KOHINOOR
GOC (ASSIGNMENT)
1. Heat of hydrogenation is minimum for :- 4. Which of the following molecules is expected to
have a greater resonance stablization ?
(1) (2)
(1) (2) (3) (4)
(3) (4)
5. Which is the major product of the following
2. How many moles of CO2 will be librated in the reaction ?
following reaction
Product
(1)
(1) 6 (2) 4 (3) 3 (4) 5
3. Which is correct option :
(A) > (2)
(Acidic strength)
(B) > (3)
(Basic strength)
(C) >
(Basic strength) (4)
(D) > 6. Acetic acid, (CH3COOH), has a pKa of 4.8.
Ethanol, (CH3CH2OH), has a pKa of 16.0. What
are the major species present, when acetic acid
(Acidic strength) and ethanol are added to water and the pH is
(1) A, B, C (2) A, C, D adjusted to 7.0 ?
(1) CH3CO2H and CH3CO2OH
(3) A, B, C, D (4) A, B, D
(2) CH3CH2O – and CH3CH2OH
(3) CH3CO2H and CH3CH2O –
(4) CH3 and CH3CH2OH
PHASE - ASSIGNMENT
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7. A molecule H2O (a) has conjugate acid (b) and 11.
conjugate base (c). What is acidic strength order
of a, b and c :-
(1) a > b > c (2) c > a > b
(3) b > a > c (4) b > c > a
8. Which of the following has most polar characters
?
(1) (2)
(3) (4) (1)
9. The correct order of acid strength in the
following
(I) (II)
(2)
(III) (IV)
(V) (VI)
(1) III > IV > VI > V > II > I (3)
(2) III > IV > VI > V > I > II
(3) III > IV > V > VI > I > II
(4) IV > III > VI > V > I > II
10. In which of the following nucleophilic
substitution reaction is not possible :-
(1) (2) (4)
(3) (4)
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12. Which of the following will react with NaHSO3 15. Which of the following is antiaromatic?
:-
(A) (1) (2)
(B)
(3) (4)
(C)
16. Compare c – c bond rotation in the following
(D)
molecules :-
(E)
(1) A, B, C, D (2) A, C, D
(3) A, D (4) A, C, D, E
13. In which of the following compound aromatic (1) I > II (2) II > I
product is not obtained
(3) I = II (4) can not be compared
(1) 17. Arrange in decreasing pKb -
(a) F – CH2 CH2 COOH
(2)
(b)
(3) (c) F – CH2 – COOH
(d) Br – CH2 – CH2 – COOH
Correct answer is-
(4) All
(1) (b) > (d) > (a) > (c)
14. Which one of the following is most reactive
towards electrophilic reagent? (2) (a) > (c) > (d) > (b)
(3) (c) > (b) > (a) > (d)
(1) (2) (4) (d) > (b) > (a) > (c)
18. Compare acidic strength of the following
compound:
(3) (4)
(1) P > Q > R (2) Q > P > R
(3) R > P > Q (4) R > P > Q
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19. Select the correct statement about this 22.
compound.
Basic strength order is
(1) All three C — N bond length are same. :-
(2) C2 — N and C3 — N bonds length are (1) a > b > c (2) b > a > c
same but shorter than C5 — N bond length. (3) c > a > b (4) c > b > a
(3) C1 — N and C5 — N bonds length are 23. Which of the following has minimum pKa :-
same but longer than C3 — N bond length.
(4) C1 — N and C3 — N bonds length are (1) (2)
different but both are longer than C5 — N
bond length.
20. Decreasing order of stability of given (3) (4)
carbocations is as :-
(a) 24. Minimum pKa value for :-
(b)
(c)
(d) (1) (2)
(1) b > d > a > c (2) a > c > b > d
(3) d > b > a > c (4) d > b > c > a
21. In the following carbocation, H/CH3 that is most
likely to migrate to the positively charged carbon (3) (4)
is -
25. Most stable carbocation is :-
(1) (2)
(1) CH3 at C-4 (2) H at C-4
(3) (4)
(3) CH3 at C-2 (4) H at C-2
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26. The correct order of decreasing basic strength is 29. Compare stability of the following carbocation ?
(i) (ii) (iii)
(1) i > ii >iii
(2) iii > ii >i
(3) iii > i >ii
(1) I > II > III > IV (2) II > III > I > IV (4) i > iii >ii
(3) II > IV > I > III (4) II > III > IV > I 30. Correct order of Ka :-
27. The order of stability of the following
carbocations
+
(I) CH2 = C H − CH2
+
(II) CH3 − CH2 − C H2
(III)
(1) B > A > D > C
(1) III > II > I (2) II > III > I
(2) B > C > A > D
(3) I > II > III (4) III > I > II
(3) B > A > C > D
28. Which of the following compounds has most
(4) B > C > D > A
acidic hydrogen ?
31. Total number of compound which can shows
tautomerism are :-
(1)
(2)
(3) (1) 1
(2) 2
(3) 3
(4) (4) 4
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32. In which of the following keto form exist more 34. Which of the following compound has negligible
dominantly in equilibrium (i.e. keto form is more enol content ?
stable than enol) :-
(1)
(1)
(2)
(2)
(3)
(4)
(3)
35.
(4)
33. Which of the following will show Tautomerism
(1) Arrange the given compounds according to
basicity :-
(1) S < Q < R < P (2) S < Q < P < R
(3) S < R < P < Q (4) P < Q < R < S
(2)
36. Which of the following cations is most stable ?
(1) (2)
(3)
(3) (4)
(4)
37. Basicity order of halide is :-
(1) F Θ > Cl Θ > I Θ > Br Θ
(2) F Θ > Cl Θ > Br Θ > I Θ
(3) I Θ > Br Θ > Cl Θ > F Θ
(4) F Θ > Cl Θ > I Θ > Br Θ
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38. In the following compound [P] :- 42. Which of the following is weakest base ?
(1) (2)
x = no. of localised lone pair, then what will be
the value of ‘x’. (3) (4)
(1) 4 (2) 5 (3) 6 (4) 3
39. Which of the following group show +m and – I 43. Among the following the aromatic compound is :
effect ?
(1) (2) (1) (2)
(3) (4) —OH
40. Which of the following is aromatic hydrocarbon (3) (4)
?
(1) 44. Most stable carbocation is :
(1)
(2) (2)
(3) (3)
(4) (4)
45. Which of the following intermediate is most
41. Which of the following order of inductive effect stable ?
is correct ?
⊕
(1) − N R3 < −NH2 [−I] (1) (2)
⊕
(2) −NO2 > − N H3 [−I]
(3) – CT3 > – CH3[+I]
(4) – OH > – OCH3 [ – I] (3) (4)
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46. The most stable free radical among the following 49. The acidity of the protons H in each of the
is – following is
(i) (ii) (iii)
(1) (2)
(1) i > ii > iii (2) ii > iii > i
(3) i > iii > ii (4) iii > i > ii
50. Which of following compounds forms highly
(3) (4) unstable enol ?
(1) (2)
47. After heterolytic bond fission of C – Cl bond,
which of the given compound forms most stable (3) (4)
intermediate carbocation ?
(1) (2) 51. Which is most stable alkene :
(1) (2)
(3) (4)
(3) (4)
48. In which of the following compound lone pair of
nitrogen is localised ?
52. Write the order of basic strength :-
(1) (2)
(3) (4)
(1) P > Q > R > S
(2) Q > P > R > S
(3) Q > P > S > R
(4) S > P > Q > R
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53. Find correct order of basic strength :- 56. Most stable carbocation among the following is
(A) (B) (C) (D)
(1) (2)
(1) A > B > C > D (2) B > A > C > D (3) (4)
(3) D > C > A > B (4) B > C > A > D
54. Compare relative stability of following
resonating structures :-
57. Compare the stability of carbocation which are
formed when react with AgNO3?
(a) (b) (c)
(1) a > b > c (2) b > a > c
(3) c > b > a (4) a > c > b
(1) a > b > c > d (2) a > c > d > b 58. Maximum stable carbocation is ?
(3) a > d > c > b (4) c > d > b > a (1)
55. Correct stability order of following resonating
structure :- (2)
(3)
(4)
59. If Δ G° < 0 then Keq is equal to :-
(1) K < 0
(2) – 1 < K < 1
(1) III > II > I (2) I > II > III (3) K = 0
(3) I > III > II (4) II > I > III (4) K > 1
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60. Major product in the reaction : 64. In which of the following has maximum
nucleophilicity :-
Product (1) (2) (3) (4)
65. Which of the following can not give white ppt.
with AgNO3 :-
(1) (2) (1) CH2= CHCH2Cl (2) PhCl
(3) PhCH2Cl (4) (CH3)3CCl
66. Which of the following is the most correct
(3) (4) electron displacement for a nucleophilic reaction
to take place?
61. Which of the following alkyl halide produces
(1)
white precipitate of AgCl most readily on
reaction with AgNO3?
(2)
(1) (2)
(3)
(4)
(3) (4)
67. In which of the following, replacement of Cl – is
most difficult?
62. The correct order of energy required for breaking (1) (2)
of C – Cl bond in the following compounds is:-
(3) (4)
68. Which is correct order of stability ?
(1) x > y > z (2) z > y > x (1)
(3) z > x > y (4) y > x > z (2)
63. (3)
(4)
What intermediate is formed in this reaction ?
(1) Carbocation (2) Benzyne
(3) Free radical (4) Nitrene
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69. Which is least stable in the following :- 73.
(1) (2)
(3) (4) Arrange the following in decreasing order of
bond energy :
70. The most stable resonating structure of (1) Hc > Ha > Hb (2) Hb > Ha > Hc
¨
⋅ ⋅ O − CH = CH2 is :-
CH3 − →
(3) Ha > Hb > Hc (4) Hc > Hb > Ha
− ⊕
(1) CH3 − O − CH CH 74. Most stable carbocation is :-
2
(2)
(1) (2)
(3)
(4) All are equally stable
71. Stability order of the following resonating (3) (4)
structure will be :-
75. Which of the following carbcation is most stable
(I) (II) :-
(1) (2)
(III) (IV)
(3) (4)
(1) I > II > III > IV (2) II > I > III > IV
(3) III > II > I > IV (4) I > III > II > IV 76. The stability of carbanion in the following :
72. In which structure carbon does not act as a
electrophile:
(1) CH3 – CH2 – Cl (2) CH3 – CO – CH3
(3) (4) CH3 – CN
(1) d > b > a > c (2) d > a > b > c
(3) a > d > b > c (4) a > b > c > d
PHASE - ASSIGNMENT
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77. Compare the stability of carbocation which are 81. Which of the following is strongest base
formed when react with AgNO3 ?
(1) (2)
(1) A > B > C (2) A > C > B
(3) B > C > A (4) B > A > C
78. Which of the following represents the correct
(3) (4)
order of stability of the given carbocations?
82. Which of the following will be strongest base:
(1) (2)
(1) III > I > II (2) I > III > II
(3) III > II > I (4) II > III > I
79. The most stable carbanion is
Θ Θ (3) (4)
(1) CH3 − C H2 (2) CH2 = C H
Θ Θ
(3) CH ≡ C (4) (CH3 )2 C H
80. The correct order of stability of given 83. The correct statement regarding electrophile is :-
carbocations is (1) Electrophile is a negatively charged speices
and can form a bond by accepting a pair of
electrons from another electrophile
(2) Electrophiles are generally neutral species
and can form a bond by accepting a pair of
electrons from a nucleophile
(3) Electrophile can be either neutral or
positively charged species and can form a
(1) I > IV > III > II
bond by accepting a pair of electrons from
(2) I > IV > II > III a nucleophile
(3) IV > I > III > II (4) Electrophile is a negatively charged species
(4) IV > I > II > III and can form a bond by accepting a pair of
electrons from a nucleophile
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84. Order of nucleophilicity of halide ion in H2O 87. Ionic species are stabilised by the dispersal of
solvent charge. Which of the following carboxylate ion
(1) F − > Cl− > Br− > I − is the most stable?
(2) I − > Br− > Cl− > F −
(1)
(3) Br− > Cl− > F − > I −
(4) I – ≈ Br – > Cl – ≈ F –
85. Select the most stable carboncation among the (2)
following -
(1) (3)
(4)
(2)
88. CH3 – O – CH=CH2, oxygen atom of this
molecule is :-
(3) (1) sp3 hybridised
(2) sp2 hybridised
(3) sp hybridised
(4)
(4) unhybridised
86. Covalent bond can undergo fission in two 89. In which molecule, lone pair of nitrogen is not
different ways. The correct representation part in resonance :-
involving a heterolytic fission of CH3 – Br is :
(1)
(1)
(2)
(3) (2)
(4)
(3)
(4)
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English 15
90. The most stable carbocation among the 92. Which of the following represent methyl
following is? carbocation ?
(1) (2)
(1) (2)
(3) (4)
(3) (4) 93. Four structures are given in options (a) to (d).
Examine them and select the anti-aromatic
structures.
91. In which of the following compound Steric
inhibition of resonance effect will operate ?
(1)
(1) a and d (2) b and c
(3) b and d (4) only d
94. Which is most basic ?
(2)
(1) (2)
(3)
(3) (4)
(4)
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95. Which of the following can show tautomerism :- 98. Which is most acidic ?
(1) (2)
(1) (2)
(3) (4)
(3) (4)
96. Which of the following has two equivalent
resonating structure ? 99. If 'X' substituent present at para position of
benzoic acid decreases its pKa, then 'X' is :-
(1) (1) – OCH3 (2) – CH3
(3) – OH (4) – CN
100. Which of the following compounds are
(2) antiaromatic :-
(3)
(4) (1) (III) and (VI) (2) (II) and (V)
(3) (I) and (V) (4) (V) and (VI)
97. Arrange the following in decreasing order of
stability:
(i)
(ii)
(iii)
(1) i > ii > iii (2) ii > i > iii
(3) iii > i > ii (4) iii > ii > i
PHASE - ASSIGNMENT
