MOLE CONCEPT [1]

JEE EXPERT
CHEMISTRY - PRACTICE ASSIGNMENT
TOPIC : MOLE CONCEPT
Q.1 Find the number of mole of chloride ion needed to react with sufficient silver nitrate to make 10.0
g of AgCl. What mass of CaCl2 is required to provide this number of mole of Cl – ?
Q.2 How many kg of pure H2SO4 could be obtained from 2.00 kg of pure iron pyrites (FeS2) according
to the following reactions ?
4FeS2 + 11O2 2Fe2O3 + 8SO2 , 2SO2 + O2 2SO3 , SO3 + H2O H2SO4
Q.3 A solution contains 0.18 g/ml of a substance, X, whose molecular weight is approximately 68000.
It is found that 0.27 ml of oxygen at 760 mm and 30°C will combine with the amount of X
contained in 1.0 ml of the solution. How many molecules of oxygen will combine with one molecule
of X ?
Q.4 5g sample of brass was dissolved in one litre dil. H2SO4. 20 ml of this solution were mixed with
Kl, liberating I2 and Cu+ and the I2 required 20 ml of 0.0327 N hypo solution for complete
titration. Calculate the percentage of Cu in the alloy.
Q.5 A compound which contains one atom of X and two atoms of Y for each three atoms of Z is made
by mixing 5.00 g of X, 1.15 ×1023 atoms of Y and 0.03 mole of Z atoms. Given that only 4.40 g of
compound results. Calculate the atomic weight of Y if the atomic weights of X and Z are 60 and 80
amu respectively.
Q.6 Calculate the mass of oxalic acid which can be oxidized by 100ml of M MnO4– solution, 10ml of
which is capable of oxidizing 50ml of 1N I– to I2.
Q.7 The iodide content of a solution was determined by the titration with cerium (IV) sulphate in the
presence of HCl, in which I- is converted of ICl. A 250 ml sample of the solution required
20 ml of 0.05 N Ce4+ solution. What is the iodide concentration in the original solution in g/litre.
Q.8 A solution is made by mixing 200 ml of 0.1M FeSO 4, 200 ml of 0.1 M KMnO 4 and
600 ml of 1M HClO4. A reaction occurs in which Fe 2+ is converted to Fe3+ & MnO4– to Mn2+ in
acid solution. Calculate the concentration of each ion.
Q.9 How many mole FeCl 3 can be prepared by the reaction of 10.0g KMnO 4, 1.07 mol FeCl 2, and
500 mL of 3.00 M HCl? MnCl2 is the reduction product.
Q.10 To 100ml of KMnO4 solution containing 0.632 gm of KMnO4, 200 ml of SnCl2 solution containing
2.371 gm is added in presence of HCl. To the resulting solution excess of HgCl 2 is added all at
once. How many gms of Hg2Cl2 will be precipitated.
Q.11 How many gram KMnO4 should be taken to make up 250 mL of a solution of such concentration
that 1mL is equivalent to 5.00 mg iron in FeSO4?
Q.12 Exactly 40 ml of an acidified solution of 0.4 M iron (II) ion is titrated with KMnO4 solution. After
addition of 32 ml KMnO 4, one additional drop turns the iron solution purple. Calculate the
concentration of permanganate solution.
Q.13 Potassium acid oxalate K 2C2O4.3H2C2O4.4H2O can be oxidized by MnO 4- in acid medium.
Calculate the volume of 0.1M KMnO4 reacting in acid sol. with one gram of the acid oxalate.
Q.14 The reaction Cl 2 + S2O32-  SO42- + Cl- is to be carried out in basic medium. Starting with
0.15 mol of Cl 2, 0.01 mol S 2O32- and 0.3 mol of OH-, how many moles of OH - will be left in
solution after the reaction is complete. Assume no other reaction occurs.
Q.15 0.5M KMnO4 solution completely reacts with 0.05M FeC 2O4 solution under acidic conditions
where the products are Fe3+, CO2 and Mn2+. The volume of FeC2O4 used is 125 ml. What volume
of KMnO4 was used.
JEE EXPERT Pvt Ldt. 16/71-C, Near Income Tax Office, Civil lines, Kanpur. Mob. No-9919447742/43,9369216022 .[Link]
MOLE CONCEPT [2]
Q.16 K2Cr2O7 oxidizes HCl to Cl 2, which oxidizes K 2MnO4. Calculate the weight of KMnO 4 formed
from one gram of potassium dichromate by reacting it with excess HCl and using the generated
chlorine for oxidizing K2MnO4 (Mn = 55; Cr = 52)
Q.17 A mixture of CaCl2 and NaCl weighing 2.385 g was dissolved in water and treated with a solution
of sodium oxalate which produces a precipitate of calcium oxalate. The precipitate was filtered
from the mixture and then dissolved in HCl to give oxalic acid which when titrated against 0.2M
KMnO4 consumed 19.64 mL of the latter. What was percentage by mass of CaCl 2 in the original
sample?
Q.18 A certain volume of Ferric sulphate solution was reduced by excess of zinc and was then titrated
against 0.1N KMnO4 solution. The titre value was 30 ml. The same volume of ferric salt solution
was reduced by another metal X and then titrated against 0.1 N KMnO4 and the titre value was 45
ml. What are the oxidation states of metal X .
Q.19 1.44g pure FeC2O4 was dissolved in dil. HCl and solution diluted to 100 mL. Calculate volume of
0.01 M KMnO4 required to oxidize FeC2O4 solution completely.
Q.20 0.804 gm of a sample of iron ore was dissolved in acid. Iron was oxidized to +2 state and it
required 117.2 ml of 0.112 N KMnO 4 solution for titration. Calculate the percentage of Fe and
FeO in the ore.
Q.21 KMnO4 oxidises X+n ion to XO3–, itself changing to Mn+2 in acid solution. 2.68 × 10–3 mole of X+n
requires 1.61 × 10–3 mole of MnO4–. What is the value of n? Also calculate the atomic mass of X,
if the weight of 1 g equivalent of XCln is 56.
Q.22 A sample of Fe2(SO4)3 and FeC2O4 was dissolved in dil. H2SO4. The complete oxidation of reaction
mixture required 40 mL of N/16 KMnO4. After the oxidation, the reaction mixture was reduced by
Zn and dil. H2SO4. On again oxidation by same KMnO4, 60 mL were required. Calculate the ratio
of Meq. of Fe2(SO4)3 and FeC2O4 in mixture.
Q.23 2.6 g sample of pyrolusite was boiled with 65 mL. of N oxalic acid and excess of dil. H 2SO4. The
liquid was then filtered and the residue washed. The filtrate and the washing were mixed and made
upto 500 mL. 100 mL of this solution required 50 mL of N/10 KMnO 4. Calculate % of MnO2 in
sample.
Q.24 0.5 g sample of iron containing mineral mainly in the form of CuFeS 2 was reduced suitably to
convert all the ferric ions into ferrous ions (Fe +3  Fe+2) and was obtained as solution. In the
absence of any interfering radical, the solution required 42 mL of 0.01 M K 2Cr2O7 for titration.
Calculate % of CuFeS2 in sample.
Q.25 Mg can reduce NO3– to NH3 in basic solution:
NO3– + Mg(s) + H2O Mg(OH)2(s) + OH–(aq) + NH3(g)
A 25.0 mL sample of NO3– solution was treated with Mg. The NH3(g) was passed into mL of 0.15
N HCl. The excess HCl required 32.10 mL of 0.10 M NaOH for its neutralisation. What was the
molarity of NO3– ions in the original sample?

ANSWER KEY
1. 0.0697, 3.86 g 2. 3.26 kg 3. 4 4. 41.53%
5. At. wt. of Y = 70 amu 6. 22.5 gm 7. 0.254 g/l
8. Fe3+ = 0.02M;MnO4- = 0.016 M ;
H+ = 0.568 M;Mn2+ = 0.004M; SO4--=0.02M;K+ = 0.02M, ClO4- = 0.6M
9. 0.316 mol FeCl 3 10. 1.176 gm 11. KMnO4 = 0.707g
12. 0.1M 13. V = 31.68 ml 14. 0.2 moles OH- 15. 7.5 ml
16. 3.22 gm 17. CaCl2 = 45.7% 18. +2 & +3
19. 600 mL MnO4- solution 20. % Fe = 61.43; %FeO = 38.57 21. n = 2, a = 97
22. 7 : 6 23. 66.92% 24. 92.48%
25. N NO  = 1.37, M NO = 0.1716
3 3

JEE EXPERT Pvt Ldt. 16/71-C, Near Income Tax Office, Civil lines, Kanpur. Mob. No-9919447742/43,9369216022 .[Link]