s shaving odd num bey Op Curwaki | double bond exhibit — See dhpomesi Dmg Explain iting proper viea pon: - —___obhicat igor 2191 ‘and _qeomediicat ior exigan anit due to the dibserent pati asviangemend > at atome cal tory Lea din, 0. dipte | 0 grouby —axound a —_Cent end gical propediey>Quch_ap_ophc activityTT ee_ci exert pimtic Dhabey:+ “the chipatincdion bh elt Loith_an_even number ay Curpulative ~ be_bon dor ecchibiling oplical_o “ igomexy on hope tah on 0dd_ ater ese hibilin masa hlained a9... ey Mical_iguombsigan —in_ compounds nih Eien Gumi : __ tive Douhte bond }o:— ee eee ' eat ae E _simfevoy image % af ach other: £ (Ee a eee i | dial dor dhe.) Semation Oh enantiomexsa: ame det uh _ vem Ay alkenegs (CHa =C=cH2) exhibit obtical idan 4 \ 4 4 (go pH LA = oN l eae pS M cole NT NS cous. — KK aSr| =F _____ ID TV cyeomeduical Tqomerxigon in Combaund> saith odd c i “|__ Double_Bond &— ______ ; atound the double bond “but Cannot he tnteyconverted | catthouk beteaking the X-bond- ! H CHS w H3c cus ——_lratersnoteculan chy ggen_bondy eg a . |_& tell _dedined bande. a Algo, inlermate citar H-bondg axe. con® debendenis & inlenPritied aj puch band ig decrease & Jina py —disoah berg em "| dil” tohevea% inlemoleculat H=bendi |Ad Oymemeduic giveching oe -Ch2 af_inedl og bendi “7 O. f : Libole moment. o=C=0° O=C=0 O=C=o Add ummetrical ; wBrechina ARRume Hic: Bending (re Active) (TR active) 24t Caleulate dhe mbe ational mode vin @ NHs_ @) (Co2 © Heo @” Benzene dn Linea matecule —— Nib = Sn-5 dn_non-lineay moleate—» Vib= 3n-6 @. wwe H —N=H Non= linea’ motecule H n= 4 (No: of atom) Nib= 3n-6 7SXI-E7 12-636 Sp eee Se a esa Upson y 8x3-57?Q4 - _© | 20> +H Non = len aNib= 3n-6 7 BxXl2-6 ¥ 36-67 Bo G12 shih Of, the bole ing peu lel do mot Dhow my nuclear _t metic wemonance Wy 2H, 12 24 ie ISE, 81D _— ia : WITH _mampno=ilodd) , Atomic nox 4 lodd) SrO | NMR (qhou) id FH -mageannze leven), A-Na=4lodd) 270 » NMR (Dhow) cid} Pe Mamono= 12 (even), A-wn=6(even) S=0 donot _ Dhow NMR- (| o- Mago no=16leven),.A-no= 8 (even) | Domot Joho NMR yy | NN = mages oz id leven ‘No = 4 (odd) S7© Neto wil PF = mags nozislodd) ,Anioz 9lodd) S70 NMR(ghow wid} SP mamH no=z 3tlodd) , [Link]= 15lodd) S70 NMR Lphe Qua |lcohy TMS in uped a9 An inkernal. / | v D } molecule” Vibrations in the teckmaique and _cwite icohi j > Tals ured Dbechagnenbu \ g when energy sion | Vibyaltongs inact a the maleculeg,- I eal a cid Mica ty, italian CER tae iatigd ne | Nasi a9 "Mote Culay Vibration — pee teen Pug awes ie two yh i ental _ gan Oe ———4 I ao Nibtabion ~ 2s nodin FA Mibvalion —| | ii | gaivechiv \ibvadion*—= Tn dhi%——y b i \libon athe ‘pad digiance lw im labo h N or but atom in _dhe- [Link] ction} (Fame bond _ | _a.caiga) 7. dynein oe e-ching Abt fom ~-———when_he moves Tnent oh, alors wish vegopect to a _Cenk-tal atem id She mame direction Js id Called 0% Qsurmme — tical rivechin: — Nile di) anti- oy eo mmehs Ma outa Ching itowal fen __ti_ When ene “atom abboroaches dhe _cendval atom but other _____-dehendp I[depau toy pom ik dinti= Qysnmedsical dre chi Nibsation— ns ann edi Cah on Ainti=tynmediic aye od —___ddreChins oo Saran Vibyalion: g in. “dhign Ay bea}, Nibyationgs | Three th tem aingo Same ~ doe dhe podition. atom “Change relative do dhe aruginat bend _ ee Tamin d-e ~ band anagteys chan eg ben ding Ucbrat. lon arte, Called dé&hoy mation ~ vibyation co = a Os, te guire Le da% energy vin ompautten beeing Ni by ationfo- —eel mn gue tat qatdigorh. SiRe \ibvadion a i Tos ee O dan odtnatn -alipacaich each other. eee ee oe ao i AT gana cat 71 i i chen ~the_rnavessent_of ators talked plac a in_Saxme_dixection. cid) Pye < Racking Teniating 2. —— One_atom move ub Jo dhe_ lens cod— snovep down +o the ptane= 1 1o} Oo = i + = = _ _ 1 Tuniphing _ ae ivy a oe go_mmove_up-and. down othe pil he —Cerbal atom.nnd Eno in Boocri? .weaien® abbeas bud if tn U, mate cites ate preqent A% Ligand Od Comdtimales mn aie tith medal ion , then —o bond abpeaus B8n cuit Jo 650 Crit esinnd. @®_ Determination ch jexce g cenGiont: — Bu udine Jelormined ohich io clam doxte Congtant Can b meahuuie HHL Imen ge 0) a bond ©) Tdenbitication’al JUPactional” ax aubey v Dv C= Diljevent Jess | emal_gicubss absorb at Chasaclerio:?& = yu sin W Sabectiusn These} fe spec xf oe Compound , dhe bregrence oy ahGens Certain a ep im the Compound id identi: [ie ae 2 © tents otion ak a ometrical id meng - 4 C iG iors _Dhawh Mdreching abSesbtion due +o Clans é sin dipote momen? white dranh deed not. U © | Dratrantion blo vinta and inteymolerutay hudvesm _ bendéng 2 == CaS I InjermoleCutay H- hend® Hhas broad | bond and ave concentration dependent echtrea®— “dinteramaleculon H - bon dg Shows Shoup amd | antenge bondp and thes ae conc ton singe be: | dents- " lr, | i re J I 5 eee a : , Pond % , dak i we ppeati_tohile hat due | “Qua_what i hi ebdi nd_dephielding cin NMS beer P ! Socoha C TF anye J the Jattouaing een cn aids i ile qobectzn a : Ms uo) (alka S519 (un, as 5 (2-45) (eH); 8 (SH) Gurring seahang camgaige the Gobuchuned Jos — p+ | phielding:— seater the electy i f Lhe muctueg the be Pha ict teld ence the arr _ | 40 dhe. Blectyonq “cand bh casey ghildi I tod ik i = ——fectltish Menonrnce scaiqing she chealal' enfin f wer ppm) Y . pant 7 é the Centre of the “atom ave ca drawn _—den nity [Link] cra he _obboming ma clic Sil d_Bo_gelo— “and ‘he ni 7 {lamoad of dhe Rocdem: l paedic_field- qu ec ony tie pao co a pee oo (oe i _ es ll a{Dove [ see = - wahak cote pal yaner 2s? 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Cy09%- tinked S—= Choind ove intexconne cded to roma ——__N€éhooxrk phuctuy a — 8G Nalounized rubber, Ba kettte - — A-A-A-f-pR-An 0-8 A-B=A-Bx5 as V 3 Ahonen A=B=A=BeA-B—3 - A i? i ee : - . | - So ae - so A-A- fi peas : AB a C0 linked A BA BAB Ty Hino gn ft — ee a —~Ce20 what ave conducti wonile che ala deri picabion and abphication Bh Conducting poljmex ° = — 0 ¥003froinked to=palymer.t @ iy Cae ting polymers Thege bolumert trove D Ltd phice : pact con quaation in the backbone hich wedbonribte OG conduchance. a Conducting} bo lumex Sp having Conjusated Keon back mes 5 7 P “backbone tohich | Cowiuaated Ke over she entive backbene ae fq Jin Yhe toy mation o} Volume Pualence band ao | NefseQente d bg kp _jumb “ the gabe sf Duf piGien® enexd 4 3 y into loner ASW) of condition Chandos | ea a : i mm CHECH : f —> AG \ 4 | Acetulene me . | g 2 — —-_- ——-__--|-_ ~palyacesulene —___- | i q | ng N 7 a | N ! ay 1 N ea we) YEDob i ee nut p Conjugated 7 87 Gr backbone Can be! 6: 2 o9 cn. nq Loni as) i I g b pense baSebone bro Ecodttyn, Cialis Con duahi @ Abe a owe nally added Ln gvedienty sin_dhera Condicdive Element piled pabyenert— \ Polumer acd ad, ——j--the binder Jo chald dhe condur ing & ike 7 fitex to__be added %o Jhat thMeghald - : : Chiack, metalic -fpibex to ete. dofedhex in Doalid | entity. 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CHo=CH7 tee CH —CHs CHS°CH ~ CHa~CHe th. ress cH=CH=CHa] | bat J metpation oS | | fon_of _tycen@ Rubber Can _be_done. bing. ulphwero-r by soul phus mono. htoxide [Aisccatam: — iz = eetananieect ore ba + BON A_NS— (Nitvile N'Rubber)-— SS re = -—Casipek basking, a apkedg, Adhemi b in ag wr aybten. eee ie=cHe +n CiecHe CHa-CH=CH ~CHa-cl = CN. = EN _ 205) ~cHe4 es oO. Liimin; af lo ket_© yack “Bay eo OS © Voit. wteqigtance Poamed. OD. Auovnchs patie Shige ab ablibide as Cxajt” at ai @.Adh pee —— I : ster 6.62 J4 ig made by— “conden pation od palyonend _—|_Y abion_a}, shescametytene—diaamine fy main acid | in £4 malay .tabio. — —___ EE | Han —(CHe)g~NH2 + n Hooc—(cHa)y=CooH __ Hescamethylene Adipic acid : Diamine eemuied) SSS | "4 telat =§ paleo H = ny 646 ~ / 7 - _ | A bb tiation’ — — _ - | O_Nylon—6. euped tr phere. “umed in | [Link] tng ock M5. -