Guru Nanak Public School Half Yearly Examination (2023-24) Subject - Science [ Chemistry ] Class - XI MLM. : 70 General Instruction - a) There are 36 questions in this question paper with internal choice, b) Section A consist of 18 MCQ carrying 1 marks. °) Section B consist of 7 very short answer question carrying 2 marks each. d) Section C consist of 5 short answer question carrying 3 marks each. ©) Section D consist of 2 case based question carrying 4 marks each. 1) Section - E consist of 3 long answer question carrying 5 marks each. Section -A Qt The following question are multiple choice question each carry 1 mark. No Internal choice. 1) The maximum no. of unpaired electron are in - a) Few b)~ Few °) Fe da Fe 2) Anelement with atomic No. 20 placed in which period of periodic table : a) 4 b 3 ) 2 d) 1 3) The oxidation no, of C (Carbon) is zero is - a) CHCl, b) CHCl, ) G4H,0, d) co 4) The IUPAC name of the following : a) 4-methyl chloro benzene b) — 4-chloro toulene ©) 1-chloro - 4 - methyl benzene. a) 1-methyl- 4 - chloro benzene 5) Which ofthe following properties generally decrease along a Period - a) Ionization Enthalpy b). Atomic radius ©) Valency d) Negative electron gain enthalpy 6) Which one is the most metallic character : a) Si b» B Al dF fec eR Pe7 8) 9) 10) 1) 12) 13) 14) 15) The unit of molarity is - a) Mol Kg" by) gMol* oo) a L Ifz=17 and A= 35 predict the symbol of the atom - a) Be b) Ca co) Cl Burning of lime to give CaO and CO, is a - a) Anoxidation process b) _ Areduction process ) __ Disproportion reaction d) Decomposition reaction ‘The delocalization of electron take place through overlap between o— bond orbital and x~ bond orbital is called - a) Inductive effect b) —_ Hyperconjugation ©) Steric effect d) Resonance In which of the following set, the ions are isoelectronic - a) Na’, Mgt, F-, O® b) FCI, Br 1 c) Ca®,p™, Cl", S™ d) N°, Cl, Mg®, Fo Which of the following compound will exhibit cis, trans (Geometrical) Isomerism. a) Butanol b) — 2-butyne c) 2 butanol d) 2-butane Which of the following is / are redox reaction - a) Burning of Gasoline b) Evaporation of water ©) Production of ©, from O,, d) Reaction of Zn & HCI ‘The IUPAC name of the compound ~ HOOC - CH, - CH - CH, - COOH COOH a) Prop 1, 2, 3 tri carboxylic acid b) But 1, 2, 4 tricarboxylic acid ©) 4~carboxyhexane - 1, 6 dioic acid d) 1, 2dicarboxy pentanoic acid Which of the following statement about a compound is incorrect 7 a) ifs Amolecule of a compound always has atom of different elements. b) Acompound can be seperated into its constitute element by simple physical process. ©) — Acompound retain the physical properti 7 perties of its constitute element The atom of element in a compound are present in a fixed rat 0. a16) 17) 18) 19) 20) 21) 22) Ground State electronic Conf a ‘Suration of nitrogen atom can be represent GR Po ay oy Tl] (ya oy Which of the following pair of elements exhibit diagonal relationship 7 a) Be, Mg b) Li, Mg ©) Be,B qd) Be, Al ‘The negative charged species which help in the substitution reaction - a) Nucleophile b) — Electrophite ©) Carbocation 4) Carbanion Section -B This section contain 7 Question with intemal choice, Very short answer type and each carry 2 mark, Tx2=14, Write the electronic configuration of - a) Mg=a@rig b) = Ca*=20 Write the empirical formula for each of the following compound - a) Na,CO, b) BH, ©) H,Po, 4d) H,0, Yellow light emitted from a sodium lamp has a wavelength (A) of 580 nm Calculate frequency (v) and wave no (v1) of yellow light. Or Calculate the no. of electron, proton and neutron in the following species - 1) Bp 2) Pe IUPAC - ° a i) CH,-CH=CH-C-OH CH, CH, i) — ch,-¢-cH,-¢-ch, I a Br@ Give one example of redox reaction in the following case - 24) 25) 26) 27) 28) 29) 30) a) Decomposition reaction. b) Metal Displacement reaction. Give Reason - a) Why Beto B the ionization enery is decrease. b) What happen in case of atomic radius from group and period. Define - a) Wavelength b) Frequency or solution is prepared by adding 2g of a substance A to 18g of H,O. Calculate the mass percentage of solute. Section -C 5x3=15 This section contain 5 question with internal choice. The following are short answer type question carry 3 marks. Calculate the oxidation number of - a) Cr,02> b) PO; 2) s,0,° or Balance the equation with the help of oxidation number - a) Mn02+CI~ Mn + Cl, +H,0 b) Zn +HNO, =————> Zn (NO,), + NO, + H,O Describe Heisenberg uncertaimity principle with its significance. Or The uncertainity is the momentum of a particle is 6 x 102 Kg ms*. Calculate the uncertainity in its position Explain the role of reaction intermediate in its chemical reaction with its type. Calculate the molecular mass of - a) HO b) CO, °) CH, An element to 3rd period of p-block element. Ithhas 4e- in its outer most shell. Predictits group. How many unpaired electron does it have. Write its configuration & type of chemical bonding.Section -D ‘The following question is case based theory carrying 4 marks each Case Study 1 We must bear in mind that when Mendeleev developed his Periodic Table, chem- 31) 4x2=8 'sts knew nothing about the internal structure of atom. However, the beginning of the 20th century witnessed profound developments in theories about sub-atomic Particles. In 1913, the English physicist, Henty Moseley observed regularities in the characteristic X-ray spectra of the elements. A plot of v (wherevis frequency of X-rays emitted) against atomic number (2) gave a straight line and not the plot of V vs atomic mass. He thereby showed that the atomic number is a more funda- mental property of an element than its atomic mass. Mendeleev's Periodic Law was, therefore, accordingly modified. This is known as the Modern Periodic Law and can be stated as: The physical and chemical properties of the elements are periodic functions of their atomic numbers. Numerous forms of Periodic Table have been devised from time to time. Some forms emphasise chemical reactions and valence, whereas others stress the electronic configuration of elements. A modem version, the so-called "long form" of the Periodic Table of the elements, is. the most convenient and widely used. The horizontal rows (which Mendeleev called series) are called periods and the vertical columns, groups. Elements having simi- lar outer electronic configurations in their atoms are arranged in vertical columns, referred to as groups or families. According to the recommendation of Interna- tional Union of Pure and Applied Chemistry (IUPAC), the groups are numbered from 1 to 18 replacing the older notation of groups IA... VIIA, VIII, IB... VIIB and O. There are altogether seven periods. The period number corresponds to the high- est principal quantum number (n) of the elements in the period. The first period contains 2 elements. The subsequent periods consists of 8, 8, 18, 18 and 32 elements, respectively. The seventh period is incomplete and like the sixth period would have a theoretical maximum (on the basis of quantum numbers) of 32 ele- ments. In this form of the Periodic Table, 14 elements of both sixth and seventh periods (lanthanoids and actinoids, respectively) are placed in separate panels at the bottom. the IUPAC has made recommendation that until a new element's | discovery is proved, and its name is officially recognised, a systematic nomencla- ture be derived directly from the atomic number of the element using the numeri- cal roots for 0 and numbers 1-9. The roots are put together in order of digits which make up the atomic number and "ium" is added at the end.Groupwise ElectronicPk 1) 2) 3) 4) 5) tical column or group have similar va. Jements in the same vel me number of electrons in the outer figurations, the sai theoretical fou! Jumn of the Pel Configurations El lence shell electronic cont orbitals, and similar properties. tion. The elements in a vertical col family and exhibit similar chemical behaviour. This ye the same number and same distributio ndation for the periodic classifica- riodic Table constitute a group or similarity arises because these n of electrons in their outer- .cks viz., s-block, p-block, als that are being filled elements ha\ most orbitals. We can classify the elements into four blo diblock and f-block depending on the type of atomic orbit with electrons. Two exceptions to this categorisation. Str .er group 18 elements is tly, helium belongs to the s-block but its positioning in the p-block along with oth justified because it has a completely filed valence shell (1s) and as a result, exhib- its properties characteristic of other noble gases. The other exception is hydrogen. Ithas only one s-electron and hence can be placed in group 1 (alkali metals). It can also gain an electron to achieve a noble gas arrangement and hence it can behave similar to a group 17 (halogen family) elements. Because it is a special case, we shall place hydrogen separately at the top of the Periodic Table. In 1913, the English physicist, ....observed regularities in the characteristic X-ray spectra of the elements. a) Johann Dobereiner b) John Alexander Newlands ©) Demitri Mendeleev d) Henry Moseley Horizontal row in periodic table called .... a) Group b) Period ©) Triad d) Octave Vertical Column in periodic table called ... a) Group b) Period c) Triad qd) Octave According to Modern Periodic Law the physical and chemical properties of the elements are periodic functions of their... a) Atomic mass b) Atomic numbers ¢) — Atomic structure d) Atomic size What is IUPAC name of element having atomic number 107. a) —_Unnilpentium b) —Unnithexium : ©) Unnilseptium 4) Unniloctiumchains (branches) are called alkyl groups. For example: (@)CH,-GH-CH,-cH, CH, () CH,-CH-CH,-CH- cH, \ CHCH, CH, 'n order to name such compounds, the names of alkyl groups are prefixed to the name of parent alkane. An alkyl group is derived from a saturated hydrocarbon by remov- ing a hydrogen atom from carbon. Thus, CH, becomes - CH, and is called methyl group. For Nomenclature of branched chain alkanes, longest carbon chain in the molecule is identified. The numbering is done in such a way that the branched carbon atoms get the lowest possible numbers. lower number is given to the one coming first in the alphabetical listing. Carbon atom of the branch that attaches to the root alkane. in alphabetical order, the prefixes iso- and neo- are considered to be the part of the fundamental name of alkyl group. The prefixes sec- and tert- are not considered to be the part of the fundamental name. Cyclic Compounds: A saturated monocyclic compound is named by prefixing ‘cyclo! to the corresponding straight chain alkane. If side chains are present, then the rules given above are applied. Names of some cyclic compounds are given below. oO Cyclopentane More branched carbon gets lower number For Nomenclature of branched chain alkanes, longest carbon chain in the molecule Alphabetical order ~ of numbering is identified. The numbering is done in such a way that the branched carbon atoms get the lowest possible numbers. lower number is given to the one coming first in the alphabetical listing. Carbon atom of the branch that attaches to the root alkane. in alphabetical order, the prefixes iso- and neo- are considered to be the part of the fundamental name of alkyl group. The prefixes sec- and tert- are not considered to be the part of the fundamental name,me molecular formula but different struc pound having the sa ular formula but N Structural Isomerism - Com ture are classified as - / have similar molec two or more compounds i enon Is e-are referred to as chal enom represe! in isomers and the ph nts three compounds : iffer in the position of S called position isomer ple, the molecular formula Chain isomerism : When different carbon skeletons, thes example, C,H,» compounds di ubstitu- sand termed as chain isomerism. Fo! n two or more (ji) Position isomerism : Whe! bon skeleton, they are ent atom or functional group on the car this phenomenon is termed as position isomerism. For exami ,H,0 represents two alcohols = CH, CH, CH,OH CH,- CH- CH, Prop - 1- ol OH Prop -2- ol re compounds having the same ii) | Functional group isomerism : Two or mol lied functional isomers and this molecular formula but different functional groups are cal phenomenon is termed as functional group isomerism. For example, the molecular for- mula C,H,O represents an aldehyde and a ketone: ° ° j I H3zC7 CHs CH3;——CH,—C——H Propanal Propanone Metamerism : It arises due to different alkyl chains on either side of the functional group in the molecule. For example, C,H,,0 represents methoxy propane (CH,OC,H,) and ethoxyethane (C,H,OC,H,)- ds that have the same constitution and sequence iv) Stereoisomerism The compounc of covalent bonds but differ in relative positions of their atoms or groups in space ai re called stereoisomers. This special type of isomerism is called as stereoisomerism and can be classified as geometrical and optical isomerism. Substrate and Reagent lons are generally not formed in the reactions of organi compounds. Molecules as such participate in the reaction. It is convenient to nai sone reagent as substrate and other as reagent. In general, a molecule whose carb — volved in new bond formation is called substrate and the other one is call 4 reagent When carbon-carbon bond is formed, the choice of naming the reactants sunctats and reagent is arbitrary and depends on molecule under observation. — seeteane i) CH, =CH,+Br, ——— > __ CH,Br- CH,Br ‘ii) McQ 1) 2) 3) 4) 5) 34) 35) cn, *CHcl ——> Hi +Hel CH, becomes - CH. is called... group ° . ) methyl gy ethyl ©) propyl For the Nomenclature of br qd) buty! fanched chain alkanes molecule is identified, carbon chain in the 8) shortest by ©) smallest none of above 8) Allotropes by Isotopes, ©) Isomers dy For the Nomenclature of branched chain alkans Isobars 1es,the numbering is done in Such a way that the branched carbon atoms getthe .. a) biggest b) Lower Possible numbers, °) Highest a) lowest ‘Which of the following is not an example of isomerisim ? a) Functional b) Positional ©) Chain d) Preconditional Section -E 3x5=15, This section consist of 3 long question carrying 5M each. An organic compound on analysis gave the following data - Carbon = 57. 82%, Hydrogen = 3.6%., rest is oxygen. Its vapour density = 83. Find empirical no and mole cularformula. = Cutz, 2 Cy, 0, Define the term - a) Inductive effect _b) Hyperconjugation c) _ Resonance effect or Calculate the estimation of Nitrogen with the help of Duma’s Method. Describe the Bohr's model of Hydrogen latom, wit limitation. or What is Quantum number ? Explain all its with suitable example ?