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PHASE 5 Mains

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PHASE 5 Mains

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FIITJEE - JEE (Main)

PHYSICS, CHEMISTRY & MATHEMATICS


BATCHES: Two Year CRP325 Batches
PHASE TEST – V
Q.P. CODE: 100836
Time Allotted: 3 Hours Maximum Marks: 300

▪ Do not open this Test Booklet until you are asked to do so.
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
Forthcoming Exam
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
– BBE Test on 17th
2. This question paper contains Three Sections.
Nov. 2024.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log tables, slide
rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall
/ room.

B. Filling of OMR Sheet:


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.

C. Marking Scheme for All Two Parts:


(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each and only
one correct option. Each question carries +4 marks which will be awarded for every correct answer and -1 mark will
be deducted for every incorrect answer.
(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative numbers or
decimals Two decimal Places (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4 marks for correct
answer and there will be no negative marking.

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Two Year CRP325 Batches_PT-V- JEE MAIN−2

Ph y s ic s
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1. Lenz’s law is a consequence of


(A) conservation of momentum (B) conservation of current
(C) conservation of charge (D) conservation of energy

2. Critical angle of light passing from glass to air is maximum for


(A) red colour. (B) green colour (C) yellow colour. (D) violet colour.

3. For the circuit shown in the figure, the current through the inductor is L

0.6 A, while the current through the capacitor is 0.4 A. The current
drawn from the generator is
C
(A) 1.0 A (B) 0.4 A

(C) 0.6 A (D) 0.2 A
Generator

4. Two plane mirrors M1 and M2 are inclined to each other at 70°. A ray incident on the
mirror M1 at an angle , then falls on M2 and, it is then reflected parallel to M1, angle of
incidence  is
(A)  = 45° (B)  = 50°
(C)  = 55° (D)  = 60°

5. The figure shows a semi-circular conducting ring of radius a, B


which is rotated with constant angular velocity  about an axis P
passing through O and parallel to field B as shown. Identify the
correct value of potential difference
1
(A) VP − VQ = Ba 2
O Q
2 

(B) VQ − VO = 2Ba 2
1
(C) VP − VO = Ba 2
4
a 2 B
(D) The maximum value of VP − VO =
2
Space For Rough Work

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6. A concave lens of focal length f produces an image (1/) times the size of the object. The
distance of the object from the lens is

(A) ( −1)f (B)


(  − 1) f (C)
(  + 1) f (D) (+1)f
 

7. Magnetic flux through a circuit of resistance R changes by an amount  in a time t. Total
quantity of electric charge Q that passes any point in the circuit during the time t is
represented by
1    
(A) Q = (B) Q = (C) Q = (D) Q = R
R t R t t

8. In the given circuit switch S is closed at t = 0, then the R


rate of change of current through the inductor initially is
(A) 0
(B) /L  L
R
(C) /2L
(D) 2/L S

9. A uniform but time varying magnetic field B = C – Kt, where K and C are positive constants
and t is time, is applied perpendicular to the plane of a circular loop of radius 'a'
and resistance R. The total charge that will pass through any point of the loop by the time B
becomes zero is:
(A) C  a2/R K (B) K a2/R
(C) C a2/R (D) none of these

10. In the series LCR circuit as shown in figure, the heat developed
in 80 seconds and amplitude of wattless current is:
(A) 4000 J, 3A (B) 8000 J, 3A
(C) 4000 J, 4A (D) 8000 J, 5A

11. The work function of metal is 1 eV. Light of wavelength 3000 Å is incident on this metal
surface. The velocity of emitted photo-electrons will be
(A) 10 m/s (B) 1 × 103 m/s (C) 1 × 104 m/s (D) 1 × 106 m/s
air
12. A ray of light is incident at an angle i at the glass water
w=4/3
interface. It emerges finally parallel to the surface of water – air
water
interface. Then the value of g would be
4 1 g
(A) (B) i glass
3 sin i sin i
4
(C) (D) 1.5
3
Space For Rough Work

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13. In an L–C circuit:


(A) the energy stored in L as well as in C is magnetic energy.
(B) the energy stored in L is magnetic but in C it is electrical.
(C) the energy stored in L is electrical but in C it is magnetic.
(D) the energy stored in L as well as in C is electrical energy.

14. In Young’s double slit experiment, the intensity at the bright fringe is I0, when two identical
slits are used. One of the slits is now covered. The new intensity at any point on the
screen is
I I I I
(A) 0 (B) 0 (C) 0 (D) 0
2 2 2 2 4

15. If the frequency of light in a photoelectric experiment is doubled, the stopping potential will
(A) Be doubled (B) Be halved
(C) Become more than double (D) Become less that double

16. The parallel light ray pass through an isosceles prism of


refractive index 3 / 2 as shown in figure. The angle
between the two emergent rays is
(A) 15° (B) 30°
(C) 45° (D) 60°

17. White light is incident normally on a glass plate (in air) of thickness 500 nm and refractive
index of 1.5. The wavelength (in nm) in the visible region (400 nm – 700 nm) that is strongly
reflected by the plate is
(A) 450 (B) 600
(C) 400 (D) 500

18. In a YDSE experiment, d = 1 mm,  = 6000 Å and D = 1 m. The minimum distance between
two points on screen having 75% intensity of the maximum intensity will be
(A) 0.50 mm (B) 0.10 mm
(C) 0.30 mm (D) 0.20 mm

19. In photoelectric effect when photons of energy h fall on a photosensitive surface


(work function h0), electrons are emitted from the metallic surface with a kinetic energy. It is
possible to say that:
(A) All ejected electrons have same kinetic energy equal to h – h0.
(B) The ejected electrons have a distribution of kinetic energy from zero to (h – h0).
(C) The most energetic electrons have kinetic energy equal to h0.
(D) All ejected electrons have kinetic energy h0.
Space For Rough Work

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20. A copper rod is moving with uniform velocity V parallel to a long straight wire carrying a
current I. The rod itself is perpendicular to the wire with its ends at distances a and b, from
it. Calculate the emf induced in the rod.
 iV b  iV b + a
(A) o  (B) o ln
2 a 2 a
 o iV b − a  o iV b
(C) ln (D) ln
2 a 2 a

PART-B
Numerical Type

1. A transparent cylinder has its right half polished so as to act as a


mirror. A paraxial light ray is incident from left that is parallel to
principal axis, exits parallel to the incident ray as shown. Find the
refractive index n of the material of the cylinder.

2. The maximum number of possible interference maxima for slit separation equal to twice the
wavelength in YDSE is

3. When a surface is irradiated with light of  = 4950 Å a photocurrent appears which vanishes
if a retarding potential 0.6 V is applied. Find the work-function of emitting surface (in eV).

4. The network shown in Figure is part of a


I
complete circuit. If at a certain instant the
current (I) is 5A, and is decreasing at a rate A 5 35 mH B
8V
of 103 A/s, then VB – VA =

5. A large glass slab ( = 5/3) of thickness 8 cm is placed over a point source of light on a
plane surface. It is seen that light emerges out of the top surface of the slab from a circular
area of radius R cm. What is the value of R?
Space For Rough Work

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Chemistry
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1. Which set of reagent(s) are required to distinguish between SO32− and SO24− ?
(A) BaCl2 and NaOH (B) BaCl2 and HCl
(C) PbCl2 and NaOH (D) PbCl2 and KOH

2. Na2TiO3 is an ionic solid which type of arrangement is possible for it?


(A) TiO32− ion forms the FCC lattice and Na+ ions occupy all octahedral voids.
(B) TiO32− forms the HCP lattice and Na+ ions occupy half of total number of tetrahedral voids
and half of the total number of octahedral voids.
(C) TiO32− ions form FCC lattice and Na+ ions occupy all tetrahedral voids.
(D) O2– ion form FCC lattice and Ti4+ ions occupy half of the total number of octahedral voids
Na+ ions occupy all tetrahedral voids.

3.

Na2CrO4 Pb(CH3COO) 2

0.2 M 0.4 M
Aq. Solution Aq. Solution

Semipermeable membrane
When the above two aqueous solutions are separated by a semipermeable membrane for
sometime, which change is observed?
(A) a yellow precipitate is formed
(B) concentration of Na+ will increase
(C) a buffer of CH3COOH and CH3COONa will be formed
(D) CO2 gas will be evolved
Space For Rough Work

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O OH

4. P P
HO H H HO
H
Above two forms of an oxo-acid of phosphorus are called
(A) tautomers (B) metamers
(C) position isomers (D) stereoisomers

5. Which is expected to form by heating white phosphorus at the highest temperature?


(A) Red phosphorus
(B) Black phosphorus
(C) P2 species
(D) either (A) or (B) depending other reaction conditions

6. Solid NH4NO3 decomposes into which species?


(A) N2O + H2O (B) NH3 + HNO3
(C) NO + H2O (D) N2 + H2O

7. Self reduction process in metallurgy takes place during


(A) froath flotation process (B) roasting
(C) smelting (D) slag formation

8. The ionic conductance of Cl– and Ca2+ ions at infinite dilution are 118 and
76.3 ohm–1 cm2 mol–1. Then a conductance value of (118 + 2  76.3) ohm–1 cm2 mol–1 is
called
(A) molar conductance of CaCl2 in the saturated solution
(B) molar conductance of CaCl2 when it’s concentration is 1 M
(C) molar conductance of CaCl2 at infinite dilution
(D) specific conductance of CaCl2 at infinite dilution

9. The boiling point of an aqueous solution of Fe4[Fe(CN)6]3 is 105.2oC at one atm pressure.
What is the molality of the solution if the degree of dissociation() of Fe4[Fe(CN)6]3 is 0.5?
[Kb of H2O = 0.52 K Kg mol–1]
(A) 0.025 (B) 25
(C) 2.5 (D) 0.25


10. Under which condition m = m ?
(A) When degree of dissociation of electrolyte is zero
(B) When no ion-pairs are present in the solution
(C) Concentration of the solution is 1 M
(D) When an equilibrium exist between the dissociated ions and undissociated electrolytes
Space For Rough Work

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_
O O

11. The incorrect statement for acetylacetonate ligand CH3 - C = CH - C - CH 3 is

(A) it form a six-membered chelate ring with metal ion


(B) the negative charge is delocalized through two oxygen and three carbon atoms
(C) it’s complex with metal ions(cation) form a ring which shows aromaticity
(D) it is a weaker ligand than C2O24− ion

12. Which is not a hydrolysis product of XeF6?


(A) XeOF4 (B) XeO2F2
(C) XeO3 (D) XeO4

13. Equimolar quantities of CH3COOH will increase the boiling point of which solvent by
maximum extent?
(A) C6H6 (B) C6H5Cl
(C) H2O (D) CS2

14. The vapour pressure over the solution of two liquids A and B is 400 mm of Hg. If the partial
pressure of A i.e., pA is 120 mm of Hg, what is the mole fraction of B in the vapour?
(A) 0.4 (B) 0.3
(C) 0.7 (D) 0.6

15. According to point defects in ionic crystals, which impurity can distort the crystal of NaCl by
maximum extent?
(A) NaBr (B) KCl
(C) KBr (D) NaF

16. A substance(X) can convert another substance(Y) to Cl2O7 and H2O. Therefore, (X) and (Y)
respectively may be
(A) H3PO4 and Cl2O5 (B) O2 and HClO4
(C) O3 and HClO3 (D) P4O10 and HClO4

17. Addition of which substance into the aqueous solution of FeSO4 prevents the hydrolysis of
Fe2+?
(A) Na2SO4 (B) H2SO4
(C) CaSO4 (D) K2SO4
Space For Rough Work

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18. Which halogen molecule can absorb the lowest amount of energy for the electronic transition
from HOMO (highest occupied molecular orbital) to LUMO (lowest unoccupied molecular
orbital)?
(A) F2 (B) Cl2
(C) Br2 (D) I2

19. A metal carbonyl, M(CO)n contains an unpaired electron, so it may gain stability by
(A) removing that unpaired electrons
(B) adding the ligand CO to form an M  CO bond
(C) dimerisation
(D) addition of one electron

20. The hydrate CeCl3.(H2O)n produces a compound(X) on heating, which is (X)?


(A) CeO (B) CeO2
(C) Ce2O3 (D) CeO4

PART-B
Numerical Type

1. The cyclic trimer of SO3 contains x number of sigma covalent bonds and y number of
x+y
pi-covalent bonds. What is the value of ?
9

2. P4O6 + O3 ⎯⎯→ ( X)
( X ) ⎯⎯→ O2 + P4O10
How many moles of dioxygen is formed in the second reaction?

3. The molar conductance(m) of an ionic electrolyte MCl2 is 80 ohm–1 cm2 mol–1. The degree of
dissociation of the electrolyte MCl2 is 0.4. If the ionic conductance of M2+ ion at infinite
dilution is 150 ohm–1 cm2 mol–1, what will the ionic conductance of one Cl– ion at infinite
dilution in ohm–1 cm2 mol–1 unit?

4. The unit cell of a metallic crystal(M) contains a simple cubic unit cell.
If x = the coordination number of the metal and y = number of unit cells shared by one
corner atom, then the value of (y - x) is

5. An aqueous solution of 0.4 M NaCl( = 0.8) is isotonic with 0.45 M aqueous solution of KCl
at constant temperature. If the degree of dissociation of KCl is x, what is the value of 9x?
Space For Rough Work

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M a th e m a ti c s
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1 A unit vector parallel to the line of intersection of the planes r. ˆi − ˆj + kˆ = 5 and ( )


( )
r. 2iˆ + ˆj − 3kˆ = 4 is
2iˆ + 5ˆj + 3kˆ 2iˆ − 5ˆj + 3kˆ
(A) (B)
38 38
2i + 5ˆj − 3kˆ
ˆ −2i + 5ˆj − 3kˆ
ˆ
(C) (D)
38 38

2 The number ‘a’ is randomly selected from the set {0, 1, 2, ......, 98, 99}, the number ‘b’ is
selected from the same set. Probability that the number 3a + 7b has a digit equal to 8 at the
unit place is
1 1
(A) (B)
16 8
1 3
(C) (D)
4 16

3 A box contains 5 red and 4 white marbles, two marbles are drawn successively from the box
without replacement and the second drawn marble is found to be white. Probability that the
first marble is also white is
3 1
(A) (B)
8 2
1 1
(C) (D)
3 4

4 A fair dice is tossed 8 times. Probability that on the eighth throw a third six is observed is
55 55
(A) 8 C3 8 (B) 7 C 2 8
6 6
5
5
(C) 7 C 2 7 (D) None of these
6
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5 The three vectors ˆi + ˆj , ˆj + kˆ , kˆ + ˆi taken two at a time from three planes. The three unit
vectors drawn perpendicular to these three planes from a parallelopiped of volume?
1 5 3 3 4
(A) (B) (C) (D)
3 3 3 3 4 3 3

6 Let L1 be the line r1 = 2iˆ + ˆj − kˆ + (iˆ + 2k)


ˆ and L2 be the line r = 3iˆ + (iˆ + ˆj + k)
2
ˆ , , μ are non-
zero scalers. Let P be a plane which contains the line L1 and is parallel to L2, the distance of
P from origin is
2 1
(A) (B) (C) 6 (D) None of these
7 7

cos  − sin  
7. For a given matrix A =  which of the following statement holds good?
sin  cos 

(A) A = A −1  R (B) A is symmetric for  = (2n + 1) , n ϵ I
2
(C) A is an orthogonal matrix (D) A is skew symmetric for θ = n, n ϵ I

8. Let A be a 2  2 real matrix with entries from {0, 1} and |A|  0. Consider the following two
statements;
(P) If A  I2, then |A| = –1
(Q) If |A| = 1 , then tr(A) = 2
where I2 denotes 2  2 identity matrix and tr(A) denotes the sum of the diagonal entries of A.
Then :
(A) Both (P) and (Q) are true (B) Both (P) and (Q) are false
(C) (P) is true and (Q) are false (D) (P) is false and (Q) is true

1 sin  1 
9. Let A =  − sin  1 sin   , where 0 ≤ θ ≤ 2, then

 −1 − sin  1 
(A) Det (A) = 0 (B) Det A ϵ (0, ∞)
(C) Det (A) ϵ [2, 4] (D) Det A ϵ [2, ∞]

3
10. The area enclosed by the curves y = cos x, y = 1 + sin 2x, x = 0 and x = equals
2
3 3 3 3
(A) −2 (B) (C) 2 + (D) 1 +
2 2 2 2
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11. A function y = f(x) satisfies the condition fʹ(x) sin x + f(x) cos x = 1, f(x) being bounded when
 /2
x → 0 if I =  f(x)dx , then
0

 2  2
(A) I (B) I
2 2 2 4

(C) 1  I  (D) 0 < I < 1
2

|x| |y| x2 y2
12. Area(in sq. units) of the region outside + = 1 and inside the ellipse + = 1 is
2 3 4 9
(A) 3(4 – ) (B) 3(– 2)
(C) 6(– 2) (D) 6(4 – )

x2 y2
13. A area enclosed by ellipse + = 1 , where 0 ≤ y ≤ 5 and y = sin x is
2 25
5 2
(A) 32 (B)
2
(C) 52 (D) 62

14. The volume of the parallelopiped formed by three non-coplanar vectors a,b,c such that
1
a = b = c and a.b = b.c = c.a = is
2
1 1
(A) (B)
2 3
(C) 4 3 (D) None of these

 1
15. Consider the differential equation y 2 dx +  x −  dy = 0 . If y (1) = 1 , then x is given by:
 y
1/ y
2 e 1 e1/ y
(A) 4 − − (B) 3 − +
y e y e
1 e1/ y 1 e1/ y
(C) 1 + − (D) 1 − +
y e y e

16. For unit vectors b and c and any non zero vector a, the value of

(a + b)  (a + c )  (b  c ). (b + c ) is
2 2
(A) a (B) 2 a
2
(C) 3 a (D) none of these

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17. A number x is chosen at random from the set 1,2,3,4,......100 . Define the event: A = the
( x − 10 )( x − 50 )  0
chosen number x satisfies . Then P ( A ) is:
( x − 30 )
(A) 0.71 (B) 0.70
(C) 0.51 (D) 0.20

18. If the system of linear equations, x + 2ay + az = 0, x + 3by + bz = 0 and x + 4cy + cz = 0 has
a non – zero solution, then a, b, c satisfy:
(A) 2b = a + c (B) b2 = ac
(C) 2ac = ab + bc (D) 2ab = ac + bc

19. Two events A and B are such that P(A) = 0.3 , P(B) = 0.4 and P(A  B) = 0.5 , then
 B 
P  is
 A B
1 3
(A) (B)
2 4
1
(C) (D) None of these
4

20. If the slope of tangent to the curve is maximum at x = 1 and curve has a minimum value 1 at
d3 y
x = 0, then the curve which also satisfies the equation = 4x – 3 is
dx 3
dy x2 x3 x4
(A) y + 2x + =0 (B) y = 1 + − +
dx 2 2 6
(C) y = 1 + x + x2 + x3 (D) none of these
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Two Year CRP325 Batches_PT-V- JEE MAIN−14

PART-B
Numerical Type

 2 1 3 4  3 − 4 
1. Let three matrices A =   , B =   ,C=   , then
 4 1 2 3   −2 3 
 A(BC)   A(BC)2   A(BC)3 
tr(A) + tr   + tr   + tr   + ... =
 2 
2 3
 2   2 

x 1
2. The value of ‘a’ (a > 0) for which the area bounded by the curves y = + , y = 0, x = a and
6 x2
x = 2a has the least value is

3. If 3rd order determinants are formed using elements 1 or –1, then maximum possible value of
such determinant is

4. Sixteen players S1, S2, .......S16 play in a tournament, they are divided in to eight pairs at
random from each pair a winner is decided on the basis of game played between the two
players of the pair, assume that all the players are of equal strength. If the probability that
“exactly one of the two players S1 and S2 is among the eight winners” be k then 15k equals

5. Let X denotes the number of times head occur in n tosses of an unbiased coin. If
P(X = 4), P(X = 5) and P(X = 6) are in A.P. then value of n is
Space For Rough Work

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Two Year CRP325 Batches_PT-V- JEE MAIN−15

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BATCHES: Two Year CRP325 Batches_PT5
PHYSICS, CHEMISTRY & MATHEMATICS
JEE MAIN-PHASE Paper Code
100836
ANSWER KEY
SECTION – I
(PHYSICS)
PART – A
1. D 2. A 3. D 4. B
5. B 6. A 7. B 8. C
9. C 10. A 11. D 12. B
13. B 14. D 15. C 16. B
17. B 18. D 19. B 20. D
PART – B
1. 2 2. 3 3. 1.9 (range 1.8 to 2)
4. 2 5. 6

SECTION – II
(CHEMISTRY)
PART – A
1. B 2. C 3. B 4. A
5. C 6. A 7. B 8. C(bonus)
9. C 10. B 11. D 12. D
13. C 14. C 15. C 16. D
17. B 18. D 19. C 20. B
PART – B
1. 2 2. 4 3. 25 4. 2
5. 5.4

SECTION – III
(MATHEMATICS)
PART – A
1 A 2 D 3 A 4 B
5 D 6 D 7. C 8. D
9. C 10. C 11. B 12. C
13. B 14. A 15. C 16. D
17. A 18. C 19. C 20. B (bonus)
PART – B
1. 6 2. 1 3. 4 4. 8
5. 7

FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000

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