MINISTRY OF EDUCATION, SINGAPORE in collaboration with UNIVERSITY OF CAMBRIDGE LOCAL EXAMINATIONS SYNDICATE General Certificate of Education Ordinary Level CANDID, rere YATE | CENTRE 7 NUMBER s NUMBER CT] SCIENCE (CHEMISTRY, BIOLOGY) 5078/03 Paper 3 Chemistry October/November 2018 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number, index number and name on all the work you hand in. You may use an HB pencil for any diagrams, graphs, tables or rough working, Write in dark blue or black pen. Do not use staples, paper clips, glue or correction fluid ‘The use of an approved scientific calculator is expected, where appropriate. ‘You may lose marks if you do not show your working or if you do not use appropriate units. DO NOT WRITE IN ANY BARCODES. Section A Answer all questions. ‘Write your answers in the spaces provided on the question paper. Section B ‘Answer any two questions. ‘Write your answers in the spaces provided on the question paper. ‘[Link] of the Data Sheet is printed on page 15. A copy of the Periodic Table is printed on page 16. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets | ] at the end of each question or part question. © UCLES & MOE 2018 [urn over rod end planed by Singapore Aaa Pbtshors Pre Lid (rt Sromoe Curie sn Aust Brat uder Kanes fam he Cater. Masten an Stl of Unrsy f Canoe cg Seough the Universty of Cameroge Itematonal Examinntons Synass) ether soley oF Jory mit he Govern ok sngares cine Soease Ve Monty of Eouasten Singapore) (2018)7 (OL Scionce (Chemistry)Section A ‘Answer all the questions in the spaces provided, 1 When completed, Table 1.1 describes three elements and their oxides. Complete the table. Table nature of oxide element ee forms | (acidic or basic or ‘amphoteric) sulfur non-metal 80, acidic potassium aluminium | (6) 2 Fig. 2.1 shows a piece of chromatography paper. It has five different food colourings spotted on it labelled A, B, C, D and E. Spot Z is a colouring that contains poisons and so should not be used in foods. The colourings were separated into their components using chromatography with an ethanol solvent. The resulting chromatogram is shown in Fig. 2.2. e e oe 7 oe Ee = oe fee |-@—_e—e—e—e—# e Zz A B C DE Zz A BC ODE Fig. 2.1 Fig. 2.2 (@)_ Using the two figures, state which of the colourings A, B, C, Dor E (Dis insoluble in ethanol, (ll) is a mixture of only three food colourings, (II) should not be used to colour food. (b) State which two of A, B, C, D and E contain the same three food colourings. 2 AND ®UCLES & MOE 2018 Pent and pulsed by Singspore Asia Publishers Pio Lis (2018)8 OL Science (Chemistry)3 The following five boxes describe two solids, two liquids and a gas. F G ‘When a magnet is passed over Liquid G is the only chemical formed powdered solid F, some of the powder when hydrogen burns in oxygen. is attracted to the magnet. 4 This curve resutted when cooling liquid H. temperature/ c times min 1 J Solid Iwill not conduct electricity when Al the atoms in a molecule of gas J it Is @ solid but melts at a fixed temperature are identical. to become a conductor. Classify each of F, G, H, | and J as an element or a compound or a mixture by placing a tick in the appropriate column in Table 3.1 Table 3.1 element ‘compound mixture F G 4 | ' J 15] ®UCLES & MOE 2018 Pris and pubis by Singapore Asia Publishers Pts Lis (2018)9 OL Science (Chemistry)4 (a) Name the process by which fuels such as petrol and diesel can be separated from petroleum. {1} (b) Briefly describe the process in part (a). You may include a sketch with your answer. [4] © UCLES & MOE 2018 Print ana pubis by Singapore Ass Pushers Pte Lid (2018)10 (OL Sciance (Chemistry)5 Simple alcohols form a homologous series. Butanol is an example of an alcohol and has the following structure. (a) Give the general formula for the homologous series of alcohols. (b) qw, lt] Name and give the chemical formula for the second member of the homologous series. name chemical formula 2) When left exposed to air, this alcohol is slowly oxidised. Give the name and draw the full structural formula of the product of this oxidation. name ... {ull structural formula 3] ©UCLES & MOE 2018 reed and published by Singapore Asia Publshers Pte Ltt (2018)11 OL Scionce (Chemistry)6 Table 6.1 contains details of seven different particles. The letters are not the chemical symbols. Table 6.1 K L ” N ° P a! a 3 1 | 1 14 | 19 number 3) 3 proton | for | 2 | 8 | 8 | 7 | to | n | a7 | total number siecle 5 5 7 | to} 1 | 18 i Use Table 6.1 to state which of particies K, L, M,N, O, P and @ (a) has a single neution, ..... (b) Is placed in Group V of the Periodic Table, .... {c) has an electronic structure of 2.8, ... (@) will form an ionic compound with chiorine, .... (©) is anion with a single negative charge, () are both isotopes of the same element. .. i @UCLES & MOE 2018 Printed and publaed by Singapore Asia Pubiare Po Ltt (2018)12 OL Science (Chemisty)7 _ Fig. 7.1 describes some of the substances that result from the chemical reactions of metal R. R a powdered metal add dilute hydrochloric acia to form S and T add acidified, 1 v aqueous $s T silver nitrate u a colourless agreen = | ————» awhite gas solution precipitate apply a ‘add aqueous buming sodium splint y ¥_ hydroxide a v popping agreen sound precipitate Fig. 7.4 (a) Identity each of R, S, T, U and V. Cie See To. vu. v aa 8] (b) Write a balanced chemical equation for any one of the reactions included in Fig. 7.1 (2) @UCLES & MOE 2018, Printed and pubied by Singapore Asia Pubs Po Lid (2018)13 (OL Science (Chemisty)8 Some indigestion tablets reduce stomach acidity. Carbonate ions, CO,%-, in these tablets react with hydrogen ions in the stomach to form water and a gas. (@) Write the ionic equation for this chemical reaction. (2) (B) One hundred of these indigestion tablets contain, in total, one mole of carbonate ions, () Calculate how many moles of hydrogen ions are present in 500cm® of a 0.08moVdm? solution of hydrogen ions. [2] (W) Calculate how many moles of carbonate ions are needed to neutralise the acidic solution. umber of moles of hydrogen ions = .. ‘number of moles of carbonate ions = .. ool] (NW) Calculate how many indigestion tablets are needed to neutralise the acidic solution. number of tablets = ... {1 UCLES & MOE 2018 Printed ae publishes by Singapore Asi Publishers Pi Lit (2018)14 OL Science (Chemistry)Section B ‘Answer any two questions in this section. ‘Write your answers in the spaces provided. 9 (a) Describe how you would distinguish between an acidic solution and an alkaline solution, (2) (@) The salt magnesium sulfate forms soluble crystals. Describe how a pure sample of these crystals can be prepared from insoluble magnesium oxide. [4] (©) Ammonia and hydrogen chloride are both compounds. When mixed with water, one of these compounds produces an alkaline solution and the other producas an acidic solution. () Explain why one solution is alkaline and the other is acidic. -l2] (i) These two solutions can neutralise one another. ‘Write either an ionic equation or a chemical equation to represent this neutralisation. (2) GUCLES & MOE 2018 Print and published by Singapore Asia Pubshors Pie Lis (2018)15 (OL Science (Chemistry)10 (a) (l)_ Most chemical reactions occur very quickly and are complete within seconds. Give an example of such a reaction and write a balanced chemical equation to represent the change. [3] (W) Other chemical reactions take many days to complete. Give an example of a reaction of this type. No chemical equation is required. 1) {b) Pieces of calcium react with a dilute acid to produce a gas. This reaction completes in five minutes. (1) List the measurements you would make to determine the speed of this reaction. vof2] (W)_ On the axes below, draw a graph for the measurements made in (b)(I) that would show how the speed of the reaction changes. fa} @UCLES & MOE 2018 Printad and pubiahed by Singapore Asia Pubishers Pa Lis (2018)16 OL Science (Chemistry)(lll) Describe how you would use your graph in (b)(l) to determine the speed of the reaction at two minutes. (2) 11 (@) Carbon and lithium are in the same period of the Periodic Table but have very different chemical properties. [Proton (atomic) numbers: C, 6; Li, 3] ()_ Explain why these two elements are placed in the same period of the Periodic Table. (W)_ Explain why these two elements have different chemical properties. [1] (b) Carbon dioxide is a gas at room temperature and pressure. (Draw a ‘dot and cross’ diagram to show the arrangement of the outer shell electrons in ‘one molecule of carbon dioxide. {Proton numbers: C, 6; O, 8} (2) GUCLES & MOE 2018 Printed and pulened by Singapore Asia Publihors Pte Lis (2018)17 OL Sciance (Chemistry)(Wl) Carbon dioxide can be liquefied and has a low bolling point. Explain, with reference to the structure of carbon dioxide, why the boiling point is low. (2) (c) When carbon dioxide is bubbled through limewater (aqueous calcium hydroxide), @ white precipitate is formed. Write @ balancad chemical equation for this reaction and use your equation to calculate the maximum mass of precipitate that can form when 4.09 of the gas is bubbled through limewater. [Relative atomic masses: 4: H, 1; C, 12; 0, 16; Ca, 40] chemical equation mass of precipitate ©UCLES & MOE 2018 Pred and pushed by Singapore Asa Pubishers Pe Lis (201618 OL Scionce (Chemistry)