.58874072 l/mol*s

 LnCa0 LnCb0
-2.95459033
-2.11693575
-1.45671683
-0.99155322
-3.36679595
-2.68369911
-2.36127409
-2.06751297

Ca0=cte
0
-2.5 -2 -1.5 -1 -0.5 -3.6 -3.4 -3.2 -3 -2.8 -2

-1

-2

Axis Title
-3

f(x) = 0.922065296540828 x − 2.64988657783083 -4

R² = 0.997722558457712 f(x) = 1.12362234365634 x − 0.9315
R² = 0.999014879694846
-5

-6

Axis Title Axis Title

 0
-3.2 -3 -2.8 -2.6 -2.4 -2.2 -2
-0.5
-1
-1.5
-2
-2.5
-3
f(x) = 1.12362234365634 x − 0.931551741917491 -3.5
R² = 0.999014879694846
-4
-4.5
-5

Axis Title