SAFETY DATA SHEET

Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

29 CFR 1910.1200 (OSHA HazCom 2012)

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product identifier
Trade name : Valvoline™ VR1 Racing™ SAE 50
Racing Oil

Product code : 822350

Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Lubricant

Details of the supplier of the safety data Emergency telephone number

sheet 1-800-VALVOLINE (1-800-825-8654)
Valvoline LLC
100 Valvoline Way Regulatory Information Number
Lexington, KY 40509 1-800-TEAMVAL (1-800-832-6825)
United States of America (USA)
1-800-TEAMVAL (1-800-832-6825) Product Information
1-800-TEAMVAL (1-800-832-6825)

[email protected]

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Eye irritation : Category 2A

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : Causes serious eye irritation.

Precautionary Statements : Prevention:

Wear eye protection/ face protection.
Wash skin thoroughly after handling.
Response:
If eye irritation persists: Get medical advice/ attention.

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Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

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IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue
rinsing.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components
Chemical name CAS-No. Classification Concentration (%)
DISTILLATES (PETROLEUM), 64742-54-7 Not a hazardous >=50.00 - < 60.00
HYDROTREATED HEAVY substance or mixture.
PARAFFINIC
Zinc O,O,O',O'-tetrakis(1,3- 2215-35-2 Skin Irrit. 2; H315 >=1.50 - < 5.00
dimethylbutyl)
bis(phosphorodithioate Eye Dam. 1; H318

Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Do not leave the victim unattended.

Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.

If inhaled : If breathed in, move person into fresh air.

If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact : Wash contaminated clothing before re-use.

If on skin, rinse well with water.
Remove contaminated clothing. If irritation develops, get
medical attention.

In case of eye contact : Protect unharmed eye.

Remove contact lenses.
Immediately flush eye(s) with plenty of water.

If swallowed : Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

Most important symptoms : Causes serious eye irritation.

and effects, both acute and No symptoms known or expected.
delayed

Notes to physician : No hazards which require special first aid measures.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing : High volume water jet

media

Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.

Hazardous combustion : carbon dioxide and carbon monoxide

products

Specific extinguishing :
methods

Product is compatible with standard fire-fighting agents.

Further information : Standard procedure for chemical fires.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Persons not wearing protective equipment should be excluded

protective equipment and from area of spill until clean-up has been completed.
emergency procedures Use personal protective equipment.

Environmental precautions : Prevent further leakage or spillage if safe to do so.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Other information : Comply with all applicable federal, state, and local regulations.

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Dispose of rinse water in accordance with local and national
regulations.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Avoid contact with skin and eyes.
Container hazardous when empty.
Do not smoke.
Do not breathe vapours/dust.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
DISTILLATES (PETROLEUM), 64742-54-7 TWA 5 mg/m3 OSHA Z-1
HYDROTREATED HEAVY Mist
PARAFFINIC
TWA 5 mg/m3 ACGIH
Inhalable
particulate matter
TWA 5 mg/m3 OSHA P0
Mist
TWA 5 mg/m3 NIOSH REL
Mist
ST 10 mg/m3 NIOSH REL
Mist
PEL 5 mg/m3 CAL PEL
particulate
Engineering measures : Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.

Personal protective equipment

Respiratory protection : No personal respiratory protective equipment normally
required.

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Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

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Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

Eye protection : Wear chemical splash goggles when there is the potential for
exposure of the eyes to liquid, vapor or mist.

Skin and body protection : Wear resistant gloves (consult your safety equipment
supplier).
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Safety shoes
Impervious clothing
Wear as appropriate:

Hygiene measures : When using do not smoke.

When using do not eat or drink.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : amber

Odour : hydrocarbon-like

Odour Threshold : No data available

pH : No data available

Melting point/freezing point : No data available

Boiling point/boiling range : 600.01 °F / 315.56 °C

(1,013.333333 hPa)
Calculated Phase Transition Liquid/Gas

Flash point : 394 - 480 °F / 201 - 249 °C

Method: Cleveland open cup

Evaporation rate : No data available

Flammability (solid, gas) : No data available

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Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

Self-ignition : No data available

Upper explosion limit / Upper : 7 %(V)

flammability limit GLP: Calculated Explosive Limit

Lower explosion limit / Lower : 0.9 %(V)

flammability limit GLP: Calculated Explosive Limit

Vapour pressure : 0.1 hPa (68 °F / 20 °C)

Calculated Vapor Pressure

Relative vapour density : No data available

Relative density : No data available

Density : 0.8901 g/cm3 (60.01 °F / 15.56 °C)

Solubility(ies)
Water solubility : No data available

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Decomposition temperature :

No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Oxidizing properties : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.

Chemical stability : Stable under recommended storage conditions.

Possibility of hazardous : Product will not undergo hazardous polymerization.

reactions

Conditions to avoid : None known.

Incompatible materials : Strong oxidizing agents

Acids

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

Hazardous decomposition
products No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation
Skin contact
Eye Contact
Ingestion
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg

Method: Calculation method

Components:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
Acute oral toxicity : LD50 (Rat): > 15 g/kg

Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg

Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate:

Acute oral toxicity : LD50 (Rat): 2,230 mg/kg
GLP: no

Acute inhalation toxicity : LC50 (Rat): > 2.3 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: Not classified as acutely toxic by inhalation
under GHS.
Remarks: Information given is based on data obtained from
similar substances.

Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg

Method: OECD Test Guideline 402
Assessment: Not classified as acutely toxic by dermal
absorption under GHS.

Skin corrosion/irritation
Not classified based on available information.
Product:
Remarks : May cause skin irritation in susceptible persons.

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

Components:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
Assessment : Slight, transient irritation
Result : Slight, transient irritation

Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate:

Species : Rabbit
Method : OECD Test Guideline 404
Result : Irritating to skin.
GLP : yes

Serious eye damage/eye irritation

Causes serious eye irritation.
Product:
Remarks : Causes serious eye irritation.
Vapours may cause irritation to the eyes, respiratory system
and the skin.

Components:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
Result : No eye irritation
Assessment : No eye irritation

Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate:

Result : Corrosive

Respiratory or skin sensitisation

Skin sensitisation
Not classified based on available information.
Respiratory sensitisation
Not classified based on available information.
Components:
Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate:
Species : Guinea pig
Assessment : Did not cause sensitisation on laboratory animals.
Method : OECD Test Guideline 406
Result : Did not cause sensitisation on laboratory animals.
GLP : yes

Germ cell mutagenicity

Not classified based on available information.
Components:
Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Result: negative

Carcinogenicity
Not classified based on available information.

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

Components:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
Carcinogenicity - : Classified based on DMSO extract content < 3% (Regulation
Assessment (EC) 1272/2008, Annex VI, Part 3, Note L)

IARC No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.

Components:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
No aspiration toxicity classification

Further information
Product:
Remarks : No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Ecotoxicology Assessment
Short-term (acute) aquatic : Not classified based on available information.
hazard

Long-term (chronic) aquatic : Not classified based on available information.

hazard

Components:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
Toxicity to fish : LL50 (Fish): > 100 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EL50 (Aquatic invertebrates): > 10,000 mg/l
aquatic invertebrates Exposure time: 48 h

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

Toxicity to algae : EL50 (Algae, algal mat (Algae)): > 100 mg/l
Exposure time: 72 h

Toxicity to fish (Chronic : NOEC (Fish): 10 mg/l

toxicity)

Toxicity to daphnia and other : NOEC (Aquatic invertebrates): 10 mg/l

aquatic invertebrates
(Chronic toxicity)

Ecotoxicology Assessment
Short-term (acute) aquatic : Not classified based on available information.
hazard

Long-term (chronic) aquatic : Not classified based on available information.

hazard

Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate:

Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 4.5 mg/l
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203
Remarks: Information given is based on data obtained from
similar substances.

Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 23 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
GLP: yes

Toxicity to algae : NOEL (Desmodesmus subspicatus (green algae)): 10 mg/l

End point: Growth inhibition
Exposure time: 72 h
Test Type: static test
Test substance: WAF
Method: OECD Test Guideline 201
Remarks: Information given is based on data obtained from
similar substances.

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.4 mg/l
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Test substance: WAF
Method: OECD Test Guideline 211
Remarks: Information given is based on data obtained from
similar substances.

Persistence and degradability

Components:
Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate:

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Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

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Biodegradability : Result: Not readily biodegradable.

Biodegradation: 1.5 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
Remarks: Information given is based on data obtained from
similar substances.

No data available
Bioaccumulative potential
Components:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
Partition coefficient: n- : log Pow: Expected > 7
octanol/water

No data available
Mobility in soil
Components:
No data available
Other adverse effects
No data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks This product neither contains, nor was manufactured with a
Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological : No data available

information

Components:

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
General advice : Dispose of in accordance with all applicable local, state and
federal regulations.

Send to a licensed waste management company.

Do not contaminate ponds, waterways or ditches with
chemical or used container.
Do not dispose of waste into sewer.

Contaminated packaging : Do not re-use empty containers.

Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Dispose of as unused product.
Empty remaining contents.

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Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

49 CFR
Not regulated as a dangerous good

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Serious eye damage or eye irritation

SARA 313 : The following components are subject to reporting levels

established by SARA Title III, Section 313:

Zinc O,O,O',O'- 2215-35-2 >= 1 - < 5 %

tetrakis(1,3-
dimethylbutyl)
bis(phosphorodit
hioate

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

Zinc, bis[O,O- 4259-15-8 >= 0.1 - < 1 %

bis(2-ethylhexyl)
phosphorodithioa
to-S,S']-, (T-4)-

Clean Air Act

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section
307
Zinc O,O,O',O'- 2215-35-2 >= 1 - < 5 %
tetrakis(1,3-
dimethylbutyl)
bis(phosphorodithioate
This product does not contain any priority pollutants related to the U.S. Clean Water Act
The components of this product are reported in the following inventories:
DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ENCS : Contact your sales representative for additional information.

KECI : On the inventory, or in compliance with the inventory

IECSC : q (quantity restricted)

PICCS : On the inventory, or in compliance with the inventory

TCSI : On the inventory, or in compliance with the inventory

TSCA : On TSCA Inventory

TSCA list
No substances are subject to TSCA 12(b) export notification requirements.
Inventories

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 SAFETY DATA SHEET
Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information
Internal information : R0169797

NFPA: HMIS III:

Flammability

HEALTH 2
1
Instability
Health

2 0 FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
Special hazard 2 = Moderate, 3 = High
4 = Extreme, * = Chronic

NFPA Flammable and Combustible Liquids Classification

Combustible Liquid Class IIIB

Full text of H-Statements

H315 Causes skin irritation.
H318 Causes serious eye damage.

Sources of key data used to compile the Safety Data Sheet

Valvoline internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for
labelling (GHS) and transport.

The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This SDS has been
prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE).

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Valvoline™ VR1 Racing™ SAE 50 Racing Oil

Version: 1.5 Revision Date: 04/29/2020 Print Date:

09/07/2021

List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data
sheet :
ACGIH : American Conference of Industrial Hygienists
BEI : Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the American Chemical Society).
CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade
GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
H-statement : Hazard Statement
IATA : International Air Transport Association.
IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA).

ICAO : International Civil Aviation Organization

ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization”
IMDG : International Maritime Code for Dangerous Goods
ISO : International Organization for Standardization
logPow : octanol-water partition coefficient
LCxx : Lethal Concentration, for xx percent of test population
LDxx : Lethal Dose, for xx percent of test population.
ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx
N.O.S.: Not Otherwise Specified
OECD : Organization for Economic Co-operation and Development
OEL : Occupational Exposure Limit
P-Statement : Precautionary Statement
PBT : Persistent , Bioaccumulative and Toxic
PPE : Personal Protective Equipment
STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity
TLV : Threshold Limit Value
TWA : Time-weighted average
vPvB : Very Persistent and Very Bioaccumulative
WEL : Workplace Exposure Level

CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act

DOT : Department of Transportation
FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act
HMIRC : Hazardous Materials Information Review Commission
HMIS : Hazardous Materials Identification System
NFPA : National Fire Protection Association
NIOSH : National Institute for Occupational Safety and Health
OSHA : Occupational Safety and Health Administration
PMRA : Health Canada Pest Management Regulatory Agency
RTK : Right to Know
WHMIS : Workplace Hazardous Materials Information System

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