CHATE COACHING CLASSES
Assignment
Class : XII Sub : Chemistry
CHAP. 9. Coordination Compounds
SECTION - A
1. Select and write the correct answer : (For one marks each)
i) The sum of coordination number and oxidation number of M in [M(en)2C2O4] Cl is_______.
a) 6 b) 7
c) 9 d) 8
ii) The number of unpaired electrons in low spin octahedral complexes of Cr2+ (d4) and Fe3+ (d5)
are respectively.
a) 0 and 1 b) 2 and 1
c) 0 and 2 d) 1 and 0
iii) Which of the following complexes are chiral?
1) [Co(en)2Cl2]+ 2) [Pt(en)Cl2 ]
3) [Cr(C 2O 4)3 ]3- 4) [Co(NH3 )4 Cl2 ]+
a) 1 and 3 b) 2 and 3
c) l and 4 d) 2 and 4
iv) Formula for the compound sodium hexacynoferrate(III) is_______.
a) [NaFe(CN)6 ] b) Na 2[Fe(CN) 6 ]
c) Na[Fe(CN)6 ] d) Na 3 [Fe(CN)6 ]
2. Answer the following : (For one marks each)
i) What is the coordination number and oxidation state of metal ion in the complex [Pt(NH3)Cl5]?
ii) What is the shape of a complex in which the coordination number of central metal ion is 6?
iii) Draw isomers of Ru(NH3)4Cl2.
SECTION -B (For Two marks each)
3. Explain linkage isomers giving one example.
4. Draw qualitatively energy-level diagram showing d-orbital splitting in the octahedra l environment. Predict
the number of unpaired electrons in the complex [Fe(CN)6]4-. Is the complex diamagnetic or paramagnetic?
Is it coloured? Explain.
5. What is difference between a double salt and a complex? Give an example.
6. What are the high-spin and low-spin complexes?
7. What is coordination number of central metal ion in each of the following complexes?
i) Co in [COCb(en)2]+,
ii) Ir in [Ir(C2O4)2Cb]3+
8. Draw possible isomers of [Pt(en2)ClBr]2+
SECTION -C (For Three marks each)
9. Write the representation of
i) Tricarbonatocobaltate(III) ion
ii) Sodium hexacyanoferrate(III)
iii) Potassium hexacyanoferrate(II)
10. Explain the structure of square planar complex: [Ni(CN)4]2+
11. i) How stability of the coordination compounds can be explained in terms of equilibrium constants')
ii) Name the factors governing the equilibrium constant s of the coordination compound ?
SECTION -D (For Four marks each)
12. Answer in detail : Optical isomers (or enantiomers)
13. i) What are strong field and weak field ligands?
ii) Explain two applications of coordination compounds.
RRR
