Code: 0136

Notes:
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1. (L.O.2.1) Choose the correct answer. For the 7. (L.O.2.1) The standard Gibbs free energy of
reaction C(s) + O2(g) → CO2(g), △E is internal formation of __________ is zero.
energy. (1) O2 (g)
a. △H >△E (2) Cl2 (g)
b. △H < △E (3) H (g)
c. △H = △E a. (1) and (2) only
d. Can not compare △H and △E b. (2) and (3) only
2. (L.O.2.1) The △Ho for the following reaction at c. (3) only
298 K is -36.4 kJ. d. (1), (2) and (3)
1/2 H2(g) + 1/2 Br2(l) → HBr(g) 8. (L.O.2.2) The normal boiling point of water is
Calculate △Eo (internal energy) at 298 K. R= 8.314 100.0 °C and its molar enthalpy of vaporization is
J/mol K. 40.67 kJ/mol. What is the change in entropy in the
a. -35.2 kJ system in J/K when 19.65 grams of water (liquid)
b. +35.2 kJ at 1 atm vaporizes at the normal boiling point?
c. -36.4 kJ a. +238
d. -37.6 kJ b. -119
3. (L.O.2.1) The symbol ΔHof [HNO3 (ℓ)] refers to c. -238
which one of the following reactions occurring at d. +119
25 °C? 9. (L.O.2.1) 2NO (g) = N2 (g) + O2 (g), H0298 = -
a. HNO3 (ℓ) → H(g) + N2 (g) + O3 (g) 180.8 kJ. At standard condition, enthalpy of
b. ½ H2(g) + ½ N2(g) + 3/2 O2(g) → HNO3(ℓ) formation of NO (g) is:
c. HNO3(ℓ) → ½ H2(g) + ½ N2(g) + 3/2 O2(g) a. + 180.8 kJ.
d. H2 (g) + N2 (g) + O3 (g) → 2HNO3 (ℓ) b. -180.8 kJ.
4. (L.O.2.1) All of the following have a standard heat c. + 90.4 kJ.
of formation value of zero at 25oC and 1.0 d. -90.4 kJ.
atm except:
a. N2(g) 10. (L.O.2.2) A reaction that is spontaneous at any
b. Fe(ℓ) temperature if the signs of H and S must be
c. Ne(g) _______ and _______, respectively.
d. H2(g) a. −, +
b. +, +
5. (L.O.2.1) Giving the following compounds: I2, H2,
c. +, −
CH4, H2O at standard condition. Which
arrangement is correct about standard entropy d. −, −
S H0 2  S H0 2O  S I02  SCH
0
11. (L.O.4.1) Which one of the following will change
a. 4
the value of an equilibrium constant?
S I02  S H0 2O  S H0 2  SCH
0
a. adding other substances that do not react with
b. 4
any of the species involved in the equilibrium
0
SCH  S H0 2O  S H0 2  S I02 b. varying the initial concentrations of products
c. 4

S I02  S H0 2  S H0 2O  SCH
0 c. changing the volume of the reaction vessel
d. 4
d. none of them
6. (L.O.2.2) Calculate ΔGo for the following reaction 12. (L.O.2.2) Consider the following reaction at
2 CO2(g) → 2 CO(g) + O2(g), given that equilibrium: 2SO2 (g) +O2 (g) ⇌ 2SO3 (g), ΔH°= -
ΔGof[CO(g)] = -137.2 kJ/mol and ΔGof [CO2(g)] = 99kJ. Le Chatelier's principle predicts that an
-394.4 kJ/mol. increase in temperature will result in __________.
a. 257.2 kJ a. a decrease in the partial pressure of SO2
b. -257.2 kJ (decrease amount of SO2)
c. 531.6 kJ b. no changes in equilibrium partial pressures
d. 514.4 kJ c. a decrease in the partial pressure of SO3 (decrease
amount of SO3)

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d. an increase in Keq b. s-1
c. mol× l-1
13. (L.O.4.1) The Keq for the equilibrium below is d. l×mol-1× s-1
0.112 at 700oC. SO2(g) + ½O2(g) ⇌ SO3 (g). What
is the value of K’eq for the following reaction at
20. (L.O.3.1) A second-order reaction has a half-life of
18 s when the initial concentration of reactant is
700oC:
0.71 M. The rate constant for this reaction is
SO3(g) ⇌ SO2(g)+ 1/2O2(g). −1 −1
a. 8.93 __________ M s .
b. 0.224 a. 7.8× 10-2
c. 0.112 b. 3.8× 10-2
d. 79.74 c. 2.0× 10-2
d. 1.3
14. (L.O.4.1) Nitrosyl chloride, NOCl, dissociates on
heating as shown below. When a 1.50 gram sample
21. (L.O.5.2) At 25oC, the vapor pressure of pure
of pure NOCl is heated at 350oC in a volume of
water is 23.76mHg. When 2.7 mol of glycerine is
1.00 liter, the percent dissociation is found to be
dissolved into 100 mol of H2O at the same
57.2%. Calculate Kc for the reaction as written.
temperature, the vapor pressure of the solution is:
NOCl(g) ⇌ NO(g) + 1/2 Cl2(g)
a. 23.13mmHg
a. 0.876
b. 0.64mmHg
b. 9.26
c. 0.62mmHg
c. 0.107
d. 32.10mmHg
d. 1.75 x 10-4
22. (L.O.3.1) At elevated temperatures, dinitrogen
15. (L.O.4.1) The equilibrium constant Kp for the
pentoxide decomposes to nitrogen dioxide and
following reaction is 5.0 10 at 25 C . N2(g) +
8
oxygen:
3H2(g) ⇌ 2NH3(g). The value of G for this N2O5 (g)→ 4NO2 (g)+ O2 (g)
reaction is _______ kJ/mol. When the rate of formation of NO2 is
a. 22 5.510-4 M/s, the rate of reaction is __________
b. -25 M/s.
c. -50 a. 2.210-4
d. -22 b. 1.3810-4
c. 5.510-4
16. (L.O.3.1) For the reaction: d. 2.810-4
2H2S(g) + O2(g) → 2S(s) + 2H2O(l), which one of
the following statements is absolutely true?
23. (L.O.2.2) Calculate the standard entropy change
a. The reaction is first order with respect to H2S for the following reaction, F2(g) + H2(g) → 2
and second order with respect to O2. HF(g), given that So[H2(g)] = 130.68 J/mol×K,
b. The reaction is fourth order overall. So[F2(g)] = 202.78 J/mol×K and So[HF(g)] =
c. The rate law is: rate = k[H2S]2[O2]. 173.78 J/ mol×K.
d. The rate law cannot be determined from the a. -159.68 J/K
information given. b. 14.1 J/K
c. 159.68 J/K
17. (L.O.3.1) The rate law for a reaction is d. -116.58 J/K
rate = k  A  B
2
24. (L.O.3.2) The decomposition of N2O5 proceeds via
Which one of the following statements is FALSE? the reaction 2N2O5(g) → 4NO2(g) + O2(g). The rate
a. The reaction is first order in A. constant of the reaction at 64°C is 4.82 × 10-3 s-1.
b. The reaction is second order in B. The rate law for the reaction is rate = __________.
c. The reaction is second order overall. a. k[N2O5]2
d. k is the reaction rate constant
b. k[N2O5]
[𝑁𝑂2 ]4 [𝑂2 ]
18. (L.O.5.1) Choose the correct answer. c. 𝑘
[𝑁2 𝑂5 ]2
A solution with a concentration higher than the d. 2k[N2O5]2
solubility is __________.
a. unsaturated 25. (L.O.2.2) Given the following information:
b. supersaturated NiCl2(s) + H2O(g) → NiO(s) + 2 HCl(g), ΔHo =
c. supercritical +122.8 kJ and ΔSo = +125.4 J/K. The reaction is
d. saturated spontaneous at
a. above 979.2 K
b. below 979.2 K
19. (L.O.3.1) The rate law of a reaction is rate = k[A]2. c. above 979.2 oC
The units of the rate constant are __________. d. below 979.2 oC
a. mol× l-1×s-1.
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