Safety Data Sheet

according to Regulation (EC) No 1907/2006

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

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1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Washing and cleaning products (including solvent based products)
Process categories [PROC]: 11
1.3. Details of the supplier of the safety data sheet
Company name: BUZIL-WERK Wagner GmbH & Co. KG
Street: Fraunhofer Str. 17
Place: D-87700 Memmingen
Telephone: +49 (0) 8331 930-6 Telefax: +49 (0) 8331 930-880
e-mail: [email protected]
Internet: www.buzil.com
1.4. Emergency telephone +49 (0) 8331 / 930-730
number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Regulation (EC) No. 1272/2008
Hazard categories:
Flammable liquid: Flam. Liq. 3
Serious eye damage/eye irritation: Eye Irrit. 2
Hazardous to the aquatic environment: Aquatic Chronic 3
Hazard Statements:
Flammable liquid and vapour.
Causes serious eye irritation.
Harmful to aquatic life with long lasting effects.
2.2. Label elements
Regulation (EC) No. 1272/2008
Signal word: Warning

Pictograms:

Hazard statements
H226 Flammable liquid and vapour.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.

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Special labelling of certain mixtures

EUH208 Contains Limonene. May produce an allergic reaction.
2.3. Other hazards
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
The inhalation of dust/mist or aerosols causes irritation of the respiratory tract.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
64-17-5 ethanol 30 - < 35 %
200-578-6 603-002-00-5 01-2119457610-43
Flam. Liq. 2, Eye Irrit. 2; H225 H319
111-76-2 2-butoxyethanol, butyl cellosolve, ethylene glycol monobutyl ether 1-<5%
203-905-0 603-014-00-0 01-2119475108-36
Acute Tox. 4, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2; H302 H312 H332 H315 H319
122-99-6 2-phenoxyethanol 1-<5%
204-589-7 603-098-00-9 01-2119488943-21
Acute Tox. 4, Eye Irrit. 2; H302 H319
25307-17-9 fatty amine polyethoxilate <1 %
246-807-3 01-2119510876-35
Acute Tox. 4, Skin Corr. 1B, Aquatic Acute 1 (M-Factor = 10), Aquatic Chronic 1 (M-Factor = 1);
H302 H314 H400 H410
5989-27-5 (R)-p-mentha-1,8-diene, d-limonene <1 %
227-813-5 601-029-00-7 01-2119529223-47
Flam. Liq. 3, Skin Irrit. 2, Skin Sens. 1, Asp. Tox. 1, Aquatic Acute 1 (M-Factor = 1), Aquatic
Chronic 1 (M-Factor = 1); H226 H315 H317 H304 H400 H410
Full text of H and EUH statements: see section 16.
Labelling for contents according to Regulation (EC) No 648/2004
< 5 % non-ionic surfactants, perfumes (Limonene).

SECTION 4: First aid measures

4.1. Description of first aid measures
After inhalation
Provide fresh air.
After contact with skin
After contact with skin, wash immediately with plenty of water and soap.
Take off contaminated clothing and wash it before reuse .
After contact with eyes
Rinse immediately carefully and thoroughly with eye-bath or water.
After ingestion
Rinse mouth immediately and drink plenty of water.
Do NOT induce vomiting.
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4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Water spray jet
alcohol resistant foam
Carbon dioxide
Extinguishing powder
Unsuitable extinguishing media
High power water jet
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products:
Carbon dioxide
Carbon monoxide
5.3. Advice for firefighters
Emergency cooling must be provided for in case of a fire in the vicinity.
Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Use personal protection equipment.
Avoid contact with skin, eyes and clothes.
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
Do not allow to enter into soil/subsoil.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal .
6.4. Reference to other sections
Personal protection equipment: see section 8
Disposal: see section 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Avoid contact with skin, eyes and clothes.
Do not mix with other chemicals.
Use personal protection equipment.
When using do not eat, drink or smoke.
Do not breathe gas/fumes/vapour/spray.
Use only in well-ventilated areas.

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Advice on protection against fire and explosion

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed.
Advice on storage compatibility
No special measures are necessary.
7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

111-76-2 2-Butoxyethanol 25 123 TWA (8 h) WEL

50 246 STEL (15 min) WEL
64-17-5 Ethanol 1000 1920 TWA (8 h) WEL
- - STEL (15 min) WEL

Biological Monitoring Guidance Values (EH40)

CAS No Substance Parameter Value Test material Sampling time

111-76-2 2-Butoxyethanol butoxyacetic acid 240 urine Post shift

mmol/mol

DNEL/DMEL values

CAS No Substance
DNEL type Exposure route Effect Value
25307-17-9 fatty amine polyethoxilate
Worker DNEL, long-term inhalation systemic 1,76 mg/m³
Worker DNEL, long-term dermal systemic 0,25 mg/kg
bw/day
Consumer DNEL, long-term inhalation systemic 0,621 mg/m³
Consumer DNEL, long-term oral systemic 0,179 mg/kg
bw/day
Consumer DNEL, long-term dermal systemic 0,179 mg/kg
bw/day

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PNEC values
CAS No Substance
Environmental compartment Value
25307-17-9 fatty amine polyethoxilate
Freshwater 0,000214 mg/l
Marine water 0,0000214 mg/l
Marine sediment 0,0171 mg/kg
Micro-organisms in sewage treatment plants (STP) 1,5 mg/kg
Soil 5 mg/kg
Secondary poisoning 2 mg/kg

8.2. Exposure controls

Protective and hygiene measures
Take off contaminated clothing.
Wash hands before breaks and after work.
When using do not eat, drink or smoke.
Eye/face protection
Wear eye/face protection. (EN 166)
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four
control digits.
Suitable material: NBR (Nitrile rubber).
Breakthrough time (maximum wearing time) >480 min.
A survey of suitable brands with detailed information on breakthrough times is available upon request .
Skin protection
Wear suitable work clothing.
Respiratory protection
If extensively sprayed or used with high pressure equipment: combination filter A1/P2 (EN 143, EN 14387).
Use only in well-ventilated areas.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: liquid
Colour:
Odour: Perfumes, fragrances
Test method
pH-Value (at 20 °C): 10,5 - 11,6
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: > 80 °C
Flash point: 24 °C
Flammability
Solid: not applicable
Gas: not applicable
Lower explosion limits: not determined
Upper explosion limits: not determined

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Auto-ignition temperature
Solid: not applicable
Gas: not applicable
Decomposition temperature: not determined
Oxidizing properties
Not oxidizing.
Vapour pressure: not determined
Density (at 25 °C): 0,94 g/cm³
Water solubility: miscible
Solubility in other solvents
not determined
Partition coefficient: not determined
Viscosity / dynamic: < 10 mPa·s
(at 25 °C)
Vapour density: not determined
Evaporation rate: not determined
9.2. Other information
Solid content: not determined

SECTION 10: Stability and reactivity

10.1. Reactivity
No hazardous reaction when handled and stored according to provisions.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions
No hazardous reaction when handled and stored according to provisions.
10.4. Conditions to avoid
The product is stable under storage at normal ambient temperatures.
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
No known hazardous decomposition products.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.

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CAS No Chemical name

Exposure route Dose Species Source
64-17-5 ethanol
oral LD50 >2000 mg/kg Rat ATE
dermal LD50 >2000 mg/kg Rat ATE
inhalative vapour LC50 >20 mg/l Rat ATE
111-76-2 2-butoxyethanol, butyl cellosolve, ethylene glycol monobutyl ether
oral LD50 1746 mg/kg Rat
dermal LD50 2275 mg/kg Rat
inhalative vapour LC50 >20 mg/l Rat ATE
inhalative aerosol ATE 1,5 mg/l
122-99-6 2-phenoxyethanol
oral LD50 1850 mg/kg Rat
dermal LD50 >2000 mg/kg Rabbit
25307-17-9 fatty amine polyethoxilate
oral LD50 1260 mg/kg Rat OECD 401
dermal LD50 >2000 mg/kg Rat ATE
inhalative aerosol LC50 >5 mg/l Rat ATE
5989-27-5 (R)-p-mentha-1,8-diene, d-limonene
oral LD50 4400 mg/kg Rat GESTIS
dermal LD50 > 5000 mg/kg Rabbit GESTIS

Irritation and corrosivity

Causes serious eye irritation.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1. Toxicity

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CAS No Chemical name

Aquatic toxicity Dose [h] | [d] Species Source
64-17-5 ethanol
Acute fish toxicity LC50 >1000 mg/l 96 h
Acute algae toxicity ErC50 >100 mg/l
Acute crustacea toxicity EC50 >1000 mg/l 48 h
111-76-2 2-butoxyethanol, butyl cellosolve, ethylene glycol monobutyl ether
Acute fish toxicity LC50 1474 mg/l 96 h Oncorhynchus mykiss
(Rainbow trout)
Acute algae toxicity ErC50 911 mg/l 72 h Pseudokirchneriella
subcapitata
Acute crustacea toxicity EC50 1550 mg/l 48 h Daphnia magna (Big water
flea)
122-99-6 2-phenoxyethanol
Acute fish toxicity LC50 220 - 460 96 h Leuciscus idus (golden
mg/l orfe)
Acute algae toxicity ErC50 > 500 mg/l 72 h Scenedesmus subspicatus
Acute crustacea toxicity EC50 > 500 mg/l 48 h Daphnia magna (Big water
flea)
25307-17-9 fatty amine polyethoxilate
Acute fish toxicity LC50 0,1 mg/l 96 h Brachydanio rerio OECD 203
(zebra-fish)
Acute algae toxicity ErC50 0,0867 mg/l 72 h OECD 201
Acute crustacea toxicity EC50 0,043 mg/l 48 h Daphnia magna (Big water OECD 202
flea)
Acute bacteria toxicity (128 mg/l) 3 h Activated sludge OECD 209
5989-27-5 (R)-p-mentha-1,8-diene, d-limonene
Acute fish toxicity LC50 18 mg/l 96 h GESTIS
Acute crustacea toxicity EC50 17 mg/l 48 h GESTIS

12.2. Persistence and degradability

The surfactants contained in this preparation comply with the biodegradability criteria as laid down in
Regulation (EC) No.648/2004 on detergents.

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CAS No Chemical name

Method Value d Source
Evaluation
64-17-5 ethanol
OECD 301 >60% 28
Readily biodegradable (according to OECD criteria).
111-76-2 2-butoxyethanol, butyl cellosolve, ethylene glycol monobutyl ether
OECD 301 >60% 28
Readily biodegradable (according to OECD criteria).
122-99-6 2-phenoxyethanol
OECD 301 >60% 28
Readily biodegradable (according to OECD criteria).
25307-17-9 fatty amine polyethoxilate
OECD 301B/ ISO 9439/ EEC 92/69/V, C.4-C >60% 28
Readily biodegradable (according to OECD criteria).
5989-27-5 (R)-p-mentha-1,8-diene, d-limonene
OECD 301 <60% 28
Not readily biodegradable (according to OECD criteria)

12.3. Bioaccumulative potential

No indication of bioaccumulation potential.
Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
111-76-2 2-butoxyethanol, butyl cellosolve, ethylene glycol monobutyl ether 0,81
122-99-6 2-phenoxyethanol 1,16
25307-17-9 fatty amine polyethoxilate 3,4
5989-27-5 (R)-p-mentha-1,8-diene, d-limonene 4,23

BCF
CAS No Chemical name BCF Species Source
25307-17-9 fatty amine polyethoxilate 23,4

12.4. Mobility in soil

The product has not been tested.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Advice on disposal
Dispose of waste according to applicable legislation.
Delivery to an approved waste disposal company.
Waste disposal number of waste from residues/unused products
070604 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease,
soaps, detergents, disinfectants and cosmetics; other organic solvents, washing liquids and mother
liquors
Classified as hazardous waste.

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Waste disposal number of contaminated packaging

150102 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); plastic packaging
Contaminated packaging
Delivery to an approved waste disposal company.

SECTION 14: Transport information

Land transport (ADR/RID)
14.1. UN number: UN 1170
14.2. UN proper shipping name: ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Classification code: F1
Special Provisions: 144 601
Limited quantity: 5L
Transport category: 3
Hazard No: 30
Tunnel restriction code: D/E
Inland waterways transport (ADN)
14.1. UN number: UN 1170
14.2. UN proper shipping name: ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Classification code: F1
Special Provisions: 144 601
Limited quantity: 5L
Marine transport (IMDG)
14.1. UN number: UN 1170
14.2. UN proper shipping name: ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Special Provisions: 144, 223
Limited quantity: 5L
EmS: F-E, S-D
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1170
14.2. UN proper shipping name: ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Special Provisions: A3 A58 A180
Limited quantity Passenger: 10 L
IATA-packing instructions - Passenger: 355

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IATA-max. quantity - Passenger: 60 L

IATA-packing instructions - Cargo: 366
IATA-max. quantity - Cargo: 220 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
Warning: Combustible liquids.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2010/75/EU (VOC): 45 %
Additional information
Regulation (EC) No. 648/2004 (Detergents regulation)
National regulatory information
Water contaminating class (D): 1 - slightly water contaminating
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes
SECTION 2: Hazards identification
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road )
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service
LC50: Lethal concentration, 50%
LD50: Lethal dose, 50%

Process categories according to ECHA guidance on information requirements and chemical safety
assessment, chapter R.12:
PROC 1: Use in closed processes.
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
PROC 8 (Transfer): Dilution of concentrated products, application of drain cleaners, dosage of textile washing
agents.
PROC 10 (Roller application or brushing): Processing without large-scale spraying.
PROC 11 (Spraying outside industrial settings): Processing with large-scale spraying (e. g. high pressure
cleaning, foam gun).
PROC 13: Treatment of articles by dipping and pouring
PROC 19 (Hand-mixing with intimate contact): Hand cleaning and disinfection.

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Relevant H and EUH statements (number and full text)

H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH208 Contains Limonene. May produce an allergic reaction.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

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