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As Organic Chemistry (SC)

As Level CAIE organic chemistry notes

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Tasfique Sami
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0% found this document useful (0 votes)
64 views44 pages

As Organic Chemistry (SC)

As Level CAIE organic chemistry notes

Uploaded by

Tasfique Sami
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
nama. Weniify tne longest cain [ functional ortoun musi be inaluded | NO Spade heiween two ieiterS - 9 o- Ho - AD mame of the branch eomes in alPhabeticg) order tonges chain 3.4 ~ dimethylheptane eee t ge S \onges* oe alphabetical order (e\ © dremyl- 2-motny\eenians yi {e) Hetn yt” atin ‘Scanned with CamScanner wan ood ao 4 t Cre} tg = =e anetianal gag ates o ne inated porous a, ool Lav eure Jeco dey l 0 ipriioiitise: funchsra) » group 52% = dimethyl - 2 = ethyl hewndiene amon a 1 om par otter 9 hon “omoa 9 po paoregqas predon “osdqun * _p pa b907699. cz or “e649 EC Yeae h ho) a oa \d=0 : ast —2=1naiiny| beriains 4= | adver 9dt qed coisas Tapa! edt mo? 2ema. smay Ivo) ear © Xow o-)- 9375 -D ' ae 1 t - an tt= dives pentarn - 2-0) f\enO 2-8 : 3 ‘ 2-9 > rs we ji 1 2 7 ‘Seanned with CamSeannet os Cia cue CHe CH (ce) CH Cena) eHo CH 3 or Loyd unt = Ci% Ave Cho SMP echoicH? ONgi of (aly 99) 3 2 OND. ala cH : a Akeletal Farm ia = x \ . z= -— Bw . ; i yx ist LP2 2 SP onnials = 10. bs ) as St _o- \inear- A Wov a4 = NY SS ~ weakest boni_sirengiia : fohdio Ariducd ~9. czc Letidre Vsioynbs Or =9° + i (é sipep e f oovit As a T ‘Scanned with CamSeannet te = a. Sjercio Tsomersiam.> wand _having the: same moerularCarmulos some, eArcuclure ! en\i0 [Link] / Arent _3_dimensianal_arercangemen’s_of clams. so Aicq\ ‘ne cama\ be super impased_on each aber - ae Greomnetrcioal Tesarnene isin fe mone ciehlal Syrreila” tout See hore mt Shapes atic artiges \nemnuse of Gla ab pase eciesion dont _adeide bond (due to tho presence nf pi bond) ponbie/4rippie cond + ecHaerg + HEL eciele + Cla —b Cla + cle aucla + Cl? —> la HNOl 7 oi oy & 2etlotiClQcriana Coke peeks i } hacd busi pve ip aati at Se 4 yout i e493 6. yevirrt OWsChs 2 T being CNS +CH3—) CHy-Chgs | — A oo ~ WJa7oels x2 > eclq, |! pe, Coa CHCA SHSCH THEO, BIPY/7e) ‘Scanned with CamSeannet CNarcles} 1) Teterimatinn” ciate produtes. 3! =>} ‘Roomy. 9} mitiation 4 “Cla eg ee dS tit s 2 eee ce Prac ® flor 2 CHa + Cle > CHa dor oven ¢ * CMa + Cla | pew iH ad AnCle CHgel 4 Cle! —» le cho@yHely sud + ea Tt yWdeticd* a oO. + bye 4 od + VI ob bo/ faa lt {22] eas 21 opogarion HAC s avd pico ¥ Q|[Awiation Ug —“e ele + ce wort @. idieviod 4 o1W t+ dendd © 6) ropogosion & eHa t Cle —p ¢ CHS + HC) 2 CWS To Db CHAN « Qe CHB C1 ¢. Che - =e echat «Ha «CR male a2 —h CHOMe + Qe @) CHa +C\2 | tonicn ene” nor _passible. & corsa 8 Cane © craze arett SE Coue ‘Scanned with CamSeanner | Icoia®y + Bro —> Co HuBrot Br * Ica Ha Bre +! Bele C2OHsSBr (OH st. eH) os ep pHd rors 21D y joe a yoT eh) ail On > JJ eHIe ot ep 7 end “(9 + DCH. 2 9 *[Link] iL Taal gid zeog fon om eOing | cl pHO I Der ¢5_ (4) wall . 3H ta He ad VWWsW -sh lo oy) ud SHe® XT ‘Scanned wth CamScannar i Caxcane? Alyene {tance a orn Mio [icine Sonree of _ ee thet (i ny ch = Ree S)-o— (oo /9 + CHD = Hid =A € 7 { J2 ie) A100), pv, + 490°C |. oH —h) -2_ 4——— ry CWE + CHD =H gq _OEFxces: cone Hosa ac v Rial ig PUMICE FAG Cn ona AE OW NEW. WewhOrel peg -eae + ent under rex 9 =H N30 — Got Fc Joptiithation sls 0° Wer vemoved -@eane ofa Gage th [“Hvb10 Hredimanetl | “= Osi0 HD ocho 8 + 74 [d2xb01 ool wD} iviporsd * DH DHS vagy CHS - ews) HETOD 4 BY \ : a3 cor i ~ OcouH Ho & \ - ch 4a A = ' . ' ; et ar You o = )* 2 t 4 H5- D00n ) cHd=pH seamed th CanScame oe potassiom dicrromaie *§ comparatively Nery Weals go can't oxidise De onkigiion of an O\K SNES iMod concentrated roi inpa tt lsc, hotlch Bed on agueous Kn Ow > ned + Hy) 4 9-e( €Hd ) Wwe F creo prmethanal deter oxidation —! -on i o 4 ht =G att = onty ecthanal exidioes do Oreo DHE acid _w -@ -u ie 09 + 420 ae i HOS yCOotHeoy c HDHD HC Ho _€00 +8490 , ~h iAaadha de ta) (tern imog) eC orn xt} Taya tt a pee cus cagan i 7? ketore - 4 Py << el ml piedb - - oko ATOREN = COQtH2O.~ J - COOH 2 aks _2 one nudregen = cua - eH cn F oH -GH =@H3 _ caroxytic aot uy CHS CHECOOK + Hooe-cH ~ 0H3 CHS ONG - Ciig- © Sen =a v Cv3 Giga en- € = 0% HOSS-CHs : ens ‘Scanned with CamScarner cnn ¢ ¥ GH -Cho-H$ cua s “ne. 4 T cH T = = Semon eeprom @=C=0 yone = CH ~COOH + Coa ne clay ' 8 Mil _* a [Wenn WR J w= ek ce @=e-9 ue I ae ) Oar p= e : v2 ie mi tema & a © Sinaia ee mS wy da Cy, oo ie Hod e | he Os ~My - CHD HCOOH ND <8 WR ea bee payee eal +Aoot m.* Z cw MOO © Nooe : OS v @ W\O0e —'C =O'ry Hove ~ eva -~ cOO# 7 44 Scanned with CamScanner t wee eS € 0 AS Mo Ab + -- T ole =\e=0 “t nooe — C&B C=O +. CODMay [[osaation prosacts to reactant | ® Ca. CnOW + (92 N20) ~ Ag CHD oCHg CH= He Ol CevaTa-©=0 rt __ Clg tn2coou- (ev), se =Heh > ehaeMe eu Of 5 eh: he ) ora — GH — OOOH + we 8 =tH2= 00H > Ca tHeG . (ENG 0 1 js re CAs» TS aa Hen =ew cy oo Se Pi a | ag “ A AY: @ 7 3 @ Wore — CHa eh, - CH We = fg [oy chy & ws || = CH a- Cha -cH ~CH 2 t= chs Seanned with CamSeannet cad . or ene tale \ ene ON \ CAD Oxidadion of A\kene sasing cold -Aiwwie ea act acitiGed oe HnO ‘ foniy di o\ fentasée a= hie ion a oS Gua spand paid ee 6 (eons! cay, = = Cy = CH = Can Cairo Fe ou CHa S = ! uct = 1 L yoo} proe ui mat y La Scanned with CamSeanner reactions Fire _codicle etinstitertion: 1 Scitophlie-adssion Coagiion sf atsineS) ® ® _ ® Ilelecraptillic empatitunion > Ao. Neclenphilliic_addition. © Tole} i ai ii ° e CMO = QH= CHS = 3! Ho@— CW ~peHA sr Hato BN ACH Gass SP aecroprite h Yearbocstion r ex fi ar. -Lpominant | “A: MWO= CW a CHBii/I=—a> / =o tHa > LiWa@ 7 Co ~CH2_ Gast c nt 8c Ghee 2 Bn TArogo eli f eft Ek corbamtion (orimary) = Tip Leko-cua) (aM Y eo auny\ group =R 2° eamanion_{seeondarsy)__¢€a5p= 4 =u) _— t Sy Re 2° eapromiion Ciertiary) Ged em R © Bian 9, Oe oe ae Scanned with CamSeanner i ; ; postive induct, “educim ¢ us da | ) aint GrooPs (Ol ase a0 padiiveindadina etek | _greone z of alkuy oh ~ Ny due O41 Wa pale b Ha -HO-C =0- CHo -CHa : £ * 8 Léiliyoh? euberrcar Bo-c AS ou ban aan : Hoe G =CHS=CHS- Peo 5 ; . — f < if (27 pr y ) 1C/ Fy wow 9 ry ae ae _—- ‘Scanned with CamScannet pong anid 9 OxYgEH Carer ry Ki Yoo IoC ‘cites t From alkane. [freesadicleaubatitution] > ee atkane pores || feom_oilione. Loaaition of Xo (Close Th) onde eGo pee WX (HEYA HGr MAT) | > seejarene notes 9 _2@ _8 __— di Erom_ajccro! SE Paotpriteains uiaosiauia sHOGIRG Ke SHOE H! We insildy Na nsoa es AtO 8 R-ov1 Fo CLOT GSIE Bas @ Soto uy=" T RGH 4” SoClo.w paRebant Nlwy* S09 Balke Fs hs poe eur? seg) Ro poals. fae ae eral rAiph + ui =< FSV FE ON BOP (De @ paso / tea Peete [a8 04 Leteleiste® BRCleot Hoh a0 _+ WDCHI eH‘! Q-on e x ve 8 =BE ey 4 i bi G98 qi Todoa\kare Reon prow /red Pela, Re Tien neat, Scanned with CamScanner eg | s f a a ae eer Regia ay oe aE | ate ES se RAUB a= cua ruan+ 25 Se, Ih a Bon] eared ( CagetOn AB ee oe ena —epi— GAZ Tey + $O' —» BS Aiysroger lenves. fromm the compound siti Jecs—\nuphtopgem ———____ ee the s- 2) eagehabetw10 ae SiagneOr o@ aytralfas2 minute ary ect Be + HO Fay asian? gir 2 unog +a) Tae Pew] A on eHgth2Br Aeon Tat amber, Crigetacn + kor Lin ethane! organic owen] very important deaction = citi & added ig Abe cukoh shai, J ystato, runt 3 ‘ . L Gr¥9, Cio Par + Ne Se Se CHaCHoNHo t HBr simary, Cin etranal "Sef or 4 a ei I St acHaBe| @ primary eee ‘ovine ame? cuit. inerare mine via SEED (Cuts cHa)yy ——+. (genta — yo yore’ Wi sernanism) Menih aeaadoncne ee pute a ee, vi ON TEH EOE BS ‘TleFe aut td 7 +CH3 “CHa @ - Br Ginen (ota) Br ¥2° 724 wih Br-c Qis-¢1- : Ape) i | MISeHs o(M9)o Or 09 °>OH with Or-c | Ceag@ig),cBr > 37 >-NO Hydrogen with Or -C. Br CH2-~CHOCH 3 7 9° 52H with Brae, Bae kent 4 3? hnalngendalikane. Sn? Hechanism: ee ee OF-¢ er SS | moe --~- Br peat eb > oA | pentavalent intermediate - ’ ar) WKANE_@ so Las alors st€p Wwvelve both she. wea ctarnith hence Sy? it —— 24° cpacbocatinn {s unstable = \ > So_gen tava ert intermedia ems instead! ii) Scanned with CamSeanner CH i ee bootome 5s mo es 4+ 2 Br Sees 6-H Sr ian dua =. eng ° s > Dasitive induction effect of ‘the _alteu\ group ‘Scanned with CamScarner ° leat a : OA ° aiaonol! 1 ReaGICTIT) en 3° al ca\sengde) ‘ 8 : g-e-k 34 re (O- a ~“Wketo ne aire oid, aldenyde, aS earboryie acd. ne 7, cupsravley, | _ fi Reduces — xido ric . PF arog _ ~2**4BAIP 4 etone 4_.__ reduced. phate OVOP oy is 4 Scanned with CamSeannet 4 nudrahon t Ol arene [gicom | —> gee readtion of alkene paks ® waiogennatzane | NadH [see reaction of halogenvalkane @ llecom ardebyde/ tetone 1 9 @) tho O=a + AN), Se ona eng ~eHp-oq_ | einanat seme TSS ethanol 8 [LardergaeJ = [aaron] \% ge ES hoi ab ucibixe OM e Dila_-a-chs + Qn SENHA Gy—e-cus | & Propanone l Hi z \Lxetone ] 3 combustion I SS subsite on +0 -Gem Inaiogenaalkaves [se source of halogeralkane' Gd A Co: ZX Reaction pith ight, reactive wis ACawgON + ON, —» 2caned Nar +H 2 [es vires renctin nace Qn WSONa (9), awire erysrating, so\id- ‘Scanned with CamSeanner EsieriGcation PEW STOPS OF CONT THOR os taro hic aleoh ———d Nerit 420. 4 cara ol _ Congcoo Nat + cata! {a CogcOOH - f ation = > spat \: ['see' source of alte ne bo’ P=conce aon ene = _cono WoSO4 Scanned with CamSeanner eo Lo] abasiaides aqiatm0r, We —o—u + Wa Siri ore aoa 4 orange 4 green lexcas ocidiGes og taCn0g Ha -8-on + Hoo RONEE AS QrEED TADOKYNE cy 2° atoanal = = + pits cH Sites es eee [2 Gidifed aa Ke Gr 307, eua=8 £0 + Ho ine RE HS oe, @) Tes negna ae Tited 2q_Wo Ors 0 nt acide: ro O7, 5 ge —C -oH wore Nee C4 Ho Coo Oz, [Link], aus NS ena ee a < oxidation | ‘Scanned with CamScanner y K g dn aR -a-R Lardyro] Cretong] | A\denyde --——-* al ean | | petone rb 1 BP vquepho\ _. : @I| Reaction sith nowt ken fro e360") °. : POR ee aero oa Q-C-H + Woy — + R-C-H tHe \ CN. “ \ Toit 6c oO A : J ae * Wen KON, gp = @-8 10 uc ee en} au } : | Jal © eg hg! “HANS TG, @ added tb eS aon yr Cbs +e .eroin oe axO S t “Ny 1-5) > 9 <2 Lee bine. TESusiOD ha Gn ee sel _® ie-* Lids Avitrs j— %- coon | re bie wat 7 = : : lk DOKI BAY J_ ie Pm OR dhe : Seanad with CamScanner es / Kejo! —— fit DNPH hyaenyde/ Da-ainerophendt hydra gina L224 ; 5 ope KetwFe consenaatign il)“ Nye eu | meach'on 42.9 4 oc, = » / Az oR y | eo ——> ae — ni R ah Se t yot-pr! Adio Sb op L 1 4 /e H20 ' ye Hany tious tis Farmaniaca| “ait iArate sol ¥ WINS ox raising apn 8 98 + . Reet Bulpocokeny @esoye cits algengae . Tjroxtaidea. : “ a ' - fenling’'s ceagend % anal . Fj pal gues mil oxid{ging ager! [otwe sol | 2 ° Z Mt 8 4 “ pia a ee — oe q = = A rr Me ROR no onidation Me ! —> ‘Scanned with CamScanner g ~b-ena- cys ! is U te vad: dijon. JEcapuale td rae ans } f d 1 yo) 9eh_ pci lute. 04, Hel + Heo - | rR tadis.| se Gn ot “ Hs -¢ “~cho~Chs = coon: =D he ; Sa aio WNENTH is ns hgaraeine é } Bik 7 ox ae Wher ge ioe ~cH- Cs CHa CHa ~SA Z ae = CHS 2 on? s 5 iz. =cHs ore Pr - QH3 Oz

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