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abd
ion a enc, ¢
agnetio” Substance ci.e moteutes eseuing €
with unpaired es),
Ese is also tnown os Glect-ran [Link]
CEPR) o Glectron magnetic Pesononce CemeR)
fuse UeetH nucle, electron with its Spin io pore
-llgna tie and also poser a magnetic moment. Gf a—
Creve preqHen b applied, telesit undergo bronsitio
—-8 petween Spin Stoten © for the ele on £0, hb.
Measurement o-eledran Spin transition & the bas
q clechron spin resonance specrroscopy CES® )
netic Resonance
(or an unpolred. eleceron s etl C
ese wv Catled hyperfine. splitting ta).
w orm
Cince 2G & men ma
eqpaty & paced Lines C0 the Ese
woet that au the three hydro
grate, me Derther tgperzine
Splitting, & produced:
cH,
| iwalent- protons, the = Lines expected 1%
gon @
jected. for each sel-,
the product the number @
fee conz+ 12 Cam zy +10
an cave ef rapthalene —ve Ton Caedicat anion)
there ave 2 acto f 4 equivalent
7 protons © P
ren i.e Cac4) +1? calah + 1) ee
5x5 cas, 4 totalne gfine
peacs coch sit 5 thers KU farms ‘as tines
coch Sit 5 ee ee d
- Scanned by CamScanner * madteat
“muse ia tha 6 as Causa “yplte
mmwelal cotth meshes | ne ee Conn) 2 ve
Lf. The appearance Seven
Apaced. Coos are die 40 PP ngleoper cle
Blanca Me 5
@ Me iy mon- magnate no forther by)
|2- eHow watreot
here are two seo f 2 protons ta+iD
tie canr+0 CamL+y)
CacoIpr0 C2R*IKBTID
“ % yo « 6 bing Al be observed.
|? . Pe bengogpinone evactical anion
oF
at conta 4 equivalent protons 5 therfore
five nw appeats- Cont +1d
|
| ° Ot4ahlkl eT
Ae Cyclepent drengt anfen edicol .
Che. odd en is delocalised over out thes
2. at appears 6 Une
BKSHA er) = 6.
a al
‘Scanned by CamScanner 4- Structural determination %- - usin
Sn ba decent
Electronic environment
ides cngermats soreh cahich
Eee ghactros. Loe °
Le ee ognetic. acto!
the unpaired electron Interacts.
ft [ietiog—
fold. the hyperfine P
cshich al related to f
spi density &
Te spasing ¢ the Lines
emstant 2! and ‘g' - value,
the way in uchich e unpotred. e7
olistvibuted co the moteute.
fer of wadical.
'
: S tracturat application vange from Ongonic, io Teg
0. ometauic wadicals to ce-Ovdinatio? comple
S bretogicot macromolecules Containing Poramagnetic |
Center:
a- Shudes af fue ewadicals. i
Ct & Widdy wsed to study the nature ¢ Organic
feroe wadicah fpvoduced by Chemical veaction .
Gx Comparison ¢ free- qadicals ¢ 0,p ¢ M-ruzlenes,
p-ugleoe anton wadical .
There ave. ivaleat- ein, Ss
re genes
CH, =
Ay, 4 6 equivalent methyl protons |
we erpet to See Ir4i6:47iCquintet) — —
4
av g be sisiaoiiszt6 + | Csebeer)
cH, “vesbectivaty
—
"Scanned by CamScanner
24 ce me ee
fxs C9 +0)"
Peon: methgt brotens,
eckram shows j1a% 1 Esiplr couple d-
woith Septet @ methy! a
m- oylene anion wadicat
4 = a
“ There are °
Cc. . 3 be g@ wing proton out
¥ | which 9 are spoil ton otk ee
u pomgpivatent §. Bix equivalent methyl
proton, 250 sheckwum gives a multiplet
a Signals with complex. Lael
3: Studs q paramagnetic Specie, —
Lnocon to faviolva the
Many chemical reaction ave
formation ¢ paramagnetic Inter meciiates, most thse
uns table Z eke beige rrepettvity, In cee |
ouise
Ese signal peeved vusepul ingormathor creqgardlinb
these gpecior. .
or when adolipted. seln, 4 Tic, reacts eofth cH cH OH
6 Ho, the free arodtcals CHOH § CH,CH 0H ave
produced . . a .
cH, HOw Cocayti) C2co%+
chon Calas atD AkD 2&
je tar A
4. Determination of Calin
E+ can be sed 40 determine the vate ¢ chemfeal
qeattion or vole g a Gong esmation change, the g
line widths are vel lated, to the sate $ the rotational
mottos which avd an isctaepius th the ‘git 4 «|
2 s § Ne |
Matrices. q Pees \ thatena in added. to Solutfen Conta:
vradieat tam, then elector exchan
4 adening g the hyperfine sta ture,
math bavadaning can be emp Gee to calewate the
ate constants for the! gachan Is + ar ber napthal
“
Naptha lena anion vadies .
¢ Studley Oxgano-metaltic 4 tvansition metal complete
fnce. the runpatred, e's of the da f-osbitals subshells
¥ Tension metals give ES@ Signal. this produces a
én ri ed. gor chet mining. electron distvibeetions
« Emmediara Viein ty ¢- the atoms, .
Bima. cucm) Compleres having #4 conyiguration ae aq
& trang Signal , cohere as CuCl) complexes ch®) signal
fo Mol~ go Strong,
on this bast, the nature o Cu in a Copper ~ proton
Compler. con be determined.
2+ Staacturat ongormation y Cie )e- Co- 0-00 o — CNHs]
ESR sheerwrum Shoum is Lined, ebtaine due+tothe
aresence tov Seb g 15 equivalent protons . it ao
Concluded. that the two CoCit? atems ave connected|
buy -—0-0- bridge § there & an Interaction gf ‘edol|
btece-ren with Both the Cobate iplone~
