IITIANS SPECTRUM EDUTECH
Total : 127 Marks CHEMICAL BONDING – CLASS TEST TIME: 2 HR
Single Choice Correct Questions : ( + 3 , –1 )
1. Which species has the maximum number of lone pair of electrons on the central atom?
(a) ClO 3− (b) XeF4 (c) SF4 (d) I 3−
2. The species having pyramidal shape is:
(a) SO3 (b) BrF3 (c) SiO 3– 2 (d) OSF2
3. In which of the following lone pair of underline atom present in pure p − orbital?
(a) N 2 H 4 (b) N ( SiH 3 )3 (c) PH 3 (d) NH 3
4. Correct order of bond angle in CH2F2
(a) H C H > H C F > F C F (b) F C F > H C F > H C H
(c) H C H > F C F > H C F (d) H C F > F C F > H C H
5. In which of the following species the bond angle around the central atom is equal to 120º?
(I) BF3 (II) BCl3 (III) BF4– (IV) SO3
(a) I (b) I, II, IV (c) II, IV (d) I, III
6. In the formation of N +2 from N2, the electron is lost from a
(a) σ−orbital (b) π−orbital (c) σ*−orbital (d) π*−orbital
7. The ONO angle is Maximum in:
(a) NO 3– (b) NO +2 (c) NO 2– (d) NO2
8. The shapes of [ClF4]– and [ClF2]– respectively are :
(a) see-saw and linear (b) see-saw and trigonal planar
(c) tetrahedral and bent (d) square planar and linear
9. CH4 has four identical C–H bonds and non-polar in nature. It would have been better if it were supposed
to have square planar structure but it is assigned tetrahedral geometry. This is due to the fact:
(a) Tetrahedral shape leads to zero dipole moment
(b) Square planar shape leads to zero dipole moment
(c) In case of square planar shape two isomers on mono substitution will be possible which is not
observed in CH4
(d) The net dipole moment of CH4 is zero
10. The correct statement for the molecule, CsI3, is:
(a) it is a covalent molecule (b) it contains Cs+ and I 3– ions
(c) it contains Cs3+ and I– ions (d) it contains Cs+, I– and lattice I2 molecule
11. Identify the correct sequence of increasing number of π − bonds in the structures of the following
molecules:
(I) H2S2O6 (II) H2SO3 (III) H2S2O5
(a) I, II, III (b) II, III, I (c) II, I, III (d) I, III, II
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IITIANS SPECTRUM EDUTECH
12. The incorrect increasing bond angles order is:
(a) BF3 < NF3 < PF3 < ClF3 (b) ClF3 < PF3 < NF3 < BF3
(c) BF3 ≈ NF3 < PF3 < ClF3 (d) BF3 > NF3 > PF3 > ClF3
13. In which of the following molecule, one or more than one homogeneous bond (atoms between
similar atoms) are not present?
(a) Borax (b) Per oxo borate (c) Tetra thionic acid (d) O2F2
Multiple Choice Correct Questions._______________________________________________ ( + 4 , –1 )
14. What is hybridization of B atoms in structure of borax {Na2B4O7.10H2O}
(a) sp2 (b) sp3 (c) sp (d) sp3d
15. Linear structure is assumed by
(a) NCO– (b) CS2 (c) NO2+ (d) BeH2 (s)
16. sp3d hybridised ion(s) is/are
(a) I 3– (b) ICl −2 (c) IClBr− (d) None of these
17. Which of the following has fractional bond order?
(a) O +2 (b) O −2 (c) F22− (d) H −2
18. Which of the following species have 3 centre-2 electrons banana bond?
(a) BeH2(s) (b) B2H6 (g) (c) BeCl2 (s) (d) Al2(CH3)6
19. In which of the following all the bonds are not of equal strength ?
(a) PCl5 (b) PF5 (c) SF4 (d) BF3
20. Which of the following are non-planar molecules?
(a) F2C = C = CF2 (b) F2B –– C ≡ C –– BF2
(c) N2Cl4 (d) SF6
21. Which of the following species are stabilized by removal of electron as explained by M.O.T.?
(a) O2- (b) O2 (c) F2 (d) N2
Comprehension Type Questions ( + 4 , –1 )
Comprehension – 1
The molecular orbital formed by the addition of atomic orbitals is called the bonding molecular
orbital and the molecular orbital formed by the subtraction of atomic orbitals is called antibonding molecular
orbital. Qualitatively, the formation of molecular orbitals can be understood in terms of the constructive or
destructive interference of the electron waves of the combining atoms. In the formation of bonding
molecular orbital, the two electron waves of the bonding atoms reinforce each other (constructive
interference) while in the formation of antibonding molecular orbital, these electron waves cancel each other
(destructive interference). The result is that in bonding molecular orbital most of the electron density is
located between the nuclei of the bonded atoms and hence the repulsion between the nuclei is very low
while in an antibonding molecular orbital, most of the electron density is located away from the space
between the nuclei, as a matter of fact there is a nodal plane (i.e. plane in which the electron density is zero)
22. In antibonding MO, electron density is minimum
(a) around one atom of the molecule
(b) between the two nuclei of the molecule
(c) at the region away from the nuclei of the molecule
(d) at no place.
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IITIANS SPECTRUM EDUTECH
23. Which of the following combination of orbitals is correct ?
(a)
(b)
(c)
(d)
Comprehension – 2
Dipole moment of a bond is a vector and physical quantity to calculate the percentage ionic character
in a covalent bond. It is expressed as:
Dipole moment
Where, δ is partial charge and d is the bond length.
It is usually expressed in terms of C.G.S. unit known as Debye (D), 1D = 10–18 esu cm. in S.I. unit it is
expressed in coulomb metre. Resultant dipole moment ( µ R ) of two bond moments ( µ1 and µ 2 ) acting at an
angle θ , is given by: µ R = µ12 + µ 22 + 2µ1µ 2 cos θ
If µ1 =µ 2 , Also if cos θ = −1 , i.e., θ =1800 , then µ = 0. (Molecule is non-polar)
If µ ≠ 0 molecule is polar
24. Identify the correct increasing order of the stability of the following alkenes
(I) cis-2-butene (II) trans-2-butene (III) isobutene
(a) II < III < I (b) I < III < II (c) I < II < III (d) III < II < I
25. Dipole moment of HCl molecule is found to be 0.816 D. Assuming HCl bond Length to be equal to
1Å, then % ionic character of HCl molecule is:
(a) 10% (b) 17% (c) 27% (d) 37%
Comprehension – 3
The study of dipole moment of a molecule is useful to explain the shape of a molecule and also to
predict a number of other properties of the molecule. The net dipole moment of a polyatomic molecule is the
resultant of the different bond moments present in that molecule.
26. The dipole moment of
Cl Cl
Cl Cl Cl
Cl Cl is 1.5 D. The dipole moment of Cl is
(a) Zero (b) 1.5 D (c) 2.60 D (d) 2.12 D
27. Which one of the following compounds will have maximum dipole moment?
(a) NF3 (b) NCl3 (c) NBr3 (d) NH3
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IITIANS SPECTRUM EDUTECH
Comprehension – 4
The concept of H-bonding was introduced to explain the abnormality in some molecules. H-atom
covalently linked with N, O of F in a molecule is held up on other side with dipole-dipole attraction with
same or other molecule of same or other compound show H-bonding. H-bonding between two molecules in
called intermolecular H-bonding. H-bonding within a molecule is called intramolecular H-bonding or
chelation. Intermolecular H-bonding gives rise to cluster formation.
28. Which of the following statement is wrong?
(a) H-bonding never involves more than two atoms
(b) The H-bond order is: H – F ...H > H – O…H > H – N …H
(c) All the three atoms involved lie in one plane
(d) H-bonding is stronger than covalent bond
29. The correct representation of H-bonding between NH3 and H2O is:
(a) H2N – H…OH2 (b) H3N…H – OH (c) H2N – H…H– OH (d) H3N…OH2
Matrix Match Questions (+4, –1 )
30. Match the molecules in Column I with the total number of lone pairs present on all the atoms in a
molecule in Column II
Column – I Column – II
(Number of lone pairs)
(A) (P) 10
(B) NO2 (Q) 5
(C) N2O3 (R) 8
(D) N2O4 (S) 3
(a) (A – S); (B – Q); (C – R); (D – P) (b) (A – P); (B – Q); (C – R); (D – S)
(c) (A – S); (B – R); (C – Q); (D – P) (d) (A – R); (B – P); (C – S); (D – Q)
31. Match the molecules in column I with the shape of the molecules given in column II and select the
correct answer:
Column – I Column - II
(A) XeF4 (P) Pyramidal
-
(B) [TeCl3] (Q) See-saw
-
(C) [IO2F2] (R) T-shaped
(D) F2SeO (S) Square planar
(a) (A – S); (B – Q); (C – R); (D – P) (b) (A – P); (B – Q); (C – R); (D – S)
(c) (A – S); (B – R); (C – Q); (D – P) (d) (A – Q); (B – R); (C – S); (D – P)
Integer Types Questions : ( + 4 , –1 )
32. How many of the following compounds can show intermolecular hydrogen bonding in their pure
solid or liquid state
33. With 2 atoms of Cl-35 isotope and three atoms of Cl-37 isotope, how many different types of PCl5
are possible?
34. If X = Number of P –– O –– P bonds in P4O6 ; Y = Number of π bonds in C(CN)4 ;
Z = Number of lone pairs in N2O3
Value of (X+Y-Z) is
35. Among the triatomic molecules/ions, BeCl2, N 3– , N2O, NO +2 , O3, SCl2, ICl2– , I 3– and XeF2 the total
number of linear molecules(s)/ion(s) where the hybridization of the central atoms does not have
contribution from the d-orbital(s) is:
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