(a) CH 3 -CH 2 -CH 2 -Br(b) CH 3 -CHBr-CH 3 (a) Propyne (b) Propene

(c) Propanol (d) Propane

(c) BrCH 2 -CH =CH 2 (d) CH 2 =C=CH 2
99. n-propyl bromide on treatment with etbanolic potassium
88. The product of reaction between propene and HBr in the hydroxide produces [[Link] 1987; MP PMT 1997]
presence of a peroxide is (a) Propane (b) Propene
(a) CH 3 -CH 2 -CH 2 Br (b) CH 3 -CHBr-CH 3 (c) Propyne (d) Propanol
(c) CH 3 -CH 2 Br (d) CH 3 -CH =CHBr 100. The dehydrohalogenation of neopentyl bromide with
alcoholic KOH mainly gives
89. Ozonolysis of 2-methyl butene-2 yields
([Link] (Screening) 1990; MP PET 1993]
(a) Only aldehyde
(a) 2-metbyl-1-butene (b) 2-methyl-2-butene
(b) Only ketone
(c) Both aldehyde and ketone (c) 2, 2-dimethyl-1-butene (d) 2-butene
(d) None of these 101. Which is the most reactive hydrocarbon in the following
(JIPMER 2002]
90. The final product formed by the ownolysis of compound
RCH = CR 2 is (NCERT 1978) (a) Ethane (b) Ethyne
(c) Ethene (d) Methane
(a) RCHO
1011. Shape of ethylene molecule is [MP PET 1993]
(c) Both (a) and (b) (d) None of these (a) Tetrahedral (b) Pyramidal
91. Which one is an unsaturated compound [BIT 1990) (c) Planar (d) Linear
(a) C 6 H., (b) c. H 1 103. Electropbilic addition on a carbon-carbon double bond
(c) C3 H 1 OH (d) CH 3 OH involves the intermediate formation of a more stable
carbocation. This statement is called
92. Ethyl alcohol on heating with cone. H 2 SO • gives
(a) Saytzeffs rule (b) Baeyer's effect
[EAMCET 1979; MP PMT 1996) (c) Markownikoff's rule (d) None of these
(a) CH 3 COOC 2 Hs (b) C 2 H 6
104. CH 2 = CHCI reacts with HCl to form (CPMT 1985, 93]
(c) C 2 H • (d) C 2 H 2 (a) CH 2 CI-CH 2 C/ (b) CH 3 -CHC/ 2
93. Monohalides on reacting with alcoholic KOH give (c) CH 2 = CHCI .HCI (d) None of these
[MP PET 1982, 86; DPMT 1981; CPMT 1979, 83)
105. Deviation from Markownikoffs rule occurs in presence of
(a) Alkanes (b) Alkenes
(a) Zinc (b) Peroxides
(c) Alkynes (d) Aromatic hydrocarbons
(c) Hg-Zn/HQ (d) Allofthese
94. Ethylene is a member of..... series [BHU 1979)
(a) Alkyne (b) Olefin 106. Presence of peroxides affects the addition of [BHU 1987]
(c) Paraffin (d) Amine (a) HBr (b) HCl
(c) HI (d) All of these
95. In a double bond between two carbon atoms of ethene,
there are [NCERT 1981) 107. Catalyst used in dimerisation of acetylene to prepare
(a) Two sigma bonds perpendicular to each other cbloroprene is [BHU 1984]

(b) One sigma and one pi bond

(a) Hgso. +H 2 sO. (b) c,, 2 c1 2
(c) Two pi bonds perpendicular to each other (c) Cu 2 C/ 2 +NH 4 Cl (d) C11 2 Cl 2 +NH 4 OH
(d) Two pi bonds at an angle of 60" 108. Chloroprene is
96. The formation of alkene from alkyl halide is an example of (a) 2-chloro-1, 3-butadiene
[CPMT 1983; AMU 1982; Pb. CET 1986) (b) 3-chloro-2, 3-butadiene
(a) Addition (b) Elimination (c) 2, 3-dichlorobutadiene
(c) Substitution (d) (a) and (c) (d) None of these
97. In the following reaction 109. Chloroprene is used in making (MP PET 1985)
(a) Synthetic rubber (b) Plastic
CH 3 -CH 2 -CH 2 -CH 3 (AIIMS1983)
(c) Petrol (d) All of these
(a) CH 3 CH = CHCH 3 predominates uo. When isobutyl magnesium bromide in dry ether is treated
with absolute ethyl alcohol, the products formed are
(b) CH 2 = CHCH 2 CH 3 predominates (UT-JEE 1995]
(c) Both are formed in equal amounts (a) CH 3 -CH-CH 2 OH and CH 3 CH 2 MgBr
(d) The amount of production depends on the nature of I
CH 3
catalyst
98. The compound B formed in the following sequences of (b) CH 3 -CH -CH 2 -CH 2 -CH 3 and Mg(OH)Br
I
reactions is CH 3
A/c Q. KOii
B
(NCERT 1981)
 (c) CH 3 -CH -CH 3 and CH 3 -CH 2 0MgBr (c) c.H 2n. 2 (d) c.H 2n-,
I
CH 3 119. The product of following reaction is
CH 3
(d) CH 3 - CH - CH 3 • CH 2 = CH 2 and Mg{.OH)Br I
I CH - C-CH = CH cOlli lll<c>, :ll,o
CH 3 3 2
I Cil)[Link],

su. The predominant product [Link], when 3-methyl-2- CH 3

pentene reacts with HOC(, is [[Link] 1995) [MP PMT 1986; MP PET 1997]
Cl OH CH ,
I I I -
(a) CH 3 -CH 2 -C-CH-CH 3 (a) CH 3 -C-CH -CH 2
I I I
CH 3 CH 3 0H
Cl Cl CH 3
I I I
(b) CH 3 -CH 1 -C-CH -CH 3 (b) CH 3 -C-CH 2 -CH 2 0H
I I
CH 3 CH 3
OH OHCH 3
I I I
(c) CH 3 - CH 1 - C - CH - CH 3 (c) CH 3 - C - CH - CH 3
I I I
CH 3 CI CH 3
CH 3 0H CH 3
I I I
(d) CH 3 -C- CH-CH 3 (d) HOCH 2 -C-CH 2 -CH 2
I I
CH 3 CH 3
112. Which of the following occurs easily in ethylene 120. Which one of the following organic compounds
[MNll 1987, NCERT 1979) decolourizes an alkaline KMnO. solution[CPMT 1987, 93]
(a) Addition (b) Substitution (a) CS 2 (b) C 3 H 6
(c) Elimination (d) Rearrangement
W ~H 8 00 CH 3 0H
113. How many gm of bromine will react with 21 gm C 3 H 6
121. Decolourization of alkaline KMnO 4 is used as a test for
[MP PET 1985]
(a) So (b) 16o [AMU1983]
(a) Aromatic hydrocarbons
(c) 240 (d) 320
(b) Olefinic hydrocarbons
114. Conjugate double bond is present in [MP PMT 1987)
(c) Acetylenic hydrocarbons
(a) Propylene (b) Butadiene
(d) Cycloalkanes
(c) Isobutylene (d) Butylene
122. The reaction
115. On passing vapours of an organic liquid over finely
divided Cu at 573K the product was an alkene. This CH 1 = CH 2 + H 2 ~ CH 3 - CH 3 is called
250-300° c
reaction is
[MP PMT 1996; CBSE PMT 2001; MH CET 2001;
(a) Catalytic oxidation of primary alcohol BHU2002]
(b) Catalytic dehydrogenation of secondary alcohol (a) Wurtz's reaction
(c) Catalytic dehydrogenation of tertiary alcohol (b) Kolbe's reaction
(d) Catalytic dehydration of tertiary alcohol (c) Sabatier and Senderen's reaction
116. The total number of sigma u and pi(IT) bonds in an (d) Carbylamine reaction
ethylene molecule are 123. The alkene which on ozonolysis yields acetone is
(a) 4u.2JT (b) 4u. lJT [MP PMT 1986, 2000)

(c) 5u,2JT (d) Su,I JT

(a) CH 2 = CH 1
117. Cyclic hydrocarbon molecule A has all the carbon and (b) CH 3 -CH= CH 2
hydrogens in a single plane. All the carbon-carbon bonds (c) (CH 3 }zC=C(CH 3 )z
are of same length and less that 1.54 A but more than L34
(d) CH 3 -CH= CH-CH 3
A. C - C - C bond angle will be [CBSE PMT 1989)
(a) 120° (b) 1so 0 124. CH 3 CH =CHCHO is oxidized to CH 3 CH = CHCOOH
using [NCERT 19,S]
(c) 100" (d) 109°28'
(a) Alkaline potassium pennanganate
118. General fonnula of alkenes is
(b) Acidified potassium pennanganate
[CPMT 1975, MNR 1987; NCERT 1987, MP PMT 1994)
(c) Selenium dioxide
(d) Osmium tetroxide