Safety Data Sheet

According to Regulation (EC) No 1907/2006

Shield Cleaner Disinfectant Concentrate

Revision: 2024-08-05 Version: 02.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name: Shield Cleaner Disinfectant Concentrate

UFI: SV43-S0EK-S002-SJSA

1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use: Restroom/bathroom cleaner.
for general surface disinfection
Uses advised against: Uses other than those identified are not recommended.

SWED - Sector-specific worker exposure description :

AISE_SWED_PW_1_1
AISE_SWED_PW_8a_1
AISE_SWED_PW_11_1
AISE_SWED_PW_19_1

1.3 Details of the supplier of the safety data sheet

Diversey Europe Operations BV, De Corridor 4, 3621ZB Breukelen [Maarssenbroeksedijk 2, 3542DN Utrecht], The Netherlands

Contact details
Diversey Ltd
Weston Favell Centre, Northampton NN3 8PD, United Kingdom
Tel: 01604 405311, Fax: 01604 406809
Regulatory Email: [email protected]

1.4 Emergency telephone number

Seek medical advice (show the label or safety data sheet where possible)
For medical or environmental emergency only:
call 0800 052 0185

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2 (H315)

Serious eye damage, Category 1 (H318)
Chronic aquatic toxicity, Category 3 (H412)

2.2 Label elements

Signal word: Danger.

Contains alkyl alcohol ethoxylate (C9-11 Pareth-5-10), n-alkyl dimethyl benzyl ammonium chloride (Benzalkonium Chloride), tetrasodium
ethylene diamine tetraacetate (Tetrasodium EDTA)

Hazard statements:
H315 - Causes skin irritation.
H318 - Causes serious eye damage.
H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements:
P280 - Wear eye or face protection.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 - Immediately call a POISON CENTRE, doctor or physician.

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2.3 Other hazards

No other hazards known.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Ingredient(s) EC number CAS number REACH Classification Notes Weight

number percent
alkyl alcohol ethoxylate [4] 68439-46-3 [4] Acute toxicity - Oral, Category 4 (H302) 3-10
Serious eye damage, Category 1 (H318)
tetrasodium ethylene diamine 200-573-9 64-02-8 01-211948676 Acute toxicity - Oral, Category 4 (H302) 1-3
tetraacetate 2-27 Acute toxicity - Inhalation, Category 4 (H332)
Specific target organ toxicity - Repeated
exposure, Category 2 (H373)
Serious eye damage, Category 1 (H318)
n-alkyl dimethyl benzyl ammonium 270-325-2 68424-85-1 [6] Skin corrosion, Category 1B (H314) 1-3
chloride Acute toxicity - Oral, Category 4 (H302)
Acute toxicity - Dermal, Category 4 (H312)
Serious eye damage, Category 1 (H318)
Acute aquatic toxicity, Category 1 M=10 (H400)
Chronic aquatic toxicity, Category 1 M=1 (H410)

Workplace exposure limit(s), if available, are listed in subsection 8.1.

ATE, if available, are listed in section 11.
[4] Exempted: polymer. See Article 2(9) of Regulation (EC) No 1907/2006.
[6] Exempted: biocidal active. See Article 15(2) of Regulation (EC) No 1907/2006.
For the full text of the H and EUH phrases mentioned in this Section, see Section 16..

SECTION 4: First aid measures

4.1 Description of first aid measures
Inhalation: Get medical attention or advice if you feel unwell.
Skin contact: Take off immediately all contaminated clothing and wash it before reuse.
Eye contact: Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE,
doctor or physician.
Ingestion: Rinse mouth. Immediately drink 1 glass of water. Never give anything by mouth to an unconscious
person. Get medical attention or advice if you feel unwell.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.

4.2 Most important symptoms and effects, both acute and delayed
Inhalation: No known effects or symptoms in normal use.
Skin contact: Causes irritation.
Eye contact: Causes severe or permanent damage.
Ingestion: No known effects or symptoms in normal use.

4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.

5.2 Special hazards arising from the substance or mixture

No special hazards known.

5.3 Advice for firefighters

As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Wear suitable gloves. Wear eye/face protection.

6.2 Environmental precautions

Dilute with plenty of water. Do not allow to enter drainage system, surface or ground water. Do not allow to enter the ground/soil. Inform
responsible authorities in case undiluted product reaches drainage system, surface or ground water or the ground/soil.

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6.3 Methods and material for containment and cleaning up

Dyke to collect large liquid spills. Absorb with liquid-binding material (sand, diatomite, universal binders). Do not place spilled materials back
into the original container. Collect in closed and suitable containers for disposal.

6.4 Reference to other sections

For personal protective equipment see subsection 8.2. For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Measures to prevent fire and explosions:
No special precautions required.
Measures required to protect the environment:
For environmental exposure controls see subsection 8.2.
Advices on general occupational hygiene:
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with
other products unless adviced by Diversey. Wash face, hands and any exposed skin thoroughly after handling. Take off contaminated clothing.
Wash contaminated clothing before reuse. Avoid contact with skin and eyes. Do not breathe spray. Use only with adequate ventilation. See
chapter 8.2, Exposure controls / Personal protection.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local and national regulations. Store in a closed container. Keep only in original packaging. Keep from freezing.
For conditions to avoid see subsection 10.4. For incompatible materials see subsection 10.5.

7.3 Specific end use(s)

No specific advice for end use available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Workplace exposure limits

Air limit values, if available:

Biological limit values, if available:

Recommended monitoring procedures, if available:

Additional exposure limits under the conditions of use, if available:

DNEL/DMEL and PNEC values

Human exposure
DNEL/DMEL oral exposure - Consumer (mg/kg bw)
Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
alkyl alcohol ethoxylate - - - -
tetrasodium ethylene diamine tetraacetate - - - 25
n-alkyl dimethyl benzyl ammonium chloride - - - 3.4

DNEL/DMEL dermal exposure - Worker

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects (mg/kg bw) effects effects (mg/kg bw)
alkyl alcohol ethoxylate - - - -
tetrasodium ethylene diamine tetraacetate - - - -
n-alkyl dimethyl benzyl ammonium chloride - - - 5.7

DNEL/DMEL dermal exposure - Consumer

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects (mg/kg bw) effects effects (mg/kg bw)
alkyl alcohol ethoxylate - - - -
tetrasodium ethylene diamine tetraacetate - - - -
n-alkyl dimethyl benzyl ammonium chloride - - - 3.4

DNEL/DMEL inhalatory exposure - Worker (mg/m3)

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
alkyl alcohol ethoxylate - - - -
tetrasodium ethylene diamine tetraacetate 3 3 1.5 1.5
n-alkyl dimethyl benzyl ammonium chloride - - - 3.96

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DNEL/DMEL inhalatory exposure - Consumer (mg/m3)

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
alkyl alcohol ethoxylate - - - -
tetrasodium ethylene diamine tetraacetate 1.2 1.2 0.6 -
n-alkyl dimethyl benzyl ammonium chloride - - - 1.64

Environmental exposure
Environmental exposure - PNEC
Ingredient(s) Surface water, fresh Surface water, marine Intermittent (mg/l) Sewage treatment
(mg/l) (mg/l) plant (mg/l)
alkyl alcohol ethoxylate - - - -
tetrasodium ethylene diamine tetraacetate 2.2 0.22 1.2 43
n-alkyl dimethyl benzyl ammonium chloride 0.0009 0.00096 0.00016 0.4

Environmental exposure - PNEC, continued

Ingredient(s) Sediment, freshwater Sediment, marine Soil (mg/kg) Air (mg/m3)
(mg/kg) (mg/kg)
alkyl alcohol ethoxylate - - - -
tetrasodium ethylene diamine tetraacetate - - 0.72 -
n-alkyl dimethyl benzyl ammonium chloride 12.27 13.09 7 -

8.2 Exposure controls

The following information applies for the uses indicated in subsection 1.2 of the Safety Data Sheet.
If available, please refer to the product information sheet for application and handling instructions.
Normal use conditions are assumed for this section.

Recommended safety measures for handling the undiluted product:

Appropriate engineering controls: If the product is diluted by using specific dosing systems with no risk of splashes or direct skin
contact, the personal protection equipment as described in this section is not required.
Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel.

REACH use scenarios considered for the undiluted product:

SWED - Sector-specific LCS PROC Duration ERC
worker exposure (min)
description
Manual transfer and dilution AISE_SWED_PW_8a_1 PW PROC 8a 60 ERC8a
Manual transfer and dilution AISE_SWED_PW_1_1 PW PROC 1 60 ERC8a

Personal protective equipment

Eye / face protection: Safety glasses or goggles (EN 16321 / EN 166).
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Repeated or prolonged contact: Chemical-resistant protective gloves (EN 374). Verify instructions
regarding permeability and breakthrough time, as provided by the gloves supplier. Consider specific
local use conditions, such as risk of splashes, cuts, contact time and temperature.
Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: ≥ 480 min Material
thickness: ≥ 0.7 mm
Suggested gloves for protection against splashes: Material: nitrile rubber Penetration time: ≥ 30 min
Material thickness: ≥ 0.4 mm
In consultation with the supplier of protective gloves a different type providing similar protection may
be chosen.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

Recommended safety measures for handling the diluted product:

Recommended maximum concentration (% w/w): 10

Appropriate engineering controls: Provide a good standard of general ventilation.

Appropriate organisational controls: No special requirements under normal use conditions.

REACH use scenarios considered for the diluted product:

SWED LCS PROC Duration ERC
(min)
Spray application AISE_SWED_PW_11_1 PW PROC 11 60 ERC8a

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Manual application AISE_SWED_PW_19_1 PW PROC 19 480 ERC8a

Personal protective equipment

Eye / face protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions.
Body protection: No special requirements under normal use conditions.
Respiratory protection: Trigger spray bottle application: No special requirements under normal use conditions. Apply
technical measures to comply with the occupational exposure limits, if available.

Environmental exposure controls: No special requirements under normal use conditions.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Information in this section refers to the product, unless it is specifically stated that substance data is listed

Method / remark
Physical state: Liquid
Colour: Clear , Blue
Odour: Product specific
Odour threshold: Not applicable
Melting point/freezing point (°C): Not determined Not relevant to classification of this product
Initial boiling point and boiling range (°C): Not determined See substance data

Substance data, boiling point

Ingredient(s) Value Method Atmospheric pressure
(°C) (hPa)
alkyl alcohol ethoxylate > 232.2 Method not given
tetrasodium ethylene diamine tetraacetate No data available Non-experimental data
n-alkyl dimethyl benzyl ammonium chloride > 107 Method not given

Method / remark
Flammability (solid, gas): Not applicable to liquids
Flammability (liquid): Not flammable.
Flash point (°C): Not applicable.
Sustained combustion: Not applicable.
( UN Manual of Tests and Criteria, section 32, L.2 )
Lower and upper explosion limit/flammability limit (%): Not determined See substance data

Substance data, flammability or explosive limits, if available:

Ingredient(s) Lower limit Upper limit
(% vol) (% vol)
n-alkyl dimethyl benzyl ammonium chloride - -

Method / remark
Autoignition temperature: Not determined
Decomposition temperature: Not applicable.
pH: ≈ 10 (neat) ISO 4316
Kinematic viscosity: Not determined
Solubility in / Miscibility with water: Fully miscible

Substance data, solubility in water

Ingredient(s) Value Method Temperature
(g/l) (°C)
alkyl alcohol ethoxylate 100 Soluble Method not given
tetrasodium ethylene diamine tetraacetate 500 Method not given 20
n-alkyl dimethyl benzyl ammonium chloride Soluble Method not given

Substance data, partition coefficient n-octanol/water (log Kow): see subsection 12.3

Method / remark
Vapour pressure: Not determined See substance data

Substance data, vapour pressure

Ingredient(s) Value Method Temperature
(Pa) (°C)
alkyl alcohol ethoxylate < 10 Method not given 37.8
tetrasodium ethylene diamine tetraacetate 0.0000000002 Read across 25
n-alkyl dimethyl benzyl ammonium chloride 2300 Method not given 20

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Method / remark
Relative density: ≈ 1.07 (20 °C) OECD 109 (EU A.3)
Relative vapour density: No data available. Not relevant to classification of this product
Particle characteristics: No data available. Not applicable to liquids.

9.2 Other information

9.2.1 Information with regard to physical hazard classes
Explosive properties: Not explosive.
Oxidising properties: Not oxidising.
Corrosion to metals: Not corrosive Weight of evidence

9.2.2 Other safety characteristics

No other relevant information available.

SECTION 10: Stability and reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal storage and use conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions known under normal storage and use conditions.

10.4 Conditions to avoid

None known under normal storage and use conditions.

10.5 Incompatible materials

None known under normal use conditions.

10.6 Hazardous decomposition products

None known under normal storage and use conditions.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Mixture data: .

Relevant calculated ATE(s):

ATE - Oral (mg/kg): >2000
ATE - Dermal (mg/kg): >2000
ATE - Inhalatory, mists (mg/l): >5

Eye irritation and corrosivity

Result: Eye damage 1 Method: OECD 438, Histology

Substance data, where relevant and available, are listed below:.

Acute toxicity
Acute oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure ATE Oral
(mg/kg) time (h) (mg/kg)
alkyl alcohol ethoxylate LD 50 1400 Rat Weight of evidence 1400
tetrasodium ethylene diamine tetraacetate LD 50 1780 Rat OECD 401 (EU B.1) 1780
n-alkyl dimethyl benzyl ammonium chloride LD 50 304.5 Rat 304.5

Acute dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure ATE Dermal
(mg/kg) time (h) (mg/kg)
alkyl alcohol ethoxylate LD 50 2000 - 5000 Rat Weight of evidence Not established
tetrasodium ethylene diamine tetraacetate LD 50 > 5000 Rabbit Method not given Not established
n-alkyl dimethyl benzyl ammonium chloride LD 50 3412 Rabbit Method not given 3412

Acute inhalative toxicity

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)

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alkyl alcohol ethoxylate No data

available
tetrasodium ethylene diamine tetraacetate LC 50 ≥ 1-5 (dust) Rat OECD 403 (EU B.2) 6
n-alkyl dimethyl benzyl ammonium chloride No data
available

Acute inhalative toxicity, continued

Ingredient(s) ATE - inhalation, dust ATE - inhalation, mist ATE - inhalation, ATE - inhalation, gas
(mg/l) (mg/l) vapour (mg/l) (mg/l)
alkyl alcohol ethoxylate Not established Not established Not established Not established
tetrasodium ethylene diamine tetraacetate Not established 30 Not established Not established
n-alkyl dimethyl benzyl ammonium chloride Not established Not established Not established Not established

Irritation and corrosivity

Skin irritation and corrosivity
Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate Not irritant Weight of evidence
tetrasodium ethylene diamine tetraacetate Not irritant Rabbit OECD 404 (EU B.4)
n-alkyl dimethyl benzyl ammonium chloride Corrosive Rabbit Method not given

Eye irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate Severe damage Rabbit Weight of evidence
OECD 437
tetrasodium ethylene diamine tetraacetate Severe damage Method not given
n-alkyl dimethyl benzyl ammonium chloride Severe damage Method not given

Respiratory tract irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate No data available
tetrasodium ethylene diamine tetraacetate No data available
n-alkyl dimethyl benzyl ammonium chloride No data available

Sensitisation
Sensitisation by skin contact
Ingredient(s) Result Species Method Exposure time (h)
alkyl alcohol ethoxylate Not sensitising Weight of evidence
tetrasodium ethylene diamine tetraacetate Not sensitising Guinea pig OECD 406 (EU B.6) /
GPMT
n-alkyl dimethyl benzyl ammonium chloride Not sensitising Guinea pig OECD 406 (EU B.6) /
Buehler test

Sensitisation by inhalation
Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate No data available
tetrasodium ethylene diamine tetraacetate No data available
n-alkyl dimethyl benzyl ammonium chloride No data available

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)

Mutagenicity
Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method
(in-vitro) (in-vivo)
alkyl alcohol ethoxylate No evidence for mutagenicity, negative OECD 473 No data available
test results
tetrasodium ethylene diamine tetraacetate No evidence for mutagenicity, negative Method not No evidence of genotoxicity, negative Method not
test results given test results given
n-alkyl dimethyl benzyl ammonium chloride No evidence of genotoxicity, negative OECD 471 (EU No evidence of genotoxicity, negative OECD 474 (EU
test results B.12/13) OECD test results B.12)
476 OECD 473

Carcinogenicity
Ingredient(s) Effect
alkyl alcohol ethoxylate No evidence for carcinogenicity, negative test results
tetrasodium ethylene diamine tetraacetate No evidence for carcinogenicity, weight-of-evidence
n-alkyl dimethyl benzyl ammonium chloride No data available

Toxicity for reproduction

Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other effects
(mg/kg bw/d) time reported
alkyl alcohol ethoxylate NOAEL > 250 Rat Not known No effects on fertility No

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developmental toxicity
tetrasodium ethylene No data No evidence for reproductive
diamine tetraacetate available toxicity
n-alkyl dimethyl benzyl No data
ammonium chloride available

Repeated dose toxicity

Sub-acute or sub-chronic oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate NOAEL 80 - 400 OECD 408 (EU
B.26)
tetrasodium ethylene diamine tetraacetate No data
available
n-alkyl dimethyl benzyl ammonium chloride No data
available

Sub-chronic dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate NOAEL 80 OECD 411 (EU 90
B.28)
tetrasodium ethylene diamine tetraacetate No data
available
n-alkyl dimethyl benzyl ammonium chloride No data
available

Sub-chronic inhalation toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate No data
available
tetrasodium ethylene diamine tetraacetate No data
available
n-alkyl dimethyl benzyl ammonium chloride No data
available

Chronic toxicity
Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Remark
route (mg/kg bw/d) time organs affected
alkyl alcohol ethoxylate No data
available
tetrasodium ethylene No data
diamine tetraacetate available
n-alkyl dimethyl benzyl No data
ammonium chloride available

STOT-single exposure
Ingredient(s) Affected organ(s)
alkyl alcohol ethoxylate No data available
tetrasodium ethylene diamine tetraacetate No data available
n-alkyl dimethyl benzyl ammonium chloride No data available

STOT-repeated exposure
Ingredient(s) Affected organ(s)
alkyl alcohol ethoxylate No data available
tetrasodium ethylene diamine tetraacetate Respiratory tract
n-alkyl dimethyl benzyl ammonium chloride No data available

Aspiration hazard
Substances with an aspiration hazard (H304), if any, are listed in section 3.

Potential adverse health effects and symptoms

Effects and symptoms related to the product, if any, are listed in subsection 4.2.

11.2 Information on other hazards

11.2.1 Endocrine disrupting properties
Endocrine disrupting properties - Human data, if available:

11.2.2 Other information

No other relevant information available.

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SECTION 12: Ecological information

12.1 Toxicity

No data is available on the mixture .

Substance data, where relevant and available, are listed below:

Aquatic short-term toxicity

Aquatic short-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate LC 50 5-7 Fish 92/69/EEC, C1, 96
semi-static
tetrasodium ethylene diamine tetraacetate LC 50 > 100 Lepomis OPP 72-1, static (EPA) 96
macrochirus
n-alkyl dimethyl benzyl ammonium chloride LC 50 0.515 Fish Method not given 96

Aquatic short-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate EC 50 5.3 Daphnia 92/69/EEC 48
tetrasodium ethylene diamine tetraacetate EC 50 140 Daphnia DIN 38412, Part 11 48
magna Straus
n-alkyl dimethyl benzyl ammonium chloride EC 50 0.016 Daphnia Method not given 48

Aquatic short-term toxicity - algae

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate EC 50 1.4 - 47 Not specified 92/69/EEC 72
tetrasodium ethylene diamine tetraacetate EC 50 > 100 Scenedesmus 88/302/EEC, Part C, 72
obliquus static
n-alkyl dimethyl benzyl ammonium chloride EC 50 0.02 Selenastrum OECD 201 (EU C.3) 72
capricornutum

Aquatic short-term toxicity - marine species

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (days)
alkyl alcohol ethoxylate No data
available
tetrasodium ethylene diamine tetraacetate No data
available
n-alkyl dimethyl benzyl ammonium chloride No data
available

Impact on sewage plants - toxicity to bacteria

Ingredient(s) Endpoint Value Inoculum Method Exposure
(mg/l) time
alkyl alcohol ethoxylate EC 50 > 140 Bacteria DIN EN ISO 3 hour(s)
8192-OECD
209-88/302/EEC
tetrasodium ethylene diamine tetraacetate EC 20 > 500 Activated OECD 209 0.5 hour(s)
sludge
n-alkyl dimethyl benzyl ammonium chloride EC 20 5 Activated OECD 209 0.5 hour(s)
sludge

Aquatic long-term toxicity

Aquatic long-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
alkyl alcohol ethoxylate EC 10 8.983 Not specified Method not 21 day(s)
given
tetrasodium ethylene diamine tetraacetate NOEC > 25.7 Brachydanio OECD 210 35 day(s)
rerio
n-alkyl dimethyl benzyl ammonium chloride No data
available

Aquatic long-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
alkyl alcohol ethoxylate EC 10 2.579 Daphnia sp. Method not 21 day(s)
given
tetrasodium ethylene diamine tetraacetate NOEC 25 Daphnia OECD 211 21 day(s)
magna

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n-alkyl dimethyl benzyl ammonium chloride NOEC 0.025 Daphnia OECD 211 21 day(s)
magna

Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
sediment)
alkyl alcohol ethoxylate No data
available
tetrasodium ethylene diamine tetraacetate No data
available
n-alkyl dimethyl benzyl ammonium chloride No data
available

Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
tetrasodium ethylene diamine tetraacetate LD 50 156 Eisenia fetida OECD 207 14
n-alkyl dimethyl benzyl ammonium chloride No data
available

Terrestrial toxicity - plants, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
tetrasodium ethylene diamine tetraacetate NOEC 0.25 - 1.25 21
n-alkyl dimethyl benzyl ammonium chloride No data
available

Terrestrial toxicity - birds, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
time (days)
n-alkyl dimethyl benzyl ammonium chloride No data
available

Terrestrial toxicity - beneficial insects, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
n-alkyl dimethyl benzyl ammonium chloride No data
available

Terrestrial toxicity - soil bacteria, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
n-alkyl dimethyl benzyl ammonium chloride No data
available

12.2 Persistence and degradability

Abiotic degradation
Abiotic degradation - photodegradation in air, if available:
Ingredient(s) Half-life time Method Evaluation Remark
tetrasodium ethylene diamine tetraacetate No data available
n-alkyl dimethyl benzyl ammonium chloride No data available

Abiotic degradation - hydrolysis, if available:

Ingredient(s) Half-life time in fresh Method Evaluation Remark
water
tetrasodium ethylene diamine tetraacetate No data available
n-alkyl dimethyl benzyl ammonium chloride No data available

Abiotic degradation - other processes, if available:

Ingredient(s) Type Half-life time Method Evaluation Remark
tetrasodium ethylene No data available
diamine tetraacetate
n-alkyl dimethyl benzyl No data available
ammonium chloride

Biodegradation
Ready biodegradability - aerobic conditions

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Ingredient(s) Inoculum Analytical DT 50 Method Evaluation

method
alkyl alcohol ethoxylate OECD 301B Readily biodegradable
tetrasodium ethylene diamine tetraacetate Weight of Not readily biodegradable.
evidence
n-alkyl dimethyl benzyl ammonium chloride Oxygen depletion > 60% Read across Readily biodegradable

Ready biodegradability - anaerobic and marine conditions, if available:

Ingredient(s) Medium & Type Analytical DT 50 Method Evaluation
method
tetrasodium ethylene diamine tetraacetate No data available
n-alkyl dimethyl benzyl ammonium chloride No data available

Degradation in relevant environmental compartments, if available:

Ingredient(s) Medium & Type Analytical DT 50 Method Evaluation
method
tetrasodium ethylene diamine tetraacetate No data available
n-alkyl dimethyl benzyl ammonium chloride No data available

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log Kow)
Ingredient(s) Value Method Evaluation Remark
alkyl alcohol ethoxylate 3.11 - 4.19 Method not given High potential for bioaccumulation
tetrasodium ethylene diamine -3.86 Method not given No bioaccumulation expected
tetraacetate
n-alkyl dimethyl benzyl ammonium 0.004 Method not given No bioaccumulation expected at 20 °C
chloride

Bioconcentration factor (BCF)

Ingredient(s) Value Species Method Evaluation Remark
alkyl alcohol ethoxylate < 500 Method not given High potential for bioaccumulation
tetrasodium ethylene 1.8 Lepomis OECD 305 Low potential for bioaccumulation
diamine tetraacetate macrochirus
n-alkyl dimethyl benzyl 79 Lepomis Low potential for bioaccumulation
ammonium chloride macrochirus

12.4 Mobility in soil

Adsorption/Desorption to soil or sediment
Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation
coefficient coefficient type
Log Koc Log Koc(des)
alkyl alcohol ethoxylate No data available Potential for mobility in soil,
soluble in water
tetrasodium ethylene diamine tetraacetate No data available Adsorption to solid soil
phase is not expected
n-alkyl dimethyl benzyl ammonium chloride No data available

12.5 Results of PBT and vPvB assessment

Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3.

12.6 Endocrine disrupting properties

Endocrine disrupting properties - Environmental effects, if available:

12.7 Other adverse effects

No other adverse effects known.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Waste from residues / unused The concentrated contents or contaminated packaging should be disposed of by a certified handler
products: or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging
material is suitable for energy recovery or recycling in line with local legislation.
European Waste Catalogue: 20 01 29* - detergents containing dangerous substances.

Empty packaging
Recommendation: Dispose of observing national or local regulations.
Suitable cleaning agents: Water, if necessary with cleaning agent.

SECTION 14: Transport information

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Land transport (ADR/RID), Sea transport (IMDG), Air transport (ICAO-TI / IATA-DGR)
14.1 UN number or ID number: Non-dangerous goods
14.2 UN proper shipping name: Non-dangerous goods
14.3 Transport hazard class(es): Non-dangerous goods
14.4 Packing group: Non-dangerous goods
14.5 Environmental hazards: Non-dangerous goods
14.6 Special precautions for user: Non-dangerous goods
14.7 Maritime transport in bulk according to IMO instruments: Non-dangerous goods

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations :
• Regulation (EC) 1907/2006 - REACH (UK amended)
• Regulation (EC) 1272/2008 - CLP (UK amended)
• Regulation (EC) 648/2004 - Detergents regulation (UK amended)
• Biocidal Products Regulations 2001 (SI 2001/880)
• Delegated Regulation (EU) 2017/2100 and Regulation (EU) 2018/605 (UK amended)
• Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)
• International Maritime Dangerous Goods (IMDG) Code

Authorisations or restrictions (Regulation (EC) No 1907/2006, Title VII respectively Title VIII): Not applicable.

Ingredients according to Detergents Regulation

non-ionic surfactants, phosphates 5 - 15 %
EDTA and salts thereof <5%
perfumes , Hexyl Cinnamal, Limonene, Citronellol, Benzyl Alcohol, disinfectants

The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) 648/2004 on
detergents (UK amended). Data to support this assertion are held at the disposal of the competent authorities of the UK and will be made
available to them, at their direct request or at the request of a detergent manufacturer.

Comah - classification: Not classified

15.2 Chemical safety assessment

A chemical safety assessment has not been carried out on the mixture

SECTION 16: Other information

The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract

SDS code: MS1003506 Version: 02.0 Revision: 2024-08-05

Reason for revision:

Overall design adjusted in accordance with Amendment 2020/878, Annex II of Regulation (EC) No 1907/2006, This data sheet contains
changes from the previous version in section(s):, 2, 3, 4, 6, 7, 8, 16

Classification procedure
The classification of the mixture is in general based on calculation methods using substance data, as required by Regulation (EC) No
1272/2008. If for certain classifications data on the mixture is available or for example bridging principles or weight of evidence can be used for
classification, this will be indicated in the relevant sections of the Safety Data Sheet. See section 9 for physical chemical properties, section 11
for toxicological information and section 12 for ecological information.

Abbreviations and acronyms:

• AISE - The international Association for Soaps, Detergents and Maintenance Products
• ATE - Acute Toxicity Estimate
• DNEL - Derived No Effect Limit
• EC50 - effective concentration, 50%
• ERC - Environmental release categories
• EUH - CLP Specific hazard statement
• LC50 - Lethal Concentration, 50% / Median Lethal Concentration
• LCS - Life cycle stage
• LD50 - Lethal Dose, 50% / Median Lethal dose
• NOAEL - No observed adverse effect level
• NOEL - No observed effect level
• OECD - Organisation for Economic Cooperation and Development

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• PBT - Persistent, Bioaccumulative and Toxic

• PNEC - Predicted No Effect Concentration
• PROC - Process categories
• REACH number - REACH registration number, without supplier specific part
• vPvB - very Persistent and very Bioaccumulative
• H302 - Harmful if swallowed.
• H312 - Harmful in contact with skin.
• H314 - Causes severe skin burns and eye damage.
• H318 - Causes serious eye damage.
• H332 - Harmful if inhaled.
• H373 - May cause damage to organs through prolonged or repeated exposure.
• H400 - Very toxic to aquatic life.
• H410 - Very toxic to aquatic life with long lasting effects.

End of Safety Data Sheet

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