RANA ACADEMY PHY.
MATH, BIO
SET TEST : SOLUTIONS
1 Dated : 23/10/2023 XII 2023 JOGINDER RANA : 8529706464
Time : 1 Hour] [Maximum Marks: 20
1. To increase the solubility of CO2 gas in soft drinks, the bottle is sealed under 1
(a) Low Pressure (b) High temperature
(c) Constant Pressure (d) High Pressure
2. Which of the following formula represents Raoult's law for a solution containing 1
non-volatile solute?
o
(a) Psolute = Psolute . Xsolute (b) p = K H.X
(c) PTotal = Psolvent (d) Psolute = posolvent .Xsolvent
3. Assertion : The pressure exerted by the vapour in equilibrium with a liquid at a given 1
temperature is called its vapour pressure.
Reason : If a non-volatile solute is added to a solvent to give a solution, the vapour pressure
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of the solution is found to be greater than the vapour pressure of the pure solvent.
4. Explain Henry's law about dissolution of a gas in a liquid. 2
5. State Raoult's law for a solution containing volatile components. What is the similarity 2
between Raoult's law and Henry's law?
6. Define Van't Hoff factor. 2
7. Define Osmotic pressure. 2
8. Determine the osmotic pressure of a solution prepared by dissolving 2.32x10-2g of K2SO4 3
2L of solution at 25oC, assuming that K2SO4 is completely dissociated.
(R=0.082 L atm K-1 mol-1 Molar mass K2SO4 = 174g mol-1)
9. 2g of benzoic (C6H5COOH) dissolved in 25g of benzene shows a depression constant for 3
benzene is 4.9 K kg mol-1. What is the percentage association of acid if it forms dimer in
solution
10. A 5% solution (by mass) of cane-sugar in water has freezing point of 271 K. Calculate the 3
freezing point of 5% solution (by mass) of glucose in water if the freezing point of pure water is
273.15K. [Molecular masses : Glucose C6H12O6 : 180 amu; Cane-sugar C12H22O11:3.42 amu]
BRANCHES : KARNAL | KURUKSHETRA | MUZAFFARNAGAR ADD. : #7/14, U.E. KARNAL (8529706464)
RANA ACADEMY PHY. MATH, BIO
SET TEST : SOLUTIONS
2 Dated : 23/10/2023 XII 2023 JOGINDER RANA : 8529706464
Time : 1 Hour] [Maximum Marks: 20
1. An azeotropic solution of two liquids has a boiling point lower than either of the two when it. 1
(a) Shows a positive deviation from Raoult's law
(b) Shows a negative deviation from Raoult's law.
(c) Shows no deviation from Raoult's law.
(d) is saturated
2. Generally solubility of one substance into another substance depends on 1
(a) The nature of substance (b) Temperature
(c) Pressure (d) All of these
1
3. Assertion : Sodium chloride used to clear snow on the roads.
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Reason : Soduium chloride depresses the freezing point of water.
4. Some liquids on mixing form 'azeotropes'. What are 'azeotropes'? 2
5. Write two characteristics of non-ideal solution. 2
6. Define Abnormal molar mass. 2
7. Define Osmotic pressure. 2
8. 1.00 g of a non-electrolyte solute dissolved in 50g of benzene lowered the freezing point 3
of benzene by 0.40 K. The freezing point depression constant of benzene is 5.12 K kg mol-1.
Find the molar mass of the solute.
9. Calculate the freezing point of a solution containing 60g of glucose (Molar mass = 180g 3
mol-1) in 250g of water. (Kf of water = 1.86 K kg mol-1)
o
10. A 0.01 m aqueous solution of A1C13 freezes at -0.068 C. Calculate the percentage of 3
dissociation. [Given : Kf for water = 1.86 K kg mol-1]
BRANCHES : KARNAL | KURUKSHETRA | MUZAFFARNAGAR ADD. : #7/14, U.E. KARNAL (8529706464)
RANA ACADEMY PHY. MATH, BIO
SET TEST : SOLUTIONS
3 Dated : 23/10/2023 XII 2023 JOGINDER RANA : 8529706464
Time : 1 Hour] [Maximum Marks: 20
1. For which of the following solutions Hmix and Vmix is negative? 1
(a) Acetone and aniline
(b) Ethyl alcohol and cyclohexane
(c) Acetone and CS2
(d) Benzene and toluene
2. Van't Hoff factor (i) for complete dissociation of K2SO4 will be. 1
(a) 7 (b) 1
(c) 2 (d) 3
3. Assertion : Osmotic pressure is a colligative property. 1
Reason : Osmotic pressure depends only on the number of particles dissolved in solution.
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4. Define Raoult's law. 2
5. Define Ideal solution. 2
6. Define Abnormal molar mass. 2
7. Define Colligative Properties. 2
8. Calculate the boiling point elevation for a solution prepared by adding 10g of CaC12 to 3
200g of water, (Kb for water = 0.52 K kg mol-1, molar mass of CaC12=111g mol-1)
9. A 10% solution (by mass) of sucrose in water has freezing point of 269.15 K. Calculate the 3
freezing point of 10% glucose in water, if freezing point of pure water is 273.15K.
(Given : Molar mass of sucrose = 342g mol-1, molar mass of glucose = 180g mol-1)
10. A 4% solution (w/w) of sucrose (M=342g mol-1) in water has a freezing point of 271.15K. 3
Calculate the freezing point of 5% glucose (M=180g mol-1) in water.
(Given: Freezing point of pure water = 273.15K)
BRANCHES : KARNAL | KURUKSHETRA | MUZAFFARNAGAR ADD. : #7/14, U.E. KARNAL (8529706464)
RANA ACADEMY PHY. MATH, BIO
SET TEST : SOLUTIONS
4 Dated : 23/10/2023 XII 2023 JOGINDER RANA : 8529706464
Time : 1 Hour] [Maximum Marks: 20
1. Which of the following solutions shows positive deviation from Raoult's law? 1
(a) Acetone + Aniline
(b) Acetone + Ethanol
(c) Water + Nitric acid
(d) Chloroform + Benzene
2. Van't Hoff factor is defined as the ration of 1
(a) Calculated colligative property to observed colligative property
(b) Normal molar mass to experimentally determined molar mass.
(c) Cryoscopic constant to Ebullioscopic constant
(d) Molar depression constant to molal elevation constant.
3. Assertion : Dilute Solution of Benzene and toluene is an ideal solution. 1
Reason : Benzene and toluene form H-bonding with each other.
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4. What is meant by negative deviation from Raoult's law? Give an example. What is the sign 2
of mix H for negative deviation?
5. What is meant by positive deviation from Raoult's law? Give an example. What is the sigh 2
of mix H for positive deviation?
6. What type of values cant it have if in forming the solution the solute molecular undergo 2
(i) dissociation (ii) association
7. Define the following term : Molality (m) 2
8. Some ethylene glycol, HOCH2CH2OH, is added to your car's cooling system along with 3
5kg of water. If the freezing point of water-glycol solution is -15.0oC, what is the boiling
point of the solution?
9. 2 g of benzoic (C6H5COOH) dissolved in 25 g of benzene shows a depression constant for 3
benzene is 4.9 K kg mol-1. What is the percentage association of acid if it forms dimer in
solution
10. Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 3
2 litres of water at 25oC assuming it to be completely dissociated.
(Atomic masses K = 39 u, S = 32 u, O = 16 u)
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