— spre Comgauve rropertie Questions For Practice suestions For Practice ven short Answer ‘Type Questions Y Give an example of maximum boiling azeotrope. sain 9, What type of intermolecular interaction exist between meth, § Calculate the boiling point of solution when 2 g of N anol and acetone? [Delhi 2014] dissolved in 50 g of water, assuming Na ‘O, (molar ma 50 42 g mol!) was O52 K ke mol") SO, undergoes complete ionisation. (k, for H,O = 52 5 | LAL 2016 short Answer Type Questions-1 aT P ; ee (2 Marks) 4, Vapour pressure of water as 20°C is 17.5 mm Hg. Calculate the vapour pressure of water at 20°C when 15 g of gluc (Molar mass 180 g mol") is dissolved in 150g of water, a a (CBSE 2015] 5. Calculate the boiling point of 1 molar solution of KCI (molar mass 74.5 g mol"). The density of solution is 1.04 g em~ and &, for H,0 is 0.52 K kg mol, 6, Calculate osmotic pressure of 0.1 M K,(Fe(CN),] solution if it is 50% ionised at 27°C. Short Answer Type Questions-II (3 Marks) 7. A 10% solution (by mass) of sucrose in water has freezing point of 269.15 K. Calculate the freezing point of 10% solution of glucose in water, if freezing point of pure water is 273.15 K (Delhi 2017] [Given: Molar mass of glucose = 180 g mol-!, Molar mass of sucrose = 342 g mol" 8. Calculate the van’t Hoff factor in each of the following: (i) 30% ionised K,[Fe(CN),] (ii) 60% ionised CaCl, (iii) Benzoie acid which is 50% dimerised in benzene. 9. A solution of glucose (molar mass = 180 g mol-*) in water has a boiling point of 100.20°C Calculate the freezing point of the same solution. Molal constants for water, k, and hy, are 1.86 K kg mol and 0.512 K kg mol", respectively. (Delhi 2017 10. Some ethylene glycol, HOCH, - CH,,OH, is added to your Car's radiator along with 5 kg 0 water. If the freezing point of water-glycol solution is -15°C. What is the boiling point o the solution? (k, = 0.52 K kg mol", and k= 1.86 K kg mol" for H,O] [AI 2014 Answers 1. CHCL, and Acetone 2. H-bonding and dipole-dipole interaction 3. 373.44 K 4,17.325mmHg 5. 374.077 K 6. x =7.47 bar 7, 265.55 K 8. (i =3, (ii) i= 2.2, (iii) I= 0.75 9. -0.73 °C 10. 377.19 KASSIGNMENT Time: 45 Minutes Very Short Answer Type Questions 1, State Henry's law. 2. Define azeotropes. Short Answer Type Questions-I - , Maris) 3. Based on solute-solvent interactions, arrange the following in order of increasing Solubility in n-octane and explain. Cyclohexane, KCl, CH,OH, CH,CN. ; : 4. (@ On mixing liquid X and Y, the volume of resulting solution decreases. What type of deviation from Raoult’s law is shown by the resulting solution? What change in temperature would you observe? (ii) How can the direction of osmosis be reversed? 5. What do you understand by depression in freezing point? Derive the relationship between depression in freezing point and molar mass of the component of solution. Short Answer Type Questions-II (3 Marks) 6. A solution is prepared by dissolving 5 g of non-volatile solute in 95 g of water. It has vapour pressure 23.375 mm Hg at 250°C. Calculate the molar mass of solute (p2 = 23.75 mm He). 7. Calculate the mass of NaC! (M.Wt. 58.5 g mol-) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming NaCl undergoes complete dissociation. 8. Determine the osmotic pressure of a solution prepared by dissolving 2.5 x 10-2 g of K,80, in 2 L solution at 25°, assuming it is completely ionised. {R = 0.0821 L atm K mL, K,SO, molar mass = 174 g mol L-}} 9. A 10% solution of urea is isotonic with 20% solution of an unknown solute ‘X’ at the same temperature. Calculate molar mass of X. Long Answer Type Questions 10. Amongst the following com; highly soluble in water? (@ phenol (ii) toluene (iii) formic acid (w) ethylene glycol (v) chloroform ; (5 Marks) pounds, identify which are insoluble, partially soluble and Answer: 5, BxMxT? s * 1000xaH =; 6. 60 g mol! 717g 8. 5.27 x 10 atm 9. 120 g molt . mol"