Dr.
Davies: AP Chemistry
Homework #24(c): Ksp Precipitation & Complex Equilibria due: >< BASISw
INDEPENDENT
SILICON VALLEY
1. A solution containing potassium bromide is mixed with one containing le d acetate �o form a solution that is 0.013 M
in KBr and 0.0035 Min Pb(C2H302h- Does a precipitate form in the mixed solution? I so, identify the precipitate.
/i
l Ksp Ph Br 2. =- 4-. b 7 x to- G::,)
Ks� � K+-- + Sr :. [&r-]-=- 0.013 fV\
'l.+
Pb(c;:,.\-\aO..a)� ..? f\, + .2 C..a \-\ao; : . [p,l..-rJ � .Oo3S CV\
Pb�c-2.ls� Pb� -+-
2B, c"'I.--)
�]
1
'2. 2
Q = (ph�+J[�r--J -: (o.oo3SJ(o.o\3J � 5.'\ ID-¼"- Ksf
�or� _:
2. Predict whether a precipitate will form if you mix 175.0 ml of a 0.0055
AgN03 solution. Identify e precipitate, if any. (.Ks Pi CJ... ::::. l.;
�
,,s.o ML
f 3 l KCI solutio with 145.0 ml of a 0.0015 M
><: 10
- 10J
o.oo�S (V\ Q x
-3 .::lO . 0 "'L-
::. o. 00 3008 M\ a
+
o. oo I� r'1 � 1<: i4-S.D ML -=- 0.000�797 M
'31'),0 <"'L
'
�Gc.sr ��+-(G\ci.'> + u-co..CJ...)
A
-<o
� :=. Lf\-�:1[a.-J e(b.io x \0-4) (3.01 x 10 -3) -::: �. o f)(\�
K'Sf I S'O 0. ft€.'4'·J-cJ-e � ��
�> �Jl � � •
3. Potassium hydroxide is used to precipitate the hydroxides of each cation from its re pective solution. Determine
l
the minimum concentration of KOH required for precipitation to begin in e ch case.
a. 0.015 M CaCb (Kse Cc...(Ot\) � e 4-- {:, 8" )C IO -h '!
Ca..c...Q� � u.�� + 20- :.[0>-. 2.� = 0.015
�(c\-\J2..csr' G>-. 'L�l"")..\ + 2ot\ cQ.i..')
q "t:'- [�L"J [cl-\"j 1 � 4-.f,8 x \o-" =- Ks
b. 0.0025 M Fe(N03h
Fe(OHJ2 Cs) �
Fe.:�-�� + 20\-\- c.c..,.._,""')
Q -= [F-e-�""][ott-]� � 4-.�7 )C \O_,,::: Ks.p
@>1� -J �f4-.8' 7 .oc ,o- '¼ ·00 :1
c. 0.0018 M MgBr 2 (Kcs,-p . M� (0\-\ 2. J =- :t -Of> x: 1 O
M 'a (.Ot\) 2. { S) � I"\�'1-+(� t- �DH - [°"}.,)
3 :=;.
'2.
Q � L.M 'a- +J[o\-\--=J i � ;i._ .ob >< lo- ' I p
-+----r------,
[ott -J -= G.o'=> x \O -l!> -= I 1 I >< to s fl\ koH
,,l .=- o -oo I 8-
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