Carboxylic acids for the formulation of watersoluble

corrosion inhibitors for coolants

Additive TC 50 AC 128 AC 6105 AC 16101-M1

Triazine-tri- Alkyl-aryl Blend of polycarboxylic Blend of long chain

carboxylic acid sulfonamido-carboxylic acid acids dimer acids.
50% active matter 75% active matter 98% active matter 98% active matter
In flakes In flakes powder powder

Additive TC 85 AC 11 AC 12

Triazine-tri- Undecanedioic acid Dodecanedioic acid

carboxylic acid 98% active matter 98% active matter
85% active matter powder powder
In flakes

All corrosion inhibitors are free of nitrites

16.06.2021 - 1
 Ether-Carboxylic-Acids

short-chain alcohol medium-chain alcohol long-chain alcohol short- and long-chain alcohol
ECK 15074 ECK 15068 ECK 14689 ECK 15075

Ether-carboxylic-acid Ether-carboxylic-acid Ether-carboxylic-acid Blend of ether-carboxylic-

based on alcohol based on lauryl alcohol based on fatty alcohol acids
ethoxylates 7 Mol EO ethoxylates 3 Mol EO ethoxylates 5 Mol EO 5 - 7 Mol EO

ECK 21508 ECK 15102

Ether-carboxylic-acid Blend of ether-carboxylic-

based on fatty alcohol acids
ethoxylates 9 Mol EO 7 - 9 Mol EO

ECK 11427

Ether-carboxylic-acid
based on fatty alcohols.
PO/9EO. Low foaming
tendency

16.06.2021 - 2
 Corrosion inhibitors (liquid)
for non-ferrous metals

watermiscible and watersoluble Neatoils, greases

coolants and cleaners and industrial lubricants

Yellow metal inhibitor Yellow metal inhibitor

liquid liquid

based on TTZ based on BTZ based on TTZ based on BTZ

CI 50 T CI 185 CI 8172 CI 189 CI 190

(can also be used CI 8173
in hard metal grinding fluids)

16.06.2021 - 3
 Corrosion inhibitors - amine and boron based
for watermiscible and watersoluble coolants

pure Boric Amines

pure Boric Amines (DEA free) Boron based corrosion inhibitors
DEA - based

AB 16130 AB 5100 AB 16164 AB 105 T AB 104 T BB 138 AB 150 AB 5095 AB 6072

B = 6.1 % B = 5.3 % B = 1,6 % B = 4.2 % B = 2,8 % B = 5.8 % B = 3.7 % B = 5.3 % B = 6.7 %

prim. Amines prim./tert. prim./tert. tert. Amines prim./tert.. primary Amines primary amines DEA DEA
Amines Amines watersoluble Amines watersoluble C.I. watersoluble C.I. amines amine borate
watersoluble C.I. carbox. Acid corr. prot. partly neutral. w. partly neutral. w. (only outside of (only outside of
partly neutral. w. carboxylic acids carboxylic acids EU available) EU available)
carboxylic acids

16.06.2021 - 4
 Amine-based, boron-free corrosion inhibitors
for watermiscible and watersoluble coolants

MEA based MEA - free

CA 790 T AC 166 (Dual Use) AC 165 AC 166-B (Dual Use) AC 128-B (Dual Use)

MEA < 20 % MEA < 3.0 % MEA < 15.0 % Amine salt Amine salt of
Amine salt of Salt of triazine- Based on modified of triazine-tri- Alkyl-aryl
different tri-carboxylic acid Fatty acid- carboxylic acid sulfonamido-
carboxylic acids Watersoluble. MEA-amides watersoluble carboxylic acid,
Cu-inactive watersoluble

for synthetic, watersoluble and watermiscible metalworking coolants

All products are free of nitrites and secondary amines

16.06.2021 - 5
 Fatty Acid Amides

AC 7094 AC 3131 AC 9033 AC 2005/2

DEA < 3.5% DEA < 7% MEA < 25% MEA < 25%
Fatty acid DEAmide Fatty acid DEAmide Oleic acid MEAmide Fatty acid MEAmide
not ethoxylated not ethoxylated ethoxylated ethoxylated
based on coconut oil emulsifying emulsifying

16.06.2021 - 6
 Corrosion inhibitors for watersoluble coolants and cleaners
based on phosphoric acid esters

PE 740
acidic
P-acid ester
6% Phosphorous

Amine based, partially and fully neutralised Amine free, partially neutralised

PA 710 PA 715 PN 720 PN 720 P PN 722

MEA MIPA NaOH NaOH NaOH
Cu-inactive Cu-inactive partially neutralised hard water stable partially neutralised
TTZ-free neutralised pH 5.0 part. neutralised pH 2.6
neutralised

as amine free products

for the formulation of
watersoluble grinding fluids
no Cobalt leaching

16.06.2021 - 7
 Defoamers for watermiscible and synthetic coolants and cleaners

Synthetic and watermiscible Semi-synthetic and conventional

coolants watermiscible coolants

Si-copolymers Polyglycol derivative Wax-based / Si free Si-copolymers

Si-copolymers

ES 562 ES 500 ES 504 ES 502 ES 563 ES 561

ES 13473

Economic, Concentrates and Concentrates Concentrates Concentrates economic,

Easy to disperse Process-solutions + process- + process- easy to disperse
Emulsions Emulsions
(concentrated)

All defoamers are free of silicone, i.e. free of polydimethylsiloxane

16.06.2021 - 8
 Sodium Sulfonates (natural and synthetic)

16.06.2021 - 9
 Other Sulfonates

Barium Sulfonate Sodium Sulfonate Calcium Sulfonate

Carboxylate

BA 7A BA 14 A NAC 7097 CA 400 / CA 1

Neutral Overbased Sodium Sulfonate/Carboxylate Calcium Sulfonate

Barium Sulfonate Barium-Sulfonate for quick formulation TBN 400 (CA 400)
of boron-amine free fluids Neutral (CA 1)
in different water hardnesses

16.06.2021 - 10
 Sulfonate-containing, boron-free emulsifier packages
for milky (conventional) coolants

EM 609 EM 4098 EM 3154 EM 3015 EM 20044

economic emulsifier- Excellent corrosion High performance Economic milky Economic milky
package, easy to modify protection milky emulsifier package package for many package for many
treatrate 20-22 wt. % treat rate 20-25 wt. % many base oils paraffinic base oils paraffinic base oils
Naphthenic base oils hardwater stable treat rate ~20 wt.% treat rate 15-20 wt.% treat rate 10-15 wt.%
Suitable for HFA-E excellent corrosion inhibition (contains DEA,
DEA free version on request)

Easy formulation with:

EP / AW support agents
Biocides
Yellow metal inhibition
Defoamers
All products will be adjusted
to the respective baseoil

All emulsifier packages are free of nitrites, phenols, secondary amines and formaldehyde-releasers

16.06.2021 - 11
 Sulfonate- based, boron- free emulsifier packages
for semi-synthetic coolants

EM 650 EM 651 EM 8188 EM 10245 EM 4111 PE N

for boron free, amine-free for boron-amine- free, for boron-free for boron-free amine-free
and preservation agent-free for aluminium processing, amine containing mineral oil-free, ester based,
watermiscible coolants low foaming, mineral oil based semi-synthetic coolants,
with Phenoxyethanol / -propanol hardwater stable semi-synthetic coolants with Phenoxypropanol
well suited for low pH values concentrate 40-50% min. oil 30-70% min. oil in concentr. excellent corrosion inhibition
for machining of steel and aluminium

EM 7244 EM 11300

good corrosion- Low foaming for boron-amine- free, for boron-free

protection semi-synthetic coolants, amine containing
cutting of aircraft aluminium, mineral oil free, ester based
low foaming, semi-synthetic coolants
Concentrate ~ 28% mineral oil 30-50% ester in concentrate

All emulsifier packages are free of nitrites, phenols, secondary amines and formaldehyde-releasers

16.06.2021 - 12
 Emulsifier packages for watermiscible and semi-synthetic and milky coolants
Boron or lactic acid based (biostable)

Lactic acid based EM 3161

EM 7045 Boron / Ester based

for formulation of Boron based For quick formulation of

semi-synthetic boron and ester based
coolants based on watermiscible
amines and lactic acid semi-synthetic coolants
for hard waters

EM 8110 and EM 8115 N EM 12378 AB 4150 / EM 611 (DEA) EM 20049 EM 680

EM 5190 N (DEA) + EM 643 + EM 681

EM 8110 + EM 8115 N eco. for formulation of Combination for formulation Combination

emulsifier package, YMI boron containing AB 4150 / EM 611 (DEA) of boron containing EM 680 + EM 681
formulation of B- based watermiscible + EM 643 watermiscible For formulation of
Semi-synthetic coolants coolants for for formulation coolants for boron and mineral oil
(transparent emulsions) application on of boron based application on containing watermiscible
low foaming, 38% min. oil ferrous and non ferrous watermiscible coolants ferrous and non-ferrous milky coolants
blending 1:1 with water metals (semi-synthetic) (semi-synthetic) Metals (AL)
very hardwater stable low foaming, blending with (semi-synthetic) Mainly for processing
EM 5190 N (DEA)
40% oil in concentrate 20 - 50 wt.% of mineral oil of aluminium
blending 1:1 with water
possible and high grade steels
incl. biocide
32% mineral oil for steel
transparent emulsions

All emulsifier packages are free of nitrites, phenols and formaldehyde-releasers

16.06.2021 - 13
 New package technology: Semi-synthetic fluids
(high pH-value, multi-metal)

Biocide-free with Biocide

Multi-metal + Aluminium
Multi-metal (ferrous and non-ferrous) Emulsion stabilizer Multi-metal + Aluminium
boron-free

Boron-free Boron-based Boron-free

EM 18244 N (flexible in
formulating)
EM 17190 + EM 18140 EM 17190 + EM 17230 CL 17140 EM 18240 + EM 18242 EM 19005 N
(easy to formulate incl.
biocide)
Without biocide-free Without biocide-free
technology: EM 18185 technology: EM 18108

• New biocide-free technology (proven technology)

• Compatible with soft and hard water (0 ppm – 1000 ppm)
• Multi-metal technology and AL technology with a high pH
• Emulsions have a pH-value of ca. 9,4 - 9,6
• Appearance: Translucent up to milky depending on the water hardness
• Low CLP-labelling of finished products
• Low foaming

All emulsifier packages are free of nitrites, phenols, secondary amines and formaldehyde-releasers

16.06.2021 - 14
 Packages for synthetic fluids

Boron based Boron free

AB 17102 AB 20043 AC 6140 (Dual Use) AC 17107

Boron based additive package Economic Boron based Boron-free corrosion inhibitor Boron-free package
low foaming incl. biocide additive package low foaming low foaming, for grinding fluids
for grinding fluids low foaming for grinding fluids excellent corrosion protection,
excellent corrosion protection for grinding fluids excellent corrosion protection biocide, defoamer incl.
Treat rate 50% in water Treat rate 30-50% in water Treat rate 40-60% in water Treat rate 50% in water
transparent solutions transparent solutions transparent solutions transparent solutions

All packages/corrosion inhibitors can be blended with the following additives

• Watersoluble EP additives: EP 3056 W (P, S), AW 18074 (S)
• AW additives: PA 710 (phosphoric acid ester)
• Yellow metal inhibitor: CI 8172
• Lubricity improvers like glycols / NEW Polyalkylene gylcol: AWS 19201 (low foaming, EO/PO)
• Biocides (if not in the package)

All emulsifier packages are free of nitrites, phenols, secondary amines and formaldehyde-releasers

16.06.2021 - 15
 Non-ionic emulsifiers

Fatty alcohol PO/EO Fatty alcohol EO Fatty acid Castor oil

AE 300 EM 643 Estisurf 600 EM 15065

Long chain fatty alcohol Long chain fatty alcohol Long chain vegetable ethoxylated castor oil,
Propoxy-/ethoxylated ethoxylated fatty acids, ethoxylated esterified with fatty acid
3 Mol 2 Mol EO

AE 700 EM 643 M EM 15111

Long chain fatty alcohol Long chain fatty alcohol Ethoxylated castor oil,
Propoxy-/ethoxylated ethoxylated esterified with fatty acid
7 Mol 5 Mol EO

16.06.2021 - 16
 Packages for special applications

Emulsification of Emulsification of Emulsification of Emulsification of

mineral- and white oils White Sprits Terpenes Rapeseed oil
Isoparaffins
n-Paraffins

EM 5110
EM 620 EM 2019-99A WS 698 quick separation TE 693 TE 694 RE 691N Esticlean
EM 9252 + active anionics RE 692B AS-VEG
stable emulsions Corrosion protection

stable and Emulsfier for stable and instable Stable Rapeseed oil emulsions
metastable white oils solvent-emulsions for mould release agents
stable terpene-emulsions
mineral oil (Textile oil for printing roll cleaners
for cleaners
emulsions Emulsifier) and solvent degreasers Blend of vegetable esters
NPE-free NPE - free as mould release agent

16.06.2021 - 17
 Arkema EP-Additives

TPS 20 TPS 32 TPS 44

Characteristics
Di-Alkyl-Trisulfide Di-Alkyl-Pentasulfide Di-Alkyl-Polysulfide
Colour (Gardner) ≤5 ≤10 yellow
Appearance clear, transparent clear, transparent clear, transparent
Odour weak very weak weak
Flash point (°C) >121 >121 >80
Sulfur content (wt.%) 20-23 29-32 42-46
Breakdown temperature (°C) 199 ±2 174 ±4 219 ±3
Copper corrosion <1b corrosive <1b
Vapour pressure 10°C (hPa) 0.03 0.03 0.10
Density (g/cm³) 0.95 1.01 1.01
Molecular weight (g/mol) 434 498 210
Pour point (°C) -20 -20 10
Melting Point (°C) 3
Boiling Point (°C) 178
Viscosity 20°C (mPa·s) 603 4
Viskosität 40°C (mm²/s) 53 164
Drum weight (kg) 195 200 200

soluble in Benzene, Toluene, White Spirit, Benzene, Toluene, White Spirit, Benzene, Toluene, White Spirit,
Mineral Oil Mineral Oil Mineral Oil
insoluble in Water, light Alcohols Water, light Alcohols Water, light Alcohols

16.06.2021 - 18
ARKEMA EP-Additives

Base Oil TPS 20 TPS 32 TPS 44

Welding load (kg) 126 315 500 400

4 ball extreme pressure test Last non seizure load 20 100 63 63

ASTM D 2783 (kg)
Load Wear Index 15 55 72 64

4 ball wear test IP 239 Wear diameter (mm) 1,33 0,83 1,07 0,85

Reichert test Wear scar (mm²) 31 4,0 9,7

(5% by weight in a ISO VG32 paraffinic base oil)

16.06.2021 - 19
 EP-Additive Packages (1/2)

EP 7038 N EP 7041 EP 340 N EP 9180 AW 14599 EP 6095 EP 362 EP 380 N EP 3056W AW 18074

Watermiscible ● ● ●
Non watermiscible ● ● ● ● ● ● ● ●
Sulfonate ● ● ●
Sulphur ● ● ● ● ● ● ● ● ● ●
Phosphorous ● ● ● ●
Zinc ●
Mineral oil ● ● ● ●
Ester ● ● ● ● ● ● ● ● ● ●

Yellow metal activity,

4 1b 4 1a 1a 4 1 4 1 1
3 h, 100C
Application active inactive universal EP similar antiwear drilling, universal EP- universal EP- watersoluble watersoluble
sulphur sulphur additive EP 340 package for threading, additive additive sulphur- Sulphur-
carrier in carrier in package for yellow metal the cutting, package package phosphorus AW/EP
metal metal cutting oils inactive treatment milling, for partial for partial AW/EP additive for
working working 3-5% light duty of AL and active substitution substitution additive for fully
fluids fluids brass, sulphur of of fully synthetic
6-9% med.
inactive chlorinated chlorinated synthetic products
duty
sulphur paraffins, paraffins products
15-18% heavy yellow metal zinc-free
duty, inactive low ash
active sulphur giving

All products are chlorine free

16.06.2021 - 20
 EP-Additive Packages (2/2)

AW 14611 EP 15000 EP 15200 EP 16006 EP 15090 EP 15099 AW 18010

Watermiscible ●
Non watermiscible ● ● ● ● ● ●
Sulfonate ●
Sulphur ● ● ● ● ●
Phosphorous ●
Zinc
Mineral oil ● ● ● ● ●
Ester ● ● ● ● ●

Yellow metal activity,

4 1a 1a 4 4 4 4
3 h, 100C
Application Antiwear Package for Economic Package for Package for Package for Package for
package for cold forming Package for the the for the the
drawing and oils (circular cold forming formulation formulation formulation formulation
stamping oils lubrication), oils (circular of cold of precision of grinding of aqueous
for inactive lubrication), forming oils. cutting, fine and chipping metalworkin
Aluminium sullphur, inactive Can be used blanking and fluids mainly g fluids for
yellow metal sulphur, for mass forming oils for titanium. the
inactive yellow metal processing of production
inactive nuts and of profiles
screws from steel
and
galvanized
steel

All products are chlorine free

16.06.2021 - 21
 Oil soluble and watermiscible phosphoric acid esters

ethoxylated

PE 755
(5 EO)
P-Ester of an ethoxylated
fatty alcohol

EP/AW-Additive
for oil soluble and
watermiscible
metalworking coolants
Acid no.: 144 mgKOH/g
Phosphorous: 4.8 wt.%

16.06.2021 - 22
 Synthetic Monoesters

Estilube Estilube Estilube Estilube Estilube

L 245 L 210 L 290 L 300 L 360

Synthetic Fatty acid- Methylester Fatty acid- Synthetic

monoester Cocoate Cocoate - oleate
excellent hydrolytic low evaporation- - stearate
stability good hydrolytic- tendency - palmitate
high flashpoint stability good oxidation
excellent good wetting good wetting stability economic
wetting properties properties low Iodine no.
compatible with rubbers compatible
with sealants

Visc. 20°C: 3.0 5.0 - - - (mm²/s)

40°C: - 2.9 4.0 4.9 8.9 (mm²/s)
Flashp. °C: 130 138 180 170 191 (°C)
Acid no.: 0.1 0.5 0.5 0.1 0.5 (mg KOH/g)
Iodine. no.: <1 <1 55 <1 65 (g I²/100g)

better lubrication

better wetting

16.06.2021 - 23
 Pentaerythritol Esters

Estilube Estilube Estilube

P688 PTO P 1600N

natural natural natural and

saturated fatty acids, synthetic
Fatty acids good lubrication fatty acids,
high flashpoint, properties high viscosity,
low evaporation excellent lubrication
tendency, properties
oxidation stability

Viscosity : 28.7 66.2 1400 (mm²/s) 40°C

Flashpoint: 290 290 270 (°C) typ
Acid no.: 0.05 0.4 0.8 (mg KOH/g)
Iodine no.: 2 87 30 (g I²/100g)

enhanced lubrication and higher viscosity

16.06.2021 - 24
 Watermiscible Esters

TE 2000 CE 960 NN

Treat rate 5-25wt.% Treat rate 5-15wt.%

Acid no.: 6 Acid no.: 0.7
Iodine no.: 18 Iodine no.: 40
Visc. 40°C mm²/s: 293 visc.40°Cmm²/s: 340
watersoluble watersoluble,
transparent transparent

directly watermiscible, when neutralised

addition of water increases viscosity

enhanced lubrication

better wetting

better emulsifiability

16.06.2021 - 25
 Rust preventatives and dewatering additives
emulsifiable and oil based

Corr. Inhib. Corr. Inh. for emulsifiable rust preventatives dewatering fluids
for greases Slushing oils

AOS 5220 AOS 6320 AOS 5210 AOS 5240 AOS 5266 CE 813 B CE 831 DW 553

corrosion MP: 40-52 °C MP: abt. 70°C oil soluble and MP: 60°C allround additive strong dewater. pure dewatering
inhibitor for oil soluble and oil soluble and emulsifiable in oil soluble and pasty thin films oily prot. film additive
Li/Ca greases emulsifiable in emulsifiable in water, thin soft emulsifiable in petrolatum cont. good demulsif. leaves no film
ashless water, water, waxy film water 10% DW 553 good corr. Prot.
acid fume Excell. gener. exc. corr. prot. stable emulsion good wetting
AOS 5225 protection for corr. protection, humidity. prot. thin hard film petrolatum free
Ba based corr. slushing oils humidity protec. penetration MIL exc. corr. prot.
Inhibitor for Ford specific. MIL specific. specific. exc. Hum. prot.
Li/Ca greases

16.06.2021 - 26
 Additive Packages
for temporary rust protection

Barium - free Barium - containing

CX 976
mp.: 70°C BX 910-4
mp. 40°C
flashpoint 39°C
solid content 60% for solvents
removable with solvents and mineral oil
very long term protection (acid fume
resistant)
Pasty waxy film
dry film Soft film oily film excel. demulsif.
good corr. prot.
economic

CX 911 CX 909 CX 908 N AOS 6303 A AOS 6340 CX 914 B CX 940 AOS 6307
mp. 38°C mp.: 40°C mp. 38°C mp. 35°C mp. 35°C mp. 35°C mp. 10°C

for solvents for solvents for solvents and for solvents and for solvents and for solvents for solvents and for solvents
and mineral oil and mineral oil mineral oil mineral oil mineral oil and mineral oil, and mineral oil
thick, hard dry hard dry film elastic dry films soft film soft waxy film mineral oil very thin oily film (acid fume
film exc. demulsific. excel. [Link] wax-free good dewatering thick soft film wax based resistant)
excel. demuls. excel. [Link] excellent good dewatering Non staining AL wax-free fingerprint resist. oily film
excel. corr. prot. excel. dewatering. dewatering excel. corr. prot. excel. corr. prot. exc. light colour excel. demulsif.
excel.. demuls. MIL spec. excel. humidity dewatering good corr. prot. [Link]. prot.
prot. good corr.
prot.

16.06.2021 - 27
 Tackiness agents

Mineral oil based Vegetable oil based Ester oil based

based on Polyisobutylene (PIB) Methacrylate Natural based on

rubbers Polyisobutylene (PIB)

Tac Oil AM Tac Oil W Tac Oil C Tac Oil GS KF 234 Tac Oil BA Tac Oil AM/E

anti misting, based on white oil, Viscosity @70°C: Based on synthetic biodegradable, against oil mist, Ester
shear stable, light colour, textile oils 4.500 - 6.500 mPas oil (alkylate) based on rapeseed oil based, H2 approval
Viscosity @70°C: Viscosity @70°C: Viscosity @70°C: for adhesive oils and chain oils Viscosity @70°C:
1.250 - 1.750 mPas 3.000 - 5.000 mPas 4.500 - 6.500 mPas Viscosity Tac-Oil BA: 1.600 - 2.400 mPas

Tac Oil 16115 Tac Oil M Tac Oil P @40°C: 20.000 - 30.000 mPas
Viscosity KF 234
Viscosity @70°C: Viscosity @70°C: Viscosity @100°C:
@100°C: 2.200 - 3.000 mPas
1.050 - 1.350 mPas 600 - 900 mPas 2.350 - 2.800 mPas
(economic) H2 approval

16.06.2021 - 28