SIIT SPARK REVISION CHEMISTRY

S.R EDUCATIONAL ACADEMY

Telangana, Andhra Pradesh, Karnataka
SIIT SPARK REVISION CHEMISTRY ASSIGNMENT
TOPIC : Chemical Equilibrium

Q.01 PCl5 dissociation a closed container as :

PCl5(g) PCl3(g) + Cl2(g)
If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is , the
partial pressure of PCl3 will be :
    2       
(A) P ·   (B) P ·   (C) P ·   (D) P ·  
   1 1       1 1   
Q.02 For the reaction : 2Hl (g) H2(g) + I2(g), the degree of dissociated () of Hl(g) is related to equilibrium
constant KP by the expression

1 2 Kp 1  2K p 2K p 2 Kp
(A) (B) (C) 1  2K p (D) 1  2 K
2 2 p

Q.03 The equilibrium constant for the reaction

A(g) + 2B(g) C(g)
is 0.25 dm6mol–2. In a volume of 5 dm3, what amount of A must be mixed with 4 mol of B to yield 1
mol of C at equilibrium.
(A) 3 moles (B) 24 moles (C) 26 moles (D) None of these
Q.04 At total equilibrium pressure P1 atm and P2 atm, N2O4 is dissociated to an extent of 33.33% and
P1
50% respectively. Ratio of P will be
2

3 4 8 3
(A) (B) (C) (D)
8 3 3 4
Q.05 For the reaction in equilibrium
2NOBr(g) 2NO(g) + Br2(g)
if p Br2  P / 9 at equilibrium and P is the total pressure. The ratio KP/P is equal to-
1 1 1 1
(A) (B) (C) (D)
9 81 27 25
Q.06 A 20.0 litre vessel initially contains 0.50 mole each of H2 and I2 gases. These substances react and
finally reach an equilibrium condition. Calculate the equilibrium concentration of HI if Keq = 49 for the
reaction H2 + I2 2HI.
(A) 0.78 M (B) 0.039 M (C) 0.033 M (D) 0.021 M
Q.07 A vessel of 250 litre was filled with 0.01 mole of Sb2S3 and 0.01 mole of H2 to attain the equilibrium
at 440°C as Sb2S3 (s) + 3H2(g) 2Sb (s) + 3H2S (g).
After equilibrium the H2S formed was analysed by dissolving it in water and treating with excess of
Pb2+ to give 1.195 g of PbS (Molecular weight = 239) precipitate.
What is value of Kc of the reaction at 440°C?
(A) 1 (B) 2 (C) 4 (D) None of these
 SIIT SPARK REVISION CHEMISTRY

Q.08 The equilibrium constant for the reaction CO(g) + H2O(g) CO2(g) + H2(g) is 3 at 500 K. In
a 2 litre vessel 60 gm of water gas [equimolar mixture of CO(g) and H2(g)] and 90 gm of steam
is initially taken. What is the equilibrium concentration of H2(g) at equilibrium (mole/L)?
(A) 1.75 (B) 3.5 (C) 1.5 (D) 0.75
Q.09 At 87°C, the following equilibrium is established
H2(g) + S(s) H 2S (g) Kp = 7 × 10–2
If 0.50 mole of hydrogen and 1.0 mole of sulfur are heated to 87°C in 1.0 L vessel, what will be
the partial pressure of H2S at equilibrium?
(A) 0.966 atm (B) 1.38 atm (C) 0.0327 atm (D) 9.66 atm
Q.10 For the reaction at equilibrium :
A(g) + 2B(g) C(g)
Equilibrium constants as function of temperature are
K at 300°C 4 × 10–4
K at 450°C 4.5 × 10–5
K at 600°C 6 × 10–7
Then
(A) Reaction is exothermic.
(B) On adding D(g) at constant volume reaction will move towards right. [D(g) is non reactive
gas]
(C) Yield of reaction will increase on increasing temperature.
(D) Both (A) and (C)
Q.11 In which of the following reactions, increase in the pressure at constant temperature does not
affect the moles at equliibrium :
1
(A) 2NH3(g) N 2(g) + 3H2(g) (B) C(g) + O (g) CO(g)
2 2
1
(C) H2(g) + O (g) H 2O(g) (D) H2(g) + I2(g) 2HI(g)
2 2
Q.12 Which of the following change at equilibrium will shift reaction in backward direction :
Fe3+(aq) + SCN–(aq) Fe(SCN)2+(aq)
(A) Addition of water
(B) Addition of KOH(aq) [Fe(OH)3 is insoluble in water]
(C) Addition of NaNO3(s)
(D) (A) and (B) both
Q.13 For the following equilibrium in a closed rigid vessel.
A (g) B (g) + C (g)
D (g) E (g) + B (g)
If some E (g) is introduced into the vessel, then at the new equilibrium.
(A) [A] increases (B) [C] decreases (C) [A] decreases (D) [B] increases
Q.14 Densities of diamond and graphite are 3.5 and 2.3 gm/mL.
C (diamond) l C (graphite) rH = –1.9 kJ/mole
favourable conditions for formation of diamond are
(A) high pressure and low temperature (B) low pressure and high temperature
(C) high pressureand high temperature (D) low pressure and low temperature
Q.15 The equilibrium SO2Cl2(g) SO2(g) + Cl2(g) is attained at 25°C in a closed rigid container and
an inert gas, helium is introduced. Which of the following statements is/are correct.
(A) concentrations of SO2, Cl2 and SO2Cl2 do not change
(B) more chlorine is formed
(C) concentration of SO2 is reduced
(D) more SO2Cl2 is formed
 SIIT SPARK REVISION CHEMISTRY

Q.16 The yield of product in the reaction

2A(g) + B(g) 2C(g) + Q kJ
would be lower at :
(A) low temperature and low pressure (B) high temperature & high pressure
(C) low temperature and to high pressure (D) high temperature & low pressure
1
Q.17 Following equilibrium is established at 727°C : SO3(g) SO2(g) + O (g)
2 2
At equilibrium pressure is 1.2 atm and density of mixture is 0.9 gm/litre.
The degree of dissociation of SO3(g) is - [Given : R = 0.08 atm-litre-mol–1 K–1]
1 2 1 1
(A) (B) (C) (D)
3 3 4 5
Q.18 An exothermic reaction is represented by the graph :

(A) (B) (C) (D)

Q.19 For the reversible reaction : N2(g) + 3H2(g) 2NH 3(g) at 500°C. The value of Kp is 1.44 ×
10–5, when partial pressure is measured in atmospheres. The corresponding value of Kc with
concentration in mol L–1 is :
(A) 1.44 × 10–5 /(0.082 × 500)2 (B) 1.44 × 10–5 /(8.314 × 773)2
(C) 1.44 × 10–5 /(0.082 × 500)2 (D) 1.44 × 10–5 /(0.082 × 773)–2
Q.20 At constant temperature, the equilibrium constant (KP) for the decomposition reaction. N2O4
2NO2 is expressed by KP = 4x2P/(1 – x2) where P is pressure, x is extent of decomposition.
Which of the following statement is true ?
(A) KP increases with increase of P
(B) KP increases with increase of x
(C) KP increases with decrease of x
(D) KP remains constant with change in P or x
Q.21 Consider the following equilibrium in a closed container : N2O4(g) 2NO2(g).
At a fixed temperature, the volume of the reaction container is halved. For this change, which of
the following statements holds true regarding the equilibrium constant (KP) and degree of
dissociation () :
(A) Neither KP nor  changes (B) Both KP and  change
(C) KP changes, but  does not change (D) KP does not change, but  changes
Q.22 For the reaction : 2NaNO3 (s) 2NaNO 2 (s) + O2(g),
the only correct change in equilibrium condition to increase the moles of O2 (g) at new equilibrium
is
(A) addition of some NaNO3(s) at initial equilibrium
(B) removal of some NaNO2(s) at initial equilibrium
(C) increase in pressure on system at initial equilibrium
(D) increase in available space over solids at initial equilibrium.
Q.23 Which of the following equilibria is not affected by change in volume of the flask –
(A) PCl5 (g) PCl3(g) + Cl2(g) (B) N2(g) + 3H2 (g) 2NH3(g)
(C) N2 (g) + O2 (g) 2NO (g) (D) SO2Cl2 (g) SO2(g) + Cl2(g)
Q.24 The equilibrium partial pressure of N2O4 (g) and NO2 (g) are 2 atm and 4 atm respectively. If
the volume of container is doubled at fixed temperature then new equilibrium partial pressure of
N2O4 (g).
(A) 0.24 atm (B) 1.24 atm (C) 0.76 atm (D) 2.48 atm
 SIIT SPARK REVISION CHEMISTRY

Q.25 Which one of the following statements is incorrect about chemical equilibrium-
(A) Chemical equilibrium can be attained, whether we start with reactants or products.
(B) Chemical equilibrium is dynamic in nature.
(C) Chemical equilibrium CaCO3(s) l CaO(s) + CO2(g) is attained when CaCO3(s) is heated
in an open vessel.
(D) At equilibrium concentration of each of the reactants and products become constant.
Q.26 Consider following reactions in equilibrium with equilibrium concentration 0.01 M of every species
(I) PCl5(g) PCl 3(g) + Cl2(g)
(II) 2HI(g) H2(g) + I2 (g)
(III) N2(g) + 3H2(g) 2NH3(g)
Extent of the reactions taking place is:
(A) I > II > III (B) I < II < III (C) II < III < I (D) III < I < II
Q.27 For the reaction A(g) + 2B(g) l C(g) + D(g) ; Kc = 1012 .
If the initial moles of A,B,C and D are 0.5, 1, 0.5 and 3.5 moles respectively in a one litre vessel.
What is the equilibrium concentration of B?
(A) 10–4 (B) 2 × 10–4 (C) 4 ×10–4 (D) 8 × 10–4
Q.28 At certain temperature (T) for the gas phase reaction
2H2O(g) + 2Cl2 (g) 4HCl(g) + O2(g)Kp = 12 × 108 atm
If Cl2, HCl & O2 are mixed in such a manner that the partial pressure of each is 2 atm and the
mixture is brough into contact with excess of liquid water. What would be approximate partial
pressure of Cl2 when equilibrium is attained at temperature (T)?
[Given : Vapour pressure of water is 380 mm Hg at temperature (T)]
(A) 3.6 ×10–5 atm (B) 10–4 atm (C) 3.6 ×10–3 atm (D) 0.01 atm
Q.29 At 675 K, H2(g) and CO2 (g) react to form CO(g) and H2O (g), Kp for the reaction is 0.16.
If a mixture of 0.25 mole of H2(g) and 0.25 mol of CO2 is heated at 675 K, mole % of CO(g) in
equilibrium mixture is :
(A) 7.14 (B) 14.28 (C) 28.57 (D) 33.33
Q.30 Following two equilibrium is simultaneously established in a container
PCl5(g) PCl3(g) + Cl2(g)
CO(g) + Cl2(g) COCl2(g)
If some Ni(s) is introduced in the container forming Ni (CO)4 (g) then at new equilibrium
(A) PCl3 concentration will increase (B) PCl3 concentration will decrease
(C) Cl2 concentration will remain same (D) CO concentration will remain same

CHEMISTRY

1) A 2) D 3) C 4) C 5) B 6) B 7) A 8) A 9) A 10) A

11) D 12) D 13) C 14) C 15) A 16) D 17) B 18) A 19) D 20) D

21) D 22) D 23) C 24) C 25) C 26) B 27) B 28) C 29) B 30) B