0% found this document useful (0 votes)
35 views83 pagesGoC
goc iit jee notes
Uploaded by
sppatelipa4444Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
0% found this document useful (0 votes)
35 views83 pagesGoC
goc iit jee notes
Uploaded by
sppatelipa4444Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
/ 83
ele) Chemistey © |
Leeture = |
2-Wwes of Runs
— ;
i Xt % RK o|arri
Radical Bana ae ane Sf ie iy
weaker ALE A Se watt:
Berd | Sone . eM must)
(Apo Ay [pes |rsent-ss
repiee ye
aRe. A+ 8 a® + &
apricwnar KOU M5) Cens)
fe electronic. disacement
2- *ybes Ve
(Fy +25 eect %
see Ne
a Sily| gue
‘ a Br de o—ord a ear? ar
1, on, —SH
) uN cekur ated ynsckar ated orpnie gpeul Ge "4 rocerbor's)
he Eon (2 Bp Carters)
EP ey oe
wlemns
, cnet)
Scanned with CamScanner Appiahens of AT -efecte ¢ @
7 Sighility of Ren dnlermediates
K life. Hine a
C 4urvival Hine ) *k Species formed
; during a ~eachon
¥ yore \iGe- He, q .
more Stable Ke Short Mives SPSes
“3: sybes % helt filha
~~ p- A -O
Se we 1K ape / onal Y
A) —t L+@ — om |x Selb
(Bodie /e )I* “* 2k —deficiertt
vacant apAo ,
A
hetevob-si (( x Ap
&) —4 ® terest Sts, de 6-valence <5~
ye eo nade dems dere
(Garvoeh™ /K
Ay nah
AU
heberdy sts le |* af -
re) a i |_\@ ——> Jy * &- valence 47
yo Kee ith
(Garranion / ©)
Scanned with CamScanner Ques - Sretiility Cunha a@rison— ®
hint | _ Stalalizohion * Destabilzcton
—— <
ye! a | Qs
e/ ey PSE}
satay ” oft 2 +e | y -E
Se
examples jo © © ®
OM > CH,
") Gees as 7 We
a 22) (f-)
@,
— ()
2) Ae
ey? Ni cig? 7%
eK 2 ce?
OE es =) C 7
®
aD 7 Oy
2) «yh, hp >
Lov
ee
Scanned with CamScanner (2 @ MeL e ®
205). 2
deetabiliz:
5) € +P > > Uy > ~é oon
+EGnin) de hub Alizes
é) By << o-€oh) ~
poig
&) > at < a G3 oo
LT
eo
2 1 cop cdc es cing hd
1) MOP é
& 5 trin)
eince HIS
pe
-arule
Scanned with CamScanner Scanned with CamScanner Reseriance
1) Hols r-bene) -es7 cheloeal cation, (where ag
Inductive >aae |
Compan
| ex 6) Acrolein cegtatnh
Nen- Ren or flaw,
7 —@end
| oe
| Axe )
| a op
| Lori” ’ a
ae" } a Oe & \east Atal
due a :
Ghani
Le : vig, WAAR
rest oe Rs-—stabith beer
6. Cro iN. \2 > >w
yh 1 Hybmd /Real air
“Ey
rs)
rn
*h
|
Scanned with CamScanner Fe %) Virplawine oth
PE 2 US ©
Mer wa We = Ny
Pp Sie ig Leer Atabe RS,
RKP’ wee
“roe 4 Contribubes lesser,
more Sra RSs. ‘
RE} Contributes amore to Rn.
se Ny St, Leide
one Sen) er
ie ae : “Teal no of
a t+} Alternate \p2sitens
le Stable RS > Wolf Pespect to thangs Jp
Ques OD raw al\ possible R-s- of Rervole
L>
\
h
xn He XT KT :
Ques 42) shailivy Gmbbarisen SS vacant p-A0
vacant p- AO ad _ Va
ay we Be ee AO
ahaa on Se oy : (Gs charge 7 pre
we hight EN, 3:25 is 166 bie’)
aaa righty umetable ’) :
| () Prame Ge? vacant ag Hy oni
| high low "
C vacant. It'S violeHion fh
B= ©
©) = autooule Pancple
ce Highly Uncdeble
‘Scanned with CamScanner : Rx 5) Pyrvote | rrole
®. 3 Sarg
re Stable ae
“ee cree \ (s -“R: 5"
(Neutral RS) Cha
~ separation mae jratien
. De aes prsssrs
Coed)
ic} z=
ul canwete-d 24)
APY h'9
Bad) Fritts cb Ae
cS fig oor
KF Jocalirced tp: in 6p
ooG sae ple of Rie)
Ree Lmidacole a a
> :
Ke 2 ¢ YY ’ Sipte ae A
7 , 4, Cites ”
Scanned with CamSca Rutes for drawing RS .
) Only Ab [sp ako patisprres -
2) Abend -2s7 Mmovem-ent §
a) from Nen-Polav +o Poay = Boral, ;
») from es vith aise to oodeficient Ave:
Op G- Rend) —> @/edia)
3 Any yonder Atv, iS mot BS, Th vnust be
cable at benst +o Azom-e wextenk 4o tor
et Gould GQnivibute to RH.
(<) #98
sO! OP
Za ae va 7
hight unstable xr. (esse gale as.)
due fo Incomplete Saceael : ao .
octet on Oxygen: as) te 1 pled
So ttle nob Gssidared R'S~ iC
4) Loch RS» pace tame mo, of total <7
(e) Sawe Met change
t
oF
a> af
yA iy la SHAK Hithly =
© Charge ;
io “saan ——__?
zen 5 po een)
5 wR dy
eae oy &,, = eR ® oh re (2
Stable _ 4 ‘@ “i Ay \
a) ey
most Or . aviov?
mest CO
Scanned with CamScanner ss “S, :
YRS fovng th Pp: repulsion i6 henst -atabte,
eww ™,_ ‘
Lr
Le =I a
‘) @) Nike Charge ebaration (+/+ or --) mae be,
toabrbarni «Maximum.
(2) Unlike Charge “Separation GA) musk be bey
aninimum ,
WM
oN Jp Ae repulsion
example ot -.,©
) enw a UN
Os, 9;
so a LL
2Q--equivalent RES
. “ethane
aa <
Yr =n] (nites Di,
®
iy repulsion
i)
2 eee.
2
I oe No,_ oe eeste
© * Mest Arable
due to- Gon
eff. rO
\ Sigua = ?? Xr >D|
%) +t eltect also affects Ro— Saltity,
examples _ ax of.
4 merry l-
De > SS settee
© pia T-As,
nm ot
Scanned with CamScanner i) aD.
<-> © +L © >i
© ‘e —
r 1 HZ de stabilizes
ii) Cor > o ey aN
rc a ow
Feast Orast Stable
she Res: duet:
tw osaeal xs: a
jor >> FPL
sdb iA
8) Ris Navivg more N° of Bencencs
amo re le.
~ex— naphthalene
S-_-
Lge \nortem
a
Scanned with CamScanner Sues pen ty oncleate/s Ahoust es
” a
Ke wach lene) te .
Vg) yt E « eee
M2) BFA
£8 © ¢ Diazametnamre)
f See
4 Wh -valence
Ae Neborched fF has ©
when Nis None
Ne whee oe ae aii )
Ques Conifpare igh la
ecviabence Gn > CS
$) we, a
Wes me he
ap in 2p -
os eR ta
2) geo?
exctemcles) Qncamplete
~ eon \ugntien’) octet)
Beret is Gn plere
@
2 > Gor &
ex r2encred)
erga
Octe® is Gompblee<
oS .
Scanned with CamScanner Rord Resoran ce cal
Ce -Bend -es- delocatieatien)
<1) eyclopspy| medal Gatien Zepuh® te igh
Babe RO due to o-Bend rewraned,
ROA — (overbhhivy behwcen (e-ebend
| and "Oe p-A-o vy Aralaliees
chm® ) Ae
os p-Chavactt xs
CT Ba de
{co Bond has,
=
S
a
(2 - Reson Hy esreuctures)
\ +
5 ri Resenom ok Hybrid
; yes) Ste
Jc
oe sr
Le » - charac
Ww (e-gepend has Np ‘ P
Ww
\ ’ and p-
_ me minimyes © kite , oa
javacteets porcsent in -exoe on
; rdeeyece Lord& are sredistvibuteol «
en
results 19 higher w ot pchavacts
4
Scanned with CamScanner e kno “Hee relaHen ship —
Efuce WwW
t
Gend 4 hw S- Yop pchavacters
avu}-<" Characters
reqy iy ~
a ‘le gs-ey \nterna) Renc
Cmer< 7 p-characters, ! _
aveal-e ron jesse angle on
4 ¢
eooiir (& eae
2 - ‘CS
i [oak cho
ro AGA, DB ad :
. (2e-Bend
(32-aend _ Tesenancé)
eee) ae
Scanned with CamScanner or
) 3 ® Coy
Ch, —ony >
ae Ae
We aatre)
) OF Faprerel
a
BW is hig
Shabu @ )
Ss) re rest oe Re
— " 0
VY
(Aromat ity alownin g o~ Rend reenane
Scanned with CamScanner f Kesenance Ene
xv “er
s 4h
< barometer fey ne Area surement
of Btabilizasbion achieved by 9 species
Aue +o resenance, (more Srabdsjizotion |
Wigheer R é)
| K€. o« < ) No. af Stabte Res.
extent of vw
| Resonance, Sree depends upon
Ubon 70 +
; riteria-l,218)
| of n—Gends) -
| “ WwW extended Conjugetionr 4s.
more Fm portant +han
Crossed Conjugtion +
ee RB Com barison —
Presede 187
| ») rT ne 7 s Soy *
Aces aud
| y Bg
| 6 2, ae
| a Wo — =62n
(2-equivatent RS). peccrey ‘Stable KS + _
Saye due to Charge paretien
gnere RE. hescer &E-
jessey Stable . anor Kable ;
Caine wa amien) Ceance Bla renter
Scanned with CamScanner I 2) ecsenche d cnssed
Comjuygtien Con fugamo”
a) ae Se an
. y
Yaa 7 Ce
aa > a
) ( > td
©
Py)
9G) > wy
\
; . eye. Ahan than
extended coniyeg? ie ok R-Bends are
mywyper?
erosced Co ay o. a RS!)
Aanre -(-4- Soe
Bak Since DLO
) OW cose Gxvendes)
omit. moot Trends
ore ape of RSe
anere R-E.,
omner-e Stable’)
Scanned with CamScanner 0 >&
(see yesonance SlnCe tp on \esser EN-N)
s) @ ~< Ge) < SID < Ey
Aart racene
Benzene Naphthalene Ph-emar7th7ene
easy Gasp SRD Peres)
\e-nee |
Scanned with CamScanner —_ Mesome nic effect
eee
tye 4 n-es7 denaHon or votthdrawel “th
tyeseypance's Lt bri polaris TH a moleule
Per mawenth, Cre. Pettmenent &S a
oe onc 12
eS Se
» Ser Qyr S
Conant Lem, oe
= Sect, $2,
SS) ts YD kL 4g ee cme)
; ® ot & :
©
Scanned with CamScanner A bplied SS of elechoniC
