VASANTH KUMAR G CHEMICAL KINETICS GPUC FOR GIRLS, PUTTUR

Preparatory-24 21.For __ order reaction, units of both rate and rate

1.Order of a reaction is determined by constant are same.(Zero order)
a) balanced chemical equation 22.Draw the distribution curve showing temperature
b) experimental rate expression dependence of rate of the reaction.
c) unbalanced chemical equation d) Thermo-Chemical eq 23. For a reaction, A+B →products, the rate law is given
2. The molecularity of a reaction cannot be; by V= k [A]1[B]1, order of reaction is
a)Zero b) Fraction c) Both a and b d)Whole number a) First order b) Second order
3.The rate of reaction at a particular moment of time is c) Third order d)Zero order
called 24.The half life period of _____ order reaction is directly
4. Define order of a reaction. For which order reaction the proportional to the initial concentration of reactant.(Zero)
unit of rate of reaction and rate constant same ? 25. The order of the reaction for decomposition of
5.Which of the following is an acceptable value of Hydrogen peroxide in alakline medium
molecularity? a) 5 b) 0 c) 3/2 d) 2 a) First order b) Second order
6. Molecularity of the reaction is always____(Intiger) c) Pseudo first order d)Zero order
7. Define collision frequency and temperature co-efficient. 26. The temperature dependence of the rate of a chemical
8.The value of activation for a radioactive decay is reaction is explained by ____
a)High b)Low c) almost zero d) Moderate 27. Show that for the first order reaction, half life period
9. Which of the following is also known as ‘Trial and error’ is independent of initial concentration of the reactants.
method? 28. The rate law equation for the reaction:
a)integrated method b)isolation method A +2B→ C +D is rate ( r) =k [A], the order with respect
c) initial rate method d)Half-life method to ‘B’ a) Two b) One c)Zero d) All of these
10. The rate of a paticular reaction doubles when 29. The representation of rate of reaction in terms of
temperature changes. concentration of the reactant is known as____
11. The order of the reaction for the decomposition of 30. The conversion of molecules X to Y follows second
hydrogen peroxide in alakline medium. order kinetics. If the concentration of X is increased to
a) First order b) Zero order three times, how will it affect the rate of formation of Y
c) Second order d)Pseudo first order 31. Order of a reaction is determined by
12. The temperature dependence of the rate of a chemical a) Balanced chemical equation
reaction is explained by___(Arrehenius equation) b) Unbalanced chemical equation
13. Show that for the first order reaction, half life period is c) Experimental rate expression
independent of initial concentration of the reactants d) Thermo-chemical equation
14. Half life period is independent of intial concentration of 32. A catalyst _____ energy of activation.(Decreases)
reactant for a) First order b) Zero order 33. For a first order reaction, the half life period is 110
c) Second order d)Third order min. Calculate the time required to complete 75 % of the
15.Define pseudo First order Reaction. Give an example. reaction.
16. Acid hydrolysis of ethyl acetate is an example for 34. For the reaction P + Q →products, rate law is r =
a)Zero order reaction b) Pseudo first order reaction k[P]1/2 [Q]3/2 a) 1 b) ½ c) 0 d) 2
c) Second order reaction d) Fraction order reaction 35. According to the collision theory, the reactant
17. In a multistep reaction, rate of reaction depends molecules are assumed to be_____(Hard sphere)
on___(Slowest step) 36. The thermal decomposition of HI on gold surface is
18. Molecularity of reaction cannot be_____(Zero) an example of a) Zero order b) First order
19. Reperesent graphically the effect of catalyst on reaction c) Half order d) Second order
rates. 37. Molecularity of elementary reaction can be predicted
20.For the reaction 2A +3B → 4C +D, which of the following only by _____ (Balanced chemical equation)
does not express average rate of the reaction ? 38. Radioactive desintigration is an example of
𝑑[𝐴] 𝒅[𝑪] 𝑑[𝐷] 𝑑[𝐵]
a) - b) - c) + d) - a) Zero order b) First order
2𝑑𝑡 𝟒𝒅𝒕 𝑑𝑡 3𝑑𝑡
c) Third order d) Second order
39. Gibb’s free energy of a reaction is not altered by the 57. What are the main criteria for effective collision
addition of____(Catalyst) according to collision theory
40.Example for fractional order of reaction is 58.In the reaction 2A + B→ A2B, the reactant A will
a) H2 + Cl2→ 2HCl b)H2 + I2→ 2HCI disappear at ___
b) H2 + F2→ 2HF d) H2 + Br2→ 2HBr a) Twice the rate that B will disappear
41. For the reaction 2N2O5→4NO2 + O2 The order of reaction b) Half the rate that B will disappear
is ____first order c) The same rate that B will disappear
42. Write any 2 difference between order and molecularity of d) D) The same rate that A2B will appear
the reaction. 59.Half life of a first order reaction is 4 seconds, and
43. In a reaction when the concentration of reactant is the initial concentration of the reaction is 0.12 M, the
increased by nine times, the rate increases by 3 times. The concentration of the reactant left after 16 seconds.
order of the reaction is a) 3 b) 2 c) 1 d) 1/2 a)0.0075M b)0.06M c)0.03M d)).0015M
44. Define rate of a reaction. What is the unit of rate of 60.A reaction involving two different reactants in an
reaction? elementary reaction can never be___(unimolecular)
45. For a chemical reaction A→B, it is found that the rate of
Preparatory-24 (problems)
reaction doubles when the concentration of A is increased
1.For the first order reaction, half-life period of the
four times. The order of the reaction is
reaction is 120 minutes, calculate the time taken to
a) two b) one c) half d) zero
complete 90%o of the reaction.
46. A reaction proceeds with a uniform rate throughout. The
2. The specific reaction rate of a reaction triples when
order is____Zero order
the temperature changes from 30C to 50°C. Calculate
47. For the first order reaction, the plot of lnR v/s t gives a
the energy of activation of the reaction (R =8.314 JK-1
straight line with slope equal to
𝒌 𝑘 𝑘
mol-1 )
a) - b) c) 𝑙𝑛 d) -k 3. The rate constant of a reaction at 500K and 700K are
𝟐.𝟑𝟎𝟑 2.303 2.303
48. Inversion of cane sugar is an example of____ 0.02 S-1 and 0.07S-1 respectively. calculate the energy
reaction(Pseudo first order). of activation of the reaction.
49. The half life period for a zero- order reaction is inversely 5. A reaction is found to have a rate constant 3.46 X 10-
5
proportional to the ___(rate constant) at 250C and rate constant 4.87 X 10-3 at 650C.
50. The number of collision per second per unit volume of Caculate activation energy for the reaction((R =8.314
reaction mixture is called as____(Collision frequency) JK-1 mol-1 )
51. For the reaction 2HI(g) → H2(g)+ I2(g), which of the 6. Rate of a reaction A B increases two times by
following relation is correct? increasing the concentration ‘A’ by four times, what is
𝑑[𝐻2 ] 𝑑[𝐼2 ] 1 𝑑[𝐻𝐼] 𝑑[𝐻2 ] the order of a reaction?
𝑎) − = b) 2 =
𝑑𝑡 𝑑𝑡 𝑑𝑡 𝑑𝑡
2𝑑[𝐻𝐼] 𝑑[𝐼2 ] 𝑑[𝐼2 ] 1 𝑑[𝐻𝐼]
7. Half -life period of a first order reaction is 30
c) - 𝑑𝑡 = 𝑑𝑡 d) = −2 seconds. Calculate the time required for the 2/3rd
𝑑𝑡 𝑑𝑡
52. For a reaction 2 NO(g) + O2(g) → 2NO2(g) the correct completion of the reaction.
expression for average rate of a reaction is____ 8.The rate of a particular reaction doubles when
a) ravg = +
∆[𝑁𝑂]
b) ravg = −
∆[𝑂2 ] temperature changes from 270C to 370C. calculate the
∆𝑡 ∆𝑡
1 ∆[𝑁𝑂] 1 ∆[𝑁𝑂2 ]
energy of activation.
c) ravg = + 2 d) ravg = − 2 9. The decomposition of N2O5 in CCl4 at 318K has
∆𝑡 ∆𝑡
53._____ of a reaction can not be fraction.(Molecularity) been studied by monitoring the concentration of N2O5
54. Define half life period of a reaction. Mention the order of a in the solution. Intially , the concentration of N2O5 is
reaction in which t1/2 is independent of concentration of the 2.33 mol L-1 and after 184 minutes it is reduced to 2.08
reactant. mol L-1 the reaction take place according to the
55. NH4NO2→ N2 +H2O is an elementary reaction. The equation.
molecularity is ____(one) 2N2O5(g) →4NO2(g) +O2(g) calculate the average rate of
56. Write Arrhenius equation realting the rate constant of a reaction in terms of minutes and the rate of production
chemical reaction and absolute temperature. What is Ea in the of NO2 during this period.
equation? VASANTH KUMAR G
10. The Initial concentration of N2O5 in the following first 26. The decomposition of Cl2O7 at 500 K in the gas phase to
order reaction N2O5(g) →4NO2(g) + ½ O2(g) was 1.24 x 10-2 Cl2 and O2 is a first order reaction. After 1 minute at 500K, the
mol L-1 at 318K. the [NO2] ater 60 minutes was 0.20 x 10-2 pressure of Cl2O7 falls from 0.08 to 0.04 atm. Calculate the rate
constant in s-1
mol L-1 at 318 K. Calculate the rate constant of the reaction
27. In first order reaction, the concentration of a reactant
at 318K.
decreses from 400 mol L-1 to 25 mol L-1 in 200 seconds.
11.Rate constant of a reaction at 300 Kand 400 K are 0.0345
Calculate the rate constant for the reaction.
s-1 and 0.1365 s-1 respectively. Calculate the activation
28. Half life period of a first order reaction is 30 minutes.
energy for the reaction. (Given R= 8.314 JK-1mol-1)
Calculate the time required for 90% Completion of the
12.A first order reaction has a rate constant l.15 x 10-3 s-1.
reaction.
How long will 5 g of this reactant take to reduce to 3g?
29. For the first order reaction, show that the time taken
13. Rate constant of a first order reaction increases four
for 75% completion of the reaction is twice the time taken
times when the temperature canges from 270C to 470C.
for 50% completion of the reaction.
Calculate its activation energy. Given R =8.314 JK-1 mol-1 )
14. . Rate constant[k] of decay of a radioactive species is
30.For a first order reaction, R→P the initial
found to be 5.5 x 10-14 s-1. Then find half life period and the
concentration of the reactant was 1.24 X10-2 mol L-1 at
time for 99.9 % decay of radioactive species
318 K. After 60 minutes its concentration was reduced to
15. For a first order reaction, the temperature coefficient of
0.20 x 10-2 mol L-1. Calculate the rate constant of the
the reaction is approximately 2. Calculate energy of
reaction at 318K
activation for the reaction(Ea) when temperature changes
from 300K to 310 K.( R =8.314 JK-1 mol-1 ) 31.The half life period of a first order reaction is 69.3
16.Calculate the rate constant of the first order reaction, If min. Calculate the time required for 75% completion of
70% of chemical reaction is completed in 23 mins the reaction
17. For a first order reaction, the half-life period is 120 min.
Calculate the time required to complete 90% of the reaction. 32.The specific reaction rate of a reaction doubled when
18. A first order reaction 40 min for 30% completion. temperature changes from 300C to 500C. Calculate the
Calculate the half-life period of the reaction. energy of activation of the reaction(R =8.314 JK-1 mol-1)

19. The energy of activation of a reaction is 60 kJ mol-1. If 33.If a first order reaction rate is 80% complete in 60
its rate constant at 310 K is 2 x 10-4 s-1. Calculate the rate minute. Find the half -life period (t1/2) of the reaction.
constant at 320K. (Given: R= 8.314 J K-1 mol-1)
34.The rate constant of a certain reaction is 10 min-1.
20. Show that for a reaction, the time taken for the
Calculate the half-life period of this reaction in seconds.
completion of 99 % of the reaction is twice for the
completion of 90% of reaction 35.The rate constant of a reaction at 250K and 400K are
21. The rate constant for a reaction at 500 K and 700K are 0.01 s-1 and 0.03 s-1 respectively. Calculate the energy of
0.02 s-1 and 0.07 s-1 respectively. Calculate activation activation of the reaction(R =8.314 JK-1 mol-1)
energy (Given: R= 8.314 J K-1 mol-1)
22. The rate constant for a first order reaction is 60 s-1. How
much time will it take to reduce the intial concentration of
the reactant to its 1/16th value?
23. 60 % of first order reaction was completed in 60 minutes
calculate the time taken for 50% completed
24. The rate constant of first order reaction becomes 5 times
when the temperature is raised from 350K to 400 K.
calculate the activation energy(Ea) for the reaction.
25. The rate constant of a first order reaction at 600K is
1.60 x 10-5 s-1. Its energy of activation is 209 KJ/mol.
Calculate the rate constant of the reaction at 700K(Given R=
8.314 JK-1mol-1)

VASANTH KUMAR G