SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : ANVIL 5 SC

Design code : A12700A

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the : Fungicide
Substance/Mixture

1.3 Details of the supplier of the safety data sheet

Company : Syngenta Crop Protection AG
Postfach
CH-4002 Basel
Switzerland

Telephone : +41 61 323 11 11

Telefax : +41 61 323 12 12

E-mail address of person : [email protected]

responsible for the SDS

1.4 Emergency telephone number

Emergency telephone : +44 1484 538444
number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Skin sensitisation, Category 1 H317: May cause an allergic skin reaction.

Chronic aquatic toxicity, Category 3 H412: Harmful to aquatic life with long lasting
effects.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal word : Warning

Hazard statements : H317 May cause an allergic skin reaction.

H412 Harmful to aquatic life with long lasting effects.

Supplemental Hazard : EUH401 To avoid risks to human health and the

Statements environment, comply with the instructions for use.

Precautionary statements :
Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P280 Wear protective gloves.
Response:
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P362 + P364 Take off contaminated clothing and wash it
before reuse.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Hazardous components which must be listed on the label:

hexaconazole (ISO)
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Hazardous components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Index-No.
Registration number
hexaconazole (ISO) 79983-71-4 Acute Tox. 4; H302 >= 2.5 - < 10
413-050-7 Skin Sens. 1; H317
613-171-00-7 Aquatic Chronic 2;
H411

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Have the product container, label or Safety Data Sheet with
you when calling the emergency number, a poison control
center or physician, or going for treatment.

If inhaled : Move the victim to fresh air.

If breathing is irregular or stopped, administer artificial
respiration.
Keep patient warm and at rest.
Call a physician or poison control centre immediately.

In case of skin contact : Take off all contaminated clothing immediately.

Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
Wash contaminated clothing before re-use.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Remove contact lenses.
Immediate medical attention is required.

If swallowed : If swallowed, seek medical advice immediately and show this

container or label.
Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Nonspecific
No symptoms known or expected.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : There is no specific antidote available.
Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Extinguishing media - small fires
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Extinguishing media - large fires
Alcohol-resistant foam
or
Water spray

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread
media fire.

5.2 Special hazards arising from the substance or mixture

Specific hazards during : As the product contains combustible organic components, fire
firefighting will produce dense black smoke containing hazardous
products of combustion (see section 10).
Exposure to decomposition products may be a hazard to
health.

5.3 Advice for firefighters

Special protective equipment : Wear full protective clothing and self-contained breathing
for firefighters apparatus.

Further information : Do not allow run-off from fire fighting to enter drains or water
courses.
Cool closed containers exposed to fire with water spray.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Refer to protective measures listed in sections 7 and 8.

6.2 Environmental precautions

Environmental precautions : Prevent further leakage or spillage if safe to do so.
Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Clean contaminated surface thoroughly.
Clean with detergents. Avoid solvents.
Retain and dispose of contaminated wash water.

6.4 Reference to other sections

For disposal considerations see section 13., Refer to protective measures listed in sections 7 and 8.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : No special protective measures against fire required.
Avoid contact with skin and eyes.

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according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

When using do not eat, drink or smoke.

For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : No special storage conditions required. Keep containers
areas and containers tightly closed in a dry, cool and well-ventilated place. Keep out
of the reach of children. Keep away from food, drink and
animal feedingstuffs.

7.3 Specific end use(s)

Specific use(s) : For proper and safe use of this product, please refer to the
approval conditions laid down on the product label.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form Control parameters Basis
of exposure)
hexaconazole 79983-71-4 TWA 1 mg/m3 Syngenta
(ISO)
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health Value
effects
propane-1,2-diol Workers Inhalation Long-term systemic 168 mg/m3
effects
Consumers Inhalation Long-term local 10 mg/m3
effects
Consumers Inhalation Long-term systemic 30 mg/m3
effects
Workers Inhalation Long-term local 10 mg/m3
effects
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
propane-1,2-diol Fresh water 260 mg/l
Marine water 26 mg/l
Intermittent use/release 183 mg/l
Sewage treatment plant 20000 mg/l
Marine sediment 57.2 mg/kg
Fresh water sediment 572 mg/kg
Soil 50 mg/kg
8.2 Exposure controls

Engineering measures
Containment and/or segregation is the most reliable technical protection measure if exposure
cannot be eliminated.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

The extent of these protection measures depends on the actual risks in use.

Maintain air concentrations below occupational exposure standards.

Where necessary, seek additional occupational hygiene advice.

Personal protective equipment

Eye protection : No special protective equipment required.

Hand protection

Material : Nitrile rubber

Break through time : > 480 min
Glove length : 0.5 mm

Remarks : Wear protective gloves. The choice of an appropriate glove

does not only depend on its material but also on other quality
features and is different from one producer to the other.
Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local
conditions under which the product is used, such as the
danger of cuts, abrasion, and the contact time. The break
through time depends amongst other things on the material,
the thickness and the type of glove and therefore has to be
measured for each case. Gloves should be discarded and
replaced if there is any indication of degradation or chemical
breakthrough.
The selected protective gloves have to satisfy the
specifications of EU Directive 89/686/EEC and the standard
EN 374 derived from it.

Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to
the specific work-place.
Remove and wash contaminated clothing before re-use.
Wear as appropriate:
Impervious clothing

Respiratory protection : No personal respiratory protective equipment normally

required.
When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.

Protective measures : The use of technical measures should always have priority
over the use of personal protective equipment.
When selecting personal protective equipment, seek
appropriate professional advice.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : suspension, fluid

Colour : off-white

Odour : No data available

Odour Threshold : No data available

pH : No data available

Melting point/range : No data available

Boiling point/boiling range : No data available

Flash point : No data available

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure :
No data available
Relative vapour density : No data available

Density : 1 g/ml

Solubility(ies)
Solubility in other solvents : Miscible
Solvent: Water

Partition coefficient: n- : No data available

octanol/water

Auto-ignition temperature : 435 °C

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

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according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

9.2 Other information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity
None reasonably foreseeable.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

Conditions to avoid : No decomposition if used as directed.

10.5 Incompatible materials

Materials to avoid : None known.

10.6 Hazardous decomposition products

Hazardous decomposition : No hazardous decomposition products are known.
products

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Information on likely routes of : Ingestion
exposure Inhalation
Skin contact
Eye contact

Acute toxicity

Product:
Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg
Method: Calculation method

Components:

hexaconazole (ISO):
Acute oral toxicity : LD50 (Rat, male): 2,189 mg/kg

Acute toxicity estimate: 500 mg/kg

Method: Converted acute toxicity point estimate

Acute inhalation toxicity : LC50 (Rat): > 5.9 mg/l

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according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute
inhalation toxicity

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity

Skin corrosion/irritation

Components:

hexaconazole (ISO):
Species : Rabbit
Result : No skin irritation

Serious eye damage/eye irritation

Components:

hexaconazole (ISO):
Species : Rabbit
Result : No eye irritation

Respiratory or skin sensitisation

Components:

hexaconazole (ISO):
Species : Guinea pig
Result : May cause sensitisation by skin contact.

Germ cell mutagenicity

Components:

hexaconazole (ISO):
Germ cell mutagenicity- : Animal testing did not show any mutagenic effects.
Assessment

Carcinogenicity

Components:

hexaconazole (ISO):
Carcinogenicity - : No evidence of carcinogenicity in animal studies.
Assessment

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according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
8.0 07.03.2018 S155038718

Reproductive toxicity

Components:

hexaconazole (ISO):
Reproductive toxicity - : No toxicity to reproduction
Assessment

SECTION 12: Ecological information

12.1 Toxicity

Product:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 40 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 113 mg/l
aquatic invertebrates

Components:

hexaconazole (ISO):
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 3.4 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 2.9 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (green algae)): 19

mg/l
Exposure time: 96 h

12.2 Persistence and degradability

Components:

hexaconazole (ISO):
Stability in water : Degradation half life: > 30 d
Remarks: Persistent in water.

12.3 Bioaccumulative potential

Components:

hexaconazole (ISO):
Bioaccumulation : Remarks: Does not bioaccumulate.

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ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
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12.4 Mobility in soil

Components:

hexaconazole (ISO):
Distribution among : Remarks: Hexaconazole has low to slight mobility in soil.
environmental compartments

Stability in soil : Dissipation time: 49 - 238 d

Percentage dissipation: 50 % (DT50)
Remarks: Product is not persistent.

12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..

Components:

hexaconazole (ISO):
Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT).. This substance is not
considered to be very persistent and very bioaccumulating
(vPvB)..

12.6 Other adverse effects

No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Do not contaminate ponds, waterways or ditches with
chemical or used container.
Do not dispose of waste into sewer.
Where possible recycling is preferred to disposal or
incineration.
If recycling is not practicable, dispose of in compliance with
local regulations.

Contaminated packaging : Empty remaining contents.

Triple rinse containers.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.

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according to Regulation (EC) No. 1907/2006

ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
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SECTION 14: Transport information

14.1 UN number
Not regulated as a dangerous good
14.2 UN proper shipping name
Not regulated as a dangerous good
14.3 Transport hazard class(es)
Not regulated as a dangerous good
14.4 Packing group
Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Remarks : Not classified as dangerous in the meaning of transport
regulations.

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Regulation (EC) No 649/2012 of the European : Not applicable
Parliament and the Council concerning the export and
import of dangerous chemicals

REACH - Candidate List of Substances of Very High : Not applicable

Concern for Authorisation (Article 59).

REACH - List of substances subject to authorisation : Not applicable

(Annex XIV)

Regulation (EC) No 1005/2009 on substances that : Not applicable

deplete the ozone layer

Regulation (EC) No 850/2004 on persistent organic : Not applicable

pollutants

REACH - Restrictions on the manufacture, placing on : Not applicable

the market and use of certain dangerous substances,
preparations and articles (Annex XVII)

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
Not applicable

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ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
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Other regulations:
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the
risks related to chemical agents at work.

15.2 Chemical safety assessment

A Chemical Safety Assessment is not required for this substance when it is used in the specified
applications.

SECTION 16: Other information

Full text of H-Statements

H302 : Harmful if swallowed.
H317 : May cause an allergic skin reaction.
H411 : Toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Chronic : Chronic aquatic toxicity
Skin Sens. : Skin sensitisation

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging
Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive
Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances
List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community
number; ECx - Concentration associated with x% response; ELx - Loading rate associated with
x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances
(Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally
Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research
on Cancer; IATA - International Air Transport Association; IBC - International Code for the
Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal
inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic
Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;
PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -
Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very

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ANVIL 5 SC
Version Revision Date: SDS Number: This version replaces all previous versions.
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High Concern; TCSI - Taiwan Chemical Substance Inventory; TRGS - Technical Rule for
Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; vPvB - Very Persistent and Very Bioaccumulative

Further information
Classification of the mixture: Classification procedure:
Skin Sens. 1 H317 Calculation method
Aquatic Chronic 3 H412 Calculation method

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

CH / EN

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