Chemistry Exam Prep Questions
Chemistry Exam Prep Questions
Classification of Elements
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(a) 2 (b) 49
8 (a) 36
(c) 18 (d) 32 (c) 50 (d) 54
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(d) Both (a) & (c) (d) The ionic radius of a metal is less than its
of atomic radius
Q.19 The valence shell electronie configuration
Inerease in atomic size down the group is due
to
transition elements is Q.25
(a) Increase in number of orbit
(a) ns'
(6) Increase in number of protons and neutrons
(b) ns np
(c) Increase in number of protons
(c) ns2 (n- 1) d-10
(d) Increase in number of protons, neutrons and
(d) ns (n- 1)d'0
inner transition electrons
Q.20 The electronic configuration of
Q.26 In which of the following pairs the radii of
elements is
second species is greater than that of first?
(a) ns
(a) K, Ca (b) H, He
(b) ns np'nd0
(c) Mg', Mg?* (d) O-0
(c) ns2(n-1) d-0(n -2) f- Q.27 The species Ar, K* and Ca2* contain the same
(d) ns (n-1) d(n -2) f-14
number of electrons. In which order do their|
Q,21 All elements in the third period have
radii increase?
(a) Three complete shells
(a) K*< Ar < Ca2* (b) Ar < K*< Ca2*
(6) Three complete subshells
(c) Three valence electrons
(c) Ca2t< Ar <K* (d) Ca<K*< Ar
Q.28 Which of the following orders of ionic radu
(d) Three electrons less than octet
Q.22 Which one of the following represents a d-block correctly represented?
(a) H>H>H (6) Nat>F>0
element?
(c) 0>FNat (d) AP>Mgt>N
(a) [Rn] 6d 7s 7p? 9.29 The correct order of the decreasing ionie radi
(b) [Xe] 4f sd' 6s*
(c) [Xe] 4f4 sd' 6s among the following electronic species are
(a) Ca2*> K> S?>CF (b) C> S>Ca*>K
(d) [Xe] Sd' 6s
(c) S>CI>K>Ca?* (d) K*> Ca>C
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Q.30 Among the clements Ca, Mg, P and CI, the order|Q.40 Which one of the following is correct order of
of increasing atomie radii is the size of iodine species?
(a) Mg< Ca <Cl< P (b) Cl<P< Mg < Ca (a) I'>1>I (b) I>1>>I
(c) P<CI < Ca < Mg (d) Ca < Mg < P <CI (c) I>I> (d) I>I'>
Q.31 lonic radii are Q.41 Which of the following ion is the largest in size?
(a) Inversely proportional to cffective nuclear charge (a) K* (b) Ca2
(b) Inversely proportional to square of cffective (c) C (d) S
nuclear charge Q.42 Which of the following has the smallest size?
(c) Directly proportional to effective nuclear (a) AlP* (6) F
charge (c) Na (d) Mg
(d) Directly proportional to square of effective Q.43 The correct order of shielding effect of s, p, d
nuclear charge and forbitals is
Q.32 The radii of F, F,O and 0 are in the order (a) s>p>d>f (b) s<p<d>f
(a) O>0>F>F (b) F>0>F>0 (c) s<p<d<f (d) s>p<d<f
(c) O>F>0>F (d) 0*> F>F>0 Q.44 Which of the following is not correct for iso
Q.33 Which ion has the largest radius? electronic ions?
(a) They have the same number of electrons
(a) Se (b) F
around their nuclei
(c) 0 (d) Rb
Q.34 When a neutral atom is converted into a cation its (b) Higher the atomic number, higher will be
(c) Size increases (c) Isoelectronic ions have same electric charge
Q.35 Which ofthe following N*, 0,F is largest in size? positively and negatively charged ions
3
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Classification of Elements cnd Periodicity in Properties
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lonization Enthalpy 0.58 Find the formula of halide of a
metal whose
Q.50 With which of the following electronic successive ionization enthalpies are x, 2x, 5
configuration an atom has the lowest ionization 100x kJ mol respectively
enthalpy? (a) MX (b) MX2
(a) 1s 2s 2p (b) Is2s 2p°3s (c) MX (d) MaX
(c) 1s 2s 2 (d) 1s 2s 2p' Q.59 Which of the following equation represents first
Q.51 Amongst the elements with following electronic enthalpy of ionization ?
configurations, which one of them may have the (a) Hg(s) Hg' te
highest ionization energy? (b) Hgo- Hg' te
(a) Ne [3s3p°] (b) Ar [3d04s4p°]
(c) Hge Hgte
() Ne [3s 3p'] (d) Ne [3s3p]
(d) Hg' Hge+e
Q.52 The first ionization potentials (eV) of N and O If you
Q.60 are given Avogadro's number of atoms of
respectively are a gas 'X. If half of the atoms are converted into
(a) 8.29, 8.29 (b) 11.32, 11.32
X(p by energy AH. The IE of X is
(c) 8.29, 11.32 (d) 11.32, 8.21
a) <4H 2N
Q.53 Correct order of Ist ionization potential among (b)
AH
elements Be, B, C, N, Ois
AH
(a) B<Be<C<0<N (b) B < Be <C<N<0
(c)Be<B<C<N<0 (d) Be «B<<C<0<N
Q.61
)N (d)
AH
(b) The electron affinity of fluorine is greater than (a) F->F (b) H H
that of chlorine (c) CI > C (d) 0 0
(c)The ionization potential of Mg is greater than 9.63 Which of the following is correet order of
aluminium metallic character for Si, Be, Mg, Na and P?
(d) The electronegativity of fluorine is greater than (a) P<Si< Be < Na < Mg
(b) P< Si< Be < Mg < Na
that of chlorine
(c) Na> Be > Mg> Be> P
Q.56 The electronie configuration having maximum
difference in first and second ionization energies is (d) Na> Si > Mg> Be>P
(a) 1s 2s 2p' 3s (b) 1s 2s 2p* 3s*3p Q.64 The first, second and third ionisation energies of
(c) 1s2s 2p 3s 3p? (d) 1s 2s 2p* 3s' Al are 578, 1817 and 2745 kJ mol-I respectivelyL
Calculate the energy required to convert all the
Q.57 The successive ionization energies for element X
atoms of Al to Al" present in 270 mg of AlC
is given below
IE: 250 kJ mol vapours
(a) 5140 kJ (b) 51.40 kJ
IE,: 820 kJ mol'
(c) 2745 k (d) 514.0 kJ
TEs: 1100 kJ mol Q.65 The electronic configurations of the elements A
IE: 1400 kJ mol has
Y, Z and J are given below. Which element
Find out the number of valence electrons for the
the highest metallic character?
element X.
Q.66 Energy required for the ionisation of 0.02 gram Q.71 What is the value of electron gain enthalpy of
atom of magnesium is x kJ. The amount of energy Na' if IE of Na = 5.1 eV?
required to ionize 1 atom of magnesium is (a) +2.55 cV (b) +10.2 eV
(A) N,O (B) B, Be (C) Al, Ga (c) Period 2, group 18 (d) Period 2, group 1
(D) F,CI (E) Zn, Ga (F)F, C Q.77 Electronic configurations of some elements are
Correct option is given in column I and their electron gain enthalpies
(a) A,C,F.D (b) A,D,E are given in column II. Match the electronie
(c) B, D, E, F (d) A, D, E, F configuration with electron gain enthalpy.
Column () Column (1)
Electron Gain Enthalpy Electronic Electron gain
Q.70 In which of the following options, the order of Configuration enthalpy/kJ mo-l
arrangement does not agree with the variation i) 1s 2s 2p (A)-53
of property indicated against it? (i) 1s* 2s 2p 3s (B)-328
(a) Li<Na < K < Rb (increasing metallic radius) ii) 1s 2s 2p (C)-141
(b) A*< Mg*< Na'<F (increasing ionic size) (iv) 1s 2s 2p (D) +48
(c) B< C <N< O (increasing first ionisation (a) i> D, ii > A, ii >B, iv >C
enthalpy) (b) i> A, ii > B, ii >C, iv > D
(d) I< Br< CI < F (increasing electron gain (c) i> D, ii > B, ii A , iv >C
enthalpy) (d) i> D, ii > C, ii > A, iv >B
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Q.84 Among the following hydroxides which is most basic?
Electro Negativity
follows the order (a) Lu(OH) (b) La(OH)»
Q.78 The clectronegativity
(a) F>0> Cl> Br (b) F>Cl> Br>0 (c) Pm(OH)» (d) Yb(OH)
(c) O>F>Cl> Br (d) CI>F>0> Br
Q.82 Match the following, regarding nature of the oxides Q.88 Which property decreases from left to rig
Column-I Column-11 across the periodic table and increases from to
a. HO i) Basic to bottom?
b. Na:0 () Amphoteric () Atomie radius (i) Electronegativity
c. ZnO (ii) Acidic (ii) lonisation energy (iv) Metallic character
. SO3 iv) Neutral (a) i) only (b) (i), (i) and (ii)
(a) aii), b(i), clii), div) (c) i), (ii) and (iv) (d) (i) and (iv)
(b) aliv), bi), c(ii), d(ii) Q.89 Which is not correct order for the stated property
(c) aiv), b(i), c(ii), d(ii) (a) Ba>Sr> Mg: Atomic radius
d) ai), bi), c(iv), d(ii) (b) F>0>N: First ionisation energy
Q.83 Match the column -
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are
function of their atomic number.
In the modern periodic table
the period
(d)
(d) Lother meyer plotted a graph betwecn atomic
indicates the value of Azimuthal quantum
volume and atomic weight of the elements.
number
Q.2 Find the incorrect one -
Find the incorrect statement-
General outer shell electronic configuration of|
Q.7
(a) form anion most readily
d-block elements is (n -1)d1-l®ns2 where
n is (a) Halogens will
3-7 (b) Increasing basic order
(c) Metallic character increase down the group (d) Bond energy of F, is less than Cl,
whereas decrease from left to right in a period.
Find out the incorrect statement
-
of the Q.8
(d) Radius of cation is smaller than that Atomic radii order of 13h group
elements
corresponding neutral atom.
(a)
B< Ga<AI < In < TI
Which of the following statement is not incorrect?
Q.3 (b) Al,O, is a basic oxide
All metals are either solid or gas at room
(a) non
I.P. order of second period-
temperature.
(c)
that of the Li <B<Be<C <0<N<F<Ne
(b) Radius of anion is smaller than
Alkali metals have lowest I.E. in
each period
corresponding neutral atom. (d)
Q.9 Find out incorrect statement-
Order of ionic radii
-
7
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Hero to Super Hero Questions| Statement & Reason Type Questions
R.7
Read the statement 1 and statement II
carefully to | Q.4 Statement I Ionization enthalpy decreases
mark the correet option out of the options given below: ot
moving down the group.
Q.1 Statement I: The first ionisation energy of Al is Statement II : Force of attraction between
nucleu
lower than magnesium. and valence shell electrons decreases on
movin
Statement II : Atomic radius of Al is smaller then down the group.
magnesium. (a) If both statement I and statement II
(a) If both statement I and statement II are true and the statement II is the correct
are
andtrue
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Statement I: Na:O is more basic than Al:OO. (b) If both statement I and statement II are true but
.7
Statement Il: Sodium is less clectropositive than statementIl is not the correct explanation of the
O aluminium. statement I.
(a) If both statement I and statement II are true and (c) If statement I is true but statement II is false.
the statement II is the correct explanation of the (d) If the statement I and statement II both are false.
statementI. (c) If statement I is false but statement I is true.
(b) If both statement I and statement II are true but | Q.9 Statement I : Cu, Ag, Au are known as coinage
statement II is not the correct explanation of the metal.
statement I. Statement II : Coinage metals are d-block metals.
(c) If statement I is true but statement II is false.
(d) If the statement I and statement II both are (a) If both statement I and statement II are true and
false the statement II is the correct explanation of the
(e) If statement I is false but statement I is true. statementI.
Q.8 StatementI: F is most electronegative elementin (b) If both statement I and statement II are true but
periodic table. statement II is not the correct explanation of the
Statement I1: Cl is having highest electron affinity. statement I.
(a) If both statement I and statement II are true and (c) If statement I is true but statement II is false.
the statement II is the correct explanation of the (d) If the statement I and statement Ilboth are false.
statement I. (e) If statement I is false but statement II is true.
(ii) Some places were left vacant for new elements (c) F T T F F TT TT
which were not discovered at that time. (d) F F T FF TF TF
(ii) In dobereiner's triads, the atomic weight ofQ.2 Match the column
the middle element was the arithmetic mean IUPAC Official Name Atomic Number
of the atomic weights of the other two. i) Mendlevium (a) 112
(iv) In the long form periodic table these are (ii) Dubnium (b) 111
seven horizontal rows called period and (c) 109
(ii) Seaborgium
twenty vertical columns called groups. (iv) Teassium (d) 107
(v) In Mendlev's periodic table lanthanoids and (e) 110
(v) Neintrinium
actinoids were included.
(vi) Rogentium (t) 103
(vi) In Newland's octaves law, every eight element
(vii) Copermicium ( ) 105
had similar properties to the first one.
(vii) Bohrium (h) 106
(vii) Eka silicon was termed as germanium and
(ix) Darmstadium (i) 108
Eka-aluminium as galium.
(x) Lawrencium G) 101
(vii) Mordern periodic law states that the physical
and chemical properties of the elements are Select the correct option.
periodic functions of their atomic numbers. () (i) (ii) (iv) (v) (vi) (vii) (vi) (ix) (x)
ix) Lothar Meyer plotted the physical properties (a) ) () (h) ) (b) (e) (a) (d) (e) (b)
such as atomic volume, melting point and (b) G) (g) (h) (i) (c) (b) (a) (e) (d) (D
boiling point against atomic weight and (c) G) (e) (h) (i) (c) (d) (a) (c) (b) ()
obtained a periodically repeated pattern. (d) G) (g) (h) (i) (c) (b) (a) (d) (e) (f)
9
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F
(b) T F TFT F T T (b) T T TF
F T TT
T
(c) T T F F T T F T (e) T T T F T F F F
(d) TF T TT F FT T
(d) T T T F T
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.7 Choose the correet statements. (v) Boron forms only [BF ] and cannot expand its
(i) Atomic radius refer to both covalent or octct furthermore duc to anavailabity of
metallic radius depending on whether the d-orbital's and shows a maximum covalency of 3.
element is a non-metal or a meta (vi) The first member of p-block elements shows
ii) The sereening effect of d-orbital clectrons of a greater ability to display or form pr-pr
a subshell is much less than s-electrons of the multiple bonds to itself like, N=N, C = C,
(ii) The periodic repetition of the properties of (vii) The oxidation state and covalency of Al in
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Both Be and Al form mainly covale
Q.10 Consider the following statements. (g)
for two compounds.
(a) The first ionisation enthalpies
(h) It is easier to remove 2p electron than
isotopes of the same element are same.
electron and 2s electron has more penetratid
(b) Sodium can't exhibit +2 oxidation state because
power than 2p.
its second ionisation potential value is zero.
The energy relcased when an electron
(c) In modern periodic table, the block indicates (i)
added to a neutral gaseous atom is call
the value of Azimuthal quantum number for
electron gain enthalpy of an atom.
the last subshell that received electrons in
Elements of group 16 have more ionizati
building up the electronic configuration. )
enthalpy values compared to those of grou
(d) Ratio between the radii of He" ion and H
15 in the corresponding periods.
atom is %.
(a) (a), (b), (c), (), (h) are correct only.
(e) Amongst isoelectronic species the positive
the cation, smaller is the ionic (b) All are except (d),
correct (e), (
charge on
(c) (i). G) are correct options
radius.
Zirconium and hafnium have identical radii (d) All corect except (6), G)
(f
of 160 and 159 pm, respectively as a
Periodic
- Table
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ANSWER KEY
Zero to Hero Questions
Q 4 6 8 10
Ans. a b
b C C
Q. 11 12 14 17 18 19 20
Ans. d d
a d d
Q. 21 22 24 26 27 28 29 30
Ans. b d a b d C b
Q. 31 34 36 37 38 39 40
Ans. d a a b b
Q 41 42 46 7 48 49 50
Ans. b a b
51
Ans. d d
3 56 58 59 60
a b d d a
61
Ans.
630 65 66 68 69 70
b b b b b C,d
7 2
Ans.
74 76 77 78 79 80
d a d d
Q. 81 82 83 84 86 88 89 90
Ans. C b b a b
Ans. C d
8 10
b
d b d
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