Battery Information Sheet
Primary Li-MnO2 cells and packs
According to REACH regulation (EC 1907/2006, Art 31) and to OSHA regulation (29 CFR
1910.1200), batteries are ARTICLES with no intended release. As such, they are not covered
by legal requirements
to generate and supply an SDS or an MSDS.
This Battery Information Sheet is provided solely as an information
document for the purpose of assisting our customers, as an
“Article Safety Datasheet”.
1. IDENTIFICATION
All data are valid for cells and packs as long no other information is given.
1.1 Product
Lithium Manganese dioxide primary cells and packs composed of these cells
1.2 Supplier
Headquarters Saft S.A.S.
Address 26 quai Charles Pasqua, 92300 LEVALLOIS-PERRET – France
Phone/Fax Phone / Fax : +33 1 58 63 16 00/+33 1 58 63 16 18
Factory Friemann & Wolf Batterietechnik GmbH
Address Industriestrasse 22, 63654 BÜDINGEN - Germany
Phone/Fax +49 (0)6042 954 150 / +49 (0)6042 954 490
Factory Saft Poitiers
Address Rue Georges Leclanché – BP n°1039, 86060 POITIERS Cedex 9 - France
Phone/Fax +33 (0)5 49 55 48 48 / +33 (0)5 49 55 48 50
Factory Saft Ltd.
Address River Drive, Tyne & Wear, SOUTH SHIELDS, NE33 2TR - UK
Phone/Fax +44 191 456 1451 / +44 191 456 6383
Factory Saft Valdese
Address 313 Crescent Street, VALDESE, NC 28690 - USA
Phone/Fax +1 828 874 4111 / +1 828 874 2431
1.3 Emergency contact: Chemtrec US Service within the USA: +800 424 93 00/ outside : +1 703 527 3887 (English)
For M cells: +49(0) 6042-954-599 (German and English)
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2. HAZARD IDENTIFICATION
Not chemically dangerous with normal use in accordance with Saft recommendations as stated in the user
manuals or other similar documentation. Under normal conditions of use, the electrode materials and
electrolyte they contain are not released to the outside, provided that the battery integrity is maintained and
seals remain intact. Exposure to the ingredients contained within or their combustion products could be harmful.
Risk of exposure only in case of abuse (mechanical, thermal, electrical) which leads to the activation of safety
valves and/or the rupture of the battery containers. In particular, the battery should not be opened, burned or
stored/used above the specified temperature range (for more details see Section 4). Electrolyte leakage or
battery venting/explosion/fire may follow, depending upon the circumstances.
Protection from charging:
Whenever lithium batteries are not the single power source in a circuit, the following measures recommended
by Underwriters Laboratories are relevant. The cells should not be connected with an electrical power source
that would increase the load through the cells. The electronic circuit shall include one of the following:
A. Two suitable diodes or the equivalent in series with the cells to prevent any reverse (charging) current.
The second diode is used to provide protection in the event that one would fail. Quality control, or
equivalent procedures, shall be established by the device manufacturer to check that the diode polarity
is correct for each unit.
or
B. A blocking diode or the equivalent to prevent any reverse (charging) current and a resistor to limit
current in case of diode failure. The resistor should be sized to limit the reverse (charging) current to
the maximum value according to the data sheet of the cell.
Hazards in case of opened cells by released material:
EYE CONTACT: Can cause eye irritation. Dust may cause inflammation of eyelids.
SKIN CONTACT: Can cause skin irritation.
INHALATION: Can cause respiratory tract and mucus membrane irritation. If gas is generated during battery
disassembly, throat irritation may occur.
INGESTION: Can be poisoning if swallowed.
3. COMPOSITION, INFORMATION OR INGREDIENTS
3.1 At cell level
3.2
Component CAS Number EINECS/ELINCS Content (wt. %)*
Lithium 7439-93-2 31-102-5 3-4
Manganese dioxide 1313-13-9 215-202-6 40-50
Organic electrolyte** N/A N/A 15-25
Carbon 1338-86-4 1-5
Copper 7440-50-8 231-159-6 1-15
Aluminium 7429-90-5 231-072-3 1-20
Stainless steel, Nickel, N/A N/A remainder
and inert material.
* Quantities vary with cell type
** Contains 1,2-Dimethoxyethane (CAS 110-71-4, EINECS 603-031-00-3), content < 3 % listed on REACH candidate list since June 2012
3.3 At battery pack level
Depending on the type of battery pack the content may vary but will not exceed the given content ranges.
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4. FIRST AID MEASURES (not anticipated under normal use)
4.1. Electrolyte contact
EYE CONTACT: Irrigate thoroughly with water for at least 15 minutes. Obtain medical attention.
SKIN CONTACT: Wash off skin thoroughly with tap water. Remove contaminated clothing and wash before reuse.
In severe cases obtain medical attention.
INHALATION: Remove from exposure, rest and keep warm. In severe cases obtain medical attention.
INGESTION: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain medical attention.
FURTHER TREATMENT: All cases of eye contamination, persistent skin irritation and casualties who have
swallowed this substance or been affected by breathing its vapours should be seen by a doctor.
4.2. Lithium metal contact
EYE CONTACT: Immediately flush with large quantities of water for at least 15 minutes, with open eyelids, and
get medical attention.
SKIN CONTACT: Remove particles of lithium from skin as quick as possible. Immediately flush with plenty of
water for at least 15 minutes and get medical attention.
INHALATION/INGESTION: Contents of an opened cell may cause respiratory tract and mucus membrane
irritation. Remove from exposure, rest and keep warm. Immediately inhale Cortisone spray. In severe cases,
track medical surveillance for 48 hours.
5. FIRE FIGHTING MEASURES (not anticipated under normal use)
EXTINGUISHING MEDIA:
• Li-MnO2 cells and batteries: CO2 extinguishers or, even preferably, copious quantities of water or water-
based foam can be used to cool down burning Li-MnO2 cells and batteries, as long as the extent of the
fire has not progressed to the point that the lithium metal they contain is exposed (marked by deep red
flames).
• Raw lithium: Use only metal (Class D) extinguishers.
• Do not use sand, dry powder or soda ash, graphite powder or fire blankets.
SPECIAL FIRE FIGHTING PROCEDURES: Fire fighters should wear self-contained breathing apparatus.
Use approved / certified vapour respirator to avoid breathing toxic fumes. Wear protective clothing and
equipment to prevent potential body contact with electrolyte solution. It is permissible to use any class of
extinguishing medium, specified above, on these batteries or their packing material. Cool exterior of batteries if
exposed to fire to prevent rupture.
PARTICULAR HAZARDS RESULTING FROM EXPOSURE TO THE SUBSTANCE/PREPARATION, TO COMBUSTION
AND GAS PRODUCTS: The cell can release vaporized or decomposed electrolyte fumes when being heated to
temperatures above their temperature rating. Solvents within the electrolyte are flammable liquids and must be
kept away from any kind of ignition source.
Above 160°C (+356°F) cells / packs may explode and release sparks, metallic parts and burning lithium.
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6. ACCIDENTAL RELEASE MEASURES (not anticipated under normal use)
INDIVIDUAL PRECAUTIONS: Evacuate the employees from the contaminated area until fumes dispersal. In case
of electrolyte leakage from a cell or battery, do not inhale the gas as possible. In case of skin or eye contact,
inhalation or ingestion, follow the measures described in section 12.
ENVIRONMENTAL PRECAUTION: Avoid sewage, surface water and underground water contamination. Avoid
ground and atmosphere contamination.
WAYS OF CLEANING: Wearing protective glasses and gloves, use absorbent material (sand, earth or vermiculite)
to absorb any exuded material. Seal leaking battery (unless hot) and contaminated absorbent material in plastic
bag and dispose of as Special waste in accordance with local regulations.
7. HANDLING AND STORAGE
IMPORTANT NOTICE: The battery should not be opened without Saft approval, destroyed or incinerated since
the battery may cause fire or the ingredients contained in the cells could be harmful under some circumstances
if exposed.
The Lithium Manganese dioxide cells described in this Battery Information Sheet are sealed units which are not
hazardous when used according to the recommendations of the manufacturer.
STORAGE:
• Store in a cool, dry place but prevent condensation on cells and batteries.
• Elevated temperatures can result in shortened battery life and degrade performance.
• Do not store batteries in high humidity environments for long periods of times.
• Since short circuit can cause burn hazard, leakage or explosion hazard, keep batteries in original
packaging until use and do not mix them.
• Keep original packaging for return of cells or battery packs to the supplier.
HANDLING:
• Do not recharge
• Do not over-discharge or force discharge
• Do not short (+) or (-) terminal with conductors.
• Do not reverse the polarity
• Do not open the battery packs or cells
• Do not submit to excessive mechanical stress (puncture, crush, deformation etc.).
• Do not expose to water or condensation, oxidizing or reducing agents, acids or bases.
• Do not expose to temperatures above the temperature rating of battery.
• Do not directly heat, solder or throw into fire.
• Immediately disconnect the batteries if, during operation, they emit an unusual smell, feel hot, change
shape, or appear abnormal in any other way. Put straight into a bucket of water. Contact Saft if any of
these problems are observed.
BATTERY PACK ASSEMBLY:
The design and assembly of battery packs require special skills, expertise and experience. Therefore it is not
recommended that the end user attempts to self-assemble battery packs. It is preferable that any battery using
lithium cells is fabricated by Saft to ensure proper battery design and construction. A full battery assembly service
is available from Saft which can be contacted for further information. If for any reason, this is not possible, Saft
can review the pack design in confidence to ensure that the design is safe (in assembly and use) and capable of
meeting stated performance requirements.
OTHER:
Follow Manufacturers recommendations regarding maximum recommended currents and operating
temperature range.
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8. EXPOSURE CONTROLS AND PERSONAL PROTECTION* (not necessary under normal use)
Handle an opened battery or cell only in a well-ventilated place.
In case of incident or after an abusive use, in case of a cell opening or a leak,
Respiratory use gas mask which covers the whole face and equipped with ABEK type filters
protection or escape mask type Self-Contained Breathing Apparatus.
Fire fighters should wear self-contained breathing apparatus.
Hand Use polypropylene, polyethylene, rubber or Viton gloves when handling leaking
protection or ruptured cells.
In case of incident or after an abusive use, in case of a leak or cell opening,
Eye
wear safety glasses with protected side shields or a mask covering the whole
protection face when handling leaking or ruptured cells
In the event of leakage or ruptured cells, wear a rubber apron and protective
Other
clothes.
*AFNOR pictograms
9. PHYSICAL AND CHEMICAL PROPERTIES
The lithium-MnO2 cells or batteries described by this Battery Information Sheet are sealed units when offered
for sale. They are manufactured “articles” and do not expose the user to hazardous chemicals when used in
accordance with manufacturer specifications.
10. STABILITY AND REACTIVITY
Product is stable under conditions described in Section 4.
The following hazards may occur under abuse conditions in case of cell opening:
HAZARDOUS REACTIONS: Lithium released from the cell may react with water in the atmosphere and produce
hydrogen, which is a highly flammable gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition of the cell may release electrolyte liquid
and vapour, harmful materials, and dusts.
MATERIALS TO AVOID: Oxidizing agents, bases, water.
CONDITIONS TO AVOID: Do not heat above the temperature given in the data sheet of the specified cell or
incinerate. Do not disassemble, crush, pierce, short, charge or recharge. Avoid mechanical or electrical abuse.
11. TOXICOLOGICAL INFORMATION
Risk of irritation occurs only if the cell is mechanically, thermally or electrically abused to the point of
compromising the enclosure. If this occurs, irritation to the skin, eyes and respiratory tract may occur.
1,2-Dimethoxyethane (EGDME) may impair fertility and may cause harm to unborn child. EGDME is listed on the
REACH candidate list as SVHC since June 2012.
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12. ECOLOGICAL INFORMATION
None known if used/disposed of correctly
13. DISPOSAL CONSIDERATIONS
Battery recycling is either mandatory (European Directive 2006/66/EC) or recommended.
Since even cells and batteries discharged to their cut-off voltage can still contain considerable amounts of
energy, terminals should always be protected to avoid short circuits.
Dispose in accordance with local laws and regulations (contact your local dealer). Store material for disposal as
indicated in Section 4.
Do NOT dump into any sewers, on the ground or into any body of water.
For large quantities a disposal service is offered on request.
See the section on “Sustainability & Environment” on
https://www.saft.com/about-us/manufacturing-our-batteries/our-sustainability-global-approach
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March 2023 – Version 2.2 – Li-MnO2 cells and battery packs
14. TRANSPORTATION INFORMATION
Persons engaged in the transport of dangerous goods shall be trained in the contents of dangerous goods
requirements commensurate with their responsibilities (Chapter 1.3, UN Recommendations on the Transport
of Dangerous Goods Model Regulations).
To verify that the Saft cells or batteries have been tested for transport according to the
UN Model Regulations, Manual of Tests and Criteria, Part III, subsection 38.3, please
perform the below two steps;
1. Go on-line to https://saft4u.saft.com/en/tsr or scan the QR Code:
2. Enter the cell or battery part number from the transport documents (Waybill or
Packing Slip) and click “Search” to receive a PDF copy of the relevant UN 38.3 Test
Summary Report for the product being shipped.
14.1 UN Class 9 Miscellaneous Dangerous Goods
Proper shipping Name Class UN No.
LITHIUM METAL BATTERIES 9 3090
LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT 9 3091
LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT 9 3091
14.2 International Agreements
By Air International: IATA: DGR Edition 2023 (64th)
By Sea International: IMDG: Code 2022 Edition
European road transportation: ADR: 1 January 2023
European rail transportation: RID: Dangerous Goods by Rail 2023
European inland waterways: ADN: 1 January 2023 Edition
15. REGULATORY INFORMATION
Regulations specifically applicable to the product:
- ACGIH and OSHA: see exposure limits of the internal components of the battery in section 14.
- IATA/ICAO (air transportation): UN 3090 or UN 3091.
- IMDG (sea transportation) : UN 3090 or UN 3091.
- Transportation within the US-DOT, 49 Code of Federal Regulations
- UK regulatory references: Classified under CHIP.
- Battery Directive (2006/66/EC): see section 9
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16. OTHER INFORMATION
Friemann & Wolf Lithium MnO2-cells are registered by Underwriters Laboratories, Northbrook, USA under File-
No. MH 46385, Project-No.: 08CA08489.
This information has been compiled from sources considered to be dependable and is, to the best of our
knowledge and belief, accurate and reliable as of the date compiled. However, neither exhaustively nor perfect
reliability can be granted. Information does not imply implicit or specific warranty of it.
This information relates to the specific products designated and may not be valid for such products used in
combination with any other materials or in any process. It is the user’s responsibility to satisfy himself as to the
suitability and completeness of this information for his particular use.
Saft does not accept liability for any loss or damage that may occur, whether direct, indirect, incidental or
consequential, from the use of this battery information sheet provided as a service to our customers. Saft does
not offer warranty against patent infringement.
26 Quai Charles Pasqua Doc N˚ BIS12-04-19 Data in this document is
92300 Levallois-Perret – Edition: March 2023 subject to change without
France Version 2.2 notice and becomes
Tel.: +33 (0)1 49 93 19 18 contractual only after written
Fax: +33 (0)1 49 93 19 69 confirmation.
www.saft.com
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March 2023 – Version 2.2 – Li-MnO2 cells and battery packs
