Carbohydrate Chemistry Quiz Questions
Carbohydrate Chemistry Quiz Questions
In the 'glycolipids', the two sugars known to occur are glucose and
(a) Fructose (b) Lactose
(c) Galactose (d) Sucrose
16. The ‘epimerisation’ involves
(a) Change of configuration
(b) Addition of one more 'C'
Carbohydrates (c) Substration of a 'C'
(d) Conversion of CHO to C O
1. The change in optical rotation, with time, of freshly prepared 17. The compound which does not contain an asymmetric carbon atom
solution of sugar is known as [CPMT 1982, 85; BHU 1997] is
(a) Rotatory motion (b) Inversion (a) Glycolaldehyde (b) Glyceraldehyde
(c) Specific rotation (d) Mutarotation (c) Glucose (d) Galactose
2. Gun-cotton is 18. Which of the following sign indicate that the sugar is actually
(a) Nitrosucrose (b) Nitrocellulose ‘dextrorotatory’
(c) Nitroglucose (d) Nitropicrin (a) – (b) +
3. Which of the following monosaccharide is a pentose (c) R – (d) All of these
[CPMT 1982, 87, 89, 93]
(a) Galactose (b) Glucose 19. The standard compound for determination of configuration in the
(c) Fructose (d) Arabinose ‘sugar chemistry’ is
4. Amide group is present in (a) Glycolaldehyde (b) Glyceraldehyde
(a) Lipids (b) Carbohydrates (c) Glucose (d) Fructose
(c) Amino acids (d) Proteins 20. Sugars are
5. Which of the following is a carbohydrate (a) Optically active polyhydroxy aldehydes
(a) Leucine (b) Albumin (b) Optically active polyhydroxy ketones
(c) Inulin (d) Maltase (c) Optically active polyhydroxy aldehydes or ketones
6. General formula for carbohydrates is (d) Polyhydroxy aldehydes or ketones which may or may not be
(a) Cn H 2nO2n 2 (b) C x (H 2O)2 x optically active
(c) C x (H 2O)y (d) None of these 21. Molecular formula of pentahydroxy acid obtained when glucose is
oxidised with Br2 water is
7. Benedict solution provides [CPMT 1983]
(a) C6 H12 O7 (b) C6 H12 O8
(a) Ag (b) Li
(c) Cu 2 (d) Ba2 (c) C6 H12 O6 (d) C6 H10 O6
8. Glucose gives silver mirror with Tollen's reagent. It shows the 22. The 'phosphoglycerides' occur in
presence of (a) The brain and the spinal chord
[MNR 1981; CPMT 1974, 81; MP PMT 1994]
(b) Nails and hairs
(a) An acidic group (b) An alcoholic group
(c) A ketonic group (d) An aldehydic group (c) Oils and fats
9. A certain compound gives negative test with ninhydrin and positive (d) Waxes
test with Benedict's solution. The compound is 23. Sucrose is a [CPMT 1983]
[NCERT 1978; KCET 2000] (a) Monosaccharide (b) Disaccharide
(a) A protein (b) A monosaccharide (c) Trisaccharide (d) Polysaccharide
(c) A lipid (d) An amino acid 24. The commonest disaccharide has the molecular formula
10. An organic compound answers Molisch's test as well as Benedict's
[CPMT 1982; Manipal MEE 1995;
test. But it does not answer Scliwanoff's test. Most probably, it is [KCET 2003]
MP PET 1999; AIIMS 1999]
(a) Sucrose (b) Protein
(c) Fructose (d) Maltose (a) C10 H18 O9 (b) C10 H 20 O10
11. Glucose when heated with CH 3 OH in presence of dry HCl gas (c) C18 H 22 O11 (d) C12 H 22 O11
gives and methyl glucosides because it contains 25. On complete hydrolysis of starch, we finally get
[CPMT 1982, 85] [MNR 1982; DPMT 1979; CBSE PMT 1991;
(a) An aldehyde group (b) A CH 2OH group MP PMT 1987; MP PET 1993]
(a) Glucose (b) Fructose
(c) A ring structure (d) Five hydroxyl groups
(c) Glucose and fructose (d) Sucrose
12. Which one is a disaccharide [CPMT 1981, 83]
(a) Glucose (b) Fructose 26. Which is monosaccharide
(c) Xylose (d) Sucrose (a) Glucose (b) Fructose
(c) Galactose (d) All of these
13. Molecular formula C6 H12 O6 is of
27. Which is polysaccharide
(a) Glucose (b) Fructose (a) Starch (b) Cellulose
(c) Both (a) and (b) (d) None of these (c) Glycogen (d) All of these
14. Hydrolysis of sucrose is called 28. The calorific values of fats, carbohydrates and proteins vary in the
[BHU 1979, 83; Pb. PMT 1999; Pb. CET 2000] order
(a) Esterification (b) Saponification (a) Fats > Carbohydrates > Proteins
(c) Inversion (d) Hydration (b) Fats > Proteins > Carbohydrates
(c) Carbohydrates > Proteins > Fats (b) It is an aldehyde sugar
(d) Proteins > Carbohydrates > Fats (c) It has six carbon atoms
29. Gun-cotton is obtained when conc. nitric acid reacts with (d) It exhibits optical activity
(a) Glycerine (b) Glycol 43. Maltose contains how many oxygen atoms
(c) Cellulose (d) Starch (a) 6 (b) 10
30. A carbohydrate consists of [NCERT 1971] (c) 11 (b) 22
(a) C and O (b) C, H and O 44. The correct name of ‘sucrose' is
(c) C, H , N and O (d) C and H (a) D glucopyranosyl D fructofura noside
31. Glucose forms many derivatives. The derivative which will help to (b) D glucopyranosyl D fructofura noside
prove the furanose structure is (c) D glucopyranosyl D fructofura noside
[AIIMS 1980; DPMT 1985]
(d) D glucopyranosyl L fructofura noside
(a) Acetyl (b) Benzoyl
(c) Osazone (d) Isopropylidene 45. Sucrose is
32. Glucose and fructose form [MP PMT 1986]
(a) Laevorotatory (b) Dextrorotatory
(c) Racemic mixture (d) Optically inactive
(a) Same osazone
46. The hydrolysis of sucrose produces a mixture which is
(b) Same acid on oxidation
(c) Same alcohol when reduced (a) Laevorotatory
(d) Different osazone (b) Dextrorotatory
(c) Equally both (+) and (–) rotatory
33. On heating with conc. H 2 SO 4 , sucrose gives [DPMT 1984]
(d) Optically inactive
(a) CO and CO 2 (b) CO and SO 2 47. Sucrose is
(c) CO , CO 2 and SO 2 (d) None of these (a) A reducing sugar
34. The letter ‘D’ in carbohydrates represents (b) Not a reducing sugar
(a) Its direct synthesis (b) Its dextrorotation (c) Partial reducing sugar
(c) Its mutarotation (d) Its configuration (d) Mixed sugar
35. Starch can be used as an indicator for the detection of traces of 48. Sucrose[CPMT
contains which of the following groups
1986]
(a) Glucose in aqueous solution (a) CHO (b) C O
(b) Protein in blood (c) Both (a) and (b) (d) None of these
(c) Iodine in aqueous solution 49. The fructose molecule in sucrose exists as
(d) Urea in blood (a) Furanose (b) Pyranose
36. It is best to carry out reactions with sugars in neutral or acid
(c) Open chain (d) All
medium and not in alkaline medium. This is because in alkaline
medium sugars undergo one of the following changes 50. Which one of the following
[AIIMS 1982] is laevorotatory [DPMT 1989]
(a) Racemisation (b) Decomposition (a) Glucose (b) Sucrose
(c) Inversion (d) Rearrangement (c) Fructose (d) None of these
37. Which one of the following compounds is found abundantly in 51. Chemically 'digestion' is [NCERT 1978]
nature [BHU 1983; Manipal MEE 1995; DCE 2004]
(a) Hydrolysis (b) Change in bacteria
(a) Fructose (b) Starch
(c) Glucose (d) Cellulose (c) Hydrogenation (d) Dehydrogenation
38. The substance that forms the plant cell walls is or Which 52. Which one of the following is the reagent used to identify glucose
carbohydrates is an essential constituents of plant cells (a) Neutral ferric chloride
[KCET 1984; MP PET 1999; CPMT 2002] (b) Chloroform and alcoholic KOH
(a) Cellulose (b) Sucrose
(c) Ammoniacal silver nitrate
(c) Vitamins (d) Starch
39. Sugar can be tested in urine by (d) Sodium ethoxide
(a) Molisch test (b) Dunstan's test 53. Sucrose on hydrolysis gives
(c) Benedict's test (d) Legal's test [MP PMT 1993; Bihar MEE 1997]
40. When sucrose is heated with conc. HNO 3 the product is (a) Two molecules of glucose
[CPMT 1979] (b) Two molecules of fructose
(a) Sucrose nitrate (b) Formic acid (c) One molecule each of glucose and fructose
(c) Oxalic acid (d) Citric acid
(d) One molecule each of glucose and mannose
41. Amylopectin is [KCET 2005]
54. Which of the following is a disaccharide [CPMT 1990, 94]
(a) Water soluble
(b) Water insoluble (a) Lactose (b) Starch
(c) Forms colloidal solution with water (c) Cellulose (d) Glucose
(d) Both (b) and (c) 55. Glucose cannot be classified as [CPMT 1989]
42. Which of the following statements about ribose is incorrect (a) A hexose (b) A carbohydrate
[CPMT 1985]
(c) An oligosaccharide (d) An aldose
(a) It is a polyhydroxy compound
56. The reagent which forms crystalline osazone derivative when reacted (c) Neutral (d) Amphoteric
with glucose, is [CPMT 1990] 71. Glucose contains [CPMT 1982]
(a) Fehling solution (b) Phenylhydrazine
(a) One CHO group
(c) Benedict solution (d) Hydroxylamine
(b) Five OH groups
57. An enzyme which brings about the conversion of starch into maltose
is known as [BHU 1979] (c) One primary alcoholic group
(a) Maltase (b) Zymase (d) Four secondary alcoholic groups
(c) Invertase (d) Diastase (e) All are correct
58. Canesugar on hydrolysis gives 72. Carbohydrates are stored in human body as
[MADT Bihar 1984; NCERT 1977; AMU 1985] [MP PMT 1999; Kerala PMT 2004]
(a) Glucose and maltose (b) Glucose and lactose (a) Glucose (b) Glycogen
(c) Glucose and fructose (d) Only glucose (c) Starch (d) Fructose
59. Glucose is a [CPMT 1984]
73. An example of a disaccharide made up of two units of the same
monosaccharides is
(a) Monosaccharide (b) Disaccharide [KCET 1989; MP PET 1996; AFMC 2005]
(c) Trisaccharide (d) Polysaccharide (a) Sucrose (b) Maltose
60. Which carbohydrate is used in silvering of mirrors (c) Lactose (d) None of these
[BHU 1973; CPMT 1991] 74. The sugar present in fruits is [KCET 1984]
(a) Sucrose (b) Starch (a) Fructose (b) Glucose
(c) Glucose (d) Fructose (c) Sucrose (d) Galactose
61. A carbohydrate that cannot be hydrolysed to simpler forms is called 75. Carbohydrates are [MADT Bihar 1983]
(a) Disaccharide (b) Monosaccharide (a) Hydrates of carbon
(c) Polysaccharide (d) Trisaccharide (b) Polyhydroxy aldehydes or ketones
62. If monosaccharide contains an aldehyde group, it is known as (c) Polyhydroxy acid compounds
(d) None of these
(a) Epimer (b) Osones
76. Glucose and fructose are [Bihar MADT 1982]
(c) Osazone (d) Aldose
(a) Isotopes
63. If a monosaccharide contains a ketogroup, it is known as
(b) Isotones
(a) Ketose (b) Osones (c) Isomers
(c) Epimer (d) Osazone (d) Homologues of each other
64. The aqueous solution of a carbohydrate gives dark blue colour with 77. Hydrolytic conversion of sucrose into glucose and fructose is known
iodine. It is as [BHU 1979, 97]
(a) Glucose (b) Fructose (a) Induction (b) Saponification
(c) Sucrose (d) Starch (c) Inversion (d) Esterification
65. Which of the following carbohydrates is a disaccharide 78. Starch is a polymer of
(a) Glucose (b) Fructose [DPMT 1982; CPMT 1975, 80; MP PMT 1994]
(c) Raffinose (d) Maltose (a) Glucose (b) Fructose
(c) Both (a) and (b) (d) None of these
66. Optical activity is shown by
79. To become a carbohydrate a compound must contain at least
(a) Glucose (b) Fructose
(a) 2 carbons (b) 3 carbons
(c) Sucrose (d) All of these
(c) 4 carbons (d) 6 carbons
67. Which is a reducing sugar 80. Lactose on hydrolysis gives [KCET 1983]
(a) Glucose (b) Fructose (a) Two glucose molecules
(c) Galactose (d) All of these (b) Two galactose molecules
68. The ultimate product of oxidation of most of hydrogen and carbon (c) A galactose molecule and a fructose molecule
in foodstuffs are [CPMT 1981] (d) A galactose molecule and a glucose molecule
(a) H 2 O alone (b) CO 2 alone 81. An example of non-reducing sugar is [KCET 1988]
(a) Cane sugar (b) Fructose
(c) H 2 O and CO 2 (d) None of these
(c) Lactose (d) Cellobiose
69. Osazone formation involves only 2 carbon atoms of glucose because 82. Cellulose is a polymer of [KCET 1984]
of [MP PMT 1986] (a) L-fructose (b) D-mannose
(a) Chelation (b) Oxidation (c) D-glucose (d) Amylose
(c) Reduction (d) Hydrolysis 83. The intermediate compound formed in the conversion of starch to
glucose is [KCET 1984]
70. Glucose will show mutarotation when solvent is
(a) Lactose (b) Sucrose
[MP PMT 1986]
(c) Maltose (d) Fructose
(a) Acidic (b) Basic
84. Invertase brings about the conversion of [KCET 1986] 94. When amylases catalyse the hydrolysis of starch, the final product
(a) Starch to glucose obtained is chiefly [Pb. PMT 1998]
(b) Sucrose to glucose and fructose (a) Cellobiose (b) Glucose
(c) Maltose to glucose (c) Maltose (d) Sucrose
95. Galactose is converted into glucose in [AFMC 1998]
(d) Glucose to C2 H 5 OH and CO 2
(a) Mouth (b) Stomach
85. Which of the following pentoses will be optically active (c) Liver (d) Intestine
CHO CHO CHO 96. Which among the following is the simplest [CPMT 1999]
| | | (a) Glucose (b) Cellulose
HCOH HCOH HCOH (c) Starch (d) None of these
| | | 97. Indigestible carbohydrate, which is also a constituent of our diet, is
HOCH HCOH HCOH (a) Cellulose (b) Galactose
(c) Maltose (d) Starch
| | |
98. Starch is converted into maltose by the
HCOH HOCH HCOH
[DPMT 1979; CPMT 1982; BHU 1999]
| | | (a) Maltase (b) Invertase
CH 2 OH CH 2 OH CH 2 OH (c) Zymase (d) Diastase
I II III 99. The disaccharide present in milk is
[MP PET 1994] [CPMT 1982, 87, 91; MP PET 2001]
(a) All (b) II and III (a) Maltose (b) Lactose
(c) I (d) II (c) Sucrose (d) Cellobiose
86. D glucose and D glucose differ from each other due to 100. Carbohydrates are used by body mainly[DCE 1999]
difference in one of the carbons with respect to its (a) For obtaining vitamins
[CBSE PMT 1995; AFMC 1999] (b) As source of energy
(a) Size of hemiacetal ring (b) Number of OH groups (c) For all its developmental needs
(c) Configuration (d) Conformation (d) For building muscles
87. Which carbohydrates has highest abundance in human blood 101. [MP PETprocess
In the viscose 1995] the solvent for cellulose consists of
(a) d-fructose (b) d-glucose [JIPMER 1999]
(c) Sucrose (d) Lactose (a) Ether and alcohol
88. Formation of silver mirror by glucose shows that it is a/an (b) Copper sulphate and ammonia
(a) Oxidising agent (b) Acid (c) Sodium hydroxide and carbon disulphide
(c) Reducing agent (d) A salt of silver (d) Acetic acid and acetic anhydride
89. Which of the following statements is right
102. Which of the following does not reduce Benedict's solution
(a) Cellulose are linear polymers of glucose molecules with [KCET 2000]
1, 4 linkages (a) Sucrose (b) Aldehyde
(b) Starches are polymers of glucose molecules with (c) Glucose (d) Fructose
1, 4 linkages and some 1, 6 cross-linkages 103. In polysaccharides the linkage connecting monosaccharide units is called
(a) Glycoside linkage (b) Nucleoside linkage
(c) Proteins are polyamides of amino acids
(c) Glycogen linkage (d) Peptide linkage
(d) The structural information about their biosynthesis is
contained in a class of compounds called nucleic acids, e.g. RNA 104. Blood sugar is the same as [DPMT 2000]
and DNA (a) Glucose (b) Galactose
90. The number of atoms in the cyclic structure of D-fructose is (c) Glycogen (d) Fructose
[MP PMT 1997] 105. Glucose has functional group [MH CET 2000]
(a) 5 (b) 6 (a) Aldehydic
(c) 4 (d) 7 (b) Aldehydic and alcoholic
91. Which is used in motion picture films
(c) Alcoholic
(a) Cellulose acetate (b) Glucose acetate
(d) Ketonic and alcoholic
(c) Starch acetate (d) Sucrose acetate
106. Which of the following is an aldohexose
92. Glucose reacts with acetic anhydride to form
[KCET 1996] [KCET (Engg.) 2001]
(a) Mono-acetate (b) Tetra-acetate (a) Cellulose (b) Sucrose
(c) Penta-acetate (d) Hexa-acetate (c) Glucose (d) Raffinose
93. Which of the following does not show any reducing test of aldehyde[CPMT 107. The calorific
1996; Orissa JEE 2004]value is maximum in case of
(a) Sucrose (b) Fructose [Kerala (Med.) 2000]
(c) Maltose (d) Lactose (a) Milk (b) Proteins
(c) Minerals (d) Carbohydrates
108. An invert sugar is [AFMC 2000] [MP PMT 2003]
(a) Isorotatory (b) Dextrorotatory (a) Glucose (b) Aspartame
(c) Laevorotatory (d) Optically inactive (c) Saccharin (d) Cyclodextrin
109. The change in optical rotation with time of freshly prepared 122. The specific rotation of equilibrium mixture of -D-glucose and -
solutions of sugar is known as [JIPMER 2000] D-glucose, is [MP PMT 2003]
37. Which of the following reacts with haemoglobin in the blood to (a) Nucleic acid (b) Carbohydrates
form carboxyhaemoglobin [Manipal MEE 1995] (c) Fats (d) Proteins
(a) CO (b) CO 2 47. Enzymes belong to which class of compounds
[KCET 1996]
(c) HCOOH (d) H 2CO 3 (a) Polysaccharides
38. Secondary structure of a protein refers to [CBSE PMT 1995] (b) Polypeptides
(a) Mainly denatured proteins and structures of prosthetic groups (c) Polynitrogen heterocyclic compounds
(b) Three dimensional structure, specially the bond between amino (d) Hydrocarbons
acid residues that are distant from each other in the 48. By the action of enzymes, the rate of biochemical reaction
polypeptide chain [CBSE PMT 1994]
(c) Linear sequence of amino acid residues in the polypeptide (a) Decreases (b) Increases
chain
(c) Does not change (d) Either (a) or (c)
(d) Regular folding patterns of continuous portions of the
49. Metal present in blood is [CPMT 1997]
polypeptide chain
(a) Al (b) Mg
39. Of the following statements about enzymes which ones are true
(c) Cu (d) Fe
(i) Enzymes lack in nucleophilic groups
(ii) Enzymes are highly specific both in binding chiral substrates 50. Which compound can exist in a dipolar (zwitter ion) state
and in catalyzing their reactions [Pb. PMT 1998]
(iii) Enzymes catalyse chemical reactions by lowering the activation (a) C6 H5 CH 2CH (N CH 2 )COOH
energy
(b) (CH 3 )2 CH .CH (NH 2 )COOH
(iv) Pepsin is a proteolytic enzyme [CBSE PMT 1995]
(a) (i) and (iv) (b) (i) and (iii) (c) C6 H5 CONHCH 2COOH
(c) (ii), (iii) and (iv) (d) (i) (d) [Link] 2CH 2COCOOH
40. Proteins are composed of [MP PMT 1995; J & K 2005]
51. What is the monomer of polypeptide
(a) amino acids (b) Carbohydrates
[KCET 1998; JIPMER 1999; Pb. CET 2002]
(c) Vitamins (d) Mineral salts
(a) Amino acid (b) Glucose
41. Read the following statements carefully
(c) Nucleoside (d) Nucleotide
(A) Albumin is a simple protein
52. Which of the following enzymes is not useful in the digestion of
(B) The amino acid alanine contains an acidic side chain
proteins [KCET 1998]
(C) Insulin is a hormone
(a) Chymotrypsin (b) Pepsin [Pb. PMT 2000]
(c) Trypsin (d) Lipase (a) Catabolism (b) Anabolism
53. Haemoglobin is [CBSE PMT 1997; BHU 2004] (c) Fermentation (d) Metabolism
(a) An enzyme (b) A globular protein 66. A biological catalyst is essentially
(c) A vitamin (d) A carbohydrate [Pb. PMT 2000; BHU 2004]
(a) A carbohydrates (b) An amino acids
54. Albumin proteins are most abundant in [BHU 1998]
(c) A nitrogen molecule (d) Fats
(a) Meat (b) Milk
67. The test used for identifying peptide linkage in proteins is
(c) Egg (d) Soyabean
[KCET (Engg.) 2001]
55. Dialysis can separate [BHU 1998]
(a) Borsche's test (b) Molisch's test
(a) Glucose and fructose (c) Ninhydrin test (d) Biuret test
(b) Glucose and sucrose 68. Which of the following is not a function of proteins
(c) Glucose and NaCl [MP PMT 2001]
(d) Glucose and proteins (a) Nails formation
56. Which one of the following is an example of a globular protein [Orissa
(b) Skin JEE 1997]
formation
(a) Keratin (b) Insulin (c) Muscle formation
(c) Collagen (d) Myoglobin (d) Providing energy for metabolism
57. Leucine amino acids is the [Pb. PMT 1999] 69. The helical structure of proteins is stabilized by
(a) Essential (b) Non-essential [MP PMT 2001]
(c) Aromatic (d) Basic (a) Peptide bonds (b) Dipeptide bond
58. Which of the following tests is not used for testing proteins (c) Hydrogen bond (d) Vander Waal's forces
[Kerala PMT 1999; KCET 1999] 70. The optically inactive amino acid is
(a) Millon's test (b) Molisch's test [MP PMT 2001; BHU 2005]
(c) Biuret test (d) Ninhydrin test (a) Lysine (b) Glycine
59. Amino acids usually exist in the form of Zwitter ions. This means (c) Arginine (d) Alanine
that it consists of [KCET 2000] 71. Which amino acid can cross link peptide chains
(a) The basic group – NH 2 and the acidic group COOH [AIIMS 2001]
(a) Serine (b) Cysteine
(b) The basic group NH 3 and the acidic group CO 2 (c) Glutamine (d) Tyrosine
(c) The basic group CO 2 and the acidic group NH 3 72. Amino acids are the building blocks of [MH CET 2001]
(a) Fat (b) Vitamin
(d) No acidic or basic group
(c) Protein (d) Carbohydrate
60. The most important energy carrier in all the living cells is
73. Which of the following protein destroys the antigen when it enters
[MP PET 2000; KCET 2000]
in body cell [AIIMS 2001; Pb. PMT 2004 ]
(a) AMP (b) ATP
(a) Antibodies (b) Insulin
(c) ADP (d) UDP
(c) Chromoprotein (d) Phosphoprotein
61. The 10% energy transfer law of food chain was given by
74. An antibiotic with a broad spectrum [AFMC 2001]
[BHU 2000]
(a) Kills the antibodies
(a) Stanley (b) Weismann
(b) Acts on a specific antigen
(c) Lindemann (d) Tansley
(c) Acts on different antigents
62. Which of the following is a conjugated protein [BHU 2000]
(d) Acts on both the antigens and antibodies
(a) Glycoprotein (b) Phosphoprotein
75. Antibodies are [CBSE PMT 2001]
(c) Chromoprotein (d) All of these
(a) Carbohydrate (b) Globular protein
63. The number of essential amino acids in man is
(c) Immunoglobulins (d) Cellulose compounds
[CBSE PMT 2000]
(a) 8 (b) 10 76. Excess of Na ions in our system causes [BHU 2001]
(c) 18 (d) 20 (a) High B.P. (b) Low B.P.
64. Pick out wrong combination [DCE 2000] (c) Diabetes (d) Anaemia
2
77. The example of a protein is [MP PET 2003]
(a) Fe Haemoglobin
(a) Narvone (b) Lacithin
(b) Mg 2 Photosynthesis (c) Cellulose (d) Insulin
78. Enzymes are made up of [CBSE PMT 2002]
(c) Se 2 Kreb Cycle
(a) Carbohydrates
(d) CO 2 Vitamin B-12 (b) Edible proteins
65. The decomposition of complex organic compounds into simpler (c) Nitrogen containing carbohydrates
compound with the help of enzyme is known as (d) Proteins with specific structure
79. Chlorophyll contains [RPMT 2002] NH 2
(a) Fe (b) Na |
(a) CH 3 CH .C OOH
(c) Mg (d) Zn
80. Which one of the following biomolecules is insoluble in water [AIIMS 2005] CH 3 NH 2
|
(a) - Keratin (b) Haemoglobin (b) CH CH .COOH
(c) Ribonuclease (d) Adenine CH 3
81. A nanopeptide contains …….. peptide linkages [KCET 2005]
CH 3 NH 2
(a) 10 (b) 8 |
(c) 9 (d) 18 (c) CH CH .COOH
82. Identify the incorrect statement [Kerala (Med.) 2003] C2 H 5
(a) An octa deca peptide contains 18 amino acid residues and 17
C2 H 5 NH 2
peptide bonds |
(b) Addition of an inert gas into a system in thermodynamic (d) CH CH .COOH
equilibrium for the dissociation of PCl5 shifts the equilibrium C2 H 5
to the left. 91. The process by which synthesis of protein takes place based on the
(c) When gold dissolves in aquaregia the complex formed is genetic information present in m-RNA is called
chloroauric acid [KCET 2003; Kerala CET 2005]
(d) In the extraction of aluminium purified bauxite is dissolved in (a) Translation (b) Transcription
molten fluorospar
(c) Replication (d) Messenger hypothesis
(e) If the pH value of a solution is to be decreased from 5 to 3, the
hydrogen ion concentration must be increased twice the initial 92. Which of the following is used in our body as a fuel for muscles and
value. nerves and to build and repair body tissues?
[DCE 2003]
83. -helix is found in [Kerala (Engg.) 2002]
(a) DNA (b) RNA (a) Cane sugar (b) Fructose
(c) Lipid (d) Protein (c) Proteins (d) Glucose
84. The main structural of protein is [UPSEAT 2000, 02] 93. Which enzyme convert glucose into alcohol
(a) The ester linkage (b) The ether linkage [Pb. CET 2003]
(c) The peptide linkage (d) All of these (a) Invertase (b) Zymase
85. Among the following, the achiral amino acid is (c) Maltase (d) Diastase
[AIIMS 2003] 94. Which one of the following structures represents the peptide chain [CBSE PMT
MP PET 1994; Bihar MEE 1997; Orissa JEE 1997]
(a) 2-Ethylalanine
(b) 2-Methylglycine H H H O
| | | | | | ||
(c) 2-Hydroxymethyl serine (a) N C C N C C N C C
| || | || |
(d) Tryptophan O O
86. Which of the following could act as a propellant or rockets
H O H
[CBSE PMT 2003] | | | || | | | | |
1 b 2 c 3 a 4 a 5 c 1 b 2 c 3 c 4 c 5 b
6 b 7 c 8 d 9 c 10 c 6 d 7 b 8 b 9 c 10 d
11 c 12 b 13 a 14 b 15 c 11 a 12 d 13 d 14 d 15 b
16 a 17 d 18 b 19 c 20 d
16 a 17 d 18 c 19 d 20 d
21 d 22 d 23 c 24 b 25 b
21 c 22 b 23 c 24 b 25 a
26 b
26 a 27 d 28 a 29 a 30 d
31 c 32 a 33 b 34 c 35 d
Assertion and Reason
36 b 37 a 38 d 39 c 40 a
41 d 42 d 43 b 44 d 45 d 1 a 2 b 3 b 4 e 5 d
46 d 47 b 48 b 49 d 50 b 6 a 7 b 8 d 9 c 10 c
11 a 12 b 13 b 14 b 15 b
51 a 52 d 53 b 54 c 55 d
16 b 17 e 18 e 19 b 20 e
56 d 57 a 58 b 59 c 60 b
21 e 22 c 23 a
61 c 62 d 63 b 64 c 65 c
66 b 67 d 68 d 69 c 70 b
71 b 72 c 73 a 74 c 75 c
76 a 77 d 78 d 79 c 80 a
81 b 82 e 83 d 84 c 85 c
86 c 87 c 88 e 89 b 90 c
91 a 92 c 93 b 94 a 95 a
Carbohydrates
96 d 97 a 98 a 99 c
1. (d) D Glucose ⇌ Equilibrium mixture ⇌
[ ] 112
o
[ ]D 52 o
Fats and Lipids (36 %) (0 .02 %)
D Glucose
1 c 2 a 3 d 4 c 5 c [ ]D 19 o
(64 %)
6 c 7 a 8 c 9 b 10 c
Glucose has two forms and . When either of these two is
11 d 12 c 13 d 14 c 15 bd dissolved in water and allowed to stand, it gets converted to an
16 c 17 a 18 a 19 c 20 c equilibrium mixture of and forms.
2. (b) Gun-cotton is a nitrocellulose or cellulose trinitrate which is
21 b 22 a 23 d 24 a 25 c used in explosive and as a binder for solid rocket propellant.
26 a 27 d 3. (d) Arabinose is an aldopentose HOCH 2 (CHOH )3 CHO
4. (d) In proteins amide group is present
Vitamins, Hormone and Nucleic Acid ( NH C H C NH C H C )n
| || | ||
R R
O O
1 d 2 a 3 c 4 c 5 c Amino or
peptide bond
6 d 7 a 8 a 9 d 10 c 5. (c) Inulin is a carbohydrate which is stored in “Roots of Dahliya”.
11 a 12 d 13 a 14 b 15 d
6. (c) Carbohydrates are hydrates of carbon. Their general formula is
C x (H 2 O)y .
16 b 17 a 18 c 19 b 20 c
8. (d) Glucose + Tollen’s reagent
21 c 22 a 23 a 24 a 25 d Gluconic acid + Ag-mirror.
26 b 27 d 28 a 29 b 30 d
9. (b) Protein gives blue-violet colour with ninhydrin
(2, 2-dihydroxyindane-1, 3-diene)
31 b 32 a 33 b 34 a 35 a Carbohydrates gives brown red ppt. with benedict’s solution
36 c 37 a 38 d 39 b 40 b
(Alk. CuSO 4 Citrate ions)
11. (c) A ring structure
41 b 42 a 43 c 44 c 45 b
46 a H OCH 3
Oo
CH 2 OH
Glucose
CH O
H C OH OH H
|
H OH
86. (c) C
H C OH C C |
| |
|
HO C H CH 3 OH (CHOH )3 HCl
O
(CHOH )3
| |
(CHOH )3 |
|
H C OH CH CH O
| | CH O |
H C CH 2 OH |
CH 2 OH
|
CH 2 OH D glucose
- Methyl glucoside D glucose
O
C H CH OH
2
41. (b) Amylopectin is not soluble in water. 94. (c) Starch Maltose .
Amylase
43. (c) C12 H 22 O11 96. (a) Glucose is the simplest carbohydrate i.e. mono saccharide rest
Maltose
are polysaccharide.
47. (b) Sucrose is not a reducing sugar.
CHO CH N NHC 6 H 5 97. (a) We can’t digest cellulose which is a polysaccharide.
| | 98. (d) Diastase enzyme converts starch into maltose.
CHOH CHOH
56. (b) |
NH 2 NHC 6 H 5 | 99. (b) Lactose is present in milk (Glucose + Galactose).
(CHOH )3 Warm (CHOH )3
| |
100. (b) Carbohydrates are rich source of energy.
CH 2 OH CH 2 OH 102. (a) Sucrose is a non reducing sugar it does not give any test with
Glucose phenylhyd razone
Benedict’s solution.
CH N NHC 6 H 5
| 103. (a) That is called glycosidic linkage.
CO
|
NH 2 NHC 6 H 5 108. (c) Invert sugar is laevo rotatory.
(CHOH )3
|
111. (c) Starch is polymer of alpha glucose.
CH 2 OH 114. (a) Raffinose (C18 H 32 O16 ) is a trisaccharide
CH N NHC 6 H 5
| C18 H 32 O16 H 2 O C 6 H 12 O 6 C 6 H 12 O 6 C 6 H 12 O 6
C N NHC 6 H 5 D glucose D fructose D mannose
79. (b) 3 carbons e.g. Glyceraldehyde CH 2 CH CHO 128. (b) Sugar Relative sweetness
|
| Sucrose 100
OH OH
Glucose 74
83. (c) Starch Maltose
Diastage
glucose.
Maltase
Lactose 16
85. (a) All are optically active.
Fructose 173
129. (a) C 6 H 12 O 6 6O 2 6CO 2 6 H 2 O 38 ATP H 2 N CH 2COOH
and so on.
131. (b) Fructose has three chiral centres and hence 23 = 8 optical NH 2
isomers are possible. 41. (d) Muscles contain myoglobin CH 3 CH
COOH
132. (b) Freezing point is the temperature at which the liquid and the
solid form of the same substance are in equilibrium and hence alanine contain side chain of methyl group.
have the same vapour pressure. Due to lower vapour pressure 43. (b) It is the general formula for polysaccharides.
of the solution, solid form of a solution separates out at a
lower temperature. The decrease is called depression in 50. (b) (CH 3 )2 . CH . CH COOH ⇌ (CH 3 )2 CH . CH COO
freezing point. | |
NH 2 NH 3
When solid is the solute, it is solvent that freezes. Hence in the
given question water will be separated out first. 52. (d) Lipase is used in lipid metabolism.
133. (a) Glucose is a monosaccharide having chemical composition
Lipid
Fatty acid Glycerol
Lipase
C 6 H 12 O6 .
53. (b) Haemoglobin is a globular protein.
59. (c) Zwitter ion is a dipolar ion containing both a positive and
Proteins, Amino Acids and Enzymes
NH 3
|
1. (b) Insulin is a protein consists of 51 amino acids in two chains. negative charge in the following form R CH COO
and Zwitterion
- 21 amino acids, - 30 amino acids The basic group CO 2 and acidic group NH 3 .
It is secreted by pancreas for controlling the sugar level in
63. (b) The amino acids which can’t be synthesised by human body so
blood.
they are essential to take from diet. They are 10 in number.
3. (a) Fibrous proteins are insoluble in water.
66. (b) Biological catalysts are enzymes and all enzymes are nucleic
4. (a) Protein
Denatured protein
Heated acid.
or change in pH 68. (d) Protein is a body building substance not energy giving
substance.
5. (c) Simple protein non - protein material
(Prostheti c group or co- factor)
76. (a) Na and K controls blood pressure and heart beat so excess
Conjugated protein of Na ion increases B.P.
2
6. (b) Heam Fe to which the porphyrine ring is attached to 80. (a) This protein is found in hair, nail, muscle etc.
central atom by co-ordinate linkage. 81. (b) The peptide bond is formed between two amino acids by the
7. (c) It is insoluble in water and used in food products capsules and elimination of a water molecule. A dipeptide contains one
photographic plates. peptide linkage. A tripeptide contains two peptide linkages.
Similarly, a nanopeptide contains 8 peptide linkages.
9. (c) Amino acids are non volatile crystalline compound.
91. (a) Synthesis of polypeptide known as translation. For this process
10. (c) Isoelectric point is a pH at which zwitter ions do not migrate three type of RNA essential.
towards any of the electrode. 92. (c) Protein is used in our body as a fuel for muscles and nerves
11. (c) Protein
Enzyme
Amino acid and to build and repair body tissues.
(Acidic medium in stomach) 93. (b) Zymase enzyme convert glucose into alcohol. It is found in the
yeast.
12. (b) Protein + conc. HNO 3 Yellow colour
C6 H12 O6 2C2 H 5 OH 2CO 2
zymase
[This test is given by a protein which consists of -amino acids glucose ethyl alcohol
containing a benzene ring such as tyrosine, phenylalanine etc.
The yellow colour is due to nitration of benzene ring.] 94. (a) In peptide linkage i.e., –CONH – group, the carboxyl group of
one amino acid molecules forms an amide by combination with
14. (b) Proteins are polymers of amino acids. the amino group of the next amino acid molecule with the
Amino acid Dipeptide Polypeptide Protein. liberation of water molecule.
21. (c) Proteins are nitrogenous compounds. H O H R
2
H O
22. (b) In stomach medium is strongly acidic. Hence, pH 2 . N C C N C
30. (d) Glycine NH 2 CH 2 COOH . C N C C
34. (c) Antigens are polysaccharides present on RBC's surface. H R C R
H O
3
1
25. (d) Cortisone is not a sex harmone, it regulates metabolism of fats, | Hydrolysis |
Fatty acid
carbohydrates, proteins etc. CH 2 O COR CH 2 OH
27. (d) Thymine is present in DNA while in RNA there is Uracil. Glycerol
28. (a) Mutation is a chemical change in the sequence of Nitrogenous 14. (d) –helix structure is formed when the chain of –amino acid
bases along the DNA strained which can lead to the synthesis coil as a right handed screw because of the formation of
of protein with altered amino acid sequence.
hydrogen bonds between amide groups of the same peptide
chain i.e., NH group in one unit is linked to carbonyl oxygen of Therefore, both assertion and reason are true.
the third unit by hydrogen bonding. This H–bonding is 2. (b) Hydrolysis of sucrose is known as inversion of canesugar
responsible for holding helix in a position. because sucrose produce equimolecular mixture of glucose and
15. (b) Three types of chemicals enter the composition of all fructose. Sucrose is dextro-rotatory which glucose and fructose
membranes proteins, lipids and carbohydrates, proteins content mixture is laevorotatory. Sucrose is disaccharide.
varies from 46–76% lipids 20–53%, while Carbohydrate 3. (b) Proteins on hydrolysis gives –amino acid because amino acids
content is 1–8% are the building block of proteins. It is also fact that amino
16. (c) Difference in mass of compound acids contain both NH 2 and COOH group.
= 390 – 180 = 210
Here assertion and reason both are correct but reason is not a
wt. of CH 3 CO – group is = 43 correct explanation of assertion.
4. (e) Sucrose does not undergo mutarotation. Glucose and fructose
210
Therefore no. of NH 2 group = 4 .88 5 . shows mutarotation because they have two forms and. It is
43 fact that sucrose is a disaccharide. Therefore, assertion is false
17. (d) Six type of tripeptide molecules are formed. but reason is true.
18. (b) Amylose is a polysaccharide. 5. (d) Here, both the reason and assertion are false, DNA occurs in
19. (c) Aspartic acid is an amino acid with acidic side chain. nucleus of the cell while RNA is found mainly in cytoplasm of
the cell. On heating, enzymes lose their specific activity.
NH 2
HOOC CH 2 CH 6. (a) All amino acid posses amino as well as carboxylic group.
COOH
NH 2 group is basic while COOH group is acidic.
Lysine, Arginine and Histidine all are basic amino acids.
Therefore, they behave as zwitter ion (dipolar ion). Here, both
20. (d) Lucas test is used for the distinction of alcohols. assertion and reason are true and reason is a correct
explanation.
21. (d) Because their Ca / Mg salts are insoluble in water.
7. (b) The assertion that activity of an enzyme is pH dependent is
22. (d) Glucose on reaction with bromine water followed by oxidation
gives gluconic acid correct. The reason that change in pH affects the solubility of
enzyme in water is also true but the reason is not the correct
C6 H12 O6 (O) CH 2OH (CHOH )4 COOH
Br2 / H 2 O
explanation of assertion. Change in pH cause denaturation of
Glucose Gluconic acid enzyme.
23. (c) NH 3 CH 2 COO 8. (d) Glycosides are formed by treating glucose with methanol in
dipolar ion
(Zwitterion or internal salt)
presence of dry HCl gas. They cannot be hydrolysed in acidic
conditions. They are not acetals but they are hemiacetals.
24. (b) Ribose is an example of aldopentose.
9. (c) The assertion is correct that haemoglobin is an oxygen carrier
25. (b)
and the reason that oxygen binds as O 2 to Fe of haemoglobin
H 1C OH HO 1 C H
|
and
| is incorrect, because oxygen binds as O 2 to Fe of haeme
H 2 C OH H 2 C OH
| | part.
OH 3 C H O OH 3 C H O
| | 10. (c) Carboxypeptidase is an exopeptidase because it breaks the peptide
H 4 C OH H 4 C OH
| | chain at terminal ends.
H 5 C H 5 C
| | Carboxypeptidase cleaves carboxy-terminal amino acids that have
6 CH
2 OH
6 CH
2 OH aromatic or branched aliphatic side chains.
- D(+) - Glucopyranose - D(+) - Glucopyranose
Two form of D–Glucopyranose are –D(+)–Glucopyranose and 11. (a) Sucrose is a non reducing sugar as it does not reduce Tollen's
–D(+)–Glucopyranose. These are anomers (a pair of or Fehling's reagent, due to absence of free aldehyde of ketone
stereoisomers which differ in configuration only around C1 group. It contains stable acetal or ketal structure which cannot
are called anomers). be opened into a free carboxyl group.
26. (b) Surcrose is composed of -D-glucopyranose unit and a – Sugar is composed of -D-glucopyranose unit and -D-fructo
D-fructofuranose unit. These units are joined by - furanose unit. These units are joined by --glycosidic linkage
glycosidic linkage between C–1 of the glucose unit and C–2 of between C- 1 of the glucose unit and C- 2 of the fructose unit.
the fructose unit.
12. (b) Carbohydrates which upon hydrolysis yield two molecules of
the same or different monosaccharides are called disaccharides.
Assertion and Reason For example, sucrose on acid hydrolysis give one molecule of
glucose and fructose.
1. (a) Glycine is an amino acid, it contains both NH 2 as well as –
COOH groups and therefore, its aqueous solution form Zwitter 13. (b) Fructose on warming with dilute alkali, gives rise to an
ion which is amphoteric in nature. equilibrium mixture of glucose, fructose and mannose. The
ability of fructose to reduce Fehling solution and Tollen's
NH 2 CH 2 COOH NH 3 CH 2 COO reagent is probably due to the isomerisation of fructose to
Glycine Zwitterion
glucose and mannose (this is called Lobry de Bruyn and
Elkenstein rearrangement).
14. (b) Glucose exists in two forms, i.e., -D-glucose with a specific
rotation of +112° and -D-glucose with a specific rotation of
+19°. However, when either of these two forms is dissolved in
water and allowed to stand. it gets converted into the same
equilibrium mixture of both the - and -forms with a small
amount of open chain form. As a result of this equilibrium, the
specific rotation of a freshly prepared solution of -glucose
decreases from +112° to 52.7° while that of glucose increases
from +19° to 52.7°.
15. (b) In acidic medium COOH group acts as the base and
accepts a proton. As a result, -amino acids exist as cations in
acidic medium and migrate towards cathode under the
influence of an electric field. In alkaline medium N H 3 group
acts as the acid and thus loses a proton. As a result, -amino
acids exist as anion and migrate towards anode under the
influence of an electric field. However at some intermediate
value of pH, the concentration of cationic form and anionic
form will become equal and hence there is no net migration of
-amino acid under the influence of an electric field.
16. (b) Valine is an essential amino acid. The amino acids which the
body cannot synthesize are called essential amino acid.
17. (e) Sequence of bases in DNA is TGAACCCTT. Since according to
base-pairing principle, T in DNA faces A in m-RNA, while G
faces C and A faces U. Therefore, sequence of bases in m-RNA
is ACUUGGGAA.
18. (e) Millons test is a test for proteins. When Millon's reagent is
added to the aqueous solution of a protein, a white precipitate
is formed.
19. (b) ATP has four negatively charged oxygen atoms very close to
each other. So the repulsive forces between them is high. On
hydrolysis of ATP, a H 2 PO4 ion is eliminated and the
number of negatively charged oxygen atoms decreases. Thus,
repulsive forces decreases and a large amount of energy is set
free. When ATP changes to ADP, which in turn changes into
AMP, energy is released at each step. This is how ATP can act
as a source of energy.
20. (e) Solubility of protein is maximum at the isoelectric point.
21. (e) Amino acids are soluble in polar solvents like H 2 O , NaOH
and HCl and insoluble in non-polar solvents like benzene, ether
etc.
22. (c) Sucrose on hydrolysis gives equal amounts of glucose and
fructose. Since glucose has less positive and fructose has more
negative magnitude of rotation, therefore, change in the sign of
rotation is observed.
1. Which does not show mutarotation (a) NH 2 ,COOH (b) NH 2 ,SO 3 H
(a) Sucrose (b) Maltose (c) Both (d) None of these
(c) Glucose (d) Fructose 11. Which functional group participates in disulphide bond formation in
2. Artificial silk is proteins [CBSE PMT 2005]
(a) Polyamides (b) Polyesters (a) Thiolactone (b) Thiol
(c) Polyacids (d) Polysaccharides (c) Thioether (d) Thioester
3. Which of the following is a protein [Pb. CET 2003] 12. Schweitzer's reagent used for dissolving cellulose in the
manufacture of artificial silk is [Roorkee 1999]
(a) Pepsin (b) Adrenaline
(c) ATP (d) Glutamin (a) CuSO 4 . 5 H 2 O
4. Glucose gives many reactions of aldehyde, because (b) CuI
[CPMT 1977] (c) [Cu (NH 3 )4 ]SO 4
(a) It is hydrolysed to acetaldehyde
(d) Cu(CH 3 COO)2 . Cu(OH )2
(b) It is a polyhydroxy ketone
13. Which one of the following statements is true for protein synthesis
(c) It is a cyclic aldehyde
(translation) [AIIMS 2005]
(d) It is a hemiacetal in equilibrium with its aldehyde form in
(a) Amino acid are directly recognized by m-RNA
solution
(b) The third base of the codon is less specific
5. Glucose in blood can be quantitatively determined with
(c) Only one codon codes for an amino acid
[JIPMER 2002]
(d) Every t-RNA molecule has more than one amino acid
(a) Tollen's reagent
attachment site.
(b) Benedict's solution 14. In both DNA and RNA, heterocyclic base and phosphate ester
(c) Alkaline iodine solution linkages are at [AIEEE 2005]
(d) Bromine water (a) C5 and C 2 respectively of the sugar molecule
6. Which of the following ions can cause coagulation of proteins [Kerala (Med.) 1999]
(b) C 2 and C5 respectively of the sugar molecule
(a) Na (b) Ag
(c) C1 and C5 respectively of the sugar molecule
(c) Ca (d) Mg
(d) C5 and C1 respectively of the sugar molecule
7. Glucose reacts with methyl alcohol to give [CPMT 1985]
15. Which of the following biomolecules contain non-transition metal
(a) methyl glucoside ion [KCET 2005]
(b) methyl glucoside (a) Vitamin B12 (b) Chlorophyll
(c) Both (a) and (b) (c) Haemoglobin (d) Insulin
(d) None of these 16. An example of a sulphur containing amino acid is
8. Molisch's test is done for the detection of [BHU 1987] [KCET 2005]
(a) Alkyl halide (b) Carbohydrate (a) Lysine (b) Serine
(c) Alkaloid (d) Fat (c) Cysteine (d) Tyrosine
9. Which of the following is not an amino acid 17. Which of the following is not present in a nucleotide
[MP PET/PMT 1998] [KCET 2005]
(SET -31)
1. (a) Sucrose does not show mutarotation due to non reducing
nature.
2. (d) It is a polysaccharide.
3. (a) Pepsin is a protein.
4. (d) It is a hemiacetal in equilibrium with its aldehyde form in
solution.
5. (a) In glucose aldehydic group is present and Tollen's reagent is
the test for aldehydes.
6. (b) Ag can cause coagulation of proteins.
7. (c) Alpha methyl glucoside and beta methyl glucoside.
8. (b) Molisch’s test is done for the detection of carbohydrate bond
formation.
9. (d) Benzidine is not an amino acid. It is an amine.
10. (c) A substance forms Zwitter ion. It can have functional groups
NH 2COOH and NH 2 , SO 3 H .
11. (b) Thiol functional group particpitates in disulphide in proteins.
12. (c) Cu (NH 3 )4 SO 4 is schweitzer’s reagent used for
manufacture of artificial silk.
13. (a) In the process of translation amino acids are directly
recognized by m-RNA.
O
|| 5
14. (c) O P O CH 2
Base
O
|
O 4 Sugar 1
Phosphate ester
linkag
3 2
15. (b) Biomolecule Metal ion
Vitamin B12 Co (transition metal)
Chlorophyll Mg (non-transition metal ion)