Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
1. Identification
1.1. Product identifier
Product Identity 404 Corrosion Proof
Alternate Names 404 Corrosion Proof
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use See Technical Data Sheet.
Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Company Name Karnak Corporation
330 Central Ave.
Clark, NJ 07066 USA
Customer Service: Karnak Corporation 800-526-4236 [Link]
Emergency VelocityEHS (USA) (800) 255-3924
24 hour Emergency Telephone No. Outside U.S., Canada, Puerto Rico, U.S. Virgin Islands 1-813-248-0585
Australia 1-300-954-583; Brazil 0-800-591-6042; China 400-120-0751;
India 000-800-100-4086; Mexico 800-099-0731
2. Hazard(s) identification
2.1. Classification of the substance or mixture
Carc. 2;H351 Suspected of causing cancer.
2.2. Label elements
Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.
Warning
H351 Suspected of causing cancer.
[Prevention]:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P281 Use personal protective equipment as required.
Page 1 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
[Response]:
P308+313 IF exposed or concerned: Get medical advice / attention.
[Storage]:
P405 Store locked up.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and
Federal Hazardous Substances regulations.
Ingredient/Chemical Designations Weight % GHS Classification Notes
Calcium carbonate 25 - 50 Not Classified [1][2]
CAS Number: 0001317-65-3
Acrylic Polymer 25 - 50 Repr. 2;H361 [1]
CAS Number: Proprietary
Titanium dioxide 1.0 - 10 Not Classified [1][2]
CAS Number: 0013463-67-7
Barium metaborate 1.0 - 10 Acute Tox. 4;H302 [1]
CAS Number: 0013701-59-2 Acute Tox. 4;H332
Sodium potassium aluminium silicate 1.0 - 10 Combustible Dust [1]
CAS Number: 0037244-96-5
In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures
General In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.
Inhalation If respiratory discomfort occurs, remove to fresh air. If discomfort continues, administer
oxygen and get medical attention.
Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and
seek medical attention.
Skin If this product comes in contact with skin, remove material with mineral oil, then wash with
soap and plenty of water.
Page 2 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
Ingestion If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Overview No specific symptom data available.
Possible cancer hazard. Contains an ingredient which may cause cancer based on animal
data (See Section 3 and Section 15 for each ingredient). Risk of cancer depends on
duration and level of exposure.
See section 2 for further details.
5. Fire-fighting measures
5.1. Extinguishing media
Carbon dioxide (CO2 ), foam, or dry chemical. Water may be used to cool containers exposed to heat.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition: No hazardous decomposition data available.
5.3. Advice for fire-fighters
Material may foam if heated above 212F.
Minimize breathing vapors, gases or fumes of decomposition products. Do not enter any enclosed or confined fire
space without proper protective equipment, including self-contained breathing apparatus.
ERG Guide No. ----
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Put on appropriate personal protective equipment (see section 8).
6.2. Environmental precautions
Do not allow spills to enter drains or waterways.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove
soiled clothing and wash thoroughly before reuse.
6.3. Methods and material for containment and cleaning up
Eliminate sources of ignition, and ventilate the area. Add sand or earth or absorb spill with suitable absorbent material
and place in a closed container.
Keep product out of sewers and waterways by diking or impounding. Advise authorities if product has entered or may
enter sewers or waterways. Assure conformity with applicable governmental regulations.
7. Handling and storage
Page 3 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
7.1. Precautions for safe handling
See section 2 for further details. - [Prevention]:
7.2. Conditions for safe storage, including any incompatibilities
Handle containers carefully to prevent damage and spillage.
Do not freeze. Do not store in excess of 200F.
Incompatible materials: Strong oxidizing agents
Vapors are heavier than air and may travel along the ground or be moved by ventilation to locations distant from the
point of material handling. To prevent fumes from entering buildings or confined areas, close all air intake sources
near the material handling or the work area. To prevent ignition, avoid smoking, keep away from heat, open flames
and sources of static or electrical sparking. Use explosion proof motors and equipment. Tank trucks or other
containers should be grounded and/or bonded when the material is transferred.
Avoid prolonged or repeated inhalation of vapors or spray mists. Avoid prolonged or repeated skin contact. Adhere to
good hygienic practices. Avoid open flames. Use with adequate ventilation.
Store in a cool, dry place, out of direct sunlight and away from heat, sparks, and flame.
See section 2 for further details. - [Storage]:
7.3. Specific end use(s)
Health studies have shown that many petroleum hydrocarbons pose potential human health risks which may vary
from person to person. As a precaution, exposure to liquids, vapors, mists or fumes should be minimized.
8. Exposure controls and personal protection
8.1. Control parameters
Exposure
CAS No. Ingredient Source Value
0001317-65-3 Calcium carbonate OSHA TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)
ACGIH TWA: 10 mg/m3 Ceiling: 20 mg/m3
NIOSH TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp)
Supplier No Established Limit
0013463-67-7 Titanium dioxide OSHA TWA 15 mg/m3
ACGIH TWA: 10 mg/m32B, Revised 2006,
NIOSH Footnote ca
Supplier No Established Limit
0013701-59-2 Barium metaborate OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
Supplier No Established Limit
0037244-96-5 Sodium potassium aluminium silicate OSHA No Established Limit
ACGIH No Established Limit
Page 4 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
NIOSH No Established Limit
Supplier No Established Limit
Proprietary Acrylic Polymer OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
Supplier No Established Limit
The exposure limits for nuisance dust are: OSHA PEL: 15 mg/m3 (50 mppcf*) TWA, ACGIH 10 mg/m3.
Carcinogen Data
CAS No. Ingredient Source Value
0001317-65-3 Calcium carbonate OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
0013463-67-7 Titanium dioxide OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No;
0013701-59-2 Barium metaborate OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
0037244-96-5 Sodium potassium aluminium OSHA Select Carcinogen: No
silicate
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
Proprietary Acrylic Polymer OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
8.2. Exposure controls
Respiratory If workers are exposed to concentrations above the exposure limit they must use the
appropriate, certified respirators.
Eyes Safety glasses or face shield for liquid material.
Skin Solvent-resistant gloves.
Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the
use of local exhaust ventilation and good general extraction. If these are not sufficient to
maintain concentrations of particulates and any vapor below occupational exposure limits
suitable respiratory protection must be worn.
Other Work Practices Long sleeves and impervious clothing to protect against splashing.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or
using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
See section 2 for further details. - [Prevention]:
Page 5 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
9. Physical and chemical properties
Appearance Light Blue Liquid
Odor Slight Ammonia
Odor threshold Not Measured
pH Not Measured
Melting point / freezing point NA
Initial boiling point and boiling range 212F
Flash Point None Unless water is removed
Evaporation rate (Ether = 1) (Butyl Acetate=1)@77F: < 1
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: Not Measured
Upper Explosive Limit: Not Measured
Vapor pressure (Pa) 77F: 23.7mm of hg
Vapor Density (Air=1): > 1
Specific Gravity (H2O=1): 1.10 - 1.45
Solubility in Water Soluble
Partition coefficient n-octanol/water (Log Kow) Not Measured
Auto-ignition temperature Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) Not Measured
9.2. Other information
No other relevant information.
10. Stability and reactivity
10.1. Reactivity
Hazardous Polymerization will not occur.
10.2. Chemical stability
Stable under normal circumstances.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
Auto-ignition temperature unknown.
10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Page 6 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
No hazardous decomposition data available.
11. Toxicological information
Acute toxicity
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation Inhalation
mg/kg mg/kg Vapor LC50, Dust/Mist LC50, Gas LC50,
mg/L/4hr mg/L/4hr ppm
Calcium carbonate - (1317-65-3) No data No data No data No data No data
available available available available available
Acrylic Polymer - (Proprietary) No data No data No data No data No data
available available available available available
Titanium dioxide - (13463-67-7) 10,000.00, Rat - 10,000.00, No data 6.82, Rat - No data
Category: NA Rabbit - available Category: NA available
Category: NA
Barium metaborate - (13701-59-2) No data No data No data No data No data
available available available available available
Sodium potassium aluminium silicate - (37244-96-5) No data No data No data No data No data
available available available available available
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate
was used in the calculation of the product's ATE (Acute Toxicity Estimate).
Classification Category Hazard Description
Acute toxicity (oral) --- Not Applicable
Acute toxicity (dermal) --- Not Applicable
Acute toxicity (inhalation) --- Not Applicable
Skin corrosion/irritation --- Not Applicable
Serious eye damage/irritation --- Not Applicable
Respiratory sensitization --- Not Applicable
Skin sensitization --- Not Applicable
Germ cell mutagenicity --- Not Applicable
Carcinogenicity 2 Suspected of causing cancer.
Reproductive toxicity --- Not Applicable
STOT-single exposure --- Not Applicable
STOT-repeated exposure --- Not Applicable
Aspiration hazard --- Not Applicable
Page 7 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
12. Ecological information
12.1. Toxicity
Harmful to aquatic life.
Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae,
Ingredient
mg/l mg/l mg/l
Calcium carbonate - (1317-65-3) Not Available Not Available Not Available
Acrylic Polymer - (Proprietary) Not Available Not Available Not Available
Titanium dioxide - (13463-67-7) 1,000.00, Fundulus 5.50, Daphnia magna 5.83 (72 hr), Pseudokirchneriella
heteroclitus subcapitata
Barium metaborate - (13701-59-2) Not Available Not Available Not Available
Sodium potassium aluminium silicate - (37244-96-5) Not Available Not Available Not Available
12.2. Persistence and degradability
There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available.
13. Disposal considerations
13.1. Waste treatment methods
Observe all federal, state and local regulations when disposing of this substance.
14. Transport information
Page 8 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
The description shown may not apply to all shipping situations. Consult 49 CFR, or appropriate
regulations, for additional description requirements.
DOT Shipping Name: NON-Regulated
DOT Label Information: NA
DOT Hazard Class: NA
DOT Packing Group: NA
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected
regulations are represented.
Toxic Substance All components of this material are either listed or exempt from listing on the TSCA
Control Act ( TSCA) Inventory.
WHMIS Classification D2A
US EPA Tier II Hazards Fire: No
Sudden Release of Pressure: No
Reactive: No
Immediate (Acute): No
Delayed (Chronic): Yes
EPCRA 311/312 Chemicals and RQs:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
EPCRA 302 Extremely Hazardous:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
EPCRA 313 Toxic Chemicals:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
California Proposition 65 (>0.0%):
⚠ WARNING: This product can expose you to chemicals including titanium dioxide, which is known to
the State of California to cause cancer and/or reproductive hazards. For more information, go to
[Link].
New Jersey RTK Substances (>1%):
Calcium carbonate
Titanium dioxide
Pennsylvania RTK Substances (>1%):
Calcium carbonate
Titanium dioxide
16. Other information
Page 9 of 10
Safety Data Sheet
404 Corrosion Proof
SDS Revision Date: 07/24/2024
The information and recommendations contained herein are based upon data believed to be correct. However, no
guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.
We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our
products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and
orders.
The full text of the phrases appearing in section 3 is:
H302 Harmful if swallowed.
H332 Harmful if inhaled.
H361 Suspected of damaging fertility or the unborn child.
This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats
are not applicable.
Disclaimer: This information relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process. Although certain hazards are described herein, we
cannot guarantee that these are the only hazards that exist. The information has been completed to the best of our
knowledge and is believed to be accurate and reliable as from the date indicated. However, no warranty is made as
to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy oneself as to the suitability and
completeness of such information for his own particular use.
End of Document
Page 10 of 10
