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Batch and Semi-Batch Titration Data

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rifky algifary
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Topics covered

  • Concentration Calculations,
  • Acid-Base Reactions,
  • Chemical Kinetics,
  • Quality Control,
  • Experimental Results,
  • Experimental Conditions,
  • Temperature Dependence,
  • Reaction Conditions,
  • Experimental Variables,
  • Chemical Safety
15 views9 pages

Batch and Semi-Batch Titration Data

.

Uploaded by

rifky algifary
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd

Topics covered

  • Concentration Calculations,
  • Acid-Base Reactions,
  • Chemical Kinetics,
  • Quality Control,
  • Experimental Results,
  • Experimental Conditions,
  • Temperature Dependence,
  • Reaction Conditions,
  • Experimental Variables,
  • Chemical Safety

BATCH

suhu waktu C HCl vol hcl 0,05 (ml) CA0 CA XA


30 0 0.05 0 0.05 0.05 0
30 5 0.05 5.4 0.05 0.018 64
30 10 0.05 4.2 0.05 0.014 72
30 15 0.05 2.1 0.05 0.007 86
30 20 0.05 1.5 0.05 0.005 90
30 25 0.05 1.5 0.05 0.005 90

35 0 0.05 0 0.05 0.05 0


35 5 0.05 4.5 0.05 0.015 70
35 10 0.05 2.6 0.05 0.008667 82.66666667
35 15 0.05 1.9 0.05 0.006333 87.33333333
35 20 0.05 1.5 0.05 0.005 90
35 25 0.05 0.8 0.05 0.002667 94.66666667
35 30 0.05 0.8 0.05 0.002667 94.66666667

40 0 0.05 0 0.05 0.05 0


40 5 0.05 2.9 0.05 0.009667 80.66666667
40 10 0.05 2.7 0.05 0.009 82
40 15 0.05 2.7 0.05 0.009 82

SEMI BATCH
Metode Titrimetri
suhu waktu C HCl vol hcl 0,05 (ml) CA0 CA XA
30 0 0.05 0 0.05 0.05 0
30 5 0.05 8.7 0.05 0.029 42
30 10 0.05 8.1 0.05 0.027 46
30 15 0.05 6.9 0.05 0.023 54
30 20 0.05 6.7 0.05 0.022333 55.33333333
30 25 0.05 7.1 0.05 0.023667 52.66666667
30 30 0.05 7.1 0.05 0.023667 52.66666667

35 0 0.05 0 0.05 0.05 0


35 5 0.05 11.5 0.05 0.038333 23.33333333
35 10 0.05 8.4 0.05 0.028 44
35 15 0.05 8.4 0.05 0.028 44
35 20 0.05 7.2 0.05 0.024 52

40 0 0.05 0 0.05 0.05 0


40 5 0.05 4.5 0.05 0.015 70
40 10 0.05 3.1 0.05 0.010333 79.33333333
40 15 0.05 3.1 0.05 0.010333 79.33333333
40 20 0.05 3.1 0.05 0.010333 79.33333333

Metode Polymath
Semibatch
Suhu K Ln K Final Value
30 303 1.9 0.641853886172 0.0295736
35 308 1.1 0.095310179804 0.0383422
40 313 0.69 -0.37106368139 0.0152029

Titrimetri Elu CA K Final Value


30 303 0.026 0.24 0.0261871
35 308 0.01 1.41 0.0107243
40 313 0.006 4.31 0.0060861

Konduktometri Elu
30 303 0.01038 1.55 0.0103127
35 308 0.0159 0.64 0.0159138
40 313 0.00695 3.26 0.0069976

Ln K vs 1/T
0.8

0.6 f(x) = 9609.67905706072 x − 31.0837062387604


R² = 0.998683487597591
0.4

0.2

0
0.00318 0.0032 0.00322 0.00324 0.00326 0.00328 0.0033 0.00332
-0.2

-0.4

-0.6

0.058
Ln Ca Ln CA0/CA 1/CA K Ln K 3.5
-2.995732274 0 20 8.0272 2.082836
3 f(x) = 0.09141478
-4.017383521 1.021651 55.55556 12.616 2.534966 R² = 0.909630430
-4.268697949 1.272966 71.42857 5.6199 1.726314 2.5 f(x) = 0.09170785
-4.96184513 1.966113 142.8571 T 1/T R² = 0.912372899
-5.298317367 2.302585 200 303 0.0033 2

Ln CA0/CA
f(x) = 0.10431708
-5.298317367 2.302585 200 308 0.003247 R² = 0.633278105
1.5
313 0.003195
-2.995732274 0 20 1
-4.199705078 1.203973 66.66667 79.88544
-4.74827103 1.752539 115.3846 0.5

-5.061928588 2.066196 157.8947 0


-5.298317367 2.302585 200 0 5 10
-5.926926026 2.931194 375
-5.926926026 2.931194 375

-2.995732274 0 20
-4.639071738 1.643339 103.4483
-4.710530702 1.714798 111.1111
-4.710530702 1.714798 111.1111

Ln Ca Ln CA0/CA 1/CA
1.8
-2.995732274 0 20 f(x) = 0.0705194292901478 x + 0.481589121730374
-3.540459449 0.544727 34.48276 1.6 R² = 0.666715814889661
-3.611918413 0.616186 37.03704 1.4
-3.772261063 0.776529 43.47826 1.2
-3.801674948 0.805943 44.77612 T = 30
Ln CA0/CA

1
-3.743687691 0.747955 42.25352 Linear (T = 30)
0.8 f(x) = 0.0202862804976631 x + 0.301319451560719
-3.743687691 0.747955 42.25352 R²
T = 35
f(x)==0.599586821644491
0.0356410735936067 x + 0.0754511303277505
0.6 R² = 0.909518281032714 Linear (T = 35)
T = 40
-2.995732274 0 20 0.4 Linear (T = 40)
-3.261435439 0.265703 26.08696
0.2
-3.575550769 0.579818 35.71429
-3.575550769 0.579818 35.71429 0
0 5 10 15 20 25 30 35
-3.729701449 0.733969 41.66667
t (menit)

-2.995732274 0 20
-4.199705078 1.203973 66.66667
-4.572380363 1.576648 96.77419 120

-4.572380363 1.576648 96.77419 f(x) = 3.67311827956989 x + 38.6666666666667


100 R² = 0.746888799678844
-4.572380363 1.576648 96.77419
80
T = 30
60 Linear (T = 30)
1/Ca

T = 35
40 f(x) = 0.643151219702654 x + 28.1071914450028 Linear (T = 35)
f(x)==0.644895335319401
R² 1.0592132505176 x + 21.2443064182195 T = 40
R² = 0.935359838343131
Linear (T = 40)
20

0
0 5 10 15 20 25 30 35
T = 30
60 Linear (T = 30)

1/Ca
T = 35
40 f(x) = 0.643151219702654 x + 28.1071914450028 Linear (T = 35)
f(x)==0.644895335319401
R² 1.0592132505176 x + 21.2443064182195 T = 40
R² = 0.935359838343131
Linear (T = 40)
20

0
0 5 10 15 20 25 30 35
t (menit)

3.6731 1.30103599
0.6432 -0.4412996 Ln K vs 1/T
1.0592 0.05751391 Ln K vs 1/T Linear (Ln K vs 1
1.4
0.0033 1.2
0.003247 1
0.8 f(x) = − 0.621761042983686 x + 1.5492721983
0.003195 0.6 R² = 0.480143049107751

Ln K
0.4
0.2
0
-0.20.5 1 1.5 2 2.5
-0.4
-0.6
t (menit)
3.5 400

f(x) = 0.091414782073925 x + 0.512732622199327 350 f(x) = 12.6163003663004 x − 2.109359


3 R² = 0.934714623793927
R² = 0.909630430181302
300
2.5 f(x) = 0.0917078524680935 x + 0.33130183843313
R² = 0.912372899586386 250
2 T = 30
Ln CA0/CA

f(x) = 0.104317084965159 x + 0.48585594283472 200


R² = 0.633278105406492 Linear (T = 30) f(x) = 8.02721088435374 x + 14.63340

1/Ca
1.5 T = 35 R² = 0.949724723622193
150
Linear (T = 35)
1 T = 40 100 f(x) = 5.61992337164751 x + 44.26819
Linear (T = 40) R² = 0.666782979860726
0.5 50

0 0
0 5 10 15 20 25 30 35 0 5 10 15 20 25

t (menit)
t (menit)

Ln K vs 1/T
Ln K vs 1/T Linear (Ln K vs 1/T)
3

2.5
f(x) = 3316.2236877078 x − 8.65414700721803
2 R² = 0.186127103699899
74
1.5

T = 30 0.5
Linear (T = 30)
19 T = 35 0
505 0.00318 0.0032 0.00322 0.00324 0.00326 0.00328 0.0033 0.00332
Linear (T = 35)
T = 40
Linear (T = 40)

35 0
0 5 10 15 20 25 30 35
-0.5

-1

-1.5

-2

-2.5

-3
f(x) = − 0.0356410735936067 x − 3.07118340388174
T = 30 -3.5 f(x)
R² ==0.909518281032714
− 0.0202862804976631 x − 3.29705172511471
Linear (T = 30) f(x)
R² ==0.599586821644491
− 0.0705194292901479 x − 3.47732139528437
-4 R² = 0.666715814889661
T = 35
8 Linear (T = 35)
-4.5
T = 40
Linear (T = 40) -5

35
f(x) = − 0.0356410735936067 x − 3.07118340388174
T = 30 -3.5 f(x)
R² ==0.909518281032714
− 0.0202862804976631 x − 3.29705172511471
Linear (T = 30) f(x)==0.599586821644491
R² − 0.0705194292901479 x − 3.47732139528437
-4 R² = 0.666715814889661
T = 35
8 Linear (T = 35)
-4.5
T = 40
Linear (T = 40) -5

35

Ln K vs 1/T
vs 1/T Linear (Ln K vs 1/T)

0.621761042983686 x + 1.54927219838444
80143049107751

1.5 2 2.5 3 3.5

t (menit)
0
0 5 10 15 20 25 3
12.6163003663004 x − 2.10935993830728
.934714623793927 -1

-2

T = 30 -3
8.02721088435374 x + 14.6334089191232 Linear (T = 30)
.949724723622193 T = 35 f(x)
f(x) == −− 0.0917078524680935
0.104317084965159 x x−−3.50846489575332
0.091414782073925 3.32703411198712
3.48158821638871
-4 R²
Linear (T = 35) R² == 0.912372899586386
0.633278105406492
0.909630430181302
5.61992337164751 x + 44.2681992337165 T = 40 -5
.666782979860726 Linear (T = 40)
-6

10 15 20 25 30 35 -7

T = 30 Linear (T = 30) T=3


t (menit)
Linear (T = 35) T = 40 Line

1/T)

0.0033 0.00332

30 35
20 25 30 35

11198712
1638871
9575332

near (T = 30) T = 35
= 40 Linear (T = 40)

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