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Carbohydrate Chemistry Quiz Questions

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104 views22 pages

Carbohydrate Chemistry Quiz Questions

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© © All Rights Reserved
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Available Formats
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15.

In the 'glycolipids', the two sugars known to occur are glucose and
(a) Fructose (b) Lactose
(c) Galactose (d) Sucrose
16. The ‘epimerisation’ involves
(a) Change of configuration
(b) Addition of one more 'C'
Carbohydrates (c) Substration of a 'C'
(d) Conversion of CHO to C  O
1. The change in optical rotation, with time, of freshly prepared 17. The compound which does not contain an asymmetric carbon atom
solution of sugar is known as [CPMT 1982, 85; BHU 1997] is
(a) Rotatory motion (b) Inversion (a) Glycolaldehyde (b) Glyceraldehyde
(c) Specific rotation (d) Mutarotation (c) Glucose (d) Galactose
2. Gun-cotton is 18. Which of the following sign indicate that the sugar is actually
(a) Nitrosucrose (b) Nitrocellulose ‘dextrorotatory’
(c) Nitroglucose (d) Nitropicrin (a) – (b) +
3. Which of the following monosaccharide is a pentose (c) R – (d) All of these
[CPMT 1982, 87, 89, 93]
(a) Galactose (b) Glucose 19. The standard compound for determination of configuration in the
(c) Fructose (d) Arabinose ‘sugar chemistry’ is
4. Amide group is present in (a) Glycolaldehyde (b) Glyceraldehyde
(a) Lipids (b) Carbohydrates (c) Glucose (d) Fructose
(c) Amino acids (d) Proteins 20. Sugars are
5. Which of the following is a carbohydrate (a) Optically active polyhydroxy aldehydes
(a) Leucine (b) Albumin (b) Optically active polyhydroxy ketones
(c) Inulin (d) Maltase (c) Optically active polyhydroxy aldehydes or ketones
6. General formula for carbohydrates is (d) Polyhydroxy aldehydes or ketones which may or may not be
(a) Cn H 2nO2n  2 (b) C x (H 2O)2 x optically active
(c) C x (H 2O)y (d) None of these 21. Molecular formula of pentahydroxy acid obtained when glucose is
oxidised with Br2 water is
7. Benedict solution provides [CPMT 1983]
  (a) C6 H12 O7 (b) C6 H12 O8
(a) Ag (b) Li
(c) Cu 2 (d) Ba2 (c) C6 H12 O6 (d) C6 H10 O6
8. Glucose gives silver mirror with Tollen's reagent. It shows the 22. The 'phosphoglycerides' occur in
presence of (a) The brain and the spinal chord
[MNR 1981; CPMT 1974, 81; MP PMT 1994]
(b) Nails and hairs
(a) An acidic group (b) An alcoholic group
(c) A ketonic group (d) An aldehydic group (c) Oils and fats
9. A certain compound gives negative test with ninhydrin and positive (d) Waxes
test with Benedict's solution. The compound is 23. Sucrose is a [CPMT 1983]
[NCERT 1978; KCET 2000] (a) Monosaccharide (b) Disaccharide
(a) A protein (b) A monosaccharide (c) Trisaccharide (d) Polysaccharide
(c) A lipid (d) An amino acid 24. The commonest disaccharide has the molecular formula
10. An organic compound answers Molisch's test as well as Benedict's
[CPMT 1982; Manipal MEE 1995;
test. But it does not answer Scliwanoff's test. Most probably, it is [KCET 2003]
MP PET 1999; AIIMS 1999]
(a) Sucrose (b) Protein
(c) Fructose (d) Maltose (a) C10 H18 O9 (b) C10 H 20 O10
11. Glucose when heated with CH 3 OH in presence of dry HCl gas (c) C18 H 22 O11 (d) C12 H 22 O11
gives  and   methyl glucosides because it contains 25. On complete hydrolysis of starch, we finally get
[CPMT 1982, 85] [MNR 1982; DPMT 1979; CBSE PMT 1991;
(a) An aldehyde group (b) A CH 2OH group MP PMT 1987; MP PET 1993]
(a) Glucose (b) Fructose
(c) A ring structure (d) Five hydroxyl groups
(c) Glucose and fructose (d) Sucrose
12. Which one is a disaccharide [CPMT 1981, 83]
(a) Glucose (b) Fructose 26. Which is monosaccharide
(c) Xylose (d) Sucrose (a) Glucose (b) Fructose
(c) Galactose (d) All of these
13. Molecular formula C6 H12 O6 is of
27. Which is polysaccharide
(a) Glucose (b) Fructose (a) Starch (b) Cellulose
(c) Both (a) and (b) (d) None of these (c) Glycogen (d) All of these
14. Hydrolysis of sucrose is called 28. The calorific values of fats, carbohydrates and proteins vary in the
[BHU 1979, 83; Pb. PMT 1999; Pb. CET 2000] order
(a) Esterification (b) Saponification (a) Fats > Carbohydrates > Proteins
(c) Inversion (d) Hydration (b) Fats > Proteins > Carbohydrates
(c) Carbohydrates > Proteins > Fats (b) It is an aldehyde sugar
(d) Proteins > Carbohydrates > Fats (c) It has six carbon atoms
29. Gun-cotton is obtained when conc. nitric acid reacts with (d) It exhibits optical activity
(a) Glycerine (b) Glycol 43. Maltose contains how many oxygen atoms
(c) Cellulose (d) Starch (a) 6 (b) 10
30. A carbohydrate consists of [NCERT 1971] (c) 11 (b) 22
(a) C and O (b) C, H and O 44. The correct name of ‘sucrose' is
(c) C, H , N and O (d) C and H (a)   D  glucopyranosyl    D  fructofura noside

31. Glucose forms many derivatives. The derivative which will help to (b)   D  glucopyranosyl    D  fructofura noside
prove the furanose structure is (c)   D  glucopyranosyl    D  fructofura noside
[AIIMS 1980; DPMT 1985]
(d)   D  glucopyranosyl    L  fructofura noside
(a) Acetyl (b) Benzoyl
(c) Osazone (d) Isopropylidene 45. Sucrose is
32. Glucose and fructose form [MP PMT 1986]
(a) Laevorotatory (b) Dextrorotatory
(c) Racemic mixture (d) Optically inactive
(a) Same osazone
46. The hydrolysis of sucrose produces a mixture which is
(b) Same acid on oxidation
(c) Same alcohol when reduced (a) Laevorotatory
(d) Different osazone (b) Dextrorotatory
(c) Equally both (+) and (–) rotatory
33. On heating with conc. H 2 SO 4 , sucrose gives [DPMT 1984]
(d) Optically inactive
(a) CO and CO 2 (b) CO and SO 2 47. Sucrose is
(c) CO , CO 2 and SO 2 (d) None of these (a) A reducing sugar
34. The letter ‘D’ in carbohydrates represents (b) Not a reducing sugar
(a) Its direct synthesis (b) Its dextrorotation (c) Partial reducing sugar
(c) Its mutarotation (d) Its configuration (d) Mixed sugar
35. Starch can be used as an indicator for the detection of traces of 48. Sucrose[CPMT
contains which of the following groups
1986]
(a) Glucose in aqueous solution (a) CHO (b)  C  O
(b) Protein in blood (c) Both (a) and (b) (d) None of these
(c) Iodine in aqueous solution 49. The fructose molecule in sucrose exists as
(d) Urea in blood (a) Furanose (b) Pyranose
36. It is best to carry out reactions with sugars in neutral or acid
(c) Open chain (d) All
medium and not in alkaline medium. This is because in alkaline
medium sugars undergo one of the following changes 50. Which one of the following
[AIIMS 1982] is laevorotatory [DPMT 1989]
(a) Racemisation (b) Decomposition (a) Glucose (b) Sucrose
(c) Inversion (d) Rearrangement (c) Fructose (d) None of these
37. Which one of the following compounds is found abundantly in 51. Chemically 'digestion' is [NCERT 1978]
nature [BHU 1983; Manipal MEE 1995; DCE 2004]
(a) Hydrolysis (b) Change in bacteria
(a) Fructose (b) Starch
(c) Glucose (d) Cellulose (c) Hydrogenation (d) Dehydrogenation
38. The substance that forms the plant cell walls is or Which 52. Which one of the following is the reagent used to identify glucose
carbohydrates is an essential constituents of plant cells (a) Neutral ferric chloride
[KCET 1984; MP PET 1999; CPMT 2002] (b) Chloroform and alcoholic KOH
(a) Cellulose (b) Sucrose
(c) Ammoniacal silver nitrate
(c) Vitamins (d) Starch
39. Sugar can be tested in urine by (d) Sodium ethoxide
(a) Molisch test (b) Dunstan's test 53. Sucrose on hydrolysis gives
(c) Benedict's test (d) Legal's test [MP PMT 1993; Bihar MEE 1997]
40. When sucrose is heated with conc. HNO 3 the product is (a) Two molecules of glucose
[CPMT 1979] (b) Two molecules of fructose
(a) Sucrose nitrate (b) Formic acid (c) One molecule each of glucose and fructose
(c) Oxalic acid (d) Citric acid
(d) One molecule each of glucose and mannose
41. Amylopectin is [KCET 2005]
54. Which of the following is a disaccharide [CPMT 1990, 94]
(a) Water soluble
(b) Water insoluble (a) Lactose (b) Starch
(c) Forms colloidal solution with water (c) Cellulose (d) Glucose
(d) Both (b) and (c) 55. Glucose cannot be classified as [CPMT 1989]
42. Which of the following statements about ribose is incorrect (a) A hexose (b) A carbohydrate
[CPMT 1985]
(c) An oligosaccharide (d) An aldose
(a) It is a polyhydroxy compound
56. The reagent which forms crystalline osazone derivative when reacted (c) Neutral (d) Amphoteric
with glucose, is [CPMT 1990] 71. Glucose contains [CPMT 1982]
(a) Fehling solution (b) Phenylhydrazine
(a) One CHO group
(c) Benedict solution (d) Hydroxylamine
(b) Five OH groups
57. An enzyme which brings about the conversion of starch into maltose
is known as [BHU 1979] (c) One primary alcoholic group
(a) Maltase (b) Zymase (d) Four secondary alcoholic groups
(c) Invertase (d) Diastase (e) All are correct
58. Canesugar on hydrolysis gives 72. Carbohydrates are stored in human body as
[MADT Bihar 1984; NCERT 1977; AMU 1985] [MP PMT 1999; Kerala PMT 2004]

(a) Glucose and maltose (b) Glucose and lactose (a) Glucose (b) Glycogen
(c) Glucose and fructose (d) Only glucose (c) Starch (d) Fructose
59. Glucose is a [CPMT 1984]
73. An example of a disaccharide made up of two units of the same
monosaccharides is
(a) Monosaccharide (b) Disaccharide [KCET 1989; MP PET 1996; AFMC 2005]
(c) Trisaccharide (d) Polysaccharide (a) Sucrose (b) Maltose
60. Which carbohydrate is used in silvering of mirrors (c) Lactose (d) None of these
[BHU 1973; CPMT 1991] 74. The sugar present in fruits is [KCET 1984]
(a) Sucrose (b) Starch (a) Fructose (b) Glucose
(c) Glucose (d) Fructose (c) Sucrose (d) Galactose
61. A carbohydrate that cannot be hydrolysed to simpler forms is called 75. Carbohydrates are [MADT Bihar 1983]
(a) Disaccharide (b) Monosaccharide (a) Hydrates of carbon
(c) Polysaccharide (d) Trisaccharide (b) Polyhydroxy aldehydes or ketones
62. If monosaccharide contains an aldehyde group, it is known as (c) Polyhydroxy acid compounds
(d) None of these
(a) Epimer (b) Osones
76. Glucose and fructose are [Bihar MADT 1982]
(c) Osazone (d) Aldose
(a) Isotopes
63. If a monosaccharide contains a ketogroup, it is known as
(b) Isotones
(a) Ketose (b) Osones (c) Isomers
(c) Epimer (d) Osazone (d) Homologues of each other
64. The aqueous solution of a carbohydrate gives dark blue colour with 77. Hydrolytic conversion of sucrose into glucose and fructose is known
iodine. It is as [BHU 1979, 97]
(a) Glucose (b) Fructose (a) Induction (b) Saponification
(c) Sucrose (d) Starch (c) Inversion (d) Esterification
65. Which of the following carbohydrates is a disaccharide 78. Starch is a polymer of
(a) Glucose (b) Fructose [DPMT 1982; CPMT 1975, 80; MP PMT 1994]
(c) Raffinose (d) Maltose (a) Glucose (b) Fructose
(c) Both (a) and (b) (d) None of these
66. Optical activity is shown by
79. To become a carbohydrate a compound must contain at least
(a) Glucose (b) Fructose
(a) 2 carbons (b) 3 carbons
(c) Sucrose (d) All of these
(c) 4 carbons (d) 6 carbons
67. Which is a reducing sugar 80. Lactose on hydrolysis gives [KCET 1983]
(a) Glucose (b) Fructose (a) Two glucose molecules
(c) Galactose (d) All of these (b) Two galactose molecules
68. The ultimate product of oxidation of most of hydrogen and carbon (c) A galactose molecule and a fructose molecule
in foodstuffs are [CPMT 1981] (d) A galactose molecule and a glucose molecule
(a) H 2 O alone (b) CO 2 alone 81. An example of non-reducing sugar is [KCET 1988]
(a) Cane sugar (b) Fructose
(c) H 2 O and CO 2 (d) None of these
(c) Lactose (d) Cellobiose
69. Osazone formation involves only 2 carbon atoms of glucose because 82. Cellulose is a polymer of [KCET 1984]
of [MP PMT 1986] (a) L-fructose (b) D-mannose
(a) Chelation (b) Oxidation (c) D-glucose (d) Amylose
(c) Reduction (d) Hydrolysis 83. The intermediate compound formed in the conversion of starch to
glucose is [KCET 1984]
70. Glucose will show mutarotation when solvent is
(a) Lactose (b) Sucrose
[MP PMT 1986]
(c) Maltose (d) Fructose
(a) Acidic (b) Basic
84. Invertase brings about the conversion of [KCET 1986] 94. When amylases catalyse the hydrolysis of starch, the final product
(a) Starch to glucose obtained is chiefly [Pb. PMT 1998]
(b) Sucrose to glucose and fructose (a) Cellobiose (b) Glucose
(c) Maltose to glucose (c) Maltose (d) Sucrose
95. Galactose is converted into glucose in [AFMC 1998]
(d) Glucose to C2 H 5 OH and CO 2
(a) Mouth (b) Stomach
85. Which of the following pentoses will be optically active (c) Liver (d) Intestine
CHO CHO CHO 96. Which among the following is the simplest [CPMT 1999]
| | | (a) Glucose (b) Cellulose
HCOH HCOH HCOH (c) Starch (d) None of these
| | | 97. Indigestible carbohydrate, which is also a constituent of our diet, is
HOCH HCOH HCOH (a) Cellulose (b) Galactose
(c) Maltose (d) Starch
| | |
98. Starch is converted into maltose by the
HCOH HOCH HCOH
[DPMT 1979; CPMT 1982; BHU 1999]
| | | (a) Maltase (b) Invertase
CH 2 OH CH 2 OH CH 2 OH (c) Zymase (d) Diastase
I II III 99. The disaccharide present in milk is
[MP PET 1994] [CPMT 1982, 87, 91; MP PET 2001]
(a) All (b) II and III (a) Maltose (b) Lactose
(c) I (d) II (c) Sucrose (d) Cellobiose
86.   D  glucose and   D  glucose differ from each other due to 100. Carbohydrates are used by body mainly[DCE 1999]
difference in one of the carbons with respect to its (a) For obtaining vitamins
[CBSE PMT 1995; AFMC 1999] (b) As source of energy
(a) Size of hemiacetal ring (b) Number of OH groups (c) For all its developmental needs
(c) Configuration (d) Conformation (d) For building muscles
87. Which carbohydrates has highest abundance in human blood 101. [MP PETprocess
In the viscose 1995] the solvent for cellulose consists of
(a) d-fructose (b) d-glucose [JIPMER 1999]
(c) Sucrose (d) Lactose (a) Ether and alcohol
88. Formation of silver mirror by glucose shows that it is a/an (b) Copper sulphate and ammonia
(a) Oxidising agent (b) Acid (c) Sodium hydroxide and carbon disulphide
(c) Reducing agent (d) A salt of silver (d) Acetic acid and acetic anhydride
89. Which of the following statements is right
102. Which of the following does not reduce Benedict's solution
(a) Cellulose are linear polymers of   glucose molecules with [KCET 2000]
  1, 4  linkages (a) Sucrose (b) Aldehyde
(b) Starches are polymers of   glucose molecules with (c) Glucose (d) Fructose
  1, 4  linkages and some   1, 6  cross-linkages 103. In polysaccharides the linkage connecting monosaccharide units is called
(a) Glycoside linkage (b) Nucleoside linkage
(c) Proteins are polyamides of   amino acids
(c) Glycogen linkage (d) Peptide linkage
(d) The structural information about their biosynthesis is
contained in a class of compounds called nucleic acids, e.g. RNA 104. Blood sugar is the same as [DPMT 2000]
and DNA (a) Glucose (b) Galactose
90. The number of atoms in the cyclic structure of D-fructose is (c) Glycogen (d) Fructose
[MP PMT 1997] 105. Glucose has functional group [MH CET 2000]
(a) 5 (b) 6 (a) Aldehydic
(c) 4 (d) 7 (b) Aldehydic and alcoholic
91. Which is used in motion picture films
(c) Alcoholic
(a) Cellulose acetate (b) Glucose acetate
(d) Ketonic and alcoholic
(c) Starch acetate (d) Sucrose acetate
106. Which of the following is an aldohexose
92. Glucose reacts with acetic anhydride to form
[KCET 1996] [KCET (Engg.) 2001]
(a) Mono-acetate (b) Tetra-acetate (a) Cellulose (b) Sucrose
(c) Penta-acetate (d) Hexa-acetate (c) Glucose (d) Raffinose
93. Which of the following does not show any reducing test of aldehyde[CPMT 107. The calorific
1996; Orissa JEE 2004]value is maximum in case of
(a) Sucrose (b) Fructose [Kerala (Med.) 2000]
(c) Maltose (d) Lactose (a) Milk (b) Proteins
(c) Minerals (d) Carbohydrates
108. An invert sugar is [AFMC 2000] [MP PMT 2003]
(a) Isorotatory (b) Dextrorotatory (a) Glucose (b) Aspartame
(c) Laevorotatory (d) Optically inactive (c) Saccharin (d) Cyclodextrin
109. The change in optical rotation with time of freshly prepared 122. The specific rotation of equilibrium mixture of -D-glucose and -
solutions of sugar is known as [JIPMER 2000] D-glucose, is [MP PMT 2003]

(a) Maturation (b) Rotatory motion (a)  19 o (b)  112 o


(c) Inversion (d) Specific rotation (c)  52 o (d)  100 o
110. Yeast cell derive their energy from glucose by 123. The charring of sugar, when treated with conc. H 2 SO 4 , is due to
[AIIMS 2001] (a) Oxidation (b) Reduction
(a) Glycolysis (b) Respiration formation (c) Dehydration (d) Hydrolysis
(c) Formation (d) None of these 124. Which among the following is the simplest sugar
111. Which of the following is correct statement [Pb. CET 2002]
[CBSE PMT 2001] (a) Glucose (b) Cellulose
(a) Troleins are amino acid (b) Starch (d) Glycogen
125. Glucose and mannose are [Orissa JEE 2004]
(b) -hydrogen is present in fructose (a) Epimers (b) Anomers
(c) Starch is polymer of -glucose (c) Ketohexoses (d) Disaccharides
(d) Amylose is compound of cellulose 126. On hydrolysis, which produces only glucose [BVP 2004]
112. Which of the following is a aldohexose [KCET 2001] (a) Galactose (b) Maltose
(a) Cellulose (b) Sucrose (c) Sucrose (d) None
127. Pick out the one which does not belong to the family
(c) Galactose (d) Raffinose
[KCET 2004]
113. The ultimate product of the hydrolysis of starch is (a) Pepsin (b) Cellulose
[DPMT 2001] (c) Ptyalin (d) Lipase
(a) Fructose (b) Glucose 128. Which of the following is the sweetest sugar
(c) Sucrose (d) None of these [MP PMT 1997; CBSE PMT 1999; AIIMS 2000
114. Raffinose is [Pb. PMT 2001] Manipal MEE 1995; CPMT 1996; BHU 1997;]
(a) Glucose (b) Fructose
(a) Trisaccharide (b) Monosaccharide
(c) Lactose (d) Sucrose
(c) Disaccharide (d) None of these
129. Oxidation of glucose is one of the most important reactions in a
115. A sugar, that is not a disaccharide, among the following is living cell. What is the number of ATP molecules generated in cells
[KCET (Med./Engg.) 2002] from one molecule of glucose
(a) Lactose (b) Galactose [CBSE PMT 1995]
(c) Sucrose (d) Maltose (a) 38 (b) 12
116. To detect the reducing and non reducing sugars, which of the (c) 18 (d) 28
following test is used [MH CET 2002] 130. Glucose has difference from fructose in that it [BHU 2005]
(a) Molisch test (b) Biuret test (a) Does not undergo hydrolysis
(c) Fehling's test (d) Millions test (b) Gives silver mirror with Tollen's reagent
(c) Monosaccharide
117. Which of the following is a disaccharide [MH CET 2002]
(d) None of these
(a) Glucose (b) Ribulose 131. In fructose, the possible optical isomers are
(c) Lactose (d) Arabinose [Orissa JEE 2005]
118. On heating glucose with Fehling's solution we get a precipitate (a) 12 (b) 8
whose colour is [CPMT 1979; CBSE PMT 1988; (c) 16 (d) 4
KCET 1992; DPMT 1983, 86; MP PMT 1996] 132. If an aqueous solution of glucoseis allowed to freeze than crystal of
(a) Yellow (b) Red which will be separated out first [DPMT 2005]
(c) Black (d) White (a) Glucose (b) Water
119. Glycolysis is [CBSE PMT 2003] (c) Both of these (d) None of these
(a) Conversion of glucose to haem 133. Which is false [J & K 2005]
(b) Oxidation of glucose to glutamate
(a) Glucose is a disaccharide
(c) Conversion of pyruvate to citrate
(b) Starch is a polysaccharide
(d) Oxidation of glucose to pyruvate
(c) Glucose and fructose are not anomers
120. Which of the following is an example of ketohexose
(d) Invert sugar consists of glucose and fructose
[Orissa JEE 2003]
(a) Mannose (b) Galactose
(c) Maltose (d) Fructose
Proteins, Amino Acids and Enzymes
121. The safest and the most common alternative of sugar is
1. Insulin is [CBSE PMT 1991]
(a) An amino acid (b) Protein [NCERT 1984; MP PET 1999; MP PMT 2001]
(c) A carbohydrate (d) A lipid (a) Proteins to amino acids
2. Peptides are (b) Fats to fatty acids
(a) Esters (b) Salts (c) Glucose to ethyl alcohol
(c) Amides (d) Ketones (d) Polysaccharides to monosaccharides
3. The proteins which are insoluble in water are 17. Which one of the following proteins transports oxygen in the blood
(a) Fibrous proteins (b) Globular proteins stream [MP PMT 1993]
(c) Both (a) and (b) (d) None of these (a) Myoglobin (b) Insulin
4. Irreversible precipitation of proteins is called (c) Albumin (d) Haemoglobin
(a) Denaturation (b) Hydrolysis 18. Enzymes are [MP PET 1993]
(c) Rearrangement (d) Electrophoresis (a) Living organisms
5. The proteins with a prosthetic group are called
(b) Dead organisms
(a) Pseudo proteins (b) Complex proteins
(c) Complex nitrogenous substances produced in living cells
(c) Conjugated proteins (d) Polypeptides
(d) None of these
6. The prosthetic group of haemoglobin is
(a) Porphin (b) Haem 19. Which is an essential constituent of diet [AFMC 1980]
(c) Globin (d) Globulin (a) Starch (b) Glucose
7. When collagen is boiled with water, it forms (c) Carbohydrate (d) Protein
(a) Precipitate (b) Solution 20. Proteins can be used
(c) Gelatin (d) Complex collagen (a) As food (b) In textile
8. Which of the following is not essential amino acid (c) As enzyme (d) All of these
(a) Valine (b) Lysine 21. Which of the following foodstuffs contains nitrogen
(c) Histidine (d) Glycine [DPMT 1986; MH CET 2002]
9. Amino acids are (a) Carbohydrates (b) Fats
(a) Liquids (c) Proteins (d) None of these
(b) Volatile solids 22. pH in stomach is approximately
(a) 7 (b) 2.0
(c) Non-volatile crystalline compounds
(c) 6.5 (d) 10
(d) Mixture of amines and acids
23. The helical structure of proteins is established by
10. Isoelectric point is a
[CPMT 1988]
(a) Specific temperature (a) Peptide bonds (b) Dipeptide bond
(b) Suitable concentration of amino acid (c) Hydrogen bond (d) Vander Waal's forces
(c) Hydrogen ion concentration that does not allow migration of 24. Natural silk is a
amino acid under electric field
(a) Polyester (b) Polyamide
(d) Melting point of an amino acid under the influence of electric
field (c) Polyacid (d) Polysaccharide
11. Proteins are hydrolysed by enzymes into 25. Protein contains [CPMT 1975; MP PMT 2002]
[CPMT 1981; BHU 1987; MP PMT 1994, 2002] (a) C, H , O and N (b) Only C and H
(a) Dicarboxylic acids (b) Hydroxy acids (c) Cl, H and O (d) All of these
(c) Amino acids (d) Aromatic acids
26. The end product of protein digestion is
12. Proteins when heated with conc. HNO 3 give a yellow colour. This [CPMT 1981; KCET 1984]
is [CPMT 1989] (a) Amino acid (b) Glucose
(a) Oxidising test (b) Xanthoprotic test (c) Glycerol (d) Oxalic acid
(c) Hoppe's test (d) Acid-base test 27. Protein can be most easily removed from [MNR 1988]
13. Enzymes are [DPMT 1980; MP PMT 1993, 96] (a) Alkanes (b) Alkenes
(a) Proteins (b) Minerals (c) Alkynes (d) Benzene
(c) Oils (d) Fatty acids 28. Which of the following contains the highest percentage of protein
14. Proteins are built up of (a) Groundnut (b) Cow's milk
[CPMT 1981, 99; BHU 1987; CBSE PMT 2001; (c) Egg (d) Wheat
MP PMT 1987, 96; KCET 1984] 29. The enzyme ptylin used for the digestion of food is present in[CPMT 1981; Pb. P
(a) Dicarboxylic acids (b) Amino acids (a) Saliva (b) Blood
(c) Alcohols (d) Hydroxy acids (c) Intestines (d) Adrenal glands
15. The main structural feature of proteins is 30. Which one of the following is an amino acid [KCET 1984]
[MNR 1987; MP PET 1993, 97, 2004]
(a) CH 3 CONH 2 (b) CH 3 CONHCH 3
(a) The ester linkage (b) The ether linkage
(c) The peptide linkage (d) All of these (c) CH 3 NHCHO (d) NH 2CH 2 .COOH
16. Pepsin enzyme hydrolyses 31. Biuret test is used for the detection of [KCET 1993]
(a) Saturated oils (b) Sugars (D) Muscles contain the protein keratin
(c) Proteins (d) Fats Point out the wrong statements in the above set of statements
32. Out of the following the best category of proteins is (a) A, B (b) C, D
[SCRA 1991] (c) A, C (d) B, D
(a) Polyamides (b) Polythioethers 42. Enzymes in the living systems [ CPMT 1999; AIIMS 2000;
(c) Glycerides (d) Polysaccharides CBSE PMT 1997; MP PET 1999;]
33. The molecular weight of protein is [KCET 1984] (a) Provide energy
(a) < 10000 (b) > 10000 (b) Provide immunity
(c) > 1000 (d) > 1000 and < 10000 (c) Transport oxygen
34. Which of the following is not a classification of proteins (d) Catalyse biological processes
[KCET 1984]
43. Which of the following statements about proteins is not true
(a) Enzymes (b) Antibodies
[MP PET 2001]
(c) Antigens (d) Hormones
(a) Amino acid residues join together to make a protein molecule
35. The protein that is a structural material is [KCET 1984]
(b) Proteins are polymers with formula (C6 H10 O5 )n
(a) Albumin (b) Oxytocin
(c) Haemoglobin (d) Keratin (c) Eggs are rich in protein
36. For   amino acids having the structure (d) Pulses are good source of proteins
44. Enzymes [AIIMS 1996]
R  CH  CO 2 H
| (a) Accelerate biochemical reactions
NH 2 (b) Have optimum activity at body temperature
Which of the following statements are true (c) Consist of amino acids
(A) Water solubility is maximum at a pH when concentrations of (d) Have all these properties
anions and cations are equal 45. The functional group which is found in amino acid is
(B) They give ninhydrin test [AFMC 1998; AIEEE 2002]
(C) On reacting with nitrous acid give off N 2 (a) COOH group (b)  NH 2 group
[MP PET 1994]
(c) CH 3 group (d) Both (a) and (b)
(a) All (b) B and C
(c) A and B (d) A 46. Amino acids are produced on hydrolysis of [AIIMS 1996]

37. Which of the following reacts with haemoglobin in the blood to (a) Nucleic acid (b) Carbohydrates
form carboxyhaemoglobin [Manipal MEE 1995] (c) Fats (d) Proteins
(a) CO (b) CO 2 47. Enzymes belong to which class of compounds
[KCET 1996]
(c) HCOOH (d) H 2CO 3 (a) Polysaccharides
38. Secondary structure of a protein refers to [CBSE PMT 1995] (b) Polypeptides
(a) Mainly denatured proteins and structures of prosthetic groups (c) Polynitrogen heterocyclic compounds
(b) Three dimensional structure, specially the bond between amino (d) Hydrocarbons
acid residues that are distant from each other in the 48. By the action of enzymes, the rate of biochemical reaction
polypeptide chain [CBSE PMT 1994]
(c) Linear sequence of amino acid residues in the polypeptide (a) Decreases (b) Increases
chain
(c) Does not change (d) Either (a) or (c)
(d) Regular folding patterns of continuous portions of the
49. Metal present in blood is [CPMT 1997]
polypeptide chain
(a) Al (b) Mg
39. Of the following statements about enzymes which ones are true
(c) Cu (d) Fe
(i) Enzymes lack in nucleophilic groups
(ii) Enzymes are highly specific both in binding chiral substrates 50. Which compound can exist in a dipolar (zwitter ion) state
and in catalyzing their reactions [Pb. PMT 1998]
(iii) Enzymes catalyse chemical reactions by lowering the activation (a) C6 H5 CH 2CH (N  CH 2 )COOH
energy
(b) (CH 3 )2 CH .CH (NH 2 )COOH
(iv) Pepsin is a proteolytic enzyme [CBSE PMT 1995]
(a) (i) and (iv) (b) (i) and (iii) (c) C6 H5 CONHCH 2COOH
(c) (ii), (iii) and (iv) (d) (i) (d) [Link] 2CH 2COCOOH
40. Proteins are composed of [MP PMT 1995; J & K 2005]
51. What is the monomer of polypeptide
(a)   amino acids (b) Carbohydrates
[KCET 1998; JIPMER 1999; Pb. CET 2002]
(c) Vitamins (d) Mineral salts
(a) Amino acid (b) Glucose
41. Read the following statements carefully
(c) Nucleoside (d) Nucleotide
(A) Albumin is a simple protein
52. Which of the following enzymes is not useful in the digestion of
(B) The amino acid alanine contains an acidic side chain
proteins [KCET 1998]
(C) Insulin is a hormone
(a) Chymotrypsin (b) Pepsin [Pb. PMT 2000]
(c) Trypsin (d) Lipase (a) Catabolism (b) Anabolism
53. Haemoglobin is [CBSE PMT 1997; BHU 2004] (c) Fermentation (d) Metabolism
(a) An enzyme (b) A globular protein 66. A biological catalyst is essentially
(c) A vitamin (d) A carbohydrate [Pb. PMT 2000; BHU 2004]
(a) A carbohydrates (b) An amino acids
54. Albumin proteins are most abundant in [BHU 1998]
(c) A nitrogen molecule (d) Fats
(a) Meat (b) Milk
67. The test used for identifying peptide linkage in proteins is
(c) Egg (d) Soyabean
[KCET (Engg.) 2001]
55. Dialysis can separate [BHU 1998]
(a) Borsche's test (b) Molisch's test
(a) Glucose and fructose (c) Ninhydrin test (d) Biuret test
(b) Glucose and sucrose 68. Which of the following is not a function of proteins
(c) Glucose and NaCl [MP PMT 2001]
(d) Glucose and proteins (a) Nails formation
56. Which one of the following is an example of a globular protein [Orissa
(b) Skin JEE 1997]
formation
(a) Keratin (b) Insulin (c) Muscle formation
(c) Collagen (d) Myoglobin (d) Providing energy for metabolism
57. Leucine amino acids is the [Pb. PMT 1999] 69. The helical structure of proteins is stabilized by
(a) Essential (b) Non-essential [MP PMT 2001]
(c) Aromatic (d) Basic (a) Peptide bonds (b) Dipeptide bond
58. Which of the following tests is not used for testing proteins (c) Hydrogen bond (d) Vander Waal's forces
[Kerala PMT 1999; KCET 1999] 70. The optically inactive amino acid is
(a) Millon's test (b) Molisch's test [MP PMT 2001; BHU 2005]

(c) Biuret test (d) Ninhydrin test (a) Lysine (b) Glycine
59. Amino acids usually exist in the form of Zwitter ions. This means (c) Arginine (d) Alanine
that it consists of [KCET 2000] 71. Which  amino acid can cross link peptide chains
(a) The basic group – NH 2 and the acidic group COOH [AIIMS 2001]
(a) Serine (b) Cysteine
(b) The basic group  NH 3 and the acidic group CO 2 (c) Glutamine (d) Tyrosine
(c) The basic group  CO 2 and the acidic group NH 3 72. Amino acids are the building blocks of [MH CET 2001]
(a) Fat (b) Vitamin
(d) No acidic or basic group
(c) Protein (d) Carbohydrate
60. The most important energy carrier in all the living cells is
73. Which of the following protein destroys the antigen when it enters
[MP PET 2000; KCET 2000]
in body cell [AIIMS 2001; Pb. PMT 2004 ]
(a) AMP (b) ATP
(a) Antibodies (b) Insulin
(c) ADP (d) UDP
(c) Chromoprotein (d) Phosphoprotein
61. The 10% energy transfer law of food chain was given by
74. An antibiotic with a broad spectrum [AFMC 2001]
[BHU 2000]
(a) Kills the antibodies
(a) Stanley (b) Weismann
(b) Acts on a specific antigen
(c) Lindemann (d) Tansley
(c) Acts on different antigents
62. Which of the following is a conjugated protein [BHU 2000]
(d) Acts on both the antigens and antibodies
(a) Glycoprotein (b) Phosphoprotein
75. Antibodies are [CBSE PMT 2001]
(c) Chromoprotein (d) All of these
(a) Carbohydrate (b) Globular protein
63. The number of essential amino acids in man is
(c) Immunoglobulins (d) Cellulose compounds
[CBSE PMT 2000]
(a) 8 (b) 10 76. Excess of Na  ions in our system causes [BHU 2001]
(c) 18 (d) 20 (a) High B.P. (b) Low B.P.
64. Pick out wrong combination [DCE 2000] (c) Diabetes (d) Anaemia
2
77. The example of a protein is [MP PET 2003]
(a) Fe  Haemoglobin
(a) Narvone (b) Lacithin
(b) Mg 2   Photosynthesis (c) Cellulose (d) Insulin
78. Enzymes are made up of [CBSE PMT 2002]
(c) Se 2   Kreb Cycle
(a) Carbohydrates
(d) CO 2  Vitamin B-12 (b) Edible proteins
65. The decomposition of complex organic compounds into simpler (c) Nitrogen containing carbohydrates
compound with the help of enzyme is known as (d) Proteins with specific structure
79. Chlorophyll contains [RPMT 2002] NH 2
(a) Fe (b) Na |
(a) CH 3  CH .C OOH
(c) Mg (d) Zn
80. Which one of the following biomolecules is insoluble in water [AIIMS 2005] CH 3 NH 2
|
(a) - Keratin (b) Haemoglobin (b) CH  CH .COOH
(c) Ribonuclease (d) Adenine CH 3
81. A nanopeptide contains …….. peptide linkages [KCET 2005]
CH 3 NH 2
(a) 10 (b) 8 |
(c) 9 (d) 18 (c) CH  CH .COOH
82. Identify the incorrect statement [Kerala (Med.) 2003] C2 H 5
(a) An octa deca peptide contains 18 amino acid residues and 17
C2 H 5 NH 2
peptide bonds |
(b) Addition of an inert gas into a system in thermodynamic (d) CH  CH .COOH
equilibrium for the dissociation of PCl5 shifts the equilibrium C2 H 5
to the left. 91. The process by which synthesis of protein takes place based on the
(c) When gold dissolves in aquaregia the complex formed is genetic information present in m-RNA is called
chloroauric acid [KCET 2003; Kerala CET 2005]
(d) In the extraction of aluminium purified bauxite is dissolved in (a) Translation (b) Transcription
molten fluorospar
(c) Replication (d) Messenger hypothesis
(e) If the pH value of a solution is to be decreased from 5 to 3, the
hydrogen ion concentration must be increased twice the initial 92. Which of the following is used in our body as a fuel for muscles and
value. nerves and to build and repair body tissues?
[DCE 2003]
83. -helix is found in [Kerala (Engg.) 2002]
(a) DNA (b) RNA (a) Cane sugar (b) Fructose
(c) Lipid (d) Protein (c) Proteins (d) Glucose
84. The main structural of protein is [UPSEAT 2000, 02] 93. Which enzyme convert glucose into alcohol
(a) The ester linkage (b) The ether linkage [Pb. CET 2003]

(c) The peptide linkage (d) All of these (a) Invertase (b) Zymase
85. Among the following, the achiral amino acid is (c) Maltase (d) Diastase
[AIIMS 2003] 94. Which one of the following structures represents the peptide chain [CBSE PMT
MP PET 1994; Bihar MEE 1997; Orissa JEE 1997]
(a) 2-Ethylalanine
(b) 2-Methylglycine H H H O
| | | | | | ||
(c) 2-Hydroxymethyl serine (a)  N  C C N  C C N  C C
| || | || |
(d) Tryptophan O O
86. Which of the following could act as a propellant or rockets
H O H
[CBSE PMT 2003] | | | || | | | | |

(a) Liquid hydrogen + liquid nitrogen (b)  N  C  C  C  N  C  C  N  C  C  C 


| | | | | || | |
(b) Liquid oxygen + liquid argon H O
(c) Liquid hydrogen + liquid oxygen H O
| | ||
(d) Liquid nitrogen +liquid oxygen (c)  N  C  N  C  NH  C  NH 
|| | |
87. Which amino acid has aromatic ring [CPMT 2003]
O H
(a) Alamine (b) Glycine
(c) Tyrosine (d) Lysine H H
| | | | | | | |
88. The pH value of the solution in which a particular amino acid does (d)  N  C  C  C  C  N  C  C  C 
|| | | | | | |
not migrate under the influence of an electric field in called the[Kerala (Med.) 2003] O
(a) Eutectic point (b) Yielding point
95. The correct statement in respect of protein haemoglobin is that it
(c) Neutralisation point (d) Effusion
(a) Acts as an oxygen carrier in the blood
(e) Isoelectric point
(b) Forms antibodies and offers resistance to diseases
89. Which part of the protein molecule is responsible for function and
(c) Functions as a catalyst for biological reactions
activity of the proteins [AMU 2002]
(d) Maintains blood sugar level
(a) Secondary structure (b) Peptide bond
96. Identify the correct statement regarding enzymes
(c) Primary structure (d) Binding sites
[AIEEE 2004]
90. The Structural formula of an amino acid, isoleucine is
[MP PMT 2003]
(a) Enzymes are specific biological catalysts that cannot be 9. Which of the following indicates the number of free OH groups
poisoned in an oil or fat
(b) Enzymes are normally heterogeneous catalysts that are very (a) Iodine value
specific in their action (b) Acid value
(c) Enzymes are specific biological catalysts that can normally (c) Acetyl value
function at very high temperature (T ~ 1000K) (d) Saponification value
(d) Enzymes are specific biological catalysts that possess well- 10. Which of the following is not glyceride
defined active sites
(a) Lipids (simple) (b) Phospholipids
97. A biological catalyst is essentially [BHU 2004] (c) Sphingolipids (d) All
(a) An enzyme 11. The most important food reserves of animals and plants are
(b) A carbohydrate [MP PET 1993]
(c) An amino acid (a) Carbohydrates (b) Proteins
(d) A nitrogen compound (c) Vitamins (d) Fats
98. Which synthesis was done by Stainley Millar [CPMT 1979] 12. Which of the following gives maximum energy in metabolic
processes [CPMT 1991; MP PET 1999]
(a) Amino acid (b) Protein
(a) Proteins (b) Carbohydrates
(c) Virus (d) Vitamin
(c) Lipids (d) Vitamins
99. The bond that determines the secondary structure of proteins is or
secondary structure of protein is due to 13. The energy change produced by the combustion of food is called the
[NCERT 1984; MP PET 1996; MP PMT 1997]
'calorific value'. The highest calorific value is given by[NCERT 1984; AFMC 1988]
(a) Coordinate bond (a) Proteins (b) Fats
(b) Covalent bond (c) Carbohydrates (d) Vitamins
(c) Hydrogen bond 14. Cell membrane contains
(d) Peptide bond (a) Alternate layers of phospholipid and coline
(b) Double layers of phospholipid
Fats and Lipids (c) Double layers of phospholipid with polar ends projected
outside
1. Tripalmitin is (d) Double layers of phospholipid with polar ends projected inside
(a) A protein (b) An enzyme 15. Which of the following compounds do not belong to lipids
(c) A lipid (d) A carbohydrate [AFMC 1998]
2. On hydrolysis, all lipids yield (a) Fats (b) Amino acids
(a) Monocarboxylic acids (b) Monohydric alcohols (c) Phospholipids (d) Carbohydrates
(c) Monohaloalkanes (d) Enzymes 16. Which is not a macromolecule [BHU 1998]
3. Which of the following is not a lipid (a) DNA (b) Starch
(a) Oils (b) Fats (c) Palmitate (d) Insulin
(c) Waxes (d) Proteins 17. A distinctive and characteristic functional group of fats is
4. The 'acid value' of an oil or fat is measured in terms of weight of [Kerala (Med.) 1999; AFMC 2005]
(a) An ester group
(a) NH 4 OH (b) NaOH
(b) A peptide group
(c) KOH (d) CH 3 COOH (c) A ketonic group
5. The ‘saponification value’ of an oil or fat is measured in terms of (d) An alcoholic group
(a) NH 4 OH (b) NaOH 18. The waxes are long chain compounds of fatty acids, which belong to
the class of [BHU 1999; AFMC 2005]
(c) KOH (d) C6 H 5 OH (a) Esters (b) Ethers
6. The ‘iodine value’ of an oil indicates (c) Alcohols (d) Acetic acid
(a) Its boiling point 19. Hydrolytic reaction of fats, with caustic soda, is known as
(b) Inflammability [Kerala (Med.) 2000; Pb. PMT 2004; MNR 1988]
(c) Unsaturation present in acid contents (a) Acetylation (b) Carboxylation
(d) Solubility of salt in oils (c) Saponification (d) Esterification
7. Hardening of oils is caused by 20. Fat consists of [MH CET 2002]
(a) H2 (b) N2 (a) Monohydroxy carboxylic acid
(b) Monohydroxy aliphatic carboxylic acid
(c) O2 (d) CO 2
(c) Monohydroxy aliphatic, saturated carboxylic acid
8. Which of the following is obtained when an oil is hydrolysed with (d) Dihydroxy aliphatic carboxylic acid
alkali 21. The alcohol obtained by the hydrolysis of oils and fats is
(a) Fat (b) Wax [KCET 2001]
(c) Soap (d) Vitamin (a) Glycol (b) Glycerol
(c) Propanol (d) Pentanol [MP PET 1996]
22. Iodine value is related to [MP PET 2002] (a) Ribose (b) Phosphate
(a) Fats and oils (b) Alcohols (c) Adenine (d) Pyridine
(c) Esters (d) Hydrocarbons 10. Which one is found in ATP ribonucleotide
23. Phospholipids are esters of glycerol with [CBSE PMT 2003] (a) Guanine (b) Uracil
(c) Adenine (d) None of these
(a) Three phosphate groups
11. Which of the following proteins acts as a messenger in living system
(b) Three carboxylic acid residues
(a) Harmone (b) Enzyme
(c) Two carboxylic acid residues and one phosphate group
(c) Protective protein (d) Transport protein
(d) One carboxylic acid residue and two phosphate groups
12. Which substance is not present in nucleic acid
24. Oils and fats are jointly called [MP PET 2003]
[MP PET/PMT 1998]
(a) Lipids (b) Soaps (a) Cytosine (b) Adenine
(c) Proteins (d) Polymer (c) Thymine (d) Guanidine
CH 2 OOCR CH 2 OH RCOOH 13. The deficiency of vitamin B1 causes
| | 
25. CHOOCR "  CHOH  RCOOH
Enzyme
[CPMT 1994; MP PMT 1999; BHU 2000]
| Hydrolysis | 
(a) Beri-beri (b) Scurvy
CH 2 OOCR CH 2 OH RCOOH
(c) Rickets (d) Anaemia
The enzyme used in the above reaction is [AMU 2003] 14. Which of the following is not present in nucleic acids
(a) Amylase (b) Lactase [MP PMT 1999]
(c) Lipase (d) Invertase (a) Uracil (b) 2-aminopyridine
26. Oleic, stearic and palmitic acids are [Pb. CET 2002] (c) Thymine (d) Adenine
(a) Fatty acid (b) Amino acid 15. In nucleic acids, the sequence is [AIIMS 1996]
(c) Nucleic acid (d) Essential acid (a) Base-phosphate-sugar (b) Phosphate-base-sugar
27. An example for a saturated fatty acid, present in nature is (c) Sugar-base-phosphate (d) Base-sugar-phosphate
[KCET 2005] 16. The segment of DNA which acts as the instructional manual for the
(a) Oleic acid (b) linoleic acid synthesis of the protein is [Pb. PMT 1998]
(c) Linolenic acid (d) Palmitic acid (a) Nucleoside (b) Nucleotide
(c) Ribose (d) Gene
Vitamin, Harmone and Nucleic acid 17. The double helical structure of DNA was proposed by
[KCET 1998]
1. A nucleotide consists of (a) Watson and Crick (b) Meicher
(a) Base and sugar (b) Base and phosphate (c) Emil Fischer (d) Khorana
18. A segment of DNA molecule which codes or specifies for one
(c) Sugar and phosphate (d) Base, sugar and phosphate polypeptide chain is called [KCET 1998]
2. Which of the following is responsible for heredity character (a) Phosphate group (b) Adenine
(a) DNA (b) RNA (c) Gene (d) Amino acid
(c) Proteins (d) Hormones 19. In DNA, the complementary bases are [CBSE PMT 1998]
3. The base adenine occurs in [MP PMT 1995] (a) Uracil and adenine; cytosine and guanine
(b) Adenine and thymine; guanine and cytosine
(a) DNA only (b) RNA only
(c) Adenine and thymine; guanine and uracil
(c) DNA and RNA both (d) Protein (d) Adenine and guanine; thymine and cytosine
4. The protein which maintains blood sugar level in the human body[KCET 1993;
20. MP PMT
The 1995]
structure of DNA is [AFMC 1999]
(a) Haemoglobin (b) Oxytocin (a) Linear (b) Single helix
(c) Insulin (d) Ptyalin (c) Double helix (d) Triple helix
5. Which of the following statements about the assembly of nucleotides
21. Vitamin B1 is [MP PMT 2000]
in a molecule of deoxyribose nucleic acid (DNA) is correct [Manipal MEE 1995]
(a) A pentose of one unit connects to a pentose of another (a) Riboflavin (b) Cobalamin
(b) A pentose of one unit connects to the base of another (c) Thiamine (d) Pyridoxine
(c) A phosphate of one unit connects to a pentose of another 22. A gene is a segment of a molecule of [AIIMS 1999]
(d) A phosphate of one unit connects to the base of another (a) DNA (b) m -RNA
6. Vitamin A is present in [MP PET 1995, 2000] (c) t-RNA (d) Protein
(a) Cod liver oil (b) Carrot 23. The deficiency of vitamin-C causes
(c) Milk (d) In all of these [MP PMT 2000; CPMT 2000]
7. Ascorbic acid is a [Bihar CEE 1995; MP PET 1995]
(a) Scurvy (b) Rickets
(a) Vitamin (b) Enzyme (c) Pyrrohea (d) Pernicious Anaemia
24. DNA contains the sugar [MP PMT 2000]
(c) Protein (d) Carbohydrate
(a) Deoxyribose (b) Ribose
8. The chemical name of vitamin C is [J & K 2005]
(c) D-Fructose (d) D-glucose
(a) Ascorbic acid (b) Folic acid
25. Which of the following is not a sex hormone
(c) Nicotinic acid (d) Tartaric acid [MP PMT 2000]
9. Which of the following is not a constituent of RNA
(a) Testosterone (b) Estrone 39. The harmone that helps in the conversion of glucose to glycogen in
(c) Estradiol (d) Cortisone (a) Adrenaline (b) Insulin
26. Acquired immune deficiency syndroms (AIDS) is characterised [AIIMS 2000]
(c) Cortisone (d) Bile acids
(a) Killer T-cells 40. Insulin production and its action in human body are responsible for
(b) Reduction in number of helper T-cells the level of diabetes. This compound belongs to which of the
(c) An autoimmune disease following categories [AIEEE 2004]
(d) Inability of body to produce interferons (a) An enzyme (b) A harmone
27. The base present in DNA, but not in RNA is (c) A co-enzyme (d) An antibiotic
[KCET (Engg.) 2001; NCERT 1978; Manipal MEE 1985; MP PMT 1994, MP
PET 1995; DCE 2004] 41. Codon is present in [Pb. PMT 2004]
(a) Guanine (b) Adenine (a) t-RNA (b) m-RNA
(c) Uracil (d) Thymine (c) r-RNA (c) All of these
28. Mutation of DNA occurs due to changes in the sequence of one of 42. Energy is stored in our body in the form of
the following [MP PMT 2001] [CBSE PMT 2001; KCET 2003]
(a) Bases (b) Ribose units (a) ATP (b) ADP
(c) Phosphate units (d) Sugar units (c) Fats (d) Carbohydrates
29. Which of the following is not true about vitamins 43. Nucleic acid is a polymer of [MP PMT 2004]
[AFMC 2001] (a) Nucleosides (b)   amino acids
(a) They are vital for life (c) Nucleotides (d) Glucose
(b) They help in digestion 44. A nucleoside on hydrolysis gives [KCET 2004]
(c) They were named by “Funic” (a) A heterocyclic base and orthophosphoric acid
(d) Their deficiency causes diseases (b) An aldopentose, a heterocyclic base and orthophosphoric acid
30. Blood calcium level can be increased by the administration of (c) An[AFMC 2001] and a heterocyclic base
aldopentose
(a) Glucogon (b) Calcitonin (d) An aldopentose and orthophosphoric acid
(c) Thyroxine (d) Paratharmone 45. An alternation in the base sequence of nucleic acid molecule is called
31. The first harmone chemically synthesised in the laboratory is [Kerala PMT 2004]
[BHU 2002] (a) Replication (b) Mutation
(a) Cortisone (b) Insuline (c) Duplication (d) Dislocation
(c) Adrenaline (d) Estrone (e) Flocculation
32. Purine derivative among the following bases is 46. Vitamin B is known as
6
[DCE 2004]
[KCET (Med./Engg.) 2002; MPPET 2004] (a) Pyridoxin (b) Thiamine
(a) Guanine (b) Cytosine (c) Tocopherol (d) Riboflavin
(c) Thymine (d) Uracil
33. RNA is different from DNA because RNA contains
[AIEEE 2002, 04]
(a) Ribose sugar and thymine
(b) Ribose sugar and uracil
(c) Deoxyribose sugar and thymine
(d) Deoxyribose sugar and uracil 1. Number of chiral carbons in   D  () -glucose is
34. Deficiency of which vitamin causes rickets [MP PET 2002] [CBSE PMT 2004; MHCET 2004]
(a) Vitamin-D (b) Vitamin-B (a) Three (b) Four
(c) Vitamin-A (d) Vitamin-K (c) Five (d) Six
35. Which do the following vitamins has isoprene units in its structure 2. The nucleic acid2002]
[JIPMER base having two possible binding sites is
(a) Vitamin A (b) Vitamin C [AIIMS 2004]
(c) Vitamin B 2 (d) Vitamin D (a) Thymine (b) Cytosine
36. (c) Guanine
The reason for double helical structure of DNA is operation of [CBSE PMT 2003; DPMT 2004] (d) Adenine
(a) Vander Waal's forces 3. Subunits present in haemoglobin are [AIIMS 2003]
(b) Dipole-dipole interaction (a) 2 (b) 3
(c) Hydrogen bonding (c) 4 (d) 5
(d) Electrostatic attractions 4. A sequence of how many nucleotides in messenger RNA makes a
37. The tripeptide harmone present in most living cells is... codon for an amino acid [CBSE PMT 2004]
[KCET 2003] (a) One (b) Two
(a) Glutathione (b) Glutamine (c) Three (d) Four
(c) Oxytocin (d) Ptyalin 5. Chargaff's rule states that in an organism [CBSE PMT 2003]
38. The function of DNA in an organism is [DCE 2003] (a) Amounts of all bases are equal
(a) To assist in the synthesis of RNA molecule (b) Amount of adenine (A) is equal to that of thymine (T) and the
(b) To store information of heredity characteristics amount of guanine (G) is equal to that of cytosine (C)
(c) To assist in the synthesis of proteins and polypeptides (c) Amount of adenine (A) is equal to that of guanine (G) and the
(d) All of these amount of thymine (T) is equal to that of cytosine (C)
(d) Amount of adenine (A) is equal to that of cytosine (C) and the (a) Lysine (b) Arginine
amount of thymine (T) is equal to guanine (G) (c) Aspartic acid (d) Histidine
6. DNA multiplication is called [Kerala (Med.) 2000] 20. Proteins do not respond to
(a) Translation (b) Transduction (a) Biuret test (b) Heller's ring test
(c) Transcription (d) Replication (c) Ninhydrin test (d) Lucas test
7. Insulin is a protein which plays the role of [KCET 1986] 21. Alkyl benzene sulphonates can be conductivity used as detergents in
(a) An antibody (b) A harmone hard water, unlike soaps, as [AMU 2002]
(c) An enzyme (d) A transport agent (a) They are highly soluble in water
8. Proteins fulfil several functions in living systems. An example of a (b) Their Ca   / Mg   salts are water soluble
protein which acts as a hormone is [KCET 1985]
(c) They are non-ionic
(a) Casein (b) Oxytocin
(c) Trypsin (d) Keratin (d) Their Ca   / Mg   salts are insoluble in water
9. Pick out the unsaturated fatty acid from the following 22. When glucose reacts with bromine water, the main product is[Pb. CET 2003; BH
[KCET 2004; MHCET 2002] (a) Acetic acid (b) Saccharic acid
(a) Stearic acid (b) Lauric acid (c) Glyceraldyhyde (d) Gluconic acid
(c) Oleic acid (d) Palmitic acid 23. A zwitter ion is [KCET 1989]
(a) A positively charged ion without a metal atom in it
10. Vitamin B12 contains metal
(b) A negatively charged ion without metal atom in it
[Bihar MEE 1997; RPET 1999; Pb. PMT 1999; AFMC 2002; (c) An ion with positive and negative charges at different points on
CBSE PMT 2003; CPMT 2003; MP PMT 2003] it
(a) Ca (II) (b) Zn (II) (d) A heavy ion with a small charge on it
(c) Fe (II) (d) Co (III) 24. Ribose is an example of [KCET 1998]
11. The number of molecules of ATP produced in the lipid metabolism (a) Ketohexose (b) Aldopentose
of a molecule of palmitic acid is (c) Disaccharide (d) Aldohexose
[CBSE PMT 1998] 25. The two forms of D-glucopyranose obtained from the solution of D-
(a) 130 (b) 36 glucose are called [IIT JEE Screening 2005]
(c) 56 (d) 86 (a) Isomer (b) Anomer
12. Protein can be most easily removed from (c) Epimer (d) Enantiomer
[UPSEAT 2000, 02] 26. Sucrose molecule is made up of [KCET 2005]
(a) Alkanes (b) Alkenes (a) A gluco pyranose and a fructo pyranose
(c) Alkynes (d) Benzene (b) A gluco pyranose and a fructo furanose
13. The enzyme which hydrolyses triglycerides to fatty acids and (c) A gluco furanose and a fructo pyranose
glycerol is called [CBSE PMT 2004] (d) A gluco furanose and a fructo furanose
(a) Zymase (b) Pepsin
(c) Maltase (d) Lipase
14. The helical structure of protein is stabilized by
[CBSE PMT 2004]
(a) Ether bonds (b) Peptide bonds
(c) Dipeptide bonds (d) Hydrogen bonds
Read the assertion and reason carefully to mark the correct option out of
15. The cell membranes are mainly composed of the options given below :
[CBSE PMT 2005] (a) If both assertion and reason are true and the reason is the correct
(a) Carbohydrates (b) Proteins explanation of the assertion.
(c) Phospholipids (d) Fats (b) If both assertion and reason are true but reason is not the correct
16. A compound of mol. wt. 180 is acetylated to give a compound of explanation of the assertion.
mol. wt. 390. The number of amino groups in the initial compound (c) If assertion is true but reason is false.
is [KCET 1996] (d) If the assertion and reason both are false.
(a) 2 (b) 4 (e) If assertion is false but reason is true.
(c) 5 (d) 6
1. Assertion : Glycine is amphoteric in nature.
17. Starting with three different amino acid molecules, how many
Reason : Glycine contains both acid and basic groups. [AIIMS 1996]
different tripeptide molecules are formed
2. Assertion : Hydrolysis of sucrose is known as inversion of
[Kerala PMT 1999; KCET 1999]
cane sugar.
(a) 12 (b) 9 Reason : Sucrose is a disaccharide. [AIIMS 1997]
(c) 8 (d) 6 3. Assertion : Proteins on hydrolysis produce amino acids.
18. Which one of the following is a polysaccharide [NDA 1999] Reason : Amino acids contain  NH 2 and COOH
(a) Nylon (b) Amylose groups. [AIIMS 1998]
(c) Ribose (d) Polyethylene 4. Assertion : Sucrose undergo mutarotation.
19. Which of the following is not an acidic amino acid Reason : Sucrose is a disaccharide. [AIIMS 2000]
5. Assertion : DNA molecules and RNA molecules are found in Reason : The reaction involves an intermediate in which
the nucleus of a cell. hybridization of C 2 changes from sp3 to sp 2 .
Reason : On heating the enzyme do not lose their specific
activity. [AIIMS 2002]
6. Assertion : All Amino acids exist as Zwitter ions.
Reason : Amino acids have both  NH 2 and COOH
group. [AIIMS 2002]
7. Assertion : Activity of an enzyme is pH-dependent.
Reason : Change in pH affects the solubility of the enzyme
in water. [AIIMS 2003]
8. Assertion : Glycosides are hydrolyzed in acidic conditions. Carbohydrates
Reason : Glycosides are acetals. [AIIMS 2003]
9. Assertion : Haemoglobin is an oxygen carrier. 1 d 2 b 3 d 4 d 5 c
Reason : Oxygen binds as O 2 to Fe of haemoglobin.[AIIMS 2003] 6 c 7 c 8 d 9 b 10 d
10. Assertion : Carboxypeptidase is an exopeptidase. 11 c 12 d 13 c 14 c 15 c
Reason : It cleaves the N-terminal bond.
[AIIMS 2004] 16 a 17 a 18 b 19 b 20 d
11. Assertion : Sucrose is a non-reducing sugar. 21 a 22 a 23 b 24 d 25 a
Reason : It has glycosidic linkage. [AIIMS 2004]
12. Assertion : Sucrose is a disaccharide. 26 d 27 d 28 a 29 c 30 b
Reason : Sucrose is dextro rotatory. 31 c 32 a 33 d 34 d 35 c
13. Assertion : Fructose reduces Fehling’s solution and Tollen’s
36 cd 37 d 38 a 39 c 40 c
reagent.
Reason : Fructose does not contain any aldehyde group. 41 b 42 c 43 c 44 a 45 b
14. Assertion : The specific rotation of a freshly prepared 46 a 47 b 48 d 49 a 50 c
solution of   glucose decreases from + 112° to
52.7° while that of  glucose increase from + 51 a 52 c 53 c 54 a 55 c
19° to 52.7°. 56 b 57 d 58 c 59 a 60 c
Reason : The change in specific rotation of an optically 61 b 62 d 63 a 64 d 65 d
active compound with time to an equilibrium
value is called mutarotation. 66 d 67 d 68 c 69 b 70 c
15. Assertion :   amino acids exist as dipolar ions or zwitter 71 e 72 b 73 b 74 a 75 b
ions.
76 c 77 c 78 a 79 b 80 d
Reason :   amino acids are the building blocks of
proteins. 81 a 82 c 83 c 84 b 85 a
16. Assertion : Valine is an essential amino acid.
86 c 87 b 88 c 89 a 90 a
Reason : The lack of essential amino acids in the diet
causes Kwashiorkor. 91 a 92 c 93 a 94 c 95 c
17. Assertion : Sequence of bases in DNA is TGAACCCTT and 96 a 97 a 98 d 99 b 100 b
sequence of bases in m-RNA is CATTAAACC.
Reason : In DNA nitrogenous bases have hydrogen bonds. 101 c 102 a 103 a 104 a 105 b
18. Assertion : Millon’s test is a test to identify carbohydrates. 106 c 107 d 108 c 109 c 110 a
Reason : Millon’s reagent is solution of mercurous nitrate 111 c 112 c 113 b 114 a 115 b
and mercuric nitrate in nitric acid containing
little nitrous acid. 116 c 117 c 118 b 119 d 120 d
19. Assertion : ATP molecules are energy rich molecules. 121 c 122 c 123 c 124 a 125 a
Reason : ATP consists of a purine base adenine, pentose 126 b 127 b 128 b 129 a 130 d
sugar ribose and a string of three phosphate
groups. 131 b 132 b 133 a
20. Assertion : Solubilities of protein is minimum at the
isoelectric point.
Reason : At isoelectric point, protein molecule behaves as
a zwitter ion.
21. Assertion : Amino acids are soluble in benzene and ether.
Reason : Amino acids exist as zwitter ions.
22. Assertion : A solution of sucrose in water is dextrorotatory
but on hydrolysis in presence of little
hydrochloric acid, It becomes laevorotatory.
Reason : Sucrose on hydrolysis gives unequal amounts of
glucose and fructose as.
23. Assertion : Treatment of D-glucose with alkali affords an
equilibrium mixture consisting of D-mannose, D-
fructose and starting substance D-glucose.
Proteins, Amino Acids and Enzymes Critical Thinking Questions

1 b 2 c 3 a 4 a 5 c 1 b 2 c 3 c 4 c 5 b

6 b 7 c 8 d 9 c 10 c 6 d 7 b 8 b 9 c 10 d

11 c 12 b 13 a 14 b 15 c 11 a 12 d 13 d 14 d 15 b
16 a 17 d 18 b 19 c 20 d
16 a 17 d 18 c 19 d 20 d
21 d 22 d 23 c 24 b 25 b
21 c 22 b 23 c 24 b 25 a
26 b
26 a 27 d 28 a 29 a 30 d
31 c 32 a 33 b 34 c 35 d
Assertion and Reason
36 b 37 a 38 d 39 c 40 a
41 d 42 d 43 b 44 d 45 d 1 a 2 b 3 b 4 e 5 d

46 d 47 b 48 b 49 d 50 b 6 a 7 b 8 d 9 c 10 c
11 a 12 b 13 b 14 b 15 b
51 a 52 d 53 b 54 c 55 d
16 b 17 e 18 e 19 b 20 e
56 d 57 a 58 b 59 c 60 b
21 e 22 c 23 a
61 c 62 d 63 b 64 c 65 c
66 b 67 d 68 d 69 c 70 b

71 b 72 c 73 a 74 c 75 c
76 a 77 d 78 d 79 c 80 a

81 b 82 e 83 d 84 c 85 c
86 c 87 c 88 e 89 b 90 c
91 a 92 c 93 b 94 a 95 a
Carbohydrates
96 d 97 a 98 a 99 c
1. (d)   D  Glucose ⇌ Equilibrium mixture ⇌
[ ]  112
o
[ ]D  52 o
Fats and Lipids (36 %) (0 .02 %)

  D  Glucose
1 c 2 a 3 d 4 c 5 c [ ]D  19 o
(64 %)
6 c 7 a 8 c 9 b 10 c
Glucose has two forms  and . When either of these two is
11 d 12 c 13 d 14 c 15 bd dissolved in water and allowed to stand, it gets converted to an
16 c 17 a 18 a 19 c 20 c equilibrium mixture of  and  forms.
2. (b) Gun-cotton is a nitrocellulose or cellulose trinitrate which is
21 b 22 a 23 d 24 a 25 c used in explosive and as a binder for solid rocket propellant.
26 a 27 d 3. (d) Arabinose is an aldopentose HOCH 2  (CHOH )3  CHO
4. (d) In proteins amide group is present
Vitamins, Hormone and Nucleic Acid ( NH  C H  C  NH  C H  C )n
| || | ||
R R
O  O
1 d 2 a 3 c 4 c 5 c Amino or
peptide bond
6 d 7 a 8 a 9 d 10 c 5. (c) Inulin is a carbohydrate which is stored in “Roots of Dahliya”.
11 a 12 d 13 a 14 b 15 d
6. (c) Carbohydrates are hydrates of carbon. Their general formula is
C x (H 2 O)y .
16 b 17 a 18 c 19 b 20 c
8. (d) Glucose + Tollen’s reagent 
21 c 22 a 23 a 24 a 25 d Gluconic acid + Ag-mirror.
26 b 27 d 28 a 29 b 30 d
9. (b) Protein gives blue-violet colour with ninhydrin
(2, 2-dihydroxyindane-1, 3-diene)
31 b 32 a 33 b 34 a 35 a Carbohydrates gives brown red ppt. with benedict’s solution
36 c 37 a 38 d 39 b 40 b
(Alk. CuSO 4  Citrate ions)
11. (c) A ring structure
41 b 42 a 43 c 44 c 45 b
46 a H OCH 3

Oo

CH 2  OH
Glucose
CH O
H  C  OH OH H
|
H OH
86. (c) C
H  C  OH C C |
| |
|
HO  C  H  CH 3 OH  (CHOH )3 HCl
O
(CHOH )3
| |
(CHOH )3 |
|
H  C  OH CH CH O
| | CH O |
H C CH 2 OH |
CH 2 OH
|
CH 2 OH   D  glucose
 - Methyl glucoside   D  glucose
O
C H CH OH
2

| 90. (a) OH H 5 atoms in the ring


(CHOH )3 O
 |  H 2O
CH CH OH
2
H
| H OH
CH 2 OH D-fructose
  Methyl glucoside
93. (a) In sucrose the two monosaccharide units joined by -1, 2
39. (c) Glucose + Benedict's solution  Red colour (Cu 2 O) . glycoside bond. Since sucrose does not have hemiacetal carbon.
Therefore it is non- reducing sugar.
40. (c) Sucrose   Oxalic acid.
[Link] 3

41. (b) Amylopectin is not soluble in water. 94. (c) Starch   Maltose .
Amylase

43. (c) C12 H 22 O11 96. (a) Glucose is the simplest carbohydrate i.e. mono saccharide rest
Maltose
are polysaccharide.
47. (b) Sucrose is not a reducing sugar.
CHO CH  N  NHC 6 H 5 97. (a) We can’t digest cellulose which is a polysaccharide.
| | 98. (d) Diastase enzyme converts starch into maltose.
CHOH CHOH
56. (b) | 
NH 2 NHC 6 H 5 | 99. (b) Lactose is present in milk (Glucose + Galactose).
(CHOH )3 Warm (CHOH )3
| |
100. (b) Carbohydrates are rich source of energy.
CH 2 OH CH 2 OH 102. (a) Sucrose is a non reducing sugar it does not give any test with
Glucose phenylhyd razone
Benedict’s solution.
CH  N  NHC 6 H 5
| 103. (a) That is called glycosidic linkage.
CO

 |
NH 2 NHC 6 H 5 108. (c) Invert sugar is laevo rotatory.
(CHOH )3
|
111. (c) Starch is polymer of alpha glucose.
CH 2 OH 114. (a) Raffinose (C18 H 32 O16 ) is a trisaccharide
CH  N  NHC 6 H 5
| C18 H 32 O16  H 2 O  C 6 H 12 O 6  C 6 H 12 O 6  C 6 H 12 O 6
C  N  NHC 6 H 5 D glucose D fructose D mannose

 6  (CHOH )


NH NHC H |
2 5
 C6 H5 NH 2  NH 3 118. (b) Glucose + Fehling solution  Gluconic acid + Cu 2 O
3
| (Red ppt)
CH 2 OH
Glucosazon e 123. (c) Charring of sugar, when it is treated with sulphuric acid
(H 2 SO 4 ) is due to dehydration. In this reaction water is
57. (d) Starch  Maltose. Diastase
removed from the sugar.
58. (c) C12 H 22 O11  H 2 O  C 6 H 12 O6  C 6 H 12 O6
Cane sugar Glucose Fructose 124. (a) Glucose is a monosaccharide while others are polysaccharide.
61. (b) Monosaccharide cannot be hydrolysed to simple forms. So glucose is the simplest sugar.
64. (d) Starch + I 2  Blue colour. 125. (a) Glucose and mannose are epimers because they both differ in
66. (d) Glucose and sucrose are dextrorotatory Fructose is configuration at C–2 and the Isomer which differ at C 2
leavorotatory position known as epimers of each other.
68. (c) Food shift  O2  CO 2  H 2O 126. (b) C12 H 22 O11  H 2 O    C6 H12 O6  C6 H12 O6
(C and H ) Hydrolysis
Maltose Glucose Glucose
70. (c) In neutral solvent, glucose shows mutarotation.
127. (b) Pepsin, ptyalin and lipase are enzyme while cellulose is not the
73. (b) Maltose    glucose + glucose.
Hydrolysis
enzyme.
Maltase

79. (b) 3 carbons e.g. Glyceraldehyde CH 2  CH  CHO 128. (b) Sugar Relative sweetness
|
| Sucrose 100
OH OH
Glucose 74
83. (c) Starch   Maltose 
Diastage
 glucose.
Maltase
Lactose 16
85. (a) All are optically active.
Fructose 173
129. (a) C 6 H 12 O 6  6O 2  6CO 2  6 H 2 O  38 ATP H 2 N CH 2COOH
  and so on.
131. (b) Fructose has three chiral centres and hence 23 = 8 optical NH 2
isomers are possible. 41. (d) Muscles contain myoglobin CH 3  CH
COOH
132. (b) Freezing point is the temperature at which the liquid and the
solid form of the same substance are in equilibrium and hence alanine contain side chain of methyl group.
have the same vapour pressure. Due to lower vapour pressure 43. (b) It is the general formula for polysaccharides.
of the solution, solid form of a solution separates out at a
lower temperature. The decrease is called depression in 50. (b) (CH 3 )2 . CH . CH  COOH ⇌ (CH 3 )2  CH . CH  COO 
freezing point. | |

NH 2 NH 3 
When solid is the solute, it is solvent that freezes. Hence in the
given question water will be separated out first. 52. (d) Lipase is used in lipid metabolism.
133. (a) Glucose is a monosaccharide having chemical composition
Lipid  
 Fatty acid  Glycerol
Lipase
C 6 H 12 O6 .
53. (b) Haemoglobin is a globular protein.
59. (c) Zwitter ion is a dipolar ion containing both a positive and
Proteins, Amino Acids and Enzymes
NH 3
|
1. (b) Insulin is a protein consists of 51 amino acids in two chains.  negative charge in the following form R  CH  COO 
and  Zwitterion

 - 21 amino acids,  - 30 amino acids The basic group CO 2 and acidic group NH 3 .
It is secreted by pancreas for controlling the sugar level in
63. (b) The amino acids which can’t be synthesised by human body so
blood.
they are essential to take from diet. They are 10 in number.
3. (a) Fibrous proteins are insoluble in water.
66. (b) Biological catalysts are enzymes and all enzymes are nucleic
4. (a) Protein 
 Denatured protein
Heated acid.
or change in pH 68. (d) Protein is a body building substance not energy giving
substance.
5. (c) Simple protein  non - protein material 
(Prostheti c group or co- factor)
76. (a) Na  and K  controls blood pressure and heart beat so excess
Conjugated protein of Na  ion increases B.P.
2
6. (b) Heam  Fe to which the porphyrine ring is attached to 80. (a) This protein is found in hair, nail, muscle etc.
central atom by co-ordinate linkage. 81. (b) The peptide bond is formed between two amino acids by the
7. (c) It is insoluble in water and used in food products capsules and elimination of a water molecule. A dipeptide contains one
photographic plates. peptide linkage. A tripeptide contains two peptide linkages.
Similarly, a nanopeptide contains 8 peptide linkages.
9. (c) Amino acids are non volatile crystalline compound.
91. (a) Synthesis of polypeptide known as translation. For this process
10. (c) Isoelectric point is a pH at which zwitter ions do not migrate three type of RNA essential.
towards any of the electrode. 92. (c) Protein is used in our body as a fuel for muscles and nerves
11. (c) Protein 
Enzyme
Amino acid and to build and repair body tissues.
(Acidic medium in stomach) 93. (b) Zymase enzyme convert glucose into alcohol. It is found in the
yeast.
12. (b) Protein + conc. HNO 3  Yellow colour
C6 H12 O6   2C2 H 5 OH  2CO 2
zymase
[This test is given by a protein which consists of -amino acids glucose ethyl alcohol
containing a benzene ring such as tyrosine, phenylalanine etc.
The yellow colour is due to nitration of benzene ring.] 94. (a) In peptide linkage i.e., –CONH – group, the carboxyl group of
one amino acid molecules forms an amide by combination with
14. (b) Proteins are polymers of amino acids. the amino group of the next amino acid molecule with the
Amino acid  Dipeptide  Polypeptide  Protein. liberation of water molecule.
21. (c) Proteins are nitrogenous compounds. H O H R
2
H O
22. (b) In stomach medium is strongly acidic. Hence, pH  2 . N C C N C
30. (d) Glycine  NH 2  CH 2  COOH . C N C C
34. (c) Antigens are polysaccharides present on RBC's surface. H R C R
H O
3
1

37. (a) Hb  CO  HbCO 95. (a) Four Fe 2


ions of each haemoglobin can bind with 4
carboxy haemoglobin it is 20 times more stable then molecules of O 2 and it is carried as oxyhaemoglobin.
oxyhaemoglobin.
Hb4  4 O2  Hb4 O8
40. (a) Peptides are formed by condensation of  -amino acids.
96. (d) Enzyme are shape selective specific biological catalyst which
H 2 N  CH 2 COOH  H 2 N  CH 2  COOH normally functions effectively at body temperature.
 H 2O
  H 2 N  CH 2  CONH  CH 2 COOH 97. (a) An enzyme (protein) is a biological catalyst.
peptide bond 98. (a) Amino acid synthesis was done by stainley millar.
Fats and Lipids 39. (b) Insulin is a hormones secreted by the pancreas that lower
blood glucose level by promoting the uptake of glucose by cells
and the conversion of glucose to glycogen by the liver and
4. (c) Acid value is the number of 1 mg of KOH required to neutralise skeletal muscle.
1 gm of the fat or oil.
40. (b) Insulin is a proteinaceous harmone secreted by  cells by islet
5. (c) Saponification value is the number of mg of KOH required to of langerhans of pancreas in our body.
neutralize the fatty acid resulting from the complete hydrolysis 41. (b) Codon is present in m-RNA, which is responsible for
of 1gm. of oil or fat. translation.
6. (c) Iodine number is the number of gms of I2 which combine 42. (a) Energy is stored in our body in the form of A.T.P
with 100 gm of oil or fat. It shows the degree of unsaturation 43. (c) Nucleic acid is a polymer of nucleotides.
of acids in fat or oil. 44. (c) Nucleoside on hydrolysis gives an aldopentose and a
heterocyclic base purine and pyrimidine.
7. (a) Oil(unsaturated)  H 2 

Ni
Fat (saturated ) 45. (b) An alternation in the base sequence of nucleic acid molecule is
8. (c) Oil  NaOH (alkali)   Glycerol  Soap
Saponification called mutation which can be by radioactive ray, by adaptation
etc.
11. (d) Fats are called energy bank of the body. Stored below the
46. (a) Vitamin B6 is called pyridoxin. It is found in fruits, green-
dermis as subcutaneous fats.
vegetables, milk, etc. Due to its deficiency, anaemia disease is
12. (c)
caused.
13. (b) 1gm carbohydrate on oxidation gives 17 kJ of energy while 1 gm
fat provide 37 kJ of energy.
18. (a) Waxes are esters of higher fatty acids. Critical Thinking Questions
19. (c) Oil/fat + Alkali    Soap + Glycerol.
Saponifica tion
1. (b) HO C
CH 2 OOCR CH 2 OH C
| | |
21. (b) CHOOCR  H 2 O  CHOH  3 R  COOH *CHOH
| | Monocarbox ylicacid
|
CH 2 OOCR CH 2 OH *CHOH
Lipid or
Triglyceride
Glycerol or
Trihydric alcohol | O
*CHOH
26. (a) Oleic acid, stearic acid and palmitic acids are produced by the |
hydrolysis of fats and the acid produced by hydrolysis of fats *CH
are called fatty acid. |
This structure
CH 2OHof -D glucose has four asymmetric carbon
27. (d) Oleic acid - C17 H 33 COOH , linoleic acid- C17 H 31 COOH , atom
linolenic acid - C17 H 29 COOH , palmitic acid - 2. (c) It is Guanine having two possible binding site.
C15 H 31 COOH . 3. (c) Four sub units are present in haemoglobin.
Saturated monocarboxylic acids form a homologous series 4. (c) The four bases in m-RNA : adenine, cytosine, guanine and
Uracil have been shown to act in the form of triplet; each
which has a general formula Cn H 2n 1COOH or triplet behaving as a code for the synthesis of a particular
C n H 2n O 2 . Only palmitic acid follows this. amino acid.
5. (b) According to Chargaff’s rule amount of adenine(A) is equal to
that of thymin(T) and the amount of guanine(G) is equal to
Vitamin, Hormone and Nucleic acid that of cytosine(C).
6. (d) Multiplication of DNA is called replication.
1. (d) Nitrogenba
 seSugar
   Phosphate 7. (b) Insulin is a harmone which decreases sugar level in the blood.
Nucleoside
8. (b) Oxytocin hormone secreted by posterior pitutary gland plays an
3. (c) Adenine is a purine base common in both RNA and DNA. important role in child birth and milk ejection for feeding baby.
4. (c) Insulin hormone is secreted by pancreas.
9. (c) Except oleic acid stearic acid, Lauric acid and Palmitic acid are
HO H O O saturated fatty acid. Oleic acid is unsaturated fatty acid.
8. (a) HO 10. (d) CO (III) Transition metal is present in vitamin B12 .

HO OH 11. (a) 130 molecules of ATP produced in the lipid metabolism of a


Ascorbic acid (vitamin C)
molecule of palmitic acid.
19. (b) Adenine  Thymine , Guanine  Cytosine
2 hydrogen bonds 3 hydrogen bonds 12. (d) Protein is insoluble in benzene.
21. (c) Vitamin B1 is thiamine. Its main source is cereals. H OH
22. (a) Gene is a part of the DNA molecule that codes for a specific 13. (d) CH 2 O COR CH 2 OH
| |
protein. CHO COR   CHOH  R  COOH
Lipase

25. (d) Cortisone is not a sex harmone, it regulates metabolism of fats, | Hydrolysis |
Fatty acid
carbohydrates, proteins etc. CH 2 O COR CH 2 OH
27. (d) Thymine is present in DNA while in RNA there is Uracil. Glycerol
28. (a) Mutation is a chemical change in the sequence of Nitrogenous 14. (d) –helix structure is formed when the chain of –amino acid
bases along the DNA strained which can lead to the synthesis coil as a right handed screw because of the formation of
of protein with altered amino acid sequence.
hydrogen bonds between amide groups of the same peptide
chain i.e., NH group in one unit is linked to carbonyl oxygen of Therefore, both assertion and reason are true.
the third unit by hydrogen bonding. This H–bonding is 2. (b) Hydrolysis of sucrose is known as inversion of canesugar
responsible for holding helix in a position. because sucrose produce equimolecular mixture of glucose and
15. (b) Three types of chemicals enter the composition of all fructose. Sucrose is dextro-rotatory which glucose and fructose
membranes proteins, lipids and carbohydrates, proteins content mixture is laevorotatory. Sucrose is disaccharide.
varies from 46–76% lipids 20–53%, while Carbohydrate 3. (b) Proteins on hydrolysis gives –amino acid because amino acids
content is 1–8% are the building block of proteins. It is also fact that amino
16. (c) Difference in mass of compound acids contain both  NH 2 and COOH group.
= 390 – 180 = 210
Here assertion and reason both are correct but reason is not a
wt. of CH 3 CO – group is = 43 correct explanation of assertion.
4. (e) Sucrose does not undergo mutarotation. Glucose and fructose
210
Therefore no. of  NH 2 group =  4 .88  5 . shows mutarotation because they have two forms  and. It is
43 fact that sucrose is a disaccharide. Therefore, assertion is false
17. (d) Six type of tripeptide molecules are formed. but reason is true.
18. (b) Amylose is a polysaccharide. 5. (d) Here, both the reason and assertion are false, DNA occurs in
19. (c) Aspartic acid is an amino acid with acidic side chain. nucleus of the cell while RNA is found mainly in cytoplasm of
the cell. On heating, enzymes lose their specific activity.
NH 2
HOOC  CH 2  CH 6. (a) All amino acid posses amino as well as carboxylic group.
COOH
 NH 2 group is basic while COOH group is acidic.
Lysine, Arginine and Histidine all are basic amino acids.
Therefore, they behave as zwitter ion (dipolar ion). Here, both
20. (d) Lucas test is used for the distinction of alcohols. assertion and reason are true and reason is a correct
explanation.
21. (d) Because their Ca   / Mg   salts are insoluble in water.
7. (b) The assertion that activity of an enzyme is pH dependent is
22. (d) Glucose on reaction with bromine water followed by oxidation
gives gluconic acid correct. The reason that change in pH affects the solubility of
enzyme in water is also true but the reason is not the correct
C6 H12 O6  (O)    CH 2OH (CHOH )4 COOH
Br2 / H 2 O
explanation of assertion. Change in pH cause denaturation of
Glucose Gluconic acid enzyme.
23. (c) NH 3  CH 2  COO  8. (d) Glycosides are formed by treating glucose with methanol in
dipolar ion
(Zwitterion or internal salt)
presence of dry HCl gas. They cannot be hydrolysed in acidic
conditions. They are not acetals but they are hemiacetals.
24. (b) Ribose is an example of aldopentose.
9. (c) The assertion is correct that haemoglobin is an oxygen carrier
25. (b)
and the reason that oxygen binds as O 2 to Fe of haemoglobin
H 1C  OH HO  1 C  H
|
and
| is incorrect, because oxygen binds as O 2 to Fe of haeme
H  2 C OH H  2 C OH
| | part.
OH  3 C  H O OH  3 C  H O
| | 10. (c) Carboxypeptidase is an exopeptidase because it breaks the peptide
H  4 C OH H  4 C OH
| | chain at terminal ends.
H 5 C H 5 C
| | Carboxypeptidase cleaves carboxy-terminal amino acids that have
6 CH
2 OH
6 CH
2 OH aromatic or branched aliphatic side chains.
 - D(+) - Glucopyranose - D(+) - Glucopyranose
Two form of D–Glucopyranose are –D(+)–Glucopyranose and 11. (a) Sucrose is a non reducing sugar as it does not reduce Tollen's
–D(+)–Glucopyranose. These are anomers (a pair of or Fehling's reagent, due to absence of free aldehyde of ketone
stereoisomers which differ in configuration only around C1 group. It contains stable acetal or ketal structure which cannot
are called anomers). be opened into a free carboxyl group.

26. (b) Surcrose is composed of  -D-glucopyranose unit and a  – Sugar is composed of -D-glucopyranose unit and -D-fructo
D-fructofuranose unit. These units are joined by    - furanose unit. These units are joined by --glycosidic linkage
glycosidic linkage between C–1 of the glucose unit and C–2 of between C- 1 of the glucose unit and C- 2 of the fructose unit.
the fructose unit.
12. (b) Carbohydrates which upon hydrolysis yield two molecules of
the same or different monosaccharides are called disaccharides.
Assertion and Reason For example, sucrose on acid hydrolysis give one molecule of
glucose and fructose.
1. (a) Glycine is an amino acid, it contains both NH 2 as well as –
COOH groups and therefore, its aqueous solution form Zwitter 13. (b) Fructose on warming with dilute alkali, gives rise to an
ion which is amphoteric in nature. equilibrium mixture of glucose, fructose and mannose. The
ability of fructose to reduce Fehling solution and Tollen's
NH 2 CH 2 COOH NH 3 CH 2 COO  reagent is probably due to the isomerisation of fructose to
Glycine Zwitterion
glucose and mannose (this is called Lobry de Bruyn and
Elkenstein rearrangement).

14. (b) Glucose exists in two forms, i.e., -D-glucose with a specific
rotation of +112° and -D-glucose with a specific rotation of
+19°. However, when either of these two forms is dissolved in
water and allowed to stand. it gets converted into the same
equilibrium mixture of both the - and -forms with a small
amount of open chain form. As a result of this equilibrium, the
specific rotation of a freshly prepared solution of -glucose
decreases from +112° to 52.7° while that of  glucose increases
from +19° to 52.7°.

15. (b) In acidic medium COOH group acts as the base and
accepts a proton. As a result, -amino acids exist as cations in
acidic medium and migrate towards cathode under the

influence of an electric field. In alkaline medium N H 3 group
acts as the acid and thus loses a proton. As a result, -amino
acids exist as anion and migrate towards anode under the
influence of an electric field. However at some intermediate
value of pH, the concentration of cationic form and anionic
form will become equal and hence there is no net migration of
-amino acid under the influence of an electric field.
16. (b) Valine is an essential amino acid. The amino acids which the
body cannot synthesize are called essential amino acid.
17. (e) Sequence of bases in DNA is TGAACCCTT. Since according to
base-pairing principle, T in DNA faces A in m-RNA, while G
faces C and A faces U. Therefore, sequence of bases in m-RNA
is ACUUGGGAA.
18. (e) Millons test is a test for proteins. When Millon's reagent is
added to the aqueous solution of a protein, a white precipitate
is formed.
19. (b) ATP has four negatively charged oxygen atoms very close to
each other. So the repulsive forces between them is high. On
hydrolysis of ATP, a H 2 PO4 ion is eliminated and the
number of negatively charged oxygen atoms decreases. Thus,
repulsive forces decreases and a large amount of energy is set
free. When ATP changes to ADP, which in turn changes into
AMP, energy is released at each step. This is how ATP can act
as a source of energy.
20. (e) Solubility of protein is maximum at the isoelectric point.

21. (e) Amino acids are soluble in polar solvents like H 2 O , NaOH
and HCl and insoluble in non-polar solvents like benzene, ether
etc.
22. (c) Sucrose on hydrolysis gives equal amounts of glucose and
fructose. Since glucose has less positive and fructose has more
negative magnitude of rotation, therefore, change in the sign of
rotation is observed.
1. Which does not show mutarotation (a)  NH 2 ,COOH (b)  NH 2 ,SO 3 H
(a) Sucrose (b) Maltose (c) Both (d) None of these
(c) Glucose (d) Fructose 11. Which functional group participates in disulphide bond formation in
2. Artificial silk is proteins [CBSE PMT 2005]
(a) Polyamides (b) Polyesters (a) Thiolactone (b) Thiol
(c) Polyacids (d) Polysaccharides (c) Thioether (d) Thioester
3. Which of the following is a protein [Pb. CET 2003] 12. Schweitzer's reagent used for dissolving cellulose in the
manufacture of artificial silk is [Roorkee 1999]
(a) Pepsin (b) Adrenaline
(c) ATP (d) Glutamin (a) CuSO 4 . 5 H 2 O
4. Glucose gives many reactions of aldehyde, because (b) CuI
[CPMT 1977] (c) [Cu (NH 3 )4 ]SO 4
(a) It is hydrolysed to acetaldehyde
(d) Cu(CH 3 COO)2 . Cu(OH )2
(b) It is a polyhydroxy ketone
13. Which one of the following statements is true for protein synthesis
(c) It is a cyclic aldehyde
(translation) [AIIMS 2005]
(d) It is a hemiacetal in equilibrium with its aldehyde form in
(a) Amino acid are directly recognized by m-RNA
solution
(b) The third base of the codon is less specific
5. Glucose in blood can be quantitatively determined with
(c) Only one codon codes for an amino acid
[JIPMER 2002]
(d) Every t-RNA molecule has more than one amino acid
(a) Tollen's reagent
attachment site.
(b) Benedict's solution 14. In both DNA and RNA, heterocyclic base and phosphate ester
(c) Alkaline iodine solution linkages are at [AIEEE 2005]
(d) Bromine water (a) C5 and C 2 respectively of the sugar molecule
6. Which of the following ions can cause coagulation of proteins [Kerala (Med.) 1999]
(b) C 2 and C5 respectively of the sugar molecule
(a) Na  (b) Ag 
(c) C1 and C5 respectively of the sugar molecule
 
(c) Ca (d) Mg
(d) C5 and C1 respectively of the sugar molecule
7. Glucose reacts with methyl alcohol to give [CPMT 1985]
15. Which of the following biomolecules contain non-transition metal
(a)   methyl glucoside ion [KCET 2005]
(b)   methyl glucoside (a) Vitamin B12 (b) Chlorophyll
(c) Both (a) and (b) (c) Haemoglobin (d) Insulin
(d) None of these 16. An example of a sulphur containing amino acid is
8. Molisch's test is done for the detection of [BHU 1987] [KCET 2005]
(a) Alkyl halide (b) Carbohydrate (a) Lysine (b) Serine
(c) Alkaloid (d) Fat (c) Cysteine (d) Tyrosine
9. Which of the following is not an amino acid 17. Which of the following is not present in a nucleotide
[MP PET/PMT 1998] [KCET 2005]

(a) Glycine (b) Alanine (a) Cytosine (b) Guanine


(c) Histidine (d) Benzidine (c) Adenine (d) Tyrosine

10. A substance forms zwitter ion. It can have functional groups


[DCE 2002]

(SET -31)
1. (a) Sucrose does not show mutarotation due to non reducing
nature.
2. (d) It is a polysaccharide.
3. (a) Pepsin is a protein.
4. (d) It is a hemiacetal in equilibrium with its aldehyde form in
solution.
5. (a) In glucose aldehydic group is present and Tollen's reagent is
the test for aldehydes.
6. (b) Ag  can cause coagulation of proteins.
7. (c) Alpha methyl glucoside and beta methyl glucoside.
8. (b) Molisch’s test is done for the detection of carbohydrate bond
formation.
9. (d) Benzidine is not an amino acid. It is an amine.
10. (c) A substance forms Zwitter ion. It can have functional groups
 NH 2COOH and  NH 2 , SO 3 H .
11. (b) Thiol functional group particpitates in disulphide in proteins.
12. (c) Cu (NH 3 )4  SO 4 is schweitzer’s reagent used for
manufacture of artificial silk.
13. (a) In the process of translation amino acids are directly
recognized by m-RNA.

O
|| 5

14. (c) O  P  O  CH 2
Base
O
|
O 4 Sugar 1
Phosphate ester
linkag
3 2
15. (b) Biomolecule Metal ion
Vitamin B12 Co (transition metal)
Chlorophyll Mg (non-transition metal ion)

Haemoglobin Fe (transition metal)


Insulin S (non-Metal)
NH 2
16. (c) H 2 N (CH 2 )4 CH
Lysine COOH
NH 2 NH 2
HOCH 2 CH HSCH 2 CH
Serine COOH cysteine COOH
NH 2
|
HO CH 2 CHCOOH
tyrosine

17. (d) Nucleotide contains nitrogenous bases like adenine, guanine,


thymin, cytosine and uracil.

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