Answers to the questionnaire
Q1. Answer: c
In a NaCl lattice, each sodium ion has 6 chloride ions surrounding it immediately,
positioned at the center of each face of a cube (or at the corners of a tetrahedron).
Likewise, each chloride ion has 6 sodium ions surrounding it in the same manner,
making the coordination number 6:6.
Q2. Answer: (A)
Q3: Which reagent :
-can confirm the carbonyl group presence in an organic compound
Answer: (B)
An aqueous solution of 2,4-dinitrophenyl hydrazine (DNP) is known as Brady's
reagent. It reacts with carbonyl compounds (aldehydes and ketone) to give a
coloured precipitate. These precipitates have a sharp melting point. The melting
points of the precipitates confirm the carbonyl compounds.
-Does not distinguish between aldehydes and ketones
* 2,4-dinitrophenylhydrazine can be used as a method for identifying aldehydes
and ketones – the 2,4-dinitrophenylhydrazone formed is a solid that can be purified
and its melting point determined
Q4. Answer: D.
Q5. Ans: A
Q6. B
Q7. A. Ester & Carboxylic acid
B. NaOH
Q8. Z= 25
A. B. Oxidation or reduction of Co in empty or partially filled d orbitals
Q9.
A. CH3CH2NH2 + HCl NH3 + CH3CH2Cl
B. Ethylamine.
Q10. S= KMnO4 or any other strong oxidizer
X= NaOH
b. T=
C= CO2 or Na2CO3
Q11.
a) i) Step I
ii) Step II
ii) Step III are as per below:
Step I.
b) Reduction
C) `yyy
d) Step I: Free radical substitution
Step II: Nucleophilic substitution(SN)
Q12.
a)
i) X) Penta-2-one Y= 2-Methylpropanal
ii) Tollens’ reagent or Ammonium Silver Complex. Again , negative test is
observed with ketone while dark red precipate is formed from blue Fehling
reagent when subjected to aldehydes.
b) CHI3CH2CHECOONa + 3H2O + NaI
Q13. a) High temperature
b) 2Al2O3(l)→4Al (l)+3O2(g)
c) Because the carbon electrodes react with oxygen during reactions and must be replaced continuously
and uses too much energy for extraction
Q14. A) 2-Hydroxypropanoic acid (lactic acid) shows optical isomerism because it has a chiral center at
carbon-2, which is attached to four different groups, allowing it to exist as two mirror-image forms
(enantiomers).
b)
HO
|
CH3—C—COOH
|
H
C ) with polarimetry
Q15. a)the molecular formula of C3H6O
b) CH₃COCH₃ and CH₃CH2CHO
c) CH₃CH2CHO
Q16. a) - Cis-Isomer (Z): The phenyl group and carboxyl group are on the same side of the double
bond. HOOC-CH=CH-C6H5
-Trans-Isomer (E): The phenyl group and carboxyl group are on opposite sides of the
double bond.
HOOC-CH=CH-C6H5
b) - Markovnikov Product: C6H5-CH(Br)-CH2-COOH
(Bromine added to the carbon adjacent to the phenyl group, hydrogen to the terminal carbon).
- Anti-Markovnikov Product: C6H5-CH2-CH(Br)-COOH
(Hydrogen added to the carbon adjacent to the phenyl group, bromine to the terminal carbon).
C6H5-CH(Br)-CH2-COOH and C6H5-CH2-CH(Br)-COOH
Q17. B)
18. D)
Q19. Addition 1. Hydrogen
Addition II. Oxidation with KMnO4.
Q20. Which of the following is a weak acid. Aniline, benzene, phenol , toluene
C)
Q21.
a) Triamminotriaqua chromium III ion
b) Triethylamine cobalt III Sulphate
c) Potassium Hexacyanoferric
d) Pentacarbonium iron (0)
Q22. Refer to your copy
Q23.
a) Air
b) NH3 (ammonia)
c) Haber Process
d) NO2
e) HNO3 formation
f) NH4NO3 and Ca(NO3)2
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