REACTIONS OF D- BLOCK ELEMENTS
REACTANT PRODUCT
REACTANT PRODUCT
KMnO4+ H2O2+ H+ O2 + Mn2+ +H2O
KMnO4+ H2S+ H+ S + Mn2+ +H2O
KMnO4+ SO2+ H2O SO42- + Mn2+ +H+
KMnO4+ SO2(excess)+ H2O S2O62- + SO42- + Mn2+ + H+
KMnO4+ Fe2+ + H+ Fe3+ + Mn2+ + H2O
KMnO4+ I- + H+ I3- + Mn2+ + H2O
KMnO4+ NO2-+ H+ Mn2+ + NO3- + H2O
KMnO4+ C2O42-+ H+ CO2 + Mn2+ + H2O
KMnO4+ I-+ H2O MnO(OH)2 + IO3- + OH-
KMnO4+ SO32-+ H2O MnO(OH)2 + SO42- + OH-
KMnO4+ HCl Cl2 + Mn2+ + Cl- + H2O
KMnO4+ OH- MnO42- + O2 + H2O
MnO42-+ H2O MnO4- + MnO(OH)2 + OH-
KMnO4 + Heat K2MnO4 + MnO2 + O2
KMnO4 + HCOOK MnO2 + KHCO3 +K2CO3 +H2O
KMnO4 + MnSO4 + H2O(in presence MnO2 + K2SO4 +H2SO4
of Zn+2)
KMnO4 + Na2S2O3 +H2O MnO2 + Na2SO4 + S +KOH
K2MnO4 + Cl2 KMnO4 + KCl
K2MnO4 + O3 + H2O KMnO4 + KOH + O2
K2CrO4 + H2SO4 K2Cr2O7 + K2SO4 + H2O
FeCr2O4 + Na2CO3 + O2 Na2CrO4 + Fe2O3 + CO2
Na2Cr2O7 + KCl K2Cr2O7 + NaCl
K2Cr2O7 + HEAT K2CrO4 + Cr2O3 + O2
K2Cr2O7 + H2SO4 K2SO4 + Cr2(SO4)3 +H2O + O2
K2Cr2O7 + H2SO4 + FeSO4 K2SO4 + Cr2(SO4)3 + Fe2(SO4)3 +H2O
K2Cr2O7 + H2SO4 + KI K2SO4 + Cr2(SO4)3 + I2 + H2O
K2Cr2O7 + H2SO4 + Na2SO3 K2SO4 + Cr2(SO4)3 + Na2SO4 + H2O
K2Cr2O7 + H2SO4 + H2S K2SO4 + Cr2(SO4)3 + H2O + S
K2Cr2O7 + H2SO4 + SO2 K2SO4 + Cr2(SO4)3 + H2O
K2Cr2O7 + Cl- + H+ Cl2 + Cr3+ + H2O
K2Cr2O7 + NO2- + H+ NO3- + Cr3+ + H2O
K2Cr2O7 + S2O32- + H+ SO42- + S + Cr3+ + H2O
K2Cr2O7 + Sn2+ H+ Sn4+ + Cr3+ + H2O
K2Cr2O7 + RCH2OH RCHO and then to RCOOH
K2Cr2O7 + CHCl3 COCl2 + Cl2 + H2O
K2Cr2O7 + ANILINE p- benzoquinone
K2Cr2O7 + H2O2 + H2SO4 K2SO4 + CrO5 + H2O
K2Cr2O7 + H2O2 (neutral solution) K[CrO(O2)2.OH] + H2O + O2
K2Cr2O7 + KOH K2CrO4 + H2O
CHAMP SQUARE, Sunrise Forum, 2nd Floor (Debuka Nursing Home Lane), Circular Road, Ranchi – 834 001, Ph.: 0651-6999023
K2CrO4 + H+ K2Cr2O7 + H2O
K2CrO7 + H2SO4(CONC.and COLD) CrO3(RED CRYSTAL) + K2SO4 + H2O
K2Cr2O7 + H2SO4(2N and warmed) K2SO4 + Cr2(SO4)3 + H2O +O2
K2Cr2O7 + HCl ( COLD & CONC.) KCl + CrCl3 + H2O + Cl2
K2Cr2O7 + HCl (WARM & CONC.) KCrO3Cl (potassium chlorochromate,
petigot’s salt)+H2O
K2Cr2O7 + Pb(NO3)2 + H2O PbCrO4 + KNO3 + HNO3
K2Cr2O7 + Pb(NO3)2 PbCr2O7 + KNO3
K2Cr2O7 + K2CO3 K2CrO4 + CO2
K2Cr2O7 + C + H2O Cr2O3 + KOH + CO
K2Cr2O7 + NH4Cl + HEAT Cr2O3 + KCl + H2O + N2
K2Cr2O7 + BORIC ACID + H2O Cr2O3.2H2O(Guigret’s green)
K2Cr2O7 + H2SO4 + SO2 K2SO4 + Cr2(SO4)3 + H2O ( which
finally crystallizes to chrome alum)
K2Cr2O7 + K4[Fe(CN)6] K2O + Cr2O3 + KCNO +K2Fe[Fe(CN)6]
K2Cr2O7 + NaCl + H2SO4 CrO2Cl2 + K2SO4 + Na2SO4 + H2O
REACTANT PRODUCT
CrO3 + HCl CrO2Cl2
CrO2Cl2 + H2O H2CrO4 + HCl
CrO2Cl2 + HEAT Cr2O3 + Cl2 + O2
CrO2Cl2 + TOLUENE in CS2 BENZALDEHYDE( Etard reaction)+
CrCl2
CrO2Cl2 + NaCl + H2O NaCrO3Cl + HCl
CrO2Cl2 + F2 CrO2F2 + Cl2
CrO2Cl2 + HF CrO2F2 + HCl
CrO2Cl2 + NaOH Na2CrO4 + NaCl + H2O
CrO2Cl2 + H2O + Pb(CH3COO)2 PbCrO4 + HCl + CH3COOH
CHAMP SQUARE, Sunrise Forum, 2nd Floor (Debuka Nursing Home Lane), Circular Road, Ranchi – 834 001, Ph.: 0651-6999023
