Petroleum Geology and Exploration Guide
Petroleum Geology and Exploration Guide
1.0: INTRODUCTION
5.0: CALCULATIONS
Petroleum geology is the study of origin, occurrence, movement, accumulation, and exploration
of hydrocarbon fuels. It refers to the specific set of geological disciplines that are applied to the
search for hydrocarbons (oil exploration).Hydrocarbons are defined as naturally occurring
organic compounds made up of hydrogen and carbon.
In the petroleum system, HCs exist in two forms; liquid and gas--- (methane, oil and
condensate).
The very fine-grained shale is one of the most common sedimentary rocks on earth. In many
places, thousands upon thousands of feet of shale are stacked up like the pages in a book, deep
underground. It is not unusual to have layers in the earth’s crust made up mostly of shale that are
4 miles thick. These shales were deposited in quiet ocean waters over millions of years time.
During much of the earth’s history, the land areas we now know as continents were covered with
water. This situation allowed tremendous piles of sediment to cover huge areas. The oceans
may have left the land we now live on, but the great deposits of shale and sandstone remain deep
underground….right under our feet!
In the deep ocean, far from land, about the only sediment deposited is the fine-grained clastic
rock known as shale. But what about the oil and gas? For the answer, we need to move to the
ancient oceans that once covered almost all of the earth.
The animals die by the trillions and rain down on the ocean floor all the time. And since the
beginning of life on earth, they have been living their exciting lives in the ocean, dying, sinking
to the bottom, and becoming part of the once-living matter that is part of most shale rocks.
It is the trillions of tiny animals that make up most of the gunk (the scientific name for this gunk
is “ooze”) deposited on the ocean floor. It’s a very fine-grained goop containing a lot of organic
material mixed with the clay-sized particles that form shale. It is called organic-rich shale.
Later, when thousands of feet of organic-rich shales have piled up over millions of years, and the
dead animal bodies are buried very deep (more than two miles down), an amazing thing
happens. The heat from deep inside the earth “cooks” the animals, turning their bodies into
what we call hydrocarbons……oil and natural gas.
At first, the oil and gas only exist between the shale particles as extremely tiny blobs, left over
from the decay of the tiny animals.
Then, the intense pressure of the earth squeezes the oil and gas out of the shale, and the oil and
gas fluids gather together in a porous layer and move sideways many miles. On their way, they
may meet up with other traveling oil or gas fluids.
Finally, the oil and gas may become “trapped” in a rock formation like sandstone or
limestone….a hydrocarbon trap. The oil and gas stay there, under tremendous pressure, until the
petroleum geologist comes looking for it. Without a trap, the geologist has no place to drill. All
oil and gas deposits are held in some sort of trap.
1.2 CONDITIONS FOR PETROLEUM GENERATION
Most of the organisms that generate petroleum are planktons, and as the planktonic OM fall in
large numbers to the seafloor, they are preserved within the sediments if conditions are suitable.
✓ When sedimentation rate is very high so that the organic matter can be buried rapidly.
✓ Sediment grain size should be very small so that oxygen cannot penetrate (i.e. the
environment should be anaerobic and reducing).
✓ No bottom dwellers (benthons) should be around to eat up the organic matter.
NOTE: shales and fine-grained limestones create anoxic environments. They therefore constitute
good source rocks for petroleum.
Vitrinite is a non fluorescent type of organic matter/ material in petroleum source rocks derived
primarily from woody material. The reflectivity of vitrinite is one of the best indicators of coal
rank and thermal maturity of petroleum source rock.
The type and amount of petroleum generated in a basin depend on some factors,,
Based on the above factors, petroleum can be divided into three types, namely;
TYPE I is derived from fine algae present in freshwater lakes particularly in warm climates.
They are usually high quality waxy oils with a H: C ratio of 1.6-1.8.
TYPE I results from planktons, algae and bacteria present in marine and ocean sediments. Most
of the world’s oil belongs to this group. The H: C ratio is usually around 1.44.
TYPE III results from derivatives of land vegetation such as plant fragments, spores and pollens
which have been incorporated into sediments. The material generates coal and /or dry gas. Thick
leafed tropical plants usually produce waxy oils. The H: C ratio is less than 1.0.
1.5 STAGES IN THE FORMATION OF PETROLEUM
Diagenesis
As the fine-grained sediments and organic matter in them get buried by overlying layers,
temperature and pressure begin to rise.
The organic matter is then attacked by anaerobic bacteria which break up the OM into a
structureless substance called kerogen while at the same time liberating methane.
Burial to high temperatures (50-80oC) matures the source rock and the production of
cycloalkanes and alkanes, two of the main components of crude oil begins (Turner, 2001).
In the early phase of the generation of petroleum (diagenesis), the sediments or source rocks are
said to be immature.
Catagenesis
As the temperature of the environment increases with further burial, the bacteria get killed.
At about 600C (the critical ‘jump tempt’), oil starts to form from the kerogen.
With further increase in temperature, the heavy molecules are cracked and progressively lighter
oil is produced. The carbon content of the resulting hydrocarbon increases and the FTC ratio
decreases as temperature increases.
This is the phase during which most of the petroleum is produced and at this point, the sediments
or source rocks are said to be matured.
Metagenesis
At a critical temperature, the point of peak oil generation is reached. After this point, oil
production drops off and ‘wet’ gas is produced.
Beyond 1200C, only dry gas is produced and pre existing heavier hydrocarbons are cracked down
to methane (thermogenic gas).
Above 1500C, all hydrocarbons are destroyed and metamorphism of the source rock is initiated.
At this stage/ time, the sediments or source rocks are said to be over matured.
TIME AFTER BURIAL VS TEMPERATURE PLOT
Majority of the oil generation occurs at the ‘oil window’ at temperature around 75-1200C at
depth of [Link] is no set time between the source rock deposition and when the oil
window is reached. The delay may range from a few million years to 300 million years.
Time after
burial (Ma)
T (0C)
NOTE:
Nearly all petroleum occurs in sediments of marine origin. Conditions in the marine environment
are anoxic and reducing. The oxidizing conditions in the continental environments would not
permit the generation of petroleum, as the organic matter (OG) would decay during oxidation.
2.0: PLAY CONCEPT/ THE PETROLEUM SYSTEM (BASIN ANALYSIS).
The search for oil and gas is a multiphase process involving the following;
Petroleum geology is principally concerned with the evaluation of seven key elements in
sedimentary basins:
• Source
• Reservoir
• Seal
• Trap
• Timing
• Maturation
• Migration
In general, all these elements must be assessed via a limited 'window' into the subsurface world,
provided by one (or possibly more) exploration wells. These wells present only a 1-dimensional
segment through the Earth and the skill of inferring 3-dimensional characteristics from them is
one of the most fundamental in petroleum geology. Recently, the availability of inexpensive,
high quality 3D seismic data (from reflection seismology) and data from various electromagnetic
geophysical techniques (such as Magnetotellurics) has greatly aided the accuracy of such
interpretation. The following section discusses these elements in brief. For a more in-depth
treatise, see the second half of this article below.
Evaluation of the source uses the methods of geochemistry to quantify the nature of organic-rich
rocks which contain the precursors to hydrocarbons, such that the type and quality of expelled
hydrocarbon can be assessed.
The reservoir is a porous and permeable lithological unit or set of units that holds the
hydrocarbon reserves. Analysis of reservoirs at the simplest level requires an assessment of their
porosity (to calculate the volume of in situ hydrocarbons) and their permeability (to calculate
how easily hydrocarbons will flow out of them). Some of the key disciplines used in reservoir
analysis are the fields of structural analysis, stratigraphy, sedimentology, and reservoir
engineering.
The seal, or cap rock, is a unit with low permeability that impedes the escape of hydrocarbons
from the reservoir rock. Common seals include evaporites, chalks and shales. Analysis of seals
involves assessment of their thickness and extent, such that their effectiveness can be quantified.
The trap is the stratigraphic or structural feature that ensures the juxtaposition of reservoir and
seal such that hydrocarbons remain trapped in the subsurface, rather than escaping (due to their
natural buoyancy) and being lost.
Analysis of maturation involves assessing the thermal history of the source rock in order to
make predictions of the amount and timing of hydrocarbon generation and expulsion.
Finally, careful studies of migration reveal information on how hydrocarbons move from source
to reservoir and help quantify the source (or kitchen) of hydrocarbons in a particular area.
Prediction of source rocks, reservoir, top seal and traps requires an understanding of the
stratigraphic and structural evolution of depositional sequences within the basin. This
understanding can be achieved through basin analysis, which serves as a platform for the
assessment of petroleum play.
Correct identification and interpretation of the fundamental tectonic and thermal processes
controlling basin formation and the geometry and sedimentary facies contained in the basin fill is
the first and most important step towards building the geological models that underpin play
assessment.
The basic unit of petroleum resource assessment is the play, but the ‘petroleum system’ concept
is also a useful way for the practicing petroleum geologist to organize his/her investigation.
1. The first requirement for play is that there should be a petroleum charge system. The
petroleum charge system comprises source rocks, which must be capable of regenerating
and expelling petroleum and a migration pathway into the reservoir unit. Source rocks are
sediments rich in organic matter derived from photosynthesizing marine algae and land
plants, containing chemical compounds known as lipids. Lipids are preserved when
sediments are preserved under anoxic conditions. Lakes, deltas and marine basins
are the main depositional settings of source beds.
2. A further requirement for a play is a porous and permeable reservoir rock. Pore space
enables the reservoir to act as a tank of hydrocarbons and permeability provides the
plumbing system by which the reservoir may be drained of its hydrocarbon content. In
both carbonates and sandstones, reservoir quality depends on depositional
environment and palaeoclimate, but is very strongly affected by diagenetic pathway.
The nature of near surface diagenesis is predictable from the position in a depositional
sequence. A number of scales of heterogeneity exist, from km scale to microscopic, that
affect the distribution of porosity and permeability in the gross reservoir unit. Particular
basin tectonic settings have association with particular type of reservoir geometry and
composition.
3. A regional top seal, or cap rock is needed to seal the petroleum in a gross reservoir unit.
The mechanics of sealing is the same as those that control secondary migration. The ideal
cap rock is of a fine-grained lithology and is ductile and laterally persistent. Thickness
and depth of burial do not appear to be critical. Two of the most successful reservoir cap
rock associations are where marine shales transgress over gently sloping clastic shelves,
and where evaporites regress over shallow- marine carbonate shelves.
4. The final requirement for the operation of a petroleum play is the presence of traps. Traps
are local subsurface concentrations of petroleum and may be classified into structural,
stratigraphic, and hydrodynamic traps. Structural traps represent the habitat of most of the
world’s already discovered petroleum, and are formed by tectonic diapiric and
gravitational processes. Stratigraphic traps are those inherited from the original
diagenetic effects. Large volumes of undiscovered petroleum probably reside in
stratigraphic traps, and owing to difficulties in detection, may remain so.
Play concepts are founded on an understanding of the stratigraphic and structural evolution
of the basin. The geological model upon which predictions f sources, reservoir and cap rocks,
and their evolution through time are based on outcomes of this understanding. The validity of
these models and therefore of the plays that are generated from them is dependent on a
correct interpretation of the boundaries and overall geometry of the genetic stratigraphic
units. Systems tracts and depositional sequences involved in the play, and on a correct
interpretation of the sedimentary facies within these stratigraphic units. Basin analysis
provides the means of making these interpretations.
Our understandings of basin analysis have shown that the location and overall form of
megasequences and depositional sequences may be understood in terms of the mechanical
processes of basin formation. Thus basin formation due to lithospheric stretching, flexure,
mantle dynamics, and strike-slip deformation each exhibit characteristic locations.
Geometries and evolutions that may be understood in terms of the controlling broad plate
tectonic and mantle processes. Knowledge of the underlying basin forming process also
implies a particular tectonic and thermal development for the basin, which is an important
input to the thermal modeling of potential source rock intervals.
A play may initially be defined as a perception or model in the mind of the geologist of how
a number of geological factors might combine to produce petroleum accumulations at a
specific stratigraphic level in a basin. These geological factors must be capable of providing
the essential ingredients of the petroleum play, namely:
• A reservoir unit, capable of storing the petroleum fluids and yielding them to the
wellbore at commercial rates.
• A petroleum charge system, comprising thermally mature petroleum source rocks
capable of expelling petroleum fluids into porous and permeable carrier beds, which
transport them towards sites of accumulation (traps) in the gross reservoir unit.
• A regional topseal or caprock to the reservoir unit, which contains the petroleum
fluids at the stratigraphic level of the reservoir.
• Petroleum traps, which concentrate the petroleum in specific locations, allowing
commercial exploitation.
• The timely relationship of the above four ingredients so that, for example traps are
available at the time of petroleum charge.
Thus, a play may further be defined as a family of undrilled prospects and discovered pools of
petroleum that are believed to share a common gross reservoir, regional topseal and petroleum
charge system. A brief description of a play might be;
Mid-Jurassic submarine fan sandstone reservoirs in late Jurassic fault blocks, sealed by Lower
Cretaceous marine mudstones, and charged during the Early Tertiary from Upper Jurassic marine
source rocks.
The geographical area over which the play is believed to extend is the play fairway. The extent
of the fairway is determined initially by the depositional or erosional limits of the gross reservoir
unit, but may also be limited by the known absence of any of the other factors.
A play may be considered proven if petroleum accumulations (pools or fields) are known to have
resulted from the operation of the geological factors that define the play. These geological
requirements are thus known to be present in the area under investigation, and the play may be
said to be “working”. In unproven plays, there is some doubt as to whether the geological factors
actually do combine to produce a petroleum accumulation. One of the objectives of play
assessment is to estimate the probability of play working: this is known as play chance.
The movement of petroleum from the source rock to the reservoir and within the reservoir rocks
into a pool is called migration.
At this time of generation, petroleum is dispersed within the sediments as discrete droplets. In
order to accumulate as pools, these droplets must migrate from the source rock into a reservoir
rock where there is sufficient porosity to host it.
The oil is stored in the tiny openings (pores) between the grains in the reservoir rocks and not in
large ravenous openings or underground lakes. Such spaces do not occur or exist underground.
Migration is principally movement along permeability paths, fluid potential gradients and even
temperature gradients. Migration may be over short distances like from source rock to reservoir
rock or over long distances (even hundreds of miles).
Like within the reservoir rock, petroleum movement under its own local pressure from strata into
wellbore shows that petroleum migrates within reservoir rocks.
PRIMARY MIGRATION
This the movement of petroleum from the source rock to the reservoir rock.
Compaction of the strata of the source rock is the main driving force of primary migration.
Compaction takes place under gravity load of the overlying material/sediments, and the process
leads to loss of porosity.
As compaction takes place, all fluids containing within the source rock clays and shales are
squeezed out in a vertical direction.
Migration is believed to be based on the movement of the squeezes water along side with the
colloidal oil droplets and possibly some little oil in solution, to region of lower pressure, which
means shallower depth.
On getting to the reservoir bed, there is gravity separation and the dispersed petroleum particles
flocculate into oil patches that continue to grow until enough oil has come together to develop
buoyancy.
The petroleum now moves independently as a separate phase within the reservoir bed until a
pool is formed.
SECONDARYY MIGRATION
Secondary migration is always in the direction of lower hydrostatic pressure because the
reservoir pressure is the main force responsible for movement at this stage.
Once there is sufficient hydrocarbon within the reservoir, and the permeability pathways are not
blocked by traps, the reservoir pressure will ensure movement. Since petroleum is immiscible in
water and floats on it, as water moves, the petroleum is move along.
The distance of movement within the reservoir rocks is dependent on the size and nature of the
reservoir, its structural configuration, presence or absence of traps or changes in
sedimentological characters.
➢ Oil will normally migrate upward towards the earth’s surface unless it is stopped by an
impermeable bed, which is called a seal.
➢ The stoppage of upward vertical by the cap rock produces a pool of oil.
➢ Movement after this becomes only lateral and this can be in the scale of hundreds of
miles.
➢ Laterally the water flowing down gradient pushes the petroleum forward (water drive) in
the direction of hydraulic gradient until it is trapped.
TERTIARY MIGRATION
This takes place due to the natural flow of fluids along pressure gradients.
As a hole is drilled into the petroleum bearing formation, the pressure of the formation fluids
drops within the hole area. There is disequilibrium and a gradient is established.
The fluids then flow into the hole to restore equilibrium and pressure balance.
❖ Petroleum migration within reservoir rocks will continue indefinitely due to the effects of
buoyancy, gradient differentials and both capillary and hydrodynamic forces, unless the
movement is stopped by a trap.
Traps for oil and gas under hydrostatic conditions have two general trapping mechanisms:
Traps for hydrocarbons under hydrostatic conditions are of structural or stratigraphic origin,
either alone or in combination, and have horizontal gas-water or oil-water contacts.
Hydrodynamic (moving liquid) traps may also occur in different structural environments, but
they are characterized by inclined gas or oil-water contacts.
They are formed by deformation of the earth’s crust by
either faulting or folding.
HYDROCARBON TRAPS
➢ A) Structural (anticline)
➢ B) Structural (faulted)
➢ C) Stratigraphic (latera lithology change)
Trapping must be in all directions for an oil pool to accumulate. Vertical movement is stopped
by impervious rock layers (shales).
The trapping shale layer on top is called the cap rock while the bottom trapping shale is called
the bottom seal. A concave cap rock will prevent migration both vertically and laterally.
In carbonate reservoir rocks in the Middle East, the caprock and bottom scats consist of
anhydrite beds.
Shales and evaporites make good seals, although any unfractured rock that has a displacement
leakage-pressure higher than that of the hydrocarbon accumulation can be a reservoir.
Most traps are not filled to their structural or stratigraphic spill points. It is possible for a trap to
overfill and leak subsequent, migrated hydrocarbons to higher trapping mechanisms.
In the first stage of filling a trap, there will be stratification of gas, oil, and water above the spill
point. In later stages, hydrocarbons fill the trap to the spill point.
Since oil will be structurally lower than gas, subsequently migrated oil will spill over to the next
higher structure. In the final stage, gas moving from below enters the trap, but a equal volume
spills out at the same time, any oil with the gas will bypass the trap entirely.
ANTICLINAL TRAPS
These vary widely in shape and size. However, they all have a common characteristic in that a
gas-water or oil-water contact completely surrounds an accumulation of hydrocarbons.
The structure generally extends through a considerable thickness of formation so that traps are
formed in all the potential reservoir rocks.
These traps depend upon the effectiveness of the seal at the face of the fault. The seal may be the
result of placing different types of formations side by side, for example, shale against sand, or it
may be caused by impermeable material called “gouge” within the fault zone itself.
A simple fault trap may occur where structural contours provide closure against a single fault.
However, in other structural configurations, such as a monocline, two or three faults may be
required to form a trap.
Fault trap accumulations tend to be elongated and parallel to the fault trend.
A common type of fault trap is that formed when growth faults develop. This is common in
deltaic sediments where there is a stratigraphic section that has had prolific deposition during its
accumulation.
STRATIGRAPHIC TRAPS
These result from lateral changes that prevent continued migration of hydrocarbons in a potential
reservoir lithology.
Many are directly related to their environment of deposition, but others (particularly carbonates)
are caused by later changes, such as dolomitization.
Pinchouts
Channels
Deposition
Unassociated with Bars
unconformities
Reefs
On lap
Associated with
unconformities Supra unconformity Strike valley
Channel
The strata can be laterally extensive or restricted depending on the nature of the basin, amount of
sediment supply, strength of the currents etc.
Due to earth movements, compressional and tensional stresses can later deform the horizontal
rock strata.
This deformation leads to the formation of geologic structures like flexures and fractures.
The structures result from the elastic or inelastic behaviour of the strata when subjected to
stresses.
FAULTS
In petroleum provinces, normal faults are the most common and important of the fault types that
can trap hydrocarbons. Normal faulting is a genetic part of basin formation because they are
syndepositional and always dip towards the subsiding basin (e.g. as in the Niger Delta).
Post accumulation faulting allows escape of hydrocarbons and may even strut as migration paths
for petroleum.
A fault may constitute a trap alone by bringing impermeable lithology against porous and
permeable strata. Such taints are usually normal faults. The fault must be sealing in order to
avoid leakage.
The fault may have resulted from the development of other structures like Anticlinal folds and
Diapirs. These structures are the real traps but the associated faults aid in the napping
mechanism.
Some structures like Roll-Over Anticlines, folds, horsts and grabbens, result from faulting.
These structures produced by the faulting are the traps rather than the fault itself.
In the Niger Delta, Roll-Over-Anticlines form the traps rather than the growth faults that
gave rise to them.
UNCONFORMITY
• Angular Unconformity
• Disconformity
• Para conformity
In an angular unconformity, the beds above the erosional surface transgresses the eroded edges
of folded and tilted older beds below.
In a Disconformity, the beds above and below the erosional surface are paralleled although they
may be of different lithologies.
NOTE! The feature of all traps is the impermeable cap rock which forms the top of the traps.
Several conditions must be satisfied for an economic hydrocarbon accumulation to exist. First,
there must be sedimentary rocks that have good source rock characteristics and have reached
thermal maturity. Second, the hydrocarbons must have migrated from the source rock to a
potential reservoir, which must have adequate porosity and permeability. Finally, there must be
a trap to arrest the hydrocarbon migration and hold sufficient quantities to make the prospect
economic. Hydrocarbon traps usually consist of an impervious layer (seal), such as shale, above
the reservoir and barrier such as a fault or facies pinch that terminates the reservoir.
The creation of reservoirs containing oil or gas involves complex geological that occurred over
millions of years ago. These processes are still taking place today.
The elevated pressures encountered with depth are due to one or both of the causes:
1. Hydrostatic pressure imposed by the weight of fluid (predominantly water) which fills the
voids of the rock above and / or contiguous with the reservoir in question.
2. Overburden pressure due to the weight of the rocks and their fluid content existing above
the reservoir.
It is more common to find subsurface pressures varying as a linear function of depth with a
gradient close to the hydrostatic gradient of fresh to moderately saline water.
Departures from this behavior, both higher and lower, are considered abnormal.
The abnormally high pressures are more important as a source of serious drilling and production
hazards.
Since most subsurface waters are saline, it is common to find the gradient to be more than
0.433psi/ft.
Studies from 100 high pressure wells in Texas-Louisiana Gulf Coast showed a pressure gradient
of 1.0 psi/ft.
This figure is commonly used and may be obtained by using an average water saturated rock
specific gravity of 2.3.
PRESSURE GRADIENT
p = p0 + pρz…………………………………………………………………………………..(1)
RFT (Repeat Formation Tester) measures pressure with depth. Changing gradients used to
identify oil/water and gas/oil contacts. It can also identify (pressure) non-communicating regions
(shales and faults).
Gas
Gas/oil contact
Depth
z Oil
Water
Oil/water
contact
Pressure
Over-pressured; Reservoir pressure higher than expected. Reservoir has been uplifted since
filling. Risk of blow-outs.
Under-pressured; pressure lower than expected. Reservoir has been down thrown.
Now imagine drilling a well. The well is drilled using a ‘mud’ that is normally an oil or water-
based mixture of fluids containing barite, that gives the mud a density much greater than water.
Why?
Mud is replaced by water and reservoir production starts. The pressure near the wellbore drops
and the oil expands. Fluid flows from high to low pressure and out through the well.
PRODUCTION
Cartoon of a reservoir
Well
Gas
Oil
Water
Typical width=0.1-10km
PRIMARY PRODUCTION
Primary production of oil and gas uses the reservoirs’ own energy. As the reservoir pressure
drops, the fluids expand and as they expand, oil and gas are produced. No other fluids are
injected into the reservoir to push out the oil and gas underground.
Typical recoveries from primary production are around 2-20% of the original oil in place (OOIP)
SECONDARY PRODUCTION
Even if primary production is allowed to continue until the reservoir pressure is atmospheric, we
still have a reservoir full of oil and gas.
After primary production comes secondary production. Here another fluid is injected to displace
the reservoir fluids. Usually this is water but can also be gas. The gas may be air, nitrogen (air
with the oxygen removed to eliminate explosive risk, natural gas that is produced from the
reservoir, or carbon dioxide.
Water flooding does not normally recover more than half of the OOIP. Why not?
TERTIARY PRODUCTION
This occurs after secondary production. Normally it refers to gas injection after water flooding,
to remove residual oil and to contact unswept zones of the reservoir. Typical recoveries are
around 40-80%.
The other main classification is: primary production (as before); water flooding, and enhanced
(or improved) oil recovery. Enhanced oil recovery refers to the injection of something other than
just water to displace oil, and includes gas injection, steam injection and polymer flooding.
Improved oil recovery is a little more general, but usually means the same as enhanced oil
recovery.
1. Fluid expansion
2. Solution gas drive
3. Compaction drive
4. Gravity drainage, or gas cap expansion
5. Water influx, or aquifer drive
1. Water flooding
2. Gas injection
3. Polymer flooding
4. Steam injection
5. Insitu combustion
6. Surfactant flooding
7. Foam flooding